Alkaline Earth Metal Or Magnesium (mg) Component Is Active Material Patents (Class 429/231.6)
  • Patent number: 8415058
    Abstract: A nonaqueous secondary battery having a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode contains, as an active material, a lithium-containing transition metal oxide containing a metal element selected from the group consisting of Mg, Ti, Zr, Ge, Nb, Al and Sn, the positive electrode mixture layer has a density of 3.
    Type: Grant
    Filed: June 12, 2012
    Date of Patent: April 9, 2013
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Hideo Sakata, Fusaji Kita, Kumiko Ishizuka
  • Patent number: 8409752
    Abstract: An active material for a battery includes an electrochemically reversibly oxidizable and reducible base material selected from the group consisting of a metal, a lithium-containing alloy, a sulfur-based compound, and a compound that can reversibly form a lithium-containing compound by a reaction with lithium ions and a surface-treatment layer formed on the base material and comprising a compound of the formula MXOk, wherein M is at least one element selected from the group consisting of an alkali metal, an alkaline earth metal, a group 13 element, a group 14 element, a transition metal, and a rare-earth element, X is an element that is capable of forming a double bond with oxygen, k is a numerical value in the range of 2 to 4.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: April 2, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jae-Phil Cho, Geun-Bae Kim, Sang-Moon Hwang, Yong-Chul Park, Won-Il Jung
  • Patent number: 8404387
    Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode contains active material particles and a coating material. The active material particles are represented by any one of the following formulae (1) to (3) and have an average particle diameter of 0.1 to 10 ?m. The coating material comprises at least particles having an average particle diameter of 60 nm or less or layers having an average thickness of 60 nm or less. The particles or the layers contain at least one element selected from the group consisting of Mg, Ti, Zr, Ba, B and C.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: March 26, 2013
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Norio Takami, Hiroki Inagaki, Keigo Hoshina
  • Publication number: 20130071747
    Abstract: The disclosure relates to positive electrode material used for Li-ion batteries, a precursor and process used for preparing such materials, and Li-ion battery using such material in its positive electrode. The disclosure describes a higher density LiCoO2 positive electrode material for lithium secondary batteries, with a specific surface area (BET) below 0.2 m2/g, and a volumetric median particle size (d50) of more than 15 ?m. This product has improved specific capacity and rate-capability. Other embodiments of the disclosure are an aggregated Co(OH)2, which is used as a precursor, the electrode mix and the battery manufactured using above-mentioned LiCoO2.
    Type: Application
    Filed: November 14, 2012
    Publication date: March 21, 2013
    Applicant: UMICORE
    Inventor: Umicore
  • Publication number: 20130071745
    Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery utilizing the same. The electrode active material includes a core capable of intercalating and deintercalating lithium and a coating layer formed on at least a portion of a surface of the core, wherein the coating layer includes a composite metal halide having a spinel structure.
    Type: Application
    Filed: July 10, 2012
    Publication date: March 21, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Jun-young MUN, Won-chang Choi, Jin-hwan Park
  • Publication number: 20130049759
    Abstract: An electrochemical test cell, containing an anode comprising a metal as an active component; a cathode comprising a porous chemically inert tube containing an active material compatible with the metal of the anode; and an electrolyte; wherein the only metal in contact with the electrolyte is the metal of the anode, is provided. This test cell is useful in a method to evaluate various combinations of materials for suitability as a combination for preparation of a battery.
    Type: Application
    Filed: August 24, 2011
    Publication date: February 28, 2013
    Applicant: Toyota Motor Engineering & Manufacturing NA
    Inventors: Hee Soo KIM, John Muldoon
  • Patent number: 8377592
    Abstract: An negative active material for a rechargeable lithium battery includes a nano-composite including a Si phase, a SiO2 phase, and a metal oxide phase of formulation MyO, where M is a metal with an oxidation number x, a free energy of oxygen-bond formation ranging from ?900 kJ/mol to ?2000 kJ/mol, x, and x·y=2. The negative active material for a rechargeable lithium battery according to the present invention can improve initial capacity, initial efficiency, and cycle-life characteristics by suppressing its initial irreversible reaction.
