Liquid Development, E.g., Aqueous Solution With Coupler, Etc. Patents (Class 430/149)
  • Patent number: 9897922
    Abstract: Provided is a method of forming a pattern, including (a) forming a chemically amplified resist composition into a film, (b) exposing the film to light, and (c) developing the exposed film with a developer containing an organic solvent, wherein the developer contains an alcohol compound (X) at a content of 0 to less than 500 ppm based on the total mass of the developer.
    Type: Grant
    Filed: August 12, 2016
    Date of Patent: February 20, 2018
    Assignee: FUJIFILM Corporation
    Inventors: Yuichiro Enomoto, Shinji Tarutani, Sou Kamimura, Kaoru Iwato, Keita Kato, Kana Fujii
  • Patent number: 8518739
    Abstract: As a display device has a higher definition, the number of pixels, gate lines, and signal lines are increased. When the number of the gate lines and the signal lines are increased, there occurs a problem that it is difficult to mount an IC chip including a driver circuit for driving the gate and signal lines by bonding or the like, whereby manufacturing cost is increased. A pixel portion and a driver circuit for driving the pixel portion are provided over the same substrate, and at least part of the driver circuit includes a thin film transistor using an oxide semiconductor interposed between gate electrodes provided above and below the oxide semiconductor. Therefore, when the pixel portion and the driver circuit are provided over the same substrate, manufacturing cost can be reduced.
    Type: Grant
    Filed: November 10, 2009
    Date of Patent: August 27, 2013
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Hidekazu Miyairi, Takeshi Osada, Kengo Akimoto, Shunpei Yamazaki
  • Publication number: 20010033219
    Abstract: A photosensitive thick film composition is provided which has superior storage stabilities and can be reliably processed by developing. The photosensitive thick film composition is composed of a photosensitive organic component containing an organic binder having an acidic functional group, such as a carboxyl group, an inorganic component containing a polyvalent metal oxide, such as borosilicate glass, and an alcohol having a plurality of hydroxyl group, such as glucitol.
    Type: Application
    Filed: March 8, 2001
    Publication date: October 25, 2001
    Applicant: Murata Manufacturing Co., Ltd.
    Inventors: Michiaki Iha, Masahiro Kubota, Shizuharu Watanabe
  • Patent number: 6153350
    Abstract: The polybenzoxazole and polybenzothiazole precursors of the invention have the following partial structure: ##STR1## where: A.sup.1 to A.sup.6 are--independently of one another--H, F, CH.sub.3, CF.sub.3, OCH.sub.3, OCF.sub.3, CH.sub.2 CH.sub.3, CF.sub.2 CF.sub.3, OCH.sub.2 CH.sub.3 or OCF.sub.3 CF.sub.3 ;T is O or S, and m is 1;Z is a carbocyclic or heterocyclic aromatic radical.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: November 28, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Michael Keitmann, Gunther Schmid
  • Patent number: 6120970
    Abstract: The polybenzoxazole and polybenzothiazole precursors of the invention have the following partial structure: ##STR1## where: A.sup.1 to A.sup.7 are--independently of one another--H, F, CH.sub.3, CF.sub.3, OCH.sub.3, OCF.sub.3, CH.sub.2 CH.sub.3, CF.sub.2 CF.sub.3, OCH.sub.2 CH.sub.3 or OCF.sub.2 CF.sub.3 ;T is O or S, and m is 1;Z is a carbocyclic or heterocyclic aromatic radical.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: September 19, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Michael Keitmann
  • Patent number: 5889141
    Abstract: Photoimageable polyquinoline compositions comprise a polyquinoline polymer, a diazonaphthoquinone and optionally a photosensitizer. The composition is prepared by dissolving the polyquinoline polymer, diazonaphthoquinone and photosensitizer in a solvent to form a solution, coating the solution onto a substrate and thereafter removing the solvent to form a film. The film is exposed to light through a photomask and developed by immersion in a selective solvent to yield a photopatterned dielectric film.
