Milling With Subsequent Classification Patents (Class 430/137.2)
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Patent number: 10042279Abstract: Provided in one example herein is a liquid electrophotographic ink composition, comprising: a carrier fluid comprising a polymer; ink particles comprising pigment particles and a polymeric resin, the pigment particles comprising titanium dioxide and being distributed in the polymeric resin; and a charge director, wherein the ink particles have an average diameter of between about 10 ?m and 50 ?m; and the pigment particles are between about 10 wt % and about 50 wt % of the ink particles. Methods of making and using the ink composition are also provided.Type: GrantFiled: September 23, 2014Date of Patent: August 7, 2018Assignee: Hewlett-Packard Development Company L.P.Inventors: Doris Pik-Yiu Chun, Dekel Green
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Patent number: 8852841Abstract: A method for producing a toner for electrostatic image development containing at least a resin binder and a charge control agent, including step 1: melt-kneading components containing a resin binder and a charge control agent to provide a melt-kneaded product; and step 2: pulverizing the melt-kneaded product, and classifying a pulverized product, wherein the resin binder contains a polyester A obtained by polycondensing an alcohol component containing 1,2-propanediol and a carboxylic acid component containing a rosin compound and an aliphatic dicarboxylic acid compound having 6 to 10 carbon atoms, wherein 1,2-propanediol is contained in the alcohol component of the polyester A in an amount of 85% by mol or more. The toner for electrostatic image development obtained by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: GrantFiled: November 30, 2012Date of Patent: October 7, 2014Assignee: Kao CorporationInventors: Takeshi Ashizawa, Shogo Watanabe, Takashi Kubo, Norihiro Hirai
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Patent number: 8815488Abstract: A method for producing a toner including the step of melt-kneading a mixture containing a resin binder and a wax with a twin-screw kneader, wherein the resin binder contains three kinds of a resin R1, a resin R2 and a resin R3 having different softening points to each other, wherein the wax contains at least two kinds of a wax W2 and a wax W3 having different melting points to each other, wherein the softening points of R1, R2 and R3 and the melting point W2 meet certain relationships, and wherein the mixture is supplied to the twin-screw kneader in an amount of from 1.3 to 5.0 kg/hr·cm2 per unit cross-sectional area of the screw. The toner obtainable by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: GrantFiled: November 9, 2012Date of Patent: August 26, 2014Assignee: Kao CorporationInventor: Takeshi Ashizawa
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Patent number: 8765343Abstract: An electrostatic latent image developing toner contains a binder resin, a colorant, europium, and bismuth.Type: GrantFiled: February 8, 2012Date of Patent: July 1, 2014Assignee: Fuji Xerox Co., Ltd.Inventors: Yuki Takamiya, Eisuke Iwazaki, Satoshi Yoshida, Satoshi Inoue
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Publication number: 20140106270Abstract: A transparent electrostatic charge image developing toner includes a binder resin and a compound represented by the following Formula (1): wherein in Formula (1), R1 represents a methyl group or a trifluoromethyl group; R2 represents a hydrogen atom; R3 represents a methyl group, a trifluoromethyl group, a t-butyl group, a phenyl group, or a naphthyl group; and M represents a rare earth element.Type: ApplicationFiled: May 2, 2013Publication date: April 17, 2014Applicant: FUJI XEROX CO., LTD.Inventors: Yuki TAKAMIYA, Tsuyoshi MURAKAMI, Eisuke IWAZAKI, Satoshi INOUE
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Publication number: 20140099575Abstract: Use of a resin blend of a petroleum based resin and a bio-derived polyester resins having low glass transition (Tg) values in a toner composition is disclosed. The resulting novel bio-based toner exhibits desirable characteristics such as good blocking performance and excellent fusing latitude.Type: ApplicationFiled: October 5, 2012Publication date: April 10, 2014Inventors: Mark E. Mang, Timothy L. Lincoln, Brian J. Andaya, Deborah M. Hudson
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Publication number: 20140017608Abstract: A toner comprising at least a binder resin, a colorant and a release agent, wherein the binder resin contains: a polyester resin A obtained by polycondensation of an aromatic dicarboxylic acid, a rosin and an alcohol having three or more hydroxyl groups, a content of the rosin being 60% by weight or more; and a polyester resin B obtained by polycondensation of an aromatic dicarboxylic acid, a rosin and a polyhydric alcohol, a content of the rosin being 5 to 60% by weight, wherein 50 to 200 parts by weight of the polyester resin B is contained with respect to 100 parts by weight of the polyester resin A.Type: ApplicationFiled: March 14, 2012Publication date: January 16, 2014Applicant: SHARP KABUSHIKI KAISHAInventor: Satoru Ariyoshi
