Silver Component Is Active Material Patents (Class 429/219)
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Publication number: 20130216901Abstract: The present invention provides novel cathodes having a reduced resistivity and other improved electrical properties. Furthermore, this invention also presents methods of manufacturing novel electrochemical cells and novel cathodes.Type: ApplicationFiled: September 21, 2011Publication date: August 22, 2013Applicant: zPower, LLCInventors: Jeff Ortega, Hongxia Zhou, George W. Adanson
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Patent number: 8501338Abstract: A system and method for improving electrochemical power sources through the dispensing encapsulation and dispersion into galvanic chambers of an electrochemical cell. Features of the method include the optimization of the concentration levels of chemicals involved in desired energy producing reactions.Type: GrantFiled: April 20, 2011Date of Patent: August 6, 2013Assignee: University of South FloridaInventors: Andres M. Cardenas-Valencia, Norma A. Alcantar, Xiaoling Ding, Ryan G. Toomey, Lawrence C. Langebrake
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Publication number: 20130196209Abstract: A positive electrode composition is presented. The composition includes at least one electroactive metal; at least one alkali metal halide; and at least one additive including a plurality of nanoparticles, wherein the plurality of nanoparticles includes tungsten carbide. An energy storage device, and a related method for the preparation of an energy storage device, are also presented.Type: ApplicationFiled: January 30, 2012Publication date: August 1, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Richard Louis Hart, Michael Alan Vallance, David Charles Bogdan, JR.
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Publication number: 20130196231Abstract: A battery may include a first electrode and a second electrode. In some examples, the first electrode may include a metal substrate including a major surface, where a plurality of tunnels extend into the major surface, and an electrode composition is deposited onto the major surface of the metal substrate, where a portion of the electrode composition is positioned within the plurality of tunnels. The battery may be positioned within a housing of an implantable medical device (IMD).Type: ApplicationFiled: January 27, 2012Publication date: August 1, 2013Applicant: MEDTRONIC, INC.Inventor: Christian S. Nielsen
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Publication number: 20130183579Abstract: A positive active material for a rechargeable lithium battery includes a core including a lithium composite metal oxide selected from the group consisting of compounds represented by the following Chemical Formula 1, Chemical Formula 2, and combinations thereof; and a shell on the core, the shell including lithium iron phosphate (LiFePO4), and the lithium iron phosphate being present in an amount in a range of about 5 to about 15 wt % based on the total weight of the positive active material. LixMO2 ??[Chemical Formula 1] (wherein, in the above Chemical Formula 1, M is one or more transition elements, and 1?x?1.1) yLi2MnO3·(1?y)LiM?O2 ??[Chemical Formula 2] (wherein, in the above Chemical Formula 2, M? is one or more transition elements, and 0?x?1).Type: ApplicationFiled: July 27, 2012Publication date: July 18, 2013Inventors: Seung-Mo Kim, Jun-Sik Jeoung
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Patent number: 8486566Abstract: A positive electrode for a lithium-ion secondary battery includes a positive-electrode mixture layer, which includes a positive-electrode active material containing lithium composite oxide, a conductive material, and a binder, and a current collector. The positive-electrode mixture layer contains a compound including sulfur and/or phosphorous, a first polymer serving as a main binder, and a second polymer different from the first polymer.Type: GrantFiled: November 3, 2008Date of Patent: July 16, 2013Assignee: Sony CorporationInventors: Masanori Soma, Kenichi Kawase, Masayuki Ihara, Atsumichi Kawashima, Kazumi Izumitani
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Publication number: 20130177808Abstract: An anode protector of a lithium-ion battery and a method for fabricating the same are provided. A passivation protector (110) is formed on a surface of an anode (102) in advance by film deposition, such as atomic layer deposition (ALD). The passivation protector (110) is composed of a metal oxide having three dimensional structures, such as columnar structures. Accordingly, the present invention is provided with effective protection of the anode electrode structure and maintenance of battery cycle life under high-temperature operation.Type: ApplicationFiled: March 2, 2012Publication date: July 11, 2013Applicant: National Taiwan University of Science and TechnologyInventors: Fu-Ming Wang, Hsin-Yi Wang, Chin-Shu Cheng
