Heterocyclic Patents (Class 430/343)
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Patent number: 7314705Abstract: A composition, method, and system for recording an image. The system includes an imaging material in which radiation energy is absorbed by an antenna material. The antenna material may be chosen from the group consisting of phthalocyanines and naphthalocyanines.Type: GrantFiled: June 2, 2006Date of Patent: January 1, 2008Assignee: Hewlett-Packard Development Company, L.P.Inventor: Makarand P. Gore
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Patent number: 7270944Abstract: A composition, method, and system for recording an image. The system includes a multiphase imaging material in which energy is absorbed by an antenna material. The absorbed energy causes the reaction of an oxidizer and a leucozine dye.Type: GrantFiled: March 29, 2005Date of Patent: September 18, 2007Assignee: Hewlett-Packard Development Company, L.P.Inventor: Makarand P. Gore
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Patent number: 7223519Abstract: Imaging compositions and methods of using the compositions are disclosed. The imaging compositions are sensitive to low levels of energy such that upon application of the low levels of energy the compositions change color or shade. The compositions may be applied to a work piece to mark it and removed from the work piece by peeling.Type: GrantFiled: July 13, 2005Date of Patent: May 29, 2007Assignee: Rohm and Haas Electronic Materials LLCInventors: Robert K. Barr, Corey O'Connor
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Patent number: 7169542Abstract: A composition, method, and system for recording an image. The system includes a multiphase imaging material in which energy is absorbed by an antenna material. The absorbed energy causes the reaction of an activator and a color-forming material.Type: GrantFiled: April 30, 2004Date of Patent: January 30, 2007Assignee: Hewlett-Packard Development Company, L.P.Inventors: Vladek Kasperchik, Makarand Gore
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Patent number: 7146909Abstract: An image forming material, a lithographic printing plate precursor and a lithographic printing method, in which a color image with good visibility is obtained by laser exposure, are provided, wherein the image forming material and the lithographic printing plate precursor each comprising a support and a layer comprising a compound represented by formula (1) which changes from a colorless state to a colored state by the effect of heat; and a lithographic printing method comprising on-press development using the lithographic printing plate precursor:Type: GrantFiled: July 19, 2005Date of Patent: December 12, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Hidekazu Oohashi, Kazuto Kunita
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Patent number: 7144676Abstract: Imaging compositions and methods of using the compositions are disclosed. The imaging compositions are sensitive to low levels of energy such that upon application of the low levels of energy the compositions change color or shade. The compositions may be applied to a work piece to mark it and removed from the work piece by peeling.Type: GrantFiled: July 12, 2004Date of Patent: December 5, 2006Assignee: Rohm and Haas Electronic Materials LLCInventors: Robert K. Barr, Corey O'Connor
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Patent number: 7141360Abstract: Imaging layers, image recording media, and methods of preparation of each, are provided. One exemplary embodiment of the imaging layer, among others, includes a matrix, a radiation absorbing compound dissolved in the matrix, at least two activators substantially dissolved in the matrix, and a color former. The activators can include a primary activator having a higher acidity than a secondary activator. In addition, the primary activator has a lower solubility in the matrix than the secondary activator. The color former is substantially insoluble in the matrix at ambient conditions and is substantially uniformly distributed in the matrix.Type: GrantFiled: June 9, 2004Date of Patent: November 28, 2006Assignee: Hewlett-Packard Development Company, L.P.Inventors: Vladek Kasperchik, Jayprakash C. Bhatt, Cari L Dorsh
