Identified Adjuvant, I.e., Surfactant, Etc. Patents (Class 430/115)
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Publication number: 20020006571Abstract: Disclosed is a liquid toner composition prepared by dispersing toner particles consisting essentially of a colorant and a resin in a carrier liquid, the resultant composition forming an electrorheological fluid.Type: ApplicationFiled: March 16, 2000Publication date: January 17, 2002Inventors: Yasuharu Suda, Hiroaki Kuno
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Patent number: 6337168Abstract: A liquid toner for electrostatic imaging which includes: an insulating non-polar carrier liquid, at least one charge director and toner particles dispersed in the carrier liquid. The particles include a core material which is unchargeable or weakly chargeable by the at least one charge director, but which is otherwise suitable for use as a toner material and a coating of at least one ionomer component in an amount effective to impart enhanced chargeability to the ordinarily unchargeable or weakly chargeable particles.Type: GrantFiled: December 9, 1997Date of Patent: January 8, 2002Assignee: Indigo N. V.Inventor: Yaacov Almog
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Patent number: 6322944Abstract: An ink for a liquid electrophotographic color printing system is optimized to reduce the lowering of image density due to wash-off, to obtain a stable over-toned color, and to have a wide reproducible color gamut. The ink includes a plurality of toners for yellow (Y), magenta (M) and cyan (C), each toner being provided in a respective one of a plurality of developing devices, and each toner having a pigment (p) for forming an image having a predetermined color, a binder (b) for binding the pigment on printing paper, a charge controller for imparting electrical properties on the toners, and a stabilizer. A carrier transfers the toners from the developing devices to a photoreceptor belt during development. The blending ratio (b/p) of the binder (b) to the pigment (p) of each toner for yellow (Y), magenta (M) and cyan (C) satisfies the following expressions: b/pyellow(Y)=5±1; b/pmagenta(M)=7±1; and b/pcyan(C)=8±1.Type: GrantFiled: September 11, 2000Date of Patent: November 27, 2001Assignee: SamSung Electronics Co., Ltd.Inventors: Yu-man Kim, In-yong Song, Yong-kook Kim, Seung-young Byeon
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Patent number: 6287741Abstract: A liquid toner composition for use in high viscosity electrostatic printing processes. The liquid toner comprises a non-aqueous carrier liquid which is an electrically non-conductive liquid being a silicone fluid of straight chained or cyclic configuration, a silicone fluid of cyclic configuration, a silicone fluid of branched configuration, or a combination thereof having a viscosity in the range of from 0.5 to 1,000 mPa.s, an insoluble marking particle, and a dispersion additive, the dispersion additive comprising a polysiloxane having at least one functional group comprising a radical which introduces an active site into the polysiloxane and wherein the functional group is a radical selected from the group comprising a vinyl group, a carboxylic group, a hydroxyl group, or an amine group. The particular advantage of the liquid composition is that the formation of rivulets is minimised during printing with resultant improvement in image quality.Type: GrantFiled: April 11, 2000Date of Patent: September 11, 2001Assignee: Research Laboratories of Australia Pty LtdInventor: Herbert Lee Marko
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Publication number: 20010008912Abstract: The invention provides novel pigment dispersants of the formula (I) 1Type: ApplicationFiled: December 1, 2000Publication date: July 19, 2001Applicant: Clariant GmbHInventors: Joachim Weber, Felix Wendelin Grimm, Erwin Dietz
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Patent number: 6218066Abstract: A liquid developer comprised of a nonpolar liquid, resin, colorant, and a cyclodextrin charge acceptance component.Type: GrantFiled: January 27, 2000Date of Patent: April 17, 2001Assignee: Xerox CorporationInventors: Weizhong Zhao, David H. Pan, John W. Spiewak, Christopher M. Knapp
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Patent number: 6190817Abstract: In an electrographic toner, containing a plurality of polymer particles (4), each polymer particle has functional groups on its surface, which dissociate into two parts in a carrier liquid (6), with one part of each group remaining firmly attached to the surface, so that the individual polymer particles carry electrostatic charges in the carrier liquid. Such a toner can be used in conjunction with carrier liquids that represent no problems from the point of view of occupational safety and environmental protection. Transfer processes and a developing system for use with this toner are described.Type: GrantFiled: December 19, 1997Date of Patent: February 20, 2001Assignee: Heidelberger Druckmaschinen AGInventor: Carsten Scheonfeld