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Publication number: 20130344433Abstract: A method for producing dry toner particles that have similar particle size and shape characteristics as chemically produced toners. The method includes melt-mixing a toner resin with a colorant and, optionally, a wax, to form a toner; grinding the toner to form toner particles; classifying the toner particles into particles averaging 4 to 10 microns in size; blending the classified toner particles with additives in a high-speed blender; and then processing the mixture with optional additional surface additives in a conical mixer. The method produces toner particles that have high circularity and sharper particle size distribution. The surface processing of the toner particles does not affect the internal constituents of the toner particles.Type: ApplicationFiled: June 26, 2012Publication date: December 26, 2013Applicant: XEROX CORPORATIONInventors: Paul CASALMIR, Bryan L. NORCOTT
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Patent number: 8580473Abstract: A toner includes a binder resin and a colorant. The binder resin contains a polyester resin A obtained by subjecting aromatic dicarboxylic acid, rosin, and trivalent or higher-valent alcohol as starting materials to polycondensation, a content of the rosin in a sum of the starting materials being 60% by weight or more, and a polyester resin B obtained by subjecting aromatic dicarboxylic acid and polyhydric alcohol as starting materials to polycondensation, the polyester resin B having a viscosity of 103 Pa·s or more and 105 Pa·s or less at a softening temperature of the polyester resin A, the polyester resin B being contained in an amount of 50 parts by weight or more and 200 parts by weight or less relative to 100 parts by weight of the polyester resin A.Type: GrantFiled: June 9, 2011Date of Patent: November 12, 2013Assignee: Sharp Kabushiki KaishaInventors: Satoru Ariyoshi, Yasuhiro Shibai, Nobuhiro Maezawa, Katsuru Matsumoto
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Publication number: 20130280648Abstract: A toner composition including at least one phosphorescent pigment that absorbs energy released by natural or artificial light, and is able to be seen in a dark environment through luminescence of a certain color created by the energy released as light, and a method of forming and using the toner are described. The phosphorescent toner has a particle size in the range of about 15-40 microns, which allows the toner to have the ability to absorb and then release the needed amount of light energy to be noticeable in a dark environment.Type: ApplicationFiled: April 18, 2012Publication date: October 24, 2013Applicant: TROY GROUP, INC.Inventors: Carrie A. Gilson, Kevin L. Heilman, Michael R. Rlley
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Publication number: 20130224643Abstract: A transparent electrostatic charge image developing toner contains a binder resin, europium, and bismuth.Type: ApplicationFiled: July 5, 2012Publication date: August 29, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Yuki TAKAMIYA, Tsuyoshi MURAKAMI, Eisuke IWAZAKI, Satoshi YOSHIDA, Satoshi INOUE
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Publication number: 20130171558Abstract: It is an object of the present invention to provide a ferrite carrier core material and a ferrite carrier for an electrophotographic developer, which have an excellent charging property, hardly cause carrier scattering due to cracking and chipping of the core material, and have a prolonged life, and methods for manufacturing these, and an electrophotographic developer using the ferrite carrier. For this object, the ferrite carrier core material and a ferrite carrier for an electrophotographic developer, wherein (1) the ferrite composition contains 0.5 to 2.5% by weight of Sr, and the presence amount of Sr—Fe oxides satisfies a specific conditional expression, (2) the distribution in the number of the shape factor SF-2 is in a specific range, (3) the BET specific surface area is 0.15 to 0.30 m2/g, (4) the average particle diameter D50 is 20 to 35 ?m, and (5) the magnetization is 50 to 65 Am2/kg.Type: ApplicationFiled: August 29, 2011Publication date: July 4, 2013Applicant: POWDERTECH CO., LTD.Inventors: Tomoyuki Suwa, Toru Iwata, Koji Aga
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Publication number: 20130157192Abstract: A method for producing a toner for electrostatic image development containing at least a resin binder and a charge control agent, including step 1: melt-kneading components containing a resin binder and a charge control agent to provide a melt-kneaded product; and step 2: pulverizing the melt-kneaded product, and classifying a pulverized product, wherein the resin binder contains a polyester A obtained by polycondensing an alcohol component containing 1,2-propanediol and a carboxylic acid component containing a rosin compound and an aliphatic dicarboxylic acid compound having 6 to 10 carbon atoms, wherein 1,2-propanediol is contained in the alcohol component of the polyester A in an amount of 85% by mol or more. The toner for electrostatic image development obtained by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: ApplicationFiled: November 30, 2012Publication date: June 20, 2013Applicant: Kao CorporationInventor: Kao Corporation
