Abstract: A silver halide color reversal reflection print photosensitive material comprises at least one blue-sensitive layer, at least one green-sensitive layer and at least one red-sensitive layer on a support. In the characteristic curves of the color sensitive layers, a fluctuation width of point-gammas and absolute values of point-gammas are defined. The distribution of the grain size of the silver halide grains in silver halide emulsions contained in the color sensitive layer can be controlled by forming the grains in the presence of a silver halide solvent.

Abstract: A photo and pressure sensitive recording medium comprising a sheet shaped supporting member, microcapsules enveloping therein at least image developing materials and photo-sensitive resins, and plastic grains having large diameter than that of the microcapsule and being softenable when exposed to external energy. The microcapsules and the plastic grains are mixedly distributed and coated on one surface of said supporting member.Since the plastic grains are not softened until they are subjected to the external energy such as heat, light and so on, the microcapsules smaller than the plastic grains can be prevented from unintentional rupturing by fingers of operators or so during the transportation or so of the recording medium even though the microcapsules are prepared to be ruptuable by small pressure such as the pressure applied by the fingers or so.

Abstract: Color correction of negative images resulting from diffusion transfer photographic recording materials is obtained through use of two dye image-providing compounds, each of which is capable of releasing a diffusible dye. One of the dye image-providing compounds releases a diffusible dye as a result of silver halide development whereas the other compound releases dye in areas where no development occurs.

Abstract: A radiation-sensitive composition including silver halide grains capable of forming an internal latent image and a nucleating agent is useful as a coating on a support to form a photographic element.

Abstract: A method for processing a silver halide photographic light-sensitive material comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent capable of releasing a photographically useful agent, which method comprises processing the photographic light-sensitive material in the presence of an oxime.According to this method for processing a silver halide photographic light-sensitive material, both stability of the photographic light-sensitive material during storage and release of a photographically useful agent during processing are achieved without undersirable side-reactions, and a high sensitivity/fog ratio is obtained.

Abstract: A silver halide photographic material which comprises a support having coated thereon a light-sensitive silver halide emulsion layer, wherein the photographic material contains at least one blocked photographic agent represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom, or a precursor thereof; R.sup.1, R.sup.2 and R.sup.3 each represents a hydrogen atom, or a substituent group; and Z represents atoms necessary to form a carbocyclic ring or a heterocyclic ring (except for a heterocyclic ring which contains an NH group at the position adjacent to the carbon atom to which R.sup.1 is attached). The blocked photographic agent is completely stable upon storage of the photographic material, and releases a photographic agent at a desired time upon processing. The blocked photographic agent also exhibits its function to a substantial degree over a wide range of pH.

Abstract: Photographic processing compositions containing a light-reflecting pigment and a styrene-butadiene copolymer are disclosed. The photographic processing compositions are useful in photographic diffusion transfer film units and processes for the provision of permanent photographic laminates. A light-reflecting layer formed in a photographic laminate from such a processing composition exhibits a reduced tendency toward cohesion or adhesion failure and separation.

Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer having associated therewith at least one blocked photographic reagent represented by formula (I) or (II); ##STR1## wherein, A represents a moiety of a photographic reagent or a moiety of a precursor of a photographic reagent bonded to the ring containing Z through a hetero atom; Y.sup.1, and Y.sup.2 and Y.sup.3 each represents a hydrogen atom or a substituent, or Y.sup.1 and Y.sup.3 in formula (I) together form a ring; Z represents an atomic group necessary for forming a carbon ring or a heterocyclic ring; and n represents 1 or 2.The silver halide photographic material is stable under storage conditions.

Abstract: The present invention is directed to a color diffusion transfer film unit comprising a transparent support carrying on a first side at least a first photosensitive silver halide emulsion layer having dye image-providing material associated therewith, a substantially opaque layer, a reflective layer and a dye image-receiving layer; said transparent support carrying on a second side a layer initially transparent to radiation actinic to said silver halide emulsion, said initially transparent layer adapted to convert an opaque layer upon contact with alkali which prevents transmission of exposing radiation to said silver halide emulsion layer wherein said photosensitive silver halide emulsion layer is intermediate said initially transparent layer and said opaque layer.

