Alkaline Earth Metal Or Magnesium (mg) Component Is Active Material Patents (Class 429/231.6)
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Patent number: 8415058Abstract: A nonaqueous secondary battery having a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode contains, as an active material, a lithium-containing transition metal oxide containing a metal element selected from the group consisting of Mg, Ti, Zr, Ge, Nb, Al and Sn, the positive electrode mixture layer has a density of 3.Type: GrantFiled: June 12, 2012Date of Patent: April 9, 2013Assignee: Hitachi Maxell, Ltd.Inventors: Hideo Sakata, Fusaji Kita, Kumiko Ishizuka
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Patent number: 8409752Abstract: An active material for a battery includes an electrochemically reversibly oxidizable and reducible base material selected from the group consisting of a metal, a lithium-containing alloy, a sulfur-based compound, and a compound that can reversibly form a lithium-containing compound by a reaction with lithium ions and a surface-treatment layer formed on the base material and comprising a compound of the formula MXOk, wherein M is at least one element selected from the group consisting of an alkali metal, an alkaline earth metal, a group 13 element, a group 14 element, a transition metal, and a rare-earth element, X is an element that is capable of forming a double bond with oxygen, k is a numerical value in the range of 2 to 4.Type: GrantFiled: March 19, 2010Date of Patent: April 2, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Jae-Phil Cho, Geun-Bae Kim, Sang-Moon Hwang, Yong-Chul Park, Won-Il Jung
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Patent number: 8404387Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode contains active material particles and a coating material. The active material particles are represented by any one of the following formulae (1) to (3) and have an average particle diameter of 0.1 to 10 ?m. The coating material comprises at least particles having an average particle diameter of 60 nm or less or layers having an average thickness of 60 nm or less. The particles or the layers contain at least one element selected from the group consisting of Mg, Ti, Zr, Ba, B and C.Type: GrantFiled: July 8, 2008Date of Patent: March 26, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Norio Takami, Hiroki Inagaki, Keigo Hoshina
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Publication number: 20130071747Abstract: The disclosure relates to positive electrode material used for Li-ion batteries, a precursor and process used for preparing such materials, and Li-ion battery using such material in its positive electrode. The disclosure describes a higher density LiCoO2 positive electrode material for lithium secondary batteries, with a specific surface area (BET) below 0.2 m2/g, and a volumetric median particle size (d50) of more than 15 ?m. This product has improved specific capacity and rate-capability. Other embodiments of the disclosure are an aggregated Co(OH)2, which is used as a precursor, the electrode mix and the battery manufactured using above-mentioned LiCoO2.Type: ApplicationFiled: November 14, 2012Publication date: March 21, 2013Applicant: UMICOREInventor: Umicore
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Publication number: 20130071745Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery utilizing the same. The electrode active material includes a core capable of intercalating and deintercalating lithium and a coating layer formed on at least a portion of a surface of the core, wherein the coating layer includes a composite metal halide having a spinel structure.Type: ApplicationFiled: July 10, 2012Publication date: March 21, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Jun-young MUN, Won-chang Choi, Jin-hwan Park
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Publication number: 20130049759Abstract: An electrochemical test cell, containing an anode comprising a metal as an active component; a cathode comprising a porous chemically inert tube containing an active material compatible with the metal of the anode; and an electrolyte; wherein the only metal in contact with the electrolyte is the metal of the anode, is provided. This test cell is useful in a method to evaluate various combinations of materials for suitability as a combination for preparation of a battery.Type: ApplicationFiled: August 24, 2011Publication date: February 28, 2013Applicant: Toyota Motor Engineering & Manufacturing NAInventors: Hee Soo KIM, John Muldoon
