Abstract: A fuel cell comprises a cathode catalyst layer and an anode catalyst layer disposed on each surface of an electrolyte membrane, an oxidant gas passage facing the cathode catalyst layer, and a fuel gas passage facing the anode catalyst layer. The cathode catalyst layer contains a metal catalyst. In a region (A), in which the differential electric potential between the cathode catalyst layer and the electrolyte membrane is larger than in another region, the metal catalyst content of the cathode catalyst layer or the specific surface area of the metal catalyst in the form of minute particles is increased, and thus a deterioration in electric power generation efficiency caused by melting of the metal catalyst due to the large differential electric potential is prevented.

Abstract: A solid electrolyte fuel cell comprising a cathode layer 12 formed on one side of a solid electrolyte layer 10 and an anode layer 18 formed on the other side of the solid electrolyte layer 10, wherein the cathode layer 16 comprises a first cathode layer 12 formed in contact with the solid electrolyte layer and a second cathode layer 14 formed covering the first cathode layer 12, the second cathode layer 14 is formed having a higher porosity than the first cathode layer 12 and the first cathode layer 12 is divided into a plurality of island-shaped portions 12a, 12a.

Abstract: According to one embodiment, a fuel cell includes a membrane electrode assembly including a plurality of unit cells which are composed of an electrolyte membrane, an anode including anode catalyst layers arranged at intervals on one of surfaces of the electrolyte membrane, and anode gas diffusion layers stacked on the anode catalyst layers, and a cathode including cathode catalyst layers arranged at intervals on the other surface of the electrolyte membrane and opposed to the anode catalyst layers, respectively, and cathode gas diffusion layers stacked on the cathode catalyst layers, wherein a thickness of at least one of the anode catalyst layer and the cathode catalyst layer of one of the unit cells, which neighbor each other, gradually decreases toward the other of the unit cells.

Abstract: This invention relates in general to components of electrochemical devices, and to methods of preparing the components. The components and methods include the use of a composition comprising an ionically conductive polymer and at least one solvent, where the polymer and the solvent are selected based on the thermodynamics of the combination. In one embodiment, the invention relates to a component for an electrochemical device which is prepared from a composition comprising a true solution of an ionically conductive polymer and at least one solvent, the polymer and the at least one solvent being selected such that |? solvent-? solute|<1, where ? solvent is the Hildebrand solubility parameter of the at least one solvent and where ? solute is the Hildebrand solubility parameter of the polymer.

Abstract: Passive recovery of liquid water from the cathode side of a polymer electrolyte membrane through the design of layers on the cathode side of an MEA and through the design of the PEM, may be used to supply water to support chemical or electrochemical reactions, either internal or external to the fuel cell, to support the humidification or hydration of the anode reactants, or to support the hydration of the polymer electrolyte membrane over its major surface or some combination thereof. Such passive recovery of liquid water can simplify fuel cell power generators through the reduction or elimination of cathode liquid water recovery devices.

Abstract: Provided is a catalyst having high durability with resistance to corrosion in an acidic electrolyte or at high potential and high oxygen reduction activity. The catalyst is a metal oxycarbonitride containing at least one group III transition metal compound and at least one group IV or V transition metal oxide having a crystallite size of 1 to 100 nm. The group III transition metal compound may be a compound of at least one selected from the group consisting of scandium, yttrium, lanthanum, cerium, samarium, dysprosium, and holmium. The group IV or V transition metal oxide may be an oxide of at least one selected from the group consisting of titanium, zirconium, tantalum, and niobium.

Abstract: A fuel cell comprises an electrolyte membrane; first and second catalyst layers formed on respective faces of the electrolyte membrane; and first and second reinforcing layers holding therebetween the electrolyte membrane and the first and second catalyst layers, wherein the first catalyst layer and the first reinforcing layer are joined together with a force of not less than a specific joint strength that suppresses expansion and contraction of the electrolyte membrane, and the second catalyst layer and the second reinforcing layer are joined together with a force of less than a specific joint strength that releases a stress due to expansion and contraction of the electrolyte membrane, or the second catalyst layer and the second reinforcing layer are not joined together.