    Type: Grant
    Filed: September 17, 2008
    Date of Patent: February 19, 2013
    Assignees: Samsung SDI Co., Ltd., Seoul National University Industry Foundation
    Inventors: Goo-Jin Jeong, Sang-Min Lee, Wan-Uk Choi, Hun-Joon Sohn
  • Publication number: 20130034770
    Abstract: The present invention is directed toward a laminated electrode and porous separator film combination including a solid electrolyte salt within the porous separator film, the combination comprising layer of powdered cathode material adhering to a surface of a separator film with a solid electrolyte therebetween; the separator film comprising 50% to 95% by weight of electrically non-conductive ceramic fibers having a coating of magnesium oxide on the surface of the fibers in an amount in the range of 5% to 50% by weight; wherein the ceramic fibers comprise Al2O3, AlSiO2, BN, AlN, or a mixture of two or more of the foregoing; and the magnesium oxide coating interconnects the ceramic fibers providing a porous network of magnesium oxide-coated fibers having a porosity of not less than 50% by volume; the pores of the network containing a solid electrolyte salt in an amount of up to 95% by volume based on pore volume of the network.
    Type: Application
    Filed: October 3, 2012
    Publication date: February 7, 2013
    Inventor: Thomas D. Kaun
  • Publication number: 20130029225
    Abstract: A secondary battery includes: a cathode including an active material; an anode; and an electrolytic solution. The active material has a composition represented by Formula (1) described below. A median diameter (D90) of the active material is from about 10.5 micrometers to about 60 micrometers both inclusive, the median diameter (D90) being measured by a laser diffraction method. A half bandwidth (2?) of a diffraction peak corresponding to a (020) crystal plane of the active material is from about 0.15 degrees to about 0.24 degrees both inclusive, the half bandwidth (2?) being measured by an X-ray diffraction method. LiaMnbFecMdPO4??(1) where M represents one or more of Mg, Ni, Co, Al, W, Nb, Ti, Si, Cr, Cu, and Zn; and 0<a?2, 0<b<1, 0<c<1, 0?d<1, and b+c+d=1 are established.
    Type: Application
    Filed: July 25, 2012
    Publication date: January 31, 2013
    Applicant: SONY CORPORATION
    Inventors: Takaaki Matsui, Tadashi Matsushita, Takehiko Ishii
  • Publication number: 20130029224
    Abstract: An electrochemical generator comprising a first type of electrochemical cell, a so-called <<high energy>> cell and a second type of electrochemical cell a so-called <<safety>> cell is provided.
    Type: Application
    Filed: January 12, 2011
    Publication date: January 31, 2013
    Applicant: Commissariat a l'energie atomique et aux energies alternatives
    Inventors: Florence Fusalba, Sébastien Martinet
  • Publication number: 20130022872
    Abstract: Disclosed herein is a cathode active material including a lithium manganese oxide, in which the lithium manganese oxide has a spinel structure with a predetermined constitutional composition represented by Formula 1 described in the detailed description, wherein a conductive material is applied to the surface of lithium manganese oxide particles, so as to exhibit charge-discharge properties in the range of 2.5 to 3.5V as well as in the 4V region.
    Type: Application
    Filed: February 16, 2012
    Publication date: January 24, 2013
    Applicant: LG CHEM, LTD.
    Inventors: Hyun Kuk Noh, Sin Kyu Kim, Geun-Chang Chung, Song-Taek Oh, Sanguck Lee, Jong Chan Kim
  • Publication number: 20130017445
    Abstract: A biodegradable battery is provided. The battery includes an anode comprising a material including an inner surface and an outer surface, wherein electrochemical oxidation of the anode material results in the formation of a reaction product that is substantially non-toxic and a cathode comprising a material including an inner surface and an outer surface, the inner surface of the cathode being in direct physical contact with the inner surface of the anode, wherein electrochemical reduction of the cathode material results in the formation of a reaction product that is substantially non-toxic, and wherein the cathode material presents a larger standard reduction potential than the anode material.
    Type: Application
    Filed: July 15, 2011
    Publication date: January 17, 2013
    Inventors: Gerald N. Hodgkinson, William Powers, Ahmad Robert Hadba
  • Publication number: 20130011741
    Abstract: A non-aqueous electrolyte secondary battery has a positive electrode containing a positive electrode active material containing a lithium-containing oxide active material, a negative electrode, and a non-aqueous electrolyte. The lithium-containing oxide active material is represented by the general formula LiaMgbMO2±? where 0.65?a?1.05, 0<b?0.3, 0???0.3, and M is at least one of manganese and cobalt.
