Abstract: A liquid hydrophobic phase transition substance is provided that may improve the safety of a battery and restrain the deterioration in performance of the battery without deteriorating the properties of the battery. The liquid hydrophobic phase transition substance includes a hydrophobic salt having a melting point of 80° C. or more and a hydrophilic salt of an alkali or an alkaline earth.

Abstract: A non-aqueous electrolyte solution is provided that realizes a large capacity, exhibits high storage characteristics and cycle characteristics, and is capable of inhibiting gas generation. The non-aqueous electrolyte solution comprises a lithium salt and a non-aqueous solvent, and further comprises: a cyclic carbonate compound having an unsaturated bond in a concentration of 0.01 weight % or higher and 8 weight % or lower; and a compound expressed by general formula (Ia) in a concentration of 0.01 weight % or higher and 5 weight % or lower. (in the formula (Ia), R11 and R12 represent, independently of each other, an organic group that is composed of one or more carbon atoms and hydrogen atoms and may optionally contain one or more oxygen atoms but excludes unsaturated bonds, provided that at least either R11 or R12 has an ether linkage. The total number of carbon atoms of R11 and R12 is between 3 and 18, and the total number of oxygen atoms contained in R11 and R12 is between 1 and 6.

Abstract: Disclosed is an electrolyte for a rechargeable lithium battery that includes a lithium salt, a phosphine compound having at least one trialkylsilyl group and organic solvent, and a rechargeable lithium battery including the electrolyte. The phosphine compound may be tris(trialkylsilyl)phosphine wherein the alkyl groups are the same or different and are each independently selected from C1 to C6 alkyl.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution, wherein the electrolytic solution includes a cyano cyclic ester carbonate represented by Formula (1) described below, where each of R1 to R3 is one of a hydrogen group, a halogen group, a cyano group, a monovalent hydrocarbon group, a monovalent halogenated hydrocarbon group, a monovalent oxygen-containing hydrocarbon group, and a monovalent halogenated oxygen-containing hydrocarbon group; arbitrary two or more of the R1 to the R3 are allowed to be bonded to each other; and when the total number of cyano groups is 1, one or more of the R1 to the R3 each are a halogen group, a monovalent halogenated hydrocarbon group, or a monovalent halogenated oxygen-containing hydrocarbon group.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The electrolytic solution includes a cyano cyclic ester carbonate represented by Formula (1) described below and one or more of compounds represented by Formula (2) to Formula (6) described below.

Abstract: This invention relates to a nonaqueous-electrolyte battery containing a current collector, a positive electrode, a negative electrode, and a nonaqueous electrolytic solution. The positive electrode contains a lithium-containing phosphoric acid compound represented by LixMPO4 as a positive-electrode active material, where M is at least one element selected from Group-2 to Group-12 metals of the periodic table, and x satisfies 0<x?1.2. The negative electrode contains a negative-electrode active material capable of occluding and releasing lithium ions. The nonaqueous electrolytic solution contains a chain ether and a cyclic carbonate having an unsaturated bond.

Abstract: An object of the present invention is to provide an ambient temperature molten salt having excellent electron conductivity in addition to ion conductivity. The present invention attains the object by providing an ambient temperature molten salt including a first imidazolium salt having a cationic segment represented by the general formula (1) and an anionic segment represented by MX4 (where M is a transition metal and X is a halogen); and a second salt having a cationic segment as a monovalent cation and an anionic segment as a halogen.

Abstract: In a non-aqueous electrolyte secondary battery, a first active material of a positive electrode includes at least one of carbon-coated LiFePO4, LiMnPO4 and Li3V2(PO4)3. A second active material of the positive electrode includes lithium nickel composite oxide. An electrolytic solution includes fluorinated ethylene carbonate.

Abstract: Technologies are generally described for electrochemical cells and batteries containing electrochemical cells. An electrochemical cell may incorporate two types of conducting polymers each located at an electrode, a cation, a polycyclic aromatic hydrocarbon radical anion that contacts one of the conducting polymers, and an electrolyte. The polycyclic aromatic hydrocarbon radical anion may be a covalent substituent of one of the conducting polymers or may be in noncovalent contact with one of the conducting polymers. The polycyclic aromatic hydrocarbon radical anion may permit the use of cations other than lithium, e.g. an alkali metal cation such as sodium or alkali earth metal cation such as calcium. Such an electrochemical cell may provide alternative batteries to existing lithium ion batteries, permitting the use of cations that may be more abundant, more easily extracted, or more sustainable compared to known lithium supplies.