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Patent number: 8377592Abstract: An negative active material for a rechargeable lithium battery includes a nano-composite including a Si phase, a SiO2 phase, and a metal oxide phase of formulation MyO, where M is a metal with an oxidation number x, a free energy of oxygen-bond formation ranging from ?900 kJ/mol to ?2000 kJ/mol, x, and x·y=2. The negative active material for a rechargeable lithium battery according to the present invention can improve initial capacity, initial efficiency, and cycle-life characteristics by suppressing its initial irreversible reaction.Type: GrantFiled: September 17, 2008Date of Patent: February 19, 2013Assignees: Samsung SDI Co., Ltd., Seoul National University Industry FoundationInventors: Goo-Jin Jeong, Sang-Min Lee, Wan-Uk Choi, Hun-Joon Sohn
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Publication number: 20130034770Abstract: The present invention is directed toward a laminated electrode and porous separator film combination including a solid electrolyte salt within the porous separator film, the combination comprising layer of powdered cathode material adhering to a surface of a separator film with a solid electrolyte therebetween; the separator film comprising 50% to 95% by weight of electrically non-conductive ceramic fibers having a coating of magnesium oxide on the surface of the fibers in an amount in the range of 5% to 50% by weight; wherein the ceramic fibers comprise Al2O3, AlSiO2, BN, AlN, or a mixture of two or more of the foregoing; and the magnesium oxide coating interconnects the ceramic fibers providing a porous network of magnesium oxide-coated fibers having a porosity of not less than 50% by volume; the pores of the network containing a solid electrolyte salt in an amount of up to 95% by volume based on pore volume of the network.Type: ApplicationFiled: October 3, 2012Publication date: February 7, 2013Inventor: Thomas D. Kaun
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Publication number: 20130029225Abstract: A secondary battery includes: a cathode including an active material; an anode; and an electrolytic solution. The active material has a composition represented by Formula (1) described below. A median diameter (D90) of the active material is from about 10.5 micrometers to about 60 micrometers both inclusive, the median diameter (D90) being measured by a laser diffraction method. A half bandwidth (2?) of a diffraction peak corresponding to a (020) crystal plane of the active material is from about 0.15 degrees to about 0.24 degrees both inclusive, the half bandwidth (2?) being measured by an X-ray diffraction method. LiaMnbFecMdPO4??(1) where M represents one or more of Mg, Ni, Co, Al, W, Nb, Ti, Si, Cr, Cu, and Zn; and 0<a?2, 0<b<1, 0<c<1, 0?d<1, and b+c+d=1 are established.Type: ApplicationFiled: July 25, 2012Publication date: January 31, 2013Applicant: SONY CORPORATIONInventors: Takaaki Matsui, Tadashi Matsushita, Takehiko Ishii
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Publication number: 20130029224Abstract: An electrochemical generator comprising a first type of electrochemical cell, a so-called <<high energy>> cell and a second type of electrochemical cell a so-called <<safety>> cell is provided.Type: ApplicationFiled: January 12, 2011Publication date: January 31, 2013Applicant: Commissariat a l'energie atomique et aux energies alternativesInventors: Florence Fusalba, Sébastien Martinet
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Publication number: 20130022872Abstract: Disclosed herein is a cathode active material including a lithium manganese oxide, in which the lithium manganese oxide has a spinel structure with a predetermined constitutional composition represented by Formula 1 described in the detailed description, wherein a conductive material is applied to the surface of lithium manganese oxide particles, so as to exhibit charge-discharge properties in the range of 2.5 to 3.5V as well as in the 4V region.Type: ApplicationFiled: February 16, 2012Publication date: January 24, 2013Applicant: LG CHEM, LTD.Inventors: Hyun Kuk Noh, Sin Kyu Kim, Geun-Chang Chung, Song-Taek Oh, Sanguck Lee, Jong Chan Kim
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Publication number: 20130017445Abstract: A biodegradable battery is provided. The battery includes an anode comprising a material including an inner surface and an outer surface, wherein electrochemical oxidation of the anode material results in the formation of a reaction product that is substantially non-toxic and a cathode comprising a material including an inner surface and an outer surface, the inner surface of the cathode being in direct physical contact with the inner surface of the anode, wherein electrochemical reduction of the cathode material results in the formation of a reaction product that is substantially non-toxic, and wherein the cathode material presents a larger standard reduction potential than the anode material.Type: ApplicationFiled: July 15, 2011Publication date: January 17, 2013Inventors: Gerald N. Hodgkinson, William Powers, Ahmad Robert Hadba
