Alkaline Earth Metal Or Magnesium (mg) Component Is Active Material Patents (Class 429/231.6)
  • Publication number: 20120171570
    Abstract: The present disclosure relates to an electrode composite material. The electrode composite material includes a number of electrode composite material particles. Each of the plurality of electrode composite material particles includes an electrode active material particle and a doped aluminum phosphate layer coated on a surface of the electrode active material particle. A material of the doped aluminum phosphate layer is a semiconducting doped aluminum phosphate.
    Type: Application
    Filed: April 29, 2011
    Publication date: July 5, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XIAN-KUN HUANG, XIANG-MING HE, CHANG-YIN JIANG, DAN WANG, JIAN GAO, JIAN-JUN LI
  • Publication number: 20120171571
    Abstract: A negative electrode material for a non-aqueous electrolyte secondary battery, which comprises a negative electrode active material capable of absorbing and releasing a lithium ion and at least one salt selected from the group consisting of a carboxylic acid salt of an alkali metal, a carboxylic acid salt of an alkali earth metal, a sulfuric acid salt of an alkali metal, a sulfuric acid salt of an alkali earth metal, a boric acid salt of an alkali metal, a boric acid salt of an alkali earth metal, a phosphoric acid salt of an alkali metal and a phosphoric acid salt of an alkali earth metal.
    Type: Application
    Filed: June 14, 2010
    Publication date: July 5, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kosuke Kurakane, Naoki Inui, Junji Suzuki
  • Patent number: 8211578
    Abstract: An improved electrolyte for a cell having an anode comprising magnesium or magnesium alloy. The cell's cathode may desirably include iron disulfide (FeS2) as cathode active material. The improved electrolyte comprises a magnesium salt, preferably magnesium perchlorate dissolved in an organic solvent which preferably includes acetonitrile or mixture of tetrahydrofuran and propylene carbonate. The electrolyte includes an additive to retard the buildup of deleterious passivation coating on the magnesium anode surface, thereby enhancing cell performance. Such additive may preferably include 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4), 1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF6), lithium hexafluorophosphate (LiPF6), or aluminum chloride (AlCl3).
    Type: Grant
    Filed: June 9, 2009
    Date of Patent: July 3, 2012
    Assignee: The Gillette Company
    Inventors: Zhiping Jiang, Rimma Sirotina, Nikolay Iltchev
  • Publication number: 20120164537
    Abstract: In a positive electrode active material for a magnesium secondary battery and a magnesium secondary battery using it, there is contained a powder particle containing a crystal phase having a structure formed with aggregation of a plurality of crystallites, and amorphous phases formed between the crystallites themselves; the amorphous phases contain at least one kind of a metal oxide selected from a vanadium oxide, an iron oxide, a manganese oxide, a nickel oxide and a cobalt oxide; and the crystal phase and the amorphous phases use the positive electrode active material enabling to store and release magnesium ions.
    Type: Application
    Filed: December 20, 2011
    Publication date: June 28, 2012
    Inventors: Takuya AOYAGI, Takashi Naito, Tadashi Fujieda, Yuichi Sawai, Katsunori Nishimura, Masahiro Yonemoto
  • Publication number: 20120156565
    Abstract: In one aspect, a positive electrode active material is provided, a method of manufacturing the positive electrode active material, and a lithium battery employing the positive electrode active material. The positive electrode active material may have high thermal stability and low capacity deterioration despite repetitive charging and discharging.
    Type: Application
    Filed: September 23, 2011
    Publication date: June 21, 2012
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Chang-Hyuk Kim, Do-Hyung Park, Seon-Young Kwon, Min-Han Kim, Ji-Hyun Kim, Jeong-Seop Lee, Yoon-Chang Kim
  • Publication number: 20120141881
    Abstract: An optimal architecture for a polymer electrolyte battery, wherein one or more layers of electrolyte (e.g., solid block-copolymer) are situated between two electrodes, is disclosed. An anolyte layer, adjacent the anode, is chosen to be chemically and electrochemically stable against the anode active material. A catholyte layer, adjacent the cathode, is chosen to be chemically and electrochemically stable against the cathode active material.
    Type: Application
    Filed: August 13, 2010
    Publication date: June 7, 2012
    Applicant: SEEO, INC
    Inventors: Michael Geier, Ilan Gur, Mohit Singh, William Hudson
  • Publication number: 20120135290
    Abstract: Disclosed is an olivine-based positive active material for a rechargeable lithium battery and a rechargeable lithium battery using the same, wherein the olivine-based positive active material for a rechargeable lithium battery is represented the following Formula 1. LixMyM?zXO4-wBw??[Chemical Formula 1] Chemical Formula 1 has the same definitions as in the specification.
