By Milling, Grinding, Crushing, Or Comminuting Patents (Class 430/137.18)
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Patent number: 11860618Abstract: The embodiments are and include at least an apparatus, system and method for forming print material particles for additive manufacturing (AM) printing. The apparatus, system and method include at least a melt chamber comprising a polymer melt; a vertical extruder that fluidically receives the polymer melt; an atomizer that atomizes the polymer melt from the vertical extruder and that distributes the atomized polymer melt; a fall chamber comprising a plurality of zones into which the atomized polymer melt is distributed; and a collector to receive the print material particles formed of the atomized polymer melt after falling through the plurality of zones.Type: GrantFiled: July 21, 2022Date of Patent: January 2, 2024Assignee: JABIL INC.Inventors: Nicholas J. Dippel, Thomas Gardner, Daryn York
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Patent number: 10669383Abstract: Spheroid polymer particles are prepared from non-spheroid particles by heating the non-spheroid particles in a liquid medium to a temperature that is above the glass transition temperature or the melting temperature of the polymer and then cooling.Type: GrantFiled: October 30, 2007Date of Patent: June 2, 2020Assignee: Evonik CorporationInventors: Jason N. Campbell, Bruce W. Hudson
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Patent number: 9529294Abstract: In accordance with various embodiments of the invention, a method of forming an ultraviolet security toner for use in printing hardware originally designed to use chemically prepared toner includes melt-blending binder resin particles and optionally a charge-control agent, a colorant and a releasing agent. The fluorescent pigment is then admixed to the melt-blended particles to form a fluorescent pre-toner. A first inorganic material is then blended with the fluorescent pre-toner, coating the particles of the fluorescent pre-toner with the first inorganic material. A second inorganic material is then blended with the coated pre-toner, adding another layer of coating to the fluorescent pre-toner. The first inorganic material has an average particle diameter size that is less than the average particle diameter size of the fluorescent pigment particles and the second inorganic material has an average particle diameter size less than that of the first inorganic material.Type: GrantFiled: September 17, 2015Date of Patent: December 27, 2016Assignee: TROY GROUP, INC.Inventors: Kevin L. Heilman, Michael R. Riley
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Patent number: 9304418Abstract: A system for pigment milling includes a pulsing direct current (DC) source that generates a DC pulse, an electromagnetic field generating subunit that includes an electromagnetic coil coupled to the pulsing DC source to receive the DC pulse and to generate a magnetic field, and a rotating container subunit that includes a container for holding magnetic particles and ink pigment particles in an ink carrier, and a rotating subunit to rotate the container. A portion of the container is disposed within the electromagnetic coil and generation of the magnetic field causing motion of the magnetic particles thereby dispersing the ink pigment particles within the ink carrier.Type: GrantFiled: July 24, 2014Date of Patent: April 5, 2016Assignee: XEROX CORPORATIONInventors: Harry P. Latchman, Ke Zhou, Frank Ping-Hay Lee
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Publication number: 20150111144Abstract: Composite materials such as composite particles have a solid non-elastomeric continuous phase made of an organic polymer having a glass transition temperature of at least 25° C. Dispersed within this solid non-elastomeric continuous phase are many multi-compartment porous chemically crosslinked elastomeric particles that have a mode particle size of at least 1 ?m and up to and including 10 ?m. The composite particles can be used as toner particles in electrophotographic imaging methods to provide fused toner images and especially stacked fused toner images.Type: ApplicationFiled: October 18, 2013Publication date: April 23, 2015Inventors: Mridula Nair, Joseph Salvatore Sedita, Peter David Rollinson
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Publication number: 20150111143Abstract: A method for producing a positively chargeable toner, including: step 1: melt-kneading a toner raw material composition containing a resin binder, a positively chargeable charge control agent, and fine fluororesin particles, and a recycled powder; step 2: cooling a melt-kneaded mixture obtained in the step 1, and pulverizing a cooled mixture; and step 3: classifying a pulverized product obtained in the step 2, wherein the resin binder in the toner raw material composition contains 50% by mass or more of a polyester having a softening point of 125° C. or higher and 170° C. or lower. The positively chargeable toner obtainable by the method of the present invention is suitably used in developing latent images formed in, for example, an electrophotographic method, an electrostatic recording method, an electrostatic printing method, or the like.Type: ApplicationFiled: October 6, 2014Publication date: April 23, 2015Applicant: Kao CorporationInventors: Kohei KATAYAMA, Masahito YAMAZAKI