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Patent number: 8475957Abstract: The present invention relates to a negative electrode structure for use in a non-aqueous electrolyte secondary battery and a method of making such negative electrode structure. The negative electrode structure comprises: a monolithic anode comprising a semiconductor material, and a uniform ion transport structure disposed at the monolithic anode surface for contacting a non-aqueous electrolyte, wherein the uniform ion transport structure serves as a current collector and the negative electrode structure does not contain another current collector. The present invention also relates to a battery comprising the negative electrode structure of the present invention, a cathode, and a non-aqueous electrolyte.Type: GrantFiled: April 17, 2009Date of Patent: July 2, 2013Assignee: Enovix CorporationInventors: Murali Ramasubramanian, Robert M. Spotnitz, Nirav S. Shah, Ashok Lahiri
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Publication number: 20130164635Abstract: The present invention relates to a solid composite for use in the cathode of a lithium- sulphur electric current producing cell wherein the solid composite comprises 1 to 75 wt.-% of expanded graphite, 25 to 99 wt.-% of sulphur, 0 to 50 wt.-% of one or more further conductive agents other than expanded graphite, and 0 to 50 wt.Type: ApplicationFiled: May 26, 2011Publication date: June 27, 2013Applicant: Sion Power CorporationInventors: Ruediger Schmidt, Alexander Panchenko, Bastian Ewald, Philip Hanefeld, Sorin Ivanovici, Helmut Moehwald, Igor P. Kovalev
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Publication number: 20130136984Abstract: A composite nitride, a method of preparing the composite nitride, an electrode active material including the composite nitride, an electrode including the electrode active material, and a lithium secondary battery including the electrode, the composite nitride including a core material including a bronze-phase titanium oxide; and a nitrogen atom doped on at least part of the core material.Type: ApplicationFiled: November 29, 2012Publication date: May 30, 2013Applicant: Samsung SDI Co., Ltd.Inventor: Samsung SDI Co., Ltd.
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Publication number: 20130130109Abstract: The present invention relates to nano structures of metal oxides having a nanostructured shell (or wall), and an internal space or void. Nanostructures may be nanoparticles, nanorod/belts/arrays, nanotubes, nanodisks, nanoboxes, hollow nanospheres, and mesoporous structures, among other nanostructures. The nanostructures are composed of polycrystalline metal, oxides such as SnO2. The nanostructures may have concentric walls which surround the internal space of cavity. There may be two or more concentric shells or walls. The internal space may contain a core such ferric oxides or other materials which have functional properties. The invention also provides for a novel, inexpensive, high-yield method for mass production of hollow metal oxide nanostructures. The method may be template free or contain a template such as silica. The nanostructures prepared by the methods of the invention provide for improved cycling performance when tested using rechargeable lithium-ion batteries.Type: ApplicationFiled: December 20, 2012Publication date: May 23, 2013Applicant: CORNELL UNIVERSITYInventor: Cornell University
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Publication number: 20130130101Abstract: A negative electrode active material and a secondary battery are provided. The negative electrode active material can be useful in maintaining excellent cell efficiency and lifespan while showing high-capacity properties, and the secondary battery may be manufactured using the negative electrode active material.Type: ApplicationFiled: November 19, 2010Publication date: May 23, 2013Inventors: Jae Woong Kim, Seung Chul Lee, Ki Duck Park, Chul Gyu Bae, Jong Goo Kang, Yoon Seong Cho
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Publication number: 20130122369Abstract: A negative active material for a rechargeable lithium battery and a rechargeable lithium battery including the same. The negative active material includes a carbon-nanoparticle composite including a crystalline carbon material including pores, and amorphous nanoparticles dispersed either inside the pores, or on the surface of the crystalline carbon material, or both inside the pores and on the surface of the crystalline carbon material. At least one of the amorphous nanoparticles includes a metal oxide layer in a form of a film on the surface, and the amorphous nanoparticles have a full width at half maximum of about 0.35 degree (°) or greater at a crystal plane producing the highest peak as measured by X-ray diffraction analysis.Type: ApplicationFiled: November 8, 2012Publication date: May 16, 2013Applicant: SAMSUNG SDI CO., LTD.Inventor: Samsung SDI Co., Ltd.