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Publication number: 20130011741Abstract: A non-aqueous electrolyte secondary battery has a positive electrode containing a positive electrode active material containing a lithium-containing oxide active material, a negative electrode, and a non-aqueous electrolyte. The lithium-containing oxide active material is represented by the general formula LiaMgbMO2±? where 0.65?a?1.05, 0<b?0.3, 0???0.3, and M is at least one of manganese and cobalt.Type: ApplicationFiled: September 13, 2012Publication date: January 10, 2013Applicant: SANYO ELECTRIC CO., LTD.Inventors: Motoharu Saito, Sho Tsuruta, Masahisa Fujimoto
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Negative electrode for rechargeable lithium battery, and rechargeable lithium battery including same
Patent number: 8349492Abstract: The negative electrode for a rechargeable lithium battery includes a current collector and a negative active material layer disposed on the current collector. The negative active material layer includes a metal-based negative active material and sheet-shaped graphite and has porosity of 20 to 80 volume %. The negative electrode for a rechargeable lithium battery can improve cell characteristics by inhibiting volume change and stress due to active material particle bombardment during charge and discharge, and by decreasing electrode resistance.Type: GrantFiled: January 22, 2008Date of Patent: January 8, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Sang-Min Lee, Goo-Jin Jeong, Min-Seok Sung, Yong-Mook Kang, Wan-Uk Choi, Sung-Soo Kim -
Publication number: 20130004846Abstract: A negative active material, a method of preparing the same, and a lithium battery including the negative active material are disclosed. The negative active material includes a silicon-based nanocore and a first amorphous carbonaceous coating layer that is formed of carbonized organic material and that is uniformly and continuously formed on a surface of the silicon-based nanocore, whereby irreversible capacity losses due to volumetric expansion/contraction caused when a lithium battery is charged and discharged are compensated and cycle lifetime characteristics are enhanced.Type: ApplicationFiled: May 4, 2012Publication date: January 3, 2013Applicant: Samsung SDI Co., Ltd.Inventors: Beom-Kwon Kim, Jae-Myung Kim, So-Ra Lee, Chang-Su Shin, Ui-Song Do
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Publication number: 20130004852Abstract: Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.Type: ApplicationFiled: September 13, 2012Publication date: January 3, 2013Applicant: POLYPLUS BATTERY COMPANYInventors: Steven J. Visco, Bruce D. Katz, Yevgeniy S. Nimon, Lutgard C. De Jonghe
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Publication number: 20120326500Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material contains, as constituent elements, Si, O, and at least one element Ml selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio x (O/Si) of O to Si is 0.5?x?1.8.Type: ApplicationFiled: June 19, 2012Publication date: December 27, 2012Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Toshio Nishi, Isao Koizumi
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Publication number: 20120328915Abstract: A lithium-ion secondary battery includes a positive electrode, a negative electrode containing an active material, and an electrolytic solution, in which the active material includes a core portion capable of occluding and releasing lithium ions, and a covering portion arranged on at least part of a surface of the core portion, in which the covering portion contains, as constituent elements, Si, O, and at least one element M1 selected from Li, C, Mg, Al, Ca, Ti, Cr, Mn, Fe, Co, Ni, Cu, Ge, Zr, Mo, Ag, Sn, Ba, W, Ta, Na, and K, and the atomic ratio y (O/Si) of O to Si is 0.5?y?1.8.Type: ApplicationFiled: June 18, 2012Publication date: December 27, 2012Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Kenichi Kawase, Takashi Fujinaga, Isao Koizumi, Toshio Nishi
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Publication number: 20120328945Abstract: A lithium ion secondary battery is provided with a positive electrode, a negative electrode containing an active material, and an electrolytic solution, wherein the active material includes a core portion capable of occluding and releasing lithium ions, an amorphous or low-crystalline coating portion disposed on at least a part of the surface of the core portion, and a fibrous carbon portion disposed on at least a part of the surface of the coating portion, and the coating portion contains Si and O as constituent elements, while the atomic ratio y (O/Si) of O relative to Si satisfies 0.5?y?1.8.Type: ApplicationFiled: June 19, 2012Publication date: December 27, 2012Applicant: SONY CORPORATIONInventors: Takakazu Hirose, Takashi Fujinaga, Isao Koizumi, Norihiro Shimoi, Kenichi Kawase