    Type: Application
    Filed: September 13, 2012
    Publication date: January 10, 2013
    Applicant: SANYO ELECTRIC CO., LTD.
    Inventors: Motoharu Saito, Sho Tsuruta, Masahisa Fujimoto
  • Patent number: 8349492
    Abstract: The negative electrode for a rechargeable lithium battery includes a current collector and a negative active material layer disposed on the current collector. The negative active material layer includes a metal-based negative active material and sheet-shaped graphite and has porosity of 20 to 80 volume %. The negative electrode for a rechargeable lithium battery can improve cell characteristics by inhibiting volume change and stress due to active material particle bombardment during charge and discharge, and by decreasing electrode resistance.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: January 8, 2013
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Sang-Min Lee, Goo-Jin Jeong, Min-Seok Sung, Yong-Mook Kang, Wan-Uk Choi, Sung-Soo Kim
  • Publication number: 20130004846
    Abstract: A negative active material, a method of preparing the same, and a lithium battery including the negative active material are disclosed. The negative active material includes a silicon-based nanocore and a first amorphous carbonaceous coating layer that is formed of carbonized organic material and that is uniformly and continuously formed on a surface of the silicon-based nanocore, whereby irreversible capacity losses due to volumetric expansion/contraction caused when a lithium battery is charged and discharged are compensated and cycle lifetime characteristics are enhanced.
    Type: Application
    Filed: May 4, 2012
    Publication date: January 3, 2013
    Applicant: Samsung SDI Co., Ltd.
    Inventors: Beom-Kwon Kim, Jae-Myung Kim, So-Ra Lee, Chang-Su Shin, Ui-Song Do
  • Publication number: 20130004852
    Abstract: Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
    Type: Application
    Filed: September 13, 2012
    Publication date: January 3, 2013
    Applicant: POLYPLUS BATTERY COMPANY
    Inventors: Steven J. Visco, Bruce D. Katz, Yevgeniy S. Nimon, Lutgard C. De Jonghe
  • Publication number: 20120326500
    Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material contains, as constituent elements, Si, O, and at least one element Ml selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio x (O/Si) of O to Si is 0.5?x?1.8.
    Type: Application
    Filed: June 19, 2012
    Publication date: December 27, 2012
    Applicant: SONY CORPORATION
    Inventors: Takakazu Hirose, Kenichi Kawase, Toshio Nishi, Isao Koizumi
  • Publication number: 20120328915
    Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material includes a core portion capable of occluding and releasing lithium ions, and a covering portion arranged on at least part of a surface of the core portion, in which the covering portion contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio y (O/Si) of O to Si is 0.5?y?1.8.
    Type: Application
    Filed: June 18, 2012
    Publication date: December 27, 2012
    Applicant: SONY CORPORATION
    Inventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Isao Koizumi, Toshio Nishi
  • Publication number: 20120328945
    Abstract: A lithium ion secondary battery is provided with a positive electrode, a negative electrode containing an active material, and an electrolytic solution, wherein the active material includes a core portion capable of occluding and releasing lithium ions, an amorphous or low-crystalline coating portion disposed on at least a part of the surface of the core portion, and a fibrous carbon portion disposed on at least a part of the surface of the coating portion, and the coating portion contains Si and O as constituent elements, while the atomic ratio y (O/Si) of O relative to Si satisfies 0.5?y?1.8.
    Type: Application
    Filed: June 19, 2012
    Publication date: December 27, 2012
    Applicant: SONY CORPORATION
    Inventors: Takakazu Hirose, Takashi Fujinaga, Isao Koizumi, Norihiro Shimoi, Kenichi Kawase
  • Publication number: 20120328936
    Abstract: A battery includes a cathode, an anode, and an aqueous electrolyte disposed between the cathode and the anode and including a cation A. At least one of the cathode and the anode includes an electrode material having an open framework crystal structure into which the cation A is reversibly inserted during operation of the battery. The battery has a reference specific capacity when cycled at a reference rate, and at least 75% of the reference specific capacity is retained when the battery is cycled at 10 times the reference rate.
