Electric Superconducting Patents (Class 428/930)
  • Patent number: 6027826
    Abstract: The invention provides methods to manufacture dense, complex c-axis oriented ceramic oxide layers with thickness greater than 2.5 microns (.mu.m) on a metallic substrate (composites) without the use of an interfacial barrier, buffer, or surface layer using a metalorganic deposition process and thermomechanical reaction treatments is disclosed. A porous amorphous metal oxide ceramic deposit is formed directly on the substrate by spray pyrolyzing a mixed metalorganic precursor solution onto the metallic substrate. The metallic substrate has been previously heated to temperatures greater than the boiling point of the organic solvent and are high enough to initiate in situ decomposition of the metalorganic precursor salts. The process does not apply the precursor solution to the substrate as a liquid coating that is pyrolyzed in subsequent processing steps.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: February 22, 2000
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Pierre L. deRochemont, Daniel E. Ryder, Michael J. Suscavage, Mikhail Klugerman
  • Patent number: 6021338
    Abstract: A radiation curable coating composition for superconducting wires including at least one (meth)acrylate terminated urethane oligomer, at least one adhesion promoter, at least one (meth)acrylate functionalized diluent and at least one free radical photoinitiator. The coating composition is able to withstand repeated thermal cycling from the ambient temperature to the critical temperature of the superconducting wire and, because the composition is radiation cured, the superconducting wire is not heated, thus avoiding degrading the superconducting wire.
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: February 1, 2000
    Assignee: DSM Desotech Inc.
    Inventors: Edward P. Zahora, Steven C. Lapin, David M. Szum, Steven R. Schmid
  • Patent number: 6002951
    Abstract: A multilayer ceramic substrate electronic component is provided having high temperature superconductor material circuitry. The high temperature superconductor material is preferably yttrium-barium-copper-oxide and is encased within a noble metal such as silver or gold when forming the surface circuitry or filling of the vias. The noble metal layers preferably have through-openings to enable direct connection of circuitry to the encased superconductor layer. A method is also provided for fabricating such multilayer ceramic substrate electronic components.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: December 14, 1999
    Assignee: International Business Machines Corporation
    Inventors: David B. Goland, Richard A. Shelleman, Subhash L. Shinde, Lisa M. Studzinski, Rao V. Vallabhaneni
  • Patent number: 5999833
    Abstract: A method for the production of a superconducting oxide tape having a Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.10 (Bi-2223) structure interposed between silver sheets, which method consists essentially of preparing a sandwich structure having interposed between silver sheets a molded layer of a superconducting oxide precursor powder consisting essentially of Bi, Pb, Sr, Ca, Cu, and O obtained from a raw material substance composed of, in atomic composition ratio, 1.00 of Bi, 0-0.2 of Pb, 0.9-1.1 of Sr, 0.9-1.1 of Ca and 1.3-1.7 of Cu, and O, heating the sandwich structure in an atmosphere consisting of oxygen and an inert gas, having an oxygen partial pressure in the range of 0-5%, and kept at a temperature in the range of 830-850.degree. C., thereby melting the molded layer, then causing the atmosphere to retain the heating temperature and meanwhile increasing the oxygen partial pressure, thereby inducing precipitation of crystal grains possessing a Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: December 7, 1999
    Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Ryoji Funahashi, Ichiro Matsubara, Kazuo Ueno, Hiroshi Ishikawa
  • Patent number: 5998050
    Abstract: A composite material is disclosed which includes a substrate, an oriented film provided on a surface of the substrate and formed of a crystal of a Y123 metal oxide of the formula LnBa.sub.2 Cu.sub.3 O.sub.y wherein Ln stands for Y or an element belonging to the lanthanoid and y is a number of 6-7, and a layer of a Y123 metal oxide of the formula LnBa.sub.2 Cu.sub.3 O.sub.y wherein Ln stands for Y or an element belonging to the lanthanoid and y is a number of 6-7 formed on the oriented film.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: December 7, 1999
    Assignees: International Superconductivity Technology Center, Hitachi Cable Ltd., Hokkaido Electric Power Co., Inc., Kyushu Electric Power Co., Inc., The Kansai Electric Power Co., Inc.,, Fujikura, Ltd.
