Electron Beam Imaging Patents (Class 430/296)
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Patent number: 12243681Abstract: A system and method for providing and programming a programmable inductor is provided. The structure of the programmable inductor includes multiple turns, with programmable interconnects incorporated at various points around the turns to provide a desired isolation of the turns during programming. In an embodiment the programming may be controlled using the size of the vias, the number of vias, or the shapes of the interconnects.Type: GrantFiled: July 27, 2023Date of Patent: March 4, 2025Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chen-Hua Yu, Mirng-Ji Lii, Hao-Yi Tsai, Hsien-Wei Chen, Hung-Yi Kuo, Nien-Fang Wu
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Patent number: 12242189Abstract: A semiconductor photoresist composition includes an organotin compound represented by Chemical Formula 1, and a solvent. A method for preparing the same, and a method of forming patterns utilizing the same are disclosed. Specific details of Chemical Formula 1 are as defined in the specification.Type: GrantFiled: November 10, 2021Date of Patent: March 4, 2025Assignee: Samsung SDI Co., Ltd.Inventor: Kyungsoo Moon
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Patent number: 12235580Abstract: A method for producing an ion-exchange resin having a water content of 5% by weight or less, a method for producing a lithography coating film forming-composition using the ion-exchange resin, and a method for washing the ion-exchange resin. The methods include the step of passing an organic solvent having a water content of 150 ppm or less through an ion-exchange resin precursor having a water content of 40% by weight or more, where a dehydration efficiency defined by the following equation is 5 or more: Dehydration efficiency=Dehydration rate (%)/[Weight of the organic solvent used per unit weight of the ion-exchange resin precursor (kg/kg)×Washing time (h)].Type: GrantFiled: June 11, 2021Date of Patent: February 25, 2025Assignee: NISSAN CHEMICAL CORPORATIONInventors: Takumi Oya, Hiroki Yamaguchi, Suguru Sassa
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Patent number: 12235578Abstract: Organometallic solutions have been found to provide high resolution radiation based patterning using thin coatings. The patterning can involve irradiation of the coated surface with a selected pattern and developing the pattern with a developing agent to form the developed image. The patternable coatings may be susceptible to positive-tone patterning or negative-tone patterning based on the use of an organic developing agent or an aqueous acid or base developing agent. The radiation sensitive coatings can comprise a metal oxo/hydroxo network with organic ligands. A precursor solution can comprise an organic liquid and metal polynuclear oxo-hydroxo cations with organic ligands having metal carbon bonds and/or metal carboxylate bonds.Type: GrantFiled: June 2, 2022Date of Patent: February 25, 2025Assignee: Inpria CorporationInventors: Stephen T. Meyers, Douglas A. Keszler, Kai Jiang, Jeremy T. Anderson, Andrew Grenville
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Patent number: 12234374Abstract: In a first aspect, a polymer composition includes a first polymer derived from a soluble polymer composition having an imide group and a Tg reducing compound having an amine group. The first polymer has a glass transition temperature that is lower than a second polymer derived from the same soluble polymer composition, but without a Tg reducing compound having an amine group. In a second aspect, a coating solution includes a soluble polymer having an imide group and a Tg reducing compound having an amine moiety that can be an amine or a first masked amine that can be converted to an amine, wherein the first masked amine can be chemically converted, thermally converted, photo-converted or dissociated.Type: GrantFiled: February 13, 2023Date of Patent: February 25, 2025Assignee: DUPONT ELECTRONICS, INC.Inventors: Kostantinos Kourtakis, Michael Mulzer, Benjamin Samson, Michael Thomas Kwasny
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Patent number: 12210287Abstract: An object of the present invention is to provide a resist pattern forming method that has excellent pattern forming properties and generates few residues and a semiconductor chip manufacturing method. The resist pattern forming method according to an embodiment of the present invention has a step A of forming a film on a substrate by using an actinic ray-sensitive or radiation-sensitive resin composition containing a photoacid generator and a resin whose polarity is increased by the action of an acid, a step B of exposing the film, step C of developing the exposed film by using an alkali developer, a step D of washing the developed film by using water, and a step E of washing the film washed in the step D by using a chemical liquid containing an alcohol-based solvent, in which the alkali developer contains a quaternary ammonium salt.Type: GrantFiled: September 2, 2021Date of Patent: January 28, 2025Assignee: FUJIFILM CorporationInventors: Tetsuya Kamimura, Yukihisa Kawada, Masahiro Yoshidome