    Type: Application
    Filed: May 29, 2012
    Publication date: December 27, 2012
    Inventors: Colin Wessells, Robert Huggins, Yi Cui, Mauro Pasta
  • Patent number: 8323816
    Abstract: Electrochemical cells having molten electrodes comprising an alkaline earth metal provide receipt and delivery of power by transporting atoms of the alkaline earth metal between electrode environments of disparate alkaline earth metal chemical potentials.
    Type: Grant
    Filed: July 20, 2009
    Date of Patent: December 4, 2012
    Assignee: Massachusetts Institute of Technology
    Inventors: David Bradwell, Donald R. Sadoway
  • Publication number: 20120301788
    Abstract: An electrode active material including a core active material and a coating layer, including a compound represented as the following Formula 1, on a surface of the core active material, a method of preparing the same, an electrode for a lithium secondary battery which includes the same, and a lithium secondary battery using the electrode. Lia-Mb-Nc??[Formula 1] where, M denotes an alkaline earth metal, a/(a+b+c) is in a range of about 0.10 to about 0.40, b/(a+b+c) is in a range of about 0.20 to about 0.50, and c/(a+b+c) is in a range of about 0.20 to about 0.50.
    Type: Application
    Filed: September 22, 2011
    Publication date: November 29, 2012
    Inventors: Jae-Hyuk Kim, Sung-Hwan Moon, Hee-Young Chu, Myung-Hwan Jeong, Chang-Ui Jeong, Yury Matulevich, Jong-Seo Choi
  • Publication number: 20120301786
    Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode contains a lithium composite oxide. The negative electrode contains a material including at least one of silicon Si and tin Sn as a constituent element. The lithium composite oxide includes lithium Li having a composition ratio a, a first element having a composition ratio b, and a second element having a composition ratio c as a constituent element. The first element including two kinds or more selected from among manganese Mn, nickel Ni, and cobalt Co, and including at least manganese. The second element including at least one kind selected from among aluminum Al, titanium Ti, magnesium Mg, and boron B. The composition ratios a to c satisfy the relationships of 1.1<a<1.3, 0.7<b+c<1.1, 0<c<0.1, and a>b+c.
    Type: Application
    Filed: December 22, 2011
    Publication date: November 29, 2012
    Applicant: SONY CORPORATION
    Inventors: Akira Takamuku, Kazuaki Endoh, Masaharu Senoue, Guohua Li, Yosuke Hosoya, Kenichi Kawase
  • Patent number: 8318354
    Abstract: An electrochemical device, having an anode containing magnesium; a cathode stable to a voltage of at least 3.2 V relative to a magnesium reference; and an electrolyte containing an electrochemically active magnesium salt obtained by mixing an organic magnesium compound with an aluminum compound in an ether solvent and separation of the electrochemically active salt from the reaction mixture is provided. The separated electrochemically active salt is stable and safe to handle in comparison to conventional Grignard based electrolyte systems.
    Type: Grant
    Filed: April 27, 2010
    Date of Patent: November 27, 2012
    Assignee: Toyota Motor Engineering & Manufacturing North America
    Inventors: John Muldoon, Hee Soo Kim
  • Patent number: 8318349
    Abstract: A negative electrode active material for a nickel-metal hydride battery of the present invention includes a hydrogen storage alloy, the hydrogen storage alloy containing La, Mg, Ni, Co, Al, and element M. The molar ratio y of Ni to the total of La and Mg is 2?y?3, the molar ratio z of Co to the total of La and Mg is 0.25?z?0.75, the molar ratio ? of Al to the total of La and Mg is 0.01???0.05, and the molar ratio x of Mg to the total of La and Mg is 0.01?x?0.5. Element M represents at least one selected from the group consisting of Y and Sn, and the content of element M in the hydrogen storage alloy is 0.4 wt % or less.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: November 27, 2012
    Assignee: Panasonic Corporation
    Inventors: Hideaki Ohyama, Kyoko Nakatsuji, Yoshitaka Dansui
  • Patent number: 8318352
    Abstract: A secondary electrochemical cell is described having (a) a first electrode comprising an active material of the formula LiaCoeFefM1gM2hM3iXY4, (b) a second electrode which is a counter-electrode to said first electrode; and (c) an electrolyte comprising an electrolyte salt, a cyclic ester and a carbonate selected from the group consisting of alkyl carbonates, alkylene carbonates, and mixtures thereof.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: November 27, 2012
    Assignee: Valence Technology, Inc.
