Polymeric Material (e.g., Proton Exchange Membrane (pem), Etc.) Patents (Class 429/492)
  • Patent number: 12294092
    Abstract: A membrane electrode assembly includes a cathode, an anode and a proton-conductive membrane, wherein the cathode includes a first metal-containing catalyst and a proton-conductive ionomer, the anode includes a proton-conductive ionomer, a second metal-containing catalyst that catalyzes the reaction of hydrogen to protons, and a third metal-containing catalyst that catalyzes the reaction of CO to CO2, a total mass ratio of platinum of the second catalyst and platinum of the third catalyst to a total mass ratio of metals of the second catalyst and the third catalyst, with the exception of platinum, is greater than 3:1, and the total mass per unit area of platinum of the second catalyst and platinum of the third catalyst is less than 0.4 mg/cm2.
    Type: Grant
    Filed: July 10, 2020
    Date of Patent: May 6, 2025
    Assignee: Greenerity GmbH
    Inventors: Jens-Peter Suchsland, Thomas Martin, Matthias Binder, Dominik Gehrig, Christian Eickes
  • Patent number: 12288911
    Abstract: Disclosed are electrolyte compositions for electrochemical devices, where the electrolyte compositions comprise a microemulsion and where the microemulsion comprises an aqueous phase and a water-immiscible phase. Also disclosed are microemulsion electrolyte compositions for electrically rechargeable electrochemical energy storage devices, including ion batteries (such as lithium ion, sodium ion, magnesium ion, calcium ion, and aluminium ion batteries), redox flow batteries and supercapacitors.
    Type: Grant
    Filed: December 20, 2019
    Date of Patent: April 29, 2025
    Assignee: VICTORIA LINK LIMITED
    Inventors: Rohan Borah, Thomas Nann, Fraser Ross Hughson
  • Patent number: 12276035
    Abstract: To provide a polymer electrolyte membrane which can be applied to a polymer electrolyte water electrolyzer, and is capable of producing a polymer electrolyte water electrolyzer having a low electrolytic voltage and excellent in hydrogen gas recovery efficiency, as well as a membrane electrode assembly and a polymer electrolyte water electrolyzer obtainable by using it. The polymer electrolyte membrane of the present invention contains a polymer electrolyte, of which the hydrogen gas permeation coefficient under the conditions of a temperature of 80° C. and a relative humidity of 10%, is at most 2.4×10?9 cm3·cm/(s·cm2·cmHg), wherein the membrane resistance value under the conditions of a temperature of 80° C. and a relative humidity of 50%, is from 50 to 150 m?·cm2.
    Type: Grant
    Filed: August 20, 2021
    Date of Patent: April 15, 2025
    Assignee: AGC Inc.
    Inventors: Takumi Okuyama, Takeshi Hirai
  • Patent number: 12272845
    Abstract: The present invention relates to a method of coating one or more metal components of a fuel cell stack, such as a bipolar plate, an electrode, gaskets etc., the method comprising the steps of providing an uncoated metal component; etching said uncoated metal component; optionally depositing an adhesion layer on the etched uncoated metal component; and depositing a carbon coating on either the adhesion layer or on the etched uncoated metal component, with the adhesion layer and the carbon coating respectively being deposited by means of one of a physical vapor deposition process, an arc ion plating process, a sputtering process, and a Hipims process. The invention further relates to a component of a fuel cell stack and to an apparatus for coating one or more components of a fuel cell stack.
    Type: Grant
    Filed: August 10, 2020
    Date of Patent: April 8, 2025
    Assignee: IHI HAUZER TECHNO COATING B.V.
    Inventors: Ruud Jacobs, Kenji Fuchigami, Roel Bosch, Dave Doerwald, Philipp Immich
  • Patent number: 12264400
    Abstract: An electrochemical apparatus includes a separator having a first reaction region and a second reaction region; a first reaction layer disposed to correspond to the first reaction region; a second reaction layer disposed to correspond to the second reaction region; a first partition wall portion protruding from one surface of the separator, disposed along a boundary between the first reaction layer and the second reaction layer, and including a first connecting flow path configured to connect the first reaction region and the second reaction region so that the first reaction region and the second reaction region fluidically communicate with each other through the first connecting flow path; and a first sealing member disposed at an end portion of the first partition wall portion and configured to seal a portion between the first reaction layer and the second reaction layer, enlarging a reaction region without increasing a size of a reaction layer.
    Type: Grant
    Filed: February 23, 2022
    Date of Patent: April 1, 2025
    Assignees: Hyundai Motor Company, Kia Corporation
    Inventor: Joon Guen Park
  • Patent number: 12261338
    Abstract: An electrochemical device comprises a first type of membrane disposed between first and second reservoirs containing an input solution, and a second type of membrane, different from the first type, is disposed between a first redox-active electrolyte chamber and the first reservoir and disposed between a second redox-active electrolyte chamber and the second reservoir. The first type of membrane and one of the second type of membranes form a membrane pair and the pair has an area specific resistance below y=5065.3x3?1331.1x2+90.035x+39 Ohm cm2 when the pair is equilibrated in an electrolyte and for at least part of a range where 0<x<0.4 and x is the mass fraction of salt in the electrolyte.