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Publication number: 20130095377Abstract: An electrochemical cell including an anode comprising a carbonaceous material, where the carbonaceous material is capable of reversibly incorporating lithium ions therein and lithium metal on the surface thereof, a cathode capable of reversibly incorporating therein lithium ions, and a non-aqueous electrolyte in contact with the anode and the cathode, where the ratio of the capacity to reversibly incorporate lithium ions of the cathode to the capacity to reversibly incorporate lithium ions in the form of LiC6 of the carbonaceous material of the anode is equal to or larger than 4.5:1.Type: ApplicationFiled: October 22, 2012Publication date: April 18, 2013Applicant: TADIRAN BATTERIES LTD.Inventor: Tadiran Batteries Ltd.
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Publication number: 20130089792Abstract: An electrochemical cell is described. The electrochemical cell includes an anode, a cathode, a separator between said anode and said cathode, and an electrolyte. The electrolyte includes a salt dissolved in an organic solvent. The separator in combination with the electrolyte has an area specific resistance less than 2 ohm-cm2. The electrochemical cell has an interfacial anode to cathode ratio of less than about 1.1.Type: ApplicationFiled: November 30, 2012Publication date: April 11, 2013Applicant: THE GILLETTE COMPANYInventor: THE GILLETTE COMPANY
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Publication number: 20130089784Abstract: A negative active material and a lithium battery including the negative active material. The negative active material includes primary particles, each including: a crystalline carbonaceous core having a surface on which silicon-based nanowires are disposed; and an amorphous carbonaceous coating layer that is coated on the crystalline carbonaceous core so as not to expose at least a portion of the silicon-based nanowires. Due to the inclusion of the primary particles, an expansion ratio is controlled and conductivity is provided and thus, a formed lithium battery including the negative active material may have improved charge-discharge efficiency and cycle lifespan characteristics.Type: ApplicationFiled: July 19, 2012Publication date: April 11, 2013Inventors: Yu-Jeong Cho, So-Ra Lee, Ha-Na Yoo, Ui-Song Do, Chang-Su Shin, Su-Kyung Lee, Jae-Myung Kim
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Publication number: 20130089783Abstract: A negative active material and a lithium battery including the same are disclosed. Due to the inclusion of silicon nanowires formed on a spherical carbonaceous base material, the negative active material may increase the capacity and cycle lifespan characteristics of the lithium battery.Type: ApplicationFiled: July 17, 2012Publication date: April 11, 2013Inventors: Ha-Na Yoo, Jae-Myung Kim, So-Ra Lee, Chang-Su Shin, Ui-Song Do, Yu-Jeong Cho, Su-Kyung Lee, Sang-Eun Park
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Publication number: 20130084499Abstract: In a non-aqueous electrolyte secondary battery, a positive electrode active material includes a carbon-coated lithium vanadium phosphate and a lithium nickel composite oxide. A negative electrode active material includes a carbon-based active material capable of intercalating and deintercalating lithium ions. When a first charge capacity of a negative electrode per unit area is “x” (mAh/cm2), and a first charge capacity of a positive electrode per unit area is “y” (mAh/cm2), a relation of “x” and “y” satisfies 0.6?y/x?0.92.Type: ApplicationFiled: September 6, 2012Publication date: April 4, 2013Applicant: FUJI JUKOGYO KABUSHIKI KAISHAInventors: Hideo Yanagita, Kazuki Takimoto
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Patent number: 8410012Abstract: The present invention relates to a catalyst composition, a method for fabricating the same and a fuel cell including the same. The catalyst composition provided by the present invention includes: a catalyst carrier; and a metal solid solution, disposed on the surface of the catalyst carrier, in which the metal solid solution includes palladium and a second metal, and the second metal is selected from the group consisting of gold, platinum, ruthenium, nickel, silver and manganese. Accordingly, the catalyst composition provided by the present invention can exhibit excellent catalytic characteristics, and can be applied in a fuel cell to enhance the electrochemical properties and stability of the fuel cell.Type: GrantFiled: January 8, 2010Date of Patent: April 2, 2013Assignees: Tatung University, Tatung CompanyInventors: Hong-Ming Lin, Cheng-Han Chen, Wei-Jen Liou, Wei-Syuan Lin, She-Huang Wu