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: March 30, 1999
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Matthew L. Marrocco, III, Makoto Kaji
  • Patent number: 5879851
    Abstract: A method for forming resist patterns comprising coating a resist comprising a polymeric or copolymeric compound having a repeating unit comprising a protected alkali-soluble group in which the protecting group is cleaved with an acid so that the compound is made alkali-soluble, and an acid generator capable of generating an acid upon the radiation exposure to a substrate to be fabricated, then pre-baking the formed resist film, successively selectively exposing the resist film, thereafter, developing a latent image with a developer containing an aqueous or alcoholic solution of a specified ammonium compound or morpholine compound. According to this method, crack formation and peeling of a pattern can be suppressed at the time of forming resist patterns.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: March 9, 1999
    Assignee: Fujitsu Limited
    Inventors: Makoto Takahashi, Satoshi Takechi
  • Patent number: 5314781
    Abstract: A blueprint developing solution and process for developing blueprints, wherein the ammonia odor in the blueprints is reduced without eliminating the odor of the developing solution, comprising the incorporation of an effective amount of sodium chlorite in the developing solution or the addition of the vapor products of an aqueous sodium chlorite solution to the developing chamber of a blueprint developing machine.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: May 24, 1994
    Inventor: Ronald L. Balk
  • Patent number: 5106724
    Abstract: There are disclosed an aqueous alkaline developer for light-sensitive lithographic printing plate commonly processing a negative-type light-sensitive lithographic printing plate having a light-sensitive layer containing a diazo compound and a positive-type light-sensitive lithographic printing plate having a light-sensitive layer containing an o-quinonediazide compound, which comprises containing an alkali agent, 0.1 to 10% by weight of a water-soluble reducing agent, a sodium, potassium or ammonium salt of an organic carboxylic acid, and a non-ionic or cationic surfactant, and having a pH in the range of 12.5 to 13.5, and also a developer composition for light-sensitive material, which comprises an aqueous solution containing a compound represented by the formula (I) shown below: ##STR1## wherein R.sub.1 represents an alkyl group or an alkoxy group each having 2 to 5 carbon atoms, or a hydroxyalkyl group having 2 to 5 carbon atoms; and R.sub.
    Type: Grant
    Filed: June 1, 1990
    Date of Patent: April 21, 1992
    Assignee: Konica Corporation
    Inventors: Akira Nogami, Minoru Seino, Masafumi Uehara, Miegi Nakano
  • Patent number: 5039594
    Abstract: The invention provides a positive working photosensitive element with improved odor and increased photospeed which comprises coating a formulation containing at least one novolak or polyvinyl phenol resin, at least one o-quinone diazide and a solvent mixture comprising propylene glycol alkyl ether and propylene glycol alkyl ether acetate, onto a substrate, drying, exposing to imaging energy and developing.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: August 13, 1991
    Assignee: Hoechst Celanese Corporation
    Inventor: Dana Durham
  • Patent number: 4983490
    Abstract: The invention provides a mixture suitable for treating a photographic composition which comprises from about 1 to about 10 parts by weight of a propylene glycol alkyl ether and from about 1 to about 10 parts by weight of a propylene glycol alkyl ether acetate.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: January 8, 1991
    Assignee: Hoechst Celanese Corporation
    Inventor: Dana Durham
  • Patent number: 4937170
    Abstract: A photographic element formed from a substrate and light sensitive coating on the substrate wherein the coating comprises a mixture of a diazo compound and an aromatic carboxylic coupling agent having phenolic hydroxy groups, in an acidic medium.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: June 26, 1990
    Assignee: Hoechst Celanese Corporation
    Inventor: Dieter Mohr
  • Patent number: 4820621
    Abstract: The aqueous developer solution for a positive-working photoresist composition comprises, as dissolved in an aqueous solvent, a water-soluble organic basic compound and a specific non-ionic surface active agent which may be an alkyl-substituted phenyl or naphthyl ether of polyoxyethyleneglycol in a specified concentration. The developer solution is advantageous in respect of the completeness of removal of film residua and scums from the substrate surface after development so that the patterned photoresist layer is imparted with greatly increased accuracy and fidelity of the pattern reproduction.