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Publication number: 20130130173Abstract: A method for producing a toner including the step of melt-kneading a mixture containing a resin binder and a wax with a twin-screw kneader, wherein the resin binder contains three kinds of a resin R1, a resin R2 and a resin R3 having different softening points to each other, wherein the wax contains at least two kinds of a wax W2 and a wax W3 having different melting points to each other, wherein the softening points of R1, R2 and R3 and the melting point W2 meet certain relationships, and wherein the mixture is supplied to the twin-screw kneader in an amount of from 1.3 to 5.0 kg/hr·cm2 per unit cross-sectional area of the screw. The toner obtainable by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.Type: ApplicationFiled: November 9, 2012Publication date: May 23, 2013Applicant: Kao CorporationInventor: Kao Corporation
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Publication number: 20130122415Abstract: There is disclosed a toner for electrostatic latent image development which includes at least a colorant, a charge control agent, and a release agent in a binder resin and is produced using a pulverizing process. An average circularity of the toner is 0.960 or more and 0.980 or less with respect to toner particles having a primary particle diameter of 3 ?m or more and 10 ?m or less. A numerical proportion of toner particles, having a concave portion of which outer diameter is 200 nm or more and being observed by a predetermined condition, is 10% by number or less.Type: ApplicationFiled: November 5, 2012Publication date: May 16, 2013Applicant: KYOCERA DOCUMENT SOLUTIONS INC.Inventor: KYOCERA Document Solutions Inc.
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Patent number: 8404425Abstract: An apparatus for manufacturing toner is provided which includes a pulverizer for pulverizing a material into particles, a classifier for classifying the particles by size, a discharging path for discharging the particles from the pulverizer to the classifier, a returning path for returning relatively coarse particles among the classified particles from the classifier to the pulverizer, and a handling unit for handling particles. A method for manufacturing toner is also provided which includes pulverizing a material into particles in a pulverizer, discharging the particles from the pulverizer to a classifier via a discharging path, classifying the particles by size in the classifier, and returning relatively coarse particles among the classified particles from the classifier to the pulverizer. The handling unit is provided on at least one of the discharging path and the returning path, and includes a mechanism for preventing accumulation of the particles using airflow.Type: GrantFiled: January 7, 2010Date of Patent: March 26, 2013Assignee: Ricoh Company, LimitedInventors: Yoichi Maekawa, Tomoyuki Satoh, Hideyuki Santo, Kazunobu Muramatsu
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Publication number: 20130071782Abstract: An electrostatic latent image developing toner contains a binder resin, a colorant, europium, and bismuth.Type: ApplicationFiled: February 8, 2012Publication date: March 21, 2013Applicant: FUJI XEROX CO., LTD.Inventors: Yuki TAKAMIYA, Eisuke IWAZAKI, Satoshi YOSHIDA, Satoshi INOUE
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Patent number: 8343705Abstract: A method of manufacturing a toner including manufacturing a coarse toner containing a binder resin and a coloring agent, and screening the coarse toner with a screen device including a top screen having an opening of from 26 to 43 ?m and a bottom screen situated below the top screen having an opening of from 54 to 150 ?m to screen the coarse toner with the top screen by ultrasonic vibration and mechanical vibration at 50° C. or lower, and with the bottom screen by mechanical vibration at 35° C. or lower.Type: GrantFiled: November 16, 2009Date of Patent: January 1, 2013Assignee: Ricoh Company, Ltd.Inventors: Yasuaki Tomioka, Yousuke Suzuki
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Publication number: 20120295196Abstract: There is provided in one embodiment a bio-toner having a bio-resin, a second resin, and one or more colorants. The second resin has at least one of a styrene acrylate resin or a polyester resin each having at least one molecular weight peak greater than 90,000 and at least one molecular weight peak less than 15,000. The bio-resin is a polyester polymer having one or more reacted di-acid monomer units and one or more reacted diol monomer units. At least one of the reacted di-acid monomer units or at least one of the reacted diol monomer units is a bio-monomer obtained from a plant or an animal source.Type: ApplicationFiled: May 16, 2012Publication date: November 22, 2012Applicant: Mitsubishi Kagaku Imaging CorporationInventors: David Urban, Takeshi Owada