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Patent number: 12189299Abstract: A digital lithography system includes adjacent scan regions, exposure units located above the scan regions, a memory, and a processing device operatively coupled to the memory. The exposure units include a first exposure unit associated with a first scan region and a second exposure unit associated with a second scan region. The processing device is to initiate a digital lithography process to pattern a substrate disposed on a stage in accordance with instructions. The processing device is to further perform a first pass of the first exposure unit over a stitching region at an interface of the first scan region and the second scan region at a first time. The processing device is to further perform a second pass of the second exposure unit over the stitching region at a second time that varies from the first time by less than forty seconds.Type: GrantFiled: February 28, 2023Date of Patent: January 7, 2025Assignee: Applied Materials, Inc.Inventors: Ying-Chiao Wang, Thomas L Laidig, Chun-Chih Chuang, Frederick Lie, Chen-Yuan Hsieh, Chun-Cheng Yeh
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Patent number: 12099296Abstract: A method for producing an optical element includes: forming a resist layer on a main surface of a substrate; forming a pattern region in the resist layer; forming a groove; forming a dielectric layer covering the pattern region; and forming an optical functional portion. The pattern region is formed in the resist layer. The groove is formed in a portion corresponding to a periphery of the pattern region as viewed in a direction orthogonal to the main surface. A dielectric is deposited to form the dielectric layer. After the dielectric layer covering the pattern region is formed, the resist layer is removed to form the optical functional portion at a position where the pattern region is disposed on the main surface. The optical functional portion is made of the dielectric.Type: GrantFiled: April 9, 2021Date of Patent: September 24, 2024Assignee: HAMAMATSU PHOTONICS K.K.Inventors: Soh Uenoyama, Hiroki Kamei, Kazuyoshi Hirose
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Patent number: 12099304Abstract: An electron beam lithography (Ebeam) method for a wafer having alignment and device layers with a design alignment. The Ebeam method includes executing an Ebeam scan of predefined length and resolution based on the design alignment over a pattern edge of the device layer, generating a signal from reflections of the Ebeam scan off the pattern edge, determining an offset of the device layer relative to the alignment layer from a comparison of the signal and the design alignment and applying the offset to the design alignment to obtain an actual measurement of Ebeam alignment.Type: GrantFiled: October 31, 2023Date of Patent: September 24, 2024Assignee: International Business Machines CorporationInventors: Simon Dawes, Ernst Kratschmer
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Patent number: 12085858Abstract: A method for enhancing a photoresist profile control includes applying a photoresist layer comprising a photoacid generator on an underlayer disposed on a material layer, exposing a first portion of the photoresist layer unprotected by a photomask to light radiation in a lithographic exposure process, providing a thermal energy to the photoresist layer in a post-exposure baking process, applying an electric field or a magnetic field while performing the post-exposure baking process, and drifting photoacid from the photoresist layer to a predetermined portion of the underlayer under the first portion of the photoresist layer.Type: GrantFiled: March 20, 2020Date of Patent: September 10, 2024Assignee: Applied Materials, Inc.Inventors: Huixiong Dai, Srinivas D. Nemani, Steven Hiloong Welch, Mangesh Ashok Bangar, Ellie Y. Yieh
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Patent number: 12080643Abstract: Integrated circuit structures having differentiated interconnect lines in a same dielectric layer, and methods of fabricating integrated circuit structures having differentiated interconnect lines in a same dielectric layer, are described. In an example, an integrated circuit structure includes an inter-layer dielectric (ILD) layer above a substrate. A plurality of conductive interconnect lines is in the ILD layer. The plurality of conductive interconnect lines includes a first interconnect line having a first height, and a second interconnect line immediately laterally adjacent to but spaced apart from the first interconnect line, the second interconnect line having a second height less than the first height.Type: GrantFiled: September 26, 2019Date of Patent: September 3, 2024Assignee: Intel CorporationInventors: Travis W. Lajoie, Abhishek A. Sharma, Juan G. Alzate Vinasco, Chieh-Jen Ku, Shem O. Ogadhoh, Allen B. Gardiner, Blake C. Lin, Yih Wang, Pei-Hua Wang, Jack T. Kavalieros, Bernhard Sell, Tahir Ghani