Abstract: A membrane-electrode assembly having catalyst layers containing an electrode catalyst disposed on the both sides of an electrolyte membrane, wherein at least one of the above-described catalyst layers contains a non-precious metal electrode catalyst and an ionomer having an ion exchange capacity of 1.2 meq/g or more.

Abstract: A fuel cell unit of a fuel cell contains a first membrane electrode assembly having a frame portion on an outer circumference thereof, a first separator, a second membrane electrode assembly having a frame portion on an outer circumference thereof, a second separator, and a third separator. A plurality of resin pins are formed integrally on the frame portion of the first membrane electrode assembly. The resin pins are integrally inserted into holes in the first separator, holes in the second membrane electrode assembly, holes in the second separator, and holes in the third separator.

Abstract: A fuel cell includes an electrolyte electrode assembly, an inner seal member, an outer seal member, a metal separator, and a cell voltage monitor terminal. The electrolyte electrode assembly includes an electrolyte, a pair of electrodes, and a resin frame member. The inner seal member extends around an electrode surface. The outer seal member extends around an outer periphery of the inner seal member. The inner seal member and the outer seal member are disposed on the resin frame member. The cell voltage monitor terminal is embedded in the resin frame member. The cell voltage monitor terminal includes an exposed portion provided between the inner seal member and the outer seal member. The exposed portion is in contact with the metal separator adjacent to the exposed portion.

Abstract: A fuel cell is formed by stacking a plurality of unit cells. Each of the unit cells includes a membrane electrode assembly, and an anode side metal separator and a cathode side metal separator sandwiching the membrane electrode assembly therebetween. In a surface of the cathode side metal separator, metal portions are exposed in at least part of a second flat portion in an area surrounded by seal lines SL of the anode side metal separator. Cutouts are formed on a surface of the cathode side metal separator by cutting at least part of the second flat portion up to the metal portions thereby to expose the metal portions through the cutouts.

Abstract: A fuel cell (1) includes an anode (11), a cathode (14), an electrolyte layer (13) containing ceria and provided between the anode (11) and the cathode (14), and at least two intermediate layers containing zirconia and provided between the electrolyte layer (13) and the anode (11). The at least two intermediate layers include a first intermediate layer (18) that contains ceria and a second intermediate layer (19) that has a higher zirconia concentration than the first intermediate layer and is provided between the first intermediate layer and the anode.

Abstract: A fuel cell electrode that contains a support layer and a catalyst layer, wherein the catalyst layer does not contain a noble metal catalyst and is formed of carbon nanotubes, wherein the carbon nanotubes have pores in sidewalls thereof, and have a pore size distribution of 0.1 nm to 30 nm and a BET specific surface area of 100 to 4,000 m2/g, wherein the pores penetrate or do not penetrate the sidewalls.

Abstract: A fuel cell unit including a membrane electrode assembly (MEA), a cathode collector plate, an anode collector plate, and a plurality of ribs is provided. The cathode collector plate is disposed at one side of the membrane electrode assembly. The anode collector plate is disposed at another side of the membrane electrode assembly. A material of the anode collector plate may be metal. The ribs are respectively disposed on the anode collector plate. A material of the ribs may be metal. The ribs and the anode collector slate form a plurality of gas channels for supplying a reaction gas to the membrane electrode assembly.

Abstract: The present invention provides a polyarylene-based copolymer including a plurality of segments having an ion exchange group and a plurality of segments having substantially no ion exchange group, wherein at least one of the segments having an ion exchange group includes a polyarylene structure, the polystyrene-equivalent weight-average molecular weight of the segments having an ion exchange group is from 10,000 to 250,000, and the ion exchange capacity of the polyarylene-based copolymer is 3.0 meq/g or more.

Abstract: Disclosed are a solid oxide fuel cell including: a) an anode support; b) a solid electrolyte layer formed on the anode support; and c) a nanostructure composite cathode layer formed on the solid electrolyte layer, wherein the nanostructure composite cathode layer includes an electrode material and an electrolyte material mixed in molecular scale, which do not react with each other or dissolve each other to form a single material, and a method for fabricating the same. The fuel cell is operable at low temperature and has high performance and superior stability.