    Type: Grant
    Filed: June 26, 1987
    Date of Patent: April 11, 1989
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Hatsuyuki Tanka, Yoshiyuki Sato, Hidekatsu Kohara, Toshimasa Nakayama
  • Patent number: 4806458
    Abstract: The invention provides a composition which comprises from about 3 to about 50% by weight of a hexa-alkyl disilazane and a solvent composition which comprises one or more compounds selected from the group consisting of a propylene glycol alkyl ether and a propylene glycol alkyl ether acetate.
    Type: Grant
    Filed: August 27, 1987
    Date of Patent: February 21, 1989
    Assignee: Hoechst Celanese Corporation
    Inventor: Dana Durham
  • Patent number: 4786580
    Abstract: The invention provides a method for developing negative working photographic elements using an aqueous developer comprising(a) a solvent composition consisting essentially of(i) n-propanol or isopropanol; and(ii) a glycol ether or acetate(b) a salt which is preferably magnesium sulfate; and(c) an ethoxylated alkyl phenol type non-ionic surfactant.
    Type: Grant
    Filed: December 27, 1983
    Date of Patent: November 22, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: Shane Hsieh, Wayne A. Mitchell
  • Patent number: 4741989
    Abstract: A developer for positive photoresists which can improve the sensitivity and resolution of the resist is disclosed. The developer comprises an aqueous solution of a quaternary ammonium hydroxide represented by the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are each an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group having 1 to 5 carbon atoms, and at least one development modifier selected from the group consisting of water-soluble aliphatic ketones, cyclic ethers, and tertiary amines, and optionally, at least one another development modifier selected from the group consisting of water-soluble primary amines and secondary amines.
    Type: Grant
    Filed: May 28, 1986
    Date of Patent: May 3, 1988
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Niwa, Ichiro Ichikawa
  • Patent number: 4711836
    Abstract: Disclosed is an aqueous developing solution containing a quaternary ammonium hydroxide developing agent, and as an additive an effective amount of a select compound which is either 1,3,5-trihydroxy benzene, 4-methylesculetin or a novolak-type resin. The aqueous developing solution is particularly useful in developing an imagewise-exposed layer of a positive-working photoresist composition containing a novolak-type resin and a photosensitive agent. In such application, it has been found that the developing solution more effectively removes the exposed portions of the photoresist composition without leaving a residue of exposed photoresist composition at the interface of the edges of the unexposed portions of the photoresist composition and the oxidized silicon substrate.
    Type: Grant
    Filed: August 11, 1986
    Date of Patent: December 8, 1987
    Assignee: Olin Hunt Specialty Products, Inc.
    Inventor: Lawrence Ferreira
  • Patent number: 4710449
    Abstract: A novel low metal ion developer composition used in a two step process which provided high contrast images and long developer bath life is provided. The process gives high contrast images. The substrate coated with positive photoresist is exposed then immersed in a "predip" bath, rinsed, and then, immersed in the developer bath, rinsed and dried. This process provided high contrast which does not decrease over the life of the developer system. The system consists of (1) a predip solution containing aqueous non-metal ion organic base and a cationic surfactant adjusted to a concentration that does not give development, and (2) a developer solution containing an aqueous solution of an non-metal ion organic base and a fluorochemical surfactant adjusted to a concentration that provides development. The high contrast is achieved by the cationic surfactant coating the resist and inhibiting the attack on the unexposed resist by the developer while permitting the developer to dissolve away the exposed resist.
    Type: Grant
    Filed: January 29, 1986
    Date of Patent: December 1, 1987
    Assignee: Petrarch Systems, Inc.
