Abstract: Provided are vinylidene fluoride copolymers exhibiting higher adhesion with respect to metal foils than do conventional vinylidene fluoride copolymers, and to provide uses of the vinylidene fluoride copolymers. The vinylidene fluoride copolymers are obtained by copolymerizing vinylidene fluoride with a compound represented by Formula (A). In Formula (A), R1, R2 and R3 are each independently a hydrogen atom, a chlorine atom or an alkyl group; and X is an atomic group with a molecular weight of not more than 500 containing a heteroatom and having a main chain composed of 1 to 20 atoms, or is a heteroatom.

Abstract: The present disclosure relates to a binder solution for an anode, comprising a thermally cross-linkable polymer binder that is cross-linked by heat, and a solvent for dissolving the thermally cross-linkable polymer binder, and exhibiting a concentration of hydrogen ions corresponding to pH 2.5 to pH 4.5; an active material slurry for an anode, comprising the binder solution; an anode using the slurry; and an electrochemical device comprising the anode. The binder solution for an anode according to one aspect of the present disclosure can relieve the volume expansion of an anode active material by the intercalation and disintercalation of lithium during cycles of electrochemical devices to improve the durability of an anode active material layer, thereby enhancing the life characteristics of the electrochemical devices, and also can provide good dispersibility to the active material slurry for an anode, thereby improving the coating stability of an anode active material layer.

Abstract: A binder composition for a rechargeable battery, including a binder polymer having a glass transition temperature (Tg) of 20° C. or less, and having a storage modulus (60° C.) of 50-150 MPa. The binder composition according to an embodiment can improve life characteristics of the rechargeable battery by efficiently controlling expansion of a negative electrode plate.

Abstract: The present invention relates to the manufacture of a high capacity electrode by synthesizing an excellent Li2MnO3-based composite material Li(LixNiyCozMnwO2) to improve the characteristics of an inactive Li2MnO3 material with a specific capacity of about 460 mAh/g. Here, a manufacturing method of a cathode material for a lithium secondary battery uses a Li2MnO3-based composite material Li(LixNiyCozMnwO2) by reacting a starting material wherein a nickel nitrate solution, a manganese nitrate solution and a cobalt nitrate solution are mixed, with a complex agent by co-precipitation.

Abstract: A battery charge/discharge control device (20) includes an input-enabled power adjustment unit (40) having an input-enabled current value calculation unit (42) and an input power limit value calculation unit (44). The input-enabled current value calculation unit (42) uses a battery current value, a battery temperature value, and an estimated charge capacity value at the time “t” upon execution of detection, so as to obtain an input-enabled current value reduction amount per unit time during charge and an enabled current amount recovery amount per unit time when being left uncontrolled.

Abstract: The present invention provides an electrode active material for an electricity storage device, having a structure represented by following formula (1). In the formula (1), R1 to R6 each denote independently a hydrogen atom (except for a case where all of R1 to R6 denote hydrogen atoms), a halogen atom, an optionally substituted phenyl group, an optionally substituted heterocyclic group, or an optionally substituted hydrocarbon group having 1 to 4 carbon atoms.

Abstract: An electric storage device having a positive electrode, a negative electrode, a separator located between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The positive electrode has a positive substrate layer, a positive composite layer containing a positive active material, and an undercoat layer located between the positive substrate layer and the positive composite layer. A density of the positive composite layer is 2.1 g/cm3 or more and 2.7 g/cm3 or less. The positive electrode has the rate of increase in sheet resistance after a solvent immersion test of 30% or less. The undercoat layer contains a binder selected from the group consisting of chitosan derivatives, cellulose derivatives and acrylic acid derivatives.

Abstract: A nano graphene platelet-based conductive ink comprising: (a) nano graphene platelets (preferably un-oxidized or pristine graphene), and (b) a liquid medium in which the nano graphene platelets are dispersed, wherein the nano graphene platelets occupy a proportion of at least 0.001% by volume based on the total ink volume and a process using the same. The ink can also contain a binder or matrix material and/or a surfactant. The ink may further comprise other fillers, such as carbon nanotubes, carbon nano-fibers, metal nano particles, carbon black, conductive organic species, etc. The graphene platelets preferably have an average thickness no greater than 10 nm and more preferably no greater than 1 nm. These inks can be printed to form a range of electrically or thermally conductive components or printed electronic components.

