Polymeric Material (e.g., Proton Exchange Membrane (pem), Etc.) Patents (Class 429/492)
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Patent number: 11962037Abstract: The present application relates to a proton exchange membrane for fuel cell, said membrane having self-regenerating properties, to cells comprising said membranes, and to the manufacturing method thereof via electrospinning.Type: GrantFiled: January 21, 2021Date of Patent: April 16, 2024Assignees: SYMBIO, COLLEGE DE FRANCE, SORBONNE UNIVERSITÉ, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Christophe Vacquier, Nathalia Rovira, Christophe Baverel, Christel Laberty-Robert, Laura Coustan, Clément Sanchez
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Patent number: 11949135Abstract: A fuel cell system includes: a first fuel cell including a first anode and a first cathode, wherein the first anode is configured to output a first anode exhaust gas; a first oxidizer configured to receive the first anode exhaust gas and air from a first air supply, to react the first anode exhaust gas and the air in a preferential oxidation reaction, and to output an oxidized gas; a second fuel cell configured to act as an electrochemical hydrogen separator, the second fuel cell including: a second anode configured to receive the oxidized gas from the first oxidizer and to output a second anode exhaust gas, and a second cathode configured to output a hydrogen stream; and a condenser configured to receive the second anode exhaust gas and to separate water and CO2.Type: GrantFiled: November 4, 2020Date of Patent: April 2, 2024Assignee: FuelCell Energy, Inc.Inventor: Hossein Ghezel-Ayagh
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Patent number: 11923584Abstract: An object of the present invention is to provide a membrane for a redox flow battery which is prevented from being curled and exhibits high power efficiency, a membrane electrode assembly for a redox flow battery, a cell for a redox flow battery, and a redox flow battery. The object can be attained by a membrane for a redox flow battery, comprising a first ion-exchange resin layer, an anion-exchange resin layer containing an anion-exchange compound, and a second ion-exchange resin layer in the presented order, wherein a value obtained by dividing a thickness of the first ion-exchange resin layer by a thickness of the second ion-exchange resin layer is 0.7 or more and 1.3 or less, and a thickness of the anion-exchange resin layer is 0.02 ?m or larger and 3 ?m or smaller.Type: GrantFiled: March 4, 2021Date of Patent: March 5, 2024Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Hiroko Kamochi, Yuka Kanada, Kazuya Kai, Junya Yamashita
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Patent number: 11905382Abstract: A proton-exchange membrane includes a polymer matrix, polymer fibers, or a combination thereof. The proton-exchange membrane also includes a proton-conducting material distributed on the polymer matrix, on the polymer fibers, in the polymer fibers, or a combination thereof.Type: GrantFiled: July 7, 2020Date of Patent: February 20, 2024Assignee: Energy and Environmental Research Center FoundationInventors: Ted R. Aulich, Jivan Thakare, John Hurley, Xiangfa Wu, Zhengping Zhou, Oksana Zholobko
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Patent number: 11901565Abstract: A fuel cell electrode catalyst includes: catalyst metal particles containing at least one of platinum or a platinum alloy; and support particles supporting the catalyst metal particles. The crystallite size 2r obtained from an X-ray diffraction image of the catalyst metal particles is 3.8 nm or less, where r represents a crystallite radius of the catalyst metal particles obtained from the X-ray diffraction image. The amount of CO adsorption Y (mL/g-Pt) on the fuel cell electrode catalyst satisfies Y?40.386/r+1.7586.Type: GrantFiled: March 9, 2022Date of Patent: February 13, 2024Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATIONInventors: Toshihiro Ikai, Tomohiro Ishida, Godai Kitayama, Yousuke Horiuchi
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Patent number: 11888197Abstract: A composite fuel cell polymer electrolyte membrane. The composite membrane includes a polymer electrolyte membrane base material including first and second inorganic particles. The first and second inorganic particles are interspersed within the polymer electrolyte membrane base material and each other. The first and second inorganic particles have first and second surface properties and the first surface property is different than the second surface property.Type: GrantFiled: May 4, 2020Date of Patent: January 30, 2024Assignees: Robert Bosch GmbH, Massachusetts Institute of TechnologyInventors: Karim Gadelrab, Jonathan Mailoa, Hejin Huang, Alfredo Alexander-Katz
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Patent number: 11884787Abstract: A novel process for making PBI films starting from gel PBI membranes polymerized and casted in the PPA process wherein acid-imbibed gel PBIs are neutralized in a series of water baths and undergo controlled drying in association with a substrate material, yielding a PBI film without the use of organic solvents.Type: GrantFiled: November 9, 2021Date of Patent: January 30, 2024Assignee: UNIVERSITY OF SOUTH CAROLINAInventors: Laura A. Murdock, Lihui Wang, Fei Huang, Brian C. Benicewicz
