Product With Molecular Orientation Patents (Class 428/910)
  • Patent number: 7112360
    Abstract: The invention relates to a transparent, biaxially oriented polyester film which comprises at least 80% by weight of thermoplastic polyester and also comprises an amount in the range from 0.05 to 0.5% by weight of a specific pigment system. The invention further relates to a process for producing the film. The film can be used as a packaging film, or for metalizing or ceramic coating, and in applications in the industrial sector, as a substrate for stamping foils.
    Type: Grant
    Filed: December 18, 2003
    Date of Patent: September 26, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Martin Mueller-Roosen, Gottfried Hilkert
  • Patent number: 7108908
    Abstract: The present invention discloses a multi-layered stretched resin film which comprises a base layer (A) containing 40 to 90 wt % of a polyolefinic resin and 10 to 60 wt % of an inorganic fine powder or an organic filler; and an amorphous resin-containing layer (B) provided on at least one side of such base layer (A), and containing 0 to 85 wt % of a polyolefinic resin and 15 to 100 wt % of an amorphous resin; where the amorphous resin-containing layer (B) has a porosity of 5% or below. Such multi-layered stretched resin film is successfully exempt from being waved or curled due to vehicle contained in offset printing ink during offset printing, and can thus ensure excellent printability.
    Type: Grant
    Filed: February 2, 2004
    Date of Patent: September 19, 2006
    Assignee: Yupo Corporation
    Inventors: Atsushi Ishige, Kazuhisa Kitamura
  • Patent number: 7105223
    Abstract: The invention relates to a single-layer, oriented polyester film where the polyester comprises an additive which on irradiation with electromagnetic radiation forms metal nuclei on which further metal can be accumulated during further steps of the process. The invention further relates to a process for producing this film and to its use in printed circuit boards, ribbon cables, smart cards, RFID labels, membrane keyboards, and film-based circuits, of any type.
    Type: Grant
    Filed: September 15, 2004
    Date of Patent: September 12, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Thorsten Kiehne, Gottfried Hilkert, Bodo Kuhmann
  • Patent number: 7101605
    Abstract: White, biaxially oriented polyester films which have a base layer B which comprises a thermoplastic polyester such as polyethylene terephthalate, and which comprise substantially only TiO2 as a white pigment, whose R value is less than 43 daN/mm2, whose emax ratio is less than 2.5 and at least one of whose two surfaces of the film has been provided with an acrylate-containing coating, are particularly tear-resistant and do not tend to delamination and are therefore suitable in particular as lid films for food containers, for example yoghurt cups. A process is described for producing the films.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: September 5, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Thorsten Kiehne, Herbert Peiffer, Bodo Kuhmann
  • Patent number: 7101627
    Abstract: The use of a heat-stabilized, heat-set oriented film comprising poly(ethylene naphthalate) as a substrate in, or in the manufacture of, an electronic or opto-electronic device containing a conjugated conductive polymer, wherein said film has a shrinkage at 30 mins at 230° C. of less than 1%; and a composite film comprising such a substrate layer and on a surface thereof a barrier layer.
    Type: Grant
    Filed: September 10, 2002
    Date of Patent: September 5, 2006
    Assignee: DuPont Teijin Films U.S. Limited Partnership
    Inventors: William Alasdair MacDonald, Leigh Beckett Richardson
  • Patent number: 7097912
    Abstract: Antimicrobial and antifogging polymeric films with preferable A/C/E structure useful for the food, medicine and agriculture applications as well as for other general packaging and non-traditional special applications. More preferably, animicrobial and antifogging films having a A/B/C/E structure. Most preferably, antimicrobial and antifogging films having a A/B/C/D/E structure. A multilayer structure (having at least an skin layer (A) having antifogging and antimicrobial properties/a core layer (C)/an outer layer (E) structure) for semi and biaxially oriented polyolefin based antifogging films having advantageous properties as compared with known and commercial films such as low values of haze, high values of sheen, lower longitudinal and transverse shrinkage, which provides high dimensional stability, and excellent antifogging and antimicrobial properties. Preferably the skin layer (A), having antifogging and antimicrobial properties, is electrical corona or flame treated.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: August 29, 2006
    Inventors: Oktay Aral, Cumbur Buyukakinci, Zakir Rzaev
  • Patent number: 7094465
    Abstract: The invention relates to a multilayer, transparent, biaxially oriented polyester film having at least one base layer B composed of a thermoplastic polyester, at least one overlayer A coextruded on the base layer B and at least one acrylic coating D which is applied to the film as an aqueous dispersion. The invention further relates to a process for producing the film and to its use.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: August 22, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Gottfried Hilkert
  • Patent number: 7094460
    Abstract: The present invention relates to an imaging member comprising an imaging layer and a base wherein said base comprises a polymer sheet having at least one oriented polymer core and adhered thereto at least one unoriented polymer layer. Another embodiment relates to an imaging element comprising an imaging layer and a base, wherein said base comprises an integral polymer sheet having at least one oriented polymer core and at least one unoriented polymer layer. The invention further relates to a process of manufacturing a base for an imaging element comprising the steps of extruding a voided core polymer sheet; orienting said extruded voided core polymer sheet; and extrusion coating said oriented extruded voided core polymer sheet with at least one unoriented polymer layer.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: August 22, 2006
