Control Of Electrolyte Or Water Patents (Class 429/450)
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Patent number: 8394517Abstract: A fuel cell system comprises a fuel cell, a reactant gas supply device, and a capacitor which supplies a power to various devices when the fuel cell is in a temporary power generation stop state. The fuel cell system drives the reactant gas supply device based on a predetermined current instruction value to supply a reactant gas to the fuel cell, thereby generating the power. Such a fuel cell system comprises a control device which judges whether or not the current instruction value is below a water balance zero current value when the water content of the fuel cell is below a predetermined threshold and the stored electric charge of the capacitor is a predetermined threshold or more. If affirmative judgment is obtained, the control device switches the power generation state of the fuel cell to the temporary power generation stop state.Type: GrantFiled: July 17, 2008Date of Patent: March 12, 2013Assignee: Toyota Jidosha Kabushiki KaishaInventor: Shigeto Kajiwara
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Patent number: 8383281Abstract: A fuel cell system has a flooding elimination mode as one of available operation modes of fuel cells and includes a drive controller. When the ambient temperature of the fuel cell system is not higher than a preset first temperature, the drive controller causes the fuel cells to be driven in the flooding elimination mode. When the ambient temperature of the fuel cell system is not lower than a preset second temperature that is higher than the first temperature, the drive controller prohibits the fuel cells from being driven in the flooding elimination mode. On the occasion of input of a checkup instruction of the fuel cells, the drive controller causes the fuel cells to be driven in the flooding elimination mode, independently of the ambient temperature. This arrangement effectively improves the user's convenience at the checkup time of the fuel cell system having the operation mode for eliminating the state of flooding.Type: GrantFiled: October 15, 2008Date of Patent: February 26, 2013Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shigeto Kajiwara, Shinji Aso
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Patent number: 8357473Abstract: When a stop trigger of a fuel cell system (100) is turned on, air humidified by a humidifier (3) which air having a humidity quantity lower than a humidity quantity at a normal operation is supplied to a fuel cell stack (11). Thereby, a takeout quantity Qm of a moisture generated in the fuel cell stack (1) is increased, then, a power generation of the fuel cell stack (1) is continued for a certain time Pg. Then, the power generation is stopped, and a cathode side of the fuel cell stack (1) is purged with the air for a certain time Pp.Type: GrantFiled: October 27, 2005Date of Patent: January 22, 2013Assignee: Nissan Motor Co., Ltd.Inventor: Keigo Ikezoe
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Publication number: 20130004874Abstract: A fuel cell system including a fuel cell and operated under a non-humidified condition is provided. The fuel cell includes a polymer electrolyte membrane sandwiched between an anode electrode and a cathode electrode, a fuel gas channel supplying the anode electrode with fuel gas containing at least a fuel component, and an oxidant gas channel supplying the cathode electrode with oxidant gas containing at least an oxidant component. The flow directions of the fuel gas and the oxidant gas are opposite each other. In addition, the fuel cell system has a moisture state control means which controls a flow rate and/or pressure of the fuel gas so that once a moisture state in an inlet region of the fuel gas channel is changed to a low moisture state side which is lower than a target moisture state, it is changed from the low moisture state to the target moisture state.Type: ApplicationFiled: January 28, 2011Publication date: January 3, 2013Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Ryoichi Nanba, Yasushi Araki
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Publication number: 20120315563Abstract: A coolant demineralizer is disclosed for a fuel cell, which removes ions released from coolant for cooling a fuel cell stack to pipes. In particular the demineralizer reduces the occurrence of differential pressure due to an ion resin layer such that the coolant smoothly flows through the demineralizer, thereby maximizing the effect of filtering ions and, at the same time, the utilization of the ion resin. To this end, the demineralizer includes a housing having an inlet port, through which coolant is introduced to pass through an interior space of the housing, and an outlet port through which the coolant is discharged; and a filter member having a plate-shape such that the coolant introduced through the inlet port passes through the filter member in a direction perpendicular to the filter member.Type: ApplicationFiled: October 13, 2011Publication date: December 13, 2012Applicants: KIA MOTORS CORPORATION, HYUNDAI MOTOR COMPANYInventors: Sung Wook Na, Hun Woo Park
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Patent number: 8329767Abstract: The present invention is a method for forming a hydrophilic polymer membrane for use in a membrane electrode assembly, comprising the polymerization of a material or materials from which the membrane may be formed, wherein the polymerization is by UV curing.Type: GrantFiled: April 3, 2008Date of Patent: December 11, 2012Assignee: ITM Power (Research) Ltd.Inventor: Donald James Highgate