    Type: Application
    Filed: September 22, 2011
    Publication date: May 31, 2012
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Han-Eol Park, Sun-Hwa Kwon, Ji-Hyun Kim, Ki-Hyun Kim, Yong-Chan You, Yoon-Chang Kim
  • Publication number: 20120135309
    Abstract: Disclosed is an positive active material for a rechargeable lithium battery that includes an olivine-type composite oxide; and a metal or an alloy thereof adhered to a surface of the olivine-type composite oxide, wherein the metal or the alloy is selected from the group consisting of germanium (Ge), zinc (Zn), gallium (Ga), and a combination thereof.
    Type: Application
    Filed: July 29, 2011
    Publication date: May 31, 2012
    Applicant: Samsung SDI Co., Ltd.
    Inventor: Ji-Hyun KIM
  • Patent number: 8187749
    Abstract: According to a positive electrode for a lithium ion secondary battery comprising a current collector and a mixture layer containing a transition metal-containing complex oxide as a positive electrode active material formed on the current collector, wherein the mixture layer has surface roughness of 0.1 ?m or more and 0.5 ?m or less in terms of a Ra value and the mixture layer has a surface treated layer treated with a coupling agent on the surface, it is possible to obtain a positive electrode which is excellent in suppression of moisture absorption. By using the positive electrode, it is possible to obtain a lithium ion secondary battery which is excellent in storage characteristics and causes less battery swelling since the amount of a gas generated upon charging and discharging decreases.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: May 29, 2012
    Assignee: Panasonic Corporation
    Inventors: Keiichi Takahashi, Kozo Watanabe, Kensuke Nakura
  • Publication number: 20120129049
    Abstract: A method of forming a silicon anode material for rechargeable cells includes providing a metal matrix that includes no more than 30 wt % of silicon, including silicon structures dispersed therein. The metal matrix is at least partially etched to at least partially isolate the silicon structures.
    Type: Application
    Filed: May 7, 2010
    Publication date: May 24, 2012
    Inventor: Philip John Rayner
  • Publication number: 20120107691
    Abstract: A positive active material for a lithium secondary battery comprises a core comprising a compound that can reversibly intercalate and deintercalate lithium; and a compound attached to the surface of the core and represented by Chemical Formula 1: Li1+xM(I)xM(II)2?xSiyP3?yO12, ??[Chemical Formula 1] wherein M(I) and M(II) are selected from the group consisting of Al, Zr, Hf, Ti, Ge, Sn, Cr, Nb, Ga, Fe, Sc, In, Y, La, Lu, and Mg, and 0<x?0.7, 0?y?1.
    Type: Application
    Filed: November 16, 2011
    Publication date: May 3, 2012
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Joon-Hyung Lee, Andriy Kvasha, Oleg Levin
  • Publication number: 20120107686
    Abstract: This invention relates to a positive electrode active material for a lithium secondary battery and a lithium secondary battery including the same, and particularly to a positive electrode active material for a lithium secondary battery, in which a lithium composite oxide having a composition of LiNi1-xMxO2 (wherein M represents one or a combination of two elements selected from the group consisting of Co, Al, Mn, Mg, Fe, Cu, Ti, Sn and Cr, and 0.96?x?1.05) is surface-modified using carbon or an organic compound, thereby achieving superior stability and improved high-rate capability compared to conventional positive electrode active materials, and to a lithium secondary battery including the same.
    Type: Application
    Filed: March 11, 2010
    Publication date: May 3, 2012
    Applicant: ECOPRO CO., LTD
    Inventors: Kwang -Sun Ryu, Suk-Joon Park, Jik-Soo Kim, Kyung Shin, Young-Min Chung, Joeng-Hun Ju, Yu-Rim Bak
  • Publication number: 20120107695
    Abstract: Provided is a lithium rechargeable battery including: a cathode plate including a cathode current collector layer and a cathode layer; an anode plate spaced from the cathode plate, the cathode plate including an anode current collector layer and an anode layer; and a polymer electrolyte disposed between the cathode plate and the anode plate, wherein at least one of the cathode layer and the anode layer includes a mixed cathode active material or a mixed anode active material.