    Assignee: Eastman Kodak Company
    Inventors: Peter T. Aylward, Sandra J. Dagan, Suresh Sunderrajan
  • Patent number: 7090788
    Abstract: This invention provides composite materials that combine the material properties of hydrophobic polymers with internal structure and order provided by polymerization of lyotropic liquid crystals (LLCs). Composites, particularly nanocomposites, are made by forming a LLC assembly that has hydrophobic regions and hydrophilic regions, combining hydrophobic polymer in the assembly and polymerizing the polymerizable LLC monomers in the assembly. The hydrophobic polymer, polymerized LLC assembly or both can be crosslinked in the composite. Nanoporous composites, particularly those with uniform-sized pores and/or with uniform pores distribution can be prepared in this way. In addition, complex polymers in which a second polymeric material, which may be organic or inorganic, can be introduced into the pores or other structural features of the composite can be prepared.
    Type: Grant
    Filed: April 24, 2003
    Date of Patent: August 15, 2006
    Assignee: TDA Research, Inc.
    Inventor: Brian Elliott
  • Patent number: 7087313
    Abstract: Disclosed is a biaxially stretched polylactic acid multilayer film and the use thereof as packaging film. The gist of the biaxially stretched polylactic acid multilayer film resides in the construction wherein a substrate layer (1) of the biaxially stretched film comprised of polylactic acid (A) has been laminated on at least one surface thereof with a coating layer (II) of an aliphatic polyester composition (D) comprised of 97˜5% by weight of an aliphatic polyester copolymer (B) having a melting point (Tm) of 80˜120° C., a crystallizing temperature (Tc) of 35˜75° C. and a difference of (Tm)?(Tc) within the range of 35˜55° C. and comprising an aliphatic or alicyclic dicarboxylic acid component (b1), an aliphatic or alicyclic dihydroxyl compound component (b2) and a difunctional aliphatic hydroxycarboxylic acid component (b3) and 3˜95% by weight of a polylactic acid copolymer (C) containing 7˜30% by weight of D-lactic acid, a total of the ingredients (B) and (C) being 100% by weight.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: August 8, 2006
    Assignee: Tohcello Co., Ltd.
    Inventors: Tohru Sawai, Junichi Narita, Hiroyuki Wakaki
  • Patent number: 7083848
    Abstract: The invention relates to a single- or multilayer, oriented film in which at least one layer is comprised of a thermoplastic polymer having a minimum amount of amide groups. The polymer is a polyester, a polyamide, or a mixture comprised of polyester and polyamide, or is a copolymer comprised of these two materials. The film also comprises a component a) which, when irradiated with electromagnetic or particulate radiation, forms metal nuclei onto which further metal can be accumulated in further steps of the process. The invention also relates to a process for the production of this film, and to its use in printed circuit boards, ribbon cables, smart cards, RFID labels, membrane keyboards, or film-based circuits of any type.
    Type: Grant
    Filed: January 18, 2005
    Date of Patent: August 1, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Holger Kliesch, Thorsten Kiehne, Gottfried Hilkert, Ingo Fischer
  • Patent number: 7083847
    Abstract: Birefringent optical films have a Brewster angle (the angle at which reflectance of p-polarized light goes to zero) which is very large or is nonexistent. This allows for the construction of multilayer mirrors and polarizers whose reflectivity for p-polarized light decreases slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer films having high reflectivity (for both planes of polarization for any incident direction in the case of mirrors, and for the selected direction in the case of polarizers) over a wide bandwidth, can be achieved.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: August 1, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: James M. Jonza, Michael F. Weber, Andrew J. Ouderkirk, Carl A. Stover
  • Patent number: 7078105
    Abstract: A conformable oriented polymeric film comprising a layer of copolyester derived from: (i) one or more diol(s); (ii) an aromatic dicarboxylic acid; and (iii) one or more aliphatic dicarboxylic acid(s) of the general formula CnH2n(COOH)2 wherein n is 2 to 8, wherein the aromatic dicarboxylic acid is present in the copolyester in an amount of from 60 to 85 mole % based on the total amount of dicarboxylic acid components in the copolyester, wherein the copolyester is a random or alternating copolyester, and wherein after deformation by subjecting and maintaining the film to 7% strain, the stress within the film immediately after deformation dissipates to a residual value of less than 60% of the original value within 10 minutes of said deformation; and use thereof as a conformable medium for signage, advertising, graphic art and other display applications or as an overlaminate for such media.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: July 18, 2006
    Assignee: DuPont Teijin Films U.S. Limited Partnership
    Inventor: Duncan Henry MacKerron
  • Patent number: 7078103
    Abstract: A conductive organic thin film includes organic molecules, each of which has: a terminal binding group that is bound with a surface of a substrate by a covalent bond, the terminal binding group being present at one of the ends of the organic molecule; a conjugate group that is polymerized with another molecule, the conjugate group being present in the organic molecule; and a photoresponsive functional group including no active hydrogen, the photoresponsive functional group being present between the terminal binding group and the conjugate group. In the conductive organic thin film, the organic molecules are aligned, and the conjugate group of each molecule is polymerized with the conjugate group of another molecule so that a conductive network is formed. This conductive organic thin film has an optical switching function, having a conductivity that varies in response to irradiation of light.
