Acyclic Carboxylic Acid Ester Solvent Patents (Class 429/343)
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Publication number: 20130122378Abstract: An electrolyte solution for a rechargeable lithium battery that includes a lithium salt; a non-aqueous organic solvent including ethyl acetate; and an additive including a sultone-based compound, wherein the sultone-based compound is included in an amount ranging from 0.1 to 5 wt % based on the total amount of the electrolyte solution is provided.Type: ApplicationFiled: August 17, 2012Publication date: May 16, 2013Applicant: Samsung SDI Co., Ltd.Inventors: Mi-Hyeun Oh, Ho-Seok Yang, Dai-In Park, Jin-Hyunk Lim
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Publication number: 20130115520Abstract: The present invention relates to a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range and an electrochemical element produced by using the same. Provided are (1) a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises an organic tin compound represented by the specific formula in an amount of 0.001 to 5% by mass of the nonaqueous electrolytic solution and (2) an electrochemical element comprising a positive electrode, a negative electrode and a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the above nonaqueous electrolytic solution is the nonaqueous electrolytic solution of (1) described above.Type: ApplicationFiled: July 22, 2011Publication date: May 9, 2013Applicant: UBE INDUSTRIES, LTD.Inventors: Koji Abe, Kei Shimamoto
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Publication number: 20130059210Abstract: An electrolyte for a rechargeable lithium battery and rechargeable lithium battery including the same is provided. The electrolyte includes a film-forming compound; a lithium salt; and an organic solvent.Type: ApplicationFiled: May 2, 2012Publication date: March 7, 2013Applicant: SAMSUNG SDI CO., LTD.Inventors: Jung-Yi YU, Woo-Cheol SHIN, Sang-II HAN, Mi-Hyun LEE, Tae-Hyun BAE
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Publication number: 20130029230Abstract: An electrolyte for the lithium secondary battery having flame retardancy, low negative electrode interfacial resistance, and excellent high temperature properties and life characteristics, and a lithium secondary battery including the same. An electrolyte for lithium secondary battery of the present invention may include a non-aqueous organic solvent, a lithium salt, fluorinated ether or phosphazene, and a resistance-improving additive represented as the following chemical formula (1): RSO2—R1—SO2F??[Chemical Formula 1] wherein R1 is a C1-C12 hydrocarbon unsubstituted or substituted with at least one fluorine.Type: ApplicationFiled: October 3, 2011Publication date: January 31, 2013Applicant: SAMSUNG SDI, CO., LTD.Inventors: Sinyoung Park, Yongbeom Lee, Sunyoung Kim, Bora Lee
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Publication number: 20130029232Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, a separator and an ionic liquid electrolyte. The separator is a polar porous membrane. The ionic liquid electrolyte and the separator made of the polar porous are used in the lithium ion secondary batteries, which can improve the electrochemical performance of the lithium ion secondary batteries.Type: ApplicationFiled: July 25, 2012Publication date: January 31, 2013Applicant: Microvast New Materials (Huzhou) Co., LTD.Inventors: ZHUOQUN ZHENG, Bin Gu, Hong Wang, Liaoying Ke, Yunhua Nie
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Publication number: 20130022879Abstract: Provided is a nonaqueous electrolyte secondary battery which, even in the case of using a low-viscosity solvent having a narrow potential window, can increase the electrochemical stability of the nonaqueous electrolyte solution and suppress side reactions of the nonaqueous electrolyte solution during charge and discharge to reduce the degradation of the battery characteristics and has an excellent storage characteristic in high-temperature environments and a nonaqueous electrolyte solution for the nonaqueous electrolyte secondary battery.Type: ApplicationFiled: April 28, 2011Publication date: January 24, 2013Applicants: MITSUBISHI CHEMICAL CORPORATION, SANYO Electric Co., Ltd.Inventors: Hidekazu Yamamoto, Kouhei Tuduki, Taizou Sunano, Maruo Kamino, Youichi Ohashi, Minoru Kotato