    Type: Application
    Filed: November 1, 2011
    Publication date: May 3, 2012
    Applicant: ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE
    Inventors: Young-Gi LEE, Kwang Man KIM, Min Gyu CHOI, Kunyoung KANG, Yil Suk YANG, Jongdae KIM
  • Publication number: 20120107687
    Abstract: Disclosed is a positive electrode for a rechargeable lithium battery and a rechargeable lithium battery including the same. The positive electrode includes a current collector; and a positive active material layer disposed on the current collector and including a lithium vanadium oxide-based positive active material represented by the following Chemical Formula 1. LixV2-yMyO5??[Chemical Formula 1] In Chemical Formula 1, M is one or more selected from the group consisting of aluminum (Al), magnesium (Mg), zirconium (Zr), titanium (Ti), strontium (Sr), copper (Cu), cobalt (Co), nickel (Ni), manganese (Mn), and a combination thereof, 1<x<4, and 0?y?0.5.
    Type: Application
    Filed: April 8, 2011
    Publication date: May 3, 2012
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Sumihito Ishida, Jung-Woo An, Kyeu-Yoon Sheem
  • Patent number: 8168331
    Abstract: An electrochemical element for use at a high temperature has an anode, a cathode comprising an intercalation material having an upper reversible potential-limit of at most 4 V versus Li/Li+ as active material, and an electrolyte arranged between the cathode and anode, which electrolyte comprises an ionic liquid with an anion and a cation a pyrrolidinium ring structure having four Carbon atoms and one Nitrogen atom. Experiments revealed that rechargeable batteries comprising such an intercalation material and N—R1—N—R2-pyrrolidinium, wherein R1 and R2 are alkyl groups and R1 may be methyl and R2 may be butyl or hexyl, are particularly suitable for use at a temperature of up to about 150 degrees Celsius and may be used in oil and/or gas production wells.
    Type: Grant
    Filed: November 30, 2004
    Date of Patent: May 1, 2012
    Assignee: Shell Oil Company
    Inventors: Adam Samuel Best, Hiske Landheer, Franciscus Güntherus Bernardus Ooms
  • Publication number: 20120100424
    Abstract: Cathode active materials, and cathodes and magnesium batteries including the cathode active materials. The cathode active materials, and cathodes and magnesium batteries include a metal sulfide-based nanosheet.
    Type: Application
    Filed: May 31, 2011
    Publication date: April 26, 2012
    Applicants: Samsung Electro-Mechanics Co., Ltd, Samsung Electronics Co., Ltd.
    Inventors: Seok-soo LEE, Young-gyoon Ryu, Jung-wook Seo, Young-min Choi
  • Patent number: 8148015
    Abstract: Described are cathode materials for lithium batteries. Better cathode materials may be produced by mixing at least two compounds and a binder additive. The first compound includes one or more salts of lithium metal phosphorous while the second compound includes one or more lithium transition metal oxides. In other instances, a conductive additive may also be incorporated. The cathode materials so produced exhibit enhanced electrical properties and thermal stability.
    Type: Grant
    Filed: March 21, 2008
    Date of Patent: April 3, 2012
    Assignee: BYD Company Limited
    Inventors: Fuzhong Pan, Xi Shen, Caimin Wan, Shengping You
  • Publication number: 20120077087
    Abstract: The present invention relates to negative-electrode active material for rechargeable lithium battery comprising: a core comprising material capable of doping and dedoping lithium; and, a carbon layer formed on the surface of the core, wherein the carbon layer has a three dimensional porous structure comprising nanopores regularly ordered on the carbon layer with a pore wall of specific thickness placed therebetween.
    Type: Application
    Filed: September 22, 2011
    Publication date: March 29, 2012
    Applicants: UNIST ACADEMY-INDUSTRY RESEARCH CORPORATION, LG CHEM, LTD.
    Inventors: Jaephil Cho, Jae-Bum Choo, Byung-Hee Han, Hyun-Jung Kim, Ki-Tae Kim, Je-Young Kim
  • Publication number: 20120070725
    Abstract: Lithium ion battery positive electrode material are described that comprise an active composition comprising lithium metal oxide coated with an inorganic coating composition wherein the coating composition comprises a metal chloride, metal bromide, metal iodide, or combinations thereof. Desirable performance is observed for these coated materials. In particular, the non-fluoride metal halide coatings are useful for stabilizing lithium rich metal oxides.
    Type: Application
    Filed: September 22, 2010
    Publication date: March 22, 2012
    Inventors: Subramanian Venkatachalam, Deepak Kumaar Kandasamy Karthikeyan, Herman A. Lopez
  • Publication number: 20120052390
    Abstract: An electrode composite material includes an individual electrode active material particle and a protective film coated on a surface of the particle. A composition of the protective film is at least one of AlxMyPO4 and AlxMy(PO3)3, M represents at least one chemical element selected from the group consisting of Cr, Zn, Mg, Zr, Mo, V, Nb, and Ta, and a valence of M is represented by k, wherein 0<x<1, 0<y<1, and 3x+ky=3.