    Type: Grant
    Filed: January 14, 2021
    Date of Patent: March 25, 2025
    Assignee: Xerox Corporation
    Inventors: Eugene S. Beh, Mahati Chintapalli, Francisco E. Torres, Michael Benedict
  • Patent number: 12237552
    Abstract: The present invention relates to a composition for fuel cell membranes and a process for the preparation thereof. In particular, the present invention relates to thermo-mechanically and chemically stable polymer electrolyte membranes which have been prepared without compromising proton conductivity by using multifunctional polydopamine and mechanically robust nanocellulose.
    Type: Grant
    Filed: May 26, 2020
    Date of Patent: February 25, 2025
    Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Kadhiravan Shanmuganathan, Farsa Ram, Ashish Kishore Lele
  • Patent number: 12230806
    Abstract: The positive electrode active material layer is placed on a surface of the positive electrode substrate. The positive electrode active material layer includes a first layer and a second layer. The first layer is interposed between the positive electrode substrate and the second layer. The positive electrode active material layer includes a positive electrode active material, carbon black, and fibrous carbon. A mass fraction of the carbon black in the first layer is higher than a mass fraction of the carbon black in the second layer. A mass fraction of the fibrous carbon in the second layer is higher than a mass fraction of the fibrous carbon in the first layer.
    Type: Grant
    Filed: February 24, 2022
    Date of Patent: February 18, 2025
    Assignee: PRIME PLANET ENERGY & SOLUTIONS, INC.
    Inventors: Shinya Suzuki, Akira Tsujiko
  • Patent number: 12227627
    Abstract: Novel PBI films which may be used in electrochemical cells, such as redox flow batteries, are disclosed. Additionally, disclosed herein are membranes which comprise the novel PBI films which may be free from an organic solvent, and have a tensile strength at break of at least 25 MPa after drying.
    Type: Grant
    Filed: December 11, 2023
    Date of Patent: February 18, 2025
    Assignee: UNIVERSITY OF SOUTH CAROLINA
    Inventors: Laura A. Murdock, Lihui Wang, Fei Huang, Brian C. Benicewicz
  • Patent number: 12227858
    Abstract: The present disclosure relates to a polybenzimidazole-based electrolyte membrane for alkaline water electrolysis, which includes a polybenzimidazole-based polymer, wherein the polybenzimidazole-based polymer is a biaxially oriented film. The polybenzimidazole-based electrolyte membrane for alkaline water electrolysis can reduce the concentration of an alkaline solution by improving the crystallinity of a polybenzimidazole-based polymer to increase the resistance against base, significantly improving the long-term stability of alkaline water electrolysis using a polybenzimidazole-based electrolyte membrane through the improved resistance against base, and by increasing the operation temperature to enhance the catalyst activity.
    Type: Grant
    Filed: January 31, 2022
    Date of Patent: February 18, 2025
    Assignee: Korea Institute of Science and Technology
    Inventors: Hyoung-Juhn Kim, Taekyung Lee, So Young Lee, Hee-Young Park, Bora Seo, Hyun Seo Park, Jong Hyun Jang, Tae Hoon Lim
  • Patent number: 12191548
    Abstract: A hybrid redox fuel cell system includes a hybrid redox fuel cell including an anode side through which a reductant is flowed and a cathode side through which liquid electrolyte is flowed, and a trickle bed reactor including a catalyst bed fluidly connected to the cathode side of the hybrid redox fuel cell. Furthermore, the liquid electrolyte includes a metal ion at a higher oxidation state and the metal ion at a lower oxidation state, and power is generated at the hybrid redox fuel cell by way of reducing the metal ion at the higher oxidation state to the lower oxidation state at the cathode side while oxidizing the reductant at the anode side.
    Type: Grant
    Filed: September 2, 2022
    Date of Patent: January 7, 2025
    Assignee: ESS TECH, INC.
    Inventors: Yang Song, Craig Evans
  • Patent number: 12170168
    Abstract: An electrode suitable for constructing an electrochemical double layer capacitor and/or supercapacitor is provided that includes an electrode material a metal organic framework (MOF), wherein the MOF includes an inorganic building unit including metal atoms selected from group 1 to group 12 elements, and functional groups of organic linkers including oxygen (O) and one or more atoms selected from the group comprising phosphorus (P), arsenic (As), antimony (Sb), silicon (Si), selenium (Se) and bismuth (Bi). The functional groups of the organic linkers can include phosphonate, arsonate, phosphonic acid, phosphinic acid, arsonic acids and/or arsenic acids, monoester and/or diester forms thereof. Further, the metal atoms may be selected from zinc (Zn), cadmium (Cd), copper (Cu), cobalt (Co), nickel (Ni), gold (Au) and silver (Ag). The use of the MOF as a semiconductor in semiconductor applications, a semiconductive device, such as a photovoltaic cell, including the MOF are also provided.