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Patent number: 7091255Abstract: A method of multiphoton photosensitizing a photoreactive composition comprises irradiating the composition with light sufficient to cause simultaneous absorption of at least two photons, thereby inducing at least one acid- or radical-initiated chemical reaction where the composition is exposed to the light. The composition comprises: (a) at least one reactive species that is capable of undergoing such reaction; and (b) at least one multi-component, multiphoton photoinitiator system.Type: GrantFiled: October 13, 2004Date of Patent: August 15, 2006Assignee: 3M Innovative Properties CompanyInventor: Robert J. DeVoe
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Patent number: 7026103Abstract: A multilayer imageable article with at least two layers including a multiphoton imageable composition. The composition includes a multiphoton-sensitive photoactive system and at least one of a dye and a dye precursor. The photoactive system includes a multiphoton sensitizer capable of simultaneously absorbing at least two photons, an electron acceptor capable of transformation to a dye-activating species upon interaction with the multiphoton sensitizer subsequent to absorption of at least two photons, and optionally an electron donor.Type: GrantFiled: June 14, 2001Date of Patent: April 11, 2006Assignee: 3M Innovative Properties CompanyInventors: Robert J. DeVoe, Robert D. DeMaster, Brook F. Duerr, Jonathan P. Kitchin, Dennis E. Vogel
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Silver-free black-and-white thermographic materials containing a benzoquinone and methods of imaging
Patent number: 7022441Abstract: Silver-free, aqueous-based direct thermographic materials are designed to have image tone with near neutral density. Without the use of organic silver salts containing reducible silver ions, the image is formed using a color developing agent precursor that releases a color developing agent when heated to a temperature of at least 80° C., a combination of cyan, yellow and magenta dye-forming color couplers that provide cyan, yellow, and magenta dyes, and a substituted or unsubstituted benzoquinone as an oxidizing agent. No silver metal or silver ions are purposely added to these materials. This combination of components provides a means for controlling image tone without reliance upon conventional toning agents.Type: GrantFiled: February 25, 2004Date of Patent: April 4, 2006Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia -
Patent number: 6974661Abstract: A composition, method, and system for recording an image. The system includes a multiphase imaging material in which energy is absorbed by an antenna material. The absorbed energy causes the reaction of an activator and a color-forming material.Type: GrantFiled: January 24, 2003Date of Patent: December 13, 2005Assignee: Hewlett-Packard Development Company, L.P.Inventors: Makarand P. Gore, Marshall Field, Vladek P Kasperchik
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Patent number: 6962763Abstract: Silver-free, aqueous-based direct thermographic materials are designed to have image tone with near neutral density. Without the use of organic silver salts containing reducible silver ions, the image is formed using a color developing agent precursor that releases a color developing agent when heated to a temperature of at least 80° C., a combination of cyan, yellow and magenta dye-forming color couplers that provide cyan, yellow, and magenta dyes, and a hindered-amine N-oxyl as an oxidizing agent. No silver metal or silver ions are purposely added to these materials. This combination of components provides a means for controlling image tone without reliance upon conventional toning agents.Type: GrantFiled: February 25, 2004Date of Patent: November 8, 2005Assignee: Eastman Kodak CompanyInventors: Joe E. Maskasky, Victor P. Scaccia
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Patent number: 6861201Abstract: Novel photopolymer compositions are disclosed which contain dyes that absorb strongly in the near infrared (near IR) region of the electromagnetic spectrum. These dyes are useful as photosensitizers for initiating a variety of photoimaging and photopolymerization reactions. Imaging Media are disclosed herein which are sensitive in the near infrared (near IR) region of the electromagnetic spectrum and which can initiate polymerization of ethylenically unsaturated monomer components in negative-acting photopolymer systems and/or which can initiate conversion of a leuco dye to its corresponding colored dye form. These imaging media comprise either a near IR dye photochemical sensitizer, a hexaarylbiimidazole (HABI) photoinitiator, a chain transfer agent, and a photopolymerizable material or a near IR dye photochemical sensitizer, a hexaarylbiimidazole (HABI) photoinitiator, and a leuco dye.Type: GrantFiled: April 7, 2004Date of Patent: March 1, 2005Assignee: E. I. du Pont de Nemours and CompanyInventors: Gregory C. Weed, Dietrich M. Fabricius