    Inventors: M. Yazid Saidi, Haitao Huang, James K. Pugh
  • Publication number: 20120282530
    Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.
    Type: Application
    Filed: July 13, 2012
    Publication date: November 8, 2012
    Applicant: Massachusetts Institute of Technology
    Inventors: Yet-Ming Chiang, William Douglas Moorehead
  • Publication number: 20120282521
    Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery adopting the same. The electrode active material includes a core capable of occluding and emitting lithium; and a surface treatment layer formed on at least a portion of a surface of the core, wherein the surface treatment layer includes a lithium-free oxide having a spinel structure.
    Type: Application
    Filed: May 1, 2012
    Publication date: November 8, 2012
    Applicant: Samsung Electronics Co. Ltd.
    Inventors: Won-chang CHOI, Jin-hwan Park
  • Publication number: 20120276444
    Abstract: A magnesium battery includes a first electrode including an active material and a second electrode. An electrolyte is disposed between the first electrode and the second electrode. The electrolyte includes a magnesium compound. The active material includes an inter-metallic compound of magnesium and bismuth.
    Type: Application
    Filed: April 29, 2011
    Publication date: November 1, 2012
    Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventor: Masaki Matsui
  • Patent number: 8298707
    Abstract: A positive active material including a compound expressed by a general formula LimMxM?yM?zO2 (here, M designates at least one kind of element selected from Co, Ni and Mn, M? designates at least one kind of element selected from Al, Cr, V, Fe, Cu, Zn, Sn, Ti, Mg, Sr, B, Ga, In, Si and Ge, and M? designates at least one kind of element selected from Mg, Ca, B and Ga. Further, x is designated by an expression of 0.9?x<1, y is indicated by an expression of 0.001?y?0.5, z is indicated by an expression of 0?z?0.5, and m is indicated by an expression of 0.5?m) and lithium manganese oxide expressed by a general formula LisMn2-tMatO4 (here, the value of s is expressed by 0.9?s, the value of t is located within a range expressed by 0.01?t?0.5, and Ma indicates one or a plurality of elements between Fe, Co, Ni, Cu, Zn, Al, Sn, Cr, V, Ti, Mg, Ca, Sr, B, Ga, In, Si and Ge) are included, so that both a large capacity and the suppression of the rise of temperature of a battery upon overcharging operation are achieved.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: October 30, 2012
    Assignee: Sony Corporation
    Inventors: Takehiko Tanaka, Yosuke Hosoya, Yoshikatsu Yamamoto, Kiyohiko Suzuki, Keizo Koga
  • Publication number: 20120270104
    Abstract: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a first inner and a second outer layer, the second outer layer comprising a fluorine-containing polymer, and the first inner layer consisting of a reaction product of the fluorine-containing polymer and the primary particle surface. An example of this reaction product is LiF, where the lithium originates from the primary particles surface. Also as an example, the fluorine-containing polymer is either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCOdMeO2, wherein M is either one or both of Mg and Ti, with e<0.02 and d+e=1; —Li+aM?1?aO2±bM1kSm with ?0.03?a?0.06, b<0.02, M? being a transition metal compound, consisting of at least 95% of either one or more elements of the group Ni, Mn, Co, Mg and Ti; M1 consisting of either one or more elements of the group Ca, Sr, Y, La, Ce and Zr, with 0?k?0.
    Type: Application
    Filed: October 19, 2010
    Publication date: October 25, 2012
    Inventors: Jens Paulsen, Randy De Palma, HeonPyo Hong, KyuBo Kim
  • Publication number: 20120258362
    Abstract: An electrode active material, a method of preparing the electrode active material, an electrode including the electrode active material, and a lithium secondary battery including the electrode; the electrode active material comprising a core active material; and a coating layer formed on a surface of the core active material, wherein the coating layer comprises a composition including a compound represented by Formula 1 below and a carbonaceous material, or a first coating layer including a carbonaceous material and a second coating layer including the compound represented by Formula 1 below: LixMy(PO4)z, ??Formula 1 where M is selected from the group consisting of alkali metal, alkaline earth metal, a group 13 element, a group 14 element, a transition metal, a rare earth element, and combinations thereof; 1?x?3, 0?y?3, and 1?z?3.