    Inventors: James M. Lewis, Andrew J. Blakeney
  • Patent number: 4692398
    Abstract: The invention provides a composition which comprises from about 3 to about 50% by weight of a hexa-alkyl disilazane and a solvent composition which comprises one or more compounds selected from the group consisting of a propylene glycol alkyl ether and a propylene glycol alkyl ether acetate.
    Type: Grant
    Filed: October 28, 1985
    Date of Patent: September 8, 1987
    Assignee: American Hoechst Corporation
    Inventor: Dana Durham
  • Patent number: 4692397
    Abstract: A method of producing a light sensitive element wherein a substrate is coated with a photosensitive layer having a particular class of diazonium salts, a colorant and a polyvinyl acetal resin. Upon imagewise exposure it is developed with an aqueous composition of salts and surfactants in the absence of organic solvents.
    Type: Grant
    Filed: November 27, 1985
    Date of Patent: September 8, 1987
    Assignee: American Hoechst Corporation
    Inventor: Shuchen Liu
  • Patent number: 4610953
    Abstract: The invention provides an aqueous alkaline developer solution for a positive-type photoresist layer for pattern-wise treatment of the surface of a substrate, e.g., semiconductor wafer. The developer solution contains a tetraalkyl ammonium hydroxide, e.g., tetramethyl ammonium hydroxide, and a trialkyl hydroxyalkyl ammonium hydroxide, e.g., trimethyl hydroxyethyl ammonium hydroxide, as the essential ingredients and the temperature dependency of the development performance thereof is noticeably smaller than that of conventional developer solutions with respect to properties of the sensitivity of the photoresist and the thickness reduction of the photoresist layer in the unexposed areas, by virtue of the compensating temperature dependencies for these properties of these two ingredients for each other.
    Type: Grant
    Filed: May 29, 1984
    Date of Patent: September 9, 1986
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Koichiro Hashimoto, Shirushi Yamamoto, Hisashi Nakane, Akira Yokota
  • Patent number: 4579811
    Abstract: Disclosed is a developer composition for exposed, light-sensitive, negative-working reproduction layers, which may contain an organic binder, comprising water and a salt of a substituted aromatic carboxylic acid, in particular, from about 5 to 60% by weight of at least one salt of an aromatic carboxylic acid having substituents which are immediately adjacent to the carboxyl group and represent an amino group, a hydroxyl group, and/or chlorine or bromine. Also disclosed is a process for developing the reproduction layers utilizing the disclosed developers, wherein the reproduction layer contains, in particular, a polymeric organic binder with an acetal, anhydride, amide and/or a carboxyl group.
    Type: Grant
    Filed: December 28, 1983
    Date of Patent: April 1, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Loni Schell, Werner Frass, Inge Gros
  • Patent number: 4576899
    Abstract: A developer is provided for lithographic plates or the like having a layer including a diazonium material, which developer enhances the effectiveness of the photolysis to which the plate had been subjected, with the result that the exposure time needed for the plate is substantially reduced. The developer, which thus enhances the apparent photospeed of the plate, includes an insolubilizing reactant that reacts with diazonium groups of diazonium materials on the plate that were not removed by photolysis during exposure in order to decrease the solubility of the diazonium material.