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Publication number: 20040146812Abstract: A composition, method, and system for recording an image. The system includes a multiphase imaging material in which energy is absorbed by an antenna material. The absorbed energy causes the reaction of an activator and a color-forming material.Type: ApplicationFiled: January 24, 2003Publication date: July 29, 2004Inventors: Makarand P. Gore, Marshall Field, Vladek P. Kasperchik
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Patent number: 6607871Abstract: An image recording medium comprising a light and heat change material capable of recording an image with laser beam is described, characterized in that therein are incorporated a heat generator having no absorption at a wavelength of 500 nm or more which undergoes exothermic decomposition to amplify heat generation when acted upon by heat and a compound which undergoes thermochemical reaction to show an absorption change at a wavelength of from 360 nm to 900 nm.Type: GrantFiled: September 21, 2000Date of Patent: August 19, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Tatsuhiko Obayashi, Atsuhiro Ookawa
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Patent number: 6558880Abstract: Photothermographic materials comprise heat-bleachable antihalation compositions in backside antihalation layers. These compositions comprise a hexaarybiimidazole and an oxonol dye that can be represented by the following Structure I: A1═L1—(L2═L3)p—(L4═L5)q—(L6═L7)r—A2−(M)k wherein A1 and A2 are the same or different activated methylene moieties, L1 through L7 independently represent a substituted or unsubstituted methine group, M represents a counterion, k is the number of M counterions necessary to provide neutral charge for Structure I, p, and q, are independently 0 or 1, and r is 0, 1, or 2. The antihalation composition is typically bleached when subjected to a temperature of at least 90° C. for at least 0.5 seconds.Type: GrantFiled: June 6, 2001Date of Patent: May 6, 2003Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, William D. Ramsden, Paul A. Zielinski, David G. Baird, LuAnn K. Weinstein, Margaret J. Helber, Doreen C. Lynch
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Patent number: 6528232Abstract: A sulfonium salt compound designated by a general formula (I), a photoresist composition containing the sulfonium salt compound and a method for patterning by employing the sulfonium salt compound.Type: GrantFiled: October 31, 2000Date of Patent: March 4, 2003Assignee: NEC CorporationInventors: Katsumi Maeda, Shigeyuki Iwasa, Kaichiro Nakano, Etsuo Hasegawa
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Patent number: 6500510Abstract: The present invention relates to use of transition metal complexes in photochromic devices, to the production of optical information storage devices based on a polymeric matrix and on metal oxides with adsorbed transition metal complexes, to the production of photochromic materials constituted by a film of metal oxide with adsorbed two different type of molecular systems, one acting as a charge transfer sensitizer and the second as an electron acceptor.Type: GrantFiled: April 7, 2000Date of Patent: December 31, 2002Assignee: Molecular Storage Technologies, Inc.Inventors: Patrick Sanders, Carlo Alberto Bignozzi
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Patent number: 6461804Abstract: According to the present invention there is provided a class of IR-sensitizing dyes, comprising two benzoindol rings and at least two sulphonic acid groups corresponding to the general formula I:Type: GrantFiled: October 12, 2000Date of Patent: October 8, 2002Assignee: Agfa-GevaertInventor: Geert Deroover
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Patent number: 6455210Abstract: This invention relates to a photothermographic element comprising a support, at least one photothermographic image-receiving layer, and at least one antihalation layer or a filter layer, wherein the antihalation or filer layer comprises an aqueous heat-bleachable composition comprising at least one dye and at least one hexaarylbiimidazole in the form of particles dispersed in a matrix comprising a hydrophilic or aqueous dispersible polymer.Type: GrantFiled: December 6, 2000Date of Patent: September 24, 2002Assignee: Eastman Kodak CompanyInventors: Mark E. Irving, Ramanuj Goswami, Kenneth N. Kilminster