Abstract: The present invention aims to provide an electrode mixture which shows little change in viscosity even after 24 hours from the preparation of the mixture and enables production of an electrode having a high electrode density and excellent flexibility and is capable of giving excellent electric properties to the resulting cell. The present invention relates to an electrode mixture including a powdery electrode material; a binder; and an organic solvent, the binder including a fluorine-containing polymer including a polymer unit based on vinylidene fluoride and a polymer unit based on tetrafluoroethylene, the fluorine-containing polymer including the polymer unit based on vinylidene fluoride in an amount of 80.0 to 89.0 mol % based on all the polymer units, and the organic solvent being N-methyl-2-pyrolidone and/or N,N-dimethylacetamide.

Abstract: The present invention aims to provide an electrode mixture which shows little change in viscosity even after 24 hours from the preparation of the mixture and enables production of an electrode having a high electrode density and excellent flexibility and is capable of giving excellent electric properties to the resulting cell. The present invention relates to an electrode mixture including a powdery electrode material; a binder; and an organic solvent, the binder including polyvinylidene fluoride and a fluorine-containing polymer including a polymer unit based on vinylidene fluoride and a polymer unit based on tetrafluoroethylene, the fluorine-containing polymer including the polymer unit based on vinylidene fluoride in an amount of 80.0 to 90.0 mol % based on all the polymer units, the polyvinylidene fluoride having a number average molecular weight of 150,000 to 1,400,000.

Abstract: A negative electrode for a rechargeable lithium battery is disclosed. The negative electrode includes a current collector and a negative active material layer positioned on the current collector and including a negative active material and a binder, wherein the negative active material includes a silicon-based material, a tin-based material, or a combination thereof, and the binder includes an organic acid including a carboxyl group-containing polymer and an organic base having a cyclic structure. A method of preparing the same, and a rechargeable lithium battery including the same are also disclosed.

Abstract: Disclosed is a positive electrode according to one embodiment of the present invention that includes a current collector and a positive active material layer on the current collector, wherein the positive active material layer includes a positive active material and activated carbon coated with a fibrous carbon material.

Abstract: Disclosed are a binder composition for a rechargeable lithium battery including a cross-linked compound of polyacrylic acid substituted with an alkali cation and polyvinyl alcohol and an electrode and rechargeable lithium battery including the same. The cross-linked compound of polyacrylic acid and polyvinyl alcohol is obtained by heating polyacrylic acid and polyvinyl alcohol to effect a cross-linking reaction via esterification. The cross-linked compound of polyvinyl alcohol and polyacrylic acid substituted with an alkali cation may improve phase stability of a binder, and has high cross-linking ratio, thereby providing for excellent performance of a rechargeable lithium battery.

Abstract: An alkali metal-sulfur-based secondary battery, in which coulombic efficiency is improved by suppressing a side reaction during charge, and a reduction in discharge capacity by repetition of charge and discharge is suppressed and which has a long battery life and an improved input/output density, includes a positive electrode or a negative electrode containing a sulfur-based electrode active material; an electrolyte solution containing an ether compound such as THF and glyme and a solvent such as a fluorine-based solvent, wherein at least a part of the ether compound and the alkali metal salt forms a complex; and a counter electrode.

Abstract: The present invention provides novel cathodes having a reduced resistivity and other improved electrical properties. Furthermore, this invention also presents methods of manufacturing novel electrochemical cells and novel cathodes. These novel cathodes comprise a silver material that is doped with a high valence early transition metal species.