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Patent number: 11888200Abstract: Methods, systems, and apparatus for treating wastewater and generating electricity. The system includes layers of sediment containing microorganisms for treating the wastewater. The system includes layers of granular activated carbon or granular activated carbon with graphene oxide or sand with graphene oxide disposed on top of the sediment layers for enhancing electron transfer, current generation rate, and wastewater treatment. The system also includes one or more anodes and one or more cathodes located on top of the layers of granular activated carbon or granular activated carbon with graphene oxide or sand with graphene oxide. The one or more anodes and the one or more cathodes are configured to generate electrical voltage. The system also includes a battery connected to the one or more anodes and the one or more cathodes and configured to store the electrical voltage generated by the one or more anodes and the one or more cathodes.Type: GrantFiled: February 25, 2019Date of Patent: January 30, 2024Assignee: UNIVERSITY OF SOUTHERN CALIFORNIAInventors: Massoud Pirbazari, Varadarajan Ravindran
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Patent number: 11888183Abstract: An electrochemical device may be formed by assembly by stacking preassembled modules, each of these modules being produced as a usual stack of electrochemical cells. The manufacture of preassembled modules can make it possible to produce electrochemical devices with a large number of electrochemical cells, without the bracing problems present and excessive crushing courses that are encountered in the cell stacks according to the prior art, i.e., in a single block.Type: GrantFiled: August 11, 2021Date of Patent: January 30, 2024Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVESInventors: Stéphane Di Iorio, Thibault Monnet, Bruno Oresic, Philippe Szynal
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Patent number: 11876247Abstract: The present disclosure relates to a solid electrolyte membrane for an all-solid-state battery and a battery comprising the same. In the present disclosure, the battery may comprise lithium metal as a negative electrode active material. The solid electrolyte membrane for an all-solid-state battery according to the present disclosure comprises a guide layer comprising metal particles to guide the horizontal growth of lithium dendrites, thereby delaying an electrical short caused by dendrite growth. Additionally, the guide layer is formed by polymer self-assembly, and thus the metal particles may be uniformly distributed in a very regular pattern within the guide layer.Type: GrantFiled: April 20, 2020Date of Patent: January 16, 2024Assignee: LG ENERGY SOLUTION, LTD.Inventors: Jung-Pil Lee, Eun-Bee Kim, Ji-Hoon Ryu, Suk-Woo Lee
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Patent number: 11855323Abstract: A heat treatment apparatus of membrane electrode assemblies includes a base, a first member extending from the base in a first direction, and a plurality of second members formed on the base in a radially outward direction of the first member and having inner surfaces facing the first member, where the first member or the second members includes a heat wire member, and membrane electrode assemblies are disposed between the first member and the second members.Type: GrantFiled: December 21, 2022Date of Patent: December 26, 2023Assignees: Hyundai Motor Company, Kia CorporationInventors: Min Jin Kim, Sam Hee Yu, Young June Park, Woo Jin Lee, Ki Sub Lee
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Patent number: 11852905Abstract: An optical element includes a first layer, a second layer, and a fluid. A first surface of the first layer is configured to change hydrophobicity in response to incoming activation light. Absorbing molecules in the fluid are repelled or attracted to the first surface in response to the hydrophobicity of the first surface.Type: GrantFiled: December 22, 2020Date of Patent: December 26, 2023Assignee: Meta Platforms Technologies, LLCInventors: Jasmine Soria Sears, Christopher Andrew Galea, Junren Wang, Stephen John Holmes
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Patent number: 11846584Abstract: A measurement apparatus for measuring a coating amount of a slurry according to the present disclosure includes a light emitter configured to irradiate terahertz wave onto a release paper coated with the slurry, a light receiver configured to receive the terahertz wave, which is irradiated from the light emitter and passes through the release paper coated with the slurry, to obtain a power of the terahertz wave, and a calculating part configured to calculate a thickness of an electrode, formed from the slurry applied to the release paper, based on the power of the terahertz wave received by the light receiver.Type: GrantFiled: November 17, 2020Date of Patent: December 19, 2023Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION, ELECTRONICS AND TELECOMMUNICATIONS RESEARCH INSTITUTEInventors: Ha Seung Seong, Ho Jin Lee, Il Min Lee, Ki Won Moon, Eui Su Lee, Dong Woo Park, Jeong Woo Park, Kyung Hyun Park, Hyun Soo Kim