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Patent number: 6416922Abstract: The present invention related to an azomethine dye precursor represented by the following general formula (1) and the image-forming material and image-forming method using the azomethine dye precursor: wherein Ar represents an aryl group or a heterocyclic group which may each have a substituent; X represents a bivalent group linking a carbon atom and a nitrogen atom; and Cp represent a coupler residue which may or may not form a ring.Type: GrantFiled: January 29, 2001Date of Patent: July 9, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Sato, Masatoshi Yumoto, Yoshimitsu Arai, Hirotaka Matsumoto
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Patent number: 6398981Abstract: The present invention is concerned with photopolymer materials sensitive to infrared, near infrared, red and green light radiation for initiating polymerization and to applications of such photopolymer, like holographic polymer dispersed liquid crystal (H-PDLC) or reversible dye doped photopolymer (RDDP) materials, for making optical devices. The invention relates to holographic polymer dispersed liquid crystal and reversible dye materials having improved electrical and optical switching properties.Type: GrantFiled: February 14, 2000Date of Patent: June 4, 2002Assignee: Universite LavalInventors: Tigran Galstian, Amir Tork
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Publication number: 20010019806Abstract: The present invention related to an azomethine dye precursor represented by the following general formula (1) and the image-forming material and image-forming method using the azomethine dye precursor: wherein Ar represents an aryl group or a heterocyclic group which may each have a substituent; X represents a bivalent group linking a carbon atom and a nitrogen atom; and Cp represent a coupler residue which may or may not form a ring.Type: ApplicationFiled: January 29, 2001Publication date: September 6, 2001Inventors: Hiroshi Sato, Masatoshi Yumoto, Yoshimitsu Arai, Hirotaka Matsumoto
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Patent number: 6274728Abstract: Compounds of formula A(B)x (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing.Type: GrantFiled: December 16, 1999Date of Patent: August 14, 2001Assignee: Ciba Specialty Chemicals Corp.Inventors: Véronique Hall-Goulle, Aline Bize
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Patent number: 6251571Abstract: Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention contain at least one polymeric binder, a specified leuco dye and a specified hydroxylamine compound. These compositions have the propensity for affording, upon thermal imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions can be imagewise heated to effect color formation (i.e., generation of an image) or, in case of compositions containing at least one near IR-absorbing dye, can be imagewise exposed to near IR radiation from a laser or other device to effect color formation (i.e., generation of an image).Type: GrantFiled: March 10, 1998Date of Patent: June 26, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Rolf Dessauer, Jonathan V Caspar
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Patent number: 6242154Abstract: A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid.Type: GrantFiled: December 11, 1998Date of Patent: June 5, 2001Assignee: Polaroid CorporationInventors: Jurgen M. Grasshoff, John L. Marshall, Richard A. Minns, Socorro M. Ramos, Stephen G. Stroud, Stephen J. Telfer, Haixin Yang, Roger A. Boggs, Eric S. Kolb
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Patent number: 6235095Abstract: An improved ink suitable for ink jet printing comprising, a mixture of a colorant, an arylketoalkene stabilizing compound or a photoreactor, and a liquid vehicle, wherein the colorant is light-stable. When the photoreactor is combined with a wavelength-selective sensitizer to form a radiation transorber, the colorant is mutable upon exposure of the radiation transorber to specific, narrow bandwidth radiation. The colored composition may also contain a molecular includant having a chemical structure which defines at least one cavity wherein each of the colorant and photoreactor or radiation transorber is associated with the molecular includant. The invention also includes ink jet print cartridges containing the improved ink, ink jet printers containing the improved ink and methods of printing using the improved ink.Type: GrantFiled: June 1, 1999Date of Patent: May 22, 2001Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 6232038Abstract: A photosensitive composition comprising (a) an ethylenically unsaturated double bond-containing compound, (b) a sensitizing dye and (c) a photopolymerization initiator, wherein the sensitizing dye is a phthalocyanine compound showing the maximum absorption within a range of from 750 to 1,200 nm.Type: GrantFiled: October 6, 1999Date of Patent: May 15, 2001Assignee: Mitsubishi Chemical CorporationInventors: Ryuichiro Takasaki, Toshiyuki Urano