    Type: Application
    Filed: February 28, 2011
    Publication date: March 1, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XIANG-MING HE, JIAN-JUN LI, LI-CHUN ZHANG, JIAN-GUO REN, JIAN GAO, WEI-HUA PU
  • Publication number: 20120052398
    Abstract: Electrochemical energy storage devices having a metal anode and a solid-state, metal-ion exchange membrane and are characterized by an interfacial layer between the anode and the membrane, wherein the interfacial layer is a solid solution comprising the metal anode and a metallic interfacial conducting agent.
    Type: Application
    Filed: August 24, 2010
    Publication date: March 1, 2012
    Applicant: BATTELLE MEMORIAL INSTITUTE
    Inventors: John P. Lemmon, Xiaochuan Lu, Guanguang Xia, Zhenguo Yang
  • Patent number: 8124281
    Abstract: A hydrogen storage alloy used in a hydrogen storage alloy electrode 11 has a crystalline structure having a mixed phase made up of at least an A2B7 type structure and an A5B19 type structure, and a surface layer of hydrogen storage alloy particles is so formed as to have a nickel content ratio greater than that of a bulk. The ratio (X/Y) of the nickel content ratio X (% by mass) of the surface layer to the nickel content ratio Y (% by mass) of the bulk is greater than 1.0 but no more than 1.2 (1.0<X/Y?1.2). The gradient between the content ratio of the nickel in the surface layer of the hydrogen storage alloy particles and the content ratio of the nickel in the bulk is alleviated and a hydrogen storage alloy electrode with high output characteristics is obtained.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: February 28, 2012
    Assignee: SANYO Electric Co., Ltd.
    Inventors: Shuhei Yoshida, Kazuaki Tamura, Yoshinobu Katayama, Teruhito Nagae, Masao Takee
  • Patent number: 8124275
    Abstract: To smoothly deliver a thermal energy required in an active site of a catalyst carried on a carrier. A method of manufacturing a catalyst carrier of the present invention includes the steps of: forming a mixed thin film in which at least metal and ceramics are mixed on a metal base, by spraying aerosol, with metal powders and ceramic powders mixed therein, on the metal base; and making the mixed thin film porous, by dissolving the metal of the mixed thin film into acid or alkaline solution to remove this metal.
    Type: Grant
    Filed: January 28, 2009
    Date of Patent: February 28, 2012
    Assignee: Hitachi Cable, Ltd.
    Inventors: Mineo Washima, Kenji Shibata, Fumihito Oka
  • Publication number: 20120045693
    Abstract: A negative active material for a rechargeable lithium battery, a method of manufacturing the same, and a rechargeable lithium battery including the same. The negative active material includes secondary particles including assembled primary particles of a compound represented by the following Chemical Formula 1, and has a specific surface area at 2 m2/g or 5 m2/g or between 2 m2/g and 5 m2/g. Li4?x-yMyTi5+x-zM?zO12 ??[Chemical Formula 1] wherein, x is at 0 or 1 or between 0 and 1, y is at 0 or 1 or between 0 and 1, z is at 0 or 1 or between 0 and 1, M is La, Tb, Gd, Ce, Pr, Nd, Sm, Ba, Sr, Ca, Mg, or a combination thereof, and M? is V, Cr, Nb, Fe, Ni, Co, Mn, W, Al, Ga, Cu, Mo, P, or a combination thereof.
    Type: Application
    Filed: December 14, 2010
    Publication date: February 23, 2012
    Inventor: Ji-Yong Eom
  • Publication number: 20120045694
    Abstract: A cathode, a method of preparing the same, and a lithium battery including the cathode. The cathode includes: a current collector; a first cathode active material layer disposed on the current collector; and a second cathode active material layer disposed on the first cathode active material layer, wherein the first cathode active material layer comprises a lithium transition metal oxide having a layered structure, and the second cathode active material layer comprises a lithium transition metal oxide having a spinel structure and an average working potential of 4.5 V or more.