Abstract: A benzoxazine-based monomer includes a halogen atom-containing functional group and a nitrogen-containing heterocyclic group. A polymer formed from the benzoxazine-based monomer may be used in an electrode for a fuel cell and electrolyte membrane for a fuel cell.

Abstract: A fuel cell separator pair has first and second separators having front and back surfaces, a corrugated plate portion shaped in a wave form at the central portion, and a flat plate portion formed in the peripheral portion and surrounding the corrugated plate portion, wherein the corrugated plate portion of the front surface constitutes a reaction gas channel and the corrugated plate portion of the back surface constitutes a coolant channel. The back surfaces of the first and second separators are facing each other. The flat plate portions of the first and second separators are arranged on top of each other so as to be in contact with each other. The flat plate portion of the second separator protrudes toward the outside beyond the flat plate portion of the first separator.

Abstract: Notches 23e are filled with part of an elastic material that is injection-molded in a region containing the notches 23e, so that a plate member 23b is taken in by the notches 23e through the repulsive force of the elastic material. Thus, the plate member 23b is secured. Further, the elastic material filling the notches 23e enlarges the joined portion between the plate member 23b and the gasket 24b. Accordingly, the gasket 24b is firmly joined to the surface of the plate member 23b, and can be prevented from being lifted up from the plate member 23b. Thus, the plate member 23b is firmly secured to the separator main body 25.

Abstract: The substrate-supported anode for a high-temperature fuel cell comprises an at least three-layer anode laminate on a metallic substrate. Each of the layers of the anode laminate comprises yttria-stabilized zirconia and nickel, wherein the mean particle size of the nickel decreases from one layer to the next as the distance from the substrate increases. The last layer of the anode laminate, which is provided for contact with the electrolyte, has a root mean square roughness of less than 4 ?m. The overall mean pore size of this layer is typically between 0.3 and 1.5 ?m. Starting powders having a bimodal particle size distribution of yttria-stabilized zirconia and nickel-containing powder are used at least for the first and second layers of the anode laminate. The mean particle size of the nickel-containing powder is reduced from one layer to the next, whereby it is advantageously no more than 0.5 ?m in the last layer of the anode laminate.

Abstract: An air battery which is capable of improving operating voltage. The air battery includes: an air electrode containing a carbonaceous matter; an anode; and an electrolyte layer containing an electrolyte which conducts ions between the air electrode and the anode, the D/G band ratio X of the carbonaceous matter being 0.058?X?0.18.

Abstract: In a manufacturing method for an electrode-membrane-frame assembly in a fuel cell, a first frame member and an electrolyte membrane member are arranged in a first mold for injection molding such that the edge of the electrolyte membrane member is arranged on the first frame member, a second mold is arranged to form a resin flow passage for forming a second frame member which is in contact with the first frame member by interposing the electrolyte membrane member, and a part of the edge of the electrolyte membrane member is pressed and fixed to the first frame member by a presser member mounted on the second mold and a molding resin material is injected into the resin flow passage to form a second frame member.

Abstract: A fuel cell anode comprises a porous ceramic molten metal composite of a metal or metal alloy, for example, tin or a tin alloy, infused in a ceramic where the metal is liquid at the temperatures of an operational solid oxide fuel cell, exhibiting high oxygen ion mobility. The anode can be employed in a SOFC with a thin electrolyte that can be a ceramic of the same or similar composition to that infused with the liquid metal of the porous ceramic molten metal composite anode. The thicknesses of the electrolyte can be reduced to a minimum that allows greater efficiencies of the SOFC thereby constructed.

Abstract: The invention concerns the use as a redox a catalyst and/or mediator in a fuel cell catholyte solution of the compound of Formula (I) wherein: X is selected from hydrogen and from various functional groups; R1-8 are independently selected from hydrogen and various functional groups; wherein R1 and X and/or R5 and X may together form an optionally substituted ring structure; wherein R1 and R2 and/or R2 and R3 and/or R3 and R4 and/or R4 and R8 and/or R8 and R7 and/or R7 and R6 and/or R6 and R5 may together form an optionally substituted ring structure; wherein (L) indicates the optional presence of a linking bond or group between the two neighbouring aromatic rings of the structure, and when present may form an optionally substituted ring structure with one or both of R4 and R8; and wherein at least one substituent group of the structure is a charge-modifying substituent.