    Type: Grant
    Filed: December 25, 2001
    Date of Patent: July 18, 2006
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 7074467
    Abstract: Disclosed herein is a heat-shrinkable co-polyester film containing terephthalic acid or dimethyl terephthalate as a dicarbonic acid component, and ethylene glycol, neopentyl glycol and propylene glycol as diol components, in which the co-polyester film has a crystallization temperature of 80–220° C., and a heat shrinkage (%) higher than 30% in at least one direction of longitudinal and transverse directions in 90° C. hot water. This film is suitable for use as various wrapping materials, such as covering, binding and casing materials. Particularly, this film is used to cover a cap, body and shoulder, etc. of various vessels and rod-shaped molded articles and thus to provide labeling, protection, binding or an improvement in product value. Also, this film can be used for multi-package.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: July 11, 2006
    Assignee: Toray Saehan Inc.
    Inventors: Sang-pil Kim, Byung-sik Park, Gi-Jeong Moon, Sang-Duk Oh, Jung-Won Kim
  • Patent number: 7063885
    Abstract: A multi-layer, thermoplastic film bi-axially oriented at a stretching ratio ? to about 3.0:1 in the machine direction and at a stretching ratio ? about 6.0:1 in the transverse direction, which film comprises a layer a) comprising at least 50 wt. % of a crystalline or partially crystalline co-polyamide characterized by a Tg?100° C. and at least one outer heat-sealing layer b) comprising a polyolefin, said film being further characterized in that it has a % free shrink at 100° C.?3 in each direction.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 20, 2006
    Assignee: Cryovac, Inc.
    Inventors: Eugenio Longo, Roberto Forloni, Gregorio Di Cesare
  • Patent number: 7060341
    Abstract: A stretchable conveyor belt having a plurality of first cuts which extend in a widthwise direction of the belt, which extend from one of opposite surfaces of the belt toward the other surface thereof and do not reach said other surface, and which are provided at a regular interval of distance in a lengthwise direction of the belt, and/or a plurality of second cuts which extend in the widthwise direction of the belt, which extend from said other surface of the belt toward said one surface thereof and do not reach said one surface, and which are provided at a regular interval of distance in the lengthwise direction of the belt, the first cuts and/or the second cuts providing a stretchability of the belt.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: June 13, 2006
    Assignees: Bando Chemical Industries, Ltd., Ishikawajima Transport Machinery Co., Ltd.
