To Make Diazo-type Intermediate, Black-line Image, Or Continuous-tone Image Patents (Class 430/148)
-
Patent number: 10269160Abstract: The present disclosure discloses a method and an apparatus for processing an image. The method includes: acquiring a first original image to be processed and creating a preset number copies of the first original image which the preset number copies and the first original image have a same image but different transparencies; offsetting content of each copy of the preset number copies of the first original image to obtain the preset number copies of first processed images; and overlaying the first original image and the preset number copies of the first processed images, and getting an overlaid first original image as a result of the first original image.Type: GrantFiled: September 26, 2017Date of Patent: April 23, 2019Assignee: TENCENT TECHNOLOGY (SHENZHEN) COMPANY LIMITEDInventors: Liang Ma, Chunhua Luo, Zhiqiang He
-
Patent number: 7153622Abstract: A construct that comprises a base material and a polyhydroxyalkanoate, wherein at least a part of the base material is coated with the polyhydroxyalkanoate, and the polyhydroxyalkanoate comprises a 3-hydroxyalkanoic acid unit other than 3-hydroxypropionic acid unit, 3-hydroxy-n-butyric acid unit, and 3-hydroxy-n-valeric acid unit. In addition, an electrostatic charge image developing toner allows to design the toner characteristics such as chargeability, flowability, stability in time and environmental stability uniform among the toners of different colors. The toner has a small particle size enough for enabling uniform dispersion and being excellent in color saturation and transparency. The toner also shows higher contribution to the environmental security. The toner includes a coloring agent of which at least a part of the surface is covered with polyhydroxyalkanoate (PHA).Type: GrantFiled: April 20, 2004Date of Patent: December 26, 2006Assignee: Canon Kabushiki KaishaInventors: Tsutomu Honma, Tetsuya Yano, Tsuyoshi Nomoto, Shinya Kozaki
-
Patent number: 5410335Abstract: A method for recording an image on a thermal recording material in which a plurality of color-development layers are laminated, the plurality of color-development layers being adapted to develop different colors, respectively, upon supply of thermal energy thereto and to form a substantially black color when all of the plurality of color-development layers undergo color development with a substantially identical density. With respect to a portion where a color other than black is to be developed, recording is effected such that a color-development density of each of the plurality of color-development layers becomes lower than a maximum color-development density of each of the plurality of color-development layers.Type: GrantFiled: July 1, 1992Date of Patent: April 25, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Mitsuru Sawano, Mitsuyuki Tsurumi, Yutaka Fujita, Yuichi Itabashi
-
Patent number: 5338642Abstract: A novel diazo type recording material is provided comprising a recording layer containing at least one light-sensitive diazo compound incorporated in microcapsules and a coupling component which undergoes reaction with said diazo compound in a basic atmosphere to develop a color on a support, wherein said coupling component is a mixture of at least one compound represented by the following general formula [I] and at least one compound represented by the following general formula [II]: ##STR1## wherein A represents an alkylene group having from 1 to 22 carbon atoms containing an ether or thioether bond; B represents hydrogen atom, cyclohexyl group, morpholino group or piperidino group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, alkoxy group having from 1 to 5 carbon atoms or halogen atom.Type: GrantFiled: December 28, 1992Date of Patent: August 16, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiharu Tanaka, Sadao Ishige, Takekatsu Sugiyama, Hirokazu Shimada
-
Patent number: 5247313Abstract: A direct color thermal printing method records a full-color image containing black characters on a thermosensitive color recording medium having three laminated thermosensitive recording layers. Three color components of each pixel are sequentially read out from three color frame memories. If all of the three color components of a pixel correspond to the maximum densities, that pixel is determined to be printed in black, and is stored as black pixel data in a black line buffer memory. When recording the black pixels, a thermal head is driven to apply a predetermined maximum amount of head energy to the thermosensitive color recording medium, for simultaneously coloring the three thermosensitive recording layers in accordance with the black pixel data.Type: GrantFiled: March 13, 1992Date of Patent: September 21, 1993Assignee: Fuji Photo Film Company, LimitedInventors: Shigenori Oosaka, Hitoshi Saito
-