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Patent number: 12038693Abstract: In a method of manufacturing a photo mask for lithography, circuit pattern data are acquired. A pattern density, which is a total pattern area per predetermined area, is calculated from the circuit pattern data. Dummy pattern data for areas having pattern density less than a threshold density are generated. Mask drawing data is generated from the circuit pattern data and the dummy pattern data. By using an electron beam from an electron beam lithography apparatus, patterns are drawn according to the mask drawing data on a resist layer formed on a mask blank substrate. The drawn resist layer is developed using a developing solution. Dummy patterns included in the dummy pattern data are not printed as a photo mask pattern when the resist layer is exposed with the electron beam and is developed.Type: GrantFiled: May 15, 2023Date of Patent: July 16, 2024Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: Chien-Cheng Chen, Chia-Jen Chen, Hsin-Chang Lee, Shih-Ming Chang, Tran-Hui Shen, Yen-Cheng Ho, Chen-Shao Hsu
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Patent number: 12009443Abstract: Photovoltaic devices, and methods of fabricating photovoltaic devices. The photovoltaic devices may include a first electrode, at least one quantum dot layer, at least one semiconductor layer, and a second electrode. The first electrode may include a layer including Cr and one or more silver contacts.Type: GrantFiled: November 29, 2022Date of Patent: June 11, 2024Assignee: The Florida State University Research Foundation, Inc.Inventors: Jobeda Jamal Khanam, Simon Y. Foo
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Patent number: 11964450Abstract: A laminated member includes a glass member of which a linear transmittance at a wavelength of 850 nm is 80% or more, a bonding layer provided on or above the glass member, the bonding layer being constituted by a resin, and a ceramic member provided on or above the bonding layer, the ceramic member being constituted by an SiC member or an AlN member.Type: GrantFiled: January 14, 2022Date of Patent: April 23, 2024Assignee: AGC Inc.Inventors: Shuhei Ogawa, Norihito Nakazawa, Shuhei Nomura
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Patent number: 11958269Abstract: A laminated member includes a glass member of which a linear transmittance at a wavelength of 850 nm is 80% or more, a bonding layer provided on or above the glass member, the bonding layer being constituted by a resin, and a Si—SiC member provided on or above the bonding layer.Type: GrantFiled: January 14, 2022Date of Patent: April 16, 2024Assignee: AGC Inc.Inventors: Shuhei Ogawa, Shuhei Nomura, Norihito Nakazawa
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Patent number: 11961697Abstract: A multi-beam apparatus for multi-beam inspection with an improved source conversion unit providing more beamlets with high electric safety, mechanical availability and mechanical stabilization has been disclosed. The source-conversion unit comprises an image-forming element array having a plurality of image-forming elements, an aberration compensator array having a plurality of micro-compensators, and a pre-bending element array with a plurality of pre-bending micro-deflectors. In each of the arrays, adjacent elements are placed in different layers, and one element may comprise two or more sub-elements placed in different layers. The sub-elements of a micro-compensator may have different functions such as micro-lens and micro-stigmators.Type: GrantFiled: May 5, 2023Date of Patent: April 16, 2024Assignee: ASML Netherlands B.V.Inventors: Xuerang Hu, Xuedong Liu, Weiming Ren, Zhong-Wei Chen
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Patent number: 11942322Abstract: In a method of manufacturing a semiconductor device, a metallic photoresist layer is formed over a target layer to be patterned, the metallic photoresist layer is selectively exposed to actinic radiation to form a latent pattern, and the latent pattern is developed by applying a developer to the selectively exposed photoresist layer to form a pattern. The metallic photo resist layer is an alloy layer of two or more metal elements, and the selective exposure changes a phase of the alloy layer.Type: GrantFiled: April 9, 2021Date of Patent: March 26, 2024Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: An-Ren Zi, Chun-Chih Ho, Yahru Cheng, Ching-Yu Chang
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Patent number: 11936158Abstract: In some implementations, a vertical-cavity surface-emitting laser (VCSEL) array may comprise a plurality of channels, a plurality of traces, and a plurality of emitters. A channel, of the plurality of channels, may include a set of emitters, of the plurality of emitters, arranged in a row of emitters. The channel may include a trace, of the plurality of traces, that has a trace width that is tapered along a length of the trace. Numerous other aspects are provided.Type: GrantFiled: October 20, 2020Date of Patent: March 19, 2024Assignee: Lumentum Operations LLCInventors: Mohammad Ali Shirazi Hosseini Dokht, Ajit Vijay Barve, Matthew Glenn Peters
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Patent number: 11919985Abstract: Provided is a copolymer that can be favorably used as a main chain scission-type positive resist that has excellent heat resistance and that can form a resist pattern having excellent resolution and clarity. The copolymer includes a monomer unit (A) represented by the following formula (I) and a monomer unit (B) represented by the following formula (II), and has a molecular weight distribution of 1.7 or less. In the formulae, L is a single bond or a divalent linking group, Ar is an optionally substituted aromatic ring group, R1 is an alkyl group, R2 is an alkyl group, a halogen atom, or a haloalkyl group, p is an integer of not less than 0 and not more than 5, and in a case in which more than one R2 is present, each R2 may be the same or different.Type: GrantFiled: September 18, 2019Date of Patent: March 5, 2024Assignee: ZEON CORPORATIONInventor: Manabu Hoshino