    Inventors: Masashi Mima, Osamu Jibu, Katsuya Teramoto, Shinichi Saruyama
  • Patent number: 7056573
    Abstract: The invention relates to a co-extruded, biaxially oriented polyester film consisting of a base layer and at least one outer layer. The film contains a UV-stabilizer and has a matt outer layer which contains a mixture and/or a blend of two components (I) and (II), whereby component (I) is substantially a polyethylene terephthalate homopolymer or a polyethylene terephthalate copolymer, or a mixture of polyethylene terephthalate homopolymers or polyethyleneterephthalate copolymers, and component (II) is a polymer which contains at least one sulphonate group.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: June 6, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Gottfried Hilkert
  • Patent number: 7056592
    Abstract: Propylene homopolymers useful in the manufacture of biaxially oriented films are provided. More particularly, the propylene homopolymers of the present invention are useful as core material for a multilayer biaxially oriented film. The propylene homopolymers of the present invention attain these properties by control of the average meso sequence length, Nm, in the xylene insoluble phase of the polymer concurrently with control of the quantity of xylene solubles in the polymer as a whole. The propylene homopolymers according to the current invention comprise from about 97 to about 91 percent by weight of a xylene insoluble fraction, and from about 9 to about 3 percent by weight of a xylene soluble fraction. The xylene insoluble fraction has a meso run length of less than or equal to 130.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: June 6, 2006
    Inventor: Sehyun Kim
  • Patent number: 7052774
    Abstract: The invention relates to a biaxially oriented polypropylene multilayer film, which comprises at least one base layer (B), an intermediate layer (I) and a top layer (I), and which contains anti-fog additives. The anti-fog additive is only added to the intermediate layer (I) in a quantity ranging from 0.5 to 8 wt. % with regard to the weight of the intermediate layer, and the film contains a maximum of 0.5 to <1 wt. % of anti-fog additives with regard to the total weight of the film. The film is suited for packaging moist goods.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: May 30, 2006
    Assignee: Trespaphan GmbH
    Inventors: Susanne Holzer, Gerhard Wieners
  • Patent number: 7041344
    Abstract: A polyester film which is excellent in uniform light diffusibility, heat-resistant dimensional stability and luminance and suitable as a substrate of a light-diffusing plate of a liquid crystal display device. The film comprises a polyester containing polyethylene-2,6-naphthalene dicarboxylate as a main component and has a heat shrinkage in two directions perpendicular to each other in the surface of the film of not higher than 0.3% when heat-treated at 105° C. for 30 minutes, a dimensional change rate in two directions perpendicular to each other in the surface of the film under a stress of 0.37 MPa within a temperature range of 30 to 150° C. of not higher than 1.0%, a density of not lower than 1.350 g/cm3, a total light transmittance of not lower than 87%, a haze value of lower than 1.5% and a thickness of 50 to 150 ?m.
    Type: Grant
    Filed: June 7, 2001
    Date of Patent: May 9, 2006
    Assignee: Teijin Limited
    Inventors: Hiroshi Kusume, Koji Furuya
  • Patent number: 7029734
    Abstract: A multilayer packaging film, package and process for aseptic packaging applications. The multilayer packaging film includes (a) an inner sealant layer comprising a olefin polymer having a Vicat Softening Point greater than 90° C.; (b) an oxygen barrier layer; and (c) an outer layer comprising a polymeric layer selected from olefin polymers and polyester homopolymers or copolymers having a silicone or other hydrogen peroxide resistant exterior coating, said outer layer having a Vicat Softening Point greater than 90° C.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: April 18, 2006
    Assignee: Curwood, Inc.
    Inventors: Sam Edward Wuest, Richard Roy Bellile
  • Patent number: 7026379
    Abstract: A copolymer resin composition provided by the process of the present invention is of considerable strength and moldability and is produced by polymerization of a monosaccharide or a polysaccharide that is derived from natural objects and has a hydroxyl group, and a carboxyl group or a salt thereof with a compound having a hydroxyl group and a carboxyl group. The monosaccharide or the polysaccharide serves as a polyfunctional central compound. The copolymer resin composition is obtained through dehydration-polycondensation of (A) at least one selected from the group consisting of a monosaccharide and a polysaccharide having a hydroxyl group, and a carboxyl group or an ion-exchanged carboxyl group; and (B) at least one selected from the group consisting of (b1) hydroxycarboxylic acid, (b2) polyhydroxycarboxylic acid, (b3) a mixture of an aliphatic polyol and an aliphatic polybasic acid, and (b4) an aliphatic polyester obtained by the reaction of an aliphatic polyol with an aliphatic polybasic acid.
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: April 11, 2006
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yumiko Oyasato, Shinetsu Fujieda, Kazutaka Matsumoto
  • Patent number: 7022407
    Abstract: A film which is a biaxially oriented film comprising polyethylene-2,6-naphthalenedicaboxylate as a principal component, having a thermal strain ratio RMD (150) in the machine direction of the film at a temperature of 150° C. is ?1.5%?RMD (150)?0.0% when the thermal strain ratio RMD (T) in the machine direction of the film at a temperature T° C. based on the length LMD (t) in the machine direction (MD) of the film at a temperature t° C. is defined by RMD(T)={[LMD(T)?LMD(35)]/LMD(35)}×100(%), excellent in insulation characteristics without lowering processing characteristics, especially the characteristics during hot-pressing and suitable as a dielectric for capacitors.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: April 4, 2006
    Assignee: Teijin Limited
    Inventors: Koji Furuya, Hiroshi Kusume, Makoto Handa
  • Patent number: 7022397
    Abstract: There is provided a membrane switch film comprising polyethylene 2, 6-naphthalenedicarboxylate as the major component and having excellent handling properties and durability, and particularly a film which is suitable for a membrane switch to be used in automobile interior devices which are potentially exposed to high temperature. The film is a membrane switch film having a refractive index in the range of 1.770–1.790 on both surfaces in either or both the film processing direction and the widthwise direction and an absolute value of no greater than 0.015 for the difference between the refractive indexes of both surfaces.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: April 4, 2006
    Assignee: Teijin DuPont Films Japan Limited
    Inventors: Koji Furuya, Makoto Handa
  • Patent number: 7018689
    Abstract: A heat-shrinkable polyester film comprising a polyester base film and a coat layer formed on one or both sides of the polyester base film, said coat layer comprising a copolymerised polyester having carboxyl group terminals and Tg in the range of 70 to 80;É, exhibits superior properties suitable for labeling or shrink-wrapping containers.