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Publication number: 20130071745Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery utilizing the same. The electrode active material includes a core capable of intercalating and deintercalating lithium and a coating layer formed on at least a portion of a surface of the core, wherein the coating layer includes a composite metal halide having a spinel structure.Type: ApplicationFiled: July 10, 2012Publication date: March 21, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jun-young MUN, Won-chang Choi, Jin-hwan Park
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Publication number: 20130071744Abstract: The present invention provides cathodes, methods of making cathodes, and electrochemical cells (e.g., batteries) that employ these cathodes having improved properties over traditional cathodes, methods, or electrochemical cells.Type: ApplicationFiled: November 3, 2010Publication date: March 21, 2013Inventors: Hongxia Zhou, George W. Adamson
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Publication number: 20130059203Abstract: Provided are an anode active material for a lithium secondary battery, a method for preparing same, and a lithium secondary battery including same. An anode active material for a lithium secondary battery according to the present invention includes: active particles by means of which lithium ions may be absorbed/released; and a coating layer coated on the surface of the active particles, wherein the coating layer includes a first material which is a hollow nanofiber and a second material which is a carbon precursor or LTO.Type: ApplicationFiled: May 11, 2011Publication date: March 7, 2013Applicant: ROUTE JJ CO., LTD.Inventors: Ji Jun Hong, Ki Taek Byun, Hyo Won Kim
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Publication number: 20130052534Abstract: A cathode includes a lithium transition metal complex compound including lithium, one, or two or more transition metals, magnesium, and oxygen as constituent elements. In a standardized X-ray absorption spectrum of the lithium transition metal complex compound measured by an X-ray absorption spectroscopic method, a first absorption edge having absorption edge energy E1 in X-ray absorption intensity of about 0.5 exits in a range where X-ray energy is from about 1303 eV to about 1313 eV both inclusive, in a discharged state in which a discharge voltage is about 3.0 V, and a second absorption edge having absorption edge energy E2 in X-ray absorption intensity of about 0.5 exits, in a charged state in which a charge voltage V is from about 4.3 V to about 4.5 V both inclusive. The absorption edge energies E1 and E2 and the charge voltage V satisfy a relation of E2?E1?(V?4.25)×4.Type: ApplicationFiled: August 13, 2012Publication date: February 28, 2013Applicant: SONY CORPORATIONInventors: Satoshi Fujiki, Hirotaka Fukudome, Kazunari Motohashi, Yosuke Hosoya, Yoshihiro Kudo
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Publication number: 20130043843Abstract: Battery formation protocols are used to perform initial charging of batteries with lithium rich high capacity positive electrode to result a more stable battery structure. The formation protocol generally comprises three steps, an initial charge step, a rest period under an open circuit and a subsequent charge step to a selected partial activation voltage. The subsequent or second charge voltage is selected to provide for a desired degree of partial activation of the positive electrode active material to achieve a desired specific capacity while providing for excellent stability with cycling. The formation protocol is particularly effective to stabilize cycling for compositions with moderate lithium enrichment.Type: ApplicationFiled: August 17, 2012Publication date: February 21, 2013Inventors: Shabab Amiruddin, Bing Li
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Publication number: 20130029223Abstract: The invention relates to materials for use as electrodes in an alkali-ion secondary (rechargeable) battery, particularly a lithium-ion battery. The invention provides transition-metal compounds having the ordered-olivine or the rhombohedral NASICON structure and the polyanion (PO4)3? as at least one constituent for use as electrode material for alkali-ion rechargeable batteries.Type: ApplicationFiled: October 4, 2012Publication date: January 31, 2013Inventors: Michel Armand, John B. Goodenough, Akshaya K. Padhi, Kirakodu S. Nanjundaswamy, Christian Masquelier
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Publication number: 20130022871Abstract: A material, in particular an active material, for an electrode of a galvanic element, and a method for the production of the material, a mixture for the production of an electrode for a galvanic element, and a galvanic element, in particular a battery, and a medical implant comprising such a battery.Type: ApplicationFiled: July 17, 2012Publication date: January 24, 2013Applicant: LITRONIK BATTERIETECHNOLOGIE GMBHInventors: Tim Traulsen, Gerd Fehrmann, Thomas Hucke, Andreas Deckert, Joerg Feller, Tom Schuffenhauer
