Indolenic Cyanine Chromophore Patents (Class 430/270.21)
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Patent number: 8859184Abstract: A write-only-read-many type optical recording medium includes a substrate, an organic material layer having a light absorption function that is sufficient for recording in the recording/reproduction wavelength range, the organic material layer being situated on the substrate, and a reflection layer being situated on the organic material layer. The recording medium is configured to have a Low-to-High recording property and record with a laser having a wavelength that is no greater than 500 nm.Type: GrantFiled: July 28, 2005Date of Patent: October 14, 2014Assignee: Ricoh Company, Ltd.Inventor: Noboru Sasa
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Patent number: 8846298Abstract: A write-only-read-many type optical recording medium includes a substrate, an organic material layer having a light absorption function that is sufficient for recording in the recording/reproduction wavelength range, the organic material layer being situated on the substrate, and a reflection layer being situated on the organic material layer. The recording medium is configured to have a Low-to-High recording property and record with a laser having a wavelength that is no greater than 500 nm.Type: GrantFiled: November 8, 2010Date of Patent: September 30, 2014Assignee: Ricoh Company, Ltd.Inventor: Noboru Sasa
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Patent number: 8632947Abstract: The invention provides a near infrared absorption polymer comprising at least two different pendent infra-red chromophoric moieties covalently bonded to the backbone of an alkali-soluble resin, at least one of which is an indole cyanine dye and the other of which is a benz[e]-indole cyanine dye. When used in the coating of a heat sensitive positive working lithographic printing plate precursor the stabilization time needed after manufacture is significantly reduced, avoiding further conditioning processes before use. The precursors are preferably imagewise exposed with a near-infrared laser emitting at between 780 nm and 850 nm.Type: GrantFiled: November 8, 2005Date of Patent: January 21, 2014Assignee: Ipagsa Industrial, S.L.Inventors: Peter Jonathan Bentley, My T. Nguyen
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Patent number: 8350015Abstract: An objective of this invention is to extend the range of choosing organic dye compounds as radiation-absorbing agents in a variety of fields by providing a novel organic dye compound which absorbs short-wavelength visible radiation and exhibits a superior in optical resistance, solubility in solvents, and heat characteristics required in a novel field in which the organic dye compound is applied: The objective is attainable by providing a cyanine dye which has a specific structure and exhibits a major adsorption maximum at a wavelength longer than 400 nm in a solution.Type: GrantFiled: February 24, 2005Date of Patent: January 8, 2013Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku KenkyujoInventors: Yasushi Aizawa, Yoshinori Koyama, Ayashi Noguchi
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Patent number: 8252510Abstract: According to one embodiment, a write-once type information storage medium comprises an organic dye based recording material having sensitivity at a wavelength of 405 nm and at a recording wavelength in the range of 600 nm to 700 nm, wherein, when absorbance of a maximum absorption wavelength in the vicinity of 405 nm is defined as 1, the absorbance is 5% or more at any wavelength in the range of 600 nm to 700 nm.Type: GrantFiled: November 29, 2006Date of Patent: August 28, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Hideo Ando, Seiji Morita, Koji Takazawa, Yasuaki Ootera, Naoki Morishita, Kazuyo Umezawa
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Patent number: 8232042Abstract: According to one embodiment, a storage medium comprises a transparent resin substrate on which a groove is formed, a recording layer formed on the groove on the transparent resin substrate, the recording layer using an organic dye material and recording information with a light beam of 620 nm or less in wavelength, a reflection layer formed on the recording layer, and a prevention layer formed between the recording layer and the reflection layer, the prevention layer preventing degradation of characteristics of the reflection layer.Type: GrantFiled: March 30, 2006Date of Patent: July 31, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Tsukasa Nakai, Seiji Morita, Koji Takazawa, Yasuaki Ootera, Naoki Morishita, Kazuyo Umezawa, Hideo Ando