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Publication number: 20120328936Abstract: A battery includes a cathode, an anode, and an aqueous electrolyte disposed between the cathode and the anode and including a cation A. At least one of the cathode and the anode includes an electrode material having an open framework crystal structure into which the cation A is reversibly inserted during operation of the battery. The battery has a reference specific capacity when cycled at a reference rate, and at least 75% of the reference specific capacity is retained when the battery is cycled at 10 times the reference rate.Type: ApplicationFiled: May 29, 2012Publication date: December 27, 2012Inventors: Colin Wessells, Robert Huggins, Yi Cui, Mauro Pasta
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Patent number: 8323816Abstract: Electrochemical cells having molten electrodes comprising an alkaline earth metal provide receipt and delivery of power by transporting atoms of the alkaline earth metal between electrode environments of disparate alkaline earth metal chemical potentials.Type: GrantFiled: July 20, 2009Date of Patent: December 4, 2012Assignee: Massachusetts Institute of TechnologyInventors: David Bradwell, Donald R. Sadoway
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Publication number: 20120301788Abstract: An electrode active material including a core active material and a coating layer, including a compound represented as the following Formula 1, on a surface of the core active material, a method of preparing the same, an electrode for a lithium secondary battery which includes the same, and a lithium secondary battery using the electrode. Lia-Mb-Nc??[Formula 1] where, M denotes an alkaline earth metal, a/(a+b+c) is in a range of about 0.10 to about 0.40, b/(a+b+c) is in a range of about 0.20 to about 0.50, and c/(a+b+c) is in a range of about 0.20 to about 0.50.Type: ApplicationFiled: September 22, 2011Publication date: November 29, 2012Inventors: Jae-Hyuk Kim, Sung-Hwan Moon, Hee-Young Chu, Myung-Hwan Jeong, Chang-Ui Jeong, Yury Matulevich, Jong-Seo Choi
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Publication number: 20120301786Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode contains a lithium composite oxide. The negative electrode contains a material including at least one of silicon Si and tin Sn as a constituent element. The lithium composite oxide includes lithium Li having a composition ratio a, a first element having a composition ratio b, and a second element having a composition ratio c as a constituent element. The first element including two kinds or more selected from among manganese Mn, nickel Ni, and cobalt Co, and including at least manganese. The second element including at least one kind selected from among aluminum Al, titanium Ti, magnesium Mg, and boron B. The composition ratios a to c satisfy the relationships of 1.1<a<1.3, 0.7<b+c<1.1, 0<c<0.1, and a>b+c.Type: ApplicationFiled: December 22, 2011Publication date: November 29, 2012Applicant: SONY CORPORATIONInventors: Akira Takamuku, Kazuaki Endoh, Masaharu Senoue, Guohua Li, Yosuke Hosoya, Kenichi Kawase
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Patent number: 8318354Abstract: An electrochemical device, having an anode containing magnesium; a cathode stable to a voltage of at least 3.2 V relative to a magnesium reference; and an electrolyte containing an electrochemically active magnesium salt obtained by mixing an organic magnesium compound with an aluminum compound in an ether solvent and separation of the electrochemically active salt from the reaction mixture is provided. The separated electrochemically active salt is stable and safe to handle in comparison to conventional Grignard based electrolyte systems.Type: GrantFiled: April 27, 2010Date of Patent: November 27, 2012Assignee: Toyota Motor Engineering & Manufacturing North AmericaInventors: John Muldoon, Hee Soo Kim
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Patent number: 8318349Abstract: A negative electrode active material for a nickel-metal hydride battery of the present invention includes a hydrogen storage alloy, the hydrogen storage alloy containing La, Mg, Ni, Co, Al, and element M. The molar ratio y of Ni to the total of La and Mg is 2?y?3, the molar ratio z of Co to the total of La and Mg is 0.25?z?0.75, the molar ratio ? of Al to the total of La and Mg is 0.01???0.05, and the molar ratio x of Mg to the total of La and Mg is 0.01?x?0.5. Element M represents at least one selected from the group consisting of Y and Sn, and the content of element M in the hydrogen storage alloy is 0.4 wt % or less.Type: GrantFiled: August 29, 2008Date of Patent: November 27, 2012Assignee: Panasonic CorporationInventors: Hideaki Ohyama, Kyoko Nakatsuji, Yoshitaka Dansui