    Type: Application
    Filed: September 23, 2011
    Publication date: October 11, 2012
    Applicant: Samsung Electronics Co. Ltd.
    Inventors: Sang-kook MAH, Gue-sung KIM
  • Publication number: 20120258368
    Abstract: A negative electrode active material, a method of preparing the negative electrode active material and a lithium secondary battery including the negative electrode active material are disclosed. A negative electrode active material includes a lithium titanate, wherein a portion of lithium of the lithium titanate is substituted by at least one selected from the group consisting of Sr, Ba, a mixture thereof and an alloy thereof, and thus a lithium secondary battery including the negative electrode active material may improve high-rate discharge characteristics.
    Type: Application
    Filed: February 2, 2012
    Publication date: October 11, 2012
    Applicant: SAMSUNG SDI CO., LTD.
    Inventors: Jong-Hee LEE, Yong-Mi Yu, Joa-Young Jeong, Jae-Myung Kim
  • Publication number: 20120258370
    Abstract: [Summary] [Assignment] Providing a noble negative-electrode active material including silicon, and a production process for the same. [Solving Means] A negative-electrode active material for non-aqueous-system secondary battery including a silicon phase and a composite oxide phase (a CaSiO3 phase, for instance) is obtained by mixing a silicon oxide (SiO, for instance) with a silicon compound (CaSi2, for instance), which includes silicon and at least one member of elements being selected from the group consisting of Group 2 (or Group 2A) elements in the Periodic Table, to prepare a mixed raw material, and then reacting the mixed raw material. The composite oxide phase demonstrates the advantage of inhibiting electrolytic solutions from decomposing in a smaller amount than does the conventional SiO2 phase.
    Type: Application
    Filed: December 8, 2010
    Publication date: October 11, 2012
    Applicant: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Manabu Miyoshi, Hideaki Ishikawa, Hitotoshi Murase
  • Publication number: 20120251886
    Abstract: A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.
    Type: Application
    Filed: March 30, 2012
    Publication date: October 4, 2012
    Applicant: GEORGIA TECH RESEARCH CORPORATION
    Inventors: Gleb Nikolayevich Yushin, Kara Linn Evanoff, Oleksandr Magazynskyy
  • Patent number: 8277979
    Abstract: An anode composite material includes an anode active material particle having a surface and a continuous aluminum phosphate layer. The continuous aluminum phosphate layer is coated on the surface of the anode active material particle. The present disclosure also relates to a lithium ion battery that includes the cathode composite material.
    Type: Grant
    Filed: May 16, 2011
    Date of Patent: October 2, 2012
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Xian-Kun Huang, Xiang-Ming He, Chang-Yin Jiang, Dan Wang, Jian Gao, Jian-Jun Li
  • Publication number: 20120244440
    Abstract: A rechargeable lithium battery, which includes: a negative electrode including a silicon-based negative active material; a positive electrode (including a positive active material capable of intercalating and deintercalating lithium, and a conductive material including a fiber shaped material and a non-fiber shaped material), wherein a weight per unit area of the positive electrode (which is a loading level (LL) of the positive electrode) is about 20 mg/cm2 to 100 mg/cm2; and a non-aqueous electrolyte.
    Type: Application
    Filed: January 31, 2012
    Publication date: September 27, 2012
    Inventors: Nathan Lee, Ung-Kuk Heo, Seung-Ho Na
  • Publication number: 20120244442
    Abstract: According to one embodiment, a battery active material includes a complex oxide containing Nb and Ti and an element M. In the active material, the molar ratio (M/Ti) of the element M to Ti satisfies the following formula (I): 0<M/Ti?0.5 (I). In the complex oxide containing Nb and Ti, the molar ratio (Nb/Ti) of Nb to Ti satisfies the following formula (II): 0?Nb/Ti?5 (II). The element M is at least one selected from the group consisting of B, Na, Mg, Al, Si, S, P, K, Ca, Mo, W, Cr, Mn, Co, Ni, and Fe.