    Type: Grant
    Filed: May 1, 1984
    Date of Patent: March 18, 1986
    Assignee: Imperial Metal & Chemical Company
    Inventors: Luigi Amariti, Llandro C. Santos
  • Patent number: 4537851
    Abstract: A water-soluble, positive-working photoresist composition is disclosed which comprises water-soluble aromatic diazonium salt, water-soluble phenolic compound, and water-soluble polymeric compound. When the film of this composition is irradiated with a pattern of actinic ray and then brought into contact with an alkaline gas or solution, the coating of unexposed areas hardens to become water-insoluble. Preferably, when the film is brought into contact with a suspension of powder or dry powder after being hardened, a positive pattern of powder is obtained by the development with water.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: August 27, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Saburo Nonogaki, Nobuaki Hayashi, Yoshifumi Tomita
  • Patent number: 4500625
    Abstract: A developer for a light-sensitive lithographic printing plate having an o-quinonediazide-containing light-sensitive layer is disclosed. The developer is comprised of an aqueous solution of an alkali silicate containing an organic boron compound. The organic boron compound is represented by the formula ##STR1## the substituents are defined within the specification. By utilizing the developer of the invention it is possible to provide excellent developing power, development stability, processability and preferred forming properties during development.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuyuki Kita, Hiroshi Matsumoto, Hitoshi Hagiwara
  • Patent number: 4478926
    Abstract: Zinc salts of sulfonic acids are described as stabilizers for diazotype materials.
    Type: Grant
    Filed: February 22, 1983
    Date of Patent: October 23, 1984
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventors: Peter Muller, Henry Mustacchi
  • Patent number: 4471043
    Abstract: Diazotype material having enhanced water-wet properties and especially suitable when imaged for being drawn or written upon, and for use as an intermediate original, is made of a support such as a transparent polymeric film carrying on one of its sides a light sensitive diazo layer formed of a dispersion of a light sensitive diazonium compound and a large amount of amorphous hydrated silica particles having a bound water content of at least 50% by weight in a polymeric binder consisting essentially of a 20 to 45% hydrolyzed polyvinyl acetate which preferably is a product of partial hydrolysis of a PVAC having in ethyl acetate at 20.degree. C. a Heoppler viscosity of 100 to 800 mPa.s. The weight ratio of the hydrated silica to the partially hydrated PVAC in the layer typically is in the range of 2:3 to 3:2. The support advantageously carries on its other side a light-pervious drafting layer formed of a dispersion of a silica filler in a partially hydrolyzed PVAC the same as that required for the diazo layer.
    Type: Grant
    Filed: November 18, 1982
    Date of Patent: September 11, 1984
    Assignee: Oc/e/ -Nederland B.V.
    Inventor: Wilhelmus J. M. van de Vorle
  • Patent number: 4439512
    Abstract: Phenylurethane compounds formed by the reaction between a phenolic coupler compound and an organic isocyanate compound are utilized to form phenolic coupler compounds in situ in order to react with chromogenic compounds present in the sensitive layer of recording or reproducing materials.The phenolic coupler compounds can also be stabilized by blocking the phenolic hydroxyl with carbonate, an alkyl ether, organosilylated ether or organophosphoric acid ester, some of which are novel compounds. These stabilized derivatives of the stabilized phenolic coupler compound will decompose by application to sufficient thermal energy or suitable liquid or gaseous fluid to form the phenolic coupler compound in situ. The phenolic coupler compound is formed in situ by applying thermal energy to the sensitive layer or by applying to the sensitive layer a liquid or gaseous fluid which is able to decompose the stabilized phenolic coupler compound and release the phenolic coupler compound.
    Type: Grant
    Filed: November 18, 1982
    Date of Patent: March 27, 1984
    Assignee: La Cellophane
    Inventor: Claude Ceintrey
  • Patent number: 4374193
    Abstract: A positive-working photosensitive material and a process for developing the same are disclosed.The positive-working photosensitive material is obtained by forming on a base material a layer of a photosensitive composition containing (A), 100 weight parts of a resin binder including a vinylic polymer compound having phenolic hydroxyl groups and (B), 3-30 weight parts of an aromatic diazonium salt having only a single diazo group.The positive-working photosensitive material is developed by using an aqueous alkali solution.
    Type: Grant
    Filed: April 29, 1981
    Date of Patent: February 15, 1983
    Assignee: Kimoto & Co., Ltd.