    Type: Grant
    Filed: July 8, 2020
    Date of Patent: December 17, 2024
    Assignee: Technische Universitat Berlin
    Inventor: Gündog Yücesan
  • Patent number: 12162966
    Abstract: To provide a sulfonic acid group-containing polymer which is capable of forming a low hydrogen permeable membrane, which shows a high ion exchange capacity, and which shows a proper softening temperature. The sulfonic acid group-containing polymer has units u1 represented by the following formula u1, units u2 represented by the following formula u2, and units u3 based on tetrafluoroethylene, in the formula u1, RF1 and RF2 are each independently a C1-3 perfluoroalkylene group, and Z+ is a hydrogen ion, a metal ion, or an ammonium ion, —[CF2—CF(CF2O—Rf1)]—??Formula u2 in the formula u2, Rf1 is a perfluoroalkyl group which may contain a SO3?Z+ group and/or an etheric oxygen atom.
    Type: Grant
    Filed: August 20, 2021
    Date of Patent: December 10, 2024
    Assignee: AGC Inc.
    Inventors: Takeshi Hirai, Hiroyuki Watabe, Susumu Saito
  • Patent number: 12148965
    Abstract: A fuel cell assembly includes an CCM layer with a sub-gasket frame around it to provide gas manifolds and sealant. A flow path is integrated on the sub-gasket in vicinity of the inlet and outlet manifolds that provides a passage for the gases to/from the active area. The flow path provides a rigid path without deforming or clogging the passage.
    Type: Grant
    Filed: July 3, 2019
    Date of Patent: November 19, 2024
    Assignee: EH Group Engineering SA
    Inventor: Mardit Matian
  • Patent number: 12119473
    Abstract: Disclosed herein are a folding type lithium air battery and a method for manufacturing the battery. The lithium air battery is configured such that a first electrolyte membrane and a second electrolyte membrane including reinforcing layers and ionic liquids that are suitable for a positive electrode and a negative electrode, respectively, are formed, and a separator including a diffusion prevention membrane is provided between the first electrolyte membrane and the second electrolyte membrane, thus guaranteeing the stability of an electrode, and improving battery performance due to excellent ionic conductivity.
    Type: Grant
    Filed: November 30, 2020
    Date of Patent: October 15, 2024
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventor: Jae Seung Lee
  • Patent number: 12113167
    Abstract: A composite electrolyte, including a sulfide electrolyte, a polymer electrolyte, and a functional additive material are provided. In some embodiments, the functional additive material is selected from polymers represented by the following structural R1—O—R2-A. In some embodiments, R1 is selected from at least one of polyvinyl group, polypropylene group, polyacrylate group, polyvinylcarbonate group, polyacrylonitrile group, and polystyrene group; R2 is a straight-chain or branched alkyl group with 3-10 carbon atoms; A is selected from at least one aromatic hydrocarbon group of benzene group, biphenyl group, triphenyl group, naphthalene group, anthracene group, phenanthrene group, and pyrene group; and X is selected from at least one of hydrogen atom, halogen atom, mercapto group, hydroxyl group, amine group, and aldehyde group.
    Type: Grant
    Filed: May 4, 2023
    Date of Patent: October 8, 2024
    Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
    Inventors: Bobing Hu, Chengyong Liu, Shangju Liao, Xiaoning He, Wenwen Xue, Zhangdi Xie, Shengyuan Huang, Jieliang Zou
  • Patent number: 12113255
    Abstract: Disclosed is an electrolyte membrane for a membrane-electrode assembly including a block copolymer composed of a hydrophilic domain and a hydrophobic domain.
    Type: Grant
    Filed: October 6, 2021
    Date of Patent: October 8, 2024
    Assignees: Hyundai Motor Company, Kia Corporation
    Inventor: Il Seok Chae
  • Patent number: 12095122
    Abstract: A fuel cell system includes a first fluid flow plate including a first plurality of first channels for flow of an oxidant or a fuel. The plurality of first channel has first channel cross-sectional flow areas. A second fluid flow plate includes a second plurality of second channels for flow of an oxidant or a fuel. The plurality of second channels has second channel cross-sectional flow areas. A membrane electrode assembly is located between the first plate and the second plate. The first flow plate includes a passage for a flow of a fluid entirely on a seam side of the first flow plate as the first plurality of first channels. The passage has a cross-sectional area for flow of the fluid smaller than the first channel cross-sectional flow area.