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Patent number: 6187498Abstract: A process including: forming a first image on a first substrate with a liquid toner comprising a resin, a colorant, a carrier liquid, and an adhesion promoting compound; transferring the image from the first substrate to a second substrate; overcoating the image on the second substrate with a transparent overcoat layer, and treating the resulting overcoated image.Type: GrantFiled: February 10, 2000Date of Patent: February 13, 2001Assignee: Xerox CorporationInventors: Christopher M. Knapp, George A. Gibson, David H. Pan, John W. Spiewak
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Patent number: 6180308Abstract: A liquid developer comprised of a nonpolar liquid, resin, colorant, and a charge acceptance component comprised of an aluminum complex of the formulas, or mixtures thereof wherein R1 is selected from the group consisting of hydrogen and alkyl, and n represents the number of R1 substituents.Type: GrantFiled: January 27, 2000Date of Patent: January 30, 2001Assignee: Xerox CorporationInventors: David H. Pan, Weizhong Zhao, John W. Spiewak, Christopher M. Knapp
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Patent number: 6174640Abstract: A polymer suitable for the preparation of liquid toners for developing electrostatic images and liquid toners incorporating such a polymer. The polymer is a reaction product of an epoxy resin and carrier soluble nitrogen bearing polymeric compound. The epoxy resin may be a reaction product of bisphenol A and epichlorhydrin and the carrier soluble nitrogen bearing polymeric compound may be an alkylated polyvinylpyrrolidone.Type: GrantFiled: July 28, 1999Date of Patent: January 16, 2001Assignee: Research Laboratories of Australia PTY Ltd.Inventor: Terence Michael Lawson
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Patent number: 6146803Abstract: In a liquid toner for use in imaging processes which comprises pigmented polymer particles, at least one charge director and a hydrocarbon liquid toner carrier, the polymer is a blend of at least two distinct polymer components, the blend being characterized in that in a 40% non-volatile mixture with a hydrocarbon liquid toner carrier, it has on a semi-logarithmic viscosity vs. temperature cooling curve, a break-point at a temperature below about 65.degree. C. at a viscosity of between about 3.times.10.sup.5 centipoises and about 5.times.10.sup.6 centipoises. The polymer blend and an electrostatic imaging process (particularly one using an intermediate transfer member) utilizing the above toner are also claimed. Use of such polymer blends enables liquid toner to be applied in such processes at no more than and in some cases less than the customary processing temperatures.Type: GrantFiled: February 28, 1994Date of Patent: November 14, 2000Assignee: Indigo N.V.Inventors: Benzion Landa, Peretz Ben-Avraham, Becky Bossidan
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Patent number: 6136492Abstract: This invention is based upon the discovery that the characteristics of toner resins made by emulsion polymerization can be improved by utilizing diacid cycloaliphatic emulsifiers in the synthesis thereof. Toner resins which are made utilizing such diacid cycloaliphatic emulsifiers do not exhibit significant electrical charge effects from the residual level of soap in the resin compared to resins made using standard soaps; such as, rosin acid soaps and fatty acid soaps. They also generally contain a lower level of ash since salts do not need to be used in their coagulation. As a result of the low level of ash, the toner resin made from the diacid soap exhibits excellent resistance to moisture sensitivity and adsorption. This feature gives the toners made from these resins better electrical charge stability compared to resins made from conventional soaps since adsorbed moisture is known to neutralize electrical charges.Type: GrantFiled: February 3, 1999Date of Patent: October 24, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Gordon Edward Hardy, Jr., Gary Lee Burroway
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Patent number: 6132922Abstract: A high viscosity, high solid volume liquid ink for use in electrophotographic printing systems. A silicone oil carrier material is combined with toner particles (including pigment, binder polymers and charge control agents) in a ratio of about 45% toner particles to 55% carrier liquid. The resultant ink preferably has a viscosity in the range 30000 to 50000 cs. The high viscosity ink of the present invention is preferably applied to a photoconductor material having a latent charged image thereon and a thin pre-wet material applied thereto. The pre-wet material is preferably a low viscosity silicone oil material. The composite layer of the combined low viscosity pre-wet and high viscosity ink permits the polymerized toner particles to migrate toward the latent charged image on the photoconductor surface. The high viscosity ink of the present invention helps maintain uniform dispersion of the toner particles in the liquid carrier.Type: GrantFiled: January 6, 1999Date of Patent: October 17, 2000Assignee: Advanced Color Technology, Inc.Inventors: Kensuke Fukae, Ichiro Yoshida