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Patent number: 11843148Abstract: A fuel cell membrane electrode assembly includes a polymer electrolyte membrane and a pair of electrocatalyst layers arranged to have the polymer electrolyte membrane therebetween, at least one of the pair of electrocatalyst layers includes particles supporting a catalyst which is composed of a noble metal component, a polymer electrolyte, and a fibrous oxide-based catalytic material, and the fibrous oxide-based catalytic material includes at least one transition metal element selected from a group consisting of Ta, Nb, Ti, and Zr.Type: GrantFiled: February 3, 2022Date of Patent: December 12, 2023Assignee: TOPPAN INC.Inventor: Hiroyuki Morioka
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Patent number: 11817606Abstract: A rebalancing reactor for a redox flow battery system may include a first side through which hydrogen gas is flowed, a second side through which electrolyte from the redox flow battery system is flowed, and a porous layer separating and fluidly coupled to the first side and the second side, wherein, the hydrogen gas and the electrolyte are fluidly contacted at a surface of the porous layer, and a pressure drop across the second side is less than a pressure drop across the porous layer. In this way, rebalancing of electrolyte charges in a redox flow battery system may be performed with increased efficiency and cost effectiveness as compared to conventional rebalancing reactors.Type: GrantFiled: April 27, 2018Date of Patent: November 14, 2023Assignee: ESS TECH, INC.Inventor: Craig E. Evans
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Patent number: 11811070Abstract: A fuel cell membrane electrode assembly and a polymer electrolyte fuel cell, which improve drainage in a high current range where a large amount of water is produced, without hindering water retention under low humidification conditions, and exhibit high power generation performance and durability even under high humidification conditions. A fuel cell membrane electrode assembly according to a first embodiment of the present invention includes a polyelectrolyte film, and two electrocatalyst layers sandwiching the polyelectrolyte film. At least one of the two electrocatalyst layers includes catalyst support particles with a hydrophobic coating, a polyelectrolyte, and a fibrous material having an average fiber diameter that is 10 nm or more and 300 nm or less. The fibrous material has a mass that is 0.2 times or more and 1.0 times or less the mass of the carrier in the catalyst support particles.Type: GrantFiled: April 8, 2021Date of Patent: November 7, 2023Assignee: TOPPAN PRINTING CO., LTD.Inventor: Hiroyuki Morioka
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Patent number: 11811073Abstract: The use of an electrocatalyst material in an anode catalyst layer, wherein the electrocatalyst material comprises a support material, the support material comprising a plurality of individual support particles or aggregates wherein each individual support particle or aggregate has dispersed thereon (i) first particles and (ii) second particles, wherein: (i) the first particles comprise Pt optionally alloyed with an alloying metal X1; wherein the optional alloying metal X1 is selected from the group consisting of Rh, Ti, Os, V, Co, Ni, Ga, Hf, Sn, Ir, Pd, Mo, Zn, W, Zr and Re; (ii) the second particles consist essentially of a second metal or a second metal compound wherein the second metal is selected from the group consisting of Ir and Ru and the second metal compound comprises IrX2 wherein X2 is selected from the group consisting of Ta, Nb, Ru, Ni and Co; and wherein if the first particles consist of Pt then the second particles do not comprise IrTa; and wherein if the first particles consist of Pt withoutType: GrantFiled: November 22, 2018Date of Patent: November 7, 2023Assignee: Johnson Matthey Hydrogen Technologies LimitedInventors: Alejandro Martinez Bonastre, Jonathan Sharman, Geoffrey Spikes
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Patent number: 11799113Abstract: Disclosed is an electrolyte membrane including an antioxidant containing elemental sulfur or a sulfur compound to improve antioxidant activity and resistance to acids. In addition, a membrane-electrode assembly including the electrolyte membrane is disclosed.Type: GrantFiled: December 7, 2021Date of Patent: October 24, 2023Assignees: Hyundai Motor Company, Kia Corporation, Industry Foundation of Chonnam National UniversityInventors: In Yu Park, Jong Kil Oh, Sun Ju Song, Jae Woon Hong, Aniket Kumar, Ye Jin Yun
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Patent number: 11779889Abstract: A proton exchange solid support includes a first solid support including a polymer, a second solid support, and a tetravalent boron-based acid group that links the first solid support to the second solid support.Type: GrantFiled: April 26, 2022Date of Patent: October 10, 2023Assignee: 1s1 Energy, Inc.Inventors: Sukanta Bhattacharyya, Daniel Sobek