Abstract: A fuel cell separator of the present invention is provided with a reactant gas flow region (8) including a plurality of straight portions (11) and one or more turn portions (12). At least one of one or more turn portions (12) includes a gas mixing portion (12b), a gas meeting portion (12a), and a gas separating portion (12c). Second rib portions (14) are formed in the gas meeting portion (12a) and the gas separating portion (12c). The second rib portions (14) are formed such that the length of an inner second rib portion (14) is shorter than the length of an outer second rib portion (14) in a direction in which the second rib portions (14) extend. An outermost second rib portion (141) located farthest from a center rib portion (13A) is formed so as to be bent inward toward the center line (131).

Abstract: Additives can be used to prepare polymer electrolyte for membrane electrode assemblies in polymer electrolyte fuel cells in order to improve both durability and performance. The additives are chemical complexes comprising certain metal and organic ligand components.

Abstract: Provided is a solid oxide fuel cell (SOFC), including: a fuel electrode for allowing a fuel gas to be reacted; an air electrode for allowing a gas containing oxygen to be reacted; an electrolyte film provided between the fuel electrode and the air electrode; and a reaction prevention film provided between the air electrode and the electrolyte film. The porosity of the reaction prevention film is less than 10%, particularly preferably “closed pore-ratio” is 50% or more. The diameter of closed pores in the reaction prevention film is 0.1 to 3 ?m. The reaction prevention film includes closed pores each containing a component (e.g., Sr) for the air electrode. This can provide an SOFC in which a decrease in output due to an increase in electric resistance between an air electrode and a solid electrolyte film hardly occurs even after long-term use.

Abstract: An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

Abstract: The cathode 114 is formed by forming several layers comprising an inorganic material that is primarily electron conductive and a complex oxide B that is primarily oxygen ion conductive and that supports an oxygen dissociation-promoting catalyst, on an electrolytic membrane 112. The electrolytic membrane 112 and the outermost layer of the cathode 114 (layer of mixture furthest from the electrolytic membrane 112) facing the separator 120 are physically and electrically continuous by means of the inorganic material a and complex oxide B disposed between them.

Abstract: Copolymers comprising at least one recurrent unit of the following formula (I) are provided: and at least one recurrent unit of the following formula (II): wherein: R1 is an alkylene group; Z is a —PO3R3R4, R3 and R4 representing independently of each other, a hydrogen atom an alkyl group, a cation; X and Y represent, independently of each other, a halogen atom, a perfluorocarbon group.

Abstract: A naphthoxazine benzoxazine-based monomer is represented by Formula 1 below: In Formula 1, R2 and R3 or R3 and R4 are linked to each other to form a group represented by Formula 2 below, and R5 and R6 or R6 and R7 are linked to each other to form a group represented by Formula 2 below, In Formula 2, * represents the bonding position of R2 and R3, R3 and R4, R5 and R6, or R6 and R7 of Formula 1. A polymer is formed by polymerizing the naphthoxazine benzoxazine-based monomer, an electrode for a fuel cell includes the polymer, an electrolyte membrane for a fuel cell includes the polymer, and a fuel cell uses the electrode.

Abstract: This invention relates to fuel cells, particularly proton exchange membrane fuel cells, more particularly to proton exchange membrane fuel cells employing nanocomposite sulphonated polystyrene-butadiene rubber-carbon nanoball (SPSBR-CNB) membranes as an electrolyte.

Abstract: A naphthoxazine benzoxazine-based monomer is represented by Formula 1 below: In Formula 1, R2 and R3 or R3 and R4 are linked to each other to form a group represented by Formula 2 below, and R5 and R6 or R6 and R7 are linked to each other to form a group represented by Formula 2 below, In Formula 2, * represents the bonding position of R2 and R3, R3 and R4, R5 and R6, or R6 and R7 of Formula 1. A polymer is formed by polymerizing the naphthoxazine benzoxazine-based monomer, an electrode for a fuel cell includes the polymer, an electrolyte membrane for a fuel cell includes the polymer, and a fuel cell uses the electrode.