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Publication number: 20120315550Abstract: The invention relates to a graphene-modified lithium iron phosphate positive electrode active material and a method for preparing the same, as well as a lithium-ion secondary cell based on this positive electrode active material. The positive electrode active material is prepared by a method in which graphene or graphene oxide and lithium iron phosphate are dispersed in an aqueous solution, agitated and ultrasonicated to mix homogeneously and for a mixture, dried to obtain a lithium iron phosphate material compounded with graphene or graphene oxide, and annealed at high temperature to obtain finally a graphene-modified lithium iron phosphate positive electrode active material. When compared with conventional modified lithium cells coated with carbon or doped with conductive polymers, the lithium-ion secondary cell based on this positive electrode active material features high cell capacity, good cycling performance of charge and discharge, long life and high cycle stability, and has great utility value.Type: ApplicationFiled: January 22, 2010Publication date: December 13, 2012Applicant: Ningbo Institute of Materials Technology and Engineering, Chinese Academy of SciencesInventors: Zhaoping Liu, Xufeng Zhou
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Patent number: 8329343Abstract: An electrode includes: an electrode collector and an electrode active material layer, wherein a film containing a salt represented by the following formula (I) is provided on the electrode active material layer: R1AnMx ??(I) wherein R1 represents an n-valent organic group containing a sulfur atom; n represents an integer of from 1 to 4; A represents an anion; M represents a metal ion; and x represents an integer of 1 or more.Type: GrantFiled: August 4, 2009Date of Patent: December 11, 2012Assignee: Sony CorporationInventors: Hiroyuki Yamaguchi, Toru Odani, Masayuki Ihara, Tadahiko Kubota
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Patent number: 8318361Abstract: Disclosed is a composition for a gel polymer electrolyte, the composition comprising: (i) a cyclic compound as a first crosslinking agent, the cyclic compound containing a cyclic group at the center thereof and having at least three double bonds at the end thereof; (ii) a linear or branched compound as a second crosslinking agent, the linear or branched compound containing an oxyalkylene group at the center thereof and having at least two (meth)acryl groups at the end thereof; (iii) an electrolyte solvent; (iv) an electrolyte salt; and (v) a polymerization initiator. Also, disclosed are a gel polymer electrolyte formed by polymerizing the composition for a gel polymer electrolyte, and an electrochemical device comprising the gel polymer electrolyte.Type: GrantFiled: September 7, 2007Date of Patent: November 27, 2012Assignee: LG Chem, Ltd.Inventors: Sung-Hoon Yu, Jeong-Ju Cho, Soo-Jin Kim, Soo-Hyun Ha
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Publication number: 20120276456Abstract: Electrolyte, comprising an aprotic solvent, a lithium salt as conducting salt, and an additive, characterized in that the additive is a compound which contains a protonable nitrogen atom and is hydrolysable by water.Type: ApplicationFiled: August 27, 2010Publication date: November 1, 2012Applicant: LI-TEC BATTERY GMBHInventors: Peter Pilgram, Rolf-Walter Terwonne, Denny Thiemig, Joerg Kaiser, Andreas Gutsch
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Patent number: 8298709Abstract: A secondary battery capable of improving the cycle characteristics while securing the initial charge and discharge characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode has an anode active material layer containing a plurality of anode active material particles having silicon (Si). The anode active material layer contains at least one of an oxide-containing film covering a surface of the anode active material particles and a metal material not being alloyed with an electrode reactant provided in a gap in the anode active material layer. The electrolytic solution contains a solvent containing an organic acid that has a portion including an electron attractive group such as —(O?)C—C(?O)— bond in the center and a hydroxyl group on the both ends.Type: GrantFiled: March 10, 2009Date of Patent: October 30, 2012Assignee: Sony CorporationInventors: Masayuki Ihara, Hiroyuki Yamaguchi, Tadahiko Kubota
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Publication number: 20120251895Abstract: An electrolyte for a lithium secondary battery, the electrolyte including a lithium salt, a non-aqueous organic solvent, and an additive represented by Formula 1 below: wherein CY1 and R1 through R7 are the same as defined above; and a lithium secondary battery containing the electrolyteType: ApplicationFiled: March 27, 2012Publication date: October 4, 2012Applicant: Samsung Electronics Co., Ltd.Inventors: Jun-young MUN, Yoon-sok Kang, Jin-hwan Park, Min-sik Park
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Publication number: 20120237837Abstract: The present invention generally relates to electrochemical batteries, and more specifically, to the combined additives in the non-aqueous electrolyte for rechargeable lithium-ion batteries containing spinel-based cathode that may enhance the performance of the batteries. The mixed additives comprising of 1,8-bis(dialkylamino)naphthalene, wherein alky group is described by CnH2n+1, n=1 to 3, and vinylene carbonate (VC) are added to the electrolyte of the lithium-ion batteries greatly improve the capacity recovery and reduce AC impedance growth during the high temperature storage. The incorporation of the two kinds of additives within the electrolyte of the battery can also improve the high temperature cycling performance.Type: ApplicationFiled: March 18, 2011Publication date: September 20, 2012Applicants: E-ONE MOLI ENERGY (CANADA) LIMITED, E-ONE MOLI ENERGY CORPORATIONInventors: Yong-Shou LIN, Li FENG