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Patent number: 8293447Abstract: An object of the present invention is to provide a toner which allows fixation at low temperatures, which is excellent in anti-offset ability, and which provides a high quality image at high and low humidities in a stable manner without causing any image defect over time. Provided is a toner, containing at least a binder resin and a colorant in which: the binder resin in the toner contains 60% by mass or more of a styrene/acryl resin and a THF-insoluble fraction A which is an extraction residue obtained by carrying out Soxhlet extraction with tetrahydrofuran (THF) for 16 hours; the THF-insoluble fraction A contains a TOL-insoluble fraction B which is an extraction residue obtained by carrying out Soxhlet extraction with toluene (TOL) for 16 hours; and a mass ratio (B/A) between the THF-insoluble fraction A and the TOL-insoluble fraction B is in the range of 0.1?B/A?0.5.Type: GrantFiled: June 22, 2011Date of Patent: October 23, 2012Assignee: Canon Kabushiki KaishaInventors: Katsuhisa Yamazaki, Masami Fujimoto, Masaaki Taya
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Patent number: 8257900Abstract: A method for preparing a toner including primarily pulverizing a toner composition powder including at least a binder resin and a colorant using a mechanical pulverizer to prepare a first particulate material with a weight average particle diameter of 7 to 30 ?m; secondarily pulverizing the first particulate material using a jet air pulverizer having a pulverization plate to prepare a second particulate material; and classifying the second particulate material in two steps to prepare particles of the toner with a weight average particle diameter of 2 to 6 ?m and an average circularity of 0.93 to 0.96. A toner including toner particles including at least a binder resin and a colorant and prepared by the method. An image forming apparatus including an image bearing member configured to bear an electrostatic image thereon; and a developing device configured to develop the electrostatic image with a developer including the toner.Type: GrantFiled: February 23, 2009Date of Patent: September 4, 2012Assignee: Ricoh Company, LimitedInventor: Kouji Noge
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Patent number: 8252502Abstract: A method for producing a toner is provided that comprises a kneading step, a milling step, a pre-externally adding step, in which at least a part of an external additive is externally added to the powder to prepare a mixture, a classifying step, a recycle step, and a post-externally adding step, wherein the internally added amount X of the external additive in the toner is regulated within a range of 0.2 part by mass to 3.0 parts by mass based on 100 parts by mass of the toner base.Type: GrantFiled: September 12, 2007Date of Patent: August 28, 2012Assignee: Ricoh Company, Ltd.Inventor: Masami Tomita
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Patent number: 8232033Abstract: A toner, a developer, a two-component developer, a developing device and an image forming apparatus are provided. In the image forming apparatus, images are formed with a developer that fills a developing tank of the developing device. The developer includes the toner containing at least a binder resin, a colorant, and a release agent, the release agent having an acid value of less than 4 mgKOH/g and in which an amount of the release agent exposed on a surface of toner is 0.5% by weight or more and 2.5% by weight or less of a total amount of the toner.Type: GrantFiled: February 20, 2009Date of Patent: July 31, 2012Assignee: Sharp Kabushiki KaishaInventors: Yoritaka Tsubaki, Hiroshi Onda, Yasuo Imura
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Patent number: 8206878Abstract: A liquid developer includes an insulating liquid and toner particles obtained by surface-modifying toner mother particles made of a material containing a rosin resin with a polyalkyleneimine.Type: GrantFiled: July 13, 2009Date of Patent: June 26, 2012Assignee: Seiko Epson CorporationInventors: Yoshihiro Ueno, Masahiro Oki
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Patent number: 8178276Abstract: A method of manufacturing a toner including granulating mother toner particles in an aqueous medium to obtain a slurry containing the mother toner particles and adjusting a size distribution of the mother toner particles by screening coarse mother toner particles from the slurry with a screen to obtain the toner containing mother toner particulates.Type: GrantFiled: March 6, 2009Date of Patent: May 15, 2012Assignee: Ricoh Company LimitedInventors: Osamu Uchinokura, Akinori Saitoh, Junichi Awamura, Masahide Yamada, Hiroshi Yamada
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Patent number: 8158323Abstract: A method of manufacturing toner including the steps of preparing a preliminary mixture by mixing a colorant and a release agent; preparing a raw material mixture by mixing the preliminary mixture with a binder resin and other raw materials; melt-kneading the raw material mixture using an open system roll type kneader; pulverizing the melt-kneaded raw material mixture into fine particles; and classifying the fine particles to prepare a toner.Type: GrantFiled: December 11, 2008Date of Patent: April 17, 2012Assignee: Ricoh Company LimitedInventors: Mitsuo Aoki, Satoshi Ogawa