    Inventors: Yasuji Yamada, Masaru Nakamura, Noriyuki Tatsumi, Jiro Tsujino, Kanshi Ohtsu, Yasuo Kanamori, Minoru Tagami, Atsushi Kume, Yuh Shiohara, Shoji Tanaka
  • Patent number: 5998336
    Abstract: A composite superconducting material made of coated particles of ceramic superconducting material and a metal matrix material. The metal matrix material fills the regions between the coated particles. The coating material is a material that is chemically nonreactive with the ceramic. Preferably, it is silver. The coating serves to chemically insulate the ceramic from the metal matrix material. The metal matrix material is a metal that is susceptible to the superconducting proximity effect. Preferably, it is a NbTi alloy. The metal matrix material is induced to become superconducting by the superconducting proximity effect when the temperature of the material goes below the critical temperature of the ceramic. The material has the improved mechanical properties of the metal matrix material. Preferably, the material consists of approximately 10% NbTi, 90% coated ceramic particles (by volume). Certain aspects of the material and method will depend upon the particular ceramic superconductor employed.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: December 7, 1999
    Assignee: The Board of Trustees of the Leland Stanford Junior University
    Inventor: Matthew J. Holcomb
  • Patent number: 5998337
    Abstract: Excellent films of a high Tc superconductor are easily produced on metal coated substrates at a temperature below 700.degree. C. These metal buffer films are made of Pt, Au, Ag, Pd, Ni or Ti. The film superconductivity is significantly improved by the metal buffer layer. Since it is easy to form this metal coating on a substrate, the invention can increase the potential number of usable substrates such as fibers, amorphous solids or semiconductors.
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: December 7, 1999
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Shinichiro Hatta, Hidetaka Higashino, Kumiko Hirochi, Hideaki Adachi
  • Patent number: 5994276
    Abstract: A composite high Tc superconductor film is applied to a substrate, said film as applied having a thickness of at least 5000 Angstrom and an outer surface having an average roughness not exceeding 250 Angstrom.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: November 30, 1999
    Assignee: McMaster University
    Inventors: Robert A. Hughes, Patrick J. Turner, John S Preston
  • Patent number: 5991647
    Abstract: A high temperature superconductor lead assembly for reducing the heat leak into a cryocooled system features a shroud configured for at least partial submersion in a cryogenic fluid contained within a bath chamber, and a high temperature superconductor lead element at least partially contained within the shroud. In use, a portion of the high temperature superconductor lead element contained within the shroud extends below a fluid level of the cryogenic fluid in the bath chamber. The portion of the high temperature superconductor lead element is thermally shielded by the shroud such that it is maintained at a temperature higher than the temperature of the cryogenic fluid. The shroud is a double-walled vacuum structure with a sealed end and an open end. In use, the open end is submerged in the cryogenic fluid.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: November 23, 1999
    Assignee: American Superconductor Corporation
    Inventors: William E. Brockenborough, Bruce Barton Gamble, Anthony J. Rodenbush, Ahmed Sidi-Yekhlef
  • Patent number: 5987340
    Abstract: A method and apparatus for temperature activated protection of electronic components from interfering electromagnetic radiation comprising the step of shielding of a component with a thin film of superconducting material characterized by a critical temperature of at least 93.degree.K, and exposing the film to a temperature below the critical temperature. To allow transmissions to and from the component, the shield is converted to a window by heating the film to a temperature above the critical temperature.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: November 16, 1999
    Assignee: The Boeing Company
    Inventors: Thomas S. Luhman, Michael Strasik, Darryl F. Garrigus
  • Patent number: 5987342
    Abstract: A superconducting ceramic includes a laminate and a superconducting ceramic tape joined to the laminate. The laminate and superconductor tape are joined such that the tape is under a compressive stress. The compressive stress is of a greater amount than the compressive stress which results from differences in thermal expansion of the tape and the laminate. The greater compressive stress can be achieved by putting the laminate under a greater tension than the superconducting ceramic tape during joining of the superconducting ceramic tape to the laminate.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: November 16, 1999
    Assignee: American Superconductor Corporation
    Inventors: John D. Scudiere, David M. Buczek, Gregory L. Snitchler, Paul J. Di Pietro
  • Patent number: 5974336
    Abstract: An oxide superconductor comprises a base material consisting of a single crystalline oxide, an oxide superconductor film consisting of a Y123 compound and formed on the single crystalline oxide base material, and a coating film consisting essentially of a Ba--Cu--O oxide and covering the surface of the oxide superconductor film, the coating film having a thermal expansion coefficient higher than that of the oxide superconductor film.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: October 26, 1999