    Type: Grant
    Filed: November 2, 2002
    Date of Patent: March 28, 2006
    Assignee: SKC Limited
    Inventors: Junggyu Lee, Jonghyuk Eun, Namil Kim, Sangil Kim, Yongin Park, Changju Lee
  • Patent number: 7011882
    Abstract: The invention relates to a multi-layered biaxially orientated polyolefin film comprising a base layer and at least one protective coating. Said protective coating contains, as the main component, one copolymer or terpolymer I, which seals against PVDC and acrylate lacquers and coatings and consists of an olefin and unsaturated carboxylate acids or the esters thereof, and small quantities of wax. The film is provided on one side with a PVDC or acrylate coating so that it can be used as roll-wrap packaging.
    Type: Grant
    Filed: September 11, 2001
    Date of Patent: March 14, 2006
    Assignee: Trespaphan GmbH
    Inventors: Susanne Holzer, Gerhard Wieners, Wilfried Tews
  • Patent number: 7011883
    Abstract: The present invention relates to a display strip to hold commodity-containing bags. It can facilitate to make a process of attaching the bags thereto automate. It enables commodity-containing bags to be removed therefrom without having their appearance degraded. The display strip according to the present invention is utilized to hold and align a plurality of commodity-containing bags vertically for the display. It comprises at least a substrate layer and a sealant layer with the sealant layer containing an ethylene-vinyl acetate copolymer and an adhesive promoting tackifier.
    Type: Grant
    Filed: May 6, 2003
    Date of Patent: March 14, 2006
    Assignee: Ishida Co., Ltd.
    Inventors: Yoshio Iwasaki, Yukio Nakagawa, Tadao Oota, Naoji Ichise
  • Patent number: 7008698
    Abstract: A shrinkable polymer film including a modified polyester resin polymerized from monomers including a dicarboxylic acid and a glycol, wherein the glycol includes 2-methyl-1,3-propanediol, and wherein the polymer film shrinks at least about 50% in a main shrinkage direction after ten seconds in an 80 degree Celsius hot water bath.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: March 7, 2006
    Assignee: Mitsubishi Polyester Film, LLC
    Inventors: Chadwick E. Marlow, Charles D. Carlson, Jr., Robert G. Posey, Gary R. Garner, Russell S. Foxhall
  • Patent number: 7005169
    Abstract: Biaxially oriented polyester films which have a polyester-containing base layer (B) which additionally comprises poly(m-xyleneadipamide) and has been provided on at least one side with an overlayer (A) which has been coated with a barrier layer (D), said barrier layer comprising polyvinyl alcohol and a copolymer of maleic acid and acrylic acid, feature improved optical properties such as high gloss and low opacity and very good barrier properties, in particular toward the passage of oxygen, and, as a consequence of their insensitivity toward moisture, are suitable as a packaging material for foods or other consumable items.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: February 28, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Oliver Klein, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6998179
    Abstract: A process for preparing a polarizer is described whereby an article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a photoacid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: February 14, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Duane D. Fansler, Todd D. Jones, Babu N. Gaddam, Robert T. Fitzsimons, Steven M. Heilmann, John J. Cael
  • Patent number: 6995213
    Abstract: Disclosed is a method of producing a novel biaxially oriented film having a high diffraction of light, and flexibility. In particular, the invention disclosed provides a method for making an opaque impact copolymer film by stretching in two dimensions an impact polypropylene copolymer. The invention is disclosed to be useful for making a material particularly suitable for a variety of applications including labeling media, food packaging and laminates. Also disclosed is a multilayer film having a first impact polypropylene copolymer layer and a second layer of another polymer wherein the multilayer film has significantly reduced haze. Also disclosed is film produced with a filler that has increased porosity and flexibility.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: February 7, 2006
    Assignee: Fina Technology, Inc.