Patent number: 5240807Abstract: A water soluble built-on mask layer is provided on a photoresist composition disposed on a substrate. The photoresist comprises an o-quinone diazide and a novolak or paravinyl phenol resin. The built-on mask layer comprises a water soluble, photobleachable diazonium salt, a coupler for the diazonium salt and an acidic, polymeric, film forming resin such as polystyrene sulfonic acid.Type: GrantFiled: August 2, 1989Date of Patent: August 31, 1993Assignee: Hoechst Celanese CorporationInventors: Sangya Jain, Salvatore Emmi, Thomas S. Phillips
-
Patent number: 4980262Abstract: A photographic contact printing process is disclosed having application in the mass production of replicate video discs from a master disc, and other applications wherein it is desired to replicate micro-detail over a relatively large area. A problem with conventional contact printing from a mask to a photographic medium is one of maintaining intimate contact over a relatively large area since dust, dirt, etc., are almost impossible to completely eliminate in any practical manner. In accordance with the present invention, a contact printing process is provided wherein intimate contact is not necessary for making high quality contact prints. The present invention recognizes that in contact printing information from a master disc to a replicate disc, the contact printing process is significantly less sensitive to imperfect contact between the master disc and the replicate disc if one employs a replicate disc comprising a photosensitive material having a certain optical properties.Type: GrantFiled: August 29, 1979Date of Patent: December 25, 1990Assignee: Eastman Kodak CompanyInventors: Harold T. Thomas, Dennis G. Howe
-
Patent number: 4960670Abstract: A thermodevelopable photo-recording method suitable for making bar-code labels, ID cards and the like, comprising using a thermodevelopable photo-recording material provided with thermodevelopable photo-recording layer containing at least a diazo compound and a coupler, and an electricity modulation type light shutter constructed by minute matrixes which come to be able or inable to transmit light when electric current is passed therethrough, and optionally an optical system for minizing or enlarging the final image, exposing said photo-recording material to light through a temporary image formed in said light shutter by turning on or off the electricity to pass through each of the minute matrixes, then heating said photo-recording material to get a record of the image therein.Type: GrantFiled: May 12, 1988Date of Patent: October 2, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Koutaro Nakamura, Yoshiro Kawashima
-
Patent number: 4937176Abstract: A method of manufacturing a semiconductor device, in which a layer of photolacquer (5) containing as a photoactive component a diazo oxide is provided on a semiconductor substrate. Of this layer, parts (9) are irradiated by a first patterned irradiation (7) and these parts are then rendered poorly developable by an intermediate treatment. Subsequently, the lacquer layer (5) is subjected to a second non-patterned irradiation (11) and is then developed. According to the invention, in the parts (9) irradiated by the first irradiation a pigment is formed, which absorbs radiation having a wavelength at which diazo oxide is photosensitive. The second irradiation is carried out with radiation of that wavelength. Thus, lacquer tracks having a rectangular profile can be obtained in a simple manner.Type: GrantFiled: September 27, 1988Date of Patent: June 26, 1990Assignee: U.S. Philips CorporationInventors: Franciscus A. Vollenbroek, Wilhelmus P. M. Nijssen, Marcellinus J. H. J. Geomini
-
Patent number: 4888266Abstract: The invention relates to a process for producing supports intended for the optical recording and reading of information. A layer containing a diazo compound is deposited onto a metallized substrate. Recording is obtained by exposing the support to light through a mask, the exposed zones of the layer of diazo compound being decomposed. Dry development in ammonia vapors shows up transparent zones and opaque zones corresponding to the information.Type: GrantFiled: March 13, 1987Date of Patent: December 19, 1989Assignee: Thomson BrandtInventors: Jean-Pierre Lacotte, Claude Puech
-
Patent number: 4863827Abstract: A process for forming a multi-level positive working photosensitive element. One forms a composition containing an alkali soluble resin, an o-quinonediazide compound and an in-situ generated acid catalyzed crosslinker in a solvent mixture. After coating on a substrate, drying and partially cross-linking the first layer, a second positive working light sensitive layer is applied. Each light sensitive layer is activated by u.v. radiation in different parts of the spectrum. The top layer is imagewise exposed and developed to form a mask. The second layer is flood exposed through this mask and developed. Each development is conducted with an aqueous alkaline solution.Type: GrantFiled: October 20, 1986Date of Patent: September 5, 1989Assignee: American Hoechst CorporationInventors: Sangya Jain, Yuh-Loo Chang
-