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Publication number: 20150044607Abstract: A method for manufacturing carrier core particles for electrophotographic developer that include manganese, magnesium, and iron as a core composition. The method includes a granulation step (A) of granulating a mixture of raw materials containing manganese, magnesium, and iron with a reducing agent added at a ratio of 0.10% to 1.00% by mass to a total mass of the raw materials containing manganese, magnesium, and iron, and a firing step of firing the granular material granulated in the granulation step. The firing step includes a first heating step (C) of applying heat at a constant temperature ranging from 500° C. to 800° C. in an atmosphere with an oxygen concentration of 1000 ppm to 15000 ppm for a predetermined period of time and a second heating step (D) of applying heat at a temperature higher than 800° C. for a predetermined period of time after the first heating step.Type: ApplicationFiled: November 30, 2012Publication date: February 12, 2015Inventor: Takeshi Kawauchi
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Patent number: 8940467Abstract: A toner is provided that, even in a small amount thereof, gives a satisfactory image density and that is free of image problems, e.g., fogging and offset resistance, even during long-term use and in a high-temperature, high-humidity environment. The toner contains a binder resin, a pigment, and a prescribed azo compound wherein, designating as (A) the solubility of the azo compound in a toluene-hexane solubility test and as (B) the solubility of the binder resin constituting the toner in the toluene-hexane solubility test, the (A) and the (B) satisfy the relationship |(B)?(A)|?60.Type: GrantFiled: February 26, 2013Date of Patent: January 27, 2015Assignee: Canon Kabushiki KaishaInventors: Yasuhiro Hashimoto, Takayuki Toyoda, Masashi Kawamura, Naotaka Ikeda, Hidekazu Fumita, Emi Watanabe, Yuhei Terui
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Patent number: 8927186Abstract: A toner for use in developing an electrostatic latent image is provided. The toner includes a colored particulate material including at least a binder resin and a colorant; and an external additive present on a surface of the colored particulate material and including a particulate crystalline hydroxyapatite. The particulate crystalline hydroxyapatite has an average aspect ratio of not less than 3 and less than 30.Type: GrantFiled: November 23, 2010Date of Patent: January 6, 2015Assignee: Ricoh Company, LimitedInventors: Masayuki Ishii, Toyoshi Sawada
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Publication number: 20140363208Abstract: The present invention relates to a liquid electrophotographic ink comprising a carrier liquid, a pigmented resin composite dispersed in the carrier liquid, and about 0.15 to about 10% (w/w) of an organic wax. The liquid electrophotographic ink is typically formulated for printing in a liquid electrophotographic printer.Type: ApplicationFiled: December 19, 2011Publication date: December 11, 2014Applicant: Hewlett-Packard Indigo B.V.Inventors: Stella Stolin Roditi, Haim Cohen, Getahun Biadglin, Femanda Orilik, Nava Klein, Albert Teishev
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Publication number: 20140349232Abstract: A method for producing a toner that comprises toner particles, each of which comprises a binder resin, which comprises a resin (A) capable of forming a crystalline structure, and a colorant, the method including: a pressure holding step of, after preparing toner particles, holding the toner particles for 5 minutes or more at a pressure of 2.0 MPa or more under conditions of a temperature T1 (° C.) represented by formula (1): 20?T1?Tp2??(1) (wherein, Tp2 represents the onset temperature of the maximum endothermic peak derived from the resin (A)), wherein a peak temperature Tp1 of the maximum endothermic peak derived from the resin (A) during the first temperature rise of the toner particles as determined by differential scanning calorimetric measurement is 50° C. to 90° C.Type: ApplicationFiled: May 21, 2014Publication date: November 27, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Tetsuya Kinumatsu, Shuntaro Watanabe, Kenji Aoki, Atsushi Tani, Yoshihiro Nakagawa, Takaaki Kaya, Toshifumi Mori, Yusuke Kosaki, Takashige Kasuya