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Patent number: 8329347Abstract: A fuel cell system includes a water vapor transport device having a wet flow field layer having a coarse microtruss structure disposed between a pair of fine microtruss structures. The coarse and fine microtruss structures of the wet flow field layer are formed from a radiation-sensitive material. A dry flow field layer has a coarse microtruss structure disposed between a pair of fine microtruss structures. The coarse and fine microtruss structures of the dry flow field layer are also formed from a radiation-sensitive material. A membrane is disposed between the wet flow field layer and the dry flow field layer and adapted to permit a transfer of water vapor therethrough from the wet fluid to the dry fluid to form a humidified fluid.Type: GrantFiled: February 8, 2010Date of Patent: December 11, 2012Assignee: GM Global Technology Operations LLCInventors: Jeffrey A. Rock, Yeh-Hung Lai, Gerald W. Fly
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Publication number: 20120299384Abstract: This disclosure relates to energy storage and generation systems, e.g., combination of flow battery and hydrogen fuel cell, that exhibit operational stability in harsh environments, e.g., both charging and discharging reactions in a regenerative fuel cell in the presence of a halogen ion or a mixture of halogen ions. This disclosure also relates to energy storage and generation systems that are capable of conducting both hydrogen evolution reactions (HERs) and hydrogen oxidation reactions (HORs) in the same system. This disclosure further relates to energy storage and generation systems having low cost, fast response time, and acceptable life and performance.Type: ApplicationFiled: January 24, 2011Publication date: November 29, 2012Inventors: Emanuel Peled, Arnon Blum, Adi Aharon, Nina Travitsky, Yaron Konra, Ido Tsamir, Vladimir Zel, Kobby Saadi, Meital Alon, Roy Gorenshtein
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Patent number: 8318364Abstract: A fuel cell system includes a fuel cell stack for generating power and power generation control means. The fuel cell stack has at least one cell that includes a cathode to which an oxidant is supplied, an anode to which a fuel is supplied, and a polymer electrolyte membrane sandwiched between the cathode and the anode. The power generation control means has dryness degree determination means for determining the degree of dryness of the fuel cell stack based on shut-down period. When the shut-down period is shorter than a predetermined period of time, the power generation control means supplies a gas for drying to the cathode for a predetermined period of time, to remove water remaining in the cathode. When the shut-down period is equal to or longer than the predetermined period of time, such a drying operation is not performed.Type: GrantFiled: July 7, 2009Date of Patent: November 27, 2012Assignee: Panasonic CorporationInventors: Hiroaki Matsuda, Hideyuki Ueda
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Patent number: 8309261Abstract: This invention provides a fuel cell system which can render the distribution of water in an electrolyte membrane even without lowing the pressure of a fuel system (1) comprises an electrolyte membrane (11), an oxidant electrode provided on one side of the electrolyte membrane (11), and a fuel electrode provided on the other side of the electrolyte membrane (11). An oxidant gas flow passage (14) for supplying an oxidant gas along the face of the oxidant electrode and a fuel gas flow passage (15) for supplying a fuel has along the face of the fuel electrode are provided so that the flow direction of the oxidant gas faces the flow direction of the fuel gas. A control unit (50) conducts control so that, when the electrolyte membrane (11) is dry, the flow rate of the fuel gas which flows through the fuel gas flow passage (15) is increased.Type: GrantFiled: June 30, 2008Date of Patent: November 13, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Takuya Hashimoto, Hideki Kubo
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Patent number: 8304123Abstract: A fuel cell system is provided that is capable of operating at high temperatures and near-ambient pressure with partial humidification of air supplied to the fuel cell stack. The fuel cells of the stack incorporate gas diffusion barrier layers at the cathode side thereof. The system includes a cooling loop for circulating a liquid coolant through the stack. In some embodiments, an incoming air stream is partially humidified with water vapor transferred from a cathode exhaust stream in a gas-exchange humidifier or enthalpy wheel. In other embodiments, a cathode recycle is employed to partially humidify the incoming air. The humidity of the air and cathode exhaust streams is maintained below a stack saturation point. Methods of operating the fuel cell system are also provided.Type: GrantFiled: April 28, 2008Date of Patent: November 6, 2012Assignees: Daimler AG, Ford Motor CompanyInventors: Richard A. Sederquist, Brian W. Wells, Alexander Mossman, Craig R. Louie
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Patent number: 8293412Abstract: A fuel cell system includes a solid oxide reversible fuel cell (SORFC) stack that is adapted to generate an exhaust stream containing hydrogen and water vapor from an outlet of the SORFC stack when the SORFC stack is operated in an electrolysis mode, a polymer electrolyte membrane (PEM) hydrogen pump that is adapted to separate at least a portion of the hydrogen contained in the exhaust stream, a first conduit that is adapted to provide the exhaust stream from the outlet of the SORFC stack into an inlet of the PEM hydrogen pump, and a second conduit that is adapted to provide at least a portion of remaining exhaust stream from an outlet of the PEM hydrogen pump into an inlet of the SORFC stack.Type: GrantFiled: November 20, 2007Date of Patent: October 23, 2012Assignee: Bloom Energy CorporationInventor: James F. McElroy
