Abstract: Electrode structures and electrochemical cells are provided. The electrode structures and/or electrochemical cells described herein may include one or more protective layers comprising a polymer layer and/or a gel polymer electrolyte layer. The polymer layer may be formed from the copolymerization of an olefinic monomer comprising at least one electron withdrawing group and an olefinic comonomer comprising at least one electron donating group. Methods for forming polymer layers are also provided.

Abstract: Disclosed is a positive electrode for secondary batteries manufactured by coating and rolling a slurry for a positive electrode mix including positive electrode active material particles on a current collector, wherein the positive electrode active material particles include one or more selected from the group consisting of lithium iron phosphate particles having an olivine crystal structure and lithium nickel-manganese-cobalt composite oxide particles according to Formula 1, the lithium nickel-manganese-cobalt composite oxide particles existing as secondary particles formed by agglomeration of primary particles, in an amount of greater than 50% and less than 90% based on the total volume of lithium nickel-manganese-cobalt composite oxide, and the lithium iron phosphate particles existing as primary particles in an amount of greater than 50% and less than 100% based on the total volume of lithium iron phosphate (Formula 1 is the same as defined in Claim 1).

Abstract: Disclosed is an electrode for secondary batteries including an electrode mix, which includes an electrode active material and a binder, coated on a current collector. More particularly, the electrode includes a first electrode mix layer including a first binder, a glass transition temperature (Tg) of which is lower than that of a second binder, and an electrode active material, and coated on the current collector; and a second electrode mix layer including the second binder, a glass transition temperature (Tg) of which is higher than that of the first binder, and an electrode active material, and coated on the first electrode mix layer.

Abstract: A solid electrolyte composition includes an inorganic solid electrolyte, a binder which is formed of core-shell type particles which have a core section and a shell section, and a dispersive medium, in which a difference between a glass transition temperature of a polymer compound which forms the core section and a glass transition temperature of a polymer compound which forms the shell section is 50° C. or more.

Abstract: Disclosed is a negative electrode for a rechargeable lithium battery that includes a negative active material and a binder, wherein the binder includes carboxymethyl cellulose, polyvinyl alcohol, and a styrene-butadiene rubber, and a rechargeable lithium battery including the same.

Abstract: The present invention concerns a composite positive electrode for a lithium battery, in particular a lithium-metal polymer (LMP) battery, the use of same for producing an LMP battery and an LMP battery comprising same.

Abstract: An electrode comprising a current collector, a conductive buffer layer composed of a conductive polymer formed on the current collector, and an active material layer formed on the conductive buffer layer. The conductive buffer layer can expand and contract between the non-lithiated and lithiated states.

Abstract: Disclosed is a method of preparing a cathode electrode material for a secondary battery, including a hydrate precursor preparation step of preparing a manganese phosphate hydrate precursor using a coprecipitation process, a synthetic powder preparation step of preparing a synthetic powder by mixing the manganese phosphate hydrate precursor in a powder form with lithium phosphate and carbon, an oxide material powder preparation step of preparing a lithium manganese phosphate oxide material powder by milling and annealing the synthetic powder, a composite powder preparation step of preparing a composite powder by mixing the lithium manganese phosphate oxide material powder with a Li2MnO3-based cathode material, and a slurry preparation step of preparing a slurry by mixing the composite powder with a conductor and a binder.

Abstract: A positive electrode for a secondary battery wherein the electrode includes a collector and a positive electrode active material layer which is stacked upon the collector, and which includes a positive electrode active material, a conductive agent, and a binder; the binder includes a first polymer and a second polymer; the first polymer is a fluorine-containing polymer; the second polymer includes a polymerized moiety having a nitrile group, a polymerized moiety having a hydrophilic group, a polymerized (meth)acrylic acid ester moiety, and a straight-chain polymerized alkylene moiety having a carbon number of at least 4; the proportion of the first polymer and the second polymer in the binder, expressed as a mass ratio, is in the range of 95:5 to 5:95.

Abstract: A method for producing a graphene-composite material, including removing any oxide layer from each of a plurality of silicon nanoparticles, forming a polyaniline layer over each clean silicon nanoparticle, binding a graphene oxide sheet to the polyaniline layer of each particle, and carbonizing the polyaniline to yield a plurality of composite particles. Each composite particle has a graphene outer layer substantially encapsulating a silicon inner core.