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Patent number: 8318352Abstract: A secondary electrochemical cell is described having (a) a first electrode comprising an active material of the formula LiaCoeFefM1gM2hM3iXY4, (b) a second electrode which is a counter-electrode to said first electrode; and (c) an electrolyte comprising an electrolyte salt, a cyclic ester and a carbonate selected from the group consisting of alkyl carbonates, alkylene carbonates, and mixtures thereof.Type: GrantFiled: March 15, 2005Date of Patent: November 27, 2012Assignee: Valence Technology, Inc.Inventors: M. Yazid Saidi, Haitao Huang, James K. Pugh
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Publication number: 20120282530Abstract: An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.Type: ApplicationFiled: July 13, 2012Publication date: November 8, 2012Applicant: Massachusetts Institute of TechnologyInventors: Yet-Ming Chiang, William Douglas Moorehead
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Publication number: 20120282521Abstract: An electrode active material, a method of manufacturing the same, and an electrode and a lithium battery adopting the same. The electrode active material includes a core capable of occluding and emitting lithium; and a surface treatment layer formed on at least a portion of a surface of the core, wherein the surface treatment layer includes a lithium-free oxide having a spinel structure.Type: ApplicationFiled: May 1, 2012Publication date: November 8, 2012Applicant: Samsung Electronics Co. Ltd.Inventors: Won-chang CHOI, Jin-hwan Park
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Publication number: 20120276444Abstract: A magnesium battery includes a first electrode including an active material and a second electrode. An electrolyte is disposed between the first electrode and the second electrode. The electrolyte includes a magnesium compound. The active material includes an inter-metallic compound of magnesium and bismuth.Type: ApplicationFiled: April 29, 2011Publication date: November 1, 2012Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.Inventor: Masaki Matsui
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Patent number: 8298707Abstract: A positive active material including a compound expressed by a general formula LimMxM?yM?zO2 (here, M designates at least one kind of element selected from Co, Ni and Mn, M? designates at least one kind of element selected from Al, Cr, V, Fe, Cu, Zn, Sn, Ti, Mg, Sr, B, Ga, In, Si and Ge, and M? designates at least one kind of element selected from Mg, Ca, B and Ga. Further, x is designated by an expression of 0.9?x<1, y is indicated by an expression of 0.001?y?0.5, z is indicated by an expression of 0?z?0.5, and m is indicated by an expression of 0.5?m) and lithium manganese oxide expressed by a general formula LisMn2-tMatO4 (here, the value of s is expressed by 0.9?s, the value of t is located within a range expressed by 0.01?t?0.5, and Ma indicates one or a plurality of elements between Fe, Co, Ni, Cu, Zn, Al, Sn, Cr, V, Ti, Mg, Ca, Sr, B, Ga, In, Si and Ge) are included, so that both a large capacity and the suppression of the rise of temperature of a battery upon overcharging operation are achieved.Type: GrantFiled: December 14, 2005Date of Patent: October 30, 2012Assignee: Sony CorporationInventors: Takehiko Tanaka, Yosuke Hosoya, Yoshikatsu Yamamoto, Kiyohiko Suzuki, Keizo Koga
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Publication number: 20120270104Abstract: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a first inner and a second outer layer, the second outer layer comprising a fluorine-containing polymer, and the first inner layer consisting of a reaction product of the fluorine-containing polymer and the primary particle surface. An example of this reaction product is LiF, where the lithium originates from the primary particles surface. Also as an example, the fluorine-containing polymer is either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCOdMeO2, wherein M is either one or both of Mg and Ti, with e<0.02 and d+e=1; —Li+aM?1?aO2±bM1kSm with ?0.03?a?0.06, b<0.02, M? being a transition metal compound, consisting of at least 95% of either one or more elements of the group Ni, Mn, Co, Mg and Ti; M1 consisting of either one or more elements of the group Ca, Sr, Y, La, Ce and Zr, with 0?k?0.Type: ApplicationFiled: October 19, 2010Publication date: October 25, 2012Inventors: Jens Paulsen, Randy De Palma, HeonPyo Hong, KyuBo Kim
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Publication number: 20120258362Abstract: An electrode active material, a method of preparing the electrode active material, an electrode including the electrode active material, and a lithium secondary battery including the electrode; the electrode active material comprising a core active material; and a coating layer formed on a surface of the core active material, wherein the coating layer comprises a composition including a compound represented by Formula 1 below and a carbonaceous material, or a first coating layer including a carbonaceous material and a second coating layer including the compound represented by Formula 1 below: LixMy(PO4)z, ??Formula 1 where M is selected from the group consisting of alkali metal, alkaline earth metal, a group 13 element, a group 14 element, a transition metal, a rare earth element, and combinations thereof; 1?x?3, 0?y?3, and 1?z?3.Type: ApplicationFiled: September 23, 2011Publication date: October 11, 2012Applicant: Samsung Electronics Co. Ltd.Inventors: Sang-kook MAH, Gue-sung KIM