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Publication number: 20120225359Abstract: This invention described the preparation of a series of compounds selected from the group comprising tris(1,1,1,3,3,3-hexafluoro-iso-propyl)phosphate, tris(perfluoroethyl)phosphate, tris(perfluoro-iso-propyl)phosphate, bis(1,1,1-trifluoroethyl)fluorophosphate, tris(1,1,1-trifluoroethyl)phosphate, hexakis(1,1,1-trifluoroethoxy)phosphazene, tris(1,1,1-trifluoroethoxy)trifluorophosphazene, hexakis(perfluoro-t-butyl)phosphazene and tris(perfluoro-t-butyl)phosphate. These compounds may be used as co-solvents, solutes or additives in non-aqueous electrolytes in various electrochemical devices. The inclusion of these compounds in electrolyte systems can enable rechargeable chemistries at high voltages that are otherwise impossible with state-of-the-art electrolyte technologies. These compounds are chosen because of their beneficial effect on the interphasial chemistries formed at high potentials, such as 5.0 V class cathodes for new Li ion chemistries.Type: ApplicationFiled: April 13, 2012Publication date: September 6, 2012Applicant: U.S. Government as represented by the Secretary of the ArmyInventors: Kang Conrad Xu, Arthur von Wald Cresce
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Publication number: 20120219866Abstract: This invention relates to a nonaqueous electrolytic solution including a lithium salt and an organic solvent containing: a carbonate and/or an ester in a total proportion exceeding 90% by volume; and a fluorine-substituted aromatic ester represented by formula (I) in an amount of 0.01%-10% by weight based on the weight of the electrolytic solution: Xn-Ph-OCOR??(1). The invention also relates to a nonaqueous electrolytic solution including an electrolyte, a nonaqueous solvent, and a compound represented by formula (3): The invention also relates to a nonaqueous-electrolyte battery including a nonaqueous electrolytic solution as described above.Type: ApplicationFiled: February 29, 2012Publication date: August 30, 2012Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Masamichi Onuki, Minoru Kotato, Koji Fukamizu, Yumiko Machida, Youichi Ohashi
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Patent number: 8252468Abstract: A non-aqueous electrolyte secondary cell is provided having enhanced safety against overcharge and reduced self-discharge. The non-aqueous electrolyte secondary cell includes: a positive electrode having a positive electrode active material; a negative electrode having a negative electrode active material; and a non-aqueous electrolyte containing a non-aqueous solvent and electrolytic salt. The non-aqueous solvent contains 20 to 80 volume % tertiary carboxylic acid ester represented by Formula 2 at 25° C. and 1 atm. The non-aqueous electrolyte contains a halogenated benzene compound. where R1 to R4 each denote a straight-chained or branched alkyl group having 4 or less carbon atoms and may be the same or different.Type: GrantFiled: July 11, 2011Date of Patent: August 28, 2012Assignee: SANYO Electric Co., Ltd.Inventor: Kentaro Takahashi
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Patent number: 8252467Abstract: A non-aqueous electrolyte secondary cell is provided having enhanced safety against overcharge and reduced self-discharge. The non-aqueous electrolyte secondary cell includes: a positive electrode having a positive electrode active material; a negative electrode having a negative electrode active material; and a non-aqueous electrolyte containing a non-aqueous solvent and electrolytic salt. The non-aqueous solvent contains 20 to 80 volume % tertiary carboxylic acid ester represented by formula 1 at 25° C. and 1 atm. The non-aqueous electrolyte contains an alkylbenzene compound and/or a halogenated benzene compound. where R1 to R4 each denote a straight-chained or branched alkyl group having 4 or less carbon atoms and may be the same or different.Type: GrantFiled: December 23, 2008Date of Patent: August 28, 2012Assignee: SANYO Electric Co., Ltd.Inventor: Kentaro Takahashi