Abstract: A liquid developer includes an insulating liquid and toner particles dispersed in the insulating liquid. The insulating liquid has a flash point not lower than 100° C. The toner particles contain a resin, and the resin contains 80 mass % or more of a first resin containing a component derived from a polyester resin. A solid content of the liquid developer corresponding to a portion of the liquid developer excluding the insulating liquid satisfies relation of G?(T0)/G?(T0+10)?10 (50° C.?T0?70° C.), where G?(T0) represents a storage elastic modulus at a temperature T0 (° C.) and G?(T0+10) represents a storage elastic modulus at a temperature (T0+10) (° C.).

Abstract: Disclosed is a positive electrode according to one embodiment of the present invention that includes a current collector and a positive active material layer on the current collector, wherein the positive active material layer includes a positive active material and activated carbon coated with a fibrous carbon material.

Abstract: The present invention provides a separator for a non-aqueous secondary battery including a porous substrate and an adhesive layer that is formed on at least one side of the porous substrate and is an aggregate layer of particles that contain a polyvinylidene fluoride resin and have an average particle diameter of from 0.01 ?m to 1 ?m, in which a content of the particles per one adhesive layer is from 0.1 g/m2 to 6.0 g/m2.

Abstract: A graphite material having pores which, when 200 rectangular regions of 6 ?m×8 ?m are randomly selected in a surface image of the graphite material observed by a scanning electron microscope, in the surface of the graphite material appearing in the regions, a pore appearing on the surface and having an aperture in a shape having a diameter of 15 nm to 200 nm, a circularity degree of 0.75 to 1.0 and a major axis/minor axis ratio of 1.0 to 1.5 is visible in two regions or more. Also disclosed is a carbon material for battery electrodes, a paste for electrodes, an electrode and a lithium ion secondary battery including the graphite material.

Abstract: Provided are methods of passivating active materials for use in electrochemical cells as well as active materials and cell components prepared using such methods. Active material particles may be combined with passivating material particles, and this combination may be mixed together using high shear mixing. The mixed combination may not include any solvents or binders. As such, drying mixing may be performed on this combination of the active material particles and passivating material particles. A passivating layer is formed on the active material particles during mixing. This passivating layer later prevents direct contact between the active material particles and the electrolyte while still allowing ionic exchange. Furthermore, the passivating layer may increase electronic conductivity between active material particles in an electrode. The passivating layer may be mechanically bonded to the surface of the active material particles rather than chemically bonded.

Abstract: In one aspect, a binder for an electrode of a lithium rechargeable battery, which increases adhesion between the electrode and an active material by saving characteristics of two monomers by grafting an acryl group to a vinyl alcohol group, and an electrode for a rechargeable battery comprising the same are provided. The electrode can improve charge and discharge cycle life characteristics of the rechargeable battery.

Abstract: Disclosed in that an electrode composition including active carbon and a hardening polymer binder, a cured material of the composition, an electrode including the cured material, a supercapacitor including the electrode, and a method of manufacturing a supercapacitor.

Abstract: To provide a lithium ion secondary battery electrode in which a coated layer is held on a surface of an active material layer over a long period of time to suppress decomposition of the electrolysis solution and to enhance the cyclability, a manufacturing process for the same, and a lithium ion secondary battery using the electrode. A lithium ion secondary battery electrode includes a current collector, an active material layer containing a binder formed on a surface of the current collector, and a coated layer formed on the surface of at least a part of the active material layer, wherein the coated layer contains a silicone-acrylic graft copolymer cured substance including an acrylic type main chain having a functional group and a side chain having a silicone graft-polymerized to the acrylic type main chain, and the coated layer is chemically bonded with the binder.

Abstract: A binder composition of the present invention is for a non-aqueous secondary battery with excellent adhesion between an electrode active material and a current collector. A degree of electrode swelling with an electrolytic solution at a high temperature is small. This binder composition can be used in production of an electrode mixture for a non-aqueous secondary battery. The binder composition can comprise a binder made of a fluorinated copolymer having repeating units derived from tetrafluoroethylene and repeating units derived from propylene, and a solvent or dispersing medium, wherein the fluorinated copolymer has a weight average molecular weight of from 10,000 to 300,000.