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Patent number: 6110638Abstract: A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid.Type: GrantFiled: November 27, 1996Date of Patent: August 29, 2000Assignee: Polaroid CorporationInventors: Roger A. Boggs, Jurgen M. Grasshoff, Eric S. Kolb, John L. Marshall, Richard A. Minns, Socorro M. Ramos, Stephen G. Stroud, Stephen J. Telfer, Haixin Yang
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Patent number: 6110646Abstract: A positive photosensitive composition comprising an alkali-soluble organic high molecular substance having phenolic hydroxyl groups and an acid color forming dye.Type: GrantFiled: August 13, 1998Date of Patent: August 29, 2000Assignee: Mitsubishi Chemical CorporationInventors: Toshiyuki Urano, Etsuko Hino
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Patent number: 6063551Abstract: One embodiment of the present invention is a method and composition comprising a novel pre-dye molecule that is colorless and stable to ordinary light. The pre-dye molecule is capable of forming a color when exposed to certain wavelengths of electromagnetic radiation. A second embodiment of the present invention is a method of converting a conventional leuco dye to a colored composition by exposing the leuco dye admixed with a radiation transorber to certain wavelengths of electromagnetic radiation.Type: GrantFiled: November 16, 1998Date of Patent: May 16, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 6004719Abstract: A process for producing an image uses an imaging medium comprising an acid-generating layer or phase comprising a mixture of a superacid precursor, a sensitizing dye and a secondary acid generator, and a color-change layer comprising an image dye. The sensitizing dye has first and second forms, the first form having substantially greater substantial absorption in a first wavelength range than the second form. The superacid precursor is not capable, in the absence of the first form of the sensitizing dye, of being decomposed by radiation in the first wavelength range. The secondary acid generator is capable of thermal decomposition, catalyzed by superacid, to form a secondary acid. While at least part of the sensitizing dye is in its first form, the medium is imagewise exposed to radiation in the first wavelength range, thereby causing, in the exposed areas of the acid-generating layer, the formation of superacid.Type: GrantFiled: May 19, 1997Date of Patent: December 21, 1999Assignee: Polaroid CorporationInventors: Russell A. Gaudiana, Robert W. Haddock, Serajul Haque, Iris B. Kliman Bloom, John L. Marshall, Socorro M. Ramos, Larry C. Takiff, Stephen J. Telfer, Michael A. Young
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Patent number: 5955237Abstract: A photosensitive recording medium comprising a base material and formed thereon a photosensitive layer containing at least yellow color-forming particles containing a first photosensitive component having a maximum hardening sensitivity to light with wavelength L1, magenta color-forming particles containing a second photosensitive component having a maximum hardening sensitivity to light with wavelength L2 and cyan color-forming particles containing a third photosensitive component having a maximum hardening sensitivity to light with wavelength L3. All the wavelengths L1, L2 and L3 are wavelengths longer than 500 nm.Type: GrantFiled: April 8, 1997Date of Patent: September 21, 1999Assignee: Brother Kogyo Kabushiki KaishaInventors: Yasuhiro Hattori, Takemi Yamamoto
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Patent number: 5955224Abstract: Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention comprise (a) at least one near IR-absorbing dye having the structure given in the specification; (b) at least one HABI compound; (c) at least one leuco dye; (d) at least one acid-generating compound; and (e) a polymeric binder. Optionally at least one UV stabilizer and/or at least one inhibitor of color formation can also be present. These compositions have the propensity for affording, upon imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions are imagewise exposed to near IR radiation from a laser or other device to effect color formation (i.e., generation of an image).Type: GrantFiled: October 22, 1998Date of Patent: September 21, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Jonathan V. Caspar, Gregory Charles Weed