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Publication number: 20120214043Abstract: A lithium sulfur battery comprising an electrolyte solvent which comprises at least one fluorosubstituted compound is described. Preferred fluorosubstituted compounds which are predominantly solvents are notably selected from the group consisting of fluorosubstituted carboxylic acid esters, fluorosubstituted carboxylic acid amides, fluorosubstituted fluorinated ethers, fluorosubstituted carbamates, fluorosubstituted cyclic carbonates, fluorosubstituted acyclic carbonates, fluorosubstituted ethers, perfluoroalkyl phosphoranes, fluorosubstituted phosphites, fluorosubstituted phosphates, fluorosubstituted phosphonates, and fluorosubstituted heterocycles. Monofluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred.Type: ApplicationFiled: October 26, 2010Publication date: August 23, 2012Applicant: SOLVAY FLUOR GMBHInventors: Jens Olschimke, Martin Bomkamp, Johannes Eicher
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Publication number: 20120202124Abstract: Disclosed is a lithium secondary battery. The lithium secondary battery includes a cathode, an anode, a separator and a non-aqueous electrolyte solution. Either the cathode or the anode or both include metal oxide coating layers on electrode active material particles forming the electrode or a metal oxide coating layer on the surface of an electrode layer formed on a current collector. The non-aqueous electrolyte solution contains an ionizable lithium salt, an organic solvent, and a dinitrile compound having a specific structure. In the lithium secondary battery, degradation of the electrode is prevented and side reactions of the electrolyte solution are inhibited. Therefore, the lithium secondary battery exhibits excellent cycle life and output performance characteristics.Type: ApplicationFiled: April 16, 2012Publication date: August 9, 2012Inventors: Jong-Ho JEON, Doo-Kyung Yang, Sung-Hoon Yu, Min-Hyung Lee
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Publication number: 20120196191Abstract: Disclosed is a lithium secondary battery. The lithium secondary battery includes a cathode, an anode, a separator and a non-aqueous electrolyte solution. The separator includes a porous substrate, and a coating layer coated on at least one surface of the porous substrate and including a mixture of inorganic particles and a binder polymer. The non-aqueous electrolyte solution contains an ionizable lithium salt, an organic solvent, and a dinitrile compound having a specific structure. The lithium secondary battery is very safe without side reactions of the electrolyte solution. Therefore, the lithium secondary battery exhibits excellent cycle life and output performance characteristics.Type: ApplicationFiled: April 16, 2012Publication date: August 2, 2012Inventors: Jong-Ho JEON, Doo-Kyung Yang, Sung-Hoon Yu, Min-Hyung Lee
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Publication number: 20120183866Abstract: The present invention relates to electrochemical storage devices containing a non-aqueous lithium based electrolyte with high ionic conductivity, low impedance, and high thermal stability. More particularly, this invention relates to the design, synthesis and application of novel fluorinated arylboron oxalate based compounds which act as anion receptors and/or additives for non-aqueous batteries. When used as an anion receptor for non-aqueous battery electrolytes, the fluorinated arylboron oxalate enhances conductivity, lithium ion transference number and Solid Electrolyte Interface (SEI) formation capability during the formation cycling.Type: ApplicationFiled: July 26, 2010Publication date: July 19, 2012Applicant: Brookhaven Science Associates ,LLCInventors: Hung Sui Lee, Xiao-Qing Yang, Kyung-Wan Nam, Xiaojian Wang
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Publication number: 20120176089Abstract: Disclosed is a lithium secondary battery including a positive electrode comprising a combination of positive active materials. The combination includes a material represented by one or both of Formulae 1 and 2; and a material of Formula 3 as follows: LiaNibMncMdO2??(Formula 1) where 0.90?a?1.2; 0.5?b?0.9; 0<c<0.4; 0?d?0.2; LiaNibCocMndMeO2??(Formula 2) where 0.90?a?1.2, 0.5?b?0.9, 0<c<0.4, 0<d<0.4, and 0?e?0.2; LiaCoMbO2??(Formula 3) where 0.90?a?1.2 and 0?b?0.2; and each M of Formulae 1-3 is independently selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, P, As, Sb, Bi, S, Se, Te, Po, and combinations.Type: ApplicationFiled: March 19, 2012Publication date: July 12, 2012Inventors: Duck-Chul Hwang, Geun-Bae Kim, Yong-Chul Park, Won-II Jung, Jun-Won Suh, Jan-Dee Kim
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Patent number: 8216725Abstract: Electrolyte for lithium secondary batteries and battery packs includes a lithium salt, a non-aqueous solvent, and an additive. The additive includes two or more members selected from the group consisting of substances A, B and C, wherein A includes one or more fused ring compounds and fused heterocyclic compounds, B includes an alkoxy aromatic compound, and C includes halogenated borane-based salt.Type: GrantFiled: January 13, 2009Date of Patent: July 10, 2012Assignee: BYD Company LimitedInventors: Yi Gao, JiangMin Zhu