    Type: Grant
    Filed: March 31, 2022
    Date of Patent: September 17, 2024
    Assignee: PLUG POWER INC.
    Inventors: Charles Carlstrom, Owen Carlstrom
  • Patent number: 12080927
    Abstract: Disclosed are an antioxidant for fuel cells, a membrane electrode assembly including the same and a method for preparing the antioxidant. The antioxidant for fuel cells includes a core including at least one selected from the group consisting of a metal oxide (MxOk) and a complex metal oxide (MxNyOj, N and M being different metals), and an outer portion (e.g., a shell) located on or over a surface of the core and formed by performing reduction treatment of the surface of the core using a thiourea-based compound. The outer portion includes metal cations (M(x-n)+, n being a natural number of 1 or more) having a smaller oxidation number than a valency of the metal (M) of the core.
    Type: Grant
    Filed: July 1, 2022
    Date of Patent: September 3, 2024
    Assignees: Hyundai Motor Company, Kia Corporation
    Inventors: Jae Jun Ko, In Yu Park, Bo Ki Hong
  • Patent number: 12062500
    Abstract: The present invention relates to a photovoltaic device (1a) comprising a solar cell unit (2a) including a working electrode comprising a light-absorbing layer (3), a counter electrode including a porous conductive layer (6), and a conducting medium for transferring charges between the counter electrode and the working electrode, and a conductor (7) electrically connected to the porous conductive layer (6). The solar cell unit (2a) comprises at least one adhering layer (8) arranged between the conductor (7) and the porous conductive layer (6) for attaching the conductor to the porous conductive layer. The adhering layer (8) comprises an adhesive and conducting particles distributed in the adhesive so that a conducting network is formed in the adhesive.
    Type: Grant
    Filed: March 17, 2021
    Date of Patent: August 13, 2024
    Assignee: EXEGER OPERATIONS AB
    Inventors: Henrik Lindström, Giovanni Fili
  • Patent number: 12051777
    Abstract: An electrolyte solution for a lithium secondary battery includes an organic solvent, a lithium salt, and a pentaerythritol diphosphite-based compound including at least one substituent selected from the group consisting of a silyl group, a sulfonyl group, a phosphoryl group and a phosphino group. A lithium secondary including the electrolyte solution is provided.
    Type: Grant
    Filed: November 2, 2021
    Date of Patent: July 30, 2024
    Assignee: SK On Co., Ltd.
    Inventors: In Haeng Cho, Myoung Lae Kim, Sung Jin Kim, Jin Hong Lee
  • Patent number: 12051838
    Abstract: A continuous automated process and production line for preparing an acid doped polybenzimidazole, PBI, polymer membrane film for use in a fuel cell, the process comprising a washing stage, a drying procedure, and a doping stage.
    Type: Grant
    Filed: May 5, 2023
    Date of Patent: July 30, 2024
    Assignee: BLUE WORLD TECHNOLOGIES HOLDING APS
    Inventors: Mads Bang, Denys Gromadskyi, Jakob Bork, Larysa Hromadska
  • Patent number: 12051837
    Abstract: The present invention relates to a composite material comprising a porous solid matrix having interconnected channels, said matrix comprising sulfonate groups on at least a part of the surface of said channels, wherein a sulfonate group is in ionic interaction with a quaternary ammonium of a polymerizable molecule. The present invention also relates to a method for preparing such a composite material and applications thereof.
    Type: Grant
    Filed: October 28, 2020
    Date of Patent: July 30, 2024
    Assignees: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE DE FRANCHE-COMTE
    Inventor: Bernard Gauthier-Manuel
  • Patent number: 12034188
    Abstract: A carbon substrate for a gas diffusion layer of a fuel cell, the carbon substrate being a porous carbon substrate having a first surface and a second surface opposite the first surface, the carbon substrate includes a plurality of carbon fibers arranged irregularly to form a non-woven type and a carbide of an organic polymer located between the carbon fibers to bind the carbon fibers to each other, the carbide has a graphite structure, and the carbon substrate has a Bragg diffraction angle 2? of less than 26.435° and a interplanar distance d(002) of less than 3.372 ?, a gas diffusion layer employing the same, an electrode for a fuel cell, a membrane electrode assembly for a fuel cell, and a fuel cell. When the gas diffusion layer is manufactured using the carbon substrate according to the present disclosure, cell voltage characteristics of the fuel cell may be greatly improved.
    Type: Grant
    Filed: December 3, 2019
    Date of Patent: July 9, 2024
    Assignee: JNTG CO., LTD.
    Inventors: Eun Sook Lee, Jy Young Jyoung, Na Hee Kang, Do Hun Kim, Tae Hyung Kim, Eun Chong Kim, Tae Nyun Kim
  • Patent number: 12006216
    Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.