    Inventors: Mark B. Miller, Scott Cooper, Juan Jose Aguirre, Mark Leland
  • Patent number: 6994915
    Abstract: Biaxially oriented polypropylene films (BOPP) having at least one layer of a propylene polymer containing at least 0.8% by weight of ethylene and, optionally, one or more C4-C10 ?-olefins, or a propylene polymer composition containing at least 0.8% by weight of one or more comonomers selected from the group consisting of ethylene and C4-C10 ?-olefins, and having I) a melting temperature of 155° C. or higher; and II) a xylene soluble fraction at room temperature lower than 3% by weight, and a value of the ratio of the polymer fraction collected at the temperature range from 25° C. to 95° C. (by TREF) to the said xylene soluble fraction higher than 8.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: February 7, 2006
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Anteo Pelliconi, Angelo Lonardo, Gabriele Mei
  • Patent number: 6991837
    Abstract: Biaxially oriented polyester films which have a polyester-containing base layer (B) which additionally comprises poly(m-xyleneadipamide) and which is coated on at least one side with a barrier layer (D), the barrier layer comprising polyvinyl alcohol and a copolymer of maleic acid and acrylic acid, feature improved optical properties such as high gloss and low opacity, and very good barrier properties, in particular with respect to oxygen passage, and are also suitable as packaging materials for foods or other consumable items as a consequence of their insensitivity toward moisture.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: January 31, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Oliver Klein, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6984437
    Abstract: Three-layer, highly oriented polyester films having an A-B-C layer construction, preferably made of polyethylene terephthalate, which, in addition to a base layer B, have a smooth surface layer A which contains no external particles and a rough surface layer C which contains external particles such as antiblocking agents or pigments, preferably SiO2, in defined amounts and particle sizes, feature in particular good producibility and processibility, high gloss of the film surface A and low opacity. The very smooth surface A is suitable in particular for coating with materials, for example SiOx, by means of plasma polymerization of hexamethyldisiloxane by the CVD or PECVD method, which provides the film with a high oxygen barrier and is suitable in particular as packaging for light- and air-sensitive foods or other consumable items.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: January 10, 2006
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Bart Janssens, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6979495
    Abstract: The present invention is directed to a biaxially oriented multi-layer film which comprises: (a) a core layer comprising a syndiotactic propylene homopolymer; and (b) at least one additional layer adjacent to the core layer comprising a polymer which is an ethylene or a propylene homopolymer, ethylene copolymer or terpolymer containing comonomers of propylene and/or butene-1. Optionally, there can be a skin layer applied to the exposed surface of the outer layer. The skin layer and/or the at least one additional layer is a polyolefin selected from the group consisting of isotactic polypropylene, polyethylene, ethylene-propylene random copolymer, ethylene-propylene block copolymer or ethylene-propylene-butene-1 terpolymer.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: December 27, 2005
    Assignee: ExxonMobil Oil Corporation
    Inventors: Jay K. Keung, Robert G. Peet, Michael T. Heffelfinger
  • Patent number: 6974621
    Abstract: Three-layer, highly oriented polyester films having an A-B-C layer construction, preferably made of polyethylene terephthalate, which, in addition to a base layer B have a smooth surface layer A which contains no external particles and a rough surface layer C which contains external particles such as antiblocking agents or pigments, preferably SiO2, in defined amounts and particle sizes, and the surface layer A is additionally provided with an acrylate-containing layer D feature in particular good producibility and processibility, high gloss of the film surface A and low opacity. The very smooth surface A or D is suitable in particular for coating with materials, for example SiOx, by means of plasma polymerization of hexamethyldisiloxane by the CVD or PECVD method, which provides the film with a high oxygen barrier and is suitable in particular as packaging for light- and air-sensitive foods or other consumable items.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: December 13, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Bart Janssens, Herbert Peiffer, Gottfried Hilkert
  • Patent number: 6974620
    Abstract: A polyester film for use in a capacitor having high heat resistance, which consists of a biaxially oriented film containing a polyester (A) as a main component and a polyimide (B) and has a glass transition temperature of 105° C. to 145° C. and an elongation at break in the machine direction of 70% to 150%, offers a high glass transition temperature and excellent insulation volume resistance and insulation breakdown voltage at high ambient temperatures. This film can produce a metallized film for use in a capacitor having high heat resistance and also a film capacitor having high heat resistance.
    Type: Grant
    Filed: February 14, 2000
    Date of Patent: December 13, 2005
    Assignee: Toray Industries, Inc.