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Patent number: 8895220Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.Type: GrantFiled: August 29, 2013Date of Patent: November 25, 2014Assignee: Lexmark International, Inc.Inventors: Michael James Bensing, Craig Michael Bartelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
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Publication number: 20140342279Abstract: A method for making polymer-encapsulated metallic ink particles is disclosed herein. An ethylene-based polymeric resin powder is formed, and is mixed with a metallic pigment powder to form a powder mixture. The powder mixture is melted to form a metallic polymer melt. A non-polar carrier is added to the metallic polymer melt to form a slurry. The slurry is processed in a microfluidizer.Type: ApplicationFiled: January 5, 2012Publication date: November 20, 2014Inventors: Doris Chun, Hou T. Ng, Albert Teishev
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Patent number: 8877420Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to plasticize the pressure plastic material; applying a shear force to the compressive fluid and the plasticized pressure plastic material, between which an interface exists, in the presence of a surfactant to granulate the pressure plastic material in the compressive fluid, so as to produce particles.Type: GrantFiled: March 9, 2011Date of Patent: November 4, 2014Assignee: Ricoh Company, Ltd.Inventors: Chiaki Tanaka, Ryota Inoue, Taichi Nemoto, Yoshitaka Yamauchi
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Publication number: 20140314449Abstract: The present disclosure provides for a liquid electrophotographic (LEP) ink comprising a carrier fluid, a pigment, a high melt viscosity ethylene acrylic acid copolymer resin, and a high acid ethylene acrylic acid copolymer resin. The high acid ethylene acrylic acid copolymer resin can have an acid content of at least 15 wt % and a viscosity of at least 8,000 poise. Additionally, the LEP ink can have a total resin acidity of at least 15 wt % and a total resin melt viscosity of at least 20,000 poise.Type: ApplicationFiled: January 31, 2011Publication date: October 23, 2014Applicant: Hewlett-Packard Development Company, L.P.Inventors: Stella Stolin Roditi, Haim Cohen, Neta Filip-Granit, Roi Liraz, Eyal Bodinger, Marc Klein, Nava Klein, Eyal Bachar, Swissa Shay, Albert Teishev, Yaron Grinwald, Fernanda Orlik, Ilanit Mor
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Patent number: 8852841Abstract: A method for producing a toner for electrostatic image development containing at least a resin binder and a charge control agent, including step 1: melt-kneading components containing a resin binder and a charge control agent to provide a melt-kneaded product; and step 2: pulverizing the melt-kneaded product, and classifying a pulverized product, wherein the resin binder contains a polyester A obtained by polycondensing an alcohol component containing 1,2-propanediol and a carboxylic acid component containing a rosin compound and an aliphatic dicarboxylic acid compound having 6 to 10 carbon atoms, wherein 1,2-propanediol is contained in the alcohol component of the polyester A in an amount of 85% by mol or more. The toner for electrostatic image development obtained by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: GrantFiled: November 30, 2012Date of Patent: October 7, 2014Assignee: Kao CorporationInventors: Takeshi Ashizawa, Shogo Watanabe, Takashi Kubo, Norihiro Hirai
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Patent number: 8846289Abstract: A method of manufacturing toner including melting, mixing, and kneading a releasing agent and a coloring agent with at least part of a polyester binder resin, and suspending and granulating an oil phase comprising the binder resin, the coloring agent, and the releasing agent in an aqueous medium.Type: GrantFiled: September 24, 2010Date of Patent: September 30, 2014Assignee: Ricoh Company, Ltd.Inventors: Satoshi Ogawa, Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Masana Shiba, Junichi Awamura
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Publication number: 20140287357Abstract: The present disclosure provides for compositions, methods, and systems directed towards a liquid electrophotographic ink comprising a carrier fluid, a pigment, a first resin, and a stable cross-linkable resin that is solvated or swellable with the carrier fluid, where the stable cross-linkable resin does not undergo cross-linking until a temperature of at least 110° C. and, once cross-linked, does not melt until a temperature of at least 300° C.Type: ApplicationFiled: October 25, 2011Publication date: September 25, 2014Inventors: Doris Chun, Hou T. Ng, Albert Teishev