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Patent number: 8206806Abstract: A cyanine compound is represented by formula (I): A1: benzene or naphthalene ring. A3: 5- or 6-membered ring. R1, R2: hydrogen atom and the like. R7: an alkyl group and the like. R12: a substituent by formula (II) or (II?). R20: a hydrogen atom and the like. Anq-: a q-valent anion. q: 1 or 2; p: a coefficient for neutral charge. In formula (II): bond between L and T is a double, conjugated double, or triple bond. L: carbon atom. T: carbon, oxygen, sulfur, or nitrogen atom. x, y, z: 0 or 1. s: 0-4. R13: hydrogen atom and the like. R14, R15, and R16: hydrogen atom and the like. In formula (II?), the bond between L? and T? is a double or conjugated double bond. L?: carbon atom. T?: carbon, oxygen, nitrogen atom. s?: 0-4. Ring containing L? and T?: 5-membered ring, may contain a heteroatom.Type: GrantFiled: March 23, 2007Date of Patent: June 26, 2012Assignee: Adeka CorporationInventors: Toru Yano, Satoshi Yanagisawa, Yohei Aoyama, Koichi Shigeno
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Patent number: 8168282Abstract: The present invention relates to a trimethine cyanine represented by the formula (1): wherein each of the symbols are defined in the specification. The present invention also relates to a use of the above dimeric trimethine cyanine compound as a dye, which is used in an optic element, particularly a high density recordable optical media.Type: GrantFiled: October 19, 2008Date of Patent: May 1, 2012Assignee: Orgchem Technologies, Inc.Inventors: Chin Kang Sha, Cheng Fen Yang, Hsin Jen Lee
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Patent number: 8142981Abstract: According to one embodiment, a write-once type information storage medium comprises an organic dye based recording material having sensitivity at a wavelength of 405 nm and at a recording wavelength in the range of 600 nm to 700 nm, wherein, when absorbance of a maximum absorption wavelength in the vicinity of 405 nm is defined as 1, the absorbance is 5% or more at any wavelength in the range of 600 nm to 700 nm.Type: GrantFiled: April 12, 2006Date of Patent: March 27, 2012Assignee: Kabushiki Kaisha ToshibaInventors: Hideo Ando, Seiji Morita, Koji Takazawa, Yasuaki Ootera, Naoki Morishita, Kazuyo Umezawa
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Patent number: 8105750Abstract: Recording and reproducing characteristics and data saving reliability are secured in a write-once two-layer recording medium. A second recording layer from a side irradiated with light for recording and reproduction includes organic dye shown by a general formula of a chemical formula 3 described below (in the formula, R1 and R2 are alkyl groups of carbon number 1 to 4; Y1, Y2 respectively are organic groups independently; and X is Cl04, BF4, PF6, SbF6), and organic dye shown by a general formula of a chemical formula 4 described below (in the formula, R1, R4 are alkyl groups of carbon number 1 to 4; R2, R3 are alkyl groups of carbon number 1 to 4 or groups forming 3 to 6 membered rings by being coupled; Y1, Y2 respectively are organic groups independently; and X is Cl04, BF4, PF6, SbF6), to secure durability.Type: GrantFiled: January 26, 2007Date of Patent: January 31, 2012Assignees: Sony Corporation, Adeka CorporationInventors: Yutaka Wada, Masatsugu Suwabe, Toru Yano, Koichi Shigeno
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Patent number: 8092891Abstract: A cyanine compound is represented by: wherein, R11 and R12 each independently represent a hydrogen atom, a hydroxyl group, a halogen atom, a nitro group, a cyano group, an organic group having 1 to 30 carbon atoms, or a group represented by the following general formula (II), (II?), or (III); R13 and R14 each independently represent a hydrogen atom, an organic group having 1 to 30 carbon atoms, or a substituent represented by the following general formula (III); R11 and R12 may be connected together to form a ring structure; R19 represents a hydrogen atom or an organic group having 1 to 30 carbon atoms; R13 and R14 may be connected together to form a heterocycle; N—R13 may be connected together with a methylene group in a polymethine chain to form a heterocycle; Z00 is an organic group having 1 to 10 carbon atoms; m is 0 or 1; s is 2 to 8; Anq? represents an anion having a valence of q; q is 1 or 2; and p represents a coefficient for maintaining charge neutrality.Type: GrantFiled: July 10, 2007Date of Patent: January 10, 2012Assignee: Adeka CorporationInventor: Satoshi Yanagisawa
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Patent number: 8067080Abstract: Provided is an optical recording medium including, in sequence: a first substrate; a first information recording layer; an intermediate layer; a second information recording layer; and a second substrate having wobble convex portions on its surface, wherein information is recorded on or reproduced from the first information recording layer and second information recording layer by irradiation with a laser beam from a first information recording layer side, wherein the second information recording layer includes, over the second substrate, a light reflective layer, a dye recording layer, and an inorganic protective layer, wherein the inorganic protective layer has a thickness of 3 nm to 40 nm, and wherein the dye recording layer includes a cyanine compound expressed by General Formula (I) and a squarylium compound expressed by General Formula (II):Type: GrantFiled: March 14, 2007Date of Patent: November 29, 2011Assignee: Ricoh Company, Ltd.Inventors: Yuki Nakamura, Masahiro Hayashi, Satoshi Mizukami, Tohru Yashiro
