Having Active Material With Organic Component Patents (Class 429/212)
  • Patent number: 11870078
    Abstract: A lithium electrode includes a protective layer containing an ion conductive electrolyte in the interior and on the surface of the electrically conductive matrix. The protective layer may make the electrical conductivity of the surface of the lithium electrode uniform, imparts strength during the growth of lithium dendrites, physically prevents the growth of lithium dendrites, and suppresses the generation of dead lithium.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: January 9, 2024
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Eunkyung Park, Bora Jung, Minchul Jang, Suk Il Youn, Byoungkuk Son
  • Patent number: 11855289
    Abstract: The present application provides a negative electrode active material, a process, a battery, a battery module, a battery pack and an apparatus related to the same. The negative electrode active material comprises a core material and a polymer modified coating on at least a part of a surface of core material; wherein the core material is one or more of a silicon-based negative electrode material and a tin-based negative electrode material; the negative electrode active material has a weight loss rate satisfying 0.2%?weight loss rate?2% in a thermogravimetric analysis test wherein temperature is elevated from 25° C. to 800° C. under a non-oxidizing inert gas atmosphere. The present application can reduce damage to the surface structure of the negative electrode active material, reduce loss of active ions and capacity, meanwhile can well improve coulomb efficiency and cycle performance of the battery.
    Type: Grant
    Filed: December 28, 2021
    Date of Patent: December 26, 2023
    Assignee: Contemporary Amperex Technology Co., Limited
    Inventors: Chengdu Liang, Yuzhen Zhao, Yingjie Guan, Yan Wen, Qisen Huang
  • Patent number: 11839476
    Abstract: The present invention provides a bio-electrode composition including a silsesquioxane bonded to a sulfonic acid salt shown by the following general formula (1): wherein R1 represents an alkylene group having 1 to 20 carbon atoms or an arylene group having 6 to 10 carbon atoms, optionally containing an ether group or an ester group, and the alkylene group may also contain an aromatic group; Rf1 and Rf2 represent H, F, O, or a CF3 group and can form a carbonyl group with a carbon atom bonded therewith; Rf3 and Rf4 represent H, F, or a CF3 group and one or more fluorine atoms are contained in Rf1 to Rf4; M is selected from Na, K, and Ag. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity.
    Type: Grant
    Filed: August 6, 2019
    Date of Patent: December 12, 2023
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Jun Hatakeyama, Motoaki Iwabuchi, Yasuyoshi Kuroda
  • Patent number: 11817578
    Abstract: Electrolytes and electrolyte additives for energy storage devices comprising silyl amine compounds or derivatives thereof are disclosed. The energy storage device comprises a first electrode and a second electrode, where one or both of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from silyl amine compounds or derivatives thereof.
    Type: Grant
    Filed: June 2, 2020
    Date of Patent: November 14, 2023
    Assignee: Enevate Corporation
    Inventors: Liwen Ji, Benjamin Yong Park, Hong Zhao
  • Patent number: 11801333
    Abstract: The present invention provides a bio-electrode composition including: (A) an ionic material; and (B) a resin other than the component (A); wherein the component (A) contains both of a repeating unit-a having a structure of any of silver salts of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide; and a repeating unit-b having silicon. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light in weight, manufacturable at low cost, and free from large lowering of the electric conductivity even when it is wetted with water or dried. The present invention also provides a bio-electrode in which the living body contact layer is formed from the bio-electrode composition, and a method for manufacturing the bio-electrode.
    Type: Grant
    Filed: March 12, 2019
    Date of Patent: October 31, 2023
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Jun Hatakeyama, Osamu Watanabe, Koji Hasegawa, Motoaki Iwabuchi, Yasuyoshi Kuroda
  • Patent number: 11791450
    Abstract: Provided is a method of improving the cycle-life of a lithium metal secondary battery, the method comprising implementing an anode-protecting layer between an anode active material layer (or an anode current collector layer substantially without any lithium when the battery is made) and a porous separator/electrolyte assembly, wherein the anode-protecting layer is in a close physical contact with the anode active material layer (or the anode current collector), has a thickness from 10 nm to 500 ?m and comprises an elastic polymer foam having a fully recoverable compressive elastic strain from 2% to 500% and interconnected pores and wherein the anode active material layer contains a layer of lithium or lithium alloy, in a form of a foil, coating, or multiple particles aggregated together, as an anode active material.
    Type: Grant
    Filed: January 24, 2019
    Date of Patent: October 17, 2023
    Assignee: Global Graphene Group, Inc.