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Patent number: 8828285Abstract: A particulate production apparatus, including a droplet discharger to discharge a liquid including a particulate element which is solidified to become a particulate; and a pressure controller to feed the liquid including a particulate element to the droplet discharger at a pressure within a desired range.Type: GrantFiled: July 27, 2012Date of Patent: September 9, 2014Assignee: Ricoh Company, Ltd.Inventors: Kiyotada Katoh, Minoru Masuda, Yasutada Shitara, Yoshihiro Norikane, Satoshi Takahashi
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Patent number: 8815488Abstract: A method for producing a toner including the step of melt-kneading a mixture containing a resin binder and a wax with a twin-screw kneader, wherein the resin binder contains three kinds of a resin R1, a resin R2 and a resin R3 having different softening points to each other, wherein the wax contains at least two kinds of a wax W2 and a wax W3 having different melting points to each other, wherein the softening points of R1, R2 and R3 and the melting point W2 meet certain relationships, and wherein the mixture is supplied to the twin-screw kneader in an amount of from 1.3 to 5.0 kg/hr·cm2 per unit cross-sectional area of the screw. The toner obtainable by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: GrantFiled: November 9, 2012Date of Patent: August 26, 2014Assignee: Kao CorporationInventor: Takeshi Ashizawa
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Patent number: 8765343Abstract: An electrostatic latent image developing toner contains a binder resin, a colorant, europium, and bismuth.Type: GrantFiled: February 8, 2012Date of Patent: July 1, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Yuki Takamiya, Eisuke Iwazaki, Satoshi Yoshida, Satoshi Inoue
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Publication number: 20140134531Abstract: A yellow toner is provided which is much more improved in color development and chroma, and much more improved in light resistance. The yellow toner contains, at least, a binder resin, a wax, and a coloring agent. The coloring agent is a compound represented by the following general formula (1).Type: ApplicationFiled: January 23, 2014Publication date: May 15, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Shosei Mori, Takeshi Sekiguchi, Taichi Shintou, Takeshi Miyazaki
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Patent number: 8703378Abstract: A method of manufacturing toner including mixing mother toner particles containing a binder resin and a coloring agent and first particles having an average primary particle diameter of from 100 nm to 1 ?m to using a mixer including a rotary shaft member, multiple stirring members provided to the surface of the shaft member, and a casing to cover the multiple stirring members, wherein the cross section of the inner periphery of the casing relative to a direction perpendicular to the rotation axis of the shaft member is circular around the rotation axis with a substantially constant distance between the inner periphery and the rotation axis. The casing covers the multiple stirring members and a cooling jacket is provided to at least part of the outer periphery of the casing. The weight ratio of the particles to the mother toner particles is from 1.5% to 10%.Type: GrantFiled: September 16, 2011Date of Patent: April 22, 2014Assignee: Ricoh Company, Ltd.Inventors: Kohsuke Satoh, Tetsuya Tanaka, Masahiro Kawamoto, Natsuko Matsushita
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Patent number: 8685607Abstract: The continuous process for manufacturing toners disclosed herein includes continuously feeding components of a toner composition into a feed section of a screw extruder at a controlled rate. The continuous process for manufacturing toners may include feeding the components of a toner composition into the feed section of a screw extruder without performing an external or secondary dispersion step. That is to say, the components of the toner composition may be fed directly into the extruder without using dispersions of individual components as used in batch processes. Rather, the toner components are added to the extruder in dry form, melt-mixed, and may be dispersed in aqueous form in the extruder. The process may produce micron-sized toner particles, thus no further size reduction may be necessary.Type: GrantFiled: August 29, 2012Date of Patent: April 1, 2014Assignee: Xerox CorporationInventors: Joo T. Chung, Chieh-Min Cheng, Zhen Lai, Mark E. Mang, Eugene F. Young, Brian Andaya, Joseph Leonardo
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Publication number: 20140080045Abstract: A method of preparing a developer includes mixing a carrier and a powder with each other while falling with gravity.Type: ApplicationFiled: August 7, 2013Publication date: March 20, 2014Inventors: Kousuke Suzuki, Yuuki Mizutani, Shinichiro Yagi