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Patent number: 8277999Abstract: A fuel cell system has an apparatus sending gas to the fuel cell; a part calculating an amount of residual water in the fuel cell system based on an operating and an environmental condition; a part judging whether at least one state quantity value that includes a generating duration of the fuel cell, an amount of electric power generated, and an amount of temperature change of a coolant is equal to or less than a prescribed threshold value; a part calculating a sending apparatus operating time for decreasing the residual water amount to a prescribed value; and a control part operating the gas sending apparatus until the end of the operating time, wherein the operating time calculating part calculates a different operating time depending on whether one of the state quantity values is equal to or less than a prescribed threshold value.Type: GrantFiled: January 30, 2007Date of Patent: October 2, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Takahide Izutani, Nobuyuki Kitamura
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Patent number: 8277998Abstract: An electrochemical fuel cell having an anode, an ion transfer membrane and a cathode has liquid water delivered to the fluid flow channels within the cathode so as to maintain a relative humidity of 100% throughout the fluid flow channels. A calibration method and apparatus is described for determining an optimum quantity or range of quantities of liquid water to be delivered to the cathode fluid flow channels under varying operating conditions. An operating method and apparatus is described that ensures an optimum quantity of liquid water is delivered to the cathode fluid flow channels under varying operating conditions.Type: GrantFiled: December 31, 2004Date of Patent: October 2, 2012Assignees: Intelligent Energy LimitedInventors: Jeremy Stephen Matcham, Nathan Grange, Paul Alan Benson, Scott Baird, Ashley Kells, Jonathan Cole, Paul L. Adcock, Peter David Hood, Simon Edward Foster
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Patent number: 8277988Abstract: An anode reactant recycling system for a fuel cell is disclosed, the system including a hollow main body, a bleed conduit, an injector, a water separator, and a hydrophilic porous media. The anode reactant recycling system for a fuel cell is adapted to minimize a required number of components, eliminate the need for the anode heat exchanger, use a single valve for removal of condensate and reactant byproducts from the anode reactant recycling system, and provide an upstream volume for startup pressurization.Type: GrantFiled: March 4, 2009Date of Patent: October 2, 2012Assignee: GM Global Technology Operations LLCInventors: Steven G. Goebel, Steven R. Falta, Jon P. Owejan
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Patent number: 8268501Abstract: A fuel cell system has produced water amount detection means that detects the amount of water produced in the fuel cell during low-efficiency operation of the system and gas supply limitation means that limits the amount of gas to be supplied to the fuel cell, based on the detected amount of water. The produced water amount detection means allows the amount of produced water to be correctly determined during low-efficiency operation of the fuel cell, thereby enabling the appropriate warm-up, and inhibits a condition, in which the amount of produced water is too large and warm up operation is hindered, to be generated. As a result, the amount of water produced during low-efficiency operation of the fuel cell is correctly determined and the appropriate warm-up is enabled.Type: GrantFiled: December 11, 2007Date of Patent: September 18, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Go Tejima
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Patent number: 8263270Abstract: A fuel cell vehicle is provided with a fuel cell which generates electric power by a reaction of a reaction gas and discharges water, a tank which accumulates water discharged from the fuel cell, a heater which vaporizes water accumulated in the tank, a discharge valve which switches between accumulating and discharging of the water with respect to the tank, an external air temperature sensor which detects an external air temperature, a vehicle speed sensor which detects a vehicle speed, a selector with which the driver selects an operation of the discharge valve between accumulating and discharging of the water with respect to the tank, and an ECU which controls these components and includes a control section and a control data storage section.Type: GrantFiled: April 4, 2006Date of Patent: September 11, 2012Assignee: Honda Motor Co., Ltd.Inventor: Katsumi Kanasugi
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Publication number: 20120219872Abstract: A fuel cell system according to the present invention includes: a hydrogen generator; a burner; an air supply device; a fuel cell; a condenser configured to condense an exhaust reducing gas to recover condensed water, the exhaust reducing gas being discharged from the fuel cell; a condensed water tank configured to store the condensed water recovered by the condenser; a water level detector configured to detect a water level in the condensed water tank; a degasifier configured to remove a carbonic acid component contained in the condensed water by using an exhaust oxidizing gas discharged from the fuel cell; a water conveyance passage configured to connect the condensed water tank and the degasifier and including a water sealing structure at a portion thereof; a water level changing unit configured to change the water level in the condensed water tank; and a controller, and the controller causes the water level changing unit to change the water level in the condensed water tank, and when the water level detecType: ApplicationFiled: December 1, 2010Publication date: August 30, 2012Applicant: PANASONIC CORPORATIONInventors: Yoshikazu Tanaka, Akinari Nakamura, Takayuki Urata