    Inventor: Bor Z. Jang
  • Patent number: 11769883
    Abstract: The electrode plate includes a current collector and an electrode active material layer disposed on at least one surface of the current collector, wherein the current collector includes a support layer and a conductive layer, the conductive layer has a single-sided thickness D2 satisfying: 30 nm?D2?3 ?m; the electrode active material layer is divided into two regions, an inner region and an outer region in a thickness direction of the electrode active material layer, in which the weight percentage of the conductive agent in the inner region of the electrode active material layer is higher than the weight percentage content of the conductive agent in the outer region of the electrode active material layer, and the conductive agent in the inner region of the electrode active material layer includes at least one of a one-dimensional conductive material and a two-dimensional conductive material.
    Type: Grant
    Filed: November 20, 2019
    Date of Patent: September 26, 2023
    Assignee: Contemporary Amperex Technology Co., Limited
    Inventors: Chengdu Liang, Jing Li, Wei Li, Qingrui Xue, Zige Zhang, Xianwei Yang
  • Patent number: 11657984
    Abstract: A separator for an electrochemical device is provided. The separator includes a porous polymer substrate, and a porous coating layer formed on at least one surface of the porous polymer substrate, wherein the porous coating layer includes inorganic particles, a first polyvinylidene fluoride copolymer and a second polyvinylidene fluoride copolymer. A method for manufacturing the separator, and an electrochemical device including the same are also provided. It is possible to provide a separator with excellent adhesion between the porous polymer substrate and the porous coating layer and excellent adhesion to an electrode, and an electrochemical device including the same.
    Type: Grant
    Filed: June 7, 2019
    Date of Patent: May 23, 2023
    Inventors: Joo-Sung Lee, A-Young Lee
  • Patent number: 11646443
    Abstract: A main object of the present disclosure is to provide a lithium solid battery in which the coulomb efficiency of the battery upon deposition and dissolution of a metal lithium is improved. The above object is achieved by providing a lithium solid battery comprising: an anode current collector, a solid electrolyte layer, a cathode active material layer, and a cathode current collector; wherein the lithium solid battery comprises a Li storing layer between the anode current collector and the solid electrolyte layer; an amount of Li storage of the Li storing layer to a cathode charging capacity is 0.13 or more; and a thickness of the Li storing layer is 83 ?m or less.
    Type: Grant
    Filed: August 6, 2018
    Date of Patent: May 9, 2023
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Ximeng Li, Masafumi Nose
  • Patent number: 11569492
    Abstract: A positive-electrode active material contains a compound that has a crystal structure belonging to a space group FM3-M and contains is represented by the composition formula (1) and an insulating compound, LixMeyO?F???(1) wherein Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr, and the following conditions are satisfied. 1.7?x?2.2 0.8?y?1.3 1???2.5 0.
    Type: Grant
    Filed: September 15, 2020
    Date of Patent: January 31, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Ryuichi Natsui, Kensuke Nakura
  • Patent number: 11563215
    Abstract: A binder for preparing a positive electrode of a lithium secondary battery, and a method for preparing a positive electrode using the same. The binder includes two or more different lithium-substituted polyacrylic acids with different molecular weights. The lithium-substituted polyacrylic acids include two different lithium-substituted polyacrylic acids differing in weight average molecular weight by 500,000 or more from each other.
    Type: Grant
    Filed: November 16, 2018
    Date of Patent: January 24, 2023
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Choonghyeon Lee, Doo Kyung Yang, Taek Gyoung Kim, Joo Hyeong Lee
  • Patent number: 11539045
    Abstract: A negative electrode for a lithium secondary battery including a lithium metal layer; a first protective layer formed on a surface of the lithium metal layer; and a second protective layer formed on a surface of the first protective layer opposite the lithium metal layer, wherein the first protective layer and the second protective layer are different from each other in at least one property selected from the group consisting of ion conductivity and electrolyte uptake.
    Type: Grant
    Filed: November 13, 2018
    Date of Patent: December 27, 2022
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Dongwook Koh, Doo Kyung Yang
  • Patent number: 11502287
    Abstract: In a method of manufacturing an electrochemical cell, a porous or non-porous metal substrate may be provided. A precursor solution may be applied to a surface of the metal substrate. The precursor solution may comprise a chalcogen donor compound dissolved in a solvent. The precursor solution may be applied to the surface of the metal substrate such that the chalcogen donor compound reacts with the metal substrate and forms a conformal metal chalcogenide layer on the surface of the metal substrate. A conformal lithium metal layer may be formed on the surface of the metal substrate over the metal chalcogenide layer.
    Type: Grant
    Filed: September 14, 2018
    Date of Patent: November 15, 2022
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Fang Dai, Shuru Chen, Meinan He, Mei Cai
  • Patent number: 11495785
    Abstract: A negative electrode for a secondary battery, and a method for producing the same, and more particularly, to a negative electrode for a secondary battery used for a negative electrode of a secondary battery, and a method for producing the same. A negative electrode for a secondary battery may include a carbon-based active material; a conductive material; and a silicon-based active material-polymer binder combination including a silicon-based active material, and a polymer binder for suppressing the expansion of the silicon-based active material bonded to a particle surface of the silicon-based active material.
