Using Specified Radiation-sensitive Composition Other Than A Nominal Sensitized Polyvinyl Alcohol Patents (Class 430/28)
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Patent number: 4324850Abstract: In forming a fluorescent screen for a color picture tube having triads of phosphor materials of the three primary colors arranged in a predetermined pattern on the inner surface of a panel, a photosensitive film which exhibits stickiness when exposed to a threshold amount of light is formed on the inner surface of the panel. Locations of the photosensitive film where the three color phosphor materials respectively occupy are exposed to light from a light source through a shadow mask mounted to the panel. The amount of exposure light for a first color phosphor material is the threshold or above and that for second and third phosphor materials is below the threshold. After completion of the light exposures for the first to third color phosphor materials through the shadow mask, the shadow mask is dismounted from the panel and the first color phosphor material is deposited onto the photosensitive film.Type: GrantFiled: February 28, 1980Date of Patent: April 13, 1982Assignee: Hitaci, Ltd.Inventors: Yoshifumi Tomita, Masahiro Nishizawa, Hiroshi Yokomizo, Hiromitu Nakai
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Patent number: 4318971Abstract: The photosensitive resin which exhibits stickiness by photo-reaction is added with a binder which does not substantially raise dark reaction, and a resultant mixture is applied onto the inner surface of face panel of the color picture tube to form a film. Portion of the film where powdery material is going to be applied is exposed to light and rendered sticky. Phosphor powder, when used as the powdery material, is applied to the sticky portion and adhered thereto to form a fluorescent screen.Type: GrantFiled: February 12, 1981Date of Patent: March 9, 1982Assignee: Hitachi, Ltd.Inventors: Masahiro Nishizawa, Kiyoshi Miura, Hiroshi Yokomizo, Osamu Sasaya, Hajime Morishita, Shoichi Uchino
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Patent number: 4288513Abstract: To accelerate printing of resist materials on a CRT color panel, an additive is incorporated into the resist to enhance cross-linking upon exposure to actinic radiation.Type: GrantFiled: April 5, 1978Date of Patent: September 8, 1981Assignee: GTE Laboratories IncorporatedInventors: Kurt B. Kilichowski, Peter Cukor, Charles Brecher
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Patent number: 4284694Abstract: A layer of an aqueous solution containing polyvinyl alcohol and a zirconyl compound is applied to a clean glass surface and dried to produce a precoating thereon. A subsequently-applied phosphor-photobinder coating thereon is exposed to a light image and then developed with a turbulent aqueous liquid. The phosphor-photobinder coating exhibits improved adherence to the surface during the developing step due to the presence of the precoating.Type: GrantFiled: April 25, 1980Date of Patent: August 18, 1981Assignee: RCA CorporationInventor: Stanley A. Harper
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Patent number: 4276363Abstract: A process for forming a phosphor screen of a color picture tube comprising forming a thin layer using a photosensitive composition which contains an aromatic diazonium salt as a photosensitive component and produces tackiness by exposure to actinic light on the surface of the substrate and contacting the tackified thin layer after exposure to light with phosphor particles to form each phosphor layer for emitting color is improved by using as the phosphor particles those coated with at least one surface coating material selected from the group consisting of Zn(OH).sub.2, Zn.sub.3 (PO.sub.4).sub.2 and AlPO.sub.4 in shortening the contact time between the thin layer and the phosphor particles.Type: GrantFiled: October 19, 1979Date of Patent: June 30, 1981Assignees: Hitachi, Ltd., Kasei Optonix, Ltd.Inventors: Toshikatsu Manabe, Saburo Nonogaki, Hajime Morishita, Shoichi Uchino, Yoshifumi Tomita, Masahiro Nishizawa, Hiroshi Yokomizo, Susumu Ohmatoi
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Patent number: 4273842Abstract: A patternwise coated powder layer can be formed by a process comprising the steps of coating a photosensitive composition, which contains an aromatic diazonium salt as a photosensitive component and becomes sticky by exposure, onto the surface of a substrate to form a thin layer, subjecting the thin layer to patternwise exposure with actinic radiation to produce stickiness at the exposed area, and then contacting powder particles with the thin layer after exposure to make the thin layer to accept the powder particles according to the powder acceptability of the thin layer. According to this process, for example, the phosphor screen of a color picture tube can simply be produced.LIST OF PRIOR ART (37 CFR 1.56 (a))The following reference is cited to show the state of the art:Japanese Patent Laid-Open Publication No.Type: GrantFiled: April 11, 1978Date of Patent: June 16, 1981Assignee: Hitachi, Ltd.Inventors: Saburo Nonogaki, Hajime Morishita, Michiaki Hashimoto, Toshikatsu Manabe, Yoshifumi Tomita, Masahiro Nishizawa
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Patent number: 4271246Abstract: A method for producing a multicolor optical filter, which comprises exposing a photographic material comprising a support and at least one black-and-white silver halide emulsion layer to light through a first pattern; developing the exposed emulsion layer with a first coupler-containing color developer to form a pattern of a first dye; then exposing an unexposed portion of said emulsion layer to light through a second pattern; developing the exposed area with a second coupler-containing color developer to form a pattern of a second dye; optionally repeating exposure and development to form patterns containing dyes of third and subsequent colors, thereby to form color patterns of at least two colors; and subjecting the product to a silver removal treatment after the final color development step.Type: GrantFiled: June 28, 1979Date of Patent: June 2, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Masamichi Sato, Kenji Matsumoto