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Patent number: 8029976Abstract: Disclosed is to provide with an optical recording medium of a write-once type in which an excellent recording characteristic can be obtained over low speed recording to high speed recording.Type: GrantFiled: October 24, 2005Date of Patent: October 4, 2011Assignees: Sony Corporation, Adeka CorporationInventors: Yutaka Wada, Masatsugu Suwabe, Junko Shimada, Toru Yano, Keiji Oya, Koichi Shigeno
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Patent number: 7935475Abstract: Disclosed herein are a near-infrared absorbing and color compensation film composition and a film using the film composition. The film composition comprises i) at least one colorant selected from the group consisting of an ionic compound of a near-infrared absorbing cyanine colorant cation having a maximum absorption wavelength in the range of 820 nm to 950 nm and a metal complex colorant anion, an ionic compound of a near-infrared absorbing diimmonium colorant cation having a maximum absorption wavelength in the range of 950 nm to 1,100 nm and a metal complex colorant anion, and an ionic compound of a selective visible light absorbing cyanine colorant cation having a maximum absorption wavelength in the range of 580 nm to 600 nm and a metal complex colorant anion, and ii) an adhesive; and a film using the film composition. When the film composition is used to produce an adhesive film or an antireflective composite film, the price of raw materials used and the number of production steps can be reduced.Type: GrantFiled: May 22, 2006Date of Patent: May 3, 2011Assignee: Cheil Industries, Inc.Inventors: Hwi Min Seo, Soo Jeong Lee
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Patent number: 7709181Abstract: Cyanine compounds represented by the general formula (I) which exhibit decomposition behavior suitable for the optical recording material to be used in optical recording layers of optical recording media for high-speed recording: (I) wherein A and B are each an optionally substituted benzene or naphthalene ring; X is O, S, Se, CR3R4, or NY; at least either of R1 and R2 is a group represented by the general formula (II) or (III) and when only either is a group represented thereby, the other is an organic group having 1 to 30 carbon atoms; R3 and R4 are each an organic group having 1 to 30 carbon atoms; Y is hydrogen or an organic group having 1 to 30 carbon atoms; at least either of Y1 and Y2 is a group represented by the general formula (IV) and when only either is a group represented thereby, the other is hydrogen or an organic group having 1 to 30 carbon atoms; Z is hydrogen, halogeno, or cyano; Anm? is an m-valent anion; m is an integer of 1 or 2; and p is a coefficient capable of keeping the electric charType: GrantFiled: September 21, 2005Date of Patent: May 4, 2010Assignee: Adeka CorporationInventors: Koichi Shigeno, Toru Yano
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Patent number: 7682773Abstract: The cyanine compound of the present invention is represented by general formula (I) below and suitable as an optical recording material used in a recording layer of optical recording media on which recording and play-back are conducted with laser beam. The cyanine compound of the present invention particularly exhibits appropriate thermal decomposition behavior to attain sensitivity compatible with high-speed recording.Type: GrantFiled: October 13, 2005Date of Patent: March 23, 2010Assignee: Adeka CorporationInventors: Mitsuhiro Okada, Toru Yano, Koichi Shigeno
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Patent number: 7674569Abstract: An optical recording material for use in an optical recording layer of an optical recording medium comprising the optical recording layer provided on a substrate, the optical recording material comprising a cyanine compound represented by general formula (I): wherein rings A and B each represent a substituted or unsubstituted benzene or naphthalene ring; X represents O, S, Se, CR3R4 or NY; one of R1 and R2 represents a specific group of formula (II) or (III), with the other representing a C1 to C30 organic group; R3 and R4 each represent a C1 to C30 organic group; Y, Y1, and Y2 each represent a hydrogen atom or a C1 to C30 organic group; Z represents a hydrogen atom, a halogen atom or a cyano group; Anm? represents an m-valent anion; m represents an integer of 1 or 2; and p represents a coefficient maintaining charge neutrality.Type: GrantFiled: June 7, 2005Date of Patent: March 9, 2010Assignee: Adeka CorporationInventors: Toru Yano, Koichi Shigeno