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Patent number: 8252469Abstract: There is disclosed a fuel cell system including a fuel cell, a water discharge channel through which a water content discharged from this fuel cell flows, and a water discharge valve which discharges, from the system, the water content in this water discharge channel, and the fuel cell system further includes a water discharge control section for controlling the water discharge valve so as to inhibit the water discharge from the water discharge valve from a time when the starting of the system is requested to a time when the temperature of the system reaches a predetermined temperature, in a case where the starting of the system is requested in an environment where an outside air temperature is less than a predetermined threshold value.Type: GrantFiled: October 16, 2007Date of Patent: August 28, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Yoshiaki Naganuma
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Patent number: 8252473Abstract: A vehicle equipped with a fuel cell recognizes an external characteristic of a following mobile unit. Corresponding to the recognized characteristic, the vehicle controls the permission, the amount and the prohibition of discharge of the water produced along with electricity generation of the fuel cell.Type: GrantFiled: September 17, 2008Date of Patent: August 28, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Takahide Izutani
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Patent number: 8252474Abstract: An object of the invention is to provide a fuel cell system capable of improving accuracy of water content estimation during a standstill. A fuel cell system includes a fuel cell having a plurality of single cells laminated together and an estimating unit for estimating residual water content distributions in a fuel gas flow channel and an oxidation gas flow channel and a moisture content distribution in an electrolyte membrane in a cell plane of each single cell while taking into consideration water transfer that occurs between an anode electrode and a cathode electrode via the electrolyte membrane. The estimating unit estimates a residual water content of the fuel gas flow channel during a standstill from a shutdown to a restart of the fuel cell system based on temperature information on each single cell acquired during the standstill.Type: GrantFiled: June 17, 2011Date of Patent: August 28, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Masahiro Okuyoshi, Masaaki Matsusue, Masashi Toida
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Patent number: 8241800Abstract: A fuel cell system includes: a polymer electrolyte fuel cell; a resistance sensor that detects the internal resistance of the fuel cell; a dew point sensor that detects the dew point of anode off gas from the fuel cell; and a controller that executes an electrolyte membrane hydration control according to the relationship between the internal resistance and the dew point. According to this configuration, it is possible to define, based on the relationship between the internal resistance and the dew point, the conditions under which the decreased power generation performance of the cell may be quickly recovered.Type: GrantFiled: April 30, 2008Date of Patent: August 14, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Yasushi Araki
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Patent number: 8232012Abstract: The invention pertains to a process for operating a polymer electrolyte membrane fuel cell (PEMFC), said PEMFC comprising: (a) a membrane comprising at least one fluorinated ionomer [polymer (I)] comprising recurring units derived from tetrafluoroethylene (TFE) and from at least one monomer of formula (M): wherein m is an integer between 1 and 6 and X? is chosen among halogens (Cl, F, Br, I), —O?M+, wherein M+ is a cation selected among H+, NH4+, K+, Li+, Na+, or mixtures thereof, said polymer (I) having an equivalent weight (EW) of from 700 to 850 g/eq.; (b) a cathode; (c) an anode; said process comprising: (i) feeding gaseous reactants at the electrodes at a relative humidity of at most 66%; (ii) maintaining an average current density between 0.05 and 1.5 A/cm2; and (iii) maintaining an average temperature of more than 65° C.Type: GrantFiled: December 20, 2007Date of Patent: July 31, 2012Assignee: Solvay Solexis S.p.A.Inventors: Vincenzo Arcella, Alessandro Ghielmi, Luca Merlo