    Type: Application
    Filed: March 1, 2012
    Publication date: September 27, 2012
    Inventors: Yasuhiro Harada, Norio Takami, Hiroki Inagaki, Yorikazu Yoshida
  • Patent number: 8273481
    Abstract: A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: September 25, 2012
    Assignees: Universitéde Montréal, Centre National de la Recherche Scientifique, Phostech Lithium Inc.
    Inventors: Laurent Gauthier, Michel Gauthier, Donald Lavoie, Christophe Michot, Nathalie Ravet
  • Patent number: 8273478
    Abstract: A rechargeable lithium battery includes an electrolyte including an additive such as an ethylene carbonate-based compound represented by Chemical Formula 1 and a silicon-included compound, and a negative electrode including a negative active material including an active element selected from the group consisting of Si, Sn, Ga, Cd, Al, Pb, Zn, Bi, In, Mg, and Ge. In Chemical formula 1, X and Y are independently selected from the group consisting of hydrogen, a halogen, and a C1 through C5 fluoroalkyl, provided that at least one of X and Y is selected from the group consisting of a halogen and a C1 through C5 fluoroalkyl. The rechargeable lithium battery has a suppressed volume expansion characteristic due to a high-capacity negative active material, and has excellent reliability and cycle-life characteristics.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: September 25, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Jin-Sung Kim, Na-Rae Park, Su-Hee Han, Jin-Hyunk Lim
  • Patent number: 8268486
    Abstract: A positive electrode includes a current collector and a positive electrode active material layer. The positive electrode active material layer includes a positive electrode active material including a core including a compound LiaCO1-bMbO2 and a surface-treatment layer. In the core compound, 0.95?a?1.1, 0.002?b?0.02, and M is one or more elements selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, P, As, Sb, Bi, S, Se, Te, Po. The surface-treatment layer includes a compound including element of P, and one or more elements selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, As, Sb, Bi, S, Se, Te, Po.
    Type: Grant
    Filed: August 16, 2007
    Date of Patent: September 18, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Duck-Chul Hwang, Yong-Chul Park, Jeom-Soo Kim, Jae-Yul Ryu, Jong-Hwa Lee, Euy-Young Jung, So-Hyun Hur
  • Patent number: 8252462
    Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a non-aqueous electrolyte, and an insulating layer formed on a surface of the positive electrode. The positive electrode includes a lithium nickel composite oxide having a layer structure, and the lithium nickel composite oxide is represented by the general formula: LixNiyM1-yO2 where M is at least one selected from the group consisting of Na, Mg, Sc, Y, Mn, Fe, Co, Cu, Zn, Al, Cr, Pb, Sb, and B, 0<x?1.2, and 0.5<y?1.0. The non-aqueous electrolyte includes a solute and a non-aqueous solvent dissolving the solute, and the non-aqueous solvent contains 40% by weight or more of a cyclic carbonic acid ester. The insulating layer includes an insulating polymeric material.
    Type: Grant
    Filed: May 4, 2009
    Date of Patent: August 28, 2012
    Assignee: Panasonic Corporation
    Inventors: Naoyuki Wada, Yoshiyuki Ozaki, Shinji Kasamatsu, Yukihiro Okada
  • Publication number: 20120214072
    Abstract: The present invention concerns electrode materials capable of redox reactions by electron and alkali-ion exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, supercapacitors and light modulating systems of the electrochromic type.
    Type: Application
    Filed: May 4, 2012
    Publication date: August 23, 2012
    Applicants: ACEP Inc., Universite De Montreal, CNRS
    Inventors: Nathalie Ravet, Simon Besner, Martin Simoneau, Alain Vallee, Michel Armand, Jean-Francois Magnan
  • Publication number: 20120202112
    Abstract: Li-ion batteries are provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and at least one hydrofluoric acid neutralizing agent incorporated into the anode or the separator. Li-ion batteries are also provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, and a separator electrically separating the anode and the cathode, where the electrolyte may be formed from a mixture of an imide salt and at least one salt selected from the group consisting of LiPF6, LiBF4, and LiClO4. Li-ion battery anodes are also provided that include an active material core and a protective coating at least partially encasing the active material core, where the protective coating comprises a material that is resistant to hydrofluoric acid permeation.