    Type: Grant
    Filed: November 25, 2020
    Date of Patent: June 11, 2024
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Naoki Hasegawa, Kazuhisa Yano, Tomohiro Takeshita, Rui Imoto, Kumiko Nomura
  • Patent number: 11996597
    Abstract: A hybrid redox fuel cell system includes a hybrid redox fuel cell including an anode side through which a reductant is flowed and a cathode side through which liquid electrolyte is flowed, and a catalyst bed fluidly connected to the cathode side of the hybrid redox fuel cell, the catalyst bed including a substrate layer and a catalyst layer spiral wound into a jelly roll structure. Furthermore, the liquid electrolyte includes a metal ion at a higher oxidation state and the metal ion at a lower oxidation state, and power is generated at the hybrid redox fuel cell by way of reducing the metal ion from the higher oxidation state to the lower oxidation state at the cathode side while oxidizing the reductant at the anode side.
    Type: Grant
    Filed: September 2, 2022
    Date of Patent: May 28, 2024
    Assignee: ESS TECH, INC.
    Inventors: Yang Song, Craig Evans
  • Patent number: 11986776
    Abstract: A method is described for forming a body having at least one through-going passage, said method has the steps of: a) providing a mixture comprising particles and at least one liquid pocket inside a curable matrix, b) subjecting said mixture to a first alternating voltage having a first frequency to form a body in which said at least one liquid pocket extends from a first surface of said body to a second surface of said body thereby forming at least one through-going passage lacking curable matrix, and c) curing said curable matrix into a cured matrix, wherein at least some of said particles are located at an interface between said at least one through-going passage comprising liquid and said cured matrix.
    Type: Grant
    Filed: March 28, 2018
    Date of Patent: May 21, 2024
    Assignee: CONDALIGN AS
    Inventors: Henrik Hemmen, Tina Bryntesen, Linn Cecilie Sørvik, Marie-Audrey Marguerite Adrienne Raux, Guttorm Johan Osborg
  • Patent number: 11967723
    Abstract: A solid-state electrolyte composition for a lithium battery. The composition includes a polymeric matrix material, inorganic nanoparticles dispersed in or chemically bonded with the polymeric matrix material, and a lithium salt. The nanoparticles are formed of a compound including lithium and a different semi-metal element or metal element. Exemplary inorganic nanoparticles include a Li-rich super ionic conductor having a LixMyPzSq structural formula, wherein M refers to the different semi-metal element or a metal element.
    Type: Grant
    Filed: December 14, 2021
    Date of Patent: April 23, 2024
    Assignee: ILLINOIS INSTITUTE OF TECHNOLOGY
    Inventors: Mohammad Asadi, Alireza Kondori, Mohammadreza Esmaeilirad
  • Patent number: 11962037
    Abstract: The present application relates to a proton exchange membrane for fuel cell, said membrane having self-regenerating properties, to cells comprising said membranes, and to the manufacturing method thereof via electrospinning.
    Type: Grant
    Filed: January 21, 2021
    Date of Patent: April 16, 2024
    Assignees: SYMBIO, COLLEGE DE FRANCE, SORBONNE UNIVERSITÉ, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Christophe Vacquier, Nathalia Rovira, Christophe Baverel, Christel Laberty-Robert, Laura Coustan, Clément Sanchez
  • Patent number: 11949135
    Abstract: A fuel cell system includes: a first fuel cell including a first anode and a first cathode, wherein the first anode is configured to output a first anode exhaust gas; a first oxidizer configured to receive the first anode exhaust gas and air from a first air supply, to react the first anode exhaust gas and the air in a preferential oxidation reaction, and to output an oxidized gas; a second fuel cell configured to act as an electrochemical hydrogen separator, the second fuel cell including: a second anode configured to receive the oxidized gas from the first oxidizer and to output a second anode exhaust gas, and a second cathode configured to output a hydrogen stream; and a condenser configured to receive the second anode exhaust gas and to separate water and CO2.
    Type: Grant
    Filed: November 4, 2020
    Date of Patent: April 2, 2024
    Assignee: FuelCell Energy, Inc.
    Inventor: Hossein Ghezel-Ayagh
  • Patent number: 11923584
    Abstract: An object of the present invention is to provide a membrane for a redox flow battery which is prevented from being curled and exhibits high power efficiency, a membrane electrode assembly for a redox flow battery, a cell for a redox flow battery, and a redox flow battery. The object can be attained by a membrane for a redox flow battery, comprising a first ion-exchange resin layer, an anion-exchange resin layer containing an anion-exchange compound, and a second ion-exchange resin layer in the presented order, wherein a value obtained by dividing a thickness of the first ion-exchange resin layer by a thickness of the second ion-exchange resin layer is 0.7 or more and 1.3 or less, and a thickness of the anion-exchange resin layer is 0.02 ?m or larger and 3 ?m or smaller.