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Publication number: 20120258368Abstract: A negative electrode active material, a method of preparing the negative electrode active material and a lithium secondary battery including the negative electrode active material are disclosed. A negative electrode active material includes a lithium titanate, wherein a portion of lithium of the lithium titanate is substituted by at least one selected from the group consisting of Sr, Ba, a mixture thereof and an alloy thereof, and thus a lithium secondary battery including the negative electrode active material may improve high-rate discharge characteristics.Type: ApplicationFiled: February 2, 2012Publication date: October 11, 2012Applicant: SAMSUNG SDI CO., LTD.Inventors: Jong-Hee LEE, Yong-Mi Yu, Joa-Young Jeong, Jae-Myung Kim
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Publication number: 20120258370Abstract: [Summary] [Assignment] Providing a noble negative-electrode active material including silicon, and a production process for the same. [Solving Means] A negative-electrode active material for non-aqueous-system secondary battery including a silicon phase and a composite oxide phase (a CaSiO3 phase, for instance) is obtained by mixing a silicon oxide (SiO, for instance) with a silicon compound (CaSi2, for instance), which includes silicon and at least one member of elements being selected from the group consisting of Group 2 (or Group 2A) elements in the Periodic Table, to prepare a mixed raw material, and then reacting the mixed raw material. The composite oxide phase demonstrates the advantage of inhibiting electrolytic solutions from decomposing in a smaller amount than does the conventional SiO2 phase.Type: ApplicationFiled: December 8, 2010Publication date: October 11, 2012Applicant: Kabushiki Kaisha Toyota JidoshokkiInventors: Manabu Miyoshi, Hideaki Ishikawa, Hitotoshi Murase
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Publication number: 20120251886Abstract: A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.Type: ApplicationFiled: March 30, 2012Publication date: October 4, 2012Applicant: GEORGIA TECH RESEARCH CORPORATIONInventors: Gleb Nikolayevich Yushin, Kara Linn Evanoff, Oleksandr Magazynskyy
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Patent number: 8277979Abstract: An anode composite material includes an anode active material particle having a surface and a continuous aluminum phosphate layer. The continuous aluminum phosphate layer is coated on the surface of the anode active material particle. The present disclosure also relates to a lithium ion battery that includes the cathode composite material.Type: GrantFiled: May 16, 2011Date of Patent: October 2, 2012Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Xian-Kun Huang, Xiang-Ming He, Chang-Yin Jiang, Dan Wang, Jian Gao, Jian-Jun Li
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Publication number: 20120244440Abstract: A rechargeable lithium battery, which includes: a negative electrode including a silicon-based negative active material; a positive electrode (including a positive active material capable of intercalating and deintercalating lithium, and a conductive material including a fiber shaped material and a non-fiber shaped material), wherein a weight per unit area of the positive electrode (which is a loading level (LL) of the positive electrode) is about 20 mg/cm2 to 100 mg/cm2; and a non-aqueous electrolyte.Type: ApplicationFiled: January 31, 2012Publication date: September 27, 2012Inventors: Nathan Lee, Ung-Kuk Heo, Seung-Ho Na
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Publication number: 20120244442Abstract: According to one embodiment, a battery active material includes a complex oxide containing Nb and Ti and an element M. In the active material, the molar ratio (M/Ti) of the element M to Ti satisfies the following formula (I): 0<M/Ti?0.5 (I). In the complex oxide containing Nb and Ti, the molar ratio (Nb/Ti) of Nb to Ti satisfies the following formula (II): 0?Nb/Ti?5 (II). The element M is at least one selected from the group consisting of B, Na, Mg, Al, Si, S, P, K, Ca, Mo, W, Cr, Mn, Co, Ni, and Fe.Type: ApplicationFiled: March 1, 2012Publication date: September 27, 2012Inventors: Yasuhiro Harada, Norio Takami, Hiroki Inagaki, Yorikazu Yoshida