Abstract: In an aspect, a binder composition for a secondary battery including a first fluoropolymer binder including a tetrafluoroethylene polymer binder, a second fluoropolymer binder including a vinylidene fluoride binder, and a non fluoropolymer binder is provided.

Abstract: In forming an anode by using metallic lithium as the anode active material, the present invention provides an anode for lithium batteries which can be produced with high productivity and in which dendrite generation is prevented, so that high safety can he secured. An anode for lithium batteries according to an embodiment of the present invention comprises a structure comprising a conductive material layer in which carbon nanotubes are anchored, with a part of the carbon nanotube extending from at least one face of the surfaces of the conductive material layer, and a deposited layer formed by depositing metallic lithium on the carbon nanotubes in the structure.

Abstract: A positive electrode for a rechargeable lithium battery includes a positive active material and a binder including polyvinylidene fluoride, a carboxyl group-containing polyvinylidene fluoride, and poly(vinylidenefluoride-tetrafluoroethylene). The positive electrode may have an improved binding force and increased flexibility. A rechargeable lithium battery includes the positive electrode. The rechargeable lithium battery may have high capacity and excellent performance.

Abstract: A low-wear fluoropolymer composite body comprises at least one fluoropolymer and additive particles dispersed therein. Also provided is a process for the fabrication of such a fluoropolymer composite body. The composite body exhibits a low wear rate for sliding motion against a hard counterface, and may be formulated with either melt-processible or non-melt-processible fluoropolymers.

Abstract: There is provided a negative electrode carbon material for a lithium secondary battery, including a graphite-based material in which holes are formed in a graphene layer plane.

Abstract: Rechargeable lithium battery cell having a housing, a positive electrode, a negative electrode and an electrolyte containing a conductive salt, wherein the electrolyte comprises SO2 and the positive electrode contains an active material in the composition LixM?yM?z(XO4)aFb, wherein M? is at least one metal selected from the group consisting of the elements Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn, M? is at least one metal selected from the group consisting of the metals of the groups II A, III A, IV A, V A, VI A, IB, IIB, IIIB, IVB, VB, VIB and VIIIB, X is selected from the group consisting of the elements P, Si and S, x is greater than 0, y is greater than 0, z is greater than or equal to 0, a is greater than 0 and b is greater than or equal to 0.

Abstract: A polymer compound for use as a binder for a negative electrode of an electrical storage device is formed by condensing polyacrylic acid and a multifunctional amine represented by the following formula (1), in which Y represents a straight chain alkyl group having 1 to 4 carbon atoms, a phenylene group, or an oxygen atom, and R1 and R2 each independently represent one or more hydrogen atoms, methyl groups, ethyl groups, trifluoromethyl groups, or methoxy groups.

Abstract: Heterogeneous metal hydride (MH) compositions comprising a main region comprising a first metal hydride and a secondary region comprising one or more additional components selected from the group consisting of second metal hydrides, metals, metal alloys and further metal compounds are suitable as anode materials for lithium ion cells. The first metal hydride is for example MgH2. Methods for preparing the composition include coating, mechanical grinding, sintering, heat treatment and quenching techniques.

Abstract: A non-aqueous electrolyte battery includes a battery device in which a positive electrode is faced to negative electrode through a separator; a non-aqueous electrolyte; a laminate film which is formed by laminating a metal layer, an outside resin layer formed in outer face of the metal layer, and an inside resin layer formed in the metal layer, and in which the battery device and the non-aqueous electrolyte is packaged by heat welding and housed; a positive electrode lead which is electrically connected to the positive electrode, and drawn from portion heat-welded of the laminate film to an exterior thereof; a negative electrode lead which is electrically connected to the negative electrode, and drawn from portion heat-welded of the laminate film to an exterior thereof; and a porous polymer layer containing, as a component, vinylidene fluoride formed between the laminate film and the battery device.