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Patent number: 11915908Abstract: The present invention relates to a method for measuring a sample with a microscope, the method comprising the steps of: measuring a tilt of the sample, correcting an orientation of the sample based on the tilt, and scanning the sample.Type: GrantFiled: October 14, 2021Date of Patent: February 27, 2024Assignee: Carl Zeiss SMT GmbHInventors: Eugen Foca, Amir Avishai, Dmitry Klochkov, Thomas Korb, Jens Timo Neumann, Keumsil Lee
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Patent number: 11914305Abstract: In embodiments of a digital lithography system, physical design data prepared at a data prep server in a hierarchical data structure. A leaf node comprises a repeater nod, comprising a bitmap image and a plurality of locations at which the bitmap appears in a physical design. At an EYE server, a repeater node bitmap is adjusted based upon, for example, spatial light modulator rotational adjustment and substrate distortion. The adjusted repeater node and the plurality of locations in which the adjusted repeater appears is compared to the repeater of the data prep server and its plurality of locations. In further embodiments, a rasterizer generates a checksum of bitmap to be printed to a substrate, from the EYE server bitmap. The checksum is compared to a checksum of the EYE server bitmap.Type: GrantFiled: February 18, 2020Date of Patent: February 27, 2024Assignee: Applied Materials, Inc.Inventors: Chung-Shin Kang, Jun Yang, Hongbin Ji
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Patent number: 11852975Abstract: An electron beam lithography (Ebeam) method for a wafer having alignment and device layers with a design alignment. The Ebeam method includes executing an Ebeam scan of predefined length and resolution based on the design alignment over a pattern edge of the device layer, generating a signal from reflections of the Ebeam scan off the pattern edge, determining an offset of the device layer relative to the alignment layer from a comparison of the signal and the design alignment and applying the offset to the design alignment to obtain an actual measurement of Ebeam alignment.Type: GrantFiled: July 8, 2020Date of Patent: December 26, 2023Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Simon Dawes, Ernst Kratschmer
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Patent number: 11809080Abstract: A method includes forming a photoresist layer over a substrate, wherein the photoresist layer includes a polymer, a sensitizer, and a photo-acid generator (PAG), wherein the sensitizer includes a resonance ring that includes nitrogen and at least one double bond. The method further includes performing an exposing process to the photoresist layer. The method further includes developing the photoresist layer, thereby forming a patterned photoresist layer.Type: GrantFiled: July 29, 2022Date of Patent: November 7, 2023Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.Inventors: Wei-Han Lai, Chin-Hsiang Lin, Chien-Wei Wang
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Patent number: 11795253Abstract: The present invention relates to a composition containing a compound (A) represented by the following general formula (I) and a compound having two or more polymerizable functional groups (B) in a molecule (except for compound (A)), wherein a mass ratio ((A)/(B)) of the compound (A) to the compound having two or more polymerizable functional groups (B) in a multi-molecule is 30/70 to 50/50: wherein, R1 and R2 each independently represent any one selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group; R3 represents any one selected from the group consisting of an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group; R4 represents any one selected from the group consisting of a (meth)acryloyl group, a styryl group, and an alkenyl group having 2 to 6 carbon atoms; and n represents any integer of 1 to 5.Type: GrantFiled: December 18, 2019Date of Patent: October 24, 2023Assignee: KURARAY CO., LTD.Inventors: Issei Oida, Daiki Noguchi, Takashi Fukumoto
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Patent number: 11784046Abstract: A method of manufacturing semiconductor device includes forming a multilayer photoresist structure including a metal-containing photoresist over a substrate. The multilayer photoresist structure includes two or more metal-containing photoresist layers having different physical parameters. The metal-containing photoresist is a reaction product of a first precursor and a second precursor, and each layer of the multilayer photoresist structure is formed using different photoresist layer formation parameters. The different photoresist layer formation parameters are one or more selected from the group consisting of the first precursor, an amount of the first precursor, the second precursor, an amount of the second precursor, a length of time each photoresist layer formation operation, and heating conditions of the photoresist layers.Type: GrantFiled: January 15, 2021Date of Patent: October 10, 2023Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.Inventors: Jia-Lin Wei, Ming-Hui Weng, Chih-Cheng Liu, Yi-Chen Kuo, Yen-Yu Chen, Yahru Cheng, Jr-Hung Li, Ching-Yu Chang, Tze-Liang Lee, Chi-Ming Yang