Abstract: A novel color diffusion transfer photographic material comprising (A) a light-sensitive element comprising a first support having thereon at least a silver halide photographic emulsion layer and a dye providing compound, (B) an image receiving element comprising a second support having thereon at least an image receiving layer and (C) means for providing an alkaline treating solution between element (A) and (B), wherein(i) the swollen film thickness of said light-sensitive element (A) is from about 10 .mu.m after being contacted with water at 25.degree. C. for 5 minutes;(ii) the swollen film thickness of said image receiving element (B) is from about 10 .mu.m to 40 .mu.m after being contacted with 0.1N KOH aqueous solution at 25.degree.C for 3 minutes; and(iii) said means for providing an alkaline treating solution provides an average thickness of said treating solution between element (A) and (B) during development of from about 40 .mu.m to 80 .mu.m.

Abstract: Photographic elements and assemblages are described which employ nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds which are capable of releasing photographically useful groups in an imagewise manner as a function of silver halide development.

Abstract: A silver halide photographic light-sensitive material is described, comprising a support having thereon a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent represented by formula (I) ##STR1## wherein A represents a photographically useful agent moiety, which may have a timing group; X.sup.1 and X.sup.2 each represents a carbonyl group, a sulfonyl group, or a sulfinyl group; Z represents an atomic group forming a 5-membered, 6-membered, or 7-membered ring; R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a sulfonyl group, or a heterocyclic group; R.sup.3 represents an alkyl group, an alkenyl group, a cycloalkyl group, a heterocyclic group, an aryl group, or an aralkyl group; m represents 0, 1, or 2; n represents 0 or 1; and the total of m+n is 1, 2, or 3.

Abstract: Photographic elements and assemblages are described which employ nondiffusible compounds which release photographically useful groups in an imagewise manner as the result of a .beta.-elimination reaction.

Abstract: Photographic assemblages are described wherein a stripping layer is employed to enable an image-receiving layer to be separated from the rest of the assemblage after processing. A reflecting layer is employed between the image-receiving layer and a transparent support. During processing, the wet reflecting layer is sufficiently transparent to permit transmission viewing of the image through the transparent support. After stripping, the reflecting layer dries to provide a reflective surface for viewing the image from the opposite direction.

Abstract: A multilayer color photographic light-sensitive material containing no image-receiving layer is described, comprising a support, an internal latent image type direct reversal silver halide emulsion layer combined with a dye-providing substance, and a void layer between the support and the layer containing the dye-providing substance closest to the support.

Abstract: A silver halide photographic light-sensitive material is described, comprising a support having provided thereon at least one light-sensitive silver halide emulsion layer associated with a substantially immobile, positive one-equivalent redox compound capable of releasing a photographically useful compound or a precursor thereof as a result of a redox reaction, said compound being represented by formula (I) ##STR1## wherein Acp represents an anion center precursor capable of causing --Z--Q to be released by a quinonemethide type releasing reaction when being reduced R.sup.1 and R.sup.

Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline photographic developing composition is effected in the presence of a compound which releases a quaternary in alkaline environment. Photographic products and processes utilizing such compounds are also disclosed.

Abstract: A photographic light-sensitive material for a color diffusion transfer process is described, comprising a support having provided thereon (1) at least two silver halide emulsion layers which are in combination with dye-releasing redox compounds, and (2) an intermediate layer between said silver halide emulsion layers; the intermediate layer comprises a hydrophilic colloid having dispersed therein two or more different kinds of particles, with one or more kinds of said particles containing a scavenger for an oxidized product of a developing agent. The material has an improved processing temperature latitude.

Abstract: Photographic assemblages are described employing metallizable redox dye-releasers and a ligand having a coordinating site which is: ##STR1## In a preferred embodiment, the ligand is an alpha amino carboxylic acid, a 2-pyridinecarboxylic acid, a 2-aminoalcohol, a 2-hydroxymethylpyridine, a 2-hydroxyacetic acid, a 1,2-diamine or a 2-hydroxypyridine-N-oxide.