Abstract: The object of the present invention is to provide a nonaqueous electrolyte secondary battery which has excellent balance of general performance with respect to performance including durability, capacity, resistance, and output characteristics. Provided is a nonaqueous electrolyte battery comprising a positive electrode and a negative electrode each being capable of occluding and releasing metal ions, and a nonaqueous electrolyte solution, wherein the nonaqueous electrolyte solution contains an electrolyte, a nonaqueous solvent, and at least one compound selected from the group consisting of a compound having a fluorosulfonyl structure (—SO2F), a difluorophosphate, and an isocyanate compound, and wherein the negative electrode has a negative electrode active material containing metal particles capable of alloying with Li and graphite particles.

Abstract: The invention relates to three-dimensional crystalline foams with high surface areas, high lithium capacity, and high conductivity for use as electrode materials and methods for their fabrication. In additional embodiments, the invention also relates to the use of three-dimensional crystalline foams as supercapacitors for improved charge and energy storage.

Abstract: A rechargeable battery is provided such that the positive electrode comprises graphite, the negative electrode also comprises graphite, and the electrolyte is a solution of lithium bromide in an ester of succinic acid or an ester of glutaric acid.

Abstract: Provided are: fine vinylidene fluoride resin particles which are solid and have an average particle diameter of 0.3 ?m or more but less than 100 ?m, a particle diameter distribution index of 1-2, a repose angle of less than 40°, and an average sphericity of 80 or more said fine vinylidene fluoride particles being suitable for coating materials and coating applications; and a method for producing the fine vinylidene fluoride resin particles.

Abstract: A rechargeable lithium-sulfur cell comprising an anode, a separator and/or electrolyte, and a sulfur cathode, wherein the cathode comprises (a) exfoliated graphite worms that are interconnected to form a porous, conductive graphite flake network comprising pores having a size smaller than 100 nm; and (b) nano-scaled powder or coating of sulfur, sulfur compound, or lithium polysulfide disposed in the pores or coated on graphite flake surfaces wherein the powder or coating has a dimension less than 100 nm. The exfoliated graphite worm amount is in the range of 1% to 90% by weight and the amount of powder or coating is in the range of 99% to 10% by weight based on the total weight of exfoliated graphite worms and sulfur (sulfur compound or lithium polysulfide) combined. The cell exhibits an exceptionally high specific energy and a long cycle life.

Abstract: The present invention provides a separator for a non-aqueous secondary battery including a porous substrate and an adhesive layer that is formed on one side or both sides of the porous substrate and is an aggregate layer of particles that include a polyvinylidene fluoride resin, the adhesive layer further including a filler that includes at least one of an organic compound or an inorganic compound, the content of the filler being from 20% by mass to 80% by mass, with respect to the total mass of the mass of the particles and the mass of the filler, and the content of the particles per one adhesive layer being from 0.1 g/m2 to 6.0 g/m2.

Abstract: A binder composition for a lithium ion secondary battery electrode, including a particulate polymer and a water-soluble polymer, wherein the water-soluble polymer includes an ethylenically unsaturated carboxylic acid monomer unit in an amount of 20% by weight to 85% by weight, a carboxylic acid amide monomer unit in an amount of 0.1% by weight to 10% by weight, and a crosslinkable monomer unit in an amount of 0.1% by weight to 2.0% by weight.

Abstract: A flexible supercapacitor comprising an electrolyte sandwiched between nickel foams electrodeposited with a nano-composite. The nanocomposite comprises of a conducting polymer, graphene oxide and a metal oxide. Process of fabricating the flexible supercapacitor is also provided. The process comprises electrodepositing a nanocomposite electro-potentiostatically on a nickel foam from an aqueous solution comprising of a conducting monomer, graphene oxide and a metal salt, placed in one compartment cell followed by compressing an electrolyte between at least two layers of electrodeposited nickel foams.

Abstract: A method for producing a conjugated diene rubber is provided which includes the steps of: (a) forming a polymer block (A) by using a polymerization initiator in an inert solvent, the polymer block (A) having an active terminal and containing a specific amount of an isoprene monomeric unit and a specific amount of an aromatic vinyl monomeric unit; (b) forming a polymer block (B) having an active terminal and containing a specific amount of a 1,3-butadiene monomeric unit and, as needed, a specific amount of an aromatic vinyl monomeric unit, thereby obtaining a conjugated diene polymer chain having an active terminal and having the polymer block (A) and a polymer block (B); (c) bringing a specific amount of a predetermined denaturant into reaction with the active terminal of the conjugated diene polymer chain having the active terminal.