    Type: Grant
    Filed: March 4, 2021
    Date of Patent: March 5, 2024
    Assignee: ASAHI KASEI KABUSHIKI KAISHA
    Inventors: Hiroko Kamochi, Yuka Kanada, Kazuya Kai, Junya Yamashita
  • Patent number: 11905382
    Abstract: A proton-exchange membrane includes a polymer matrix, polymer fibers, or a combination thereof. The proton-exchange membrane also includes a proton-conducting material distributed on the polymer matrix, on the polymer fibers, in the polymer fibers, or a combination thereof.
    Type: Grant
    Filed: July 7, 2020
    Date of Patent: February 20, 2024
    Assignee: Energy and Environmental Research Center Foundation
    Inventors: Ted R. Aulich, Jivan Thakare, John Hurley, Xiangfa Wu, Zhengping Zhou, Oksana Zholobko
  • Patent number: 11901565
    Abstract: A fuel cell electrode catalyst includes: catalyst metal particles containing at least one of platinum or a platinum alloy; and support particles supporting the catalyst metal particles. The crystallite size 2r obtained from an X-ray diffraction image of the catalyst metal particles is 3.8 nm or less, where r represents a crystallite radius of the catalyst metal particles obtained from the X-ray diffraction image. The amount of CO adsorption Y (mL/g-Pt) on the fuel cell electrode catalyst satisfies Y?40.386/r+1.7586.
    Type: Grant
    Filed: March 9, 2022
    Date of Patent: February 13, 2024
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Toshihiro Ikai, Tomohiro Ishida, Godai Kitayama, Yousuke Horiuchi
  • Patent number: 11884787
    Abstract: A novel process for making PBI films starting from gel PBI membranes polymerized and casted in the PPA process wherein acid-imbibed gel PBIs are neutralized in a series of water baths and undergo controlled drying in association with a substrate material, yielding a PBI film without the use of organic solvents.
    Type: Grant
    Filed: November 9, 2021
    Date of Patent: January 30, 2024
    Assignee: UNIVERSITY OF SOUTH CAROLINA
    Inventors: Laura A. Murdock, Lihui Wang, Fei Huang, Brian C. Benicewicz
  • Patent number: 11888183
    Abstract: An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.
    Type: Grant
    Filed: August 11, 2021
    Date of Patent: January 30, 2024
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Stéphane Di Iorio, Thibault Monnet, Bruno Oresic, Philippe Szynal
  • Patent number: 11888200
    Abstract: Methods, systems, and apparatus for treating wastewater and generating electricity. The system includes layers of sediment containing microorganisms for treating the wastewater. The system includes layers of granular activated carbon or granular activated carbon with graphene oxide or sand with graphene oxide disposed on top of the sediment layers for enhancing electron transfer, current generation rate, and wastewater treatment. The system also includes one or more anodes and one or more cathodes located on top of the layers of granular activated carbon or granular activated carbon with graphene oxide or sand with graphene oxide. The one or more anodes and the one or more cathodes are configured to generate electrical voltage. The system also includes a battery connected to the one or more anodes and the one or more cathodes and configured to store the electrical voltage generated by the one or more anodes and the one or more cathodes.
    Type: Grant
    Filed: February 25, 2019
    Date of Patent: January 30, 2024
    Assignee: UNIVERSITY OF SOUTHERN CALIFORNIA
    Inventors: Massoud Pirbazari, Varadarajan Ravindran
  • Patent number: 11888197
    Abstract: A composite fuel cell polymer electrolyte membrane. The composite membrane includes a polymer electrolyte membrane base material including first and second inorganic particles. The first and second inorganic particles are interspersed within the polymer electrolyte membrane base material and each other. The first and second inorganic particles have first and second surface properties and the first surface property is different than the second surface property.
    Type: Grant
    Filed: May 4, 2020
    Date of Patent: January 30, 2024
    Assignees: Robert Bosch GmbH, Massachusetts Institute of Technology
    Inventors: Karim Gadelrab, Jonathan Mailoa, Hejin Huang, Alfredo Alexander-Katz
  • Patent number: 11876247
    Abstract: The present disclosure relates to a solid electrolyte membrane for an all-solid-state battery and a battery comprising the same. In the present disclosure, the battery may comprise lithium metal as a negative electrode active material. The solid electrolyte membrane for an all-solid-state battery according to the present disclosure comprises a guide layer comprising metal particles to guide the horizontal growth of lithium dendrites, thereby delaying an electrical short caused by dendrite growth. Additionally, the guide layer is formed by polymer self-assembly, and thus the metal particles may be uniformly distributed in a very regular pattern within the guide layer.
    Type: Grant
    Filed: April 20, 2020
    Date of Patent: January 16, 2024
    Assignee: LG ENERGY SOLUTION, LTD.