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Publication number: 20130022869Abstract: A positive electrode active material for a lithium secondary battery includes a lithium cobalt complex oxide containing an alkali earth metal and a transition metal in a predetermined mixture ratio. A method of preparing the positive electrode active material includes mixing a lithium salt, a transition metal precursor, and an alkali earth metal salt to form a mixture, and performing at least one thermal treatment on the mixture. A positive electrode for a lithium secondary battery includes the positive electrode active material, and a lithium secondary battery includes the positive electrode.Type: ApplicationFiled: May 21, 2012Publication date: January 24, 2013Inventor: Seung-Beob Yi
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Publication number: 20130022870Abstract: An anode active material, an anode including the anode active material, a lithium battery including the anode, and a method of preparing the anode active material. The anode active material includes: a multilayer metal nanotube including: an inner layer; and an outer layer on the inner layer, wherein the inner layer includes a first metal having an atomic number equal to 13 or higher, and the outer layer includes a second metal different from the first metal.Type: ApplicationFiled: July 11, 2012Publication date: January 24, 2013Applicants: INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY, SAMSUNG ELECTRONICS CO., LTD.Inventors: Jae-man CHOI, Seung-sik HWANG, Moon-seok KWON, Min-sang SONG, Jeong-kuk SHON, Myung-hoon KIM, Han-su KIM, Un-gyu PAIK, Tae-seup SONG
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Publication number: 20130017433Abstract: A battery includes a first portion including a substrate having formed thereon a current collector and an anode electrode material. A second portion is formed on a substrate and includes a current collector and a cathode electrode material. The first portion is joined to the second portion and a separator is disposed between the first portion and the second portion as joined to separate the anode electrode material from the cathode electrode material. An electrolyte is placed in contact with the anode electrode material, the cathode electrode material and the separator.Type: ApplicationFiled: June 20, 2012Publication date: January 17, 2013Applicant: The Regents of the University of MichiganInventors: Ann M. SASTRY, Fabio ALBANO
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Publication number: 20130011737Abstract: A process of electroless plating a tin or tin-alloy active material onto a metal substrate for the negative electrode of a rechargeable lithium battery comprising steps of (1) immersing the metal substrate in an aqueous plating solution containing metal ions to be plated, (2) plating tin or tin-alloy active material onto the metal substrate by contacting the metal substrate with a reducing metal by swiping one on the other, and (3) removing the plated metal substrate from the plating bath and rinsing with deionized water. A rechargeable lithium battery using tin or tin-alloy as the anode active material.Type: ApplicationFiled: July 8, 2011Publication date: January 10, 2013Applicant: U.S. Government as represented by the Secretary of the ArmyInventor: SHENGSHUI ZHANG
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Negative electrode for rechargeable lithium battery, and rechargeable lithium battery including same
Patent number: 8349492Abstract: The negative electrode for a rechargeable lithium battery includes a current collector and a negative active material layer disposed on the current collector. The negative active material layer includes a metal-based negative active material and sheet-shaped graphite and has porosity of 20 to 80 volume %. The negative electrode for a rechargeable lithium battery can improve cell characteristics by inhibiting volume change and stress due to active material particle bombardment during charge and discharge, and by decreasing electrode resistance.Type: GrantFiled: January 22, 2008Date of Patent: January 8, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Sang-Min Lee, Goo-Jin Jeong, Min-Seok Sung, Yong-Mook Kang, Wan-Uk Choi, Sung-Soo Kim -
Publication number: 20120328945Abstract: A lithium ion secondary battery is provided with a positive electrode, a negative electrode containing an active material, and an electrolytic solution, wherein the active material includes a core portion capable of occluding and releasing lithium ions, an amorphous or low-crystalline coating portion disposed on at least a part of the surface of the core portion, and a fibrous carbon portion disposed on at least a part of the surface of the coating portion, and the coating portion contains Si and O as constituent elements, while the atomic ratio y (O/Si) of O relative to Si satisfies 0.5?y?1.8.Type: ApplicationFiled: June 19, 2012Publication date: December 27, 2012Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Takashi Fujinaga, Isao Koizumi, Norihiro Shimoi, Kenichi Kawase