    Type: Grant
    Filed: December 27, 2017
    Date of Patent: November 8, 2022
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Young Jae Kim, Je Young Kim
  • Patent number: 11469417
    Abstract: Described herein are acidified metal oxide (“AMO”) materials useful in applications such as a battery electrode or photovoltaic component, in which the AMO material is used in conjunction with one or more acidic species. Advantageously, batteries constructed of AMO materials and incorporating acidic species, such as in the electrode or electrolyte components of the battery exhibit improved capacity as compared to a corresponding battery lacking the acidic species.
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: October 11, 2022
    Assignee: HHeLi, LLC
    Inventor: Paige L. Johnson
  • Patent number: 11462740
    Abstract: A conductive material paste for an electrochemical device contains a conductive material, an imidazole compound represented by the following formula (I), a binder, and an organic solvent. In formula (I), X1 and X2 are each hydrogen or a monovalent organic group that optionally forms a ring structure, and X3 and X4 are each hydrogen or an independent monovalent organic group.
    Type: Grant
    Filed: November 29, 2018
    Date of Patent: October 4, 2022
    Assignee: ZEON CORPORATION
    Inventors: Shinsuke Sugawara, Maki Mesuda, Tomoya Murase
  • Patent number: 11420875
    Abstract: This application belongs to the field of energy storage technology, and specifically discloses a negative active material including SiOx particles and a modified polymer coating layer covering the SiOx particles, in which 0<x<2; wherein the negative active material has a peak intensity I1 at the Raman shift ranging from 280 cm?1 to 345 cm?1, a peak intensity 12 at the Raman shift ranging from 450 cm?1 to 530 cm?1, and a peak intensity 13 at the Raman shift ranging from 900 cm?1 to 960 cm?1, and I1, I2 and I3 satisfy 0.1?I1/I2?0.6, and 0.2?I3/I2?1.0. This application also discloses a method for preparing a negative active material and related secondary batteries, battery modules, battery packs and apparatus.
    Type: Grant
    Filed: January 27, 2022
    Date of Patent: August 23, 2022
    Assignee: Contemporary Amperex Technology Co., Limited
    Inventors: Chengdu Liang, Yuzhen Zhao, Yingjie Guan, Yan Wen, Qisen Huang
  • Patent number: 11411221
    Abstract: An electrode for a lithium-ion electrochemical cell comprises silicon particles and carbon particles coated on a conductive current collector. The silicon and carbon particles being bound to each other and to the current collector by a cross-linked binder formed from a combination of a poly(carboxylic acid) such as poly(acrylic acid) and a branched polyethyleneimine. A method of preparing the anode also is described.
    Type: Grant
    Filed: February 14, 2020
    Date of Patent: August 9, 2022
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Zhangxing Shi, Lu Zhang
  • Patent number: 11367927
    Abstract: An energy storage device includes an anode; a cathode; an electrolyte in contact with both the anode and the cathode; and an electrically non-conductive separator between the anode and the cathode. The separator includes a membrane having a plurality of voids, wherein at least some of the voids are partially filled with inorganic particles, and wherein the inorganic particles exhibit a shear modulus greater than the shear modulus of the membrane.
    Type: Grant
    Filed: May 14, 2018
    Date of Patent: June 21, 2022
    Assignees: International Business Machines Corporation, Korea Research Institute of Chemical Technology
    Inventors: Younes Ansari, Young-Hye Na, Ho-Cheol Kim, Sogol Teschler, Yongku Kang, Do Youb Kim, Dong Wook Kim, Jung Don Suk
  • Patent number: 11355742
    Abstract: This application discloses a negative electrode plate and a lithium-ion secondary battery, wherein the negative electrode plate includes a negative electrode current collector and a negative active material layer disposed on at least one surface of the negative electrode current collector, and wherein the negative active material layer includes a graphite material; wherein a ratio r between diffraction peak intensity of (004) crystal surface and diffraction peak intensity of (110) crystal surface of the negative electrode plate, a porosity s of the negative electrode plate, and a resistivity t of the negative electrode plate satisfy: 0.05 ? 100 × s r × t ? 10. The negative electrode plate and the lithium-ion secondary battery provided by this application can simultaneously achieve high safety performance, cycle performance and rate performance.