Abstract: Several embodiments related to batteries having electrodes with nanostructures, compositions of such nanostructures, and associated methods of making such electrodes are disclosed herein. In one embodiment, a method for producing an anode suitable for a lithium-ion battery comprising preparing a surface of a substrate material and forming a plurality of conductive nanostructures on the surface of the substrate material via electrodeposition without using a template.

Abstract: Provided is a method for manufacturing a film-wrapped electrical device, including: a first injection step of depressurizing, to a given pressure lower than atmospheric pressure, the inside of an injection chamber (2) in which a bag-shaped laminate film wrapping member (29) is placed, the laminate film wrapping member (29) having an opening portion (29a) and housing an electrode assembly (21?) including a positive electrode and a negative electrode stacked with a separator therebetween, and injecting part of a predetermined injection amount of an electrolyte solution (20) into the wrapping member (29) through the opening portion (29a); and a second injection step of, after the first injection step, pressurizing the inside of the injection chamber (2) to a pressure higher than the given pressure and injecting the rest of the predetermined injection amount of the electrolyte solution (20).

Abstract: An apparatus comprising an insulating substrate (101); at least two charge collectors (102, 103) spaced apart on the substrate (101) surface; a proton-generating electrode layer (104) configured to generate proton charge carriers; a proton-accepting electrode layer (105) configured to accept the generated proton charge carriers, wherein each of the proton-generating electrode layer (104) and proton-accepting electrode layer (105) are configured to be electrically connected to a different one of the respective charge collectors (102, 103), and to overlap in a junction region such that the charge carriers of the layers can be transferred between the proton-generating (104) and proton-accepting (105) electrode layers to thereby generate a voltage.

Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode and an electrolyte solution, wherein the negative electrode includes a negative active material layer, the electrolyte solution contains fluoroethylene carbonate, and when a content (mg) of the fluoroethylene carbonate is denoted as X and a reaction area (m2) of the negative active material layer is denoted as Y, X and Y satisfy a relation of 10?(X/Y)?100.

Abstract: A battery structure is provided for making alkali ion and alkaline-earth ion batteries. The battery has a hexacyanometallate cathode, a non-metal anode, and non-aqueous electrolyte. A method is provided for forming the hexacyanometallate battery cathode and non-metal battery anode prior to the battery assembly. The cathode includes hexacyanometallate particles overlying a current collector. The hexacyanometallate particles have the chemical formula A?n?AmM1xM2y(CN)6, and have a Prussian Blue hexacyanometallate crystal structure.

Abstract: A non-aqueous electrolyte secondary battery allows gas generated when an aqueous binder is used as a binder of a negative electrode active material to be effectively discharged from the electrode, and has small decrease of the battery capacity despite use over a long period of time. The non-aqueous electrolyte secondary battery has a positive electrode active material layer, a negative electrode active material layer, and a separator. The density of the negative electrode active material layer is 1.4 to 1.6 g/cm3, an electrolyte solution layer is disposed between at least one layer of the negative electrode active material layer and the positive electrode active material layer, and the separator, and the ratio of total thickness of the positive electrode, the negative electrode and the separator to total thickness of the positive electrode, the negative electrode, the separator and the electrolyte solution layer, is 0.85 or more and less than 1.0.

Abstract: The present invention provides a non-aqueous electrode secondary battery supplied with a non-aqueous electrolyte comprising an overcharge additive. The positive electrode material layer constituting the positive electrode in the non-aqueous electrolyte secondary battery is characterized by having a differential pore volume peak A as well as a peak B located on the smaller pore diameter side than the peak A in a pore diameter range of 0.05 ?m to 2 ?m in a pore size distribution curve measured by a mercury porosimeter, wherein the pore size distribution curve has a minimum C corresponding to a minimum differential pore volume between the peak A and the peak B, such that a ratio (XC/XL) of the minimum C's differential pore volume XC to a differential pore volume XL, which is the larger between the peak A's differential pore volume XA and the peak B's differential pore volume XB is 0.6 or larger.