Abstract: A non-aqueous secondary battery contains a positive electrode, a negative electrode, a separator and a non-aqueous electrolytic solution. The positive electrode contains a layered structure lithium-containing compound oxide, or a spinel lithium-containing compound oxide containing manganese as an active material. The non-aqueous electrolytic solution contains at least one additive selected from a sulfonic acid anhydride, a sulfonate ester derivative, a cyclic sulfate derivative and a cyclic sulfonate ester derivative, and a vinylene carbonate or a derivative of the vinylene carbonate.

Abstract: The present invention provides a non-aqueous electrolyte solution which contains a silyl ester group-containing phosphonic acid derivative.

Abstract: The present invention provides a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range, an electrochemical element produced by using the same and a sulfonic ester compound having a branched structure which is used for the same. The present invention relates to a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises a sulfonic ester compound represented by the following Formula (I) in an amount of 0.

Abstract: Provided are a nonaqueous electrolyte battery having improved durability properties such as cycle and storage properties, and improved load characteristic, and a nonaqueous electrolyte solution that is appropriate for the nonaqueous electrolyte battery. The nonaqueous electrolyte solution contains a lithium salt and a nonaqueous solvent that dissolves the lithium salt. The nonaqueous electrolyte solution also contains a compound represented by formula (1) and a specific compound that acts in conjunction with the aforementioned compound.

Abstract: The present invention provides an electrolyte containing novel additive for electrochemical device and the electrochemical device thereof. The additive is a compound represented by below formula (I): wherein R1 and R2 are independently hydrogen, methyl, ethyl, or halogen; n and m are independently 1, 2, or 3. The additive of the present invention can protect the surface of the carbonaceous material on the anode and suppress the occurrence of exfoliation, thereby increasing the lifetime of the electrochemical device. Furthermore, the additive of the present invention also slows down the decay of capacity on the cathode during charging-discharging cycles, and hence maintains a better performance.

Abstract: A non-aqueous electrolyte is provided that includes a non-aqueous solvent and an electrolyte salt, wherein the non-aqueous solvent contains a fluorinated ether (1) represented by the following Formula: HCF2CF2CF2CH2—O—CF2CF2H (1). This non-aqueous electrolyte has good wettability to a polyolefin separator, can provide a battery with excellent load characteristics for a long period, does not easily decompose in the battery under high-temperature storage, and causes little gas generation due to decomposition. Furthermore, a non-aqueous electrolyte secondary battery is provided that includes a positive electrode, a negative electrode, a separator, and the above-described non-aqueous electrolyte.

Abstract: A polymer electrolyte includes a fluorine-containing structure having an alicyclic 1,3-disulfonimide in a principal chain or side chain of the polymer. A battery includes the polymer electrolyte. An imide monomer is able to introduce a fluorine-containing structure having an alicyclic 1,3-disulfonimide into a principal chain or side chain of a polymer through a polymerization reaction or a combination of a polymerization reaction and a fluorination reaction. A manufacturing method for a polymer electrolyte includes a polymerization step of polymerizing a raw material that includes one or two or more types of imide monomers that are able to introduce a fluorine-containing structure having an alicyclic 1,3-disulfonimide into a principal chain or side chain of a polymer through a polymerization reaction or a combination of a polymerization reaction and a fluorination reaction.

Abstract: Lithium salts with fluorinated chelated orthoborate anions are prepared and used as electrolytes or electrolyte additives in lithium-ion batteries. The lithium salts have two chelate rings formed by the coordination of two bidentate ligands to a single boron atom. In addition, each chelate ring has two oxygen atoms bonded to one boron atom, methylene groups bonded to the two oxygen atoms, and one or more fluorinated carbon atoms bonded to and forming a cyclic bridge between the methylene groups.

Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The electrolytic solution includes an unsaturated six-membered ring ester carbonate represented by Formula (1) described below, or an unsaturated six-membered ring ester carbonate represented by Formula (2) described below, or both, where each of W, X, and Y is one of >C?CR1R2 and >CR3R4; each of R1 to R4 is a hydrogen group or the like; arbitrary two or more of R1 to R4 are allowed to be bonded with each other; and one or more of W, X, and Y are >C?CR1R2, where Z is one of >C?CR7R8 and >CR9R10; each of R5 to R10 is a hydrogen group or the like; and arbitrary two or more of R5 to R10 are allowed to be bonded with each other.