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Patent number: 8673532Abstract: A method for producing dry toner particles that have similar particle size and shape characteristics as chemically produced toners. The method includes melt-mixing a toner resin with a colorant and, optionally, a wax, to form a toner; grinding the toner to form toner particles; classifying the toner particles into particles averaging 4 to 10 microns in size; blending the classified toner particles with additives in a high-speed blender; and then processing the mixture with optional additional surface additives in a conical mixer. The method produces toner particles that have high circularity and sharper particle size distribution. The surface processing of the toner particles does not affect the internal constituents of the toner particles.Type: GrantFiled: June 26, 2012Date of Patent: March 18, 2014Assignee: Xerox CorporationInventors: Paul Casalmir, Bryan L. Norcott
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Patent number: 8614041Abstract: Disclosed is a toner for electrophotography containing at least a binder resin. This toner for electrophotography is characterized in that (a) the tetrahydrofuran (THF) soluble content in the toner has a first peak in the molecular weight region of not less than 2,000 but less than 5,000 and a second peak in the molecular weight region of not less than 100,000 but less than 200,000 in the chromatogram obtained by gel permeation chromatography (GPC); (b) the binder resin contains at least a carboxyl group-containing vinyl resin (C) and a glycidyl group-containing vinyl resin (E); and (c) the mass ratio of the styrene monomer to the acrylic monomer in the binder resin, namely (S/A), is not less than 4.6 but less than 8.5.Type: GrantFiled: December 18, 2007Date of Patent: December 24, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Hiroshi Matsuoka, Kazuya Sakata, Hiroyuki Takei, Kenji Uchiyama, Ichiro Sasaki
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Patent number: 8609313Abstract: A toner containing a resin binder and a colorant, wherein the resin binder contains a crystalline resin and an amorphous resin, the crystalline resin containing a composite resin containing: a polycondensation resin component obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms, and a carboxylic acid component containing an aromatic dicarboxylic acid compound, and a styrenic resin component, and the amorphous resin containing a polyester obtained from an alcohol component containing an aliphatic diol in an amount of 60% by mol or more, and a carboxylic acid component. The toner of the present invention is suitably used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: GrantFiled: May 13, 2011Date of Patent: December 17, 2013Assignee: Kao CorporationInventors: Akihiro Eida, Shogo Watanabe, Takashi Kubo
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Patent number: 8603373Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to produce a melt of the pressure plastic material; and discharging the melt of the pressure plastic material by differential pressure to a space, so as to form particles, wherein the discharging includes at least one of (A) discharging the melt of the pressure plastic material while a compressive fluid is supplied to the melt of the pressure plastic material, and (B) discharging the melt of the pressure plastic material through one or more through-holes, to which vibration is applied, so as to change the shape of the melt of the pressure plastic material from a columnar shape, through the columnar shape with constrictions, into a particle shape.Type: GrantFiled: October 31, 2011Date of Patent: December 10, 2013Assignee: Ricoh Company, Ltd.Inventors: Shinji Ohtani, Chiaki Tanaka
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Patent number: 8592127Abstract: A method for producing a toner, comprising the step of feeding raw materials containing a resin binder and a colorant to an open-roller type kneader, and melt-kneading the raw materials, wherein the resin binder contains a crystalline polyester and an amorphous polyester, and wherein the crystalline polyester and the amorphous polyester fed to the open-roller type kneader are in a weight ratio, i.e. crystalline polyester/amorphous polyester, of from 5/95 to 30/70, and have a ratio of average particle sizes of crystalline polyester/amorphous polyester of from 1.5 to 4.0. The toner obtained according to the present invention is used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: GrantFiled: July 28, 2009Date of Patent: November 26, 2013Assignee: Kao CorporationInventor: Akihiro Eida