    Type: Grant
    Filed: November 9, 2019
    Date of Patent: June 7, 2022
    Assignee: Contemporary Amperex Technologv Co., Limited
    Inventors: Zhiqiang Li, Changlong Han
  • Patent number: 11342553
    Abstract: The present application describes a method of forming an energy storage device that directly adds a lithium layer (such as a lithium foil or otherwise deposited lithium) into the cell stack during cell assembly for prelithiating. The method includes providing a silicon-based anode, providing a cathode, positioning a separator between the anode and the cathode, and disposing a lithium layer between the silicon-based anode and the separator, such that the lithium layer is in contact with the anode.
    Type: Grant
    Filed: October 2, 2019
    Date of Patent: May 24, 2022
    Assignee: ENEVATE CORPORATION
    Inventors: Shiang Jen Teng, Xiaohua Liu, David J. Lee, Tracy Ho, Mai Vietnam, Benjamin Yong Park, Frederic Bonhomme
  • Patent number: 11342548
    Abstract: A zinc electrode comprises an anode material, the anode material comprising: an electroactive material comprising at least one of zinc or a compound comprising zinc, a stabilizer additive comprising at least one of: bismuth, copper, indium, a compound comprising bismuth, a compound comprising copper, a compound comprising indium, or any combination thereof, a conductive additive, and a binder.
    Type: Grant
    Filed: November 22, 2019
    Date of Patent: May 24, 2022
    Assignee: RESEARCH FOUNDATION OF THE CITY UNIVERSITY OF NEW YORK
    Inventors: Gautam G. Yadav, Jungsang Cho, Xia Wei, Michael Nyce, Sanjoy Banerjee
  • Patent number: 11329288
    Abstract: The present invention relates to a secondary battery negative electrode binder composition with which a stable negative electrode active material layer can be formed, which can follow volumetric changes in the negative electrode, whereby a secondary battery can be manufactured that achieves a high charge/discharge capacity and allows for improvement in charge/discharge cycle characteristics. Provided is a binder composition for fabricating a secondary battery negative electrode, containing an element capable of forming an alloy with lithium as an active material, which is a secondary battery negative electrode binder composition comprising an emulsion in which polymer particles derived from an ethylenically unsaturated monomer are dispersed in an aqueous solution of a polyvinyl alcohol-based resin, wherein the ratio of the polyvinyl alcohol-based resin/polymer particles is 60/40 to 99/1, as a weight ratio of resin solids.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: May 10, 2022
    Assignee: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Tomotake Yano, Mitsuo Shibutani
  • Patent number: 11296314
    Abstract: A negative electrode material contains composite particles. Each of the composite particles contains a negative electrode active material particle and a film. The negative electrode active material particle contains a silicon oxide phase and a lithium silicate phase. The film covers a surface of the negative electrode active material particle. The film contains an anion-exchange resin. To an ion-exchange group of the anion-exchange resin, a fluoride ion is bound. The content of the anion-exchange resin in the negative electrode material is not higher than 33 mass %.
    Type: Grant
    Filed: February 28, 2019
    Date of Patent: April 5, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Ryosuke Ohsawa, Akira Tsujiko, Kaoru Inoue
  • Patent number: 11296311
    Abstract: Systems and methods are provided for carbon additives for direct coating of silicon-dominant anodes. An example composition for use in directly coated anodes may include a silicon-dominated anode active material, a carbon-based binder, and a carbon-based additive, with the composition being configured for low-temperature pyrolysis. The low-temperature pyrolysis may be conducted at <600° C. An anode may be formed using a direct coating process of the composition on a current collector. The anode active material yields silicon constituting between 86% and 97% of weight of the formed anode after pyrolysis. The carbon-based additive yields carbon constituting between 2% and 6% of weight of the formed anode after pyrolysis.
    Type: Grant
    Filed: January 17, 2020
    Date of Patent: April 5, 2022
    Assignee: ENEVATE CORPORATION
    Inventors: Monika Chhorng, David J. Lee, Rahul Kamath
  • Patent number: 11258065
    Abstract: An energy storage device includes: a positive electrode plate containing a positive composite layer including a positive active material capable of occluding and releasing a lithium ion; and a negative electrode plate containing a negative composite layer including a negative active material capable of occluding and releasing a lithium ion. A peak pore diameter Rp of the positive composite layer in a pore distribution measured by a mercury penetration method is 0.5 ?m or less, and a peak pore diameter Rn of the negative composite layer in a pore distribution measured by a mercury penetration method is 0.5 ?m or less. A ratio Rp/Rn of the peak pore diameter of the positive composite layer to the peak pore diameter of the negative composite layer is 0.60 or more and 1.70 or less.
    Type: Grant
    Filed: January 13, 2017
    Date of Patent: February 22, 2022
    Assignee: GS Yuasa International Ltd.