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Patent number: 11777116Abstract: A fuel cell system (200), wherein the fuel cell system (200) has: a) a fuel cell stack (10), b) an anode gas path (20) which fluidically communicates with the fuel cell stack (10) and which serves for supplying anode gas from an anode gas store (22) to the fuel cell stack (10), c) a cathode gas path (30) which fluidically communicates with the fuel cell stack (10) and which serves for supplying cathode gas from a cathode gas store (32) to the fuel cell stack (10), d) a cooling fluid path (40) which fluidically communicates with the fuel cell stack (10) and which serves for supplying cooling fluid from a cooling fluid store (42) to the fuel cell stack (10), e) a vibration generator (60) which is in data-transmitting communication with a control unit (50) and which serves for setting the fuel cell stack (10) into a vibrating state, and f) the control unit (50) for actuating the vibration generator (60) in order to set the fuel cell stack (10) into the vibrating state by means of the vibration generator (60).Type: GrantFiled: November 5, 2020Date of Patent: October 3, 2023Assignee: Robert Bosch GmbHInventors: Arnold Gente, Jan Hendrik Ohs, Udo Riegler, Ulrich Berner
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Patent number: 11769885Abstract: An electrode layer can have an electrically conductive material, a catalyst, an ionomer binder, and a perfluorocarbon compound. The ionomer binder forms hydrophilic regions on the electrically conductive material to support proton and water transport. The perfluorocarbon compound forms hydrophobic regions on the electrically conductive material to support oxygen solubility and transport. The electrode can be used in making a membrane electrode assembly and can be configured as a cathode thereof. Fuel cells and fuel stacks can include such membrane electrode assemblies.Type: GrantFiled: September 28, 2021Date of Patent: September 26, 2023Assignee: HYZON MOTORS INC.Inventors: Rajesh Bashyam, Zhai Jun
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Patent number: 11749809Abstract: A fuel cell membrane electrode assembly and a polymer electrolyte fuel cell, which improve drainage in a high current range where a large amount of water is produced, without hindering water retention under low humidification conditions, and exhibit high power generation performance and durability even under high humidification conditions. A fuel cell membrane electrode assembly according to a first embodiment of the present invention includes a polyelectrolyte film, and two electrocatalyst layers sandwiching the polyelectrolyte film. At least one of the two electrocatalyst layers includes catalyst support particles with a hydrophobic coating, a polyelectrolyte, and a fibrous material having an average fiber diameter that is 10 nm or more and 300 nm or less. The fibrous material has a mass that is 0.2 times or more and 1.0 times or less the mass of the carrier in the catalyst support particles.Type: GrantFiled: April 8, 2021Date of Patent: September 5, 2023Assignee: TOPPAN PRINTING CO., LTD.Inventor: Hiroyuki Morioka
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Patent number: 11710843Abstract: A redox flow battery and battery system are provided. In one example, the redox flow battery includes a cell stack assembly interposed by two endplates and comprising a plurality of mated membrane frame plates and bipolar frame plates forming, at a mated interface, a plurality of negative and positive flow channels configured to distribute negative and positive electrolyte into a plurality of bipolar plates. In the battery a membrane is coupled to each of the plurality of membrane frame plates and positioned sequentially between two of the bipolar plates included in the plurality of bipolar plates.Type: GrantFiled: May 5, 2021Date of Patent: July 25, 2023Assignee: ESS Tech, Inc.Inventors: Craig E. Evans, Sean Casey, Thiago Groberg, Yang Song
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Patent number: 11710833Abstract: This anode catalyst layer for a fuel cell contains electrode catalyst particles, a carbon carrier on which the electrode catalyst particles are loaded, water electrolysis catalyst particles, a proton-conducting binder, and graphitized carbon. The graphitized carbon has a bulk density of 0.50/cm3 or less.Type: GrantFiled: September 4, 2019Date of Patent: July 25, 2023Assignee: CATALER CORPORATIONInventors: Akihiro Hori, Yosuke Horiuchi
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Patent number: 11705568Abstract: The present invention provides a catalysed ion-conducting membrane comprising an ion-conducting membrane, an electrocatalyst layer having two opposing faces, and a layer A comprising an ion-conducting material and a carbon containing material. Also provided are methods for preparing the catalysed ion-conducting membrane.Type: GrantFiled: August 21, 2020Date of Patent: July 18, 2023Assignee: JOHNSON MATTHEY HYDROGEN TECHNOLOGIES LIMITEDInventors: Dash Fongalland, Jonathan Sharman