Patent number: 4842979Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive layer containing microcapsules containing at least one diazonium salt capable of azo-coupling with 2-hydroxy-3-naphthoic acid anilide to develop a blue color, a 2-hydroxy-3-naphthoic acid amide derivative, a benzoylacetic amide derivative represented by the following formula and a basic substance: ##STR1## wherein X represents a hydrogen atom, a halogen atom, a lower alkyl group or an alkoxy, aralkyloxy, phenoxy or acylamino group having up to 18 carbon atoms; Y represents an alkyl or aralkyl group having from 7 to 18 carbon atoms, an alkoxy, aralkyloxy, phenoxy, naphthyloxy, alkylthio, aralkylthio or phenylthio group having from 6 to 18 carbon atoms, a naphthylthio group, a sulfonyloxy group, a sulfamoyl gorup, a ureido group, a thioureido group or an acylamino group; X' and Y' each represents a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group; and Y and Y' may combine to form a substitType: GrantFiled: November 30, 1987Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Ishige, Toshimasa Usami, Hiroshi Kamikawa, Toshiharu Tanaka
-
Patent number: 4743524Abstract: Diazotypes with new yellow coupler with an active methylene group are disclosed; the couplers do not migrate and excel by their relatively reduced coupling speed for greatly improved shelf life of diazotypes. In preferred embodiments the improved new diazotypes contain acetoacetoxyethyl methacrylate or acrylate as yellow coupler.Type: GrantFiled: October 17, 1986Date of Patent: May 10, 1988Assignee: Andrews Paper & Chemical Co., Inc.Inventors: Peter Muller, Henry Mustacchi, Leonard Kreicas
-
Patent number: 4729935Abstract: A process for the production of photographic images utilizing a photographic element comprising a transparent support and a coating on the support comprising a diazonium composition having a light absorbency of about 45% or less, and a colorant composition, said coating having a light transmission of not more than about 0.1%.Type: GrantFiled: October 18, 1985Date of Patent: March 8, 1988Assignee: Hoechst Celanese CorporationInventors: John E. Walls, Major S. Dhillon
-
Patent number: 4571373Abstract: The exposure latitude of positive-acting, color pre-press proofing photosensitive articles can be improved by positioning an optical filter between the separation half-tone positive and the photosensitive article.Type: GrantFiled: June 11, 1984Date of Patent: February 18, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventors: Arlene K. Musser, Peter M. Koelsch
-
Patent number: 4552826Abstract: A microform article useful for producing composite images has an image-forming layer separate from a photosensitive layer and allows for the subsequent addition, when needed, just prior to imaging, of a second photosensitive, resist layer for an add-on image. The unique construction and method therefor provide a positive or negative first image, with the possibility of either positive or negative additional images, the images not necessarily being in the same phase.Type: GrantFiled: October 13, 1983Date of Patent: November 12, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventor: Richard S. Fisch
-
Patent number: 4540648Abstract: The present invention relates to a two-component diazotype material comprising a support and one or several light-sensitive layers, each of which contains at least one light-sensitive diazonium salt, a coupler component and an acid stabilizer, and at least one of the layers contains a compound which absorbs light in the ultraviolet spectral region. The light-absorbing compound is present in the form of a dye salt of at least one benzothiazole which is converted into its leuco base under the action of an alkaline medium. It thus partially or completely loses its absorptivity toward radiation in the long-wave ultraviolet and short-wave visible spectral regions. The light-absorbing compound comprises a benzothiazole, in particular according to the general formula: ##STR1## wherein R.sub.1 denotes hydrogen, alkyl or aralkyl,R.sub.2 denotes hydrogen or an optionally substituted alkyl, aralkyl, aryl, pyridylalkyl, carbalkyl, carboxyalkyl, carboxyaryl, carbamoyl, or sulfamoyl radical, orR.sub.1 and R.sub.Type: GrantFiled: February 28, 1984Date of Patent: September 10, 1985Assignee: Hoechst AktiengesellschaftInventor: Siegfried Scheler
-
Patent number: 4495269Abstract: An aqueous diazo coating composition is disclosed to be used in accordance with an alkaline vapor development system, containing a hydrolyzed resin together with a diazo light-sensitive compound, coupling agent and stabilizing materials. The aqueous diazo coating composition of the present invention provides a method of fabricating a light-sensitive diazo member for use in combination with a development system utilizing alkaline vapors which excludes the use of organic solvents.Type: GrantFiled: August 20, 1984Date of Patent: January 22, 1985Assignee: AM International, Inc.Inventors: Edward C. Bialczak, John J. Chernovitz
-