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Patent number: 6120957Abstract: Toner includes binder resin having an acid value in a range from 10 mgKOH/g to 100 mgKOH/g; and at least one kind of compound selected from among Color Index Pigment Yellow 180 and derivatives thereof. A liquid developer includes the toner and carrier liquid. Toner includes binder resin having a weight average molecular weight (Mw) in a range from 3000 to 10000; and at least one kind of compound selected from among Color Index Pigment Yellow 180 and derivatives thereof. A liquid developer includes the toner and carrier liquid.Type: GrantFiled: June 22, 1999Date of Patent: September 19, 2000Assignee: Minolta Co., Ltd.Inventors: Hidetoshi Miyamoto, Toshimitsu Fujiwara, Keyaki Yogome
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Patent number: 6117608Abstract: A liquid toner of the present invention comprises particles containing a foaming inhibitor and an electrically insulating dispersion medium dispersing the particles therein. One preferred liquid toner comprises copolymer resin particles and an electrically insulating dispersion medium, the copolymer resin particles containing a copolymer resin composed of at least two different monomer components including a first and a second monomer components and a foaming inhibitor, and the copolymer resin particles being dispersed in the dispersion medium, wherein the copolymer resin and the dispersion medium are related to each other such that (i) a difference .DELTA.(.delta.p.sup.1 -.delta.d) between a SP value .delta.p.sup.1 of a homopolymer composed only of the first monomer component and a SP value .delta.d of the dispersion medium is not smaller than 1.0, (ii) a difference .DELTA.(.delta.p.sup.2 -.delta.d) between a SP value .delta.p.sup.Type: GrantFiled: March 30, 1999Date of Patent: September 12, 2000Assignee: Dai Nippon Printing Co., Ltd.Inventors: Makoto Aoyagi, Katsuya Teshima
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Patent number: 6100312Abstract: A radiation sensitive colored composition comprising (A) a copolymer having, as constitutional repeating units, at least ((1) a monofuctional macromonomer having the specified structure and weight-average molecular weight of 3.times.10.sup.4 or below, (2) a monomer having the specified structure and (3) a quaternary ammonium salt monomer; (B) a radiation sensitive compound; and (C) a pigment: which can provide a color filter having excellent pattern reproducibility because of its high suitablity for dispersion of fine-grain pigment and its high storage stability.Type: GrantFiled: November 7, 1997Date of Patent: August 8, 2000Assignees: Fuji Photo Co., Ltd., Fujifilm Olin Co., Ltd.Inventors: Nobuo Suzuki, Naoki Kato
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Patent number: 6020103Abstract: A liquid toner for use in a liquid developer contains a dispersion medium and toner particles, each of which toner particles contains a coloring agent and a binder agent and is dispersed in the dispersion medium, the toner particles comprising small toner particles with a particle diameter of 0.1 .mu.m or less in an amount of 20 wt. % or less of the total weight of the toner particles, and having an average particle diameter of 0.3 to 5 .mu.m. Using the above-mentioned liquid toner in which the amount of the toner particles is controlled to 5 to 100 wt. % of the total weight of the liquid toner, a latent electrostatic image formed on a photoconductor can be developed to a toner image.Type: GrantFiled: July 3, 1997Date of Patent: February 1, 2000Assignee: Ricoh Company, Ltd.Inventors: Kazuo Tsubuko, Akihiko Gotoh, Tsuyoshi Asami, Yukio Tabata
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Patent number: 5998075Abstract: The invention provides the following liquid developers (1)-(5). (1) A liquid developer including a carrier liquid having an aniline point of 80.degree. C. to 100.degree. C.; and at least one compound selected from among Color Index Pigment Yellow 180, Color Index Solvent Yellow 162 and derivatives of these. (2) A liquid developer including a carrier liquid having an aniline point of 80.degree. C. to 100.degree. C.; toner; and at least one compound selected from among salicylic acid metal salt and derivatives thereof. (3) A liquid developer including a carrier liquid having an aniline point of 80.degree. C. to 100.degree. C.; toner; and at least one compound selected from among borate-containing compound and derivatives thereof.Type: GrantFiled: June 17, 1999Date of Patent: December 7, 1999Assignee: Minolta Co., Ltd.Inventors: Toshimitsu Fujiwara, Hidetoshi Miyamoto, Keyaki Yogome