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Patent number: 11695147Abstract: Disclosed is an antioxidant for a polymer electrolyte membrane of a fuel cell including cerium hydrogen phosphate (CeHPO4). The presence of cerium hydrogen phosphate in the antioxidant enhances the dissolution stability of cerium and improves the ability to capture water, leading to an increase in proton conductivity. In addition, the cerium hydrogen phosphate has a crystal structure composed of smaller cerium particles. This crystal structure greatly improves the ability of the antioxidant to prevent oxidation of the electrolyte membrane. Also disclosed are an electrolyte membrane including the antioxidant, a fuel cell including the electrolyte membrane, a method for preparing the antioxidant, a method for producing the electrolyte membrane, and a method for fabricating the fuel cell.Type: GrantFiled: September 8, 2020Date of Patent: July 4, 2023Assignee: Korea Institute of Science and TechnologyInventors: So Young Lee, Seung Ju Lee, Hyun Seo Park, Jin Young Kim, Sung Jong Yoo, Jong Hyun Jang, Hyoung-Juhn Kim, Hee-Young Park
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Patent number: 11664504Abstract: A method of producing electrical power includes: a cathode having a porphyrin precursor attached to a substrate, and having a first enzyme, wherein the first enzyme reduces oxygen; an anode having a first region of an anode substrate and having a gold nanoparticle composition located thereon, and having a second region of the anode substrate having an enzyme composition located thereon, wherein the enzyme composition includes a second enzyme, wherein the first region and second region are separate regions; and a neutral fuel liquid in contact with the anode and cathode, the neutral fuel liquid having a neutral pH and a fuel reagent; and operating the fuel cell to produce electrical power with the neutral fuel liquid having the neutral pH and the fuel reagent.Type: GrantFiled: August 19, 2021Date of Patent: May 30, 2023Assignee: CFD Research CorporationInventors: Mary Arugula, Erica Wagner Pinchon, Sameer Singhal, Yevgenia Ulyanova
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Patent number: 11591294Abstract: Aqueous electrolytes comprising fluorenone/fluorenol derivatives are disclosed. The electrolyte may be an anolyte for an aqueous redox flow battery. In some embodiments, the compound, or salt thereof, has a structure according to any one of formulas I-III where Q1-Q4 independently are CH, C(R1) or N, wherein 0, 1, or 2 of Q1-Q4 are N; Q5-Q8 independently are CH, C(R2), or N, wherein 0, 1, or 2 of Q5-Q8 are N; Y is C?O or C(H)OH; R1 and R2 independently are an electron withdrawing group; n is an integer >1; and x and y independently are 0, 1, 2, 3, or 4, where at least one of x and y is not 0.Type: GrantFiled: November 13, 2020Date of Patent: February 28, 2023Assignee: Battelle Memorial InstituteInventors: Wei Wang, Ruozhu Feng, Xin Zhang, Aaron M. Hollas, Vijay Murugesan, Nadeesha P. Nambukara Wellala, Yuyan Shao, Zimin Nie
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Patent number: 11594747Abstract: A boron-containing proton-exchange solid support may include a proton-exchange solid support comprising an oxygen atom and a tetravalent boron-based acid group comprising a boron atom covalently bonded to the oxygen atom.Type: GrantFiled: November 8, 2021Date of Patent: February 28, 2023Assignee: 1s1 Energy, Inc.Inventors: Sukanta Bhattacharyya, Daniel Sobek
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Patent number: 11581546Abstract: A catalyst layer comprising an interface to a polyelectrolyte membrane, the catalyst layer includes a layer forming material, which includes a catalytic substance, a conductive carrier which supports the catalytic substance, a polyelectrolyte, and a fibrous material, and a plurality of pores which contain no layer forming material. A pore area ratio which is a total area ratio of the plurality of pores to an area of a cross-section orthogonal to the interface is 25.0% or more and 35.0% or less in a cross-sectional image captured by a scanning electron microscope.Type: GrantFiled: September 23, 2020Date of Patent: February 14, 2023Assignee: TOPPAN PRINTING CO., LTD.Inventor: Madoka Ozawa
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Patent number: 11569520Abstract: A heat treatment apparatus of membrane electrode assemblies includes a base, a first member extending from the base in a first direction, and a plurality of second members formed on the base in a radially outward direction of the first member and having inner surfaces facing the first member, where the first member or the second members includes a heat wire member, and membrane electrode assemblies are disposed between the first member and the second members.Type: GrantFiled: November 12, 2019Date of Patent: January 31, 2023Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Min Jin Kim, Sam Hee Yu, Young June Park, Woo Jin Lee, Ki Sub Lee