    Type: Application
    Filed: March 17, 2011
    Publication date: February 23, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Kyu-sung PARK, Seung-sik Hwang
  • Patent number: 8114309
    Abstract: A lithium-manganese composite oxide for a lithium ion battery having a good cycle property at high-temperature and battery property of high capacity is provided. A spinel type lithium-manganese composite oxide for a lithium ion battery represented by a general formula: Li1+xMn2-yMyO4 (wherein M is one or more elements selected from Al, Mg, Si, Ca, Ti, Cu, Ba, W and Pb, and, ?0.1?x?0.2, and 0.06?y?0.3), and when D10, D50 and D90 are defined as a particle size at which point the cumulative frequency of volume reaches 10%, 50% and 90% respectively, d10 is not less than 2 ?m and not more than 5 ?M, d50 is not less than 6 ?m and not more than 9 ?m, and d90 is not less than 12 ?m and not more than 15 ?M, and BET specific surface area thereof is greater than 1.0 m2/g and not more than 2.0 m2/g, and the tap density thereof is not less than 0.5 g/cm3 and less than 1.0 g/cm3.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: February 14, 2012
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Yoshio Kajiya, Hirohito Sato, Ryuichi Nagase
  • Publication number: 20120034525
    Abstract: Disclosed is a positive electrode active material that provides an improved capacity density. Specifically disclosed is a positive electrode active material for a lithium ion battery with a layered structure represented by Lix(NiyM1-y)Oz (wherein M represents at least one element selected from a group consisting of Mn, Co, Mg, Al, Ti, Cr, Fe, Cu, and Zr; x is in the range from 0.9 to 1.2; y is in the range from 0.3 to 0.95; and z is in the range from 1.8 to 2.4), wherein, when a value obtained by dividing an average of peak intensities observed between 1420 and 1450 cm?1 and between 1470 and 1500 cm?1 by the maximum intensity of a peak appearing between 520 and 620 cm?1 in an infrared absorption spectrum obtained by FT-IR is represented by A, A satisfies the following relational formula: 0.20y?0.05?A?0.53y?0.06.
    Type: Application
    Filed: March 3, 2010
    Publication date: February 9, 2012
    Applicant: JX NIPPON MINING & METALS CORPORATION
    Inventors: Hirohito Satoh, Yoshio Kajiya, Ryuichi Nagase
  • Publication number: 20120028119
    Abstract: A cathode composite material includes a cathode active material particle having a surface and a continuous aluminum phosphate layer coated on the surface of the cathode active material particle. A material of the cathode active material particle is layered type lithium nickel manganese oxide. The present disclosure also relates to a lithium ion battery and a method for making the cathode composite material.
    Type: Application
    Filed: May 13, 2011
    Publication date: February 2, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XIAN-KUN HUANG, XIANG-MING HE, CHANG-YIN JIANG, DAN WANG, JIAN GAO, JIAN-JUN LI
  • Publication number: 20120028121
    Abstract: A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.
    Type: Application
    Filed: August 25, 2011
    Publication date: February 2, 2012
    Applicants: UNIVERSITE DE MONTREAL, PHOSTECH LITHIUM INC., CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Laurent GAUTHIER, Michel Gauthier, Donald Lavoie, Christophe Michot, Nathalie Ravet
  • Publication number: 20120028113
    Abstract: An anode composite material includes an anode active material particle having a surface and a continuous aluminum phosphate layer. The continuous aluminum phosphate layer is coated on the surface of the anode active material particle. The present disclosure also relates to a lithium ion battery that includes the cathode composite material.
    Type: Application
    Filed: May 16, 2011
    Publication date: February 2, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITY
    Inventors: XIAN-KUN HUANG, XIANG-MING HE, CHANG-YIN JIANG, DAN WANG, JIAN GAO, JIAN-JUN LI
  • Patent number: 8105719
    Abstract: Primary and secondary Li-ion and lithium-metal based electrochemical cell systems. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plasticized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.
    Type: Grant
    Filed: February 21, 2011
    Date of Patent: January 31, 2012
    Assignee: UChicago Argonne, LLC
    Inventors: Ilias Belharouak, Khalil Amine
  • Publication number: 20120021284
    Abstract: Disclosed is a positive electrode and a lithium battery including the positive electrode. The positive electrode includes a current collector, a first layer irreversibly deintercalating lithium ions, and a second layer allowing reversible intercalation and deintercalation of lithium ions. In one embodiment, the first layer further comprises a first sublayer and a second sublayer, in which the first sublayer is interposed between the current collector and the second sublayer. The first sublayer comprises a first active material represented by Formula 1 Li2Mo1-nR1nO3, and the second sublayer comprises a second active material represented by Formula 2 Li2Ni1-mR2mO2. In Formula 1, 0?n?1; and R1 is selected from the group consisting of manganese (Mn), iron (Fe), cobalt (Co), copper (Cu), zinc (Zn), magnesium (Mg), nickel (Ni), and combinations of at least two of the foregoing elements.