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Patent number: 11756731Abstract: A system and method for providing and programming a programmable inductor is provided. The structure of the programmable inductor includes multiple turns, with programmable interconnects incorporated at various points around the turns to provide a desired isolation of the turns during programming. In an embodiment the programming may be controlled using the size of the vias, the number of vias, or the shapes of the interconnects.Type: GrantFiled: April 22, 2019Date of Patent: September 12, 2023Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: Chen-Hua Yu, Mirng-Ji Lii, Hao-Yi Tsai, Hsien-Wei Chen, Hung-Yi Kuo, Nien-Fang Wu
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Patent number: 11746085Abstract: The present invention discloses a triphenylsulfonium salt compound as shown in the general formula (I), wherein R1 represents an electron-withdrawing group and R2 represents an amplification group. Said compound shows significantly enhanced solubility and photosensitivity compared with unsubstituted triphenylsulfonium salts, and has significantly advantageous performance compared with prior art improved substitutes.Type: GrantFiled: September 27, 2019Date of Patent: September 5, 2023Assignees: Changzhou Tronly Advanced Electronic Materials Co., Ltd., Changzhou Tronly New Electronics Materials Co., Ltd.Inventor: Xiaochun Qian
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Patent number: 11691880Abstract: The present embodiments relate to a method for manufacturing a two-dimensional material using a top-down method, the method includes the steps of preparing a bulk crystal, forming a metal layer on the bulk crystal, and then attaching a thermal release tape on the metal layer, exfoliating a two-dimensional material to which the metal layer and the thermal release tape have been attached from the bulk crystal, transferring the two-dimensional material to which the metal layer and the thermal release tape have been attached onto a substrate, and removing the thermal release tape and the metal layer from the substrate onto which the two-dimensional material has been transferred.Type: GrantFiled: July 29, 2021Date of Patent: July 4, 2023Assignee: AJOU UNIVERSITY INDUSTRY-ACADEMIC COOPERATION FOUNDATIONInventors: Jaehyun Lee, Jiyun Moon
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Patent number: 11681219Abstract: A resist composition including a polymer; and a compound represented by Formula 1, in Formula 1, R1 is hydrogen, a halogen, an alkyl group having 1 to 7 carbon atoms, a carbonyl group having 1 to 7 carbon atoms, an ester group having 1 to 7 carbon atoms, an acetal group having 1 to 7 carbon atoms, an alkoxy group having 1 to 7 carbon atoms, an ether group having 1 to 7 carbon atoms, or a group represented by Formula R, and R2, R3, R4 and R5 are hydrogen, a halogen, an alkyl group having 1 to 7 carbon atoms, an ester group having 1 to 7 carbon atoms, an acetal group having 1 to 7 carbon atoms, an alkoxy group having 1 to 7 carbon atoms, or an ether group having 1 to 7 carbon atoms,Type: GrantFiled: August 12, 2020Date of Patent: June 20, 2023Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Yechan Kim, Su Min Kim, Ju-Young Kim, Jinjoo Kim, Hyunwoo Kim, Juhyeon Park, Hyunji Song, Songse Yi, Suk Koo Hong
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Patent number: 11635685Abstract: A resist composition comprising a base polymer and an acid generator containing a sulfonium or iodonium salt of iodized benzamide group-containing fluorinated sulfonic acid offers a high sensitivity, minimal LWR and improved CDU independent of whether it is of positive or negative tone.Type: GrantFiled: October 27, 2020Date of Patent: April 25, 2023Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Jun Hatakeyama, Takayuki Fujiwara, Tomomi Watanabe
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Patent number: 11631813Abstract: Generally, examples described herein relate to deposition masks and methods of manufacturing and using such deposition masks. An example includes a method for forming a deposition mask. A mask layer is deposited on a substrate. Mask openings are patterned through the mask layer. A central portion of the substrate is removed to define a substrate opening through a periphery portion of the substrate. The mask layer with the mask openings through the mask layer extending across the substrate opening.Type: GrantFiled: March 2, 2020Date of Patent: April 18, 2023Assignee: Applied Materials, Inc.Inventors: Kevin Moraes, Alexander N. Lerner
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Patent number: 11610758Abstract: A collimated electron beam is illuminated to a grounded metal mask such that patterns on the mask can be transferred to a substrate identically. In a preferred embodiment, a linear electron source can be provided for enhancing lithographic throughput. The metal mask is adjacent to the substrate, but does not contact with substrate.Type: GrantFiled: January 15, 2020Date of Patent: March 21, 2023Assignee: KKT HOLDINGS SYNDICATEInventors: Tzu-Yi Kuo, Yu-Kuang Tseng