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Patent number: 8129085Abstract: A toner includes toner particles containing at least binder resin and colorant. The toner particles contain a large-sized toner particle group of particles and a small-sized toner particle group of particles having a volume average particle size smaller than that of the large-sized toner particle group. In the toner, a volume average particle size D50v is 4 ?m to 8 ?m at 50% in accumulated volume counted from a large particle-side in accumulated volume distribution of entire toner particles; a content of toner particles contained in a toner particle group having a volume average particle size of 7 ?m or more is 24% to 47% by volume based on the entire toner particles; and a content of toner particles contained in a toner particle group having a number average particle size of 5 ?m or less is 10% to 50% by number or less based on the entire toner particles.Type: GrantFiled: July 23, 2008Date of Patent: March 6, 2012Assignee: Sharp Kabushiki KaishaInventors: Yoshinori Yamamoto, Hiroshi Onda, Yoshiaki Akazawa
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Publication number: 20120052431Abstract: To provide a toner, containing: a crystalline polyester resin; and a non-crystalline polyester resin, wherein the crystalline polyester resin has a melting point of 60° C. to 80° C., and wherein the toner satisfies the relationship represented by the following formula: (W1?W1?)/W1<0.50, where W1 is a temperature width at a 1/3 height of a height of an endothermic peak of the crystalline polyester resin at the time of an initial temperature elevation on a DSC curve of the toner as measured by differential scanning calorimetry, and W1? is a temperature width at a 1/3 height of a height of an endothermic peak of the crystalline polyester resin after the toner has been heated at 50° C. for 24 hours.Type: ApplicationFiled: August 12, 2011Publication date: March 1, 2012Inventors: Mamoru HOZUMI, Tsuyoshi Sugimoto, Naohiro Watanabe, Tomoyuki Satoh, Shinya Hanatani, Osamu Uchinokura
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Patent number: 8114565Abstract: Provided is a toner production method that reuses a fine particle toner having a particle diameter failing to meet a predetermined standard diameter which is generated in pulverizing and classifying processes carried out for a toner material including at least a binder resin, release agent and pigment. The method includes granulating the fine particle toner by means of a granulating apparatus so as to increase a loose apparent density of the fine particle toner from the range of 0.05 g/cc to 0.25 g/cc to the range of 0.30 g/cc to 0.60 g/cc, in which wherein the granulating apparatus contains two left and right press rolls having the same diameters, the two press rolls having a rotational speed ratio of 0.40 to 0.95.Type: GrantFiled: February 20, 2009Date of Patent: February 14, 2012Assignee: Ricoh Company, Ltd.Inventor: Atsushi Inoue
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Patent number: 8105741Abstract: A method for manufacturing toner includes steps of supplying, periodically dispensing, and solidifying. The supply step supplies a liquid to be atomized, which includes at least a resin and a colorant. The periodic dispensation step periodically dispenses droplets of the liquid through an atomizing unit. The solidification step solidifies the dispensed droplets into toner particles. The atomizing unit includes a thin film, a vibration actuator, and multiple holes. The thin film has a relatively stiff portion and a relatively elastic portion, and is configured to contact the liquid. The vibration actuator is connected to and supports a periphery of the thin film, and is configured to induce vibration of the thin film. The multiple holes are formed in the relatively stiff portion, and are configured to discharge droplets therethrough when the thin film vibrates.Type: GrantFiled: May 13, 2008Date of Patent: January 31, 2012Assignee: Ricoh Company, Ltd.Inventors: Yoshihiro Norikane, Shinji Ohtani
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Patent number: 8105742Abstract: A method for manufacturing a toner, including periodically forming liquid droplets of a toner constituent liquid comprising a resin and a colorant by vibrating a thin film having a plurality of holes provided on a retention part thereof to discharge the liquid droplets of the toner constituent liquid from the plurality of holes and forming toner particles by solidifying the liquid droplets discharged from the plurality of holes. In periodically forming the liquid droplets of the toner constituent liquid, a flow of gas in a direction of discharge of the liquid droplets is formed by a gas flow generation unit provided downstream from the thin film relative to the direction of discharge of the liquid droplets, including a tapered part forming an aperture corresponding to a hole formation area of the thin film.Type: GrantFiled: May 15, 2008Date of Patent: January 31, 2012Assignee: Ricoh Company, Ltd.Inventors: Yoshihiro Norikane, Shinji Ohtani, Yohichiroh Watanabe, Kazumi Suzuki