    Type: Application
    Filed: May 5, 2011
    Publication date: January 26, 2012
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: SOON-REWL LEE, ICK-KYU CHOI, YOUNG-KI KIM, JAY-HYOK SONG, YOUNG-HUN LEE, YU-MI SONG, YOON-CHANG KIM
  • Publication number: 20120015230
    Abstract: Disclosed is a mixed metal oxide comprising Na, M1, and M2, where M1 represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba; and M2 represents at least one element selected from the group consisting of Mn, Fe, Co, and Ni, wherein the molar ratio of Na:M1:M2 is a:b:1, where a is a value within the range of not less than 0.5 and less than 1; b is a value within the range of more than 0 and not more than 0.5; and “a+b” is a value within the range of more than 0.5 and not more than 1. An electrode having an active material containing the mixed metal oxide is also disclosed. Further disclosed is an electrode containing the electrode active material as well as a sodium secondary battery comprising the electrode as a positive electrode.
    Type: Application
    Filed: March 10, 2010
    Publication date: January 19, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Satoru Kuze, Masami Makidera, Taketsugu Yamamoto
  • Publication number: 20120015231
    Abstract: A lithium mixed metal oxide, shown by the following formula (A): Lix(Mn1-y-z-dNiyFezMd)O2 (A) wherein M is one or more elements selected from the group consisting of Al, Mg, Ti, Ca, Cu, Zn, Co, Cr, Mo, Si, Sn, Nb and V; x is 0.9 or more and 1.3 or less; y is 0.3 or more and 0.7 or less; z is more than 0 and 0.1 or less, and d is more than 0 and 0.1 or less. A positive electrode active material, including the lithium mixed metal oxide. A positive electrode, including the positive electrode active material. A nonaqueous electrolyte secondary battery, including the positive electrode.
    Type: Application
    Filed: March 18, 2010
    Publication date: January 19, 2012
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Takamori, Cedric Pitteloud
  • Patent number: 8080340
    Abstract: An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula x{zLi2MnO3•(1-z)LiM?O2}.(1-x)LiMn2?yMyO4 for 0<x<1; 0?y?0.5; and 0<z<1, comprised of layered zLi2MnO3.(1-z)LiM?O2 and spinel LiMn2?yMyO4 components, physically mixed or blended with one another or separated from one another in a compartmentalized electrode, in which M is one or more metal ions, and in which M? is selected from one or more first-row transition metal ions, The electrode is activated by removing lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: December 20, 2011
    Assignee: UChicago Argonne, LLC
    Inventors: Michael M. Thackeray, Sun-Ho Kang, Christopher S. Johnson
  • Publication number: 20110305947
    Abstract: Disclosed are a positive active material for a lithium rechargeable battery and a lithium rechargeable battery using the same, and the positive active material is represented by the following Chemical Formula 1, and has an effective magnetic moment of about 2.4 ?B/mol or greater at a temperature of more than or equal to a Curie temperature. Chemical Formula 1: LiMeO2. In Chemical Formula 1, Me is NixCOyMnzM?k, 0.45?x?0.65, 0.15?y?0.25, 0.15?z?0.35, 0.9?a?1.2, 0?k?0.1, x+y+z+k=1, and M? is Al, Mg, Ti, Zr, or a combination thereof. The positive active material may have an a-axis lattice constant of the positive active material of about 2.865 ? or greater, and may have a c-axis lattice constant of the positive active material of about 14.2069 ? or greater. A mole ratio of Li to Me of Chemical Formula 1 may range from about 0.9 to about 1.2.
    Type: Application
    Filed: June 13, 2011
    Publication date: December 15, 2011
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Yu-Mi SONG, Do-Hyung PARK, Seon-Young KWON, Ji-Hyun KIM, Min-Han KIM, Kyoung-Hyun KIM
  • Publication number: 20110287316
    Abstract: The invention relates generally to carbon nano-tube composites and particularly to carbon nano-tube compositions for electrochemical energy storage devices and a method for making the same.
    Type: Application
    Filed: May 23, 2011
    Publication date: November 24, 2011
    Applicant: ADA TECHNOLOGIES, INC.
    Inventors: Wen Lu, Joshua Buettner-Garrett, Michael Krysiak
  • Publication number: 20110281173
    Abstract: Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode.
    Type: Application
    Filed: November 6, 2009
    Publication date: November 17, 2011
    Applicant: SEEO, INC.