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Patent number: 4269918Abstract: A strongly fixed patternwise coated powder layer is formed on a substrate by subjecting a thin layer of photo-sensitive composition containing an aromatic diazonium salt as a photo-sensitive component capable of becoming sticky due to the formation of a photolytic reaction product of the salt by a patternwise light exposure, thereby making the light-exposed part of the thin layer sticky, bringing the thin layer in contact with powdery grains, thereby forming a powder-containing coating layer, and contacting the powder-containing coating layer with a powdery material that reacts with the photolytic product, thereby forming a water-insoluble or slightly water-soluble solid material to fix the powdery grains to the substrate.Type: GrantFiled: August 3, 1979Date of Patent: May 26, 1981Assignee: Hitachi, Ltd.Inventors: Saburo Nonogaki, Hajime Morishita, Shoichi Uchino, Toshikatsu Manabe
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Patent number: 4268594Abstract: A method of manufacturing a fluorescent screen for color picture tubes comprises applying to the tube front plate a continuous sensitized filter layer and exposing it, applying a continuous sensitized fluorescent layer and exposing it through a mask and removing the unexposed parts of the fluorescent layer and the filter layer therebeneath by washing.Type: GrantFiled: April 17, 1980Date of Patent: May 19, 1981Inventors: Eberhard Gesswein, Werner Moller
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Patent number: 4263385Abstract: A method for the manufacture of multi-colored microlithographic displays especially fluorescent screens for cathode ray tubes is provided in which a film of a positive phototackifiable polyacetylene sulfone polymer is applied to the substrate of the display. The film is then exposed in predetermined areas with a sufficient amount of radiation to tackify the exposed areas. The exposed areas are then contacted with a pigment or phosphor which is desired to be applied to the exposed area and it selectively adheres to the exposed areas. The exposure and dusting are repeated for each application of different color pigments, toners or phosphors.Type: GrantFiled: March 6, 1980Date of Patent: April 21, 1981Assignee: RCA CorporationInventor: Thomas R. Pampalone
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Patent number: 4263386Abstract: A method for the manufacture of multi-colored microlithographic displays especially fluorescent screens for cathode ray tubes is provided in which a film of an olefin sulfone polymer is applied to the substrate of the display. The film is then exposed in predetermined areas with a sufficient amount of radiation to depolymerize and lower the melting point of the polymer in the exposed areas. The film is then heated to a temperature above the softening point of the exposed polymer but below the softening point of unexposed polymer and contacted with the pigment or phosphor which is desired to be applied which selectively adheres to the exposed areas. The exposure and dusting are repeated for each application of different color pigments, toners or phosphors.Type: GrantFiled: March 6, 1980Date of Patent: April 21, 1981Assignee: RCA CorporationInventors: Pabitra Datta, Nitin V. Desai
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Patent number: 4255504Abstract: Additions of fluorescein or a fluorescein salt and a diol to a photosensitized polymeric material increase the photosensitivity thereof in a method for photodepositing a luminescent-screen structure for a cathode-ray tube.Type: GrantFiled: July 23, 1979Date of Patent: March 10, 1981Assignee: RCA CorporationInventor: David F. Hakala
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Patent number: 4254197Abstract: When a low molecular weight dihydric or trihydric alcohol is added to a photoresist composition comprising a water-soluble polymer substance and a bisazide photo-crosslinking agent, the fluidity of the composition is improved and the drying speed is moderately retarded and it enables the formation of a photoresist layer having a uniform film thickness and uniform drying degree. The said alcohol is exemplified by ethylene glycol, glycerol, etc. and is preferably added in an amount of 5-300 parts by weight per 100 parts by weight of the water-soluble polymer substance.Type: GrantFiled: December 18, 1978Date of Patent: March 3, 1981Assignee: Hitachi, Ltd.Inventors: Kiyoshi Miura, Naomitsu Watanabe, Yoshifumi Tomita
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Patent number: 4247612Abstract: In a method of forming a fluorescent screen on the inner surface of a face plate of a color picture tube wherein a film of photosensitive composition consisting essentially of a diazonium salt, the portions of the films to be deposited with phosphors are exposed to light through a color selection electrode so as to impart sticky property to the portions by a photoreaction and moisture in atmosphere and then a powder of phosphors is deposited by utilizing the sticky property, a photosensitive binder is incorporated into photosensitive film which undergoes a cross-linkage reaction with the photosensitive composition, thus rendering the mixture insoluble in water.Type: GrantFiled: August 8, 1979Date of Patent: January 27, 1981Assignee: Hitachi, Ltd.Inventors: Masahiro Nishizawa, Hiroshi Yokomizo, Yoshifumi Tomito, Saburo Nonogaki, Toshikatsu Manabe
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Patent number: 4245020Abstract: A method of making a display screen for a color television display tube in which a photoconductive layer on the window portion of the tube is provided with a uniform charge which may be either positive or negative. A charge pattern is then formed on that layer by scanning it with an electron beam passing through an apertured color selection electrode. The energy of the beam is such that the average depth of penetration of the electrons is greater than the thickness of the photoconductive layer so that the charge disappears at the regions struck by the beam. The remaining charge pattern is developed with a suspension of charged phosphor particles. By repeating this process, patterns of red, green and blue luminescent phosphor particles can be successively provided to form the display screen. It is also possible to scan the layer simultaneously or successively by three electron beams and to develop the resultant charge pattern with a light-absorbing pigment.Type: GrantFiled: February 26, 1979Date of Patent: January 13, 1981Assignee: U.S. Philips CorporationInventor: Jacob van den Berg