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Publication number: 20120171574Abstract: A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound.Type: ApplicationFiled: January 3, 2011Publication date: July 5, 2012Inventors: Aruna Zhamu, ChenGuang Liu, David Neff, Bor Z. Jang, Zhenning Yu
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Publication number: 20120121990Abstract: An electrolyte for a lithium secondary battery, the electrolyte comprising: a lithium salt, a non-aqueous organic solvent, and an additive represented by Formula 1 below: wherein R1, R2, R3, and R4 are the same as defined in the detailed description.Type: ApplicationFiled: June 29, 2011Publication date: May 17, 2012Applicant: Samsung Electronics Co., Ltd.Inventors: Yoon-sok KANG, Seok-soo Lee, Young-gyoon Ryu, Jin-hwan Park, Mi-jeong Song
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Publication number: 20120028133Abstract: Provided are an electrolyte which may prevent the degradation of the battery performance by including a functional group which can react with a side reaction site which is responsible for decomposition of negative electrode material components and a functional group which can react with moisture which is responsible for decomposition of positive electrode material components in an electrolyte of the battery to ensure the stability of the battery at high temperatures, and a secondary battery manufactured by adding the same. The present invention may employ a compound including a functional group which can react with a side reaction site of a negative electrode material and a functional group which can react with moisture to maximize the improvement of the storage performance of a secondary battery at high temperatures.Type: ApplicationFiled: March 2, 2010Publication date: February 2, 2012Applicant: LG CHEM, LTD.Inventors: Yo Jin Kim, Han Ho Lee, Seung Don Choi
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Publication number: 20120021296Abstract: A nonaqueous electrolyte battery includes: a positive electrode; a negative electrode; and a nonaqueous electrolyte, wherein the nonaqueous electrolyte contains a solvent, an electrolyte salt, and a polyacid and/or a polyacid compound, and the solvent contains a chain carboxylate with a total carbon number of 4 or more.Type: ApplicationFiled: June 28, 2011Publication date: January 26, 2012Applicant: SONY CORPORATIONInventors: Yusuke Funada, Shunsuke Saito, Haruo Watanabe, Tadahiko Kubota
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Patent number: 8097368Abstract: The present invention provides a non-aqueous electrolyte secondary battery comprising a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte, wherein the non-aqueous electrolyte comprises a non-aqueous solvent and lithium salt as an electrolyte, and wherein the non-aqueous solvent contains chain fluorinated carboxylic acid ester represented by the formula CH3COOCH2CH3-xFx (wherein x is 2 or 3) and a film forming chemical decomposed in the range of +1.0 to 3.0 V based on an equilibrium potential between metal lithium and lithium ion.Type: GrantFiled: July 22, 2009Date of Patent: January 17, 2012Assignees: Sanyo Electric Co., Ltd., Kanto Denka Kogyo Co., Ltd.Inventors: Takanobu Chiga, Hiroyuki Matsumoto, Ryo Mogi, Osamu Omae, Masafumi Kobayashi
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Publication number: 20120009487Abstract: A non-aqueous electrolyte solution for a lithium secondary battery includes a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent. The lithium salt includes LiN(CF3SO2)2. The non-aqueous electrolyte solution further includes a sulfate-based compound and vinylene carbonate. A lithium secondary battery having the above non-aqueous electrolyte solution may keep overall high temperature performance in a high level and also improve low temperature power characteristics.Type: ApplicationFiled: March 26, 2010Publication date: January 12, 2012Applicant: LG CHEM, LTD.Inventors: Ra-Young Hwang, Ji-Sang Yu
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Publication number: 20110318654Abstract: A composite material comprising a reaction product of (A) at least one organic polymer, (B) sulfur and (C) carbon in a polymorph which comprises at least 60% sp2-hybridized carbon atoms, and additionally particles or domains which comprise carbon (C) filled with sulfur (B).Type: ApplicationFiled: May 26, 2011Publication date: December 29, 2011Applicant: BASF SEInventor: Nicole JANSSEN
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Publication number: 20110318655Abstract: A non-aqueous electrolyte secondary battery is described, capable of inhibiting the raise of the internal resistance at a low temperature after use in a high-temperature circumstance, and having a good power performance at a low temperature. The non-aqueous electrolyte secondary battery has a non-aqueous electrolyte, and is characterized in containing a sulfate ester with a specific structure in an amount of 4.0 wt % or less relative to the total weight of the non-aqueous electrolyte.Type: ApplicationFiled: June 27, 2011Publication date: December 29, 2011Applicant: GS YUASA INTERNATIONAL LTD.Inventors: YUDAI KAWASOE, KATSUSHI NISHIE, TOMONORI KAKO, SHINYA KITANO