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Patent number: 7598360Abstract: A bisstyryl compound. The bisstyryl compound has formula (I): wherein Z1 and Z2 are benzene, naphthalene, or heterocyclic ring, R1 is H, C1-5 alkyl, hydroxyl, halogen atoms, or alkoxy, R2 is H, halogen atoms, C1-5 alkyl, nitro, ester, carboxyl, sulfo, sulfonamide, sulfuric ester, amide, C1-3 alkoxy, amino, alkylamino, cyano, C1-6 alkylsulfonyl, or C2-7 alkoxy carbonyl, R3, R4, R5, and R6 are H, halogen atoms, alkyl, aralkyl, or heterocyclic ring containing O, S, or N, or R3 and R4 are joined to a nitrogen atom or R5 and R6 are joined together to form a ring, R7 and R8 are H or alkyl, W is nitrogen with or without Z1 and Z2 or aromatic group without Z1 and Z2, Y is carbon, oxygen, sulfur, selenium, —NR, or —C(CH3)2, m is 1-3, n is 1-18, and X1 and X2 are anionic groups or anionic organometallic complexes.Type: GrantFiled: October 21, 2005Date of Patent: October 6, 2009Assignee: Industrial Technology Research InstituteInventors: Shin-Shin Wang, Chien-Wen Chen, Jong-Lieh Yang, Chii-Chang Lai, Hui-Ping Tsai, Wen-Ping Chu, Wen-Yih Liao, Chien-Liang Huang, Tzuan-Ren Jeng, Ching-Yu Hsieh, An-Tse Lee
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Patent number: 7598359Abstract: A bis(indolestyryl) compound. The bis(indolestyryl) compound has formula (I): wherein A and B comprise benzene, naphthalene, or heterocyclic ring containing O, S, or N, R1 and R1? are H, halogen, C1-5 alkyl, nitro, ester, carboxyl, sulfo, sulfonamide, amide, sulfo ester, C1-3 alkoxy, amino, alkylamino, cyano, C1-6 alkylsulfonyl, or C2-7 alkoxy carbonyl, R2, R2?, R3, and R3? comprise H, C1-6 alkyl, C6-18 aryl, C2-6 alkenyl, C3-6 cycloalkenyl, or C3-6 cycloalkyl, R4 is H, C1-5 alkyl, hydroxyl, halogen, or alkoxy, R5 and R5? comprise H, halogen, C1-5 alkyl, nitro, C1-3 alkoxy, amino, cyano, C1-6 alkylsulfonyl, or C2-7 alkoxy carbonyl, W comprises oxygen, sulfur, selenium, —NR, or —C(CH3)2, n is 1˜18 and Z1 and Z2 are different and comprise an anion or an anionic organometallic complex with +1 or +2 valence, wherein R bonded to nitrogen is C1-4 alkyl.Type: GrantFiled: September 1, 2005Date of Patent: October 6, 2009Assignee: Industrial Technology Research InstituteInventors: Shin-Shin Wang, Jong-Lieh Yang, Chii-Chang Lai, Hui-Ping Tsai, Wen-Ping Chu, Chien-Wen Chen, Chien-Liang Huang, Wen-Yih Liao, Ming-Chia Lee
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Patent number: 7553604Abstract: A cyanine compound represented by formula (I): wherein ring A and ring B each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted naphthalene ring; R1, R2, R3, and R4 each represent an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted benzyl group, or R1 and R2 are taken together, or R3 and R4 are taken together, to form a 3- to 6-membered ring, provided that at least one of R1, R2, R3, and R4 is a substituted benzyl group; Y1 and Y2 each represent an organic group having 1 to 30 carbon atoms; Anm? represents an m-valent anion; m represents an integer 1 or 2; and p represents a coefficient for maintaining overall charge neutrality.Type: GrantFiled: July 27, 2004Date of Patent: June 30, 2009Assignee: Adeka CorporationInventors: Toru Yano, Koichi Shigeno, Mitsuhiro Okada
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Patent number: 7449279Abstract: An optical information recording medium including a substrate in which at least one of a groove and a pit is formed; a recording layer located overlying the substrate and including a dye; and a reflection layer located overlying the recording layer, wherein the optical information recording medium has an absorbance curve with an absorbance L of from 10 to 40% against light having a wavelength ? of from 645 nm to 670 nm, a ratio (Lmax/Lmin) of a maximum absorbance Lmax of the absorbance curve to a minimum absorbance Lmin of from 1.0 to 2.0 at the wavelength range of from 645 nm to 670 nm, and a reflectance of from 45 to 85% against the light having a wavelength ? of from 645 nm to 670 nm.Type: GrantFiled: August 22, 2005Date of Patent: November 11, 2008Assignee: Ricoh Company, Ltd.Inventors: Tohru Yashiro, Soh Noguchi, Tatsuya Tomura
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Patent number: 7425401Abstract: An optical recording medium containing a cyanine dyes of formula: Where at least one pair of R1 & R2 and R3 & R4 are benzyl moieties, rings A and B are each a benzene or naphthalene ring, Y1 and Y2 are C 1-30 organic groups and Anm? is an m valent anion, present in an integer p.Type: GrantFiled: July 27, 2004Date of Patent: September 16, 2008Assignee: Adeka CorporationInventors: Toru Yano, Koichi Shigeno, Mitsuhiro Okada