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Publication number: 20120326500Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material contains, as constituent elements, Si, O, and at least one element Ml selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio x (O/Si) of O to Si is 0.5?x?1.8.Type: ApplicationFiled: June 19, 2012Publication date: December 27, 2012Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Toshio Nishi, Isao Koizumi
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Publication number: 20120328915Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material includes a core portion capable of occluding and releasing lithium ions, and a covering portion arranged on at least part of a surface of the core portion, in which the covering portion contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio y (O/Si) of O to Si is 0.5?y?1.8.Type: ApplicationFiled: June 18, 2012Publication date: December 27, 2012Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Isao Koizumi, Toshio Nishi
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Publication number: 20120321955Abstract: A lithium-ion secondary battery is characterized in that it is equipped with: a positive electrode comprising a positive-electrode active material that includes a lithium-transition metal composite oxide including at least lithium and manganese and possessing a layered rock-salt structure; a negative electrode comprising a negative-electrode active material that includes at least one kind of carbon-based materials, silicon-based materials, and tin-based materials; and a non-aqueous electrolytic solution, wherein: said lithium-transition metal composite oxide exhibits an irreversible capacity; and an actual capacity of said negative electrode at the time of first-round charging up to 0 V with respect to metallic lithium is smaller than an actual capacity of said positive electrode at the time of first-round charging up to 4.7 V with respect to metallic lithium.Type: ApplicationFiled: April 1, 2011Publication date: December 20, 2012Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Naoto Yasuda, Toru Abe, Junichi Niwa
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Publication number: 20120321953Abstract: A nano graphene-enabled vanadium oxide composite composition for use as a lithium battery cathode active material, wherein the composite composition is formed of one or a plurality of graphene, graphene oxide, or graphene fluoride sheets or platelets and a plurality of nano-particles, nano-rods, nano-wires, nano-sheets, and/or nano-belts of a vanadium oxide with a size smaller than 100 nm (preferably smaller than 20 nm, further preferably smaller than 10 nm, and most preferably smaller than 5 nm), and wherein the graphene, graphene oxide, or graphene fluoride (having a thickness <20 nm, preferably <10 nm, further preferably <5 nm, and being most preferably of single-layer or less than 5 layers) is in an amount of from 0.01% to 50% (preferably <10%) by weight based on the total weight of graphene, graphene oxide or graphene fluoride and the vanadium oxide combined.Type: ApplicationFiled: June 17, 2011Publication date: December 20, 2012Inventors: Guorong Chen, Aruna Zhamu, Bor Z. Jang, Zhenning Yu
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Publication number: 20120321954Abstract: The present invention is a production process for composite oxide being expressed by a compositional formula: LiMn1-xAxO2 (where “A” is one or more kinds of metallic elements other than Mn; and 0?“x”<1), and the composite oxide is obtained via the following: a raw-material mixture preparation step of preparing a raw-material mixture by mixing a metallic-compound raw material and a molten-salt raw material with each other, the metallic-compound raw material at least including an Mn-containing nitrate that includes one or more kinds of metallic elements in which Mn is essential, the molten-salt raw material including lithium hydroxide and lithium nitrate, and exhibiting a proportion of the lithium nitrate with respect to the lithium hydroxide (i.e., (Lithium Nitrate)/(Lithium Hydroxide)) that falls in a range of from 1 or more to 3 or less by molar ratio; a molten reaction step of reacting the raw-material mixture at 500° C.Type: ApplicationFiled: February 7, 2011Publication date: December 20, 2012Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Ryota Isomura, Hitotoshi Murase, Naoto Yasuda
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Publication number: 20120313587Abstract: Several embodiments related to lithium-ion batteries having electrodes with nanostructures, compositions of such nanostructures, and associated methods of making such electrodes are disclosed herein. In one embodiment, a method for producing an anode suitable for a lithium-ion battery comprising preparing a surface of a substrate material and forming a plurality of conductive nanostructures on the surface of the substrate material via electrodeposition without using a template.Type: ApplicationFiled: February 11, 2011Publication date: December 13, 2012Applicant: Washington Stat University Research FoundationInventors: M. Grant Norton, Uttara Sahaym