Abstract: The present invention relates to a rechargeable accumulator comprising one or more metal-air cells, each cell comprising a metallic negative electrode, a first positive electrode for releasing oxygen, a second positive electrode which is a porous air electrode containing at least one oxygen reducing catalyst, and an automatic device for protecting the air electrode during the charging and discharging phases of the accumulator. The invention also relates to a method for storing and releasing electrical energy using such an accumulator.

Abstract: A long-life battery whose properties do not deteriorate after charge-discharges cycles is provided. A non-aqueous electrolyte secondary battery includes a cathode, an anode, and a non-aqueous electrolytic solution containing an electrolyte. At least one of the cathode and the anode includes a binder. The binder includes a layer having electron conductivity on a surface thereof. The binder improves the contact property between particles of the active materials of the battery and the conductivity in the electrode without impairing the binding property of the binder. Preferably, the binder includes a metal on the surface thereof and the metal does not form an alloy with lithium to further improve the lifetime of the battery.

Abstract: There are provided a battery electrode wherein an active material layer is formed on a collector surface, and the layer contains an active material and a block copolymer having a vinyl alcohol polymer block; and a lithium ion secondary battery having a laminate structure in which a pair of electrodes having an active material layer are disposed in such a manner that the active material layers face each other via a separator, and an electrolyte composition containing a lithium-containing electrolyte salt fills the gaps between the pair of electrodes and the separator, wherein at least one of the pair of electrodes is the above battery electrode. Thus, there can be provided a lithium ion secondary battery which can be easily produced and be less polarized, exhibiting excellent charge/discharge properties and cycle characteristics.

Abstract: In one aspect, a binder for an electrode of a lithium rechargeable battery, which increases adhesion between the electrode and an active material by saving characteristics of two monomers by grafting an acryl group to a vinyl alcohol group, and an electrode for a rechargeable battery comprising the same are provided. The electrode can improve charge and discharge cycle life characteristics of the rechargeable battery.

Abstract: [Problem] An object of the invention is to provide a lithium secondary battery that shows good cycle performance and at the same time prevents a battery thickness increase due to charge-discharge cycles, and a method of manufacturing such a battery. [Means for Solving the Problem] A lithium secondary battery includes a negative electrode (2) having a negative electrode current collector (11) and a negative electrode active material layer (12) disposed on the negative electrode current collector (11), a positive electrode (1) having a positive electrode active material, a separator (3), and a non-aqueous electrolyte. The negative electrode active material layer includes negative electrode active material particles and a negative electrode binder, and the negative electrode active material particles include silicon particles and/or silicon alloy particles. The silicon particles and the silicon alloy particles have a crystallite size of 100 nm or less.

Abstract: A current conductor for an electrochemical power device that includes an array of carbon nanotubes (CNT) anchored in a carbon nanotube metal composite layer and a structure that may incorporate nanoscale particles or thin film onto the current conductor is described. Additionally, a process for creating the structure using electrochemical plating of the metal layer onto the CNT array followed by separation of the structure from the substrate is provided. Another process includes creating the structure using co-electrodeposition of the CNT and metal from an electroplating bath using surfactants, physical energy, and a magnetic and/or electric field to orient the CNT and enhance the CNT density in the composite.

Abstract: This invention relates to a waterborne fluoropolymer composition useful for the fabrication of Li-Ion-Battery (LIB) electrodes. The fluoropolymer composition contains an organic carbonate compound, which is more environmentally friendly than other fugitive adhesion promoters currently used in waterborne fluoropolymer binders. An especially useful organic carbonate compound is ethylene carbonate (EC) and vinylene carbonate (VC), which are solids at room temperature, and other carbonates which are liquid at room temperature such as propylene carbonate, methyl carbonate and ethyl carbonate. The composition of the invention is low cost, environmentally friendly, safer, and has enhanced performance compared to current compositions.