    Assignees: Kabushiki Kaisha Toshiba, International Superconductivity Technology Center
    Inventors: Yasuji Yamada, Tamaki Masegi, Junichi Kawashima, Yusuke Niiori, Izumi Hirabayashi
  • Patent number: 5958599
    Abstract: A biaxially textured alloy article includes a rolled and annealed biaxially textured base metal substrate characterized by an x-ray diffraction phi scan peak of no more than 20.degree. FWHM; and a biaxially textured layer of an alloy or another material on a surface thereof. The article further includes at least one of an electromagnetic device or an electro-optical device epitaxially joined to the alloy.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: September 28, 1999
    Assignee: Lockheed Martin Energy Research Corporation
    Inventors: Amit Goyal, John D. Budai, Donald M. Kroeger, David P. Norton, Eliot D. Specht, David K. Christen
  • Patent number: 5935911
    Abstract: A starting material which is converted to a continuous body of an oxide superconductor by a heat treatment is filled in a tubular Ag sheath member. The diameter of the filled member is reduced by extrusion to form a wire. The wire is subjected to a heat treatment so that the starting material inside the sheath member is converted to a continuous body of an oxide superconductor. A superconducting wire constituted by the sheath member and the oxide superconductor filled inside the sheath member is obtained. A superconducting coil can be obtained by winding the superconducting wire.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: August 10, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yutaka Yamada, Satoru Murase, Hisashi Yoshino, Noburu Fukushima, Hiromi Niu, Shigeo Nakayama, Misao Koizumi
  • Patent number: 5922650
    Abstract: Microstrip/stripline transmission lines have a plurality of strips on a substrate where strips are separated by a gap. This arrangement results in a reduced maximum current density compared to previous transmission lines with the same power handling capability. The strips can have the same width or different widths. The gaps can have the same width or different widths. The transmission lines can be used in filters and resonators and can be made of high temperature superconductive materials.
    Type: Grant
    Filed: February 6, 1996
    Date of Patent: July 13, 1999
    Assignee: Com Dev Ltd.
    Inventor: Shen Ye
  • Patent number: 5916697
    Abstract: A material formed as a film comprised of monomolecular layers (2,3,4,5) stacked on a substrate (1), wherein said film includes at least one first set (R) of layers which form an electric charge reservoir, and a second set (S) of layers which form a conductive cell and which contain a number of conductive copper oxide layers (4), separated from each other by intermediate layers (5), the reservoir and the conductive cell being adjacent in the layer stack. There are at least four conductive copper oxide layers, and the intermediate layers have the chemical formula Ca.sub.1-x M.sub.x and are free of strontium, wherein x is a real number between 0 and 0.2, M is a component with an ionic radius close to that of the Ca.sup.2+ ion, and the intermediate layers may be complete or not.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: June 29, 1999
    Assignees: Michael Lagues, Jacques Lewiner, Ufinnova
    Inventor: Michel Lagues
  • Patent number: 5914297
    Abstract: An oxide superconductor composite having improved texture and durability. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: June 22, 1999
    Assignee: American Superconductor Corp
    Inventor: Eric R. Podtburg
  • Patent number: 5912211
    Abstract: A superconducting ceramic film is deposited on a substrate sputtering. In virtue of the low thermal conductivity of ceramic, a laser beam is radiated to the ceramic film in order to remove the irradiated portion by sublimation and produce a pattern on the ceramic film.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: June 15, 1999
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventor: Shunpei Yamazaki
  • Patent number: 5908812
    Abstract: A superconducting oxide composite structure including a superconducting oxide member, a metal layer surrounding the superconducting oxide member, and an insulating layer of a complex oxide formed in situ adjacent to the superconducting oxide member and the metal layer is provided together with a method of forming such a superconducting oxide composite structure including encapsulating a superconducting oxide member or precursor within a metal matrix layer from the group of: (i) a reactive metal sheath adjacent to the superconducting oxide member or precursor, the reactive metal sheath surrounded by a second metal layer or (ii) an alloy containing a reactive metal; to form an intermediate product, and, heating the intermediate product at temperatures and for time sufficient to form an insulating layer of a complex oxide in situ, the insulating layer to the superconducting oxide member or precursor and the metal matrix layer.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: June 1, 1999
    Assignee: The Regents of the University of California
    Inventors: James D. Cotton, Gilbert Neal Riley, Jr.
