Abstract: A process for the preparation of an electrostatographic photosensitive device comprising combining a sodium additive comprising sodium carbonate, sodium bicarbonate, sodium selenite, sodium hydroxide or mixtures thereof with trigonal selenium particles, an organic resin binder and a solvent for the binder to form a milling mixture, milling the milling mixture to form a uniform dispersion, applying the dispersion to a substrate in an even layer and drying the layer.

Abstract: A layer of amorphous silicon containing H, preferably 10-40 atomic %H, is used as a photoconductive layer for electrophotographic photosensitive member.

Abstract: A process for depositing particles within a softenable layer to form a migration imaging member wherein the layer is softened by heating, exposed in a first deposition zone to a high impingement rate of vapors of selenium or selenium alloy moving along in a line of sight path from a selenium or selenium alloy source to form a sub-surface monolayer of spherical particles comprising the selenium or selenium alloy, removed from the first deposition zone prior to a substantial dropoff in transmission optical density, exposed to a lower impingement rate of vapors of selenium or selenium alloy in a second deposition zone to increase the size of the spherical particles while maintaining a narrow particle size distribution and achieving a high surface packing density thereby increasing the transmission optical density of the imaging member, and thereafter removed from the second deposition zone prior to a substantial dropoff in transmission optical density.

Abstract: An image-forming member for electrophotography has a photoconductive layer comprising a hydrogenated amorphous semiconductor composed of silicon and/or germanium as a matrix and at least one chemical modifier such as carbon, nitrogen and oxygen contained in the matrix.

Abstract: A photoconductive material comprising a phthalocyanine and a phthalocyanine derivative in which the phthalocyanine molecule has benzene nuclei substituted with at least one member selected from nitro and cyano groups, and an electrophotographic plate comprising a photoconductive layer of the photoconductive material dispersed in a binder resin.

Abstract: A photoconductor material having high sensitivity to infrared light is provided therefore making it suitable for use in laser printers. The photoconductor of this invention has a dark decay of approximately 40 volts/second, thereby enhancing the use of this invention with infrared laser printers as compared to prior art infrared sensitive photoconductors. The photoconductor of this invention comprises cadmium sulfide (CdS), cadmium selenide (CdSe), cadmium carbonate (CdCO.sub.3) and cadmium oxide (CdO) in a binder, and preferably also includes a small amount of copper dopant. The photoconductor of this invention is prepared by adding ammonia to a suspension of cadmium sulfide/cadmium carbonate in water and then adding hydrogen selenide to this suspended solution.

Abstract: An electrophotographic photosensitive member comprises a photoconductive layer composed of photoconductive powders dispersed in a deionized resin.

Abstract: Disclosed is a photosensitive element for electrophotography comprised of a layered structure having a polycyclic quinone pigment dispersed in an organic resin binder as a charge generating layer and an organic charge transport layer mixed with a resin binder.

Abstract: An electrophotographic photoreceptor comprises an electrically conductive substrate, a layer of charge generating material which chloroaluminium phthalocyanine and chloroaluminium monochlorophthalocyanine are evaporated in a vacuum over the electrically conductive substrate and the evaporated film of chloroaluminium phthalocyanine and chloroaluminium monochlorophthalocyanine are treated by an organic solvent selected from the group consisting tetrohydrofurane, methanol, acetone, methyl ethyl ketone, .alpha.-chloronaphthalene, pyridine, a layer of charge transport material overcoated the layer of charge generating material. The electrophotographic photoreceptor and the preparation thereof is disclosed to apply for use in a laser printing machine in which a light of laser diode or light emission diode is used as a light source.

Abstract: A layered electrophotographic photoconductor whose charge generation layer comprises a bisazo pigment selected from the group consisting of the bisazo pigments represented by formula (1) and whose charge transport layer contains a charge transport material selected from the group consisting of anthrancene compounds represented by formula (2) or from the group consisting of distyrylbenzene compounds represented by formula (3) ##STR1##

Abstract: Photoconductive particles are prepared by the reaction of a water-soluble metal salt with an ion exchange resin having an anion which reacts with the metal ion of the water-soluble metal salt to produce a water insoluble metal compound and the deposition of the water insoluble metal compound resulting from the reaction on the surface of the photoconductive particles.

Abstract: A photoconductive layer embodies the combination of an organic photoconductive donor compound, such as poly(N-vinyl) carbazole and derivatives thereof, and an acceptor-sensitizer compound having the general formula ##STR1## in which M is a metal such as boron, aluminum, gallium, indium and thallium, X and Y are oxygen sulphur, nitrogen, phosphorus, antimony or selenium, Z.sub.1 and Z.sub.2 are halogen, or substituted or unsubstituted alkyl, alkaryl or heterocyclic groups, R.sub.1 and R.sub.2 are substituted or unsubstituted aryl, alkaryl, alkyl or alicyclic groups, and n is 2 or 3.