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Patent number: 5989769Abstract: A liquid developer composition including: a resin, a colorant, a liquid carrier vehicle, and a cake inducing agent.Type: GrantFiled: October 30, 1998Date of Patent: November 23, 1999Assignee: Xerox CorporationInventors: Ralph A. Mosher, William M. Prest, Jr., Paul W. Morehouse, Jr., Samuel Kaplan, Timothy J. Fuller, Weizhong Zhao, Anita C. VanLaeken, Raymond W. Stover
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Patent number: 5981134Abstract: A liquid developer for electrophotography using a polyester resin as a toner binder resin which is suitable for high-speed systems and has excellent stability over time is disclosed.The invention is a novel liquid developer for electrophotography having colored particles dispersed in an electrically insulated fluid medium. The liquid developer includes an oil-soluble ionic surface active agent as a charge controller. According to one embodiment, the colored particles include a binder resin having an acid value of 40 mgKOH/g or higher but less than or equal to 100 mgKOH/g. According to another embodiment, the colored particles include a binder resin having a glass transition temperature Tg of 35.degree. C. or higher but less than or equal to 65.degree. C.Type: GrantFiled: March 23, 1998Date of Patent: November 9, 1999Assignee: Minolta Co., Ltd.Inventors: Hidetoshi Miyamoto, Seishi Ojima, Toshimitsu Fujiwara
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Patent number: 5972548Abstract: A process for forming high quality colored or multi-colored ceramic images or designs on ceramic surfaces comprising: (a) forming a liquid toner image comprised of polymer based toner particles incorporating a ceramic pigment and a carrier liquid, on an imaging surface; (b) transferring the image to a ceramic surface; and (c) heating the image and the ceramic substrate surface to an elevated temperature at which the ceramic pigment sinter and fuse to the ceramic substrate surface.Type: GrantFiled: October 14, 1997Date of Patent: October 26, 1999Assignee: Indigo N.V.Inventors: Benzion Landa, Peretz Ben-Avraham
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Patent number: 5958643Abstract: A liquid developer having polymer particles dispersed in a dispersion medium, wherein the polymer particles have a mean volume particle size d.sub.50 of 0.5.about.5.0 .mu.m, and degree of flatness (longest diameter of a single particle/shortest diameter of a single particle) is greater than 1.5 but less than 30.Type: GrantFiled: August 6, 1996Date of Patent: September 28, 1999Assignee: Minolta Co., Ltd.Inventors: Toshimitsu Fujiwara, Shuji Iino, Hidetoshi Miyamoto
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Patent number: 5955236Abstract: A toner for electrographic printing includes a liquid carrier and a release agent added to the carrier to reduce the amount of carrier leaving the developer section, thus allowing operation at higher speeds and reducing the time and energy required for carrier removal in subsequent sections. An imaging system, or unit of an imaging system, and a method of imaging employ an imaging member such as a belt to form a liquid-toned image, to condition the image, and to transfer it to a print-receiving medium. The member moves through several sections, and transports liquid toner out of an image-developing section. In a preferred embodiment the release agent wets the imaging member, and has a higher boiling point than the carrier and a lower surface tension, though its viscosity may be higher. The release agent reduces carrier entrainment, and coats the imaging member, also enhancing transfer of the final print image. It may also counteract aging characteristics of the imaging member.Type: GrantFiled: January 30, 1998Date of Patent: September 21, 1999Assignee: Delphax SystemsInventor: Michael D. Bower
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Patent number: 5942365Abstract: A liquid developer comprised of a liquid, resin particles, an optional nonpolar liquid soluble charge director, and a charge adjuvant comprised of an aluminum salt of an acid, wherein the acid is a hydroxy carboxylic acid, an amino carboxylic acid, an aromatic carboxylic acid, an aliphatic carboxylic acid, or a sulfonic acid and imaging processes using the same one disclosed.Type: GrantFiled: June 19, 1997Date of Patent: August 24, 1999Assignee: Xerox CorporationInventors: George A. Gibson, Scott D. Chamberlain, Thomas R. Pickering, John W. Spiewak, Jacques C. Bertrand, Roger N. Ciccarelli, Denise R. Bayley