Abstract: An electrolyte for a rechargeable lithium battery and rechargeable lithium battery including the same is provided. The electrolyte includes a film-forming compound; a lithium salt; and an organic solvent.

Abstract: The present invention relates to a sodium secondary battery comprising a first electrode comprising a carbonaceous material which can be doped and dedoped with a sodium ion, a second electrode, and a non-aqueous electrolytic solution in which an electrolyte salt is dissolved in a non-aqueous solvent, wherein the non-aqueous electrolytic solution comprises a cyclic carbonate containing an unsaturated bond, a cyclic carbonate containing fluorine, or both, in the range of 0.01% by volume or more and 10% by volume or less relative to the non-aqueous electrolytic solution.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The electrolytic solution includes an allene compound having a tetravalent skeleton represented by Formula (1) described below.

Abstract: A secondary battery capable of improving the cycle characteristics and the storage characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution contains a solvent contains a sulfone compound having a structure in which —S(?O)2—S—C(?O)— bond is introduced to a benzene skeleton and an ester carbonate halide.

Abstract: There are provided a nonaqueous-type electrolyte solution having high flame retardancy and a good capacity retention rate, and a device comprising the nonaqueous-type electrolyte solution. The nonaqueous-type electrolyte solution is used in a device comprising a positive electrode, a negative electrode and the nonaqueous-type electrolyte solution, and contains a lithium salt and a compound having a phosphazene structure, and further contains 0.05% by mass or more and 12.0% by mass or less of at least one disulfonate ester selected from a cyclic disulfonate ester and a chain disulfonate ester based on the total of the nonaqueous-type electrolyte solution.

Abstract: A nonaqueous electrolytic secondary battery includes: a positive electrode; a negative electrode; and an electrolyte that contains a nonaqueous electrolytic solution, wherein the nonaqueous electrolytic solution contains at least one phosphorus compound selected from the group consisting of phosphine oxide, phosphonic ester, and phosphinic ester, and the phosphine oxide, the phosphonic ester, and the phosphinic ester are phosphorus compounds represented by the following formulae (I), (II), and (III), respectively.

Abstract: A nonaqueous electrolyte secondary battery comprising positive and negative electrodes capable of absorbing and desorbing lithium ions; a nonaqueous electrolytic solution; and a separator provided between the positive electrode and the negative electrode. The negative electrode comprises a negative electrode active material layer containing at least a styrene polymer as a binder in a content of 0.3 to 8.0 mass % based on the total mass of the negative electrode active material layer. The nonaqueous electrolytic solution contains at least a cyclic sulfonic acid ester including at least two sulfonyl groups in a content of 0.002 to 5.0 mass % based on the total mass of the nonaqueous electrolytic solution.

Abstract: An electrolyte for the lithium secondary battery having flame retardancy, low negative electrode interfacial resistance, and excellent high temperature properties and life characteristics, and a lithium secondary battery including the same. An electrolyte for lithium secondary battery of the present invention may include a non-aqueous organic solvent, a lithium salt, fluorinated ether or phosphazene, and a resistance-improving additive represented as the following chemical formula (1): RSO2—R1—SO2F??[Chemical Formula 1] wherein R1 is a C1-C12 hydrocarbon unsubstituted or substituted with at least one fluorine.

Abstract: According to one embodiment, a nonaqueous electrolyte battery includes a nonaqueous electrolyte which is a liquid at 20° C. under a pressure of 1 atmosphere. The nonaqueous electrolyte contains a first compound having a functional group represented by Chemical formula (I), at least one compound selected from a compound having an isocyanato group and a compound having an amino group, a nonaqueous solvent, and an electrolyte.

Abstract: Provided is a nonaqueous electrolyte secondary battery which, even in the case of using a low-viscosity solvent having a narrow potential window, can increase the electrochemical stability of the nonaqueous electrolyte solution and suppress side reactions of the nonaqueous electrolyte solution during charge and discharge to reduce the degradation of the battery characteristics and has an excellent storage characteristic in high-temperature environments and a nonaqueous electrolyte solution for the nonaqueous electrolyte secondary battery.

Abstract: An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.

Abstract: Disclosed is an electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the same. The electrolyte includes a lithium salt, a trialkylsilyl cyanide compound represented by the following Chemical Formula 1, and an organic solvent. In the above Chemical Formula 1, R1 to R3 are the same or different, and selected from C1 to C6 alkyls.