Abstract: In multilayer wholly solid lithium ion secondary batteries, a laminate having a collector layer of material with high conductivity superimposed on an active material layer has been disposed so as to attain a lowering of battery impedance. Consequently, in the fabrication of each of positive electrode layer and negative electrode layer, stacking of three layers consisting of an active material layer, a collector layer and an active material layer has been needed, thereby posing the problem of complex processing and high production cost. In the invention, a positive electrode layer and a negative electrode layer are fabricated from paste consisting of active material mixed with conductive substance in a given mixing ratio, and no collector layer is disposed. This realizes process simplification and manufacturing cost reduction without deterioration of battery performance and has also been effective in enhancing of battery performance, such as improvement to cycle characteristics.

Abstract: A method for producing an energy cell, in particular an energy storage cell or battery, having the steps of: arranging a plurality of films of the energy cell at a processing location, and cutting the plurality of films in one operation, wherein the cutting of the films is carried out by a laser beam, and wherein the laser beam is guided in a liquid. Also an apparatus for producing an energy cell.

Abstract: A method for producing a non-aqueous electrolyte secondary battery includes: subjecting a mixture of a negative-electrode active material on which oil has been adsorbed, CMC and water to hard kneading to prepare a primary kneaded mixture; diluting the primary kneaded mixture with water to prepare a slurry; and adding a binder to the slurry. The method further includes defining an amount of the oil to a value equal to or more than 50 ml/100 g and equal to or less than 62 ml/100 g, wherein the amount of the oil is an amount at the time when the viscosity characteristics of the negative-electrode active material exhibits 70% of the maximum torque that is generated when the oil is titrated onto the negative-electrode active material. The 1% aqueous solution viscosity of the CMC is defined to a value equal to or more than 6000 mPa·s and equal to or less than 8000 mPa·s.

Abstract: The non-aqueous electrolyte secondary battery provided by this invention comprises a positive electrode and a negative electrode, wherein the positive electrode has a positive electrode active material layer comprising a positive electrode active material as a primary component, and the negative electrode has a negative electrode active material layer comprising a negative electrode active material as a primary component, having a negative electrode active material's linseed oil absorption number B (mL/100 g) to positive electrode active material's DBP absorption number A (mL/100 g) ratio B/A of 1.27 to 1.79.

Abstract: A silicon electrode is described, formed by combining silicon powder, a conductive binder, and SLMP™ powder from FMC Corporation to make a hybrid electrode system, useful in lithium-ion batteries. In one embodiment the binder is a conductive polymer such as described in PCT Published Application WO 2010/135248 A1.

Abstract: The present disclosure relates to multilayered materials that are designed to roll spontaneously into micron-sized, cylindrical “jelly roll” or scroll structures. Specifically in this disclosure, at least one of the layers is comprised of a nanosheet material.

Abstract: A composition containing an electrode active material, a water-insoluble polymer (A), and a water-soluble polymer (B), wherein: the water-insoluble polymer (A) contains 20 wt % to 60 wt % of an aliphatic conjugated diene monomer unit (a1), 0.5 wt % to 10 wt % of an ethylenically unsaturated carboxylic acid monomer unit (a2), and 30 wt % to 79.5 wt % of a unit (a3) of a monomer that is copolymerizable therewith; the water-soluble polymer (B) contains 20 wt % to 60 wt % of an ethylenically unsaturated carboxylic acid monomer unit (b1), 25 wt % to 78 wt % of a (meth)acrylic acid ester monomer unit (b2), and 2 wt % to 15 wt % of a unit (b3) of a sulfonic acid group-containing monomer that is copolymerizable therewith; and a ratio (A)/(B) of the water-insoluble polymer (A) relative to the water-soluble polymer (B) is 80/20 to 95/5.

Abstract: An exemplary embodiment provides a lithium ion secondary battery using a high energy type anode, which enables long-life operation thereof. A secondary battery according to an exemplary embodiment comprises an electrode element in which a cathode and an anode are oppositely disposed, an electrolytic solution, and an outer packaging body which encloses the electrode element and the electrolytic solution inside; wherein the anode is formed by binding an anode active material, which comprises carbon material (a) that can absorb and desorb a lithium ion, metal (b) that can be alloyed with lithium, and metal oxide (c) that can absorb and desorb a lithium ion, to an anode collector with an anode binder; and wherein the electrolytic solution comprises a liquid medium which is hard to generate carbon dioxide at a concentration of 10 to 75 vol %.