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Patent number: 5935755Abstract: Disclosed is a process which comprises (a) applying to a recording sheet a marking material comprising a Raman-detectable component which, when irradiated with monochromatic radiation, exhibits a detectable Raman spectrum, thereby forming a mark on the recording sheet; (b) irradiating the mark on the recording sheet with monochromatic radiation; and (c) measuring the Raman spectrum of radiation scattered from the mark when the mark is irradiated with monochromatic radiation.Type: GrantFiled: August 21, 1995Date of Patent: August 10, 1999Assignee: Xerox CorporationInventors: Peter M. Kazmaier, Erwin Buncel, Herbert F. Shurvell
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Patent number: 5923929Abstract: Scuff resistance, abrasion resistance and peel resistance of a wide class of liquid toners may be improved by the addition of a minor amount of an additional material which, at the fusing temperature used for the toner, has a much lower viscosity, preferably several orders of magnitude lower, than the viscosity of the toner particles at the fusing temperature and which forms a separate phase from the toner particles when solidified. It is believed that such material, during the fusing process, migrates to the outer surface of the image. During cooling of the image after it is fused, the additional material forms a substantially separate phase resulting in a hard slippery coating of the additional material which protects the image from abrasion.Type: GrantFiled: June 26, 1997Date of Patent: July 13, 1999Assignee: Indigo N.V.Inventors: Peretz Ben Avraham, Becky Bossidon, Yaacov Almog, Benzion Landa
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Patent number: 5919866Abstract: The toner particles of this invention comprise pigment and a resin. The resin comprises a novel polymer formed from ethylenically unsaturated monomers, macromeric moieties that render the resin dispersible in hydrocarbon solvents, and a surface-release promoting moiety. When used for toner particles the polymer further comprises charge directing chelating moieties. The toner particles also include a charge director, preferably a metal cation. The toner particles, when dispersed in a carrier liquid, are useful as liquid toners for electrographic or electrophotographic processes.Type: GrantFiled: February 9, 1998Date of Patent: July 6, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Prabhakara S. Rao, Valdis Mikelsons
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Patent number: 5876896Abstract: Disclosed is a liquid toner composition, comprising an ethylene-based copolymer resin, an ethylene-based copolymer resin, an electrically insulating liquid material, and a surfactant represented by general formula given below ##STR1## where R is an alkyl group or an alkylaryl group, n, which represents ad adduct ethyleneoxide mole number, is an integer of 4 to 13, and R' is H or R(CH.sub.2 CH.sub.2 O).sub.n group.Type: GrantFiled: August 18, 1997Date of Patent: March 2, 1999Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Yasuharu Suda, Hiroyoshi Kawamura, Hiroaki Kuno
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Patent number: 5866292Abstract: A positively charged liquid developer comprised of a nonpolar liquid, thermoplastic resin particles, pigment, a charge director, and a charge control agent comprised of a PEO:PPO, preferably in a solid form.Type: GrantFiled: July 23, 1997Date of Patent: February 2, 1999Assignee: Xerox CorporationInventors: Scott D. Chamberlain, David H. Pan, Christopher M. Knapp, John W. Spiewak, George A. Gibson, Frank J. Bonsignore
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Patent number: 5858595Abstract: Low optical density magnetic fluid which is a stable dispersion of fine magnetic particles. A method of forming the stable dispersion which includes providing an ion exchange resin, loading the ion exchange resin with an ion capable of forming a magnetic phase, treating the loaded resin to form magnetic particles and micronizing the resin and magnetic particles in a fluid to form an aqueous stable colloid. The invention provides submicron particles and submicron particles which are dispersed in an aqueous colloid. A method of forming the stable dispersion which includes providing an ion exchange resin, loading the ion exchange resin with an ion, treating the loaded resin to form nanoscale particles. Fluidizing the resin and particles to form an aqueous stable colloid. A method of forming magnetic materials having tunable magnetic properties and the magnetic materials formed thereby.Type: GrantFiled: June 7, 1995Date of Patent: January 12, 1999Assignee: Xerox CorporationInventor: Ronald F. Ziolo
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Patent number: 5840453Abstract: A solvation-based method for charging toner particles in a liquid electrophotographic developer composition is provided. The method makes use of a material containing specific salvation sites which are incorporated into the resinous phase of the toner, and a charge director which is a metal salt, the metal, cationic component of which is effective to form a highly stable, "solvated" charged toner complex. Toner and developer compositions are also provided which make use of the novel solvation-based mode of charge direction.Type: GrantFiled: December 3, 1993Date of Patent: November 24, 1998Assignee: Colorep, Inc.Inventor: Ronald Swidler