Abstract: Layers of controllably dopable amorphous silicon and germanium can be produced by means of low pressure chemical vapor deposition, at a reaction temperature between about 450.degree. C. and about 630.degree. C., for Si, and between about 350.degree. C. and about 400.degree. C. for Ge, in an atmosphere comprising a Si-yielding or Ge-yielding precursor such as SiH.sub.4 or GeI.sub.4, at a pressure between about 0.05 Torr and about 0.7 Torr, preferably between about 0.2 and 0.4 Torr. For undoped Si and P-doped Si, the preferred temperature range is from about 550.degree. C. to about 630.degree. C., for B-doped Si, it is from about 480.degree. C. to about 540.degree. C. The material produced has a density in excess of 0.9 of the corresponding crystalline density, and contains less than 1 atomic percent of hydrogen. An advantageous doping method is addition of dopant-forming precursor, e.g., PH.sub.3 or B.sub.2 H.sub.6, to the atmosphere.

Abstract: A plurality of aggregate photoconductive particles having a predominant particle size of less than about 1.0 micron are disclosed. Such particles are useful in heterogeneous photoconductive compositions, electrophotographic elements and electrophotographic imaging processes.

Abstract: Improvement in the humidity resistance of photoconductive cadmium sulfoselenide (CdSSe) is achieved by soaking commercially available CdSSe in a solution of vinylidene chloride-acrylonitrile copolymer in an organic solvent, followed by removing the excessive solution and then heating the soaked photoconductive material.

Abstract: An electrophotographic element comprising an electrically conductive support and a mono-layer or multi-layer type photosensitive layer, superposed thereon, containing as an active ingredient a disazo pigment having the following general formula: ##STR1## where Ar is a substituted or non-substituted phenyl, substituted or non-substituted naphthyl, anthryl, pyrenyl, pyridyl, thienyl, furyl or carbazolyl group.

Abstract: A photoconductive material for electrophotography is composed of photoconductive cadmium sulfide particles provided with a hydroxide, oxide or sulfide of a metal element or semiconductive element on the particle surface. The photoconductive material dispersed in a binder resin can be used as a photoconductive layer for an electrophotographic photosensitive member.

Abstract: A sensitizing dye and a hydrophilic resin are dissolved in a first solvent, and a second solvent is added to the solution. The second solvent is less volatile than the first solvent, miscible therewith and does not dissolve both of the sensitizing dye and the hydrophilic resin. A powder of the sensitized zinc oxide is incorporated into the solution. After blending, the mixture is dried and pulverized to obtain a powder of sensitized zinc oxide. This powder is then mixed with a bonding agent consisting of a resinous material having an acid value of 5-30 to form a mixture which is formed into a thin photosensitive layer for use in electrophotography.

Abstract: An imaging method, and novel materials, in which there is provided an imaging mono-layer comprising a plurality of electrically photosensitive particles which comprise a resin carrier, a colorant dye, an electrically photosensitive organic material, a sensitizing dye, and a solubilizing agent for the sensitizing dye in the organic material. The imaging mono-layer is subjected to an electric field, exposed to a pattern of sensitizing electromagnetic radiation, separation of the photosensitized particles from the unsensitized particles, and color-amplification of the desired image by imbibing the colorant dye into a suitable substrate.

Abstract: A method of rendering a surface of substrate photoconduction comprising applying to the substrate a layer of N-vinyl carbazole and a prepolymer formed thereupon and completely polymerizing the monomer or prepolymer in situ on the substrate.

Abstract: An electrophotographic element comprising, in successive layers; a conductive substrate, a charge generation layer and a charge transport layer, the charge generation layer being formed by the steps of; adding to a dispersion comprising a photoconductive organic pigment, a solvent and a resin being superior in mutual solubility with said solvent a resinous solution comprising said solvent and a resin being relatively inferior in mutual solubility with said solvent to the former resin; dispersing (or stirring) the resulting mixture again, thereby obtaining a photoconductive organic pigment-dispersed resinous solution; and applying said resinous solution onto the conductive substrate and drying.

Abstract: This invention is directed to photosensitive material for electrophotography and more particularly it is directed to the improvement of the properties with respect to humidity of photosensitive material by using photoconductive material in combination with ion exchange resin or by using photoconductive material which is previously washed in an aqueous solution in the presence of ion exchange resin.

Abstract: An electrophotographic element that comprises an electrically conductive support and a photoconductive layer containing a photosensitive azo-compound dispersed in a film-forming polymeric binder is prepared by synthesizing the photosensitive azo-compound in situ, by reaction between a diazonium compound and an azo-coupling component, in the film-forming polymeric layer on the support. The azo-compounds thus synthetized are distributed in the binder layer in an almost perfectly homogeneous form. Under an electron microscope screen scan they are not distinguishable as separate particles, even at a ten thousand fold magnification. By forming a very thin photoconductive layer in this way and coating it with a charge transporting top layer, especially useful electrophotographic elements are obtained. The invention relates also to electrophotographic elements prepared according to the process.