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Publication number: 20080138740Abstract: The cyanine compound of the present invention is represented by general formula (I) below and suitable as an optical recording material used in a recording layer of optical recording media on which recording and play-back are conducted with laser beam. The cyanine compound of the present invention particularly exhibits appropriate thermal decomposition behavior to attain sensitivity compatible with high-speed recording.Type: ApplicationFiled: October 13, 2005Publication date: June 12, 2008Applicant: ADEKA CORPORATIONInventors: Mitsuhiro Okada, Toru Yano, Koichi Shigeno
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Patent number: 7094517Abstract: High sensitive organic dye-in-polymer (DIP) medium for write-once-read-many (WORM) optical discs with fluorescent reading. The medium consists of a fluorescent color means, capable of absorbing writing radiation produced by a laser, a compound capable of generating free radicals upon influence of heat produced by the writing radiation and a polymer capable of producing a translucent film enabling high quantum yield of the fluorescence induced in the color means. The color means can be selected from xanthene dyes of the eosine and rhodamine groups, acridine, oxazine, azine, peylene, violanthrone, cyanine, phtalocyanine, indigoide colors and porphyries. The free radicals generating compound can be chosen from the group of compounds comprising azo and diazoi compounds or peroxyde compounds. The film producing polymer can be selected from the group of compounds comprising cellulose ethers, vinyl resins or acrylic resins.Type: GrantFiled: May 13, 1999Date of Patent: August 22, 2006Assignee: D Data Inc.Inventors: Mark Alperovich, Eugene Levich, Irene Zuhl, Svetlana Makievskaya
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Patent number: 7078149Abstract: A method for fabricating an optical recording medium is provided. A dye layer is formed on a molded substrate by spin-coating. A reflection layer is formed on the dye layer by sputtering so that the optical disc has enough reflection rate. The dye layer comprises a cyanine type dye and an azo metal chelate compound selected from the formula (I): wherein M is a metal ion; R1 is a hydrogen atom, a linear or branched alkyl group containing 1 to 6 carbon atoms, amino group, alkyl amino group or toluidinyl group; R2 is a hydrogen atom, a hydroxyl group, a halogen atom, an ether group, an ester group or a linear or branched alkyl group containing 1 to 6 carbon atoms; R3 is a hydrogen atom or a linear or branched alkyl group containing 1 to 6 carbon atoms; R4 is a hydrogen atom, a halogen atom or a linear or branched alkyl group containing 1 to 6 carbon atoms; A1 is a heterocyclic derivative group constituted by carbon atoms and nitrogen atoms.Type: GrantFiled: October 3, 2002Date of Patent: July 18, 2006Assignee: Ritek CorporationInventors: Wen-Dar Liu, Nae-Jen Wang, Wan-Chun Chen, Biing-Hwang Lin, Hui-Jen Chen, Hsin-Te Kuo
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Patent number: 7008753Abstract: The present invention provides an optical recording medium including a recording layer and an optical reflection layer formed on a substrate. The recording layer contains at least one particular polymethine pigment selected from polymethine pigments having 1 to 4 carbons in the methine main chain, so as to obtain a sufficient recording sensitivity for a red wavelength range of light.Type: GrantFiled: March 4, 2004Date of Patent: March 7, 2006Assignee: Sony CorporationInventors: Shinichiro Tamura, Mitsuaki Oyamada
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Patent number: 6821708Abstract: This invention provides a data storage media comprising at least a cyanine-TCNQ complex dye having the structural formula: wherein Q and Q′ denote aromatic or polyaromatic, R1 and R2 are selected from the group consisting of alkyl, arylester, alkoxy, alkylthio, and alkoxythio etc., n represents an integer of 0, 1, 2, and 3, TCNQ-m represents 7,7′,8,8′-tetracyanoquinodimethane or its derivatives, and m is an integer of 1 or 2. The data storage media comprising the cyanine-TCNQ complex dye includes a reflection optical recording media and a non-reflection fluorescent optical recording media suiting the requirement.Type: GrantFiled: February 28, 2003Date of Patent: November 23, 2004Assignees: Industrial Technology Research Institute, National Tsing Hua UniversityInventors: Wen-Yih Liao, Ming-Chia Lee, Chien-Liang Huang, Chuen-Fuw Yan, Tzuan-Ren Jeng, Andrew Teh Hu, Chung-Chun Lee