    Type: Application
    Filed: February 6, 2012
    Publication date: August 9, 2012
    Inventors: Gleb Nikolayevich Yushin, Bogdan Zydrko, Kara Evanoff
  • Publication number: 20120196185
    Abstract: The present invention relates to a positive electrode active substance for non-aqueous electrolyte secondary batteries which comprises particles comprising a polyanionic compound and carbon, and a lipophilic treatment agent with which the respective particles are coated, wherein the positive electrode active substance has an average particle diameter of 1 to 50 ?m. The positive electrode active substance preferably has an oil absorption of not more than 20 mL/100 g. The positive electrode active substance according to the present invention exhibits a good compatibility with a resin and is excellent in packing property and dispersibility in the resin, and therefore can provide an electrode sheet in which the positive electrode active substance is filled with a high packing density.
    Type: Application
    Filed: July 27, 2010
    Publication date: August 2, 2012
    Inventors: Yoshiteru Kono, Kenji Ogisu, Toshiyuki Hakata, Yuji Mishima, Katsuji Iwami, Masayuki Yokota, Minoru Yamasaki, Akihisa Kajiyama, Hideaki Sadamura
  • Publication number: 20120196186
    Abstract: The present invention discloses a composite material having an ionic and electronic conductive outer shell with an active material inner core located within the outer shell. The outer shell can be impervious to a gas and a liquid, and in some instances contains a compound such as SiO2, Al2O3, P2S5, and Li2S. The composite material may or may not have a secondary outer shell that is located on an exterior of the outer shell. The outer shell and/or the secondary outer shell can contain a compound such as SiO2, Al2O3, P2S5, and/or Li2S. In some instances, the outer shell contains Li2S:P2S5, while in other instances, the outer shell contains LiPON. In addition, the inner core can contain an element such as lithium, sodium, potassium, and the like.
    Type: Application
    Filed: February 1, 2011
    Publication date: August 2, 2012
    Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventor: Monique N. Richard
  • Patent number: 8227100
    Abstract: The present invention relates to a negative active material for a lithium ion battery and a lithium ion battery including the negative active material. The negative active material for a lithium ion battery includes a hexagonal lithium vanadium composite oxide including lithium, vanadium, and magnesium. The lithium and the vanadium are included in a mole ratio within a range of 1.15?Li/V?1.35, and the magnesium and the vanadium are included in a mole ratio within a range of 0.01?Mg/V?0.06. The present invention provides a negative active material for a lithium ion battery having a stable crystal structure, excellent high rate of charge and discharge, and good charge and discharge cycle characteristics.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: July 24, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Toru Inagaki, Akira Takamuku, Geun-Bao Kim
  • Patent number: 8221921
    Abstract: A non-aqueous electrolyte battery has a cathode, an anode, an electrolyte, and a separator. The separator is a microporous resin film of a single layer made of a resin material in which at least one kind of insulating and flame-retarding fiber is dispersed in a polyolefin resin.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: July 17, 2012
    Assignee: Sony Corporation
    Inventors: Kenichi Ogawa, Hiroyuki Akashi, Yoshiaki Obana, Atsushi Kajita, Yukako Teshima
  • Patent number: 8221917
    Abstract: A positive active material composition for a rechargeable battery, a positive electrode including the same, and a rechargeable battery including the same, the positive active material composition including a positive active material and a surface-modified metal oxide.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: July 17, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Dai-Hoe Lee, Takaya Saito, Hyun-Ki Jung, Min-Hee Kim
  • Publication number: 20120177974
    Abstract: A non-aqueous electrolyte battery according to the present invention is a non-aqueous electrolyte battery including a positive electrode, a negative electrode, a separator and a non-aqueous electrolyte, wherein aluminum silicate or a derivative thereof is contained in a location that can come into contact with the non-aqueous electrolyte in the battery. In the non-aqueous electrolyte battery, it is preferable that at least one of the separator, the positive electrode, the negative electrode and the non-aqueous electrolyte contains aluminum silicate or a derivative thereof.
    Type: Application
    Filed: October 21, 2011
    Publication date: July 12, 2012
    Inventors: Hiroshi NAKAJIMA, Hideaki Katayama, Yuki Takei