Abstract: Photographic assemblages are described employing metallizable redox dye-releasers and a sequestering agent which is gluconic acid, N[CH.sub.2 --P--(O)(OH).sub.2 ].sub.3 or (HO).sub.2 P(O)--C(CH.sub.3)(OH)--P(O)(OH).sub.2.

Abstract: A color diffusion transfer photographic element containing a compound having a sulfinic acid group or a slat thereof is disclosed. The element is comprised of a photosensitive element and an alkaline processing composition element. The sufinic acid group or a salt thereof includes a compound represented by the general formula (Y-SO.sub.2).sub.n M wherein M is a hydrogen atom, an alkyl metal atom, an alkaline earth metal atom, an ammonium group, or an organic base; Y is an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group, and n is 1 or 2. By utilizing the compound within the processing solution it is possible to prevent the deterioration of processing composition which occurs when the material is stored for a long period of time.

Abstract: Photographic elements and diffusion transfer assemblages are described wherein a sufficient amount of a reflecting agent, such as titanium dioxide, is employed in the yellow dye image-providing material layer so that the layer is an effective yellow filter layer for good color reproduction.

Abstract: Photographic assemblages and processes are described wherein a stripping layer is employed to enable an image-receiving layer to be separated from the rest of the assemblage after processing. Each side of the stripping layer has a hydrophilic layer immediately adjacent thereto, only one of which contains a surfactant-like material having a hydrocarbon fatty tail of at least eight carbon atoms which is remote from a polar group, the material being present in an amount sufficient to enable a clean separation between the image-receiving layer and the portion of the assemblage containing the silver halide emulsion layer.Transparencies or prints which are less bulky and free from surface defects at the stripping layer interface can thereby be obtained from integral assemblages.

Abstract: A color diffusion transfer photographic element is disclosed. The element provides a transferred dye image in a mordant layer and includes a compound having recurrent units represented by the general formula (I): ##STR1## the substituents within the general formula (I) are defined within the specification. By utilizing the compound the images produced having improved preservability having specific improvements with respect to the elimination of yellow stains which are formed in white areas of the images after storage for a long period of time. Furthermore, the images formed do not deteriorate at high temperatures and the use of the compound does not decrease the D.sub.max in print images.

Abstract: There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.

Abstract: An optical barrier layer for use in reflection type image carrying media of the type wherein a thin transparent image receiving layer includes an image which is viewed through one side of the image receiving layer with ambient light that is reflected from a light scattering layer located on the other side of the image-receiving layer. The optical barrier layer is a thin, transparent layer located between the image receiving layer and the light scattering layer and operates to minimize nonlinear density effects of multiple internal reflections.

Abstract: Photographic assemblages and processes are described wherein a stripping layer is employed to enable an image-receiving layer to be separated from the rest of the assemblage after processing. Each side of the stripping layer has a hydrophilic layer immediately adjacent thereto, only one of which contains particulate material substantially insensitive to light and in a volume percentage of about 5 to about 75 percent of the hydrophilic material-particulate material mixture, so that upon separation, substantially all of the stripping layer will remain with the portion of the assemblage having the hydrophilic layer containing the particulate material.Transparencies or prints which are less bulky can thereby be obtained from integral assemblages.

Abstract: This invention relates to diffusion transfer processes and products wherein the transmission density of the pigmented processing composition layer is increased by employing an alkali earth metal salt to increase the light-absorbing ability of a carboxynaphthol phthalein optical filter agent within said processing composition layer. In another embodiment, a carboxyindole phthalein optical filter agent also is included in said processing composition layer, and a zinc or cadmium salt is employed to shift the spectral absorption of the carboxyindole phthalein into the green region of the visible spectrum. In a further embodiment, a calcium salt is employed in a viscous pigmented processing composition comprising a light-reflecting pigment, colloidal silica and a metal chelating agent, e.g., an alkylene polyamine polyacetic acid to stabilize the spreading characteristics of the composition.