    Inventors: Shota Ito, Kenta Nakai, Akihiko Miyazaki, Tomonori Kako, Sumio Mori
  • Patent number: 11251466
    Abstract: A lithium secondary battery includes: a positive electrode; an negative electrode; and an electrolyte between the positive electrode and the negative electrode, wherein the positive electrode includes a positive active material represented by Formula 1, the electrolyte includes a lithium salt, a non-aqueous solvent, and a trialkoxyalkylsilane compound represented by Formula 2, and an amount of the trialkoxyalkylsilane compound in the electrolyte is about 0.1 weight percent to about 5 weight percent based on a total weight of the electrolyte: wherein, in Formula 1 and Formula 2, x, y, z, M, A, R1 to R3, and Ar are as defined as the specification.
    Type: Grant
    Filed: October 9, 2018
    Date of Patent: February 15, 2022
    Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.
    Inventors: Eunha Park, Myongchun Koh, Dongyoung Kim, Insun Park, Yeonji Chung
  • Patent number: 11251638
    Abstract: A method for charging aluminum batteries includes performing a first charging procedure for the aluminum battery until the voltage of the aluminum battery reaches a set value. The first charging procedure at least includes a first constant-current charging using a first constant current to charge an aluminum battery in a first stage. The range of the first constant current is from 5 C to 100 C, and C (C-rate) refers to a unit of the capacity of the aluminum battery. When the voltage of the aluminum battery reaches the set value, a first constant-voltage charging uses a first constant voltage to charge the aluminum battery. According to the charging current provided by the first constant voltage to the aluminum battery or the charge time for the aluminum battery charged by the first constant voltage, a determination is made to stop the charging process on the aluminum battery.
    Type: Grant
    Filed: June 10, 2019
    Date of Patent: February 15, 2022
    Assignee: Industrial Technology Research Institute
    Inventors: Sheng-Cheng Chiu, Chien-Chih Chiang, Ping-I Pan, Chang-Chung Yang
  • Patent number: 11233241
    Abstract: The present invention is directed at intercalative metal oxide/conductive polymer composites suitable for use as electrode materials for rechargeable batteries. The composites can be prepared by agitation of the metal oxide and the conductive polymer in aqueous media. The present invention is also directed at a sodium rich layered manganese oxide hydrate prepared by annealing manganese (II, III) oxide and sodium hydroxide. The sodium rich manganese (III, IV) oxide so formed indicates an enhanced capacity for Na-ion storage suitable for the use of electrode materials for aqueous energy storage.
    Type: Grant
    Filed: May 13, 2020
    Date of Patent: January 25, 2022
    Assignee: The UNIVERSITY OF NEW HAMPSHIRE
    Inventor: Teng Xiaowei
  • Patent number: 11165099
    Abstract: Electrolytes and electrolyte additives for energy storage devices comprising a cyclic organosilicon compound are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from a cyclic organosilicon compound.
    Type: Grant
    Filed: December 21, 2018
    Date of Patent: November 2, 2021
    Assignee: Enevate Corporation
    Inventors: Liwen Ji, Benjamin Yong Park
  • Patent number: 11145864
    Abstract: Provided is a binder composition for a non-aqueous secondary battery electrode that has excellent viscosity stability and can form an electrode mixed material layer having excellent electrolyte solution resistance. The binder composition for a non-aqueous secondary battery electrode contains a polymer including a functional group that is bondable with a cationic group and an organic compound including at least two cationic groups.
    Type: Grant
    Filed: January 31, 2017
    Date of Patent: October 12, 2021
    Assignee: ZEON CORPORATION
    Inventor: Taku Matsumura
  • Patent number: 11133506
    Abstract: Provided is a binder composition that exhibits sufficient adhesion and that achieves the excellent dispersibility of a conductive auxiliary agent. The binder composition according to an embodiment of the present invention is a binder composition containing a vinylidene fluoride copolymer composition containing vinylidene fluoride and an acrylic monomer; the acrylic monomer being at least one type selected from acrylic acid and methacrylic acid; and a ratio (Mn2/Mn1) of a number average molecular weight of the vinylidene fluoride copolymer composition after being adsorbed onto alumina (Mn2) to a number average molecular weight of the vinylidene fluoride copolymer composition before being adsorbed onto alumina (Mn1) being less than 2.
    Type: Grant
    Filed: May 18, 2017
    Date of Patent: September 28, 2021
    Assignee: KUREHA CORPORATION
    Inventors: Yuki Sakai, Shintarou Kamata, Emi Sugawara
  • Patent number: 11121361
    Abstract: The present invention provides a method of preparing a slurry for a secondary battery positive electrode which includes forming a first mixture in a paste state by adding a lithium iron phosphate-based positive electrode active material, a conductive agent, a binder, and a solvent, and preparing a slurry for a positive electrode by mixing while further adding a solvent to the first mixture in the paste state.