Patent number: 4492749Abstract: This invention relates to a derivative of 2-hydroxy-naphthalene of the general formula ##STR1## wherein A is ##STR2## and X is --OH or ##STR3## and R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are identical or different and are hydrogen, cycloalkyl having up to eight carbon atoms, which is optionally substituted by lower alkyl groups, aralkyl having up to 10 carbon atoms or aryl which is substituted by lower alkyl, lower alkoxy, halogenalkyl or alkyl-substituted amino groups or by halogen, or R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4 in each case are, conjointly with the nitrogen atom to which they are attached, identical or different heterocyclic groups which are optionally substituted by lower alkyl.Type: GrantFiled: September 15, 1983Date of Patent: January 8, 1985Assignee: Hoechst AktiengesellschaftInventor: Siegfried Scheler
-
Patent number: 4478926Abstract: Zinc salts of sulfonic acids are described as stabilizers for diazotype materials.Type: GrantFiled: February 22, 1983Date of Patent: October 23, 1984Assignee: Andrews Paper & Chemical Co., Inc.Inventors: Peter Muller, Henry Mustacchi
-
Patent number: 4411979Abstract: A diazo type thermosensitive recording material comprising a support material and a thermosensitive recording layer formed thereon, wherein the thermosensitive recording layer comprises a diazo compound, a coupler, a thermo-fusible or thermo-softening binder agent and a thermo-fusible material. The weight ratio of the diazo compound and the thermo-fusible material is in the range of 1:2 to 1:30, and both the diazo compound and the coupler exist as separate particles in the thermosensitive recording layer.Type: GrantFiled: January 6, 1982Date of Patent: October 25, 1983Assignee: Ricoh Company, Ltd.Inventors: Masanaka Nagamoto, Yoshihiro Koseki, Susumu Iwata
-
Patent number: 4374911Abstract: A method of fabricating a photomask having at least three distinct zones of light transmissibility is disclosed. A first mask is made from a predetermined pattern, this mask having only two distinct zones of light transmissibility. A second mask, made by contact printing of a diazo film, is formed from a selected portion of one zone of the original pattern, which zone has the greater light transmissibility. The second mask, being a contact print, is the photographic opposite of the first. The two masks are then aligned with the selected portion of the second mask superimposed over its original location in the first mask and a composite latent image thereof is formed in a suitable emulsion. This composite image is then developed and fixed on an appropriate support to form a photomask having at least three density zones.Type: GrantFiled: January 14, 1980Date of Patent: February 22, 1983Assignee: International Business Machines CorporationInventor: Phillip A. Hartley
-
Patent number: 4343884Abstract: One component diazotype material is imagewise exposed and developed odorless and curlfree with 0.6-4.5 g/m.sup.2 per square meter of a substantially water free liquid developer in a pressure development or transfer roller apparatus.Type: GrantFiled: December 29, 1980Date of Patent: August 10, 1982Assignee: Andrews Paper & Chemical Co., Inc.Inventors: Peter Muller, Henry Mustacchi
-
Patent number: 4304831Abstract: A two-component type diazo copying material according to this invention, which comprises a support and a photosensitive layer formed thereon, said layer consisting essentially of a diazo compound expressed by the following general formula I and a coupler mixture consisting of a compound expressed by the following formula II, a compound expressed by the following general formula III and a compound expressed by the following general formula IV, can form a genuine black-color image and is especially optimum for preparing a secondary original used in electrophotographic copying machines. General formula I ##STR1## (wherein R represents alkyl radical having 1 to 5 carbon atoms; R.sub.1 and R.sub.2 represent substituted or non-substituted alkyl radical, aralkyl radical or cycloalkyl radical, or R.sub.1 and R.sub.2 may form a heterocyclic ring together with the nitrogen atom to which they bond; and X represents anion.) ##STR2## (wherein X is of no account or represents O, S, SO or SO.sub.2.) ##STR3## [wherein R.sub.Type: GrantFiled: August 2, 1979Date of Patent: December 8, 1981Assignee: Ricoh Co., Ltd.Inventors: Tsutomu Matsuda, Masanori Rimoto
-
Patent number: 4291109Abstract: Disclosed herein is a method and apparatus for producing color transparencies on a recording element comprising an additive color filter screen having disposed thereon a coating of a visible light-transmissive, invisible light-sensitive, silverless material, preferably a diazo or vesicular material. The method comprises the steps of imagewise exposing a panchromatic auxiliary layer, e.g. a photoconductive layer, to a multicolored object, such exposure being made through the recording element of the invention. This step acts to produce in the auxiliary layer a monochrome image containing color image information of the multicolored object. Next, the silverless material is exposed to invisible actinic radiation, such exposure being made through the monochrome image formed in or on the panchromatic auxiliary layer. This step serves to transfer the color image information from the auxiliary layer to the silverless layer of the recording element.Type: GrantFiled: November 26, 1979Date of Patent: September 22, 1981Assignee: Eastman Kodak CompanyInventor: Keith E. Whitmore