Abstract: Photographic elements and assemblages are described employing positive-working redox dye-releasers, wherein the element contains an oxidant which is located between the support and the photosensitive portion thereof. The oxidant has an electrode potential of from about -200 mV up to about 1200 mV versus a saturated calomel electrode at a pH of about 5 to about 6. After processing, the oxidant reacts with the electron transfer agent to prevent it from reacting with the dye releaser which would otherwise cause further dye release. The reduced form of the oxidant is then substantially incapable of reducing the positive-working redox dye-releaser. D.sub.min stability is thereby improved.

Abstract: Photographic elements, assemblages and processes are described for producing a monochromatic dye image. The assemblage comprises:(a) a photosensitive element comprising a support having thereon a layer of nondiffusible dye image-providing material, a stripping layer, an opaque layer and a silver halide emulsion layer;(b) a transparent cover sheet; and(c) opaque processing composition for application between the element and cover sheet. A dye mordant layer may also be present on the element or cover sheet.After exposure and processing, the layer of nondiffusible dye image-providing material on a support is stripped away to provide a monochromatic retained dye image without the need for bleaching and fixing.

Abstract: A coupler containing in the coupling position a carbamoyloxy group ##STR1## upon oxidative coupling, releases a carbamic acid fragment that, in turn, is capable of thermally releasing ammonia or an amine. Such a carbamoyloxy substituted coupler and carbamic acid fragment are useful in imaging such as in photothermography and thermography. Ammonia or an amine released from the carbamic acid fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The carbamoyloxy substituted coupler also generally is a dye-forming coupler that reacts with the oxidized form of a color developing agent to form a dye. An image is produced in an exposed photothermographic material comprising the carbamoyloxy substituted coupler by thermal development. An image is produced in a thermographic material comprising the carbamoyloxy substituted coupler and a color developing agent by imagewise heating the thermographic material.

Abstract: Photographic assemblages, elements, receiving elements and cover sheets are described employing a novel timing layer comprising the following recurring units: ##STR1## wherein R.sup.1 is a straight or branched chain alkyl group of from 1 to about 10 carbon atoms or aralkyl group of from about 7 to about 10 carbon atoms;R.sup.2 is a substituted or unsubstituted aryl group of from 6 to about 12 carbon atoms;R.sup.3 is a straight or branched aliphatic group having from 1 to about 20 carbon atoms or an aromatic group having from about 6 to about 20 carbon atoms, the group being substituted with at least one free carboxylic acid group, free sulfonic acid group, free phosphoric acid group or salt thereof;x is from about 1 to about 30 weight percent; andy+z is from about 99 to about 70 weight percent, the ratio of y:z ranging from about 15:85 to about 70:30.The timing layer has a high activation energy and provides improved processing temperature latitude.

Abstract: A novel silver halide photographic element which contains a nondiffusible complex capable of releasing a diffusible, photographically useful material is disclosed.Said nondiffusible complex becomes active for ligand exchange upon reduction under alkalin conditions to release a diffusible, photographically useful material, said complex being represented by the following formula: ##STR1## wherein La is a quadridentate ligand group; Lb is a didentate ligand group; BALL is a ballast group; PHOTO is a photographically useful material group; Y is a counter ion; and r is the number of counter ions necessary for neutralizing the electric charge on the CO(III) complex.

Abstract: Photographic assemblages and processes are described wherein a certain stripping agent is employed to enable an image-receiving layer to be separated from the rest of the assemblage after processing. The stripping agent comprises a straight chain alkyl or polyethylene oxide perfluoroalkylated ester or perfluoroalkylated ether, and preferably has the following formula: ##STR1## wherein R.sup.1 is an alkyl or substituted alkyl group having from 1 to about 6 carbon atoms or an aryl or substituted aryl group having from about 6 to about 10 carbon atoms; ##STR2## R.sup.3 is H or R.sup.1 ; n is an integer of from about 4 to about 20; andx and y each independently represents an integer of from about 2 to about 50, andz represents an integer of from 1 to about 50.Less bulky black-and-white or color prints or transparencies can thereby be obtained from integral assemblages. Materials from the discarded layers may also be recycled.