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Patent number: 8227134Abstract: Disclosed are self-hydrating membrane electrode assemblies (MEAs), including MEAs that have been magnetically modified, which comprises (i) a cathode comprising an electrically conducting material having a catalytic material on at least a portion of a first surface thereof, the catalytic material comprising an effective amount of at least one catalyst component and at least one ion conducting material; (ii) a separator adjacent to and in substantial contact with the first surface of the cathode and comprising an ion conducting material; and (iii) an anode adjacent to and in substantial contact with the surface of the separator opposite the cathode and comprising an electrically conducting material having a catalytic material on at least a portion of a surface thereof adjacent to the separator, the catalytic material comprising an effective amount of at least one catalyst component and at least one ion conducting material; wherein the separator permits water to pass from the first surface of the cathode to theType: GrantFiled: October 15, 2003Date of Patent: July 24, 2012Assignee: University of Iowa Research FoundationInventors: Johna Leddy, Wayne L. Gellett, Drew C. Dunwoody
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Patent number: 8221610Abstract: An electrochemical method for providing hydrogen using ammonia, ethanol, or combinations thereof, comprising: forming an anode comprising a layered electrocatalyst, the layered electrocatalyst comprising at least one active metal layer deposited on a carbon support; providing a cathode comprising a conductor; disposing a basic electrolyte between the anode and the cathode; disposing a fuel within the basic electrolyte; and applying a current to the anode causing the oxidation of the fuel, forming hydrogen at the cathode.Type: GrantFiled: May 4, 2008Date of Patent: July 17, 2012Assignee: Ohio UniversityInventor: Gerardine G. Botte
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Publication number: 20120178010Abstract: The present invention provides a fuel cell having a membrane electrode assembly disposed between a first diffusion media that has a first set of material characteristics and a second diffusion media that has a second set of material characteristics. The membrane electrode assembly and the first and second diffusion media provide a cell assembly. The cell assembly provides a water transport mechanism that selectively controls water transportation across a thickness of the first and second diffusion media and through the membrane electrode assembly. The first set of material characteristics has at least one material characteristic substantially different from at least one material characteristic of the second set of material characteristics. The selection of the first and second set of material characteristics defines the water transport mechanism for managing hydration of the first and the second diffusion media.Type: ApplicationFiled: March 19, 2012Publication date: July 12, 2012Inventors: CHUNXIN JI, STEVEN R. FALTA, JEANETTE E. OWEJAN
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Publication number: 20120178009Abstract: A fuel cell plate includes a structure having opposing sides bounded by a periphery providing at least one edge. Gas flow channels are arranged on the one side and arranged within a perimeter that is spaced inboard from the periphery to provide a first gasket surface between the perimeter and the periphery. Inlet and outlet flow channels are arranged on the other side and extend to the periphery and are configured to provide gas at the at least one edge. Holes extend through the structure and fluidly interconnect the inlet and outlet flow channels to the gas flow channels. In one example, the fuel cell plate is a water transport plate in a fuel cell having external manifolds that supply fluid to the plate.Type: ApplicationFiled: November 9, 2009Publication date: July 12, 2012Inventors: Robert A. Love, Jeffrey G. Lake
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Patent number: 8211589Abstract: A diffusion media for use in a fuel cell stack and that is adjacently aligned with lands of a reactant plate of the fuel cell stack. The diffusion media includes a sheet having a permeable material with a thickness. A plurality of water transport pores are defined through the sheet. Each of the pores has a pore diameter that is greater than 1.5 times the thickness.Type: GrantFiled: October 4, 2005Date of Patent: July 3, 2012Inventor: Joerg Roth
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Patent number: 8192880Abstract: A fuel cell system of the invention includes, a fuel cell, a water reservoir configured to accumulate water discharged from the fuel cells, and a status estimator configured to estimate a status of the water reservoir based on a stated of the fuel cell.Type: GrantFiled: October 16, 2008Date of Patent: June 5, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Naoki Kanie, Masahiro Okuyoshi
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Patent number: 8187760Abstract: A fuel-cell system is advantageous for repressing water from flowing backward from a reservoir to a condenser, flowing backward which results from the inside of the condenser being turned into negative pressure. The fuel-cell system has a fuel cell for generating electric power by reactant gas, a condenser for generating condensed water by condensing water content included in the reactant gas to be supplied to the fuel cell or in off gas of the reactant gas, and a reservoir for reserving the condensed water collected at the condenser. A drain valve is disposed between the condenser and the reservoir. The drain valve is switchable between a closed state in which communication between the condenser and the reservoir is shut off and an opened state in which the condenser is communicated with the reservoir to discharge the water in the condenser to the reservoir. A controller carries out inner-pressure increment and drain controls for opening the drain valve after increasing inner pressure in the condenser.Type: GrantFiled: February 26, 2007Date of Patent: May 29, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Junichi Yokoyama