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Publication number: 20130280648Abstract: A toner composition including at least one phosphorescent pigment that absorbs energy released by natural or artificial light, and is able to be seen in a dark environment through luminescence of a certain color created by the energy released as light, and a method of forming and using the toner are described. The phosphorescent toner has a particle size in the range of about 15-40 microns, which allows the toner to have the ability to absorb and then release the needed amount of light energy to be noticeable in a dark environment.Type: ApplicationFiled: April 18, 2012Publication date: October 24, 2013Applicant: TROY GROUP, INC.Inventors: Carrie A. Gilson, Kevin L. Heilman, Michael R. Rlley
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Patent number: 8551681Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.Type: GrantFiled: September 8, 2008Date of Patent: October 8, 2013Assignee: Lexmark International, Inc.Inventors: Michael James Bensing, Craig Michael Bertelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
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Publication number: 20130244165Abstract: A toner is provided that, even in a small amount thereof, gives a satisfactory image density and that is free of image problems, e.g., fogging and offset resistance, even during long-term use and in a high-temperature, high-humidity environment. The toner contains a binder resin, a pigment, and a prescribed azo compound wherein, designating as (A) the solubility of the azo compound in a toluene-hexane solubility test and as (B) the solubility of the binder resin constituting the toner in the toluene-hexane solubility test, the (A) and the (B) satisfy the relationship |(B)?(A)|?60.Type: ApplicationFiled: February 26, 2013Publication date: September 19, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Yasuhiro Hashimoto, Takayuki Toyoda, Masashi Kawamura, Naotaka Ikeda, Hidekazu Fumita, Emi Watanabe, Yuhei Terui
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Patent number: 8501381Abstract: The invention relates to a liquid developer composition comprising a dispersant, and toner particles dispersed in said dispersant. The liquid developer composition can be used for printing onto a substrate. The binder resin in the toner particles is curable, e.g. by UV-light.Type: GrantFiled: March 19, 2008Date of Patent: August 6, 2013Assignee: Hologi Hitec-Imaging GmbHInventors: Hans-Josef Humpert, Serge Tavernier, Kerstin Hymon
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Patent number: 8455172Abstract: A method for producing a toner, containing: dispersing, in an aqueous medium, an oil phase which contains an organic solvent, and a binder resin component contained in the organic solvent, where the binder resin component contains a crystalline polyester resin and an amorphous polyester resin; and removing the organic solvent from the dispersion to obtain the toner, in which the dispersing further contains heating and dissolving the crystalline polyester and the amorphous polyester in the organic solvent to obtain a solution, cooling the solution so as to recrystallize the crystalline polyester resin, and mechanically pulverizing the recrystallized crystalline polyester resin so as to obtain a crystalline polyester dispersion.Type: GrantFiled: September 27, 2010Date of Patent: June 4, 2013Assignee: Ricoh Company, Ltd.Inventors: Junichi Awamura, Hiroshi Yamashita, Teruki Kusahara, Tsuyoshi Sugimoto, Tomomi Suzuki
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Patent number: 8445170Abstract: Provided is a binder resin for color toners which comprises at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E) and a reaction product thereof, and contains both a tetrahydrofuran (THF) soluble portion and a THF insoluble gel portion, wherein the THF soluble portion has a main peak in the molecular weight region of not less than 10,000 and less than 15,000 in the chromatogram obtained by gel permeation chromatography (GPC), the content of the THF insoluble gel portion is less than 1 mass %, and the softening point is not more than 130 degrees centigrade.Type: GrantFiled: August 27, 2008Date of Patent: May 21, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Kazuya Sakata, Hiroshi Matsuoka, Hiroyuki Takei, Kenji Uchiyama, Ichirou Sasaki
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Patent number: 8435714Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes melt mixing a resin in the absence of an organic solvent, optionally adding a surfactant to the resin, adding to the resin at least one colorant and other optional toner additives, adding to the resin a basic agent and water to form a mixture, and subjecting the mixture to acoustic mixing at a suitable frequency to form to form an emulsion. A phase inversion may then be performed to create a phase inversed emulsion including a disperse phase comprising molten resin and the optional ingredients of the toner composition, at which time toner-sized droplets may be solidified from the disperse phase into toner particles, which can be recovered for use.Type: GrantFiled: June 25, 2010Date of Patent: May 7, 2013Assignee: Xerox CorporationInventors: Zhen Lai, Chieh-Min Cheng, Shigang Qiu, Emily L. Moore, Tie Hwee Ng