Abstract: A rechargeable electrochemical battery in the form of a single or multi-stranded wire assembly may be utilized as a power source for any number of implantable or non-implantable medical devices. As the wire form battery may be scaled to micro size, it may be utilized to power medical devices that were traditionally non-active devices, but which may be enhanced with active components. The wire form battery may be cut to size for a particular application which provides the same open circuit voltage regardless of how the wire is ultimately configured and the length of the wire utilized. Although the battery is in wire form, various arrangements of the components within the battery are also possible.

Abstract: Provided are a composite and a method of preparing an anode slurry including the same. More particularly, the present invention provides a composite including a (semi) metal oxide, a conductive material on a surface of the (semi) metal oxide, and a binder, and a method of preparing an anode slurry including preparing a composite by dispersing a conductive material in an aqueous binder and then mixing with a (semi) metal oxide, and mixing the composite with a carbon material and a non-aqueous binder.

Abstract: Provided is a binder for secondary battery electrodes comprising polymer particles obtained by polymerizing three or more kinds of monomers wherein the polymer particles have a mean particle diameter of 0.3 ?m to 0.7 ?m. The binder exhibits superior adhesion force to electrode current collectors and excellent support force to the active material and basically improves safety of electrodes, thus providing a secondary battery with superior cycle characteristics.

Abstract: This invention relates to a waterborne fluoropolymer composition useful for the fabrication of Li-ion-Battery (LIB) electrodes. The fluoropolymer composition contains an organic carbonate compound, which is more environmentally friendly than other fugitive adhesion promoters currently used in waterborne fluoropolymer binders. An especially useful organic carbonate compound is ethylene carbonate (EC) and vinylene carbonate (VC), which are solids at room temperature, and other carbonates which are liquid at room temperature such as propylene carbonate, methyl carbonate and ethyl carbonate. The composition of the invention is low cost, environmentally friendly, safer, and has enhanced performance compared to current compositions.

Abstract: A control system for a lithium secondary battery measures a voltage V of a negative electrode that uses silicon oxide as a negative electrode active material, with respect to a lithium reference electrode and a discharge capacity Q of the lithium secondary battery during discharge of the lithium secondary battery; generates a V?dQ/dV curve representing a relationship between dQ/dV, which is a proportion of an amount of change dQ in the discharge capacity Q to an amount of change dV in the voltage V, and the voltage V; calculates an intensity ratio of two peaks appearing on the V?dQ/dV curve for two voltage values in the voltage V; and senses a state of the negative electrode utilizing the intensity ratio.

Abstract: A secondary battery includes an electrode assembly, a battery case, and a cap assembly. The electrode assembly includes first and second electrodes. The battery case accommodates the electrode assembly therein and has an opened surface. The cap assembly seals the battery case and includes first and second terminal portions coupled to the respective first and second electrodes. In the secondary battery, at least one of the first and second terminal portions is coupled to a variable member including a plurality of variable plates. Accordingly, the path and resistance of current may be varied in the secondary battery, so that it is possible to reduce or prevent generation of heat caused by overcurrent. Thus, it may be possible to reduce or prevent an explosion and fire of the battery, thereby improving the safety of the battery.

Abstract: In manufacture of a storage battery electrode containing graphene as a conductive additive, the efficiency of reduction of graphene oxide is reduced with high efficiency under mild conditions, and cycle characteristics and rate characteristics of a storage battery are improved. Provided is a manufacturing method of a storage battery electrode. In the manufacturing method, a paste containing an active material, a binder, graphene oxide, and a solvent is formed; the paste is applied to a current collector and the solvent contained in the paste is evaporated to form an active material layer; the active material layer is immersed in a liquid containing alcohol; and the active material layer is taken out from the liquid and heated so that the graphene oxide is reduced.

Abstract: An electrode/separator assembly for use in an electrochemical cell includes a current collector; a porous composite electrode layer adhered to the current collector, said electrode layer comprising at least electroactive particles and a binder; and a porous composite separator layer comprising inorganic particles substantially uniformly distributed in a polymer matrix to form nanopores and having a pore volume fraction of at least 25%, wherein the separator layer is secured to the electrode layer by a solvent weld at the interface between the two layers, said weld comprising a mixture of the binder and the polymer. Methods of making and using the assembly are also described.