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Patent number: 8101331Abstract: A process for making particles is provided. In embodiments, a suitable process includes a mixing tank for mixing a plurality of particles dispersed within a liquid media and a vane unit for applying a swirling effect to the plurality of droplets received from the mixing tank through a spray nozzle. The vane unit is in operable communication with a spray nozzle for launching a plurality of droplets, the plurality of droplets including different combinations of the plurality of particles. The process further includes a plurality of outlet ports, where each of a first set of outlet ports includes a filter and of the other outlet port is filterless.Type: GrantFiled: December 18, 2009Date of Patent: January 24, 2012Assignee: Xerox CorporationInventors: Fa-Gung Fan, Steven M. Malachowski, Yuhua Tong, Chieh-Min Cheng, Pinyen Lin
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Publication number: 20110305982Abstract: A toner includes a binder resin containing a polyester resin A obtained by subjecting aromatic dicarboxylic acid, rosin, and trivalent or higher-valent alcohol as starting materials to polycondensation, a content of the rosin in a sum of the starting materials being 60% by weight or more, and a polyester resin B obtained by subjecting aromatic dicarboxylic acid and polyalcohol as starting materials to polycondensation; a dispersing aid for dispersing the polyester resin A into the polyester resin B; and a colorant.Type: ApplicationFiled: June 9, 2011Publication date: December 15, 2011Inventors: Katsuru MATSUMOTO, Yasuhiro SHIBAI, Satoru ARIYOSHI, Nobuhiro MAEZAWA
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Publication number: 20110305988Abstract: A toner includes a binder resin and a colorant. The binder resin contains a polyester resin A obtained by subjecting aromatic dicarboxylic acid, rosin, and trivalent or higher-valent alcohol as starting materials to polycondensation, a content of the rosin in a sum of the starting materials being 60% by weight or more, and a polyester resin B obtained by subjecting aromatic dicarboxylic acid and polyhydric alcohol as starting materials to polycondensation, the polyester resin B having a viscosity of 103 Pa·s or more and 105 Pa·s or less at a softening temperature of the polyester resin A, the polyester resin B being contained in an amount of 50 parts by weight or more and 200 parts by weight or less relative to 100 parts by weight of the polyester resin A.Type: ApplicationFiled: June 9, 2011Publication date: December 15, 2011Inventors: Satoru ARIYOSHI, Yasuhiro Shibai, Nobuhiro Maezawa, Katsuru Matsumoto
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Publication number: 20110305985Abstract: A toner includes a binder resin, a colorant, and, a benzilic acid compound. The binder resin contains a polyester resin A obtained by subjecting aromatic dicarboxylic acid, rosin and trivalent or higher-valent alcohol as starting materials to polycondensation, a content of the rosin in a sum of the starting materials being 60% by weight or more, and a polyester resin B obtained by subjecting aromatic dicarboxylic acid and polyhydric alcohol as starting materials to polycondensation.Type: ApplicationFiled: June 9, 2011Publication date: December 15, 2011Inventors: Satoru ARIYOSHI, Yasuhiro Shibai, Katsuru Matsumoto, Nobuhiro Maezawa
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Patent number: 8039191Abstract: A toner having a BET specific surface area of from 1.5 to 3.5 m2/g, obtainable by a process including the steps of; step (1): pulverizing a toner composition containing at least a resin binder and a colorant in the presence of fine inorganic particles having an average primary particle size of from 6 to 20 nm to obtain mother toner particles having a volume-median particle size of from 3 to 8 ?m; and step (2): externally adding silica having an average primary particle size of from 25 to 60 nm to the mother toner particles obtained in the above step (1). The toner of the present invention is suitably used for, for example, developing a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.Type: GrantFiled: June 6, 2007Date of Patent: October 18, 2011Assignee: Kao CorporationInventor: Akihiro Eida
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Publication number: 20110229814Abstract: A toner containing a mother toner particle containing a binder resin, a releasing agent, and a coloring agent and an external additive comprising an inorganic particulate, which is mixed with the mother toner particle in a mixing process by a mixer, wherein the external additive is isolated from the mother toner particle by ultrasonic vibration and collected, in an aqueous solution comprising a polyoxyethylene lauryl ether compound serving as a surface active agent, in an amount of from 0.1 ppm to 10 ppm/(toner 4 g/100 ml) as measured by atomic absorption spectrometry.Type: ApplicationFiled: March 11, 2011Publication date: September 22, 2011Inventors: Masayuki KAKIMOTO, Akio MATSUI, Yoshikatsu MATSUDA, Masanori RIMOTO