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Publication number: 20130084521Abstract: The carrier core particles for electrophotographic developer include a core composition expressed by a general formula Fe3O4 as a main ingredient and 30 ppm to 400 ppm Na. Such carrier core particles can reduce environmental dependency thereof, while optimizing the resistivity.Type: ApplicationFiled: May 17, 2011Publication date: April 4, 2013Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MSTERIALS CO., LTDInventor: Takeshi Kawauchi
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Publication number: 20130034808Abstract: A pulverizer including a solid-gas mixer to mix a compressed gas and particles of a raw material to be pulverized to prepare a solid-gas mixture; a particle path controlling nozzle connected with the solid-gas mixer to feed the solid-gas mixture fed from the solid-gas mixer while accelerating the solid-gas mixture and controlling the particles of the raw material so as to choose different flow paths based on particle diameters of the particles of the raw material; a collision member; and an accelerating tube connected with the particle path controlling nozzle to further accelerate the solid-gas mixture fed from the particle path controlling nozzle while maintaining the flow paths of the particles and ejecting the accelerated solid-gas mixture toward the collision member to pulverize the raw material.Type: ApplicationFiled: July 24, 2012Publication date: February 7, 2013Inventor: Keisuke YAGOME
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Patent number: 8362198Abstract: There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a polyester (p1) not containing an aromatic ring or a polyester (p2) containing an aromatic ring, and produced by polycondensation of a polyol component and a polycarboxylic acid component, and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0?H2/H1?0.Type: GrantFiled: February 18, 2011Date of Patent: January 29, 2013Assignee: Sanyo Chemical Industries, Ltd.Inventors: Yasuhiro Shindo, Sho Kim
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Patent number: 8362197Abstract: There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a polyester (p1) not containing an aromatic ring or a polyester (p2) containing an aromatic ring, and produced by polycondensation of a polyol component and a polycarboxylic acid component, and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0?H2/H1?0.Type: GrantFiled: May 20, 2009Date of Patent: January 29, 2013Assignee: Sanyo Chemical Industries, Ltd.Inventors: Yasuhiro Shindo, Sho Kim
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Publication number: 20130011781Abstract: A carrier core particle for an electrophotographic developer includes a composition expressed by a general formula: MnxFe3?xO4+y (0<x?1, 0<y), a full width at half maximum z of the most intense peak (311) plane in a powder X-ray diffraction pattern satisfying 0.16 (degree)?z, and a magnetization of 50 emu/g or higher in an external magnetic field of 1000 Oe.Type: ApplicationFiled: March 8, 2011Publication date: January 10, 2013Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.Inventors: Takeshi Kawauchi, Sho Ogawa
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Publication number: 20120322005Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to plasticize the pressure plastic material; applying a shear force to the compressive fluid and the plasticized pressure plastic material, between which an interface exists, in the presence of a surfactant to granulate the pressure plastic material in the compressive fluid, so as to produce particles.Type: ApplicationFiled: March 9, 2011Publication date: December 20, 2012Inventors: Chiaki Tanaka, Ryota Inoue, Taichi Nemoto, Yoshitaka Yamauchi
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Patent number: 8329375Abstract: A toner for developing an electrostatic charge image includes: an amorphous polyester resin; a crystalline polyester resin; and a releasing agent, an amount of the releasing agent in the toner being from 5 to 15% by weight; an amount of the releasing agent present at a surface of the toner being from 10 to 35% by weight; and the toner showing at least one endothermic peak in each of a temperature range from 45 to 60° C., a temperature range from 65 to 80° C., and a temperature range from 85 to 100° C. in a temperature-rise process of differential scanning calorimetry of the toner.Type: GrantFiled: April 22, 2009Date of Patent: December 11, 2012Assignee: Fuji Xerox Co., Ltd.Inventors: Hiroshi Nakazawa, Masanobu Ninomiya, Hirokazu Hamano