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Patent number: 8182952Abstract: There is disclosed a fuel cell system capable of drying a fuel cell in a short time after a system stop instruction is issued. The fuel cell system includes a controller to control the execution of a normal operation and a dry operation which decreases the water content of the fuel cell as compared with the normal operation. The controller executes the dry operation prior to the system stop instruction so that the water content of the fuel cell is decreased as compared with the normal operation at a time of the system stop instruction. The controller may execute the dry operation before the system stop instruction in a case where it is predicted that the temperature of the fuel cell at the system stop or the next system start is a predetermined low temperature.Type: GrantFiled: October 29, 2007Date of Patent: May 22, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hiroaki Tanaka, Kazuhiro Watanabe
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Patent number: 8173311Abstract: A fuel cell system and method for controlling relative humidity in a fuel cell system. A controller can be signally coupled to one or more sensors and configured to operate at least one flow manipulation device in response to changes in a relative humidity of a reactant passing through the cathode flowpath of the fuel cell in order to maintain the relative humidity within a prescribed range. The controller correlates one or more of a temperature setpoint, pressure setpoint, stoichiometry setpoint or actual operating condition of any of them to an operating condition of the system. In this way, a desired level of relative humidity can be achieved, maintained or both while minimizing the use of power-robbing flow manipulation devices, such as a pump, compressor, fan or related component.Type: GrantFiled: February 26, 2007Date of Patent: May 8, 2012Assignee: GM Global Technology Operations LLCInventors: Sebastian Lienkamp, Matthew C. Kirklin
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Patent number: 8148027Abstract: The present invention refers to a self-humidifying electrically conducting composite material for the manufacture of a fuel cell.Type: GrantFiled: September 7, 2007Date of Patent: April 3, 2012Assignees: Nanyang Technological University, Gashub Technology Pte LtdInventors: Ming Han, Siew Hwa Chan
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Patent number: 8133623Abstract: A fuel cell including a fuel cell stack having a fuel cell unit provided with, in order to enable appropriate control of a wet state before power generation efficiency of the fuel cell is reduced, a polymer electrolyte membrane having one surface thereof provided with an oxidizer electrode and another surface thereof provided with a fuel electrode. The fuel cell unit includes plural power generation cell units and a pair of wet state detection cell units.Type: GrantFiled: March 16, 2011Date of Patent: March 13, 2012Assignee: Canon Kabushiki KaishaInventor: Satoshi Mogi
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Patent number: 8129055Abstract: Moisture caused by humidity in the fuel gas and water vapor from the water that is generated become condensed inside a fuel cell when power generation in the fuel cell is temporarily stopped, making obstruction to the fuel gas flow channel when power generation is restarted possible. A fuel cell includes an electrolyte membrane sandwiched between a fuel electrode and an oxidant electrode. Oxidant is supplied to the oxidant electrode in the fuel cell, and the fuel emitted from the fuel electrode of the fuel cell is resupplied back to the fuel electrode. When requested power generating capacity for the fuel cell is less than a prescribed capacity, the oxidant supply is temporarily stopped while the fuel continues to circulate in order to prevent obstruction in the fuel flow channel due to water condensation, making a reliable fuel supply becomes possible.Type: GrantFiled: September 2, 2005Date of Patent: March 6, 2012Assignee: Nissan Motor Co., Ltd.Inventors: Hitoshi Igarashi, Keisuke Suzuki, Masatoshi Iio
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Patent number: 8114549Abstract: In a polymer electrolyte membrane fuel cell, a groove (cathode-side gas flow path) in a cathode-side separator, and a groove (anode-side gas flow path) in an anode-side separator are formed such that air and hydrogen flow in a direction opposite to the direction of gravity. A surface treatment may applied to the surface of the grooves such that the hydrophilicity is higher on the downstream side than on the upstream side in the grooves.Type: GrantFiled: September 10, 2007Date of Patent: February 14, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Koichi Numata
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Patent number: 8101312Abstract: A fuel cell stack include a first group of cells, provided in the vicinity of the overall negative end of a fuel cell stack, and second group of cells, provided throughout the remainder of the fuel cell stack. The first cells have a higher resistance to flooding than the second cells, and the overall polarity of the fuel cell stack is reversed, the end of the stack where the water content is largest is made overall positive.Type: GrantFiled: January 25, 2007Date of Patent: January 24, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shigetaka Hamada, Masaaki Kondo