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Publication number: 20120315543Abstract: A coin-type lithium secondary battery includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The negative electrode includes a negative electrode active material including a silicon alloy material, a conductive agent including a carbon material, and a binder. The silicon alloy material includes a phase A including a lithium-silicon alloy and a phase B including an intermetallic compound of a transition metal element and silicon. In the lithium-silicon alloy, a ratio of lithium atoms relative to silicon atoms is 2.75 to 3.65 in a 100% state-of-charge.Type: ApplicationFiled: September 15, 2010Publication date: December 13, 2012Inventors: Toshie Wata, Tadayoshi Takahashi
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Patent number: 8318340Abstract: Electrochemical cells including a casing or cup for direct electrical contact with a negative electrode or counter electrode and serving as the current collector for the electrode. The casing includes a substrate having a plated coating of an alloy including copper, tin and zinc, the coating having a composition gradient between the substrate and the external surface of the coating wherein the copper content is greater adjacent the substrate than at the external surface of the coating and the tin content is greater at the external surface of the coating than adjacent the substrate. Methods for forming a coated casing and an electrochemical cell including a coated casing are disclosed, preferably including providing an electrode casing with a coating utilizing variable current density plating that reduces discoloration of a surface exposed to the ambient atmosphere.Type: GrantFiled: November 3, 2011Date of Patent: November 27, 2012Assignee: Eveready Battery Company, Inc.Inventor: Jason L. Stimits
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Publication number: 20120282530Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.Type: ApplicationFiled: July 13, 2012Publication date: November 8, 2012Applicant: Massachusetts Institute of TechnologyInventors: Yet-Ming Chiang, William Douglas Moorehead
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Publication number: 20120282521Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery adopting the same. The electrode active material includes a core capable of occluding and emitting lithium; and a surface treatment layer formed on at least a portion of a surface of the core, wherein the surface treatment layer includes a lithium-free oxide having a spinel structure.Type: ApplicationFiled: May 1, 2012Publication date: November 8, 2012Applicant: Samsung Electronics Co. Ltd.Inventors: Won-chang CHOI, Jin-hwan Park
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Publication number: 20120282522Abstract: A lithium metal oxide positive electrode material useful in making lithium-ion batteries that is produced using spray pyrolysis. The material comprises a plurality of metal oxide secondary particles that comprise metal oxide primary particles, wherein the primary particles have a size that is in the range of about 1 nm to about 10 ?m, and the secondary particles have a size that is in the range of about 10 nm to about 100 ?m and are uniformly mesoporous.Type: ApplicationFiled: May 2, 2012Publication date: November 8, 2012Applicant: Washington UniversityInventors: Richard L. Axelbaum, Xiaofeng Zhang
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Publication number: 20120270105Abstract: A nonaqueous electrolyte secondary battery disclosed in the present application includes: a positive electrode capable of absorbing and releasing lithium, containing a positive electrode active material composed of a lithium-containing transition metal oxide having a layered crystalline structure; and a negative electrode capable of absorbing and releasing lithium, containing a negative electrode active material composed of a lithium-containing transition metal oxide obtained by substituting some of Ti element of a lithium-containing titanium oxide having a spinel crystalline structure with one or more element different from Ti, wherein a retention of the negative electrode is set to be greater than a retention of the positive electrode, and an irreversible capacity rate of the negative electrode is set to be greater than an irreversible capacity rate of the positive electrode, whereby a discharge ends by negative electrode limitation.Type: ApplicationFiled: April 18, 2012Publication date: October 25, 2012Inventors: Natsumi Goto, Takashi Takeuchi, Masaki Hasegawa