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Publication number: 20040214107Abstract: The present invention provides an optical recording medium including a recording layer 2 and an optical reflection layer 3 formed on a substrate 1. The recording layer 2 contains at least one particular polymethine pigment selected from polymethine pigments having 1 to 4 carbons in the methine main chain, so as to obtain a sufficient recording sensitivity for a red wavelength range of light.Type: ApplicationFiled: March 4, 2004Publication date: October 28, 2004Inventors: Shinichiro Tamura, Mitsuaki Oyamada
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Publication number: 20040197705Abstract: A cyanine compound of formula (I), an optical filter containing the cyanine compound, and an optical recording material containing the cyanine compound which is used to form an optical recording layer of an optical recording medium: 1Type: ApplicationFiled: March 30, 2004Publication date: October 7, 2004Applicant: ASAHI DENKA CO., LTD.Inventors: Masaaki Shimizu, Koichi Shigeno, Toru Yano
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Publication number: 20040161701Abstract: Disclosed are novel trimethine cyanine dyes, light absorbents, light-resistant improvers, and optical recording media which comprise the trimethine cyanine dyes. The cyanine dyes exert satisfactory solubility and heat resistance when used in high-density optical recording media.Type: ApplicationFiled: February 5, 2004Publication date: August 19, 2004Applicant: KABUSHIKI KAISHA HAYASHIBARA SEIBUTSU KAGAKU KENYUJOInventors: Ayako Hohsaka, Dai Matsuura, Toshio Kawata, Shigeo Yasui
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Publication number: 20040142278Abstract: An optical recording medium dye is disclosed.Type: ApplicationFiled: January 9, 2004Publication date: July 22, 2004Inventors: Chao-Nan Kuo, Mei-Jung Hu
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Patent number: 6743568Abstract: Optical recording media using mixtures of benzoindolenic trimethine cyanine dyes, where the first benzoindolenic trimethine cyanine dye bears a heterocyclic azo dye metal complex as the counterion and the second benzoindolenic trimethine cyanine dye has a different type of counterion. This combination of these benzoindolenic trimethine cyanine dyes coated on a substrate results in high density media, where the dyes have a high solubility and heat resistance.Type: GrantFiled: February 12, 2001Date of Patent: June 1, 2004Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku KenkyujoInventors: Ayako Hohsaka, Dai Matsuura, Toshio Kawata, Shigeo Yasui
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Patent number: 6727041Abstract: Optical recording media comprising a base (1), a recording layer (2) formed thereon, and a reflecting layer (3) formed on the layer (2), wherein the recording layer (2) contains at least one kind of specified dyes selected from among polymethine dyes having 1 to 4 carbon atoms in the main methine chain to secure a sufficient recording sensitivity to a light in the red wavelength region.Type: GrantFiled: February 7, 2000Date of Patent: April 27, 2004Assignee: Sony CorporationInventors: Shinichiro Tamura, Mitsuaki Oyamada
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Publication number: 20030138729Abstract: This invention provides a data storage media comprising at least a cyanine-TCNQ complex dye having the structural formula: 1Type: ApplicationFiled: February 28, 2003Publication date: July 24, 2003Inventors: Wen-Yih Liao, Ming-Chia Lee, Chien-Liang Huang, Chuen-Fuw Yan, Tzuan-Ren Jeng, Andrew Teh Hu, Chung-Chun Lee
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Patent number: 6589706Abstract: A cyanine dye (I) for using in high density optical disc recording medium, having the following structure: in which R1 represents R2 represents and alkyl with C1-C18 or X− represents an acid anion. This cyanine dye is suitable for use as a &lgr;=500 nm−650 nm visible light-absorbing organic dye useful as a high density optical disc recording medium.Type: GrantFiled: November 22, 2000Date of Patent: July 8, 2003Assignees: Industrial Technology Research Institute, National Tsing-Hua UniversityInventors: Wen-Yih Liao, Andrew Teh Hu, Chien-Liang Huang, Huei-Wen Yang, Der-Ray Huang, Ding-Yih Hu, Ming-Chia Lee, Hong-Ji Lee
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Patent number: 6582881Abstract: An optical recording element having a transparent substrate and on the surface of said substrate, a recording layer, a light reflecting layer is disclosed. The recording layer comprises (i) a metallized azo ether dye having an azo group linking a substituted 3-hydroxypyridine nucleus to a phenyl nucleus wherein the phenyl nucleus has an ether substituent ortho to the azo group and said phenyl nucleus is free of strong electron withdrawing groups and (ii) a cyanine dye. The recording layer also has, when unrecorded a refractive index, at a selected wavelength from 400 to 660 nm, comprising a real part (n) greater than 1.8 and an imaginary part (k) less than 0.2.Type: GrantFiled: February 20, 1998Date of Patent: June 24, 2003Assignee: Eastman Kodak CompanyInventors: Derek D. Chapman, Ann L. Carroll-Lee, Csaba A. Kovacs