  • Patent number: 5906965
    Abstract: A high temperature superconductor (HTS) tri-layer structure and a method for providing the same are described. Preferable two dimensional growth for all layers is provided resulting in smooth surfaces and highly crystalline layers. Full oxygenation of HTS under-layer(s) is provided despite having thick intervening dielectric mid-layer. HTS over- and under-layers are preferably structurally and electrically similar and have high crystallinity, the HTS layers have high T.sub.c (e.g. >90K) comparable to T.sub.c of single layer superconductor layers and a high J.sub.c (e.g. >10.sup.6 A/cm.sup.2), the tri-layer properties do not significantly degrade as the thickness of the layers is increased, and the dielectric mid-layer has high resistivity and is substantially pin-hole free.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: May 25, 1999
    Assignee: Superconductor Technologies, Inc.
    Inventor: Muralidhar R. Rao
  • Patent number: 5906963
    Abstract: A lanthanum aluminate (LaAlO.sub.3) substrate on which thin films of layered perovskite copper oxide superconductors are formed. Lanthanum aluminate, with a pseudo-cubic perovskite crystal structure, has a crystal structure and lattice constant that closely match the crystal structures and lattice constants of the layered perovskite superconductors. Therefore, it promotes epitaxial film growth of the superconductors, with the crystals being oriented in the proper direction for good superconductive electrical properties, such as a high critical current density. In addition, LaAlO.sub.3 has good high frequency properties, such as a low loss tangent and low dielectric constant at superconductive temperatures. Finally, lanthanum aluminate does not significantly interact with the superconductors. Lanthanum aluminate can also used to form thin insulating films between the superconductor layers, which allows for the fabrication of a wide variety of superconductor circuit elements.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: May 25, 1999
    Assignee: TRW Inc.
    Inventors: Randy Wayne Simon, Christine Elizabeth Platt, Alfred Euinam Lee, Gregory Steven Lee
  • Patent number: 5898020
    Abstract: A biaxially textured article includes a rolled and annealed, biaxially textured substrate of a metal having a face-centered cubic, body-centered cubic, or hexagonal close-packed crystalline structure; and an epitaxial superconductor or other device epitaxially deposited thereon.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: April 27, 1999
    Inventors: Amit Goyal, John D. Budai, Donald M. Kroeger, David P. Norton, Eliot D. Specht, David K. Christen
  • Patent number: 5897945
    Abstract: Metal oxide nanorods and composite materials containing such nanorods. The metal oxide nanorods have diameters between 1 and 200 nm and aspect ratios between 5 and 2000.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: April 27, 1999
    Assignee: President and Fellows of Harvard College
    Inventors: Charles M. Lieber, Peidong Yang
  • Patent number: 5891585
    Abstract: An Nb.sub.3 Al multi-filamentary superconducting wire capable of realizing both stabilization of a superconducting state and increase in capacity is provided. The Nb.sub.3 Al multi-filamentary superconducting wire includes a core formed of copper or copper alloy and located at the center of the wire; a multi-filamentary superconductor layer located around the core and having filaments containing Nb and Al as constituent elements embedded in a matrix formed of copper or copper alloy; and a high resistance layer located around the multi-filamentary superconductor layer, and is characterized in that a sectional area of the core is at least 15% of the total sectional area of the core and the matrix and that the core and the matrix are formed of copper or copper alloy of at least 99.9% purity.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: April 6, 1999
    Assignees: Sumitomo Elkectric Industries, Ltd., Japan Atomic Energy Research Institute
    Inventors: Naoki Ayai, Yuichi Yamada, Akira Mikumo, Kenichi Takahashi, Norikiyo Koizumi, Toshinari Ando, Makoto Sugimoto, Hiroshi Tsuji
  • Patent number: 5883051
    Abstract: A superconducting Josephson junction element including a first, a-axis oriented, superconductive metal oxide crystal grain having a first area of a {001} plane, and a second, c-axis oriented, superconductive metal oxide crystal grain having a second area of a {110} plane, wherein the first and second crystal grains are in contact with each other at the first and second areas to form a grain boundary therebetween.