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Patent number: 5914213Abstract: A process for generation of acid uses a medium comprising a first acid-generating component capable of generating a first acid, and a secondary acid generator, this secondary acid generator being capable of thermal decomposition to form a secondary acid, the thermal decomposition of the secondary acid generator being catalyzed by the first acid. At least part of the medium is exposed to so as to cause formation of the first acid from the first acid-generating component; and the medium is then heated to cause, in the exposed part of the medium, acid-catalyzed thermal decomposition of the secondary acid generator and formation of the secondary acid.Type: GrantFiled: October 6, 1997Date of Patent: June 22, 1999Assignee: Polaroid CorporationInventors: Jurgen M. Grasshoff, John L. Marshall, Richard A. Minns, Socorro M. Ramos, Stephen G. Stroud, Stephen J. Telfer, Haixin Yang, Roger A. Boggs, Eric S. Kolb
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Patent number: 5912257Abstract: Styryl dyes and compositions which exhibit superior two-photon absorption cross-sections and are useful in two-photon pumped cavity lasing, two-photon pumped upconversion lasing, optical power limiting, optical power stabilization, optical signal reshaping, and infrared beam detection and indication are disclosed. Also disclosed are multiphasic nanostructured composites which include a glass having pores, an optically active coating material on the pore surface, and a polymeric material in the pores. These composites are useful in producing multifunctional optical materials, such as broadly tunable lasers. Methods for killing cells and viruses using a photosensitizer and a two-photon upconverting dye are also described. These methods are especially useful to kill cells and viruses in biological materials, such as in photodynamic therapy of tumors and cancers or blood purification protocols.Type: GrantFiled: September 5, 1996Date of Patent: June 15, 1999Assignee: The Research Foundation of State university of New YorkInventors: Paras N. Prasad, Jayant D. Bhawalkar, Guang S. He, Chan F. Zhao, Raz Gvishi, Gary E. Ruland, Jaroslaw Zieba, Ping Chin Cheng, Shan Jen Pan
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Patent number: 5908495Abstract: An improved ink suitable for ink jet printing comprising, a mixture of a colorant, an arylketoalkene stabilizing compound or a photoreactor, and a liquid vehicle, wherein the colorant is light-stable. When the photoreactor is combined with a wavelength-selective sensitizer to form a radiation transorber, the colorant is mutable upon exposure of the radiation transorber to specific, narrow bandwidth radiation. The colored composition may also contain a molecular includant having a chemical structure which defines at least one cavity wherein each of the colorant and photoreactor or radiation transorber is associated with the molecular includant. The invention also includes ink jet print cartridges containing the improved ink, ink jet printers containing the improved ink and methods of printing using the improved ink.Type: GrantFiled: September 24, 1997Date of Patent: June 1, 1999Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5883232Abstract: Disclosed are diazahemicyanine hydrophobic cationic dyes represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are lower alkyl groups having not more than 5 carbon atoms, R.sup.5 is a lower alkyl group having not more than 5 carbon atoms or a lower alkoxy lower alkyl group having not more than 6 carbon atoms, and Z.sup.- is a counter ion having a hydrophobic organic group, and a thermal transfer ink ribbon having a substrate and and ink layer laminated thereon containing said cationic dye.Type: GrantFiled: July 14, 1998Date of Patent: March 16, 1999Assignees: Sony Corporation, Hodog aya Chemical Co., Ltd.Inventors: Masanobu Hida, Kengo Ito, Yoshio Fujiwara, Nobuo Suzuki, Hiroyoshi Yamaga, Junichi Hagiwara