    Type: Grant
    Filed: March 21, 2018
    Date of Patent: September 14, 2021
    Inventors: Byoung Hoon Ahn, Sang Hoon Choy, Chang Wan Koo, Hyun Chul Ha
  • Patent number: 11121398
    Abstract: Provided is a rechargeable alkali metal-sulfur cell comprising an anode active material layer, an electrolyte, and a cathode active material layer comprising multiple particulates, wherein at least one of the particulates comprises one or a plurality of sulfur-containing material particles being embraced or encapsulated by a thin layer of a conductive sulfonated elastomer composite having from 0.01% to 50% by weight of a conductive reinforcement material dispersed in a sulfonated elastomeric matrix material, wherein the conductive reinforcement material is selected from graphene sheets, carbon nanotubes, carbon nanofibers, metal nanowires, conductive polymer fibers, or a combination thereof and the composite has a recoverable tensile strain from 2% to 500%, a lithium ion conductivity from 10?7 S/cm to 5×10?2 S/cm, and a thickness from 0.5 nm to 10 ?m. This battery exhibits an excellent combination of high sulfur content, high sulfur utilization efficiency, high energy density, and long cycle life.
    Type: Grant
    Filed: June 15, 2018
    Date of Patent: September 14, 2021
    Assignee: Global Graphene Group, Inc.
    Inventors: Aruna Zhamu, Bor Z. Jang
  • Patent number: 11024875
    Abstract: A solid silicon secondary battery, by substitutions of silicon for lithium, enables decrease of preparations cost and minimizing of environmental pollutions. By laminate pressing multiple times a positive or negative electrode material, the present invention enables increase of the density of a positive or negative electrode active material to increase current density and capacity. By having mesh plates equipped inside the positive electrode active material and the negative electrode active material, the present invention enables effective moving of electrons. By enabling common use of an electrode, of a silicon secondary battery, connected during a serial connections of the silicon secondary battery, the present invention enables decreasing of the thickness of a silicon secondary battery assembly and increasing of output voltage. By being integrally formed with a PCB or a chip and supplying a power source, the present invention plays the role of a backup power source for instant discharging.
    Type: Grant
    Filed: July 21, 2015
    Date of Patent: June 1, 2021
    Assignee: REKRIX CO., LTD.
    Inventors: Byung Hoon Ryu, Jae Kyung Kong
  • Patent number: 11018348
    Abstract: A cathode of a lithium-air battery includes a carbon nanotube composite film and a protecting layer. The carbon nanotube composite film includes a carbon nanotube network structure and a catalyst in particle form located in the carbon nanotube network structure. The carbon nanotube composite film is disposed on a surface of the protecting layer. The protecting layer allows conduction of lithium ions while preventing organic substances in an electrolyte of the lithium-air battery reaching the carbon nanotube composite film. A lithium-air battery is also disclosed.
    Type: Grant
    Filed: August 28, 2015
    Date of Patent: May 25, 2021
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Yang Wu, Shun-Chao Ma, Zhang-Quan Peng, Jia-Ping Wang, Kai-Li Jiang, Shou-Shan Fan
  • Patent number: 11008673
    Abstract: In order to provide a method for preparing a chalcogenide-carbon nanofiber, capable of implementing oxidation resistance characteristics and process simplification, the present invention provides a method for preparing a chalcogenide-carbon nanofiber and a chalcogenide-carbon nanofiber implemented by using the same, the method comprising the steps of: forming a chalcogenide precursor-organic nanofiber comprising a chalcogenide precursor and an organic material; and forming a chalcogenide-carbon nanofiber by selectively and oxidatively heat treating the chalcogenide precursor-organic nanofiber such that the carbon of the organic material is oxidized and the chalcogenide is reduced at the same time, wherein the oxidation reactivity of the chalcogenide is lower than that of carbon, the selective and oxidative heat treatment is carried out through one heat treatment step instead of a plurality of heat treatment steps, and the chalcogenide can form a chalcogenide-carbon nanofiber having a structure formed with at
    Type: Grant
    Filed: July 29, 2016
    Date of Patent: May 18, 2021
    Assignee: SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION
    Inventors: Young Chang Joo, Dae Hyun Nam
  • Patent number: 10980234
    Abstract: Antimicrobial cationic polycarbonates and polyurethanes have been prepared comprising one or more pendent guanidinium and/or isothiouronium groups. Additionally, antimicrobial particles were prepared having a silica core linked to surface groups comprising a guanidinium and/or isothiouronium group. The cationic polymers and cationic particles can be potent antimicrobial agents against Gram-negative microbes, Gram-positive microbes, and/or fungi.