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Publication number: 20120251882Abstract: A composite includes a compound selected from the group consisting of a lithium lanthanum zirconium oxide and a lithium lanthanum tantalum oxide; a lanthanum oxide; and an oxide selected from the group consisting of a lanthanum zirconium oxide and a lanthanum tantalum oxide. An electrode active material for a secondary lithium battery may include such composite. Methods of preparing the composite, an electrode for a secondary lithium battery including the electrode active material, and a secondary lithium battery including the electrode are disclosed.Type: ApplicationFiled: September 23, 2011Publication date: October 4, 2012Applicant: SAMSUNG SDI CO., LTD.Inventors: Sung-Hwan Moon, Yury Matulevich, Jae-Hyuk Kim, Hee-Young Chu, Myung-Hwan Jeong, Chang-Ui Jeong, Jong-Seo Choi
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Patent number: 8277683Abstract: Nano-sized structured dense and spherical layered positive active materials provide high energy density and high rate capability electrodes in lithium-ion batteries. Such materials are spherical second particles made from agglomerated primary particles that are Li1+?(NixCoyMnz)1?tMtO2?dRd, where M is selected from can be Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, Zr, or a mixture of any two or more thereof, R is selected from F, Cl, Br, I, H, S, N, or a mixture of any two or more thereof, and 0???0.50; 0<x?1; 0?y?1; 0<z?1; 0?t?1; and 0?d?0.5. Methods of preparing such materials and their use in electrochemical devices are also described.Type: GrantFiled: May 22, 2009Date of Patent: October 2, 2012Assignee: Uchicago Argonne, LLCInventors: Haixia Deng, Ilias Belharouak, Khalil Amine
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Publication number: 20120231338Abstract: A support for carrying a catalyst is obtained by carbonizing raw materials containing a nitrogen-containing organic substance and a metal. The support for carrying a catalyst may have a peak at a diffraction angle of around 26° in an X-ray diffraction pattern, the peak including 20 to 45% of a graphite-like structure component and 55 to 80% of an amorphous component. In addition, the support for carrying a catalyst may have an intensity ratio of a band at 1,360 cm?1 to a band at 1,580 cm?1 (I1,360/I1,580) in a Raman spectrum of 0.3 or more and 1.0 or less. In addition, the support for carrying a catalyst may be obtained by carbonizing the raw materials to obtain a carbonized material, subjecting the carbonized material to a metal removal treatment, and subjecting the resultant to a heat treatment.Type: ApplicationFiled: December 3, 2010Publication date: September 13, 2012Applicants: NATIONAL UNIVERSITY CORPORATION GUNMA UNIVERSITY, NISSHINBO HOLDINGS INC.Inventors: Erina Matsuzaka, Takeaki Kishimoto, Jun-ichi Ozaki
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Publication number: 20120223681Abstract: Electrodes as well as electrode production methods are provided that can include a substrate with the substrate comprising non-conductive material. Batteries including electrodes of the disclosure are provided. Electricity storage methods are provided that can utilize the electrodes and/or batteries of the disclosure.Type: ApplicationFiled: February 29, 2012Publication date: September 6, 2012Inventors: Bradley W. Stone, Alfred T. Volberding
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Publication number: 20120219859Abstract: A compound of formula Ab?MgaMbXy or Ab?MgaMb(XOz)y for use as electrode material in a magnesium battery is disclosed, wherein A, M, X, b?, a, b, y, and z are defined herein.Type: ApplicationFiled: March 2, 2012Publication date: August 30, 2012Applicant: PELLION TECHNOLOGIES, INC.Inventors: Robert E. DOE, Timothy K. MUELLER, Gerbrand CEDER, Jeremy BARKER, Kristin A. PERSSON
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Publication number: 20120219858Abstract: The object of the present invention is to inhibit occurrence of structural collapse caused by volumetric change of primary particles of negative electrode active material and to improve adhesion between negative electrode active material and electrically conductive agent and between negative electrode mix layer and collector, whereby improvement of life is attained in negative electrode for non-aqueous secondary battery and non-aqueous secondary battery. In the negative electrode for non-aqueous secondary battery of the present invention, the negative electrode active material comprises silicon and/or tin, and at least one element selected from elements which do not react with lithium and has pores in both of the inner core portion and the outer peripheral portion of primary particles and a material which cures by a heat treatment is used as a binder.Type: ApplicationFiled: February 14, 2012Publication date: August 30, 2012Inventors: Takashi NAKABAYASHI, Shin TAKAHASHI