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Patent number: 8273481Abstract: A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.Type: GrantFiled: August 25, 2011Date of Patent: September 25, 2012Assignees: Universitéde Montréal, Centre National de la Recherche Scientifique, Phostech Lithium Inc.Inventors: Laurent Gauthier, Michel Gauthier, Donald Lavoie, Christophe Michot, Nathalie Ravet
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Patent number: 8273478Abstract: A rechargeable lithium battery includes an electrolyte including an additive such as an ethylene carbonate-based compound represented by Chemical Formula 1 and a silicon-included compound, and a negative electrode including a negative active material including an active element selected from the group consisting of Si, Sn, Ga, Cd, Al, Pb, Zn, Bi, In, Mg, and Ge. In Chemical formula 1, X and Y are independently selected from the group consisting of hydrogen, a halogen, and a C1 through C5 fluoroalkyl, provided that at least one of X and Y is selected from the group consisting of a halogen and a C1 through C5 fluoroalkyl. The rechargeable lithium battery has a suppressed volume expansion characteristic due to a high-capacity negative active material, and has excellent reliability and cycle-life characteristics.Type: GrantFiled: March 31, 2009Date of Patent: September 25, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Jin-Sung Kim, Na-Rae Park, Su-Hee Han, Jin-Hyunk Lim
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Patent number: 8268486Abstract: A positive electrode includes a current collector and a positive electrode active material layer. The positive electrode active material layer includes a positive electrode active material including a core including a compound LiaCO1-bMbO2 and a surface-treatment layer. In the core compound, 0.95?a?1.1, 0.002?b?0.02, and M is one or more elements selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, P, As, Sb, Bi, S, Se, Te, Po. The surface-treatment layer includes a compound including element of P, and one or more elements selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, As, Sb, Bi, S, Se, Te, Po.Type: GrantFiled: August 16, 2007Date of Patent: September 18, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Duck-Chul Hwang, Yong-Chul Park, Jeom-Soo Kim, Jae-Yul Ryu, Jong-Hwa Lee, Euy-Young Jung, So-Hyun Hur
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Patent number: 8252462Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a non-aqueous electrolyte, and an insulating layer formed on a surface of the positive electrode. The positive electrode includes a lithium nickel composite oxide having a layer structure, and the lithium nickel composite oxide is represented by the general formula: LixNiyM1-yO2 where M is at least one selected from the group consisting of Na, Mg, Sc, Y, Mn, Fe, Co, Cu, Zn, Al, Cr, Pb, Sb, and B, 0<x?1.2, and 0.5<y?1.0. The non-aqueous electrolyte includes a solute and a non-aqueous solvent dissolving the solute, and the non-aqueous solvent contains 40% by weight or more of a cyclic carbonic acid ester. The insulating layer includes an insulating polymeric material.Type: GrantFiled: May 4, 2009Date of Patent: August 28, 2012Assignee: Panasonic CorporationInventors: Naoyuki Wada, Yoshiyuki Ozaki, Shinji Kasamatsu, Yukihiro Okada
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Publication number: 20120214072Abstract: The present invention concerns electrode materials capable of redox reactions by electron and alkali-ion exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, supercapacitors and light modulating systems of the electrochromic type.Type: ApplicationFiled: May 4, 2012Publication date: August 23, 2012Applicants: ACEP Inc., Universite De Montreal, CNRSInventors: Nathalie Ravet, Simon Besner, Martin Simoneau, Alain Vallee, Michel Armand, Jean-Francois Magnan
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Publication number: 20120202112Abstract: Li-ion batteries are provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, a separator electrically separating the anode and the cathode, and at least one hydrofluoric acid neutralizing agent incorporated into the anode or the separator. Li-ion batteries are also provided that include a cathode, an anode comprising active particles, an electrolyte ionically coupling the anode and the cathode, and a separator electrically separating the anode and the cathode, where the electrolyte may be formed from a mixture of an imide salt and at least one salt selected from the group consisting of LiPF6, LiBF4, and LiClO4. Li-ion battery anodes are also provided that include an active material core and a protective coating at least partially encasing the active material core, where the protective coating comprises a material that is resistant to hydrofluoric acid permeation.Type: ApplicationFiled: February 6, 2012Publication date: August 9, 2012Inventors: Gleb Nikolayevich Yushin, Bogdan Zydrko, Kara Evanoff