    Type: Grant
    Filed: November 16, 2019
    Date of Patent: April 20, 2021
    Assignees: Coral Bay II, LLC, Agency For Science, Technology And Research
    Inventors: Willy Chin, James L. Hedrick, Ashlynn L. Z. Lee, Robert J. Ono, Qingxing Xu, Yi Yan Yang
  • Patent number: 10978698
    Abstract: Provided is a method of producing a rechargeable alkali metal-sulfur cell, comprising: (a) providing an anode layer; (b) providing particulates comprising primary particles of a sulfur-containing material encapsulated or embraced by a thin layer of a conductive sulfonated elastomer composite, wherein the conductive sulfonated elastomer composite comprises from 0% to 50% by weight of a conductive reinforcement material dispersed in a sulfonated elastomeric matrix material, and the conductive sulfonated elastomer composite has a thickness from 1 nm to 10 ?m, a fully recoverable tensile strain from 2% to 500%, a lithium ion conductivity from 10?7 S/cm to 5×10?2 S/cm, and an electrical conductivity from 10?7 S/cm to 100 S/cm; (c) forming the particulates, a resin binder, and an optional conductive additive into a cathode layer; and (d) combining the anode layer, the cathode layer, an optional porous separator, and an electrolyte to form the alkali metal-sulfur cell.
    Type: Grant
    Filed: June 15, 2018
    Date of Patent: April 13, 2021
    Assignee: Global Graphene Group, Inc.
    Inventors: Aruna Zhamu, Bor Z. Jang
  • Patent number: 10971728
    Abstract: Decomposition of an aqueous electrolyte solution when an aqueous lithium ion secondary battery is charged and discharged is suppressed, and the operating voltage of the battery is improved. The aqueous lithium ion secondary battery includes an anode, a cathode, and an aqueous electrolyte solution, the anode including a composite of an anode active material and polytetrafluoroethylene, wherein peaks of the polytetrafluoroethylene at around 1150 cm?1 and at around 1210 cm?1 are observed in FT-IR measurement of the composite, but a peak of the polytetrafluoroethylene at around 729 cm?1 is not observed in Raman spectroscopy measurement of the composite.
    Type: Grant
    Filed: June 4, 2020
    Date of Patent: April 6, 2021
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Takeshi Tojigamori, Hiroshi Nishiyama
  • Patent number: 10971718
    Abstract: An energy storage device includes a cathodic material in an activated state; and an anodic material in an activated state; wherein: the cathodic material is covalently attached to, or confined within, a first polymer matrix, the first polymer matrix is configured to prevent or minimize substantial diffusion of the cathodic material in the activated state; and the anodic material is a phenazine, a phenothiazine, a triphenodithiazine, a carbazole, a indolocarbazole, a biscarbazole, or a ferrocene covalently attached to, or confined within, a second polymer matrix, the second polymer matrix is configured to prevent or minimize substantial diffusion of the anodic material in the activated state.
    Type: Grant
    Filed: October 7, 2019
    Date of Patent: April 6, 2021
    Assignee: GENTEX CORPORATION
    Inventors: David A Theiste, Leroy J. Kloeppner, Sue F. Franz, Punam Giri, Rongguang Lin
  • Patent number: 10938021
    Abstract: Energy storage devices are disclosed. In some embodiments, the energy storage devices comprise a positive electrode comprising a carbon-based material comprising porous carbon sheet(s). Fabrication processes for manufacturing the energy storage devices are disclosed.
    Type: Grant
    Filed: August 28, 2017
    Date of Patent: March 2, 2021
    Assignee: The Regents of the University of California
    Inventors: Maher F. El-Kady, Richard B. Kaner, Matthew Kowal
  • Patent number: 10923720
    Abstract: A graphene-enabled hybrid particulate for use as a cathode active material of an alkali metal-selenium battery, wherein the hybrid particulate is composed of a single or a plurality of graphene sheets and one or a plurality of fine selenium particles or coatings, having a diameter or thickness from 0.5 nm to 10 ?m, and the graphene sheets and the selenium particles or coatings are mutually bonded or agglomerated into a hybrid particulate containing an exterior graphene sheet or multiple exterior graphene sheets embracing the selenium particles or coatings, and wherein the hybrid particulate has an electrical conductivity no less than 10?4 S/cm and the graphene amount is from 0.01% to 30% by weight based on the total weight of graphene and selenium combined. Typically and desirably, the hybrid particulate is substantially spherical or ellipsoidal in shape.
    Type: Grant
    Filed: April 9, 2018
    Date of Patent: February 16, 2021
    Assignee: Global Graphene Group, Inc.