    Inventors: Takeo Moriya, Toshio Yamagata
  • Patent number: 4370406
    Abstract: A single-phase, non-emulsion water containing subtractive developer for lithographic plates having photopolymer coatings is provided. These developers include water and an active or primary solvent which is only partially soluble in water and which is a good solvent for the photopolymer of a lithographic plate that has not been exposed to and insolubilized by actinic radiation, this active solvent typically being present at a concentration near its water solubility limit. Preferably, a cosolvent is also included to increase the water solubility of the active solvent when necessary. A desensitizer may be included to impart to the formulation the properties of a one-step developer or of a finisher. Formulation and development methods for these developers are also included, and they may be used either as developers or as a machine developer solution replenisher.
    Type: Grant
    Filed: May 12, 1981
    Date of Patent: January 25, 1983
    Assignee: Richardson Graphics Company
    Inventor: Thomas H. Jones
  • Patent number: 4366224
    Abstract: A developer composition for positive photosensitive lithographic printing plates and photoresists comprising an aqueous solution of an inorganic lithium compound and sodium metasilicate.
    Type: Grant
    Filed: August 6, 1981
    Date of Patent: December 28, 1982
    Assignee: American Hoechst Corporation
    Inventor: Shane Hsieh
  • Patent number: 4343884
    Abstract: One component diazotype material is imagewise exposed and developed odorless and curlfree with 0.6-4.5 g/m.sup.2 per square meter of a substantially water free liquid developer in a pressure development or transfer roller apparatus.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: August 10, 1982
    Assignee: Andrews Paper & Chemical Co., Inc.
    Inventors: Peter Muller, Henry Mustacchi
  • Patent number: 4331479
    Abstract: A light-sensitive nameplate material comprising an aluminum support having a porous aluminum oxide film on the surface thereof and a light-sensitive organic coating layer comprising an o-quinone diazide provided on the aluminum oxide film.
    Type: Grant
    Filed: September 8, 1977
    Date of Patent: May 25, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadao Toyama
  • Patent number: 4329422
    Abstract: A desensitizing solution and process for using the solution are disclosed to desensitize a diazo photosensitive printing plate after development. The solution comprises a water soluble desensitizing agent capable of reacting with any residual photosensitive diazo on the developed plate to render the diazo incapable of forming an oleophilic substance and a filming agent selected from water soluble aliphatic polyols have less than eight carbon units, the acid derived monoesters of these polyols, and the alkali metal salts of the monoesters.
    Type: Grant
    Filed: June 25, 1979
    Date of Patent: May 11, 1982
    Assignee: Napp Systems (USA), Inc.
    Inventor: Eugene L. Langlais
  • Patent number: 4304831
    Abstract: A two-component type diazo copying material according to this invention, which comprises a support and a photosensitive layer formed thereon, said layer consisting essentially of a diazo compound expressed by the following general formula I and a coupler mixture consisting of a compound expressed by the following formula II, a compound expressed by the following general formula III and a compound expressed by the following general formula IV, can form a genuine black-color image and is especially optimum for preparing a secondary original used in electrophotographic copying machines. General formula I ##STR1## (wherein R represents alkyl radical having 1 to 5 carbon atoms; R.sub.1 and R.sub.2 represent substituted or non-substituted alkyl radical, aralkyl radical or cycloalkyl radical, or R.sub.1 and R.sub.2 may form a heterocyclic ring together with the nitrogen atom to which they bond; and X represents anion.) ##STR2## (wherein X is of no account or represents O, S, SO or SO.sub.2.) ##STR3## [wherein R.sub.
    Type: Grant
    Filed: August 2, 1979
    Date of Patent: December 8, 1981
    Assignee: Ricoh Co., Ltd.
    Inventors: Tsutomu Matsuda, Masanori Rimoto
  • Patent number: 4296193
    Abstract: A photosensitive material and a process for developing the same are disclosed.The photosensitive material is obtained by forming on a base material a layer of photosensitive composition comprising (A), 100 weight parts of a water soluble resin binder containing at least 60 weight % of acrylamide-diacetoneacrylamide copolymer, the copolymerization ratio of acrylamide and diacetoneacrylamide being 8:2-5:5 and average polymerization degree being 300-1500, and (B), 5-20 weight parts of a water soluble diazonium salt.The photosensitive material is developed by using an aqueous alkali solution.