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Patent number: 5792584Abstract: The invention relates to a method for producing liquid toner compositions containing charge directors and in which the electrical properties of the charge directors are stabilized, which method comprises the steps of: (A) first making a homogeneous liquid composition which comprises (1) liquid hydrocarbon compatible with liquid toners for electrostatic imaging, (2) at least one charge director, and (3) at least one stabilizing component in an amount effective to stabilize the electrical properties of the at least one charge director, the stabilizing component being selected from solubilizable acids which include organic moieties (e.g. C.sub.12 to C.sub.18 saturated aliphatic carboxylic acids, C.sub.4 to C.sub.18 ethylenically unsaturated aliphatic carboxylic acids, C.sub.7 to C.sub.Type: GrantFiled: July 27, 1994Date of Patent: August 11, 1998Assignee: Indigo N.V.Inventor: Yaacov Almog
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Patent number: 5789133Abstract: Toner particles having a polar group of either an acid group or a basic group at least on surface layers thereof are employed, and a polymer, which contains a polar group of reverse polarity to the polar group of the surface layers of the toner particles and is soluble in a medium, is added to the medium.Type: GrantFiled: February 6, 1997Date of Patent: August 4, 1998Assignee: Nippon Paint Co., Ltd.Inventors: Naoya Yabuuchi, Yashuhiro Shibai, Tsuyoshi Imamura
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Patent number: 5783350Abstract: The developer for electrostatic photography according to the present invention comprises toner particles containing a thermoplastic resin and a colorant dispersed in an electrically insulating carrier having a melting point above room temperature wherein the thermoplastic resin is insoluble in the electrically insulating carrier at a temperature below the melting point of the electrically insulating carrier but becomes solvated with the electrically insulating carrier at a temperature above the melting point of the electrically insulating carrier. The present invention provides a developer for electrostatic photography, which enables to reduce the emission of vapor, to carry out a fixing treatment at a higher rate, to reduce the amount of energy required for fixing treatment and to create a high-quality image even after repeated use of the developer.Type: GrantFiled: December 9, 1996Date of Patent: July 21, 1998Assignee: Fuji Xerox Co., Ltd.Inventors: Hirotaka Matsuoka, Takako Kobayashi
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Patent number: 5783349Abstract: A liquid developer comprised of a nonpolar liquid, resin, optional colorant, a charge director, and an optional charge control agent, and wherein the charge director is comprised of a mixture of phosphoric acid esters I, II and III, and IV a nonpolar liquid soluble organic aluminum complex of the formulas ##STR1## hydrates thereof or mixtures thereof, wherein R.sub.1 is selected from the group consisting of hydrogen and alkyl, and n represents a number of from about 1 to about 6.Type: GrantFiled: June 30, 1997Date of Patent: July 21, 1998Assignee: Xerox CorporationInventors: John W. Spiewak, Mary Ann Machonkin, David H. Pan, Scott D. Chamberlain, Christopher M. Knapp
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Patent number: 5763131Abstract: A toner for electrographic printing includes a liquid carrier and a release agent added to the carrier to reduce the amount of carrier leaving the developer section, thus allowing operation at higher speeds and reducing the time and energy required for carrier removal in subsequent sections. An imaging system, or unit of an imaging system, and a method of imaging employ an imaging member such as a belt to form a liquid-toned image, to condition the image, and to transfer it to a print-receiving medium. The member moves through several sections, and transports liquid toner out of an image-developing section. In a preferred embodiment the release agent wets the imaging member, and has a higher boiling point than the carrier and a lower surface tension, though its viscosity may be higher. The release agent reduces carrier entrainment, and coats the imaging member, also enhancing transfer of the final print image. It may also counteract aging characteristics of the imaging member.Type: GrantFiled: August 2, 1996Date of Patent: June 9, 1998Assignee: Delphax SystemsInventor: Michael D. Bower