Abstract: The present invention is directed to compositions comprising free standing and stacked assemblies of two dimensional crystalline solids, and methods of making the same.

Abstract: In one aspect, a composite binder for a battery, including an inorganic particle; a binder polymer; and an organic-inorganic coupling agent, a negative electrode including the composite binder, and a lithium battery including the negative electrode is provided.

Abstract: A coating formulation for forming a conductive coating film on a surface of a collector for constructing an electrode plate for an electricity storage device is provided. The coating formulation contains (A) a polymeric acid, (B) a vinyl carboxylate copolymer represented by the following formula (1): wherein R1 is selected from the group consisting of H, Na, organic groups derived from vinyl carboxylate monomers, and cations capable of forming electrolytes for the electricity storage device, R2 to R4 are independently selected from the group consisting of H, Na, C1-C6 alkyl groups, and cations capable of forming electrolytes for the electricity storage device, and a ratio (m/n) of m to n is from 0.0001 to 1, (C) a conductive material, and (D) a polar solvent.

Abstract: The present invention provides cathodes, methods of making cathodes, and electrochemical cells (e.g., batteries) that employ these cathodes having improved properties over traditional cathodes, methods, or electrochemical cells.

Abstract: An electrode includes a binder and an electroactive material, wherein the binder includes a polymer including a linear polysiloxane or a cyclic polysiloxane.

Abstract: The present invention relates to a battery separator including: a porous substrate; and a layer of a crosslinked polymer supported on at least one surface of the porous substrate, in which the crosslinked polymer is obtained by reacting (a) a reactive polymer having, in the molecule thereof, a reactive group containing active hydrogen with (b) a polycarbonate urethane prepolymer terminated by an isocyanate group.

Abstract: A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m2/g to about 200 m2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm2 to about 3.5 mg/cm2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.

Abstract: This invention relates to a coating formulation, a coating formulation for manufacturing an electrode plate and an undercoating formulation, and their use. These coating formulations are all characterized by containing, in a polar solvent, a hydroxyl-containing resin and an organic acid and/or a derivative thereof. The hydroxyl-containing resin is at least one of (1) a polyvinyl acetal resin, (2) an ethylene-vinyl alcohol copolymer, (3) a modified and/or unmodified polyvinyl alcohol, and (4) a cyanoethyl-containing polymer. According to the present invention, there is provided a coating formulation capable of forming a coating of excellent adhesion and solvent resistance on a surface of a metal material such as an aluminum material.

Abstract: A sheet-form electrode for a secondary battery includes a current collector; an electrode active material layer formed on one surface of the current collector; a porous organic-inorganic layer formed on the electrode active material layer and including inorganic particles and a polymer binder; and a first porous supporting layer formed on the porous organic-inorganic layer. The sheet-form electrode for a secondary battery has supporting layers on at least one surface thereof to exhibit surprisingly improved flexibility and prevent the release of the electrode active material layer from a current collector even if intense external forces are applied to the electrode, thereby preventing the decrease of battery capacity and improving the cycle life characteristic of the battery.

Abstract: Disclosed are an electrode for a lithium secondary battery which includes a metal substrate and a plated layer arranged on the metal substrate and bearing active material particles and resin particles embedded therein, in which a part of the active material particles and the resin particles has a protruding portion beyond the plated layer; and a lithium secondary battery using the electrode. The electrode helps the lithium secondary battery to be resistant to deterioration and property degradation at high temperature and allows the battery to have high input-output performance and to be suitable typically for hybrid electric vehicles.

Abstract: The present invention is a solventless method of producing polymer coated active pharmaceutical ingredient that is taste-masked and may be released in relatively short time. It employs high energy vibrations or acoustic mixing of API particles, water soluble coating material particles and hydrophobic polymer particles, with or without use of other pharmaceutically relevant powders as media. Additionally the method is capable of producing individually coated drug particles without agglomeration or the long drying times associated with solvent based coating methods.