    Type: Grant
    Filed: October 22, 1996
    Date of Patent: March 16, 1999
    Assignee: International Superconductivity Technology Center
    Inventors: Yoshihiro Ishimaru, Jian-Guo Wen, Kunihiko Hayashi, Youichi Enomoto, Naoki Koshizuka, Shoji Tanaka
  • Patent number: 5883050
    Abstract: A Hg-based superconducting cuprate film on a substrate is disclosed, which comprises a compound having the formula Hg.sub.1-x M.sub.x Ba.sub.2 Ca.sub.n-1 Cu.sub.n O.sub.y, M is a metal cation, x ranges from 0 to 1, n is an integer greater than 0, and y is an oxygen sufficiency factor having a value less than about 10.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: March 16, 1999
    Assignee: The University of Kansas
    Inventors: Sang-Ho Yun, Judy Z. Wu
  • Patent number: 5877124
    Abstract: A superconducting oxide ceramic pattern is described. The pattern is comprised of a high Tc superconducting region and a low Tc superconducting region which exhibits a resistivity at the liquid nitrogen temperature while the high Tc region is superconducitive at that temperature. The low Tc region is doped with impurity such as Si and then subjected to thermal treatment to oxidizing the impurity.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: March 2, 1999
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventor: Shumpei Yamazaki
  • Patent number: 5872080
    Abstract: A superconducting article including a flexible polycrystalline metal substrate, a layer of an adhesion layer material upon the surface of the flexible polycrystalline metal substrate, a layer of a cubic oxide material upon the adhesion layer material, the first layer of cubic oxide material deposited by ion beam assisted deposition, a layer of a buffer material upon the ion beam assisted deposited cubic oxide material layer, and, a layer of YBCO upon the buffer material layer is provided and has demonstrated J.sub.c 's of 1.3.times.10.sup.6 A/cm.sup.2, and I.sub.c 's of 120 Amperes across a sample 1 cm wide.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: February 16, 1999
    Assignee: The Regents of the University of California
    Inventors: Paul N. Arendt, Xin Di Wu, Steve R. Foltyn
  • Patent number: 5869430
    Abstract: According to an aspect, a tape-type high temperature superconducting wire is provided by applying compression work to a wire manufactured by drawing so that an oxide high temperature superconductor is divided into a plurality of superconductors by a stabilizing material of substantially equal thickness. According to another aspect, a high temperature superconducting wire is provided by packing a material which becomes a superconductor portion into a metal sheath which becomes the stabilizing material and applying drawing work thereto, followed by bundling an assembly of these wire in a metal sheath and applying drawing work thereto. The thickness of the superconductor portion is approximately 10% or less than the thickness of the wire. The critical current density is hardly decreased in the high temperature superconducting wire even if subjected to bending work.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 9, 1999
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hidehito Mukai, Kenichi Sato, Nobuhiro Shibuta
  • Patent number: 5866515
    Abstract: A superconducting conductor fabricated from a plurality of wires, e.g., fine silver wires, coated with a superconducting powder. A process of applying superconducting powders to such wires, to the resulting coated wires and superconductors produced therefrom.
    Type: Grant
    Filed: July 19, 1995
    Date of Patent: February 2, 1999
    Assignee: BASF Corporation
    Inventors: Stephen E. Dorris, Dominick A. Burlone, Carol W. Morgan
  • Patent number: 5866252
    Abstract: This invention permits superconducting ceramics, as well as other ceramic materials, to be spray deposited onto indefinitely large sheets of metallic substrate from a carboxylic acid salt solution. Elemental metal precursors of the superconductor are introduced into the solution as carboxylic acid salts. The deposit formed on the malleable metallic substrate is then thermomechanically calcined to form c-axis textured metal-superconductor composite sheet structures. These composite sheet structures can be formed by pressing together two ceramic-substrate structures, ceramic face-to-face, to form a metal-ceramic-metal sheet structure, or by overlaying a metal sheet over the deposited structure. Once the structure has been thermomechanically calcined, the c-axis of the superconductor is oriented parallel to the vector defining the plane of the metal sheet, i.e., perpendicular to the surface of the plane.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: February 2, 1999
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: L. Pierre de Rochemont, Michael J. Suscavage, Daniel F. Ryder, Jr., Mikhail Klugerman
  • Patent number: 5863869
    Abstract: Superconducting transition metal oxide films are provided which exhibit very high onsets of superconductivity and superconductivity at temperatures in excess of 40.degree. K. These films are produced by vapor deposition processes using pure metal sources for the metals in the superconducting compositions, where the metals include multi-valent nonmagnetic transition metals, rare earth elements and/or rare earth-like elements and alkaline earth elements. The substrate is exposed to oxygen during vapor deposition, and, after formation of the film, there is at least one annealing step in an oxygen ambient and slow cooling over several hours to room temperature. The substrates chosen are not critical as long as they are not adversely reactive with the superconducting oxide film. Transition metals include Cu, Ni, Ti and V, while the rare earth-like elements include Y, Sc and La. The alkaline earth elements include Ca, Ba and Sr.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 26, 1999
    Assignee: International Business Machines Corporation
    Inventors: Praveen Chaudhari, Richard Joseph Gambino, Roger Hilson Koch, James Andrew Lacey, Robert Benjamin Laibowitz, Joseph Michael Viggiano
  • Patent number: 5861361
    Abstract: A FET type superconducting device comprises a thin superconducting channel, a superconducting source region and a superconducting drain region formed of an oxide superconductor over a principal surface of the substrate, and a gate electrode on a gate insulator disposed on the superconducting channel for controlling the superconducting current flowing through the superconducting channel by a signal voltage applied to the gate electrode. The superconducting channel is formed of(Pr.sub.w Y.sub.1-w)Ba.sub.2 Cu.sub.3 O.sub.7-z (0<w<1, 0<z<1) oxide superconductororY.sub.1 Ba.sub.2 Cu.sub.3-v CO.sub.V O.sub.7-u (0<v<3, 0<u<1) oxide superconductor.These oxide superconductors have smaller carrier densities than the conventional oxide superconductor so that the superconducting channel has a larger thickness than the one funned of the conventional oxide superconductor.