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Patent number: 5759733Abstract: A liquid developer for use in electrophotography is disclosed, which comprises (i) a toner comprising as the main toner components a colorant, a resin, and a polyolefin resin having an acid value of from 5 to 50 and a melt viscosity at 200.degree. C. of from 100 to 15,000 cps, and (ii) a carrier liquid in which the toner is dispersed. The polyolefin resin and the colorant in the liquid developer may constitute an integral flushing colorant which is prepared by subjecting the resin and the colorant to flushing processing.Type: GrantFiled: January 13, 1992Date of Patent: June 2, 1998Assignee: Ricoh Company, Ltd.Inventors: Kazuo Tsubuko, Shinichi Kuramoto, Toshiki Nanya, Kazuhiko Umemura, Kayoko Nagai
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Patent number: 5753763Abstract: The toner particles of this invention comprise pigment and a resin. The resin comprises a novel polymer formed from ethylenically unsaturated monomers, macromeric moieties that render the resin dispersible in hydrocarbon solvents, and a surface-release promoting moiety. When used for toner particles the polymer further comprises charge directing chelating moieties. The toner particles also include a charge director, preferably a metal cation. The toner particles, when dispersed in a carrier liquid, are useful as liquid toners for electrographic or electrophotographic processes.Type: GrantFiled: October 30, 1996Date of Patent: May 19, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Prabhakara S. Rao, Valdis Mikelsons
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Patent number: 5750306Abstract: A graft copolymer of recurring units of (C.sub.6 -C.sub.18)alkyl (meth)acrylate (A), N-vinylpyrrolidone (B), glycidyl (meth)acrylate (C), and glycidyl (meth)acrylate units esterified with (meth)acrylic acid (D) onto which polymeric side chains of units of N-vinylpyrrolidone, (C.sub.1 -C.sub.3)alkyl acrylate and, if appropriate, (C.sub.1 -C.sub.3)alkyl methacrylate are grafted. The polymer is suitable as a binder for colorless, negatively chargeable liquid toners, in particular in combination with graft copolymers of (C.sub.1 -C.sub.6)alkyl (meth)acrylate, (C.sub.6 -C.sub.18)alkyl (meth)acrylate and units in which chains of N-vinyl-pyrrolidone units are grafted onto one of the units mentioned, as a charge control agent. After fixing of the electrophotographically produced toner image, the toners give colorless resist masks or printing screens with a high resistance toward etching agents and solvents.Type: GrantFiled: December 27, 1995Date of Patent: May 12, 1998Assignee: Agfa-Gevaert AGInventors: Raimund Josef Faust, Danuta Eva Allen, Silvia Lutz
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Patent number: 5714297Abstract: A positively charged liquid developer comprised of a nonpolar liquid, thermoplastic resin particles, pigment, a charge director, and a charge control agent comprised of Rhodamine Y.Type: GrantFiled: January 6, 1997Date of Patent: February 3, 1998Assignee: Xerox CorporationInventors: Scott D. Chamberlain, John W. Spiewak, David H. Pan, George A. Gibson, Christopher M. Knapp, Roger N. Ciccarelli
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Patent number: 5714296Abstract: A graft copolymer of recurring units of (C.sub.6 -C.sub.18)alkyl (meth)acrylate (A), vinylpyridine (B), glycidyl (meth) acrylate (C), and glycidyl (meth) acrylate units esterified with (meth)acrylic acid (D) onto which polymeric side chains of units of vinylpyridine, (C.sub.1 -C.sub.3)alkyl acrylate, and optionally (C.sub.1 -C.sub.3)alkyl methacrylate are grafted. The polymer is suitable as a binder for colorless, positively chargeable liquid toners, in particular in combination with a copolymer of (C.sub.6 -C.sub.18)alkyl (meth) acrylate and hydroxyalkyl (meth)acrylate as charge control agents. After fixing of the electrophotographically produced toner image, the toners give colorless resist masks or printing screens with a high resistance toward etching agents and solvents.Type: GrantFiled: December 27, 1995Date of Patent: February 3, 1998Assignee: Agfa-Gevaert AGInventors: Raimund Josef Faust, Danuta Eva Allen
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Patent number: 5714993Abstract: A process for the preparation of toner compositions comprising: forming a mixture comprised of at least one free radical reactive monomer, a colorant, a stabilizer compound containing a stable free radical reactive group, and a liquid vehicle; and heating the mixture from about 75.degree. to about 200.degree. C. to effect polymerization of said monomer, wherein there results stabilized core resin particles containing said colorant and wherein said stabilized core particles are stabilized by said stable free radical reactive stabilizer compounds being bonded directly to the core particles.Type: GrantFiled: May 8, 1996Date of Patent: February 3, 1998Assignee: Xerox CorporationInventors: Barkev Keoshkerian, Michael K. Georges, Stephan V. Drappel