    Type: Grant
    Filed: June 20, 1980
    Date of Patent: October 20, 1981
    Assignee: Kimoto & Co., Ltd.
    Inventors: Takeo Moriya, Toshio Yamagata
  • Patent number: 4286041
    Abstract: A composition and process for developing diazotype material utilizes a developing liquid comprising a buffered, aqueous solution of an azo-coupling component having a pH between 5.5 and 8 and, as an additive compound, sorbic acid, an alkali metal salt, ammonium salt, or magnesium salt of sorbic acid or mixtures of the same. The process produces a clear copy image more quickly than a process in which the developing liquid does not contain the additive compound and, when the azo-coupling component is a mixture of phloroglucinol and resorcinol, forms a neutrally black image. The additive compound is added in an amount of 10 to 80%, and preferably 30 to 60%, by weight, of the maximum amount soluble in the solution at room temperature.
    Type: Grant
    Filed: March 1, 1979
    Date of Patent: August 25, 1981
    Assignee: Oce-van der Grinten
    Inventor: Wilhelmus J. M. van de Vorle
  • Patent number: 4275137
    Abstract: Diazotype material having a thin light-sensitive layer that is developable excellently by a limited application (1.5 to 4.5 cm.sup.3 /m.sup.2) of a buffered aqueous solution of an azo component, and which adheres well to the support even in moist condition, can be obtained by providing on a paper support a light-sensitive layer containing a binder and filler with at least one diazo compound, when the binder comprises a condensation product of an amino compound with formaldehyde, e.g. cross-linked hexamethoxymethyl-melamine, and a hydrophilic polymer crosslinkable with said product, e.g. highly hydrolyzed polyvinyl alcohol, and the filler comprises starch particles, e.g. rice starch powder, in a weight proportion to said polymer of at least 5 to 1, and even as high as 30-70 to 1. A water-sealing layer on both sides of the support, or only on a side beneath the light-sensitive layer, renders the material curl resistant.
    Type: Grant
    Filed: September 3, 1975
    Date of Patent: June 23, 1981
    Assignee: Oce-van der Grinten N.V.
    Inventor: Adrianus J. N. A. Verhoof
  • Patent number: 4267249
    Abstract: Benzene diazonium compounds of the general formula ##STR1## wherein R.sub.1 is alkylamino, dialkylamino, cycloalkylamino, dicycloalkylamino, cycloalkylalkylamino, aralkylamino, diaralkylamino, alkylaralkylamino, cycloalkylaralkylamino, arylamino, diarylamino, alkylarylamino, cycloalkylarylamino, acoylamino, acoylalkylamino, acoylcycloalkylamino, acoylaralkylamino, acoylarylamino, aroylamino, aroylalkylamino, aroylcycloalkylamino, aroylaralkylamino, aroylarylamino, morpholino, piperidino, triazinyl, alkylthio, hydroxyalkylthio, cycloalkylthio, aralkylthio, or arylthio; R.sub.2 is alkyl, aralkyl, aryl, or alkoxyalkyl; R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 may be the same or different and are hydrogen, alkyl, cycloalkyl, aralkyl, aryl, or halogen, at least one of the substituents R.sub.3 to R.sub.8 not being hydrogen; and X is an anion.
    Type: Grant
    Filed: August 22, 1979
    Date of Patent: May 12, 1981
    Assignee: Aerni-Leuch AG
    Inventor: Niklaus Baumann
  • Patent number: 4196003
    Abstract: A light-sensitive copying layer containing an o-quinone-diazide compound and at least one of a secondary amine and a tertiary amine.
    Type: Grant
    Filed: February 2, 1977
    Date of Patent: April 1, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masaru Watanabe