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Patent number: 5858583Abstract: Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention comprise (a) at least one hexaarylbiimidazole (HABI) compound, (b) at least one leuco dye, (c) at least one acid-generating compound, (d) a polymeric binder, (e) optionally at least one UV stabilizer and/or at least one inhibitor of color formation, and, in certain embodiments, (f) at least one near IR-absorbing dye. These compositions have the propensity for affording, upon thermal imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions can be imagewise heated to effect color formation (i.e.Type: GrantFiled: July 3, 1997Date of Patent: January 12, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Rolf Dessauer, Jonathan V. Caspar
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Patent number: 5837429Abstract: One embodiment of the present invention is a method and composition comprising a novel pre-dye molecule that is colorless and stable to ordinary light. The pre-dye molecule is capable of forming a color when exposed to certain wavelengths of electromagnetic radiation. A second embodiment of the present invention is a method of converting a conventional leuco dye to a colored composition by exposing the leuco dye admixed with a radiation transorber to certain wavelengths of electromagnetic radiation.Type: GrantFiled: June 5, 1996Date of Patent: November 17, 1998Assignee: Kimberly-Clark WorldwideInventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5786132Abstract: One embodiment of the present invention is a method and composition comprising a novel pre-dye molecule that is colorless and stable to ordinary light. The pre-dye molecule is capable of forming a color when exposed to certain wavelengths of electromagnetic radiation. A second embodiment of the present invention is a method of converting a conventional leuco dye to a colored composition by exposing the leuco dye admixed with a radiation transorber to certain wavelengths of electromagnetic radiation.Type: GrantFiled: May 29, 1996Date of Patent: July 28, 1998Assignee: Kimberly-Clark CorporationInventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5783710Abstract: The present invention relates to benzothioxanthene dyes of the formula I, ##STR1## in which R.sup.1 is SO.sub.3.sup..crclbar. M.sup..sym. or SO.sub.2 NR.sup.4 R.sup.5, R.sup.2 and R.sup.3 independently of one another are hydrogen, SO.sub.3.sup..crclbar. M.sup..sym. or SO.sub.2 NR.sup.4 R.sup.5 and X, Y, n, R.sup.4, R.sup.5 and M.sup..sym. are as defined in claim 1, to their preparation and to their use, especially in inks and recording liquids.Type: GrantFiled: March 10, 1997Date of Patent: July 21, 1998Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Bauer, Dieter Baumgart, Walter Zoller
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Patent number: 5700850Abstract: A light-stable colored composition which includes a colorant and a radiation transorber. The colorant, in the presence of the radiation transorber, is adapted, upon exposure of the transorber to specific, narrow bandwidth radiation, to be mutable. The radiation transorber also imparts light-stability to the colorant so that the colorant does not fade when exposed to sunlight or artificial light.Type: GrantFiled: June 5, 1995Date of Patent: December 23, 1997Assignee: Kimberly-Clark WorldwideInventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5693589Abstract: A thermal recording element comprising a support having thereon a dye layer comprising a polymeric binder containing:(a) a metallized complex of a formazan dye that absorbs at from about 400 to about 850 nm; and(b) an organic carboxylic acid;the dye layer having associated therewith:(c) a hexaarylbiimidazole which is an oxidative dimer of a 2,4,5-triarylimidazole having one of the following formulas: ##STR1## wherein: R, R.sup.1 and R.sup.2 each independently represents hydrogen, a substituted or unsubstituted alkyl or alkoxy group of from 1 to about 12 carbon atoms, amino, a substituted or unsubstituted cycloalkyl group having from about 5 to about 7 carbon atoms, or an electron-rich heterocyclic group having from about 5 to about 7 atoms, with the proviso that at least one of R and R.sup.1 is the alkoxy or amino group;X and X.sup.1 each independently represents oxy or imino;Z is an alkylene group of 1 or 2 carbon atoms; andm, n and o each independently represents an integer of 0 to 5.Type: GrantFiled: May 8, 1996Date of Patent: December 2, 1997Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Robert J. Perry, Paul Anthony Zielinski