    Inventors: Hui He, Aruna Zhamu, Bor Z. Jang
  • Patent number: 10903485
    Abstract: A negative electrode for nonaqueous electrolyte secondary batteries includes a negative electrode current collector and a negative electrode mixture layer disposed on the negative electrode current collector, and the negative electrode mixture layer contains a negative electrode active material containing lithium titanate, a binder, and a (meth)acrylic acid-based polymer. The amount of the (meth)acrylic acid-based polymer in the negative electrode mixture layer is 10 mass % or less relative to the total amount of the (meth)acrylic acid-based polymer and the binder. The amount of the (meth)acrylic acid-based polymer in a portion of the negative electrode mixture layer that extends from the surface to the middle of the negative electrode mixture layer in the thickness direction (upper region) is 60 mass % or more relative to the total amount of the (meth)acrylic acid-based polymer.
    Type: Grant
    Filed: August 22, 2017
    Date of Patent: January 26, 2021
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Masanori Sugimori, Yasunori Baba, Katsunori Yanagida
  • Patent number: 10864485
    Abstract: Disclosed herein are porous asymmetric silicon membranes. The membranes are characterized by high structural stability, and as such are useful as anode components in lithium ion batteries.
    Type: Grant
    Filed: September 10, 2019
    Date of Patent: December 15, 2020
    Assignee: Georgia Southern Research and Service Foundation, Inc.
    Inventors: Ji Wu, Hao Chen, Ian Byrd
  • Patent number: 10825575
    Abstract: The present invention provides a thick-film paste composition for printing the front side of a solar cell device having one or more insulating layers. The thick-film paste comprises an electrically conductive metal and an oxide composition dispersed in an organic medium that includes an organopolysiloxane and a fluorine-containing degradation agent.
    Type: Grant
    Filed: February 3, 2020
    Date of Patent: November 3, 2020
    Inventors: Hee Hyun Lee, Viacheslav V Diev, Eric Maurice Smith, Kalyan Venkata Chalapathi Rapolu
  • Patent number: 10811688
    Abstract: The invention features a method of making a battery electrode for an electrochemical cell. The method includes mixing a base polymer with an ion source, and then reacting the base polymer with an electron acceptor in the presence of the ion source to form a solid, ionically conductive polymer material having an ionic conductivity greater than 1×10?4 S/cm at room temperature. The battery electrode is electrochemically active when used in the electrochemical cell.
    Type: Grant
    Filed: August 9, 2017
    Date of Patent: October 20, 2020
    Assignee: IONIC MATERIALS, INC.
    Inventors: Michael A. Zimmerman, Alexei B. Gavrilov
  • Patent number: 10797306
    Abstract: Provided is an impact-transfer method of producing multiple anode particulates for a lithium battery, the method comprising: (a) mixing multiple particles of a graphitic material, multiple polymer-coated porous primary anode active material particles, with or without the presence of externally added milling balls or beads, to form a mixture in an impacting chamber of an energy impacting apparatus; (b) operating the energy impacting apparatus for peeling off graphene sheets from the particles of graphitic material and transferring the peeled graphene sheets to surfaces of the polymer-coated anode active material particles to produce particulates of graphene-encapsulated polymer-coated porous anode active material particles; (c) recovering the particulates from the impacting chamber and separating the particles of ball-milling media from the particulates; and (d) thermally converting the polymer in the polymer-coated particles into a carbon foam to obtain porous, graphene-encapsulated carbon foam-protected anod
    Type: Grant
    Filed: January 2, 2019
    Date of Patent: October 6, 2020
    Assignee: Global Graphene Group, Inc.
    Inventor: Bor Z. Jang
  • Patent number: 10790509
    Abstract: A positive-electrode active material precursor for a nonaqueous electrolyte secondary battery is provided that includes a nickel-cobalt-manganese carbonate composite represented by general formula NixCoyMnzMtCO3 (where x+y+z+t=1, 0.05?x?0.3, 0.1?y?0.4, 0.55?z?0.8, 0?t?0.1, and M denotes at least one additional element selected from a group consisting of Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W) and a hydrogen-containing functional group, wherein H/Me representing the ratio of the amount of hydrogen to the amount of metal components Me included in the positive-electrode active material precursor is greater than or equal to 1.60.
    Type: Grant
    Filed: January 5, 2017
    Date of Patent: September 29, 2020
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Kikoo Uekusa, Satoshi Matsumoto, Masao Wakabayashi
  • Patent number: 10781101
    Abstract: The invention provides a method for producing a solid electrolyte, which includes reacting two or more kinds of solid raw materials using a multi-axial kneading machine to give a crystalline solid electrolyte, and which can provide a crystalline solid electrolyte with excellent productivity.
    Type: Grant
    Filed: June 16, 2016
    Date of Patent: September 22, 2020
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Atsushi Sato, Minoru Senga, Masao Aida