Abstract: Lithium salts with fluorinated chelated orthoborate anions are prepared and used as electrolytes or electrolyte additives in lithium-ion batteries. The lithium salts have two chelate rings formed by the coordination of two bidentate ligands to a single boron atom. In addition, each chelate ring has two oxygen atoms bonded to one boron atom, methylene groups bonded to the two oxygen atoms, and one or more fluorinated carbon atoms bonded to and forming a cyclic bridge between the methylene groups.

Abstract: Described herein are materials for use in electrolytes that provide a number of desirable characteristics when implemented within batteries, such as high stability during battery cycling up to high temperatures high voltages, high discharge capacity, high coulombic efficiency, and excellent retention of discharge capacity and coulombic efficiency over several cycles of charging and discharging. In some embodiments, a high voltage electrolyte includes a base electrolyte and a set of additive compounds, which impart these desirable performance characteristics.

Abstract: A secondary battery includes a cathode, an anode, and an electrolyte. The anode includes an anode active material containing silicon, boron, carbon, and one or more of metal elements selected from the group consisting of cobalt, titanium and iron. In the anode active material, a boron content is from 4.9 mass % to 19.8 mass % both inclusive, a carbon content is from 4.9 mass % to 19.8 mass % both inclusive, a total of the boron content and the carbon content is from 9.8 mass % to 29.8 mass % both inclusive, a ratio of a silicon content to the total of the silicon content and a content of the metal element is from 70 mass % to 95 mass % both inclusive. A reaction phase whose half-width of a diffraction peak obtained by X-ray diffraction is 1 degree or more is included and the anode active material is capable of reacting with an electrode reactant.

Abstract: A nonaqueous electrolyte battery includes: an electrode group including a positive electrode and a negative electrode; and a nonaqueous electrolyte including an electrolytic solution, the electrode group including an insulating layer, the insulating layer containing a ceramic, the electrolytic solution including an electrolyte salt and an additive, the electrolyte salt including the compound of formula (1), and the additive being at least one of the compounds of formulae (2) to (14), and the compound of formula (1) being contained in 0.001 mol/L to 2.5 mol/L with respect to the electrolytic solution.

Abstract: A nonaqueous electrolyte includes: a nonaqueous electrolytic solution containing a nonaqueous solvent, an electrolyte salt, an overcharge controlling agent capable of generating a redox reaction at a prescribed potential, and at least one member selected from the compounds (1) to (10).

Abstract: An electrode and method for preparing the same in which droplets of a first electrode ink composition and droplets of a second electrode ink composition are ejected from an ink jet device onto a base material and the first electrode ink composition contains at least one electrode active material and the second electrode ink composition contains at least one binder material. The resulting electrode is suitable for use in a battery.

Abstract: Disclosed is a nonaqueous electrolytic solution which forms a nonaqueous-electrolyte battery having high capacity and excellent storage characteristics at high temperatures, while sufficiently enhancing safety at the time of overcharge, and a nonaqueous-electrolyte battery using the same. The nonaqueous electrolytic solution has an electrolyte and a nonaqueous solvent with (A) a compound of formula (2): wherein R7 is an optionally halogenated and/or phenylated alkyl group comprising 1-12 carbon atoms, R8 to R12 are independently a hydrogen atom, a halogen atom, an optionally halogenated ether or alkyl group comprising 1-12 carbon atoms, and at least one of R8 to R12 is an optionally halogenated alkyl group comprising 2-12 carbon atoms; and/or (B) a carboxylic acid ester with a phenyl group substituted by at least one alkyl group (having 4 or more carbon atoms) that is optionally substituted.

Abstract: An ionic liquid having high electrochemical stability and a low melting point. An ionic liquid represented by the following general formula (G0) is provided. In the general formula (G0), R0 to R5 are individually any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, a methoxyethyl group, and a hydrogen atom, and A? is a univalent imide-based anion, a univalent methide-based anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate, or hexafluorophosphate.

Abstract: The exemplary embodiment has an object to provide a nonaqueous electrolyte solution having a flame retardancy over a long period and having a good capacity maintenance rate. The exemplary embodiment is a nonaqueous electrolyte solution containing a lithium salt, at least one oxo-acid ester derivative of phosphorus selected from compounds represented by a predetermined formula, and at least one disulfonate ester selected from a cyclic disulfonate ester and a linear disulfonate ester represented by the predetermined formulae.

Abstract: The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2??(I) (In the formula, X1 represents a group —C(?O)—, a group —C(?O)—C(?O)—, a group —S(?O)2—, a group —P(?O) (—R3)—, or a group —X2—S(?O)2O—.