-
Patent number: 4282300Abstract: A method and apparatus for producing a highly readable diazo copy from a blue line original. An illumination source provides actinic energy which is substantially absorbed by the blue image of a diazo blue line print and in which no substantial exposure of the diazo paper can occur from energy which is non-responsive to the blue image. The light source produces major energy in the range of about 4600 to 5900 Angstroms. A filter or other means is provided to remove any spurious wavelengths which are non-responsive to the blue image and which can expose the diazo paper.Type: GrantFiled: December 4, 1978Date of Patent: August 4, 1981Assignee: Eliott IndustriesInventor: Howard W. Wegener
-
Patent number: 4273850Abstract: This invention relates to an improvement in a two-component diazotype material, composed of a support and of a light-sensitive layer applied to the support, the layer containing at least one benzene diazonium salt as the light-sensitive component and at least one coupler, the improvement comprising the combination of at least one 2,5-dialkoxy-4-mercaptobenzene diazonium salt and at least one compound of the general formula ##STR1## in which R.sub.1 and R.sub.2 are identical or different and denote hydrogen or alkyl, alkenyl, aralkyl, aryl or cycloalkyl groups, which can be further substituted.Type: GrantFiled: February 25, 1980Date of Patent: June 16, 1981Assignee: Hoechst AktiengesellschaftInventor: Hans-Dieter Frommeld
-
Patent number: 4252884Abstract: Negative-working diazography material is comprised of (i) at least one diazonium compound, (ii) at least one acid labile enolic, preferably phenolic blocked-coupler adapted to be converted in the presence of acid to an active azo-coupling component, and (iii) at least one light-sensitive acid progenitor. The diazonium compound can itself concurrently function as the acid progenitor, e.g., when complexed with a Lewis acid. Upon imagewise exposure to light, acid catalyst is photochemically liberated, thus unblocking coupler molecules such that dye image forms under alkaline developing conditions only where the material has been irradiated.Type: GrantFiled: August 14, 1979Date of Patent: February 24, 1981Assignee: James River Graphics, Inc.Inventor: Everett W. Bennett
-
Patent number: 4225662Abstract: This invention provides yellow-developing couplers for use in diazo copying materials, which couplers are superior in light fastness and are expressed by the general formula: ##STR1## wherein X and Y represent hydrogen atom, halogen, or alkyl radical or alkoxy radical having 1 to 6 carbon atoms.Type: GrantFiled: April 11, 1979Date of Patent: September 30, 1980Assignee: Ricoh Company, Ltd.Inventors: Tsutomu Matsuda, Masanori Rimoto, Chihiro Hayashi
-
Patent number: 4224397Abstract: A diazotype material useful for making duplicates of continuous tone originals, such as X-ray films, comprising a transparent film support having a coating of a layer thereon consisting essentially of at least two light-sensitive diazo compounds having different photolysis rates, couplers for the diazo compounds, an ultraviolet radiation absorbing material and homogeneously distributed in the layer at least about 7% by weight, based on the weight of lacquer, of an inert particulate material such as silica. The use of this material makes it possible to approximate a logarithmic photolysis, thereby providing sufficient linearity in the corresponding characteristic curve to achieve the desired duplicating results.Type: GrantFiled: January 26, 1979Date of Patent: September 23, 1980Assignee: Trans World Technology Laboratories Inc. (TWT Labs, Inc.)Inventor: Gilbert Zweig
-
Patent number: 4220700Abstract: There is disclosed a composition and element, comprising a diazo resin and a mordant for anionic dyes that is compatible with the resin. The element of the invention is suitable for dye immersion and dye transfer to a mordanted receiver.Type: GrantFiled: February 3, 1978Date of Patent: September 2, 1980Assignee: Eastman Kodak CompanyInventors: Hugh G. McGuckin, Hyman L. Cohen
-
Patent number: 4207110Abstract: This invention relates to an improvement in a diazotype material comprising, in the light-sensitive layer, a diazo component and a coupling component which yields a black dyestuff image, the improvement that the diazo component is a 2,5-dialkoxy-4-morpholino-benzene diazonium salt and the coupling component is a combination of(a) 6-methoxy-2-hydroxy-3-naphthoic acid-N(.omega.-aminoalkyl)-amide as a blue coupler,(b) a 2-alkyl- or 2-aryl-1,3-dihydroxybenzene or a cyanoacetoamide as a yellow coupler, and(c) at least one compound of the general formula ##STR1## wherein X is zero, =S, =SO, or =SO.sub.2, as a reddish-brown coupler, the molar ratio of blue coupler to yellow coupler being in the range of about (0.7 to 0.9):1, and the molar ratio of blue coupler to reddish-brown coupler being in the range of about (6 to 12):1.Type: GrantFiled: October 13, 1978Date of Patent: June 10, 1980Assignee: Hoechst AktiengesellschaftInventors: Siegfried Scheler, Heinz Schafer