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Patent number: 11560304Abstract: A method for functionalizing a surface of a dielectric plate that is transparent to visible light—to be able to examine the dielectric plate using optical microscopy—includes depositing a negative film on the dielectric slide. The negative film comprises a polymerizable composition that polymerizes when exposed to an electron beam. The polymerizable composition is polymerized—by exposing the negative film to the electronic beam—at a set of points representing a preset pattern. Non-polymerized portions of the polymerizable composition are dissolved—to develop the negative film—forming a set of pads of polymerized portions of the polymerizable composition. Each pad corresponds to one point of the preset pattern. A metal film is disposed on the negative film, and the developed negative film is dissolved to define holes through the metal film. Each of the holes corresponds to a base of one pad of the set of pads.Type: GrantFiled: April 17, 2019Date of Patent: January 24, 2023Assignees: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITÉ D'AIX-MARSEILLEInventors: Kheya Sengupta, Emmanuelle Benard, Igor Ozerov, Frédéric Bedu, Hervé Dallaporta
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Patent number: 11550222Abstract: Embodiments of the present disclosure generally relate to a multilayer stack used as a mask in extreme ultraviolet (EUV) lithography and methods for forming a multilayer stack. In one embodiment, the method includes forming a carbon layer over a film stack, forming a metal rich oxide layer on the carbon layer by a physical vapor deposition (PVD) process, forming a metal oxide photoresist layer on the metal rich oxide layer, and patterning the metal oxide photoresist layer. The metal oxide photoresist layer is different from the metal rich oxide layer and is formed by a process different from the PVD process. The metal rich oxide layer formed by the PVD process improves adhesion of the metal oxide photoresist layer and increases the secondary electrons during EUV lithography, which leads to decreased EUV dose energies.Type: GrantFiled: June 2, 2020Date of Patent: January 10, 2023Assignee: Applied Materials, Inc.Inventors: Tejinder Singh, Lifan Yan, Abhijit B. Mallick, Daniel Lee Diehl, Ho-yung Hwang, Jothilingam Ramalingam
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Patent number: 11527484Abstract: An electronic device includes a substrate, and the substrate may include one or more layers. The one or more layers may include a dielectric material and may include one or more electrical traces. The electronic device may include a layer of conductive material, and the layer of conductive material may define a void in the conductive material. The electronic device may include a fiducial mark, and the fiducial mark may include a filler material positioned in the void defined by the conductive material. The fiducial mark may be coupled to the layer of conductive material. The filler material may have a lower reflectivity in comparison to the conductive material, for instance to provide a contrast with the conductive material.Type: GrantFiled: October 23, 2020Date of Patent: December 13, 2022Assignee: Intel CorporationInventors: Jesse C. Jones, Gang Duan, Jason Gamba, Yosuke Kanaoka, Rahul N. Manepalli, Vishal Shajan
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Patent number: 11453176Abstract: The present invention relates to a method for interconnecting components of a sporting good, in particular a sports shoe, and a sports shoe manufactured with such a method. The method may include (a.) forming a pattern element having at least one removable at least partially non-transparent or non-reflective portion, (b.) irradiating at least one of the first and the second component via the pattern element with heat radiation and (c.) interconnecting the irradiated first and second component.Type: GrantFiled: November 23, 2020Date of Patent: September 27, 2022Assignee: ADIDAS AGInventors: Andreas Johannes Seefried, Clemens Paul Dyckmans, Maximilian Philipp Kurtz
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Patent number: 11429023Abstract: A negative resist composition comprising an onium salt having formula (A) and a base polymer is provided. The resist composition exhibits a high resolution during pattern formation and forms a pattern with minimal LER.Type: GrantFiled: October 17, 2019Date of Patent: August 30, 2022Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Daisuke Domon, Naoya Inoue, Masaki Ohashi, Keiichi Masunaga, Masaaki Kotake
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Patent number: 11417495Abstract: A multi-charged particle beam irradiation apparatus includes a forming mechanism to form multiple charged particle beams, a multipole deflector array to individually deflect each beam of the multiple charged particle beams so that a center axis trajectory of each beam of the multiple charged particle beams may not converge in a region of the same plane orthogonal to the direction of a central axis of a trajectory of the multiple charged particle beams, and an electron optical system to irradiate a substrate with the multiple charged particle beams while maintaining a state where the multiple charged particle beams are not converged.Type: GrantFiled: March 8, 2021Date of Patent: August 16, 2022Assignee: NuFlare Technology, Inc.Inventors: Kazuhiko Inoue, Masataka Shiratsuchi, Munehiro Ogasawara