    Inventors: Tetsuya Tsunekawa, Masayoshi Asakura, Tetsuya Yamagata
  • Patent number: 6962740
    Abstract: Three-layer, highly oriented polyester films having an A-B-C layer construction, preferably made of polyethylene terephthalate, which, in addition to a base layer B have a smooth surface layer A which contains no external particles and a rough surface layer C which contains external particles such as antiblocking agents or pigments, preferably SiO2, in defined amounts and particle sizes, and the surface layer C is additionally provided with an acrylate-containing layer D feature in particular good producibility and processibility, high gloss of the film surface A and low opacity. The very smooth surface A is suitable in particular for coating with materials, for example SiOx, by means of plasma polymerization of hexamethyldisiloxane by the CVD or PECVD method, which provides the film with a high oxygen barrier and is suitable in particular as packaging for light- and air-sensitive foods or other consumable items.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: November 8, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Bart Janssens, Herbert Peiffer, Stefan Bartsch
  • Patent number: 6956088
    Abstract: Metallocene catalyzed polyethylenes are found to have improved physical properties, improved processability and improved balance of properties. Surprisingly, there is a direct relationship between MD shrinkage, and MD tear. Additionally, MD tear is greater than TD tear, and MD tear is also greater than intrinsic tear. MD tear to TD tear ratios are above 0.9, and dart drop impact is above 500 g/mil. The polyethylenes have a relatively broad composition distribution and relatively broad molecular weight distribution.
    Type: Grant
    Filed: July 19, 2002
    Date of Patent: October 18, 2005
    Assignee: Univation Technologies, LLC
    Inventors: James McLeod Farley, John F. Szul, Matthew Gary McKee
  • Patent number: 6953617
    Abstract: A polyolefin blend having in a range of 40 to less than 90% by weight of a high modulus, isotactic polypropylene; and in a range of 10 to 60% by weight of a 1-butene/ethylene copolymer; the 1-butene/ethylene copolymer having about 0.5 to about 10 wt % of an ethylene. A polyolefin blend can be in a form of a transparent, oriented film having a biaxially oriented layer with an oxygen transmission rate of at least about 200 cc/100 sq. in./day/atmosphere (3077 cc/sq. m./24h/atmosphere), a tensile modulus of at least about 160,000 psi (1.103 GPa) and a haze value of no greater than about 3% measured at a thickness of about 1 mil (25 ?m).
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: October 11, 2005
    Assignee: Applied Extrusion Technologies, Inc.
    Inventor: Mark DeMeuse
  • Patent number: 6951595
    Abstract: A method of forming a reinforced polymer film structure is disclosed that includes the steps of slitting a biaxially oriented polymer film web having a top face and a bottom face into a first portion and a second portion, identifying the first portion and the second portion, and placing the first portion atop the second portion, such that the bottom face of the first portion is adjacent the top face of the second portion. This structure provides an impact and tear resistant laminate. Also disclosed is a method of forming a polymer film structure by identifying a molecular orientation direction profile of two portions of biaxially oriented polymer film and layering the two portions such that a molecular orientation direction profile of one does not coincide with a molecular orientation direction profile of the other.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: October 4, 2005
    Assignee: Mitsubishi Polyester Film, LLC
    Inventors: Charles David Carlson, Jr., Russell Scott Foxhall
  • Patent number: 6946203
    Abstract: A biaxially oriented thermoplastic structure including a low density core layer formed from polypropylene, highly crystalline polypropylene or high density polyethylene, and outer layers formed from highly crystalline polypropylene or high density polyethylene. The thickness of the core layer is about 60 to about 95% of the overall thickness of the structure. The stiffness of the structure in the machine direction is in a range from about 0.015 to about 0.15 pound force-centimeters.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: September 20, 2005
    Assignee: Exxon Mobil Oil Corporation
    Inventors: Mark W. Lockhart, Jason Chaneske, Robert M. Sheppard
  • Patent number: 6946193
    Abstract: A biaxially oriented multilayer film usable to form adhesive labels to be attached to containers, such as bottles and cans. The film includes a core layer comprising polypropylene and a migratory slip agent and an outer slip layer on one side of the core layer. The slip layer includes primarily polypropylene, by weight, and a minor percent, by weight, of an additive, with the additive and the migratory amide being present in amounts to provide a COF on the surface of the slip layer of no greater than 0.45 and to provide an adhesion of the adhesive employed on the formed label for the slip layer of at least 50%.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: September 20, 2005
    Assignee: Applied Extrusion Technologies, Inc.