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Publication number: 20110269028Abstract: A non-aqueous electrolyte secondary cell is provided having enhanced safety against overcharge and reduced self-discharge. The non-aqueous electrolyte secondary cell includes: a positive electrode having a positive electrode active material; a negative electrode having a negative electrode active material; and a non-aqueous electrolyte containing a non-aqueous solvent and electrolytic salt. The non-aqueous solvent contains 20 to 80 volume % tertiary carboxylic acid ester represented by Formula 2 at 25° C. and 1 atm. The non-aqueous electrolyte contains a halogenated benzene compound. where R1 to R4 each denote a straight-chained or branched alkyl group having 4 or less carbon atoms and may be the same or different.Type: ApplicationFiled: July 11, 2011Publication date: November 3, 2011Applicant: SANYO ELECTRIC CO., LTD.Inventor: Kentaro Takahashi
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Patent number: 8043749Abstract: An electrolyte for a lithium ion secondary battery and a lithium ion secondary battery comprising the electrolyte. The electrolyte comprises a non-aqueous organic solvent, a lithium salt, and at least one aromatic phosphate compound. Exothermic reactions are inhibited in the battery upon overcharge or during high-temperature storage to prevent an increase in the temperature of the battery, resulting in an improvement in safety. In addition, the battery exhibits good swelling stability during high-temperature storage as well as improved cycle life characteristics. The electrolyte further comprises an ethylene carbonate-based compound. The presence of the ethylene carbonate-based compound leads to further improvements in the overcharge safety, high-temperature safety and cycle life characteristics of the battery.Type: GrantFiled: July 28, 2009Date of Patent: October 25, 2011Assignee: Samsung SDI Co., Ltd.Inventor: Jaehou Nah
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Publication number: 20110236768Abstract: A non-aqueous electrolyte secondary battery that includes a non-aqueous electrolyte solution containing a non-aqueous solvent and an electrolyte, and vinylene carbonate (C3H2O3) and Li[M(C2O4)xRy] at 0.6 parts by weight or more and 3.9 parts by weight or less in total to 100 parts by weight of the non-aqueous electrolyte solution, wherein M is selected from the group consisting of P, Al, Si, and C; R is selected from the group consisting of a halogen group, an alkyl group, and a halogenated alkyl group; x is a positive integer; and y is 0 or a positive integer.Type: ApplicationFiled: June 7, 2011Publication date: September 29, 2011Inventor: Satoshi Tani
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Publication number: 20110236766Abstract: There are disclosed electrolytes comprising solutions of lithium salts with large anions in polar aprotic solvents with a particular concentration of background salts. The concentration of the background salts is selected to be equal or close to the concentration of a saturated solution of these salts in the aprotic solvents used. The electrolytes disclosed can be used in chemical sources of electric energy such as secondary (rechargeable) cells and batteries comprising sulphur-based positive active materials. The use of such electrolytes increases cycling efficiency and cycle life of the cells and batteries.Type: ApplicationFiled: June 3, 2011Publication date: September 29, 2011Inventors: Vladimir KOLOSNITSYN, Elena KARASEVA
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Publication number: 20110207000Abstract: An electrochemical system is provided by the present invention which includes a positive electrode; a negative electrode; an electrolyte containing a lithium salt dissolved in a non-aqueous solvent; and a nitrile component in the electrolyte. A preferred nitrile component is an aromatic nitrile. Also described is a process for inhibiting electrolyte decomposition wherein an initial cycle is performed on an inventive electrochemical system such that a solid-electrolyte interphase forms on the anode, inhibiting electrolyte decomposition.Type: ApplicationFiled: September 7, 2006Publication date: August 25, 2011Inventors: T. Richard Jow, Shengshui Zhang, Conrad Xu
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Publication number: 20110195316Abstract: Disclosed is a lithium battery including: a positive electrode including manganese dioxide as a positive electrode active material; a negative electrode including at least one selected from lithium metal and a lithium alloy, as a negative electrode active material; a porous insulating member interposed between the positive electrode and the negative electrode; and an organic electrolyte. The organic electrolyte contains 0.0008 to 1.2% by weight of an alkyl ester of an aliphatic hydroxycarboxylic acid. The alkyl ester may be a C1-6 alkyl ester of an aliphatic hydroxycarboxylic acid having 2 to 7 carbon atoms, such as a C1-4 alkyl 4-hydroxybutyrate.Type: ApplicationFiled: June 18, 2010Publication date: August 11, 2011Inventor: Kenichi Morigaki