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Patent number: 11404532Abstract: An integrated circuit having a fingered capacitor with multiple metal fingers formed in inverted-trapezoid-shaped trenches in a multi-layer structure having a polish stop layer over an ultra-low-K dielectric layer over a low-K dielectric layer over a dielectric cap layer. The ultra-low-K dielectric layer reduces capacitance variations between the fingers, while the polish stop layer prevents metal height variations that would otherwise result from performing CMP directly on the ultra-low-K dielectric layer. The layered structure may include another low-K dielectric layer over the polish stop layer that provides a soft landing for the CMP. The polish stop layer may be removed after the CMP polishing and another ultra-low-K dielectric layer may be formed to encapsulate the tops of the metal fingers in the ultra-low-K dielectric material.Type: GrantFiled: July 29, 2020Date of Patent: August 2, 2022Assignee: NXP B.V.Inventors: Chunshan Yin, Cheong Min Hong, Yu Chen
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Patent number: 11294274Abstract: The present disclosure provides an apparatus for a semiconductor lithography process in accordance with some embodiments. The apparatus includes a pellicle membrane, a porous pellicle frame, a mask with a patterned surface, a first thermal conductive adhesive layer that secures the pellicle membrane to the porous pellicle frame, and a second thermal conductive adhesive layer that secures the porous pellicle frame to the mask.Type: GrantFiled: January 13, 2020Date of Patent: April 5, 2022Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: Amo Chen, Yun-Yue Lin, Ta-Cheng Lien, Hsin-Chang Lee, Chih-Cheng Lin, Jeng-Horng Chen
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Patent number: 11262654Abstract: Chain scission resist compositions suitable for EUV lithography applications may include monomer functional groups that improve the kinetics and/or thermodynamics of the scission mechanism. Chain scission resists may include monomer functional groups that reduce the risk that leaving groups generated through the scission mechanism may chemically corrode processing equipment.Type: GrantFiled: December 27, 2019Date of Patent: March 1, 2022Assignee: Intel CorporationInventors: Lauren Doyle, Marie Krysak, Patrick Theofanis, James Blackwell, Eungnak Han
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Patent number: 11092523Abstract: The present invention provides methods for controllably forming a layer of amorphous ice and other amorphous solids on a substrate, and also provides cryoelectron microscopy (cryo-EM) sample preparation methods and systems that utilize in vacuo formation of amorphous ice and other solids. Formation of the amorphous solid layer can be independent of the deposition of sample molecules to be analyzed using electron microscopy, and allows for the generation of a uniformly thick layer. Optionally, mass spectrometry instruments are used to generate and purify molecules deposited on the generated amorphous solid layer. The techniques and systems described herein can deliver near ideal cryo-EM sample preparation to greatly increase resolution, sensitivity, scope, and throughput of cryo-EM protein imaging, and therefore greatly impact the field of structural biology.Type: GrantFiled: July 6, 2018Date of Patent: August 17, 2021Assignee: Wisconsin Alumni Research FoundationInventors: Joshua Coon, Michael Westphall
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Patent number: 11088337Abstract: In a method of forming a gate-all-around field effect transistor, a gate structure is formed surrounding a channel portion of a carbon nanotube. An inner spacer is formed surrounding a source/drain extension portion of the carbon nanotube, which extends outward from the channel portion of the carbon nanotube. The inner spacer includes two dielectric layers that form interface dipole. The interface dipole introduces doping to the source/drain extension portion of the carbon nanotube.Type: GrantFiled: October 1, 2019Date of Patent: August 10, 2021Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Timothy Vasen, Marcus Johannes Henricus Van Dal, Gerben Doornbos
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Patent number: 10981304Abstract: A method of nanoscale patterning is disclosed. The method comprises: mixing predetermined amounts of a first solvent and a second solvent to generate a solvent, the first solvent and the second solvent being immiscible with each other; dissolving a solute material in the solvent to generate a coating material, the solute material having solubility that is higher in the first solvent than in the second solvent; and applying the coating material onto a substrate to form a plurality of pinholes in the coating material. The formation of the plurality of pinholes is associated with suspension drops mostly comprised of the second solvent, separated from the solute material dissolved in the first solvent, in the coating material. A method of making a stamp with a nanoscale pattern is also disclosed based on the above method.Type: GrantFiled: June 1, 2017Date of Patent: April 20, 2021Assignee: OKINAWA INSTITUTE OF SCIENCE AND TECHNOLOGY SCHOOL CORPORATIONInventors: Yabing Qi, Luis Katsuya Ono