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Patent number: 11563230Abstract: A fuel cell single cell includes a pair of separators each having manifold holes, a frame disposed between the separators, a power generating unit disposed in an opening of the frame, and a plurality of gas flow channels configured to connect the power generating unit with the manifold holes. Each of the gas flow channels has a distal channel portion defined by a frame groove provided in the frame and configured to communicate with the manifold holes, and a proximal channel portion defined by a separator groove provided in the corresponding separator and configured to communicate with the power generating unit. Each of the gas flow channels is configured to be independent of adjacent other gas flow channels, at least over a range from a distal end of the distal channel portion, which communicates with the manifold holes, to a point in the proximal channel portion.Type: GrantFiled: December 5, 2019Date of Patent: January 24, 2023Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Masaya Kobayashi, Nobuaki Nonoyama
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Patent number: 11522206Abstract: A fuel cell system includes a fuel cell stack of a plurality of power generation cells and an impedance measuring device for measuring the impedance in the fuel cell stack. When stopping the operation of the fuel cell system, a method for stopping the operation of the fuel cell system operates the plurality of power generation cells to generate electric power, until the impedance value becomes equal to or greater than an objective impedance value. After the impedance value has become equal to or greater than the objective impedance value, the operation stopping method still continues the power generation of the multiple power generation cells for a given period of time.Type: GrantFiled: March 18, 2021Date of Patent: December 6, 2022Assignee: Honda Motor Co., Ltd.Inventors: Nobuki Koiwa, Shinya Watanabe, Yuji Matsumoto, Kazuhide Inoue
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Patent number: 11515556Abstract: The presently disclosed subject matter relates generally to a highly ionically conductive solid electrolyte membrane and to batteries comprising such solid electrolyte membrane.Type: GrantFiled: January 22, 2019Date of Patent: November 29, 2022Assignees: North Carolina Agricultural and Technical State University, The University of North Carolina at GreensboroInventors: Sung-Jin Cho, Alla Letfullina
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Patent number: 11508971Abstract: There is provided a catalyst layer for a fuel cell that can inhibit reduction in water electrolysis function. The catalyst layer for a fuel cell according to this disclosure comprises carbon supports on which Pt particles are supported, and Ir oxide particles, wherein the ratio of the mean primary particle size of the Ir oxide particles with respect to the mean primary particle size of the Pt particles is 20 or greater. The mean primary particle size of the Pt particles may be 20.0 nm or smaller and the mean primary particle size of the Ir oxide particles may be 100.0 nm to 500.0 nm.Type: GrantFiled: October 16, 2020Date of Patent: November 22, 2022Assignee: Toyota Jidosha Kabushiki KaishaInventor: Noriyuki Kitao
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Patent number: 11489173Abstract: The present invention relates to a fuel cell and a fuel cell stack comprising the same, and according to one aspect of the present invention, there is provided a fuel cell comprising a membrane-electrode assembly having a first surface and a second surface opposite to the first surface, wherein an anode electrode and a cathode electrode are each disposed on the first surface; an end plate disposed apart at a predetermined interval on the second surface; a first gas diffusion layer disposed on the anode electrode; a second gas diffusion layer disposed on the cathode electrode; a first separating plate disposed on the first gas diffusion layer and having a plurality of flow channels; and a second separating plate disposed on the second gas diffusion layer and having a plurality of flow channels.Type: GrantFiled: January 31, 2019Date of Patent: November 1, 2022Assignee: LG CHEM, LTD.Inventors: Sung Hyun Yun, Joo Yong Park, Do Young Kim, Woon Jo Kim, Kyung Mun Kang, Jae Choon Yang
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Patent number: 11469475Abstract: The present disclosure provides a separator, a lithium metal negative electrode, and a lithium metal secondary battery which include a solid superacid coating layer. The solid superacid coating layer suppresses a growth of lithium dendrites in a lithium metal secondary battery employing lithium metal as a negative electrode by improving a mobility and a reaction uniformity of lithium at an interface of the lithium metal negative electrode and an electrolyte solution. In the lithium metal secondary battery, the solid superacid coating layer comprising solid superacid material having a porous structure is formed on at least one of the lithium metal negative electrode and the separator.Type: GrantFiled: March 31, 2020Date of Patent: October 11, 2022Assignee: Korea Electronics Technology InstituteInventors: Sanggil Woo, Jisang Yu, Goojin Jeong, Jenam Lee