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Publication number: 20120003551Abstract: A fuel cell includes an electrode assembly having an electrolyte between an anode and a cathode for generating an electric current and byproduct water. A porous plate is located adjacent to the electrode and includes reactant gas channels for delivering a reactant gas to the electrode assembly. A separator plate is located adjacent the porous plate such that the porous plate is between the electrode assembly and the separator plate. The separator plate includes a reactant gas inlet manifold and a reactant gas outlet manifold in fluid connection with the reactant gas channels, and a purge manifold in fluid connection with the porous plate such that limiting flow of the reactant gas from the reactant gas outlet manifold and opening the purge manifold under a pressure of the reactant gas in the reactant gas channels drives the byproduct water toward the purge manifold for removal from the fuel cell.Type: ApplicationFiled: March 18, 2009Publication date: January 5, 2012Inventors: Paravastu Badrinarayanan, Kazuki Amemiya
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Publication number: 20120003560Abstract: A fuel cell includes an electrode assembly having an electrolyte between a cathode catalyst and an anode catalyst, and a flow field plate having a channel for delivering a reactant gas to the electrode assembly. The flow field plate includes a channel having a channel inlet. A porous diffusion layer is located between the electrode assembly and the flow field plate. The porous diffusion layer includes a first region near the channel inlet and a second region downstream from the first region relative to the channel inlet. The first region includes a filler material that partially blocks pores of the first region such that the first region has a first porosity and the second region has a second porosity that is greater than the first porosity.Type: ApplicationFiled: March 18, 2009Publication date: January 5, 2012Inventors: Jeremy P. Meyers, Michael L. Perry, Carl A. Reiser, Ned E. Cipollini, Wayde R. Schmidt, Gopal R. Krishnan, John A. Trela, Robert M. Darling
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Patent number: 8084162Abstract: In a case of consuming a power generation reaction inducing gas, which causes lowering in performance and degradation of a fuel cell during suspension of operation thereof, and in a case of performing warm up at a time of activation at low temperatures, in order to automatically perform short circuiting control, there is provided a fuel cell having a structure including a switch which is switchable in accordance with a state of containing water generated in a power generation portion.Type: GrantFiled: May 18, 2007Date of Patent: December 27, 2011Assignee: Canon Kabushiki KaishaInventors: Akira Morita, Akiyoshi Yokoi, Toru Nakakubo, Satoshi Mogi
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Patent number: 8080342Abstract: A fuel cell system determines a water blockage or a dry state of the system using voltage sensors that determine anode and cathode voltages of single fuel cells as well as a total voltage for the fuel cell system. The system also compensates for water blockages or dry states by adjusting supplies of fuel and oxidation gases to the system.Type: GrantFiled: March 7, 2006Date of Patent: December 20, 2011Assignee: Nissan Motor Co., Ltd.Inventor: Yuichiro Tabuchi
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Publication number: 20110300458Abstract: A fuel cell assembly includes a fuel cell configuration having a solid electrolyte-based fuel cell with terminal contacts tapping an electrical voltage from the fuel cell configuration between which the fuel cell is disposed. An assembly has an electrically conductive component and another component disposed between a first terminal contact and the electrically conductive component on the side of the first terminal contact away from the fuel cell and has a lower electrical conductivity than that thereof. A supply duct transports a fluid medium connecting the first terminal contact to the electrically conductive component through the other component. The electrically conductive component is connected to the first terminal contact and/or a voltage supply adjusting an electrical potential on the electrically conductive component to an electrical potential on the first terminal contact. There is a maximum potential difference of 3 volts between the electrically conductive component and the first terminal contact.Type: ApplicationFiled: January 27, 2010Publication date: December 8, 2011Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Dieter Illner, Josef Lersch, Arno Mattejat, Walter Stuehler, Franco Tardivo, Ottmar Voitlein
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Patent number: 8071248Abstract: A fuel cell system includes a fuel cell stack, a fuel inlet conduit, a water inlet conduit, and a hydrometer, such as an alcoholometer. The hydrometer is adapted to provide a measurement of a water-to-fuel ratio of a fuel inlet stream within the fuel inlet conduit. The water inlet conduit is adapted to provide a quantity of water to the fuel inlet conduit in order to achieve a desired water-to-ratio being provided to the fuel cell stack.Type: GrantFiled: January 23, 2007Date of Patent: December 6, 2011Assignee: Bloom Energy CorporationInventor: Arne Ballantine
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Patent number: 8057939Abstract: Electrical power generators incorporating stabilized fuels and methods for the encapsulation of fuels are provided. More particularly, methods for the passivation or encapsulation of water reactive, hydrogen gas generating fuels. The electrical power generators employ water reactive fuels encapsulated in a water vapor permeable, liquid water impermeable membrane, or coated with a water vapor permeable, liquid water impermeable substance to control the quantity of water that is permitted reach the chemical fuel. In the event of damage, electrical power generators incorporating the fuels of the invention are protected from explosions that might otherwise result from rapid, uncontrolled hydrogen generation.Type: GrantFiled: December 6, 2005Date of Patent: November 15, 2011Assignee: Honeywell International Inc.Inventors: Steven J. Eickhoff, Roland A. Wood, Thomas M. Rezachek