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Patent number: 10937630Abstract: Systems and methods are described herein for electron-beam lithography. In some aspects, a photo electron emitter and channel array assembly (PEECAA) may include a photo-electron emitting cathode having a uniform planar surface and an array of beam channels proximate to the cathode. In some cases, at least one of the cathode or the array of beam channels is removable from the PEECAA. The array of beam channels may include a grid of apertures, a plurality of beam channels, and a shared lens array including a plurality of lenses proximate to an exit of the plurality of beam channels. Individual apertures of the grid of apertures align with individual beam channels to allow electrons from the cathode to pass through the array of beam channels and the shared lens array to form a pixelated pattern, such that, upon exposure to the target, the pixelated pattern is permanently formed on the target.Type: GrantFiled: April 27, 2020Date of Patent: March 2, 2021Inventor: John Bennett
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Patent number: 10919220Abstract: A technique to have precise materials deposition in the micro and nanometer scale relating to 3D printing. A microfluidic pipette and an atomic force microscopy (AFM) needle are used to position the pipette a distance from a working stage to avoid surface tension physics associated with droplet formation of pipette excreted material, “ink.” The combination provides greater control over both the amounts of placement of the ink. In practice, both the AFM needle and the pipette are lowered to a work stage (or the stage is raised to the AFM needle). The pipette excretes a pool of ink onto the stage and the AFM needle is placed into the pool. A unit of ink from the pool adheres to the AFM needle. The AFM needle then moved to a work space on the stage and deposits the ink in the work area through a predetermined printing technique. The system is capable of printing photoresist, polymers, nanomaterials, DNA, proteins, stem cells, semiconductors, metal, plastic and almost anything imaginable.Type: GrantFiled: March 13, 2017Date of Patent: February 16, 2021Assignee: CARBON DESIGN INNOVATIONS, INC.Inventor: Ramsey Stevens
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Patent number: 10906332Abstract: A pretreatment solution for inkjet recording contains a photoacid generator that generates sulfonic acid through light exposure.Type: GrantFiled: July 16, 2019Date of Patent: February 2, 2021Assignee: KYOCERA Document Solutions Inc.Inventor: Katsuki Osanishi
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Patent number: 10875252Abstract: The present invention relates to a method for interconnecting components of a sporting good, in particular a sports shoe, and a sports shoe manufactured with such a method. The method may include (a.) forming a pattern element having at least one removable at least partially non-transparent or non-reflective portion, (b.) irradiating at least one of the first and the second component via the pattern element with heat radiation and (c.) interconnecting the irradiated first and second component.Type: GrantFiled: December 19, 2017Date of Patent: December 29, 2020Assignee: adidas AGInventors: Andreas Johannes Seefried, Clemens Paul Dyckmans, Maximilian Philipp Kurtz
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Patent number: 10872188Abstract: Disclosed are mask definition tools, apparatus, methods, systems and computer program products configured to process data representing a semiconductor fabrication mask. A non-limiting example of a method includes performing a decomposition process on a full Transmission Cross Coefficient (TCC) using coherent optimal coherent systems (OCS) kernels; isolating a residual TCC that remains after some number of coherent kernels are extracted from the full TCC; and performing at least one decomposition process on the residual TCC using at least one loxicoherent system. The loxicoherent system uses a plurality of distinct non-coherent kernel functions and is a compound system containing a paired coherent system and an incoherent system that act in sequence. An output of the coherent system is input as a self-luminous quantity to the incoherent system, and the output of the incoherent system is an output of the loxicoherent system.Type: GrantFiled: May 30, 2019Date of Patent: December 22, 2020Assignee: International Business Machines CorporationInventor: Alan E. Rosenbluth
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Patent number: 10811492Abstract: A method of fabricating an integrated circuit includes applying photoresist to a MESA dielectric layer of a semiconductor structure, to generate a photoresist layer. The method also includes exposing the photoresist layer with a grayscale mask, to generate an exposed photoresist layer. The photoresist exposed layer includes a thick photoresist pattern in a first region, a thin photoresist pattern in a second region where a height of the thin photoresist pattern is less than half a height of the thick photoresist pattern, and a gap region between the thick photoresist pattern and the thin photoresist pattern.Type: GrantFiled: October 31, 2018Date of Patent: October 20, 2020Assignee: TEXAS INSTRUMENTS INCORPORATEDInventors: Jeffrey Alan West, Byron Lovell Williams, John Britton Robbins