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Patent number: 11453749Abstract: Aromatic polymers exhibiting thermal stability and conductivity upon imbibement into an acid are disclosed for electrochemical gas sensor applications. Membrane electrode assemblies for electrochemical gas sensors are also provided, comprising a sensing electrode, a counter electrode, and a polymer membrane comprising the polymers of the present invention, disposed between the sensing electrode and the counter electrode.Type: GrantFiled: February 25, 2019Date of Patent: September 27, 2022Assignee: ADVENT TECHNOLOGIES HOLDINGS, INCInventors: Emory Sayre De Castro, Christos L. Chochos, Nora Gourdoupi, Vasilis G. Gregoriou, George Paloumbis
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Patent number: 11430999Abstract: A separator plate for an electrochemical system is described. The separator plate may be used with a bipolar plate and for an electrochemical system comprising a plurality of bipolar plates. The separator plate may have a flow field and guiding structures for guiding a medium through the flow field. The guiding structures of the flow field have a mean height h1 determined perpendicularly to the planar surface plane of the plate. The separator plate may also have a contiguous, lowered transition region where medium flowing from a channel into the flow field, or from the flow field into the channel, flows through the transition region, wherein the transition region has a maximum height hmax determined perpendicularly to the planar surface plane of the plate, where applies: hmax?0.95·h1.Type: GrantFiled: December 18, 2017Date of Patent: August 30, 2022Assignee: REINZ-DICHTUNGS-GMBHInventors: Claudia Kunz, Joachim Scherer, Thomas Stoehr
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Patent number: 11424460Abstract: A four-fluid bipolar plate for a fuel cell includes an oxidant flow field, a fuel reactant flow field, a dedicated coolant passage, and a water management flow field. The bipolar plate includes at least one porous layer. A first side of the porous layer is fluidly connected to the water management flow field via a plurality of pores that act as a bubble barrier. An opposing second side of the porous layer includes either the fuel reactant flow field or the oxidant flow field. In one example, the dedicated coolant passage is internal to the bipolar plate, and may be configured to flow an antifreeze-type coolant.Type: GrantFiled: June 10, 2021Date of Patent: August 23, 2022Assignee: NIMBUS POWER SYSTEMS INC.Inventors: Matthew P. Wilson, Michael E. Gorman, Samuel J. Angles
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Patent number: 11394044Abstract: Disclosed are an antioxidant for fuel cells, a membrane electrode assembly including the same and a method for preparing the antioxidant. The antioxidant for fuel cells includes a core including at least one selected from the group consisting of a metal oxide (MxOk) and a complex metal oxide (MxNyOj, N and M being different metals), and an outer portion (e.g., a shell) located on or over a surface of the core and formed by performing reduction treatment of the surface of the core using a thiourea-based compound. The outer portion includes metal cations (M(x?n)+, n being a natural number of 1 or more) having a smaller oxidation number than a valency of the metal (M) of the core.Type: GrantFiled: November 12, 2019Date of Patent: July 19, 2022Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Jae Jun Ko, In Yu Park, Bo Ki Hong
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Patent number: 11394045Abstract: To provide an electrolyte material having a low hydrogen gas permeability and excellent hot water resistance. An electrolyte material comprising a polymer having units represented by the following formula u1 and units based on chlorotrifluoroethylene at the specific proportion: wherein Q11 is a perfluoroalkylene group which may have an etheric oxygen atom, Q12 is a single bond or a perfluoroalkylene group which may have an etheric oxygen atom, Y1 is a fluorine atom or the like, s is 0 or 1, Rf1 is a perfluoroalkyl group which may have an etheric oxygen atom, X1 is an oxygen atom or the like, a is 0 when X1 is an oxygen, and Z+ is H+ or the like.Type: GrantFiled: January 3, 2019Date of Patent: July 19, 2022Assignee: AGC Inc.Inventors: Susumu Saito, Satoru Hommura
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Patent number: 11333571Abstract: The invention provides a dynamic seal test device for cryogenic fluid medium. The dynamic seal test device includes stator unit, rotor unit, slipway, servo motor unit and sensors. The tested seal is installed inside the stator, and the thermal insulation stator and vacuum rotor together form a dynamic seal test structure. The seals and shaft sleeves can be flexibly replaced, which is beneficial to study the influence of different seal types, structure, and seal land configurations on the sealing performance. The servo motor provides power for the rotor and controls the rotation speed. The device greatly improves the thermal insulation capacity to avoid the gasification for the cryogenic fluid medium induced by the heat transfer from environment so that ensuring the stability of the test device.Type: GrantFiled: September 16, 2019Date of Patent: May 17, 2022Assignee: DALIAN UNIVERSITY OF TECHNOLOGYInventors: Yongqing Wang, Lingsheng Han, Kuo Liu, Fanze Kong, Haibo Liu, Yongquan Gan, Minghua Dai