    Inventors: Mohit Singh, Ilan Gur, Hany Basam Eitouni, Nitash Pervez Balsara
  • Publication number: 20110274973
    Abstract: The positive active material for a rechargeable lithium battery includes a composite material of a microporous carbon-based material and a lithium composite compound and a carbon layer on the surface of the composite material.
    Type: Application
    Filed: January 24, 2011
    Publication date: November 10, 2011
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Kyeu-Yoon SHEEM, Sumihito ISHIDA, Bok-Hyun KA
  • Publication number: 20110274972
    Abstract: The present invention aims to increase the discharge capacity and to improve the cycle life performance in a nickel-metal hydride rechargeable battery using a La—Mg—Ni based hydrogen-absorbing alloy as an active material of a negative electrode. The present invention provides a hydrogen-absorbing alloy represented by the general formula (1): M1uMgvCawM2xNiyM3z . . . (1) (wherein, M1 is one or more elements selected from rare earth elements; M2 is one or more elements selected from the group consisting of Group 3A elements; Group 4A elements, Group 5A elements, and Pd (excluding rare earth elements); M3 is one or more elements selected from the group consisting of Group 6A elements, Group 7A elements, Group 8 elements, Group 1B elements, Group 2B elements, and Group 3B elements (excluding Ni and Pd); u, v, w, x, y, and z are numbers satisfying, u+v+w+x+y+z=100, 3.4?v?5.9, 0.8?w?3.1, 0?(x+z)?5, and 3.2?(y+z)/(u+v+w+x)?3.
    Type: Application
    Filed: January 20, 2010
    Publication date: November 10, 2011
    Applicant: GS Yuasa International Ltd.
    Inventors: Manabu Kanemoto, Tetsuya Ozaki, Masaharu Watada
  • Patent number: 8053115
    Abstract: It is an object of the present invention to provide an active material for lithium ion battery having an excellent discharge capacity in the potential flat part and a high-performance and long-life lithium ion battery, and particularly to provide a technology of improving voltage flatness. The present invention provides an active material for lithium ion battery represented by a composition formula: Li[Li(1-2x)/3MgxTi(5-x)/3]O4 (0<x<1/2) in which a part of the element of lithium titanate is substituted with Mg, and a lithium ion battery using this active material as a negative electrode active material.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: November 8, 2011
    Assignee: GS Yuasa International Ltd.
    Inventors: Daisuke Endo, Tokuo Inamasu, Toshiyuki Nukuda, Yoshihiro Katayama
  • Patent number: 8053109
    Abstract: A non-aqueous electrolyte secondary battery has a high initial capacity and excels in cycle characteristics and storage characteristics even when charged until the potential of the positive electrode active material exceeds as high as 4.3V versus lithium. The non-aqueous electrolyte of the secondary battery contains both 1,3-dioxane and a sulfonic acid ester compound.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: November 8, 2011
    Assignees: Sanyo Electric Co., Ltd., Ube Industries, Ltd.
    Inventors: Masato Iwanaga, Noriko Yamashita, Koji Abe, Kazuhiro Miyoshi
  • Publication number: 20110269018
    Abstract: An electrode for an electrochemical device of the present invention includes an electrode mixture layer that includes a lithium-containing composite oxide expressed by the general composition formula (1): Li1+xMO2 as an active material, where x satisfies ?0.3?x?0.3 and M represents an element group including Ni, Mn, and Mg. The relationships 70?a?97, 0.5<b<30, 0.5<c<30, ?10<b?c<10, and ?8?(b?c)/c?8 are established, where a, b, and c represent the ratios of the number of elements of Ni, Mn, and Mg in the element group M to the total number of elements in the element group M, respectively, in units of mol %. The Ni has an average valence of 2.5 to 3.2, the Mn has an average valence of 3.5 to 4.2, and the Mg has an average valence of 1.8 to 2.2.
    Type: Application
    Filed: June 17, 2010
    Publication date: November 3, 2011
    Inventors: Satoshi Kono, Mitsuhiro Kishimi, Masayuki Oya
  • Publication number: 20110262811
    Abstract: Provided is a non-aqueous electrolyte secondary battery having excellent input/output characteristics and excellent adherence between its electrode material mixture layer and current collector. Disclosed is an electrode for a non-aqueous electrolyte secondary battery, having a current collector and an electrode material mixture layer attached to a surface of the current collector, in which the electrode material mixture layer includes a metal oxide-containing electrode active material and a binder; the oil absorption capacity of the electrode active material is 25 g or more and 200 g or less, per 100 g of the electrode active material; and when the thickness of the electrode material mixture layer is designated as T, an amount W1 of the binder in a region 0.1 T thick from the surface side of the electrode material mixture layer, and an amount W2 of the binder in a region 0.1 T thick from the current collector side of the electrode material mixture layer, satisfy 0.9?W1/W2?1.1.