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Patent number: 5695904Abstract: A dry electrostatographic process involving the development of the latent image using a semi-dry developer having a solids content ranging from about 50% to about 99% by weight based on the weight of the semi-dry developer, and wherein the semi-dry developer is prepared by a developer preparation process comprising: (i) removing liquid from a liquid developer in an effective amount to yield the semi-dry developer; or (ii) adding a liquid additive to a dry developer containing toner particles ranging in size of from about 1 to 7 microns in an effective amount to yield the semi-dry developer.Type: GrantFiled: August 19, 1992Date of Patent: December 9, 1997Assignee: Xerox CorporationInventors: James R. Larson, Joseph Mammino
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Patent number: 5695903Abstract: A process for developing irradiated radiation-sensitive recording materials using an aqueous-alkaline developer which contains compounds of the formula (I) ##STR1## wherein A is H, Na, K, NH.sub.4 or NR.sub.4, whereR is a substituted or unsubstituted alkyl radical,W and X, independently of one another are H or --CH.sub.2 --COOA,Y is H or COOA andZ is H or OH,wherein the compound of the formula (I) contains at least 3 COOA units.Type: GrantFiled: December 20, 1995Date of Patent: December 9, 1997Assignee: Agfa-Gevaert AGInventors: Andreas Elsaesser, Werner Frass, Jutta Bachstein
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Patent number: 5688624Abstract: A positively charged liquid developer comprised of a nonpolar liquid, thermoplastic resin particles, pigment, a charge director, and a charge control agent comprised of a PEO:PPO, preferably in a solid form.Type: GrantFiled: January 6, 1997Date of Patent: November 18, 1997Assignee: Xerox CorporationInventors: Scott D. Chamberlain, David H. Pan, Christopher M. Knapp, John W. Spiewak, George A. Gibson, Frank J. Bonsignore
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Patent number: 5679492Abstract: A negatively charged liquid developer comprised of a nonpolar liquid, a mixture of a first and a second thermoplastic resin with dissimilar melt indexes, a pigment, charge director, optional charge adjuvent, a charge control agent comprised of a component of the alternative formulas ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen and alkyl, and n is 0 (zero), 1, 2, 3, or 4, and wherein the melt index of the first resin is from about 50 to about 800 grams, and the melt index of the second resin from about 850 to about 2,500 grams.Type: GrantFiled: August 8, 1996Date of Patent: October 21, 1997Assignee: Xerox CorporationInventors: Scott D. Chamberlain, Edward B. Caruthers, Jr., Constance J. Thornton, George A. Gibson
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Patent number: 5672457Abstract: A mixed resin liquid developer and a process for the preparation of liquid developers comprised of a nonpolar liquid, a mixture of thermoplastic resin particles, a charge director, and a charge control agent, the process characterized by the addition of a first thermoplastic resin and a charge control agent, followed by adding to the product obtained a second thermoplastic resin.Type: GrantFiled: June 3, 1996Date of Patent: September 30, 1997Assignee: Xerox CorporationInventors: George A. Gibson, Scott D. Chamberlain
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Patent number: 5672456Abstract: A positively charged liquid developer comprised of a nonpolar liquid, thermoplastic resin, a cyclodextrin charge control additive, pigment, and a charge director comprised of a nonpolar liquid soluble organic aluminum complex, or mixtures thereof of the formulas ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen and alkyl, and n represents the number of R substituents.Type: GrantFiled: January 6, 1997Date of Patent: September 30, 1997Assignee: Xerox CorporationInventors: Scott D. Chamberlain, David H. Pan, John W. Spiewak
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Patent number: 5633109Abstract: Disclosed is an ink composition which comprises an aqueous liquid vehicle, a photochromic material, and a vesicle-forming lipid, wherein vesicles of the lipid are present in the ink.Type: GrantFiled: December 5, 1995Date of Patent: May 27, 1997Assignee: Xerox CorporationInventors: Carol A. Jennings, Marcel P. Breton, MaryAnna Isabella, Eric G. Johnson, Trevor I. Martin, John F. Oliver
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Patent number: H1828Abstract: A process for the preparation of colored dispersions which comprises adding colorant, a liquid vehicle, a free radical initiator, and a stable free radical agent to a microfluidizer; heating at a temperature of from about 100 to about 160.degree. C.; and thereafter, optionally cooling.Type: GrantFiled: July 30, 1997Date of Patent: January 4, 2000Assignee: Xerox CorporationInventors: Raymond W. Wong, Marcel P. Breton