    Type: Grant
    Filed: April 17, 1996
    Date of Patent: January 19, 1999
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takao Nakamura, Michitomo Iiyama
  • Patent number: 5855988
    Abstract: An electromagnetic wave absorbing shielding material which is thin and lightweight and shows high electromagnetic wave absorbing capacity in a wide frequency region. The material comprises:(1) a one-dimensional conductive segment pattern which is a conductive segment pattern formed from a conductive material, wherein the conductive segment pattern has a length of more than 1/2 of the wavelength of the subjective electromagnetic wave, and the segment pattern has no electrical connection therebetween,(2) an electromagnetic wave shielding layer, and(3) an insulating intermediate material having a thickness of 0.1-10.0 mm, located between the one-dimensional conductive segment pattern (1) and the electromagnetic wave shielding layer (2).
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: January 5, 1999
    Assignee: Nippon Paint Co., Ltd.
    Inventor: Seiichi Matsuo
  • Patent number: 5856276
    Abstract: A novel ceramic substrate useful for the preparation of superconducting films, said substrate having the formula REBa.sub.2 MO.sub.6 where RE represents rare earth metals--Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and M represents metals Nb, Sb, Sn, Hf, Zr; and a process for the preparation of superconducting YBa.sub.2 Cu.sub.3 O.sub.7-.delta. thick films on new ceramic substrate.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: January 5, 1999
    Assignee: Council of Scientific & Industrial Research
    Inventors: Jacob Koshy, Jijimon Kumpukkattu Thomas, Jose Kurian, Yogendra Prasad Yadava, Alathoor Damodaran Damodaran
  • Patent number: 5849669
    Abstract: A high critical temperature superconducting Josephson device includes a bicrystal substrate formed of a first single crystal substrate and a second single crystal substrate, with end faces of the first and second single crystal substrates having different crystal orientations and being joined to each other. A first superconducting electrode formed of a first film of a high critical temperature superconductor material is located on the first single crystal substrate, whereas a second superconducting electrode formed of a second film of a high critical temperature superconductor material is located on the second single crystal substrate. A bridge is formed of a third film of a high critical temperature superconductor material and located on the bicrystal substrate across a joint between said first and said second single crystal substrates.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: December 15, 1998
    Assignee: Oki Electric Industry Co., Ltd.