    Inventors: Jung-Pil Lee, Eun-Bee Kim, Ji-Hoon Ryu, Suk-Woo Lee
  • Patent number: 11855323
    Abstract: A heat treatment apparatus of membrane electrode assemblies includes a base, a first member extending from the base in a first direction, and a plurality of second members formed on the base in a radially outward direction of the first member and having inner surfaces facing the first member, where the first member or the second members includes a heat wire member, and membrane electrode assemblies are disposed between the first member and the second members.
    Type: Grant
    Filed: December 21, 2022
    Date of Patent: December 26, 2023
    Assignees: Hyundai Motor Company, Kia Corporation
    Inventors: Min Jin Kim, Sam Hee Yu, Young June Park, Woo Jin Lee, Ki Sub Lee
  • Patent number: 11852905
    Abstract: An optical element includes a first layer, a second layer, and a fluid. A first surface of the first layer is configured to change hydrophobicity in response to incoming activation light. Absorbing molecules in the fluid are repelled or attracted to the first surface in response to the hydrophobicity of the first surface.
    Type: Grant
    Filed: December 22, 2020
    Date of Patent: December 26, 2023
    Assignee: Meta Platforms Technologies, LLC
    Inventors: Jasmine Soria Sears, Christopher Andrew Galea, Junren Wang, Stephen John Holmes
  • Patent number: 11846584
    Abstract: A measurement apparatus for measuring a coating amount of a slurry according to the present disclosure includes a light emitter configured to irradiate terahertz wave onto a release paper coated with the slurry, a light receiver configured to receive the terahertz wave, which is irradiated from the light emitter and passes through the release paper coated with the slurry, to obtain a power of the terahertz wave, and a calculating part configured to calculate a thickness of an electrode, formed from the slurry applied to the release paper, based on the power of the terahertz wave received by the light receiver.
    Type: Grant
    Filed: November 17, 2020
    Date of Patent: December 19, 2023
    Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION, ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTE
    Inventors: Ha Seung Seong, Ho Jin Lee, Il Min Lee, Ki Won Moon, Eui Su Lee, Dong Woo Park, Jeong Woo Park, Kyung Hyun Park, Hyun Soo Kim
  • Patent number: 11843148
    Abstract: A fuel cell membrane electrode assembly includes a polymer electrolyte membrane and a pair of electrocatalyst layers arranged to have the polymer electrolyte membrane therebetween, at least one of the pair of electrocatalyst layers includes particles supporting a catalyst which is composed of a noble metal component, a polymer electrolyte, and a fibrous oxide-based catalytic material, and the fibrous oxide-based catalytic material includes at least one transition metal element selected from a group consisting of Ta, Nb, Ti, and Zr.
    Type: Grant
    Filed: February 3, 2022
    Date of Patent: December 12, 2023
    Assignee: TOPPAN INC.
    Inventor: Hiroyuki Morioka
  • Patent number: 11817606
    Abstract: A rebalancing reactor for a redox flow battery system may include a first side through which hydrogen gas is flowed, a second side through which electrolyte from the redox flow battery system is flowed, and a porous layer separating and fluidly coupled to the first side and the second side, wherein, the hydrogen gas and the electrolyte are fluidly contacted at a surface of the porous layer, and a pressure drop across the second side is less than a pressure drop across the porous layer. In this way, rebalancing of electrolyte charges in a redox flow battery system may be performed with increased efficiency and cost effectiveness as compared to conventional rebalancing reactors.
    Type: Grant
    Filed: April 27, 2018
    Date of Patent: November 14, 2023
    Assignee: ESS TECH, INC.
    Inventor: Craig E. Evans
  • Patent number: 11811073
    Abstract: The use of an electrocatalyst material in an anode catalyst layer, wherein the electrocatalyst material comprises a support material, the support material comprising a plurality of individual support particles or aggregates wherein each individual support particle or aggregate has dispersed thereon (i) first particles and (ii) second particles, wherein: (i) the first particles comprise Pt optionally alloyed with an alloying metal X1; wherein the optional alloying metal X1 is selected from the group consisting of Rh, Ti, Os, V, Co, Ni, Ga, Hf, Sn, Ir, Pd, Mo, Zn, W, Zr and Re; (ii) the second particles consist essentially of a second metal or a second metal compound wherein the second metal is selected from the group consisting of Ir and Ru and the second metal compound comprises IrX2 wherein X2 is selected from the group consisting of Ta, Nb, Ru, Ni and Co; and wherein if the first particles consist of Pt then the second particles do not comprise IrTa; and wherein if the first particles consist of Pt without
    Type: Grant
    Filed: November 22, 2018
    Date of Patent: November 7, 2023
    Assignee: Johnson Matthey Hydrogen Technologies Limited
    Inventors: Alejandro Martinez Bonastre, Jonathan Sharman, Geoffrey Spikes
  • Patent number: 11811070
    Abstract: A fuel cell membrane electrode assembly and a polymer electrolyte fuel cell, which improve drainage in a high current range where a large amount of water is produced, without hindering water retention under low humidification conditions, and exhibit high power generation performance and durability even under high humidification conditions. A fuel cell membrane electrode assembly according to a first embodiment of the present invention includes a polyelectrolyte film, and two electrocatalyst layers sandwiching the polyelectrolyte film. At least one of the two electrocatalyst layers includes catalyst support particles with a hydrophobic coating, a polyelectrolyte, and a fibrous material having an average fiber diameter that is 10 nm or more and 300 nm or less. The fibrous material has a mass that is 0.2 times or more and 1.0 times or less the mass of the carrier in the catalyst support particles.