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Publication number: 20030068577Abstract: This invention is to provide a kind of cyanine-TCNQ complex dyes mixture (II, III, and IV) used as the data storage media having the structural formula (I): 1Type: ApplicationFiled: July 31, 2001Publication date: April 10, 2003Inventors: Wen-Yih Liao, Chien-Liang Huang, Chuen-Fun Yan, Huei-Wen Yang, Tzuan-Ren Jeng, Der-Ray Huang, Andrew Teh Hu, Ming-Chia Lee, Chung-Chun Lee
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Patent number: 6531261Abstract: An optical information recording disc showing good recording characteristics is prepared by the steps of coating a dye solution of a laser light-sensitive dye in a fluorinated cyclic alkane or alkene on a transparent substrate disc and drying the coated dye solution. The fluorinated cyclic alkane or alkene can be employed in combination with other organic solvents.Type: GrantFiled: May 26, 2000Date of Patent: March 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihisa Usami, Yoshio Inagaki
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Patent number: 6506539Abstract: A complex of a dye cation and an anionic TCNQ derivative of the formula (I): in which [Dye]+ is a dye cation, L1 is a linking group, R1 is a substituent group, p is an integer of 1-4, and r is an integer of 0-3 under the condition of 1<p+r<4, is favorably employable as a dye compound for preparing a recording layer of CD-R or DVD-R.Type: GrantFiled: April 6, 2001Date of Patent: January 14, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichi Morishima, Takashi Usami
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Publication number: 20030008234Abstract: Optical data carrier comprising a preferably transparent substrate which may, if desired, have previously been coated with one or more reflection layers and to whose surface a light-writeable information layer, if desired one or more reflection layers and if desired a protective layer or a further substrate or a covering layer have been applied, which can be written on or read by means of blue, red or infrared light, preferably laser light, where the information layer comprises a light-absorbent compound and, if desired, a binder, characterized in that at least one cyanine dye is used as light-absorbent compound.Type: ApplicationFiled: March 20, 2002Publication date: January 9, 2003Inventors: Horst Berneth, Friedrich-Karl Bruder, Wilfried Haese, Rainer Hagen, Karin Hassenruck, Serguei Kostromine, Peter Landenberger, Rafael Oser, Thomas Sommermann, Josef-Walter Stawitz, Thomas Bieringer
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Publication number: 20020150030Abstract: An optical information recording medium recordable at a high density two times or more higher than that of currently-used CD-Rs by using a material having optimum optical characteristics as an organic dye material of a recording layer. The optical information recording medium comprises a recording layer on a transparent substrate having a spiral pregroove formed thereon, wherein the track pitch Tp of the pregroove is 1.0 &mgr;m≦Tp≦1.2 &mgr;m and the optical phase difference &Dgr;S is 0.15≦&Dgr;S≦0.55.Type: ApplicationFiled: April 17, 2002Publication date: October 17, 2002Inventors: Yoshikazu Takagishi, Atsuo Shimizu, Ryuichi Sunagawa, Keiichi Ida, Mitsuo Sekiguchi, Isao Matsuda
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Patent number: 6413607Abstract: The present invention provides organic dye compounds which exert excellent recording characteristics in high-density optical recording media, and uses thereof. The present invention solves the objects of the present invention by providing non-symmetric trimethine cyanine dyes having a specific structure and properties, light absorbents and optical recording media comprising the cyanine dyes, and a process for preparing the cyanine dye comprising a step of reacting either 3,3-dimethyl-5-nitroindolium compounds or 3,3-dimethyl-5-sulfonamideindolium compounds, which have a reactive methyl group or an appropriate leaving group, with 3,3-dimethylbezoindolium compounds, which have a reactive methyl group or an appropriate leaving group.Type: GrantFiled: December 5, 2000Date of Patent: July 2, 2002Assignee: Kabushiki Kaisha Hayashibara Seibutsu Kagaku KenkyujoInventors: Chiaki Kasada, Yoshie Hata, Toshio Kawata, Shigeo Yasui