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Publication number: 20110183216Abstract: Disclosed is a non-aqueous electrolyte including an electrolyte salt and an electrolyte solvent, the non-aqueous electrolyte further including a compound containing both a carboxy group and a (meth)acrylic group, and a secondary battery including the non-aqueous electrolyte. The use of the compound containing both the carboxy group and the (meth)acrylic group as a component for an electrolyte significantly reduces the increase of battery thickness at high temperature storage.Type: ApplicationFiled: August 8, 2008Publication date: July 28, 2011Applicant: LG CHEM, LTD.Inventors: Soojin Kim, Jeong-ju Cho
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Publication number: 20110183215Abstract: A new cathode design is provided comprising a cathode active material mixed with a binder and a conductive diluent in at least two differing formulations. Each of the formulations exists as a distinct cathode layer. After each layer is pressed or sheeted individually, a first one of the layers is contacted to a current collector. The other layer is then contacted to the opposite side of the layer contacting the current collector. Therefore, by using electrodes comprised of layers, where each layer is optimized for a desired characteristic (i.e. high capacity, high power, high stability), the resulting battery will display improved function over a wide range of applications. Such an exemplary cathode is comprised of: SVO (100?x %)/SVO (100?y %)/current collector/SVO (100?y %)/SVO (100?x %), wherein x and y are different and represent percentages of non-active materials.Type: ApplicationFiled: April 2, 2007Publication date: July 28, 2011Applicant: Greatbatch Ltd.Inventors: Amy C. Marschilok, Randolph A. Leising, Esther S. Takeuchi
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Publication number: 20110171539Abstract: The invention relates to a positive electrode/electrolyte pair for lithium batteries operating at a voltage above 4.2 V versus Li+/Li. The electrolyte of the lithium battery used in the invention includes at least a first additive chosen from optionally substituted, cyclic or acyclic, carboxylic or dicarboxylic anhydrides and carboxylic or dicarboxylic acids, and mixtures thereof, and optionally a second additive which is a lithium salt, the total content of additive(s) being greater than or equal to 0.01% by weight and less than or equal to 30% by weight, relative to the total weight of electrolyte, and the positive electrode is made of a material having a spinel structure. The lithium batteries of the invention are applicable in particular in the field of portable equipment, such as telephones, computers, camcorders, cameras and tooling.Type: ApplicationFiled: June 11, 2009Publication date: July 14, 2011Inventors: Sébastien Patoux, Carole Bourbon, Sébastien Martinet, Carole Pagano
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Publication number: 20110117448Abstract: An object of the invention is to provide an inexpensive non-aqueous electrolyte secondary battery that allows reversible charge and discharge to be carried out. The non-aqueous electrolyte secondary battery according to the invention includes a positive electrode, a negative electrode containing carbon capable of storing and releasing potassium, and a non-aqueous electrolyte including potassium ions.Type: ApplicationFiled: January 20, 2006Publication date: May 19, 2011Inventors: Takao Inoue, Masahisa Fujimoto
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Publication number: 20110045361Abstract: A nonaqueous electrolytic solution for lithium battery comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a carboxylate compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution. (In the formula R1 and R2 each independently represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; R3 represents a hydrogen atom, a methyl group, or a group —CH2CO2CR1R2C?CH (R1 and R2 have the same meaning as above) .) A lithium battery uses the nonaqueous electrolytic solution having excellent cycle property and storage property.Type: ApplicationFiled: March 18, 2009Publication date: February 24, 2011Applicant: UBE INDUSTRIES, LTD.Inventors: Koji Abe, Kazuhiro Miyoshi