Abstract: The solid oxide fuel cell of the present invention has a substrate (1); an electrolyte (3) that is disposed on one surface of the substrate (1); and at least one electrode element E having an anode (5) and a cathode (7) disposed on the same surface of the electrolyte (3) with a predetermined space therebetween.

Abstract: According to the invention, a fuel cell system features a fuel cell (14) having a solid polymer electrolyte membrane (4), and an antioxidant residing in or contacting the solid polymer electrolyte membrane (4), for inactivating active oxygen.

Abstract: An SOFC unit cell 100 includes a fuel-side electrode 110, an electrolyte 120 stacked on the fuel-side electrode 110, and an oxygen-side electrode 130 stacked on the electrolyte 120. The fuel-side electrode 110 is formed of NiO and/or Ni and YSZ. The amount by volume of Ni and/or NiO is 35 to 55 vol. %, as reduced to Ni, on the basis of the entirety of the fuel-side electrode, and the amount by volume of YSZ is 45 to 65 vol. % on the basis of the entirety of the fuel-side electrode. The ratio of the mean particle size of YSZ (R2) to the mean particle size of Ni and/or NiO (R1); i.e., R2/R1, is 0.5 or more. Reduction treatment of the fuel-side electrode 110 after firing is carried out by supplying a reducing gas containing a reducing agent (hydrogen) in an amount of 4 to 100 vol. % at a high temperature of 800° C.

Abstract: A proton (H+)-conducting hydrocarbon (HC)-based polymer electrolyte membrane (PEM) having first and second oppositely facing surfaces comprises a HC-based membrane with at least one perfluoropolymer incorporated on or within at least the first and second surfaces. A method for fabricating the PEM comprises surface treating a HC-based polymeric membrane sheet via immersion in an aqueous solution or dispersion of said at least one perfluoropolymer, followed by drying of the surface treated polymeric membrane sheet.

Abstract: The present invention concerns electrode catalysts used in fuel cells, such as proton exchange membrane (PEM) fuel cells. The invention is related to the reduction of the noble metal content and the improvement of the catalytic efficiency by low level substitution of the noble metal to provide new and innovative catalyst compositions in fuel cell electrodes. The novel electrode catalysts of the invention comprise a noble metal selected from Pt, Pd and mixtures thereof alloyed with a further element selected from Sc, Y and La as well as any mixtures thereof, wherein said alloy is supported on a conductive support material.

Abstract: A fuel cell is disclosed comprising: a power generation layer including an electrolyte membrane, and an anode and a cathode provided on respective surfaces of the electrolyte membrane; a fuel gas flow path layer located on a side of the anode of the power generation layer to supply a fuel gas to the anode while flowing the fuel gas along a flow direction of the fuel gas approximately orthogonal to a stacking direction in which respective layers of the fuel cell are stacked; and an oxidizing gas flow path layer located on a side of the cathode of the power generation layer to supply an oxidizing gas to the cathode while flowing the oxidizing gas along a flow direction of the oxidizing gas opposed to the flow direction of the fuel gas.

Abstract: A catalyst layer includes (i) an electrocatalyst, and (ii) a water electrolysis catalyst, iridium or iridium oxide and one or more metals M or an oxide thereof, wherein M is selected from transition metals and/or Sn, with the exception of ruthenium. Such a catalyst layer has utility in fuel cells that experience high electrochemical potentials.

Abstract: A carbon nanosphere has at least one opening. The carbon nanosphere is obtained by preparing a carbon nanosphere and treating it with an acid to form the opening. The carbon nanosphere with at least one opening has higher utilization of a surface area and electrical conductivity and lower mass transfer resistance than a conventional carbon nanotube, thus allowing for higher current density and cell voltage with a smaller amount of metal catalyst per unit area of a fuel cell electrode.