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Publication number: 20020075793Abstract: There is disclosed an optical recording medium having at least a recording layer provided on a light-transmissive substrate having grooves and lands with prepits, wherein said lands are generally rectangular or trapezoidal in cross section having a top surface and sidewalls, as well as a specified land height (h1), and said prepits are formed in a land in the center area of the land in a width direction thereof, and spaced from the adjacent grooves by boundary walls of a specified height (h2). The optical recording medium permits address information and disc rotation control information to be accessed accurately even if a track pitch is small, and which still can be manufactured efficiently, with the added capability of signal recording in high density and reproduction of high-quality signals.Type: ApplicationFiled: September 12, 2001Publication date: June 20, 2002Applicant: TDK CorporationInventor: Syuji Tsukamoto
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Patent number: 6398981Abstract: The present invention is concerned with photopolymer materials sensitive to infrared, near infrared, red and green light radiation for initiating polymerization and to applications of such photopolymer, like holographic polymer dispersed liquid crystal (H-PDLC) or reversible dye doped photopolymer (RDDP) materials, for making optical devices. The invention relates to holographic polymer dispersed liquid crystal and reversible dye materials having improved electrical and optical switching properties.Type: GrantFiled: February 14, 2000Date of Patent: June 4, 2002Assignee: Universite LavalInventors: Tigran Galstian, Amir Tork
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Patent number: 6383722Abstract: An object of the invention is to provide a method for preparing an optical recording medium, featuring a high production yield, a reduced loss and a high utilization of dye solution, and ensuring to produce media of consistent quality even by continuous coating as well as an optical recording medium. The object is achieved by a method for preparing an optical recording medium, comprising the step of applying a solution of a dye in a solvent onto a resin substrate to form a dye film, wherein the solvent of the dye solution is a mixture of tetrafluoropropanol and/or octafluoropentanol with an aliphatic saturated alcohol of 1 to 4 carbon atoms, and a recording layer is formed by applying the dye solution.Type: GrantFiled: May 26, 1999Date of Patent: May 7, 2002Assignee: TDK CorporationInventors: Masahiro Shinkai, Atsushi Monden
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Publication number: 20020037474Abstract: A high-density recordable optical recording disk with a cyanine dye mixture as a recording layer. The cyanine dye mixture at least comprises cyanine dye I and cyanine dye II.Type: ApplicationFiled: December 1, 2000Publication date: March 28, 2002Inventors: Wen-Yih Liao, Andrew Teh Hu, Chien-Liang Huang, Huei-Wen Yang, Yun-Chiao Chen, Wen-Hsin Yen, Tzuan-Ren Jeng, Der-Ray Huang, Ding-Yih Hu, Ming-Chia Lee
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Patent number: 6361922Abstract: The present invention discloses optical recording elements having optical recording layers containing tetra dyes. The dyes have metallized azo dianionic dye with cationic dye counterions. The recording layer has a thickness from 225 to 300 nm.Type: GrantFiled: October 16, 1996Date of Patent: March 26, 2002Assignee: Eastman Kodak CompanyInventors: Derek David Chapman, James C. Fleming, Ramanuj Goswami, Csaba Andras Kovacs
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Publication number: 20020025491Abstract: A complex of a dye cation and an anionic TCNQ derivative of the formula (I): 1Type: ApplicationFiled: April 6, 2001Publication date: February 28, 2002Inventors: Shinichi Morishima, Takashi Usami
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Patent number: 6346364Abstract: An optical information recording medium comprising a light transmitting substrate, a light absorptive layer containing at least one light absorbing substance formed on the substrate and a light reflective layer made of a metal film formed on the light absorptive layer, wherein an optical parameter represented by &rgr;=nabsdabs/&lgr; wherein nabs is the real part of the complex refractive index of the light absorptive layer, dabs is the average thickness of the light absorptive layer and &lgr; is the wavelength of a reading laser beam, is 0.6<&rgr;<1.6.Type: GrantFiled: June 14, 2000Date of Patent: February 12, 2002Assignee: Taiyo Yuden Co., Ltd.Inventors: Emiko Hamada, Yuji Arai, Yosikazu Takagisi, Takashi Ishiguro
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Publication number: 20010044074Abstract: Disclosed are novel trimethine cyanine dyes, light absorbents, light-resistant improvers, and optical recording media which comprise the trimethine cyanine dyes. The cyanine dyes exert satisfactory solubility and heat resistance when used in high-density optical recording media.Type: ApplicationFiled: February 12, 2001Publication date: November 22, 2001Inventors: Ayako Hohsaka, Dai Matsuura, Toshio kawata, Shigeo Yasui