Abstract: An electrophotographic element having a conductive support upon which a coating of oleophilic resin-encapsulated zinc oxide particles, and a sensitizer dispersed in a binder containing vinyl chloride and vinyl acetate polymers is disclosed. Capsule wall can be 5A to 1.mu. thick. The oleophilic resin can be silicone, urethane, epoxy.

Abstract: A photoconductive insulating layer for an electrophotographic sensitive member formed of a fine powder of CdS.nCdCO.sub.3, wherein 0<n.ltoreq.4, bonded by an insulating resin and having manganese stearate dispersed therein. Advantageously the CdS.nCdCO.sub.3 contains copper as an acceptor impurity in an amount of between about 0.025 and 0.1 grain atomic weight of copper per 100 gram atomic weight of cadmium, the manganese stearate is present in an amount of about 2 to 4 parts by weight per 100 parts by weight of CdS.nCdCO.sub.3 and is preferably adherent thereto, the layer is between 10 and 100 microns thick and the CdS.nCdCO.sub.3 particle size is about 1 to 2 microns or less. In producing the layer the CdS.nCdCO.sub.3 (Cu) is produced by reacting Cd, Cu and CO.sub.

Abstract: An endless belt or cylinder in which the base or substrate is a conductive member and there is a coating of a wholly inorganic, microcrystalline, high quantum yield, electronically anisotropic photoconductive material on the substrate. The coating is capable of being charged and thereafter exposed to radiant energy from an object such as a scene or pattern for selectively discharging the coating and providing a latent image of the object on the coating. The latent image can thereafter be developed by toner and transferred to a receptor such as a sheet of paper, cloth and the like.The belt may be formed of highly flexible synthetic organic resin such as polyester or the like and in such case the coating will be deposited onto an intervening thin layer of an ohmic material.The cylinder may be a relatively rigid one of metal.The coating may be cadmium sulfide.The method of making the cylinder or belt comprises forming the cylinder or belt and placing same in a sputtering apparatus and r.f.

Abstract: An electrophotographic recording material having a porous layer of photoconductor-binder, particularly with crystalline tetragonal lead monoxide as the photoconductor, is provided between an electrically conductive layer and a dielectric foil, said pores of the layer of photoconductor-binder, prior to providing the foil, being filled with a high-ohmic dielectric liquid to wet both the layer of photoconductor-binder and the foil. Preferably, the pores of the layer are filled with tetramethyl tin as the photoconductor-binder. As a result of this, the use of an adhesive between the foil and the layer of photoconductor-binder may be omitted. A large porosity and hence a great sensitivity of the layer of photoconductor-binder are maintained.

Abstract: Electrophotographic members prepared by coating a paper or film with a slurry of photoconductive metal-compound particles, e.g., zinc oxide particles, dispersed in a liquid vehicle containing a solution of resinous binder having carboxyl groups. Viscosity of the coating slurry is controlled and/or stabilized by incorporating into the slurry a viscosity stabilizing agent comprising a chelate precursor which forms with the binder a chelating agent having the property of complexing metal ions, e.g., zinc ions, by formation of a ring structure incorporating the metal ion. Suitable viscosity stabilizing agents include: ethylenediamine, diethylenetriamine, and ethylenediaminetetraacetic acid and its salts.

Abstract: High speed organic photoconductors are produced by crystallizing p-terphenyl from solution in a solvent having defined solubility parameter limits. Heterogeneous photoconductive insulating compositions comprising a dispersion of these p-terphenyls in an electrically insulating binder can be applied to an electrically conducting support to provide an electrophotographic element with high photoconductive speed.

Abstract: A printing drum is disclosed for electrostatic copying. The drum has a photo-electric-sensitive layer consisting of amorphous silicon advantageously containing hydrogen. The layer is designed to have a PN transition. A method is also disclosed for producing the layer by means of decomposition of a conveyed silicon-containing gas to which, if necessary, a gaseous doping material is added during a glow discharge in a heated printing drum.

Abstract: This invention is directed to photosensitive material for electrophotography and more particularly it is directed to the improvement of the properties with respect to humidity of photosensitive material by using photoconductive material in combination with ion exchange resin or by using photoconductive material which is previously washed in an aqueous solution in the presence of ion exchange resin.

Abstract: Disclosed is a method of forming finely divided photosensitive trigonal selenium particles which are submicron in size and generally spherical in shape. The method comprises forming an alkaline solution containing selenide and/or polyselenide ions, followed by the precipitation of finely divided trigonal selenium particles from said solution by the addition of an oxidizing agent to said alkaline solution. The trigonal selenium particles are formed into a binder layer photosensitive device by dispersing them with an organic resin in solution with an organic solvent which when applied to a substrate in a uniform layer, is heated to remove the solvent and form the device. Continued heat treatment of the device can result in enhancement of its ability to accept an electrostatic charge.