Abstract: Hybrid radical energy storage devices, such as batteries or electrochemical devices, and methods of use and making are disclosed. Also described herein are electrodes and electrolytes useful in energy storage devices, for example, radical polymer cathode materials and electrolytes for use in organic radical batteries.

Abstract: A secondary battery includes: a positive electrode, a negative electrode, and an electrolytic solution containing a nitrogen-containing aromatic compound, wherein the nitrogen-containing compound contains an aromatic skeleton containing one or two or more aromatic rings and one or two or more nitrogen-containing functional groups bonded to the one or two or more aromatic rings and represented by the following formula (1) (Y?X?N—??(1) wherein X represents C or P; Y represents a group constituted of one kind or two or more kinds of elements selected from the group consisting of H, C, N, O, S, F, Cl, Br, and I, provided that arbitrary two or more of X and Y may be bonded to each other to form a ring structure; and z is 2 or 3.

Abstract: Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.

Abstract: The non-aqueous secondary battery of the present invention comprises a positive electrode containing a lithium-containing composite oxide as an active material, a negative electrode, a separator, and a non-aqueous electrolyte. The non-aqueous electrolyte contains polyvalent organic lithium salt, and the content of the polyvalent organic lithium salt is 0.001 parts by mass or more and 1 part by mass or less with respect to 100 parts by mass of all of the components of the non-aqueous electrolyte other than the polyvalent organic lithium salt.

Abstract: An anode or an electrolytic solution or both contain a metal salt including an unsaturated carbon bond. The electrolytic solution contains an unsaturated carbon bond cyclic ester carbonate represented by Formula (1) or a halogenated cyclic ester carbonate represented by Formula (2) or both, and contains a cyclic ester represented by Formula (3), where each of R1 and R2 is a group such as a hydrogen group, where each of R3 to R6 is a group such as a hydrogen group; and each of one or more of R3 to R6 is a group such as a halogen group, where X is an ether bond (—O—) or a methylene group (—CH2—); each of R7 to R10 is a group such as a hydrogen group; and each of R7 to R10 is a group such as an alkyl group when X is the ether bond.

Abstract: A gel polymer electrolyte precursor and a rechargeable cell comprising the same are provided. The gel polymer electrolyte precursor comprises a bismaleimide monomer or bismaleimide oligomer, a compound having formula (I): a non-aqueous metal salt electrolyte, a non-protonic solvent, and a free radical initiator, wherein the bismaleimide oligomer is prepared by reaction of barbituric acid and bismaleimide, X comprises oxygen, organic hydrocarbon compounds, organic hydrocarbon oxide compounds, oligomers or polymers, n is 2 or 3, and A independently comprises wherein m is 0˜6, X comprises hydrogen, cyano, nitro or halogen, and R1 independently comprises hydrogen or C1˜4 alkyl.

Abstract: A secondary battery capable of improving the cycle characteristics while securing the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer containing a plurality of anode active material particles having silicon (Si). The anode active material layer contains at least one of an oxide-containing film covering a surface of the anode active material particles and a metal material not being alloyed with an electrode reactant provided in a gap in the anode active material layer. The electrolytic solution contains a solvent containing an organic acid that has a portion including an electron attractive group such as —(O?)C—C(?O)— bond in the center and a hydroxyl group on the both ends.

Abstract: An object is to provide a high-capacity lithium ion secondary battery enhanced in safety against overcharging by adding an overcharge retardant additive, which is highly responsive to excessive voltage application, to a nonaqueous electrolytic solution. A lithium ion secondary battery comprising: a separator, positive and negative electrodes arranged with the separator interposed therebetween and reversibly storing/releasing lithium ions, and an organic electrolytic solution having an electrolyte containing the lithium ions dissolved therein, wherein the organic electrolytic solution contains an aromatic compound represented by a general formula (1) below: where R1 represents an alkyl group and R2 to R5 each independently represent any one of hydrogen, a halogen group, an alkyl group, an aryl group, an alkoxy group and a tertiary amine group; and a concentration of the aromatic compound is 0.1 mol/L or less.

Abstract: A nonaqueous electrolyte containing a monofluorophosphate and/or a difluorophosphate and a compound having a specific chemical structure or specific properties. The nonaqueous electrolyte can contain at least one of a saturated chain hydrocarbon, a saturated cyclic hydrocarbon, an aromatic compound having a halogen atom and an ether having a fluorine atom.