    Inventor: Zhongmin Wen
  • Patent number: 5849670
    Abstract: In order to provide a crystal oriented high quality thallium group superconducting wire having a high critical current density, thallium group superconducting film is formed on oxide single crystal fiber having plane facets and polygonal cross section in the thallium group superconducting wire, wherein c-axis of the thallium group superconducting film is oriented perpendicularly, and a- and b-axis are oriented in parallel to the longitudinal direction of the above fiber, respectively, and resulting to obtain a high quality thallium group superconducting wire with Jc of 10.sup.5 A/cm.sup.2 or more at 77K.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: December 15, 1998
    Assignees: Hitachi, Ltd., International Superconductivity Technology Center
    Inventors: Toshihide Nabatame, Junichi Kawashima, Izumi Hirabayashi, Yuh Shiobara, Shoji Tanaka
  • Patent number: 5846909
    Abstract: Use of monolayer films for the direct modification of high-T.sub.c superconductor structures and devices. Methods for the formation of superconductor localized monolayer films have been discovered based on the spontaneous adsorption of molecules containing ligating functionalities, such as alkylamine, arylamine, and alkylthiol moieties. Molecules containing these types of functionalities are found to bind tenaciously to the metal ions which form the high-T.sub.c superconductor surface. The derivatized superconductor structures can be prepared simply by soaking the high-T.sub.c, superconductor structure or device in a dry organic solvent system which contains the derivatizing agent. Large changes in the superconductor interfacial properties can be achieved with such procedures allowing for the atomic level control of the surface properties of the superconductor.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: December 8, 1998
    Assignees: University of Texas System, Northwestern University
    Inventors: John T. McDevitt, Chad A. Mirkin
  • Patent number: 5843584
    Abstract: A superconductive article is made from interconnected superconductive, metallic tapes. The tapes are mechanically joined, and electrically interconnected by a plurality of superconductive interconnections that extend between the tapes. Articles of the invention may be formed from tapes comprising superconductive Nb.sub.3 Sn having Nb.sub.3 Sn interconnections.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: December 1, 1998
    Assignee: General Electric Company
    Inventor: Thomas Robert Raber
  • Patent number: 5834405
    Abstract: A superconducting multilayer ceramic substrate is disclosed, prepared by firing a laminate of at least two polymer bonded cast sheets of a ceramic dielectric oxide powder, at least one sheet of which has a metallization pattern provided thereon, to thereby form a superconducting oxide reaction layer at the interface between the sintered ceramic material and the embedded metallic conductor lines of the metallization pattern.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: November 10, 1998
    Assignee: International Business Machines Corporation
    Inventors: Byung Tae Ahn, Robert Bruce Beyers, Emanuel Israel Cooper, Edward August Giess, Eugene John O'Sullivan, Judith Marie Roldan, Lubomyr Taras Romankiw
  • Patent number: 5821199
    Abstract: A process and structure wherein a film comprised of a perovskite or a spinel is built epitaxially upon a surface, such as an alkaline earth oxide surface, involves the epitaxial build up of alternating constituent metal oxide planes of the perovskite or spinel. The first layer of metal oxide built upon the surface includes a metal element which provides a small cation in the crystalline structure of the perovskite or spinel, and the second layer of metal oxide built upon the surface includes a metal element which provides a large cation in the crystalline structure of the perovskite or spinel. The layering sequence involved in the film build up reduces problems which would otherwise result from the interfacial electrostatics at the first atomic layers, and these oxides can be stabilized as commensurate thin films at a unit cell thickness or grown with high crystal quality to thicknesses of 0.5-0.7 .mu.m for optical device applications.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: October 13, 1998
    Assignee: Lockheed Martin Energy Systems, Inc.
    Inventors: Rodney Allen McKee, Frederick Joseph Walker
  • Patent number: 5814584
    Abstract: Compounds of the general formula A.sub.2 MeSbO.sub.6 wherein A is either barium (Ba) or strontium (Sr) and Me is a non-magnetic ion selected from the group consisting of scandium (Sc), indium (In) and gallium (Ga) have been prepared and included in high critical temperature thin film superconductor structures.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: September 29, 1998
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Arthur Tauber, William D. Wilber, Steven C. Tidrow, Robert D. Finnegan, Donald W. Eckart
  • Patent number: 5814583
    Abstract: A high-temperature superconducting thin film of compound oxide selected from the group consisting of:Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Ho.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Lu.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,Sm.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Nd.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Gd.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,Eu.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Er.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Dy.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,Tm.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, Yb.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x, La.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x,(La, Sr).sub.2 CuO.sub.4-x,which is deposited on a substrate of MgO or SrTiO.sub.3, with the outer surface of the high-temperature superconducting thin film being covered with a protective crystalline film of SrTiO.sub.3.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: September 29, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hideo Itozaki, Saburo Tanaka, Nobuhiko Fujita, Shuji Yazu, Tetsuji Jodai
  • Patent number: 5801124
    Abstract: The invention provides a superconducting ceramic laminate including a superconducting tape mechanically coupled to, and compressively strained to 0.1% or more under a predetermined load by, at least one cladding tape. The material and thickness of the cladding tape or tapes are selected relative to the material and thickness of the superconducting tape to locate the neutral axis so that, under a predetermined heavy load, the maximum compressive strain on any superconducting portion of the superconducting tape is less than the critical compressive strain and the maximum tensile strain on any superconducting portion of the superconducting tape under a predetermined load is less than the critical tensile strain. By "heavy load" is meant a load on the laminate equivalent to a load on the unlaminated superconducting tape selected for the laminate including a surface bend strain on the unlaminated superconducting tape of at least 0.1%.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: September 1, 1998
    Assignee: American Superconductor Corporation
    Inventors: Bruce B. Gamble, Gilbert N. Riley, Jr., John D. Scudiere, Michael D. Manlief, David M. Buczek, Gregory L. Snitchler
  • Patent number: 5798312
    Abstract: An elongate superconductor wiring element having, as seen in section, oxide superconductor material regions in each of which the c-axes of the oxide superconductor crystals are aligned with each other and are transverse to the longitudinal axis of the element. To reduce the dependence of critical current density on angular position of the element relative to a magnetic field, there are a plurality of said regions whose alignment directions of the c-axes are different as between different ones of said regions, so that the wiring element comprises a plurality of said regions having respectively different c-axis alignment directions.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: August 25, 1998
    Assignee: Hitachi, Ltd.