Abstract: According to one embodiment, there is provided a negative electrode. The negative electrode includes a negative electrode layer. The negative electrode layer contains a titanium composite oxide and a carboxymethyl-cellulose compound. The carboxymethyl-cellulose has a degree of etherification of 1 or more and 2 or less. The negative electrode layer has a density of 2.2 g/cm3 or more.

Abstract: According to one embodiment, there is provided a positive electrode including a positive electrode active material-including layer including a positive electrode active material, which includes a lithium-manganese oxide LiMn2-xMxO4, and a conductive agent. In the positive electrode active material-including layer, an average particle diameter d50 is within 2 ?m to 5 ?m, a particle diameter d10 and a particle diameter d90, where a cumulative frequency from a smaller side is, respectively, 10% and 90%, is within 0.5 ?m to 3 ?m and within 4 ?m to 10 ?m, respectively, in a particle size distribution. X, represented by X=(d50?d10) /d50 is within 0.4 to 0.8. Y, represented by Y=(d90?d50)/d90 is within 0.2 to 0.6.

Abstract: Provided is a negative electrode slurry composition including a binder resin, a water-soluble polymer, and a negative electrode active material, wherein the binder resin including (A) a styrene-butadiene copolymer latex having a gel amount of 70 to 98% and having a glass transition temperature in dynamic viscoelasticity measurement with a single peak at ?30° C. to 60° C. and (B) a polymer latex formed of a hetero-phase structure having a glass transition temperature in dynamic viscoelasticity measurement with at least one peak at ?100° C. to 10° C. and having a glass transition temperature in dynamic viscoelasticity measurement with at least one peak at 10° C. to 100° C., and the negative electrode active material including a carbon-based active material and a silicon-based active material.

Abstract: A homologous series of cyclic carbonate or propylene carbonate (PC) analogue solvents with increasing length of linear alkyl substitutes were synthesized and used as co-solvents with PC for graphite based lithium ion half cells. A graphite anode reaches a capacity around 310 mAh/g in PC and its analogue co-solvents with 99.95% Coulombic efficiency. Cyclic carbonate co-solvents with longer alkyl chains are able to prevent exfoliation of graphite when used as co-solvents with PC. The cyclic carbonate co-solvents of PC compete for solvation of Li ion with PC solvent, delaying PC co-intercalation. Reduction products of PC on graphite surfaces via single-electron path form a stable Solid Electrolyte Interphase (SEI), which allows the reversible cycling of graphite.

Abstract: An electrode is produced by forming an electrode layer on a surface of a current collector using an electrode composition containing a binder including a polyamide acid that is obtained from a specific aromatic tetracarboxylic acid compound and a diamine component containing a diamine having a carboxyl group, and subsequently performing heat treatment to remove a solvent and perform an imidization reaction of the polyamide acid. It is preferable that the electrode composition further contains a crosslinking agent having an epoxy group or an oxazoline group. It is also preferable that the electrode composition further contains a pyridine.

Abstract: Disclosed in the invention are a silicon-carbon composite anode material for lithium ion batteries and a preparation method thereof The material consists of a porous silicon substrate and a carbon coating layer. The preparation method of the material comprises preparing a porous silicon substrate and a carbon coating layer. The silicon-carbon composite anode material for lithium ion batteries has the advantages of high reversible capacity, good cycle performance and good rate performance. The material respectively shows reversible capacities of 1,556 mAh, 1,290 mAh, 877 mAh and 474 mAh/g at 0.2 C, 1 C, 4 C and 15 C rates; the specific capacity remains above 1,500 mAh after 40 cycles at the rate of 0.2 C and the reversible capacity retention rate is up to 90 percent.

Abstract: A lithium ion battery includes at least one battery cell. The battery cell includes a cathode electrode, an anode electrode, and a separator. The separator is sandwiched between the cathode electrode and the anode electrode. At least one of the cathode electrode and the anode electrode includes a current collector. The current collector is a graphene layer.