    Type: Grant
    Filed: April 8, 2021
    Date of Patent: November 7, 2023
    Assignee: TOPPAN PRINTING CO., LTD.
    Inventor: Hiroyuki Morioka
  • Patent number: 11799113
    Abstract: Disclosed is an electrolyte membrane including an antioxidant containing elemental sulfur or a sulfur compound to improve antioxidant activity and resistance to acids. In addition, a membrane-electrode assembly including the electrolyte membrane is disclosed.
    Type: Grant
    Filed: December 7, 2021
    Date of Patent: October 24, 2023
    Assignees: Hyundai Motor Company, Kia Corporation, Industry Foundation of Chonnam National University
    Inventors: In Yu Park, Jong Kil Oh, Sun Ju Song, Jae Woon Hong, Aniket Kumar, Ye Jin Yun
  • Patent number: 11779889
    Abstract: A proton exchange solid support includes a first solid support including a polymer, a second solid support, and a tetravalent boron-based acid group that links the first solid support to the second solid support.
    Type: Grant
    Filed: April 26, 2022
    Date of Patent: October 10, 2023
    Assignee: 1s1 Energy, Inc.
    Inventors: Sukanta Bhattacharyya, Daniel Sobek
  • Patent number: 11777116
    Abstract: A fuel cell system (200), wherein the fuel cell system (200) has: a) a fuel cell stack (10), b) an anode gas path (20) which fluidically communicates with the fuel cell stack (10) and which serves for supplying anode gas from an anode gas store (22) to the fuel cell stack (10), c) a cathode gas path (30) which fluidically communicates with the fuel cell stack (10) and which serves for supplying cathode gas from a cathode gas store (32) to the fuel cell stack (10), d) a cooling fluid path (40) which fluidically communicates with the fuel cell stack (10) and which serves for supplying cooling fluid from a cooling fluid store (42) to the fuel cell stack (10), e) a vibration generator (60) which is in data-transmitting communication with a control unit (50) and which serves for setting the fuel cell stack (10) into a vibrating state, and f) the control unit (50) for actuating the vibration generator (60) in order to set the fuel cell stack (10) into the vibrating state by means of the vibration generator (60).
    Type: Grant
    Filed: November 5, 2020
    Date of Patent: October 3, 2023
    Assignee: Robert Bosch GmbH
    Inventors: Arnold Gente, Jan Hendrik Ohs, Udo Riegler, Ulrich Berner
  • Patent number: 11769885
    Abstract: An electrode layer can have an electrically conductive material, a catalyst, an ionomer binder, and a perfluorocarbon compound. The ionomer binder forms hydrophilic regions on the electrically conductive material to support proton and water transport. The perfluorocarbon compound forms hydrophobic regions on the electrically conductive material to support oxygen solubility and transport. The electrode can be used in making a membrane electrode assembly and can be configured as a cathode thereof. Fuel cells and fuel stacks can include such membrane electrode assemblies.
    Type: Grant
    Filed: September 28, 2021
    Date of Patent: September 26, 2023
    Assignee: HYZON MOTORS INC.
    Inventors: Rajesh Bashyam, Zhai Jun
  • Patent number: 11749809
    Abstract: A fuel cell membrane electrode assembly and a polymer electrolyte fuel cell, which improve drainage in a high current range where a large amount of water is produced, without hindering water retention under low humidification conditions, and exhibit high power generation performance and durability even under high humidification conditions. A fuel cell membrane electrode assembly according to a first embodiment of the present invention includes a polyelectrolyte film, and two electrocatalyst layers sandwiching the polyelectrolyte film. At least one of the two electrocatalyst layers includes catalyst support particles with a hydrophobic coating, a polyelectrolyte, and a fibrous material having an average fiber diameter that is 10 nm or more and 300 nm or less. The fibrous material has a mass that is 0.2 times or more and 1.0 times or less the mass of the carrier in the catalyst support particles.
    Type: Grant
    Filed: April 8, 2021
    Date of Patent: September 5, 2023
    Assignee: TOPPAN PRINTING CO., LTD.
    Inventor: Hiroyuki Morioka