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Publication number: 20120196185Abstract: The present invention relates to a positive electrode active substance for non-aqueous electrolyte secondary batteries which comprises particles comprising a polyanionic compound and carbon, and a lipophilic treatment agent with which the respective particles are coated, wherein the positive electrode active substance has an average particle diameter of 1 to 50 ?m. The positive electrode active substance preferably has an oil absorption of not more than 20 mL/100 g. The positive electrode active substance according to the present invention exhibits a good compatibility with a resin and is excellent in packing property and dispersibility in the resin, and therefore can provide an electrode sheet in which the positive electrode active substance is filled with a high packing density.Type: ApplicationFiled: July 27, 2010Publication date: August 2, 2012Inventors: Yoshiteru Kono, Kenji Ogisu, Toshiyuki Hakata, Yuji Mishima, Katsuji Iwami, Masayuki Yokota, Minoru Yamasaki, Akihisa Kajiyama, Hideaki Sadamura
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Publication number: 20120196186Abstract: The present invention discloses a composite material having an ionic and electronic conductive outer shell with an active material inner core located within the outer shell. The outer shell can be impervious to a gas and a liquid, and in some instances contains a compound such as SiO2, Al2O3, P2S5, and Li2S. The composite material may or may not have a secondary outer shell that is located on an exterior of the outer shell. The outer shell and/or the secondary outer shell can contain a compound such as SiO2, Al2O3, P2S5, and/or Li2S. In some instances, the outer shell contains Li2S:P2S5, while in other instances, the outer shell contains LiPON. In addition, the inner core can contain an element such as lithium, sodium, potassium, and the like.Type: ApplicationFiled: February 1, 2011Publication date: August 2, 2012Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.Inventor: Monique N. Richard
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Patent number: 8227100Abstract: The present invention relates to a negative active material for a lithium ion battery and a lithium ion battery including the negative active material. The negative active material for a lithium ion battery includes a hexagonal lithium vanadium composite oxide including lithium, vanadium, and magnesium. The lithium and the vanadium are included in a mole ratio within a range of 1.15?Li/V?1.35, and the magnesium and the vanadium are included in a mole ratio within a range of 0.01?Mg/V?0.06. The present invention provides a negative active material for a lithium ion battery having a stable crystal structure, excellent high rate of charge and discharge, and good charge and discharge cycle characteristics.Type: GrantFiled: December 10, 2008Date of Patent: July 24, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Toru Inagaki, Akira Takamuku, Geun-Bao Kim
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Patent number: 8221921Abstract: A non-aqueous electrolyte battery has a cathode, an anode, an electrolyte, and a separator. The separator is a microporous resin film of a single layer made of a resin material in which at least one kind of insulating and flame-retarding fiber is dispersed in a polyolefin resin.Type: GrantFiled: March 25, 2008Date of Patent: July 17, 2012Assignee: Sony CorporationInventors: Kenichi Ogawa, Hiroyuki Akashi, Yoshiaki Obana, Atsushi Kajita, Yukako Teshima
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Patent number: 8221917Abstract: A positive active material composition for a rechargeable battery, a positive electrode including the same, and a rechargeable battery including the same, the positive active material composition including a positive active material and a surface-modified metal oxide.Type: GrantFiled: November 5, 2009Date of Patent: July 17, 2012Assignee: Samsung SDI Co., Ltd.Inventors: Dai-Hoe Lee, Takaya Saito, Hyun-Ki Jung, Min-Hee Kim
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Publication number: 20120177974Abstract: A non-aqueous electrolyte battery according to the present invention is a non-aqueous electrolyte battery including a positive electrode, a negative electrode, a separator and a non-aqueous electrolyte, wherein aluminum silicate or a derivative thereof is contained in a location that can come into contact with the non-aqueous electrolyte in the battery. In the non-aqueous electrolyte battery, it is preferable that at least one of the separator, the positive electrode, the negative electrode and the non-aqueous electrolyte contains aluminum silicate or a derivative thereof.Type: ApplicationFiled: October 21, 2011Publication date: July 12, 2012Inventors: Hiroshi NAKAJIMA, Hideaki Katayama, Yuki Takei