Abstract: A direct positive type light sensitive silver halide photographic material is disclosed. At least one layer containing an unfogged internal latent image type silver halide emulsion, is provided on a support, and an internal latent image type silver halide emulsion having fog centers in silver halide grains, is incorporated in said layer or in another constituent layer of the photographic material. A dye image forming substance may be incorporated in the same layer or in a separate layer to form a color diffusion transfer type light sensitive photograhic material. The photographic materials present a positive image having a high maximum density and a low minimum density.

Abstract: Color prints are prepared in the form of retained images by the dye diffusion transfer process using a photographic recording material comprising in that order a transparent layer support, a light-sensitive element containing at least one silver halide emulsion layer and a non-diffusing color-providing compound associated thereto, a light-reflecting opaque layer and a mordant layer. The recording material is subjected to imagewise exposure through the transparent layer support. During development a colored moiety is released from the color-providing compound in imagewise distribution and transferred to the mordant layer. Silver and silver halide is removed by bleaching and fixing. The colored color-providing compounds retained in the light-sensitive element in imagewise distribution complementary to the transferred colored moiety form the color image visible through the transparent layer support against the light-reflecting background of the opaque layer.

Abstract: Photographic material and process suitable for producing by diffusion transfer a color image and comprising on a support at least two differently spectrally sensitive negative working silver halide emulsion layers (FIG. 3, layers 12, 14 and 16) and having operatively associated with each of said emulsion layers a different non-diffusing dye providing compound that is initially immobile in an alkali-permeable colloid medium and wherefrom by reduction in alkaline medium a dye or dye precursor can be split off in diffusible state, wherein at least one of said negative working silver halide emulsion layers is associated in water-permeable relationship with a visible light-sensitive direct-positive emulsion layer (FIG. 3, layers 13 and 15) whereby interimage effects can be obtained.

Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.

Abstract: Image transfer photographic assemblages, processes, compositions and cover sheets are described which employ a manganous compound. After processing, the manganous compound is capable of diffusing to the silver halide emulsion layer and a redox dye-releaser associated therewith to inhibit further dye release. Post-process D.sub.min stability is thereby improved.

Abstract: Photographic assemblages are described employing positive-working redox dye-releasers and a cover sheet containing an oxidant having an electrode potential of from about -200 mV up to about 1000 mV versus a saturated calomel electrode at a pH of about 5 to about 6. The oxidant is capable of oxidizing electron transfer agent in the system. The reduced form of the oxidant is incapable of reducing the positive-working redox dye-releaser. After processing, the oxidant reacts with the electron transfer agent to prevent it from reacting with the dye releaser which would otherwise cause further dye release. D.sub.min stability is thereby improved.

Abstract: Photographic assemblages and processes are described employing positive-working redox dye-releasers and a processing composition containing a ketal blocked quinone which is soluble therein. After processing, when the pH is lowered, the free quinone is released for reaction with residual electron transfer agent present in the assemblage to prevent it from reacting with the dye releaser, which would otherwise cause further dye release. D.sub.min stability is thereby improved.

Abstract: In a color photographic recording material for the dye diffusion transfer process a transparent layer support, a light sensitive element, a light-reflecting opaque layer and an image-receiving layer form in that order a non-disconnectable assembly of layers and the light-sensitive element contains at least one silver halide emulsion layer and associated therewith an electron donor compound and a non-diffusing reducible color-providing compound that when reduced liberates a diffusible dye under alkaline development conditions. The material provides "development control on viewing" when the first part, e.g. about 2 minutes, of total development is conducted in dark and is completed at ambient light.