    Inventors: Michiya Okada, Kazuhide Tanaka, Toyotaka Yuasa, Toshimi Matsumoto, Katsuzo Aihara, Shinpei Matsuda
  • Patent number: 5795848
    Abstract: Superconductivity is inhibited in selected portions of a high temperature superconductor ("HTS") material by patterning the selected portions with a resist. The patterned material is ion-bombarded to implant impurity ions in non-resist-bearing portions of the material. After low temperature annealing, the non-resist-bearing portions of the material lose their superconducting characteristics, but such characteristics are preserved in the material's resist-bearing portions. The material's crystalline structure is preserved, so additional layers can be epitaxially grown atop the inhibited material. Superconductivity is inhibited at a selected depth in a HTS material by subjecting the material to impurity ion bombardment at an energy level controlled to implant ions in the material at the selected depth. After low temperature annealing, the material loses its superconducting characteristics at the selected depth, but such characteristics are preserved at other depths (i.e.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: August 18, 1998
    Assignee: The University of British Columbia
    Inventor: Qi Yuan Ma
  • Patent number: 5786304
    Abstract: A joining product of oxide superconducting materials having a high current density and process for producing the same. A joining product comprising a plurality of oxide superconducting materials having an identical crystal orientation joined with each other through a superconducting phase of the same type as described above which has the same crystal orientation as the oxide superconducting materials and a lower peritectic temperature than the oxide superconducting materials.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: July 28, 1998
    Assignee: Nippon Steel Corporation
    Inventors: Keiichi Kimura, Katuyoshi Miyamoto, Misao Hashimoto
  • Patent number: 5759960
    Abstract: A superconductive device (e.g., magnet) having a superconductive lead assembly and cooled by a cryocooler coldhead having first and second stages. A first ceramic superconductive lead has a first end thermally connected to the first stage and a second end thermally connected to the second stage. A jacket of open cell material (e.g., polystyrene foam) is in surrounding compressive contact with the first ceramic superconductive lead, and a rigid, nonporous support tube surrounds the jacket. This protects the first ceramic superconductive lead against shock and vibration while in the device. The rigid support tube has a first end and a second end, with the second end thermally connected to the second stage.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: June 2, 1998
    Assignee: General Electric Company
    Inventors: Robert Adolph Ackermann, Kenneth Gordon Herd, Evangelos Trifon Laskaris, Richard Andrew Ranze
  • Patent number: 5753380
    Abstract: The present invention concerns an aluminum alloy conductor of a cryostatic stabilizer for use at ultra low temperatures of 30.degree. K. or lower which is provided on and around a superconductor. The aluminum alloy conductor is made of 6 to 200 weight ppm of at least one element selected from the group of metallic and semimetallic effective elements consisting of B, Ca, Ce, Ga, Y, Yb and Th, and aluminum and inevitable impurities. The aluminum alloy conductor is obtained by adding at least one of these elements into a high purity aluminum whose purity is at least 99.98 wt. %. The aluminum alloy conductor has a 0.2% proof strength of not greater than 2.6 Kg/mm.sup.2.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: May 19, 1998
    Assignees: Sumitomo Chemical Co., Ltd., The Texas A&M University System
    Inventors: Akihiko Takahashi, Hitoshi Yasuda, Karl Theodore Hartwig, Lacy Clark McDonald
  • Patent number: 5747181
    Abstract: A superconductive article is made from interconnected superconductive, metallic tapes. The tapes preferably are mechanically joined and electrically interconnected by a plurality of superconductive interconnections that extend between the tapes. The interconnections are formed by overlapping the edges of two tapes and forming a plurality of superconductive welds between the tapes in the overlapping regions. Articles of this invention may be formed from superconductive tapes made from Nb.sub.3 Sn having superconductive interconnections that also include Nb.sub.3 Sn.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: May 5, 1998
    Assignee: General Electric Company
    Inventor: Thomas Robert Raber