    Inventor: William John Waywood
  • Patent number: 6946192
    Abstract: The application discloses a transparent, biaxially oriented polyester film having a base layer at least 80% by weight of which is composed of a thermoplastic polyester, and having at least one outer layer, wherein the outer layer is composed of a polymer, or of a mixture of polymers, which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 40% by weight of ethylene terephthalate units and/or units from cycloaliphatic or aromatic diols and/or dicarboxylic acids, with the proviso that the Tg2 value of the polyester film is above the Tg2 value of the base layer but below the Tg2 value of the outer layer, and at least one film surface has a surface tension of from 35 to 65 mN/m and/or has been provided with a functional coating of thickness from 5 to 100 nm. The film has low atmospheric oxygen transmission. It is particularly suitable for packaging uses, specifically for packaging foods and other consumable items, and for laminating, metallizing and printing.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: September 20, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Herbert Peiffer, Cynthia Bennett, Guenther Crass, Gottfried Hilkert, Werner Roth
  • Patent number: 6946188
    Abstract: A multilayered polymer film includes a first set of optical layers and a second set of optical layers. The first set of optical layers is made from a polyester which is often birefringent. The polyesters of the first set of optical layers typically have a composition in which 70-100 mol % of the carboxylate subunits are first carboxylate subunits and 0-30 mol % are comonomer carboxylate subunits and 70 to 100 mol % of the glycol subunits are first glycol subunits and 0 to 30 mol % of the glycol subunits are comonomer glycol subunits, where at least 0.5 mol % of the combined carboxylate and glycol subunits are comonomer carboxylate or comonomer glycol subunits. The multilayered polymer film may be used to form, for example, a reflective polarizer or a mirror.
    Type: Grant
    Filed: October 1, 2003
    Date of Patent: September 20, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: Timothy J. Hebrink, William W. Merrill, Carl A. Stover
  • Patent number: 6939616
    Abstract: A film roll of a heat-shrinkable polyester film characterized in that the heat-shrinkable polyester film meets the following requirements (1) and (2). (1) When samples are cut off therefrom at an almost equal interval along the longitudinal direction, and immersed in hot water at 85° C. for 10 seconds, subsequently in water at 25° C. and withdrawn, heat-shrinkage percentages in the maximum shrinkage direction of all the samples are 20% or more. (2) When raw polymers used for production of the film above comprises of a major constitutional unit and one or more sub constitutional units different therefrom; and the content of the primary sub constitutional unit is determined, the content of the primary sub constitutional unit in each sample is more than 7 mole % in 100% of all constitutional units, and when an average of the contents of the primary sub constitutional unit is calculated, the contents thereof of all the samples fall within a range of ±2 mole % relative to the average.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: September 6, 2005
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Satoshi Hayakawa, Norimi Tabota, Yoshinori Takegawa, Katsuya Ito, Shigeru Komeda, Katsuhiko Nose
  • Patent number: 6936350
    Abstract: The present application relates to a white, biaxially oriented, flame-retardant, UV-resistant polyester film with at least one base layer which comprises, based on the weight of the base layer, from 2 to 60% by weight of a cycloolefin copolymer (COC), where the glass transition temperature of the COC is within the range from 70 to 270° C. The film also comprises from 0.01 to 5.0% by weight of a UV stabilizer as light stabilizer and also comprises from 0.5 to 30% by weight of flame retardant, based in each case on the weight of the layer comprising the UV stabilizer and/or comprising the flame retardant. The film of the invention is suitable for packing foods or other consumable items which are sensitive to light and/or to air, or for use in industry, e.g. in the production of hot-stamping foils or as a label film, or for image-recording papers, printed sheets or magnetic recording cards.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: August 30, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Herbert Peiffer, Gottfried Hilkert, Hans Mahl
  • Patent number: 6926945
    Abstract: There is provided an easily adhesive, biaxially oriented laminated polyester film for optical use which has excellent adhesion, transparency and easy slipperiness. The biaxially oriented laminated film has a coating layer formed on at least one surface of an aromatic polyester film, the coating layer containing either a polyester resin, an acrylic resin and wax or a polyester resin and an acrylic resin having an oxazoline group and an alkylene oxide chain.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: August 9, 2005
    Assignee: Teijin Dupont Films Japan Limited
    Inventors: Shinji Yano, Koji Kubo
  • Patent number: 6916548
    Abstract: The invention relates to biaxially orientated, co-extruded polyester films, which have at least one base layer that contains a thermoplastic polyester, preferably polyethylene terephthalate and approx. 2 to 60 wt.-% of a cycloolefin copolymer that is preferably composed of norbornene and ethylene units and which have at least one cover layer that is devoid of a COC and which optionally have additional cover or intermediate layers and can contain conventional additives such as stabilisers and anti-blocking agents. Said films are characterized in particular by a degree of whiteness>70%, an opacity>55% and a gloss, (at least on one side)>100 and are therefore suitable for numerous industrial applications. During the production of the films in accordance with the co-extrusion process, up to 70 wt.-% of reclaimed product can be used, without having a noticeable negative effect on the physical properties of the film.
    Type: Grant
    Filed: May 17, 2001
    Date of Patent: July 12, 2005
    Assignee: Mitsubishi Polyester Film GmbH
    Inventors: Ursula Murschall, Cynthia Bennett, Ulrich Kern, Herbert Peiffer