Abstract: A solid polymer electrolyte membrane having (a) an ion exchange material and (b) dispersed in said ion exchange material, a hydrogen peroxide decomposition catalyst bound to a carbon particle support, wherein the hydrogen peroxide decomposition catalyst comprises (i) polyvinylphosphonic acid and (ii) transition metal with multiple oxidation states or a lanthanide metal with multiple oxidation states.

Abstract: The invention relates to DMFC catalyst coated membranes having improved water crossover and methanol crossover performance, excellent power output and durability, which utilize a thin composite reinforced polymer membrane layer and a thin cathode layer to achieve these performance benefits, and methods of making these catalyst coated membranes. The catalyst coated membrane for use in a direct methanol fuel cell have an anode layer, a thin cathode layer, a thin reinforced ionomer membrane, and do not rely on any additional barrier layers or complex water and/or methanol management layers or peripherals or to improve performance.

Abstract: A solid electrolyte including a layered metal oxide represented by the formula (1), (La1-xAx)(Sr1-yBy)3(Co1-zCz)3O10-???(1) [wherein A represents a rare earth element other than La; B represents Mg, Ca, or Ba; C represents Ti, V, Cr, or Mn; 0?x?1, 0?y?1, 0?z<1; and ? represents an oxygen deficiency amount].

Abstract: A polymer electrolyte comprising at least one aromatic polyether copolymer with main chain pyridine groups and side chain carboxylic acid or carboxylic ester or toluene or methoxy phenyl or hydroxyl phenyl or propenyl or styrene groups and/or pyridine groups, which have the ability to be covalently cross-linked.

Abstract: The disclosed methods enable zirconium sulfophenyl phosphonate, zirconium sulfate, or zirconia sulfate, which has high performance as a proton conducting material and high catalytic activity, to be produced at low temperature by reaction by adding sulfophenyl phosphonic acid or sulfuric acid to zirconium nanoparticles, the zirconium nanoparticles being a precursor of strongly acidic zirconium particles obtained by reacting zirconium alkoxide with zirconium butoxide as a chelating agent and nitric acid as a catalyst in isopropyl alcohol as a solvent.

Abstract: A membrane electrode assembly (MEA) comprises substantially concentric and tubular-shaped layers of a cathode, an anode and an ion-exchange membrane. The MEAs of the invention can be used in an electrochemical cell, which comprises the following layers which are tubular-shaped, arranged substantially concentrically, and listed from the inner layer to the outer layer; (i) a cylindrical core; (ii) one of the electrodes; (iii) a membrane; (iv) the other of the electrodes; and (v) an outer cylindrical sleeve.

Abstract: A fuel cell includes a solid electrolyte layer containing Zr; an intermediate layer containing CeO2 solid solution having a rare-earth element excluding Ce; an air electrode layer containing Sr, the intermediate layer and the air electrode layer being stacked in this order on one surface of the solid electrolyte layer; and a fuel electrode layer on another surface of the solid electrolyte layer which is opposite to the one surface. A value obtained by dividing a content of the rare-earth element excluding Ce by a content of Zr is equal to or less than 0.05 at a site of the solid electrolyte layer, the site being 1 ?m away from an interface between the solid electrolyte layer and the intermediate layer.

Abstract: Provided is a catalyst composition comprising an intermetallic phase comprising Pt and a metal selected from either Nb or Ta, and a dioxide of the metal. Also provided is a low temperature method for making such compositions that results in the formation of intermetallic phase with small crystallite size and thus greater mass activity. In particular, a Pt3Nb—NbO2 catalyst composition can be prepared that is useful as a fuel cell catalyst and offers a very stable chemical substrate along with good electrode activity and remarkable durability. The use of Pt3Nb—NbO2 can considerably prolong fuel cell lifetime by reducing Pt dissolution levels and subsequent voltage losses. The Pt3Nb—NbO2 can be used in the cathode and/or anode of a fuel cell.

Abstract: The present invention relates to a process for operating a fuel cell, especially for operating a fuel cell in which the electrolyte responsible for the proton conduction is volatile. By means of the process according to the invention, better operation of such a fuel cell is possible, and they exhibit an improved lifetime.