    Type: Application
    Filed: July 6, 2010
    Publication date: October 27, 2011
    Inventors: Masahiro Kinoshita, Tetsuo Nanno
  • Patent number: 8034485
    Abstract: Provided are negative electrode compositions for lithium-ion electrochemical cells that include metal oxides and polymeric binders. Also provided are electrochemical cells and battery packs that include electrodes made with these compositions.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: October 11, 2011
    Assignee: 3M Innovative Properties Company
    Inventors: Jeffrey R. Dahn, Jing Li, Mark N. Obrovac
  • Patent number: 8029930
    Abstract: A positive electrode material for a lithium secondary battery, which is high in safety, high in capacity, excellent in cycle performance, and high in charge/discharge efficiency, is provided. The positive electrode material for a lithium secondary battery is a powder containing a Li—Ni—Co—O or Li—Ni—Co—Ba—O system component as a main component and having an amorphous phase of an oxide mixed in each of particles or formed at the surface of the particle.
    Type: Grant
    Filed: November 17, 2003
    Date of Patent: October 4, 2011
    Assignee: Kawatetsu Mining Co., Ltd.
    Inventors: Yoshiaki Hamano, Hidefumi Konnai
  • Patent number: 8026000
    Abstract: A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: September 27, 2011
    Assignees: Sanyo Electric Co., Ltd., UBE Industries, Ltd.
    Inventors: Masato Iwanaga, Yukihiro Oki, Koji Abe, Kazuhiro Miyoshi
  • Patent number: 8021787
    Abstract: The preservation performance of a nonaqueous electrolyte secondary cell charged to high potential is improved while the initial capacity and the cycle property of the cell are also improved. The nonaqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material containing lithium cobalt compound oxide and lithium manganese nickel compound oxide having a layer structure, the lithium cobalt compound oxide having at least zirconium and magnesium added in LiCoO2; a negative electrode having a negative electrode active material; and a nonaqueous electrolyte having a nonaqueous solvent and an electrolytic salt. The potential of the positive electrode is more than 4.3 V and 5.1 V or less based on lithium. The nonaqueous electrolyte contains vinylene carbonate as the nonaqueous solvent and, as the electrolytic salt, at least one of lithium bis(pentafluoroethane sulfonyl)imide and lithium bis(trifluoromethane sulfonyl)imide at 0.1 M or more and 0.
    Type: Grant
    Filed: May 30, 2007
    Date of Patent: September 20, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Masato Iwanaga, Kentaro Takahashi, Yukihiro Oki, Yoshihiko Ikeda, Akira Kinoshita, Nobumichi Nishida
  • Patent number: 8021785
    Abstract: Provided are a cathode active material with high safety, with high discharge capacity even at high operating voltage, and with excellent cyclic charge and discharge properties, its production method and a non-aqueous electrolyte secondary battery containing the cathode active material. The cathode active material for a non-aqueous electrolyte secondary battery comprises a surface-modified lithium-containing composite oxide particle, wherein the particle is a lithium-containing composite oxide particle represented by the general formula LipNxO2 (wherein N?NiyM1-y-zLz, M contains at least one element selected from Co and Mn, L is an element selected from alkaline earth metal elements, aluminum and transition metal elements other than Ni, Co and Mn, 0.9?p?1.1, 0.9?x<1.1, 0.2?y?0.9, and 0?z?0.3), and a surface layer of the particle contains aluminum, said surface layer within 5 nm having an aluminum content of at least 0.8 as an atomic ratio to a total of Ni and the element M.
    Type: Grant
    Filed: April 10, 2008
    Date of Patent: September 20, 2011
    Assignee: AGC Seimi Chemical Co., Ltd.
    Inventors: Yukimitsu Wakasugi, Takeshi Kawasato, Yukiko Amagasaki, Nozomi Honda
  • Patent number: 8021786
    Abstract: A non-aqueous electrolyte secondary cell superior in resistance against continuous charging at high potential is provided. The non-aqueous electrolyte secondary cell includes: a positive electrode having lithium phosphate and a positive electrode active material comprising lithium cobalt oxide containing at least one selected from Mg, Al, Ti, and Zr; and a separator having pores having an average diameter of 0.05 to 0.2 ?m.
    Type: Grant
    Filed: March 31, 2008
    Date of Patent: September 20, 2011
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Atsushi Kaiduka, Masato Iwanaga, Yukihiro Oki