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Publication number: 20110182625Abstract: According to one embodiment, a developing agent containing a toner particle and an aggregate of a toner dust powder having a smaller volume average particle size than a volume average particle size of the toner particle and alumina is provided.Type: ApplicationFiled: January 13, 2011Publication date: July 28, 2011Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventor: Nobuo Tohata
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Patent number: 7833688Abstract: Use of a wax in a toner, such as carnauba wax, to give an increase in charge control agent in a toner, such as a magenta toner, to give an increased glass transition temperature is disclosed. The toner may contain a resin comprising amorphous and crystalline polyesters to provide good low melt characteristics.Type: GrantFiled: March 30, 2007Date of Patent: November 16, 2010Assignee: Xerox CorporationInventors: Mark E. Mang, Eugene F. Young
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Patent number: 7820353Abstract: A method for producing a toner, including at least the following steps: step (A): pulverizing a negatively chargeable charge control resin that does not soften at a temperature of 180° C. or lower to an average particle size of from 0.05 to 2 ?m; step (B): melt-kneading at least a pulverized product of the negatively chargeable charge control resin obtained in the step (A), a resin binder, and a colorant; and step (C): pulverizing a melt-kneaded product obtained in the step (B) and classifying the pulverized product. The toner obtained according to the present invention is suitably used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: GrantFiled: November 18, 2008Date of Patent: October 26, 2010Assignee: Kao CorporationInventors: Akihiro Eida, Takeshi Ashizawa
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Patent number: 7820354Abstract: The present invention relates to a process for producing a toner including the steps of melt-kneading raw materials containing two or more kinds of polyesters, heat-treating a melt-kneaded product, pulverizing a heat-treated product, and classifying a pulverized product, wherein the two or more kinds of polyesters contain at least one kind of an amorphous polyester, and the heat-treating step is carried out at a temperature t (° C.) and time h (hour) satisfying the following formulas (a) and (b), Tg1?t?Tm?10??(a) h?100/(t?30), with proviso that t>30??(b) wherein Tg1 is a glass transition temperature (° C.) of the melt-kneaded product before the heat-treating step; and Tm is the lowest softening point (° C.) of softening points of the two or more kinds of polyesters, and the toner produced by the process.Type: GrantFiled: April 20, 2005Date of Patent: October 26, 2010Assignee: Kao CorporationInventor: Eiji Shirai
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Publication number: 20100266822Abstract: A process for preparing a black toner for electrophotography, including the steps of (I) melt-kneading a raw material mixture containing a resin binder and a black colorant with an open-roller type kneader; (II) cooling the melt-kneaded mixture obtained in the step (I) and pulverizing the cooled mixture; and (III) classifying the pulverized product obtained in the step (II), wherein the resulting toner has a volume-median particle size (D50v) of from 3 to 6.5 ?m, contains 5.0% by volume or less of particles having particle sizes of (1.4×D50v) ?m or more, and contains 5.0% by number or less of particles having particle sizes of (0.6×number-median particle size (D50p)) ?m or less; and a black toner for electrophotography obtained by the process as defined above, wherein the toner is a toner for nonmagnetic monocomponent development. The black toner is used for development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method, or the like.Type: ApplicationFiled: June 30, 2010Publication date: October 21, 2010Applicant: KAO CORPORATIONInventors: Akihiro Eida, Takashi Okuno
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Publication number: 20100196818Abstract: Employment of a carrier core material for an electrophotographic developer containing 0.8 to 5% by weight of Mg, 0.1 to 1.5% by weight of Ti, 60 to 70% by weight of Fe and 0.2 to 2.5% by weight of Sr and having an amount of Sr dissolved with a pH4 standard solution of 80 to 1000 ppm, a carrier using the core material and a process for producing them, and an electrophotographic developer using the carrier.Type: ApplicationFiled: January 12, 2010Publication date: August 5, 2010Applicant: POWDERTECH CO., LTD.Inventors: Takashi KOJIMA, Toru IWATA, Koji AGA
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Patent number: 7763410Abstract: A vibrating sieve for classifying a particulate material, including an oscillator comprising a transducer; and at least two meshes layered together and located in contacting relation to a transducer, wherein a lowermost mesh receiving a vibration from the transducer transmits the vibration to an uppermost mesh to classify the particulate material fed thereon.Type: GrantFiled: November 1, 2004Date of Patent: July 27, 2010Assignee: Ricoh Company, Ltd.Inventors: Kimitoshi Yamaguchi, Masashi Nagayama, Naoki Imahashi