Abstract: A process for preparing polymeric oximes and photographic processing compositions containing polymeric oximes are described. The polymeric oximes are prepared by a process which comprises: introducing into an aqueous polymerization medium a portion of a polymerizable monomer to be polymerized, said polymerizable monomer having the formula ##STR1## wherein R is hydrogen or methyl, R.sup.1 is hydrogen, alkyl of from 1 to 4 carbon atoms, benzyl or phenyl, R.sup.2 is alkyl of from 1 to 4 carbon atoms, benzyl or phenyl, alkylene is a divalent alkylene radical having 1 or 2 carbon atoms, and R.sup.

Abstract: Curve shape control, especially for lower scale contrast, of a photographic element is achieved by employing with the silver halide emulsion layer two nondiffusible redox dye-releasing compounds of different relative reactivities, the reactivity of the compound which is more reactive being at least 1.5 times the reactivity of the compound which is less reactive. Preferred compounds are ballasted sulfonamido compounds, each of which has a color-providing moiety attached thereto through a sulfonamido group which is alkali-cleavable upon oxidation. Preferred more reactive sulfonamido compounds have a N,N-disubstituted carbamoyl ballast group. The color-providing moieties can be (1) transferred imagewise to an image-receiving layer to provide a useful image, or (2) can be merely diffused out of the element to provide a retained image therein which can be treated to form a color transparency or a motion picture film.

Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formula ##STR1## wherein R.sup.1 is a monovalent organic radical; R.sup.2 is hydrogen or a monovalent organic radical; Z is a moiety that undergoes .beta.-elimination in aqueous alkaline solution and preferably is a moiety that undergoes .beta.-elimination in aqueous alkaline solution to release a photographically useful reagent; and n is an integer 3, 4 or 5.

Abstract: This invention relates to photographic products and processes employing silver halide solvent precursors of the formulae ##STR1## wherein R.sup.1 and R.sup.2, the same or different, each are hydrogen, alkyl, phenalkyl, phenyl or phenyl substituted with an electron-donating or electron-withdrawing group; R.sup.3 is alkyl, phenalkyl, phenyl or substituted phenyl; Z is --CN or --SO.sub.2 R.sup.4 wherein R.sup.4 is branched-chain alkyl, phenalkyl, phenyl or substituted phenyl; and n is an integer 3, 4 or 5.

Abstract: An image receptor element for the dye diffusion transfer process contains an image-receiving layer, which has increasing dye absorption capacity with increasing distance from the light-sensitive layers. Such an image-receiving layer may be obtained by use of mordants in concentrations which increase with increasing distance from the light-sensitive layers or by use of at least two mordants of different dye absorption capacity, the mordant of higher dye absorption capacity being arranged in a partial layer of the image-receiving layer further away from the light-sensitive layers. Such image receptor elements provide higher dye densities with lower total concentrations of mordants.

Abstract: Diffusion transfer film units and a diffusion transfer process operative therein are described which are capable of providing relatively high resolution monochromatic dye developer transfer images.

Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer for use with negative-working silver halide emulsions and positive-working redox dye-releasers. The outermost timing layer has a negative temperature coefficient and has a development accelerator associated therewith to increase the development of the silver halide emulsion at low temperatures. The timing layer next to the neutralizing layer has a greater penetration time by the alkaline processing composition so that the neutralizing layer is permeated only after silver halide development has been substantially completed. The temperature latitude of the system is thereby increased.

Abstract: A diffusion transfer color photographic element wherein (1) a light-sensitive sheet comprising a support having superposed thereon at least one silver halide emulsion layer having associated therewith a color image providing compound and (2) a cover sheet comprising a support having thereon at least one neutralizing layer and at least one neutralization timing layer are arranged so that they can contact each other with their supports remote the area of contact and which is so designed that a processing composition may be spread in a uniform layer between the light-sensitive sheet (1) and the cover sheet (2), further wherein a protective layer which consists essentially of a hydrophilic colloid is provided as the topmost layer of the light-sensitive sheet (1) and there is provided an ultraviolet absorbant-containing layer for light-sensitive sheet (1) adjacent the protective layer. The element exhibits improved storage stability.