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Patent number: 11331631Abstract: A proton exchange membrane includes a porous structural framework and a boron-based acid group bonded to the porous structural framework. The porous structural framework may be formed of an amorphous or crystalline inorganic material and/or a synthetic or natural polymer. The boron-based acid group may be a tetravalent boric acid derivative, such as a cyclic boric acid derivative, borospiranic acid, or a borospiranic acid derivative. The boron-based acid group may be the reaction product of boric acid or a boric acid derivative and a poly-hydroxy compound.Type: GrantFiled: September 1, 2021Date of Patent: May 17, 2022Assignee: 1s1 Energy, Inc.Inventors: Sukanta Bhattacharyya, Daniel Sobek
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Patent number: 11305106Abstract: The invention provides a variety of novel devices, systems, and methods of utilizing mixed-ionic-electronic conductor (MIEC) materials adapted to function with an applied current or potential. The materials, as part of a circuit, are placed in contact with a part of a human or nonhuman animal body. A sodium selective membrane system utilizing the MIEC is also described.Type: GrantFiled: October 9, 2019Date of Patent: April 19, 2022Assignee: Battelle Memorial InstituteInventors: Amy M. Heintz, Krenar Shqau, Ramanathan Lalgudi, Patrick Ganzer, Mingming Zhang, Jacob Lilly
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Patent number: 11283094Abstract: Provided are a fuel cell and a method for manufacturing the fuel cell capable of enhancing the joining (joint strength) with a resin sheet and contributing to reduction in the material cost and the product cost. A GDL (e.g., An-GDL) has a protrusion protruding to the outside of a MEA, and the resin sheet is bonded with the GDL at the protrusion of the GDL via the adhesive layer on the outside of the MEA.Type: GrantFiled: February 28, 2020Date of Patent: March 22, 2022Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Noritoshi Oka
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Patent number: 11276868Abstract: A fuel cell plate comprising a face intended to route a fuel gas or an oxidizing gas to the active surface of a Membrane Electrode Assembly, said face of the plate comprising projecting ribs delimiting a determined number of channels provided for the circulation of gas, the channels having a determined length (LCA) and a determined width (E), the ribs having a determined width (LA), the plate being characterized in that the product P of the total length (LN) of the ribs on the plate per unit of active surface (in cm2) multiplied by the rate of opening (TO) of the plate is between 4.7 and 10, i.e. that 4.7<P (cm?1)=LN×TO)/S<10, the rate of opening TO being defined by TO=100·(E/E+LA), the active surface of the plate being the surface of the plate intended to be facing the active surface of the Membrane Electrode Assembly.Type: GrantFiled: January 31, 2018Date of Patent: March 15, 2022Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventor: Johan Andre
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Patent number: 11258072Abstract: A catalyst layer (20) for a fuel cell and to a method suitable for producing the catalyst layer (20). The catalyst layer (20) includes a catalyst material (22) containing a catalytic material (24) and optionally porous carrier material (23) on which the catalytic material (24) is supported. The catalyst layer also includes mesoporous particles (21) made from hydrophobic material.Type: GrantFiled: December 18, 2014Date of Patent: February 22, 2022Assignee: Audi AGInventors: Dustin Banham, Brooks Friess, Siyu Ye
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Patent number: 11242420Abstract: A method for producing a fluorosulfonyl group-containing compound to obtain a compound represented by the following formula 5 from a compound represented by the following formula 1 as a starting material and a method for producing a fluorosulfonyl group-containing monomer in which the fluorosulfonyl group-containing compound is used: wherein R1 and R2 are a C1-3 alkylene group, and RF1 and RF2 are a C1-3 perfluoroalkylene group.Type: GrantFiled: February 26, 2020Date of Patent: February 8, 2022Assignee: AGC Inc.Inventors: Takeshi Hirai, Daisuke Jomuta, Chikaya Tamitsuji
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Patent number: 11198608Abstract: To provide a metal-based structure or nanoparticles whose homogeneity is not deteriorated and whose sticking formation is easy, and a production method thereof with a high safety. A metal-based structure comprises a hydrogen compound, cluster, or an aggregate thereof, represented by the general formula: MmH. The M is a metal-based atom. The m is an integer of 3 or more and 300 or less. H is a hydrogen atom.Type: GrantFiled: September 18, 2018Date of Patent: December 14, 2021Inventor: Kohei Taguchi