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Publication number: 20110045359Abstract: The invention relates to reactive ionic liquids containing organic cations with groups or substituents which are susceptible to electrochemical reduction and anions obtained from fluoroalkyl phosphates, fluoroalkyl phosphinates, fluoroalkyl phosphonates, acetates, triflates, imides, methides, borates, phosphates and/or aluminates, for use in electrochemical cells, such as lithium ion batteries and double-layer capacitors.Type: ApplicationFiled: March 31, 2009Publication date: February 24, 2011Applicant: MERCK PATENT GESELLSCHAFTInventors: Michael Schmidt, Nikolai (Mykola Ignatyev, William-Robert Pitner
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Patent number: 7879499Abstract: An electrolyte for a lithium ion secondary battery includes a non-aqueous organic solvent; lithium salt; and difluoro oxalato borate and fluoro ethylene carbonate (FEC). The capacity retention property and durability of a lithium ion secondary battery including the electrolyte is excellent even when the battery is left at a high temperature.Type: GrantFiled: August 13, 2009Date of Patent: February 1, 2011Assignee: Samsung SDI Co., Ltd.Inventors: Jinsung Kim, Narae Park, Jinhyunk Lim, Suhee Han, Jinbum Kim, Jungkang Oh
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Publication number: 20110008683Abstract: The invention discloses a method of increasing the cycle life of rechargeable battery with a negative electrode (anode) made of lithium or lithium-containing alloys and electrolyte/salt solution which comprises one or more non-aqueous organic solvents and one or more lithium salts, the method comprising adding to the electrolyte/salt solution a lithium dendrite scavenging additive in an amount sufficient that a rate of lithium dendrite formation is equal to or lower than a rate of lithium dissolution occurring due to interaction with the dendrite scavenging additive dissolved in the electrolyte.Type: ApplicationFiled: September 20, 2010Publication date: January 13, 2011Inventors: Vladimir KOLOSNITSYN, Elena KARASEVA
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Patent number: 7867294Abstract: A process is provided to produce non-aqueous electrolytic solution for use in batteries having low acid content and low water content. The invention involves removing acids and water from non-aqueous electrolytic solutions typically found in lithium or lithium-ion batteries by using nitrogen-containing compounds such as triazines. After treatment by a triazine such as melamine, the concentrations of acids and water in the electrolytic solutions are substantially decreased. The present invention provides a process to prepare extremely pure electrolytic solutions having low (<20 ppm) concentrations of both water and acids.Type: GrantFiled: April 14, 2010Date of Patent: January 11, 2011Assignee: Novolyte Technologies Inc.Inventors: Zhongyi Deng, Jerry L. Decker, Wu Xu, John R. Sans, Pascal Bolomey
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Publication number: 20100304225Abstract: The invention relates to an electrolyte formulation comprising a) an ionic liquid which is electrochemically stable over a range of at least 4.5 V, has a viscosity of less than 300 mPa·s at 20° C. and has a conductivity of at least 1 mS/cm at 20° C., and b) an aprotic, dipolar solvent in an amount of 20 to 60% by volume based on the electrolyte formulation, wherein the conductivity of the electrolyte formulation is greater at least by a factor of 2 than the conductivity of the ionic liquid.Type: ApplicationFiled: May 28, 2008Publication date: December 2, 2010Applicant: EVONIK DEGUSSA GmbHInventors: Matthias Pascaly, Armin Modlinger, Martin Schuster, Roy Van Hal, Claus Hilgers, Marc Uerdingen
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Patent number: 7745048Abstract: Disclosed is a rechargeable lithium polymer battery comprising a negative electrode including a negative active material layer deposited on a substrate, a positive electrode including a positive active material; and a polymer electrolyte including a lithium salt, an organic solvent, and a polymer.Type: GrantFiled: October 21, 2004Date of Patent: June 29, 2010Assignee: Samsung SDI Co., Ltd.Inventors: Duck-Chul Hwang, Yun-Suk Choi, Chung-Kun Cho, Sang-Mock Lee
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Publication number: 20100143806Abstract: A mixture of low-acid lithium borate salts and lithium hydride, to methods for producing the same and to the use thereof for battery electrolytes.Type: ApplicationFiled: July 3, 2008Publication date: June 10, 2010Inventors: Rainer Dietz, Ulrich Wietelmann, Uwe Lischka
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Publication number: 20100143797Abstract: A secondary lithium battery electrolyte including a lithium salt, a nonaqueous organic solvent, and an electrolyte additive represented by Formula 1: where n is an integer in the range of 1 to 4. A secondary lithium battery having excellent cycle and high temperature retention characteristics can be provided by using such secondary lithium battery electrolyte.Type: ApplicationFiled: September 15, 2009Publication date: June 10, 2010Applicant: Samsung SDI Co., LtdInventors: Seok-soo LEE, Young-gyoon RYU, Dong-Ioon LEE