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Patent number: 8329371Abstract: A non-magnetic toner, including a binder resin; a wax present dispersing in the toner in the shape of a particle; and a colorant, wherein the wax having a particle diameter not less than 2.0 ?m and less than 3.0 ?m is not less than 20% and less than 40% by number based on total number thereof; the wax has a mode value not less than 1.5 ?m and less than 2.0 ?m in a frequency distribution of 0.1 ?m width; and the following relationship is satisfied: 45<XZ/Y<62 wherein X represents a softening point (° C.) of the toner; Y represents a volume-average particle diameter (?m) of the toner; and Z represents a total parts by weight of the wax included in 100 parts by weight of the toner.Type: GrantFiled: December 21, 2007Date of Patent: December 11, 2012Assignee: Ricoh Company, Ltd.Inventors: Yoshihiro Mikuriya, Hideaki Yasunaga, Hiroaki Katoh, Kazuoki Fuwa, Masayuki Hagi, Masahide Inoue
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Publication number: 20120295195Abstract: The carrier core particles 11 for electrophotographic developer contain lithium as a core composition. When the carrier core particles 11 are immersed in pure water at a weight ratio of 1 part core particles 11 to 10 parts pure water and shaken, the amount of lithium that leaches out to the pure water is 0.10 ppm or lower.Type: ApplicationFiled: January 25, 2011Publication date: November 22, 2012Applicants: Dowa IP Creation Co., Ltd., Dowa Electronics Materials Co., Ltd.Inventor: Takeshi Kawauchi
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Patent number: 8309681Abstract: There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a lactone ring-opening polymer (p), and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0?H2/H1?0.9??(1) [in the relational formula (1), H1 represents a measurement value of a heat of fusion (J/g) at the time of the initial temperature elevation measured by DSC; and H2 represents a measurement value of a heat of fusion (J/g) at the time of the second temperature elevation measured by DSC].Type: GrantFiled: July 22, 2009Date of Patent: November 13, 2012Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takao Mukai, Koji Ota
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Patent number: 8293447Abstract: An object of the present invention is to provide a toner which allows fixation at low temperatures, which is excellent in anti-offset ability, and which provides a high quality image at high and low humidities in a stable manner without causing any image defect over time. Provided is a toner, containing at least a binder resin and a colorant in which: the binder resin in the toner contains 60% by mass or more of a styrene/acryl resin and a THF-insoluble fraction A which is an extraction residue obtained by carrying out Soxhlet extraction with tetrahydrofuran (THF) for 16 hours; the THF-insoluble fraction A contains a TOL-insoluble fraction B which is an extraction residue obtained by carrying out Soxhlet extraction with toluene (TOL) for 16 hours; and a mass ratio (B/A) between the THF-insoluble fraction A and the TOL-insoluble fraction B is in the range of 0.1?B/A?0.5.Type: GrantFiled: June 22, 2011Date of Patent: October 23, 2012Assignee: Canon Kabushiki KaishaInventors: Katsuhisa Yamazaki, Masami Fujimoto, Masaaki Taya
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Publication number: 20120264044Abstract: Disclosed is a negative-chargeable erasable electrophotographic toner including a binder resin, a near infrared absorption dye, a decolorizing agent, a charge controlling agent, and fluororesin particles. The toner is obtained by adding 5 to 20 parts by mass of the fluororesin particles to 100 parts by mass of the binder resin.Type: ApplicationFiled: April 12, 2012Publication date: October 18, 2012Applicants: CASIO COMPUTER CO., LTD., CASIO ELECTRONICS MANUFACTURING CO., LTD.Inventors: Hideki IKEDA, Hideyoshi Niinuma, Toshiaki Kanamura
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Patent number: 8288069Abstract: Provided is a toner including: toner particles each containing at least a binder resin and a wax; and an external additive, in which surfaces of the toner particles have an average surface roughness (Ra) measured with a scanning probe microscope of 1.0 nm or more and 30.0 nm or less; and the toner has a surface tension index I for a 45-vol % aqueous solution of methanol measured by a capillary suction time method and calculated from the following equation (1) of 5.0×10?3 N/m or more and 1.0×10?1 N/m or less: I=P?/(A×B×106)??Eq. (1) where I represents the surface tension index (N/m) of the toner, P? represents a capillary pressure (N/m2) of the toner for the 45-vol % aqueous solution of methanol, A represents a specific surface area (m2/g) of the toner, and B represents a true density (g/cm3) of the toner.Type: GrantFiled: November 5, 2010Date of Patent: October 16, 2012Assignee: Canon Kabushiki KaishaInventors: Hiroyuki Fujikawa, Kunihiko Nakamura, Nozomu Komatsu, Yoshiaki Shiotari, Takeshi Ohtsu, Takayuki Itakura