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Patent number: 8051992Abstract: A water transfer device can include first and second flow paths separated by a water transfer membrane and a hydrophilic diffusion medium. The hydrophilic diffusion medium is disposed between the water transfer membrane and the first flow path. Water content of a first fluid stream flowing through the first flow path is transferred through the diffusion medium and water transfer membrane and into a second fluid stream flowing through the second flow path. The hydrophilic diffusion medium is operable to absorb liquid water in the first fluid stream and hold the absorbed liquid water in contact with the water transfer membrane. The hydrophilic diffusion medium is also operable to diffuse water vapor in the first fluid stream and transport the water vapor to the water transfer membrane. The water transfer membrane transfers the water in contact therewith to the second fluid stream flowing through second flow path.Type: GrantFiled: January 25, 2008Date of Patent: November 8, 2011Assignee: GM Global Technology Operations LLCInventors: Glenn W Skala, Yan Zhang, Annette M Brenner
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Patent number: 8053131Abstract: The present invention provides an apparatus and method for determining deterioration of a fuel cell, the method including measuring in real time fluoride ion concentration or pH value of outflow water from a fuel cell stack during operation in a fuel cell vehicle, calculating a fluoride emission rate from the measured value and, if the calculated fluoride emission rate is out of a predetermined normal range, determining deterioration of an electrolyte membrane of the fuel cell stack.Type: GrantFiled: January 28, 2009Date of Patent: November 8, 2011Assignees: Hyundai Motor Company, Industry-Academy Cooperation Foundation, SCNUInventors: Ik Jae Son, Byung Ki Ahn, Tae Won Lim, Jong Hyun Lee, Kwon Pil Park, Ho Lee, Chang Won Jung, Seung Chan Oh, Jae Jun Ko, Young Min Kim, Sae Hoon Kim, Jong Jin Yoon, Se Joon Im
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Publication number: 20110269046Abstract: The degree of dryness in a fuel cell can be judged more accurately. A system has: an impedance calculation part that calculates an impedance of a fuel cell extracts from the calculated impedance a high-frequency impedance which is an impedance in a high frequency range and a low-frequency impedance which is an impedance in a low frequency range, and subtracts the high-frequency impedance from the low-frequency impedance to calculate a differential impedance; a water content calculation part that calculates the water content of an electrolyte membrane using the high-frequency impedance and calculates the water content of a catalyst layer using the differential impedance; and a water content control part that performs water content recovery processing to increase the water content of the catalyst layer if the water content of the catalyst layer is smaller than a predetermined water content.Type: ApplicationFiled: January 5, 2010Publication date: November 3, 2011Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Keigo Suematsu
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Patent number: 8048581Abstract: A polymer electrolyte membrane (PEM) fuel cell power plant is cooled evaporatively with a water coolant system which does not permit liquid water to exit or flow through the coolant system. The coolant system utilizes a hydrophobic porous member (28) for venting gases such as fuel and/or air from a coolant water flow field in the system. Coolant water (36) is prevented from continuosly contacting the porous member during operation of the power plant thus preventing blockage of the porous member by coolant water or contaminants disposed in the coolant water.Type: GrantFiled: December 16, 2006Date of Patent: November 1, 2011Assignee: VTC Power CorporationInventors: Robert Darling, Craig E. Evans
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Publication number: 20110253465Abstract: Automated systems and methods remove water from a fuel cell powered vehicle and eliminate the need for one or more separate steps to discharge the water. The water may be simultaneously drained or discharged from the vehicle holding tank while the fuel cell powered vehicle is being refueled.Type: ApplicationFiled: April 16, 2010Publication date: October 20, 2011Inventors: Augustus Baldini, Richard Day
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Patent number: 8034502Abstract: A device and method to extract water from a moisture-rich fuel cell flowpath. A water transport unit is integrated into the fuel cell so that liquid water stagnation within flow channels and manifolds is reduced. In one embodiment, the device includes numerous flowpaths that include an active region and an inactive region. The water transport unit includes a hydrophilic member such that upon passage of a fluid with the excess water through the inactive region of the device flowpath and into the presence of the hydrophilic member, it absorbs excess water from the fluid.Type: GrantFiled: April 2, 2007Date of Patent: October 11, 2011Assignee: GM Global Technology Operations LLCInventors: Jon P. Owejan, Thomas W. Tighe, Thomas A. Trabold, Jeffrey A. Rock