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Publication number: 20100173243Abstract: An apparatus for manufacturing toner is provided which includes a pulverizer for pulverizing a material into particles, a classifier for classifying the particles by size, a discharging path for discharging the particles from the pulverizer to the classifier, a returning path for returning relatively coarse particles among the classified particles from the classifier to the pulverizer, and a handling unit for handling particles. A method for manufacturing toner is also provided which includes pulverizing a material into particles in a pulverizer, discharging the particles from the pulverizer to a classifier via a discharging path, classifying the particles by size in the classifier, and returning relatively coarse particles among the classified particles from the classifier to the pulverizer. The handling unit is provided on at least one of the discharging path and the returning path, and includes a mechanism for preventing accumulation of the particles using airflow.Type: ApplicationFiled: January 7, 2010Publication date: July 8, 2010Inventors: Yoichi MAEKAWA, Tomoyuki Satoh, Hideyuki Santo, Kazunobu Muramatsu
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Publication number: 20100124441Abstract: A toner containing a lignin resin, a carbon-neutral biomass polymer having a low environmental load and taking global environmental protection into account, as a constitutional component of a binder resin, and having a wide fixing non-offset range and an excellent fixing property, is provided. The toner contains at least a binder resin, a colorant, and a release agent. Furthermore, in the toner, the binder resin includes a resin A that is a lignin resin and a resin B that is another resin component, and the resin B has a peak top molecular weight of 103 to 104 and an acid number of 20 or less.Type: ApplicationFiled: November 18, 2009Publication date: May 20, 2010Inventors: Satoru ARIYOSHI, Katsuru Matsumoto
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Patent number: 7687215Abstract: The presently disclosed embodiments relate in general to toners for use in electrophotographic apparatuses, such as printers and copiers. More particularly, a toner formulation of at least one binder, at least one colorant, and an embrittling agent, and methods for making the same, is provided wherein the embrittling agent increases grinding rate of the toner formulation.Type: GrantFiled: October 20, 2005Date of Patent: March 30, 2010Assignee: Xerox CorporationInventors: Mark E. Mang, Hui Chang, Gerald P. Cox, Joseph L. Leonardo
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Publication number: 20090280424Abstract: Provided as toners for developing electrostatically charged images capable of preventing a sticking and curling phenomenon even with an increase in number of printed sheets and processes for producing the same, with the use of a cyclic polyolefinic resin, are a toner for developing electrostatically charged images contains a cyclic polyolefinic resin and a polar resin wherein 10 to 50 parts by weight of the polar resin is present in relation to 100 parts by weight of the cyclic polyolefinic resin, and a process for producing a toner for developing electrostatically charged images comprises a step of melt-kneading at least a cyclic polyolefinic resin and a coloring agent to obtain a kneaded product, a step of grinding the kneaded product to obtain colored particles, and a step of melt-kneading, grinding and classifying the colored particles and a polar resin to obtain the toner.Type: ApplicationFiled: May 5, 2009Publication date: November 12, 2009Inventors: Hirotoshi Ikeya, Hiroshi Kumashiro, Nobuyuki Aoki
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Patent number: 7604915Abstract: Use of a charge control agent in a toner, such as a magenta toner, to give an increased triboelectric charge is disclosed. The magenta toner may contain a magenta resin, such as xanthene.Type: GrantFiled: August 23, 2006Date of Patent: October 20, 2009Assignee: Xerox CorporationInventors: Joo T. Chung, Scott M. Silence, Julia Kohlmeier, John Ianni
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Publication number: 20090233213Abstract: A method for preparing a toner including primarily pulverizing a toner composition powder including at least a binder resin and a colorant using a mechanical pulverizer to prepare a first particulate material with a weight average particle diameter of 7 to 30 ?m; secondarily pulverizing the first particulate material using a jet air pulverizer having a pulverization plate to prepare a second particulate material; and classifying the second particulate material in two steps to prepare particles of the toner with a weight average particle diameter of 2 to 6 ?m and an average circularity of 0.93 to 0.96. A toner including toner particles including at least a binder resin and a colorant and prepared by the method. An image forming apparatus including an image bearing member configured to bear an electrostatic image thereon; and a developing device configured to develop the electrostatic image with a developer including the toner.Type: ApplicationFiled: February 23, 2009Publication date: September 17, 2009Inventor: Kouji NOGE