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Patent number: 5681380Abstract: An improved ink suitable for ink jet printing comprising, a mixture of a colorant, an arylketoalkene stabilizing compound or a photoreactor, and a liquid vehicle, wherein the colorant is light-stable. When the photoreactor is combined with a wavelength-selective sensitizer to form a radiation transorber, the colorant is mutable upon exposure of the radiation transorber to specific, narrow bandwidth radiation. The colored composition may also contain a molecular includant having a chemical structure which defines at least one cavity wherein each of the colorant and photoreactor or radiation transorber is associated with the molecular includant. The invention also includes ink jet print cartridges containing the improved ink, ink jet printers containing the improved ink and methods of printing using the improved ink.Type: GrantFiled: December 19, 1996Date of Patent: October 28, 1997Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5672562Abstract: A thermal recording element comprising a support having thereon a dye layer comprising a polymeric binder containing:(a) a formazan dye that absorbs at from about 400 to about 850 nm, and(b) a hexaarylbiimidazole which is an oxidative dimer of a 2,4,5-triarylimidazole having one of the following formulas: ##STR1##Type: GrantFiled: May 8, 1996Date of Patent: September 30, 1997Assignee: Eastman Kodak CompanyInventors: Ramanuj Goswami, Robert J. Perry, Paul Anthony Zielinski
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Patent number: 5667943Abstract: Certain squaric acid derivatives are useful for the thermochemical generation of acid. The squaric acid derivatives may be used in imaging media in conjunction with acid-sensitive materials which undergo a color change when contacted by the acid generated from the squaric acid derivatives. Preferably, the acid-sensitive materials undergo an irreversible color change, so that the image can be fixed by neutralizing all the acid generated with excess base, thereby preventing further color change in the image during long term storage.Type: GrantFiled: April 8, 1996Date of Patent: September 16, 1997Assignee: Polaroid CorporationInventors: Roger A. Boggs, Jurgen M. Grasshoff, Mark R. Mischke, Anthony J. Puttick, Stephen J. Telfer, David P. Waller, Kenneth C. Waterman
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Patent number: 5645964Abstract: A digital information recording media which includes a recording layer comprising a light-stable colored composition which composition is mutable or decolorizable upon exposure to a specific wavelength of ultraviolet radiation. The light-stable colored composition includes a colorant and an ultraviolet radiation transorber. The colorant, in the presence of the radiation transorber, is adapted, upon exposure of the transorber to specific, narrow bandwidth ultraviolet radiation, to be mutable. The radiation transorber also imparts light-stability to the colorant so that the colorant does not fade when exposed to sunlight or artificial light. The ultraviolet radiation transorber is adapted to absorb radiation and interact with the colorant to effect the irreversible mutation of the colorant. Especially useful radiation is incoherent, pulsed ultraviolet radiation produced by a dielectric barrier discharge excimer lamp or coherent, pulse radiation produced by an excimer laser.Type: GrantFiled: June 5, 1995Date of Patent: July 8, 1997Assignee: Kimberly-Clark CorporationInventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5643356Abstract: An improved ink suitable for ink jet printing comprising, a mixture of a colorant, an arylketoalkene stabilizing compound or a photoreactor, and a liquid vehicle, wherein the colorant is light-stable. When the photoreactor is combined with a wavelength-selective sensitizer to form a radiation transorber, the colorant is mutable upon exposure of the radiation transorber to specific, narrow bandwidth radiation. The colored composition may also contain a molecular includant having a chemical structure which defines at least one cavity wherein each of the colorant and photoreactor or radiation transorber is associated with the molecular includant. The invention also includes ink jet print cartridges containing the improved ink, ink jet printers containing the improved ink and methods of printing using the improved ink.Type: GrantFiled: June 5, 1995Date of Patent: July 1, 1997Assignee: Kimberly-Clark CorporationInventors: Ronald Sinclair Nohr, John Gavin MacDonald
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Patent number: 5565306Abstract: The present invention provides a thermofixable photosensitive recording material comprising a substrate and a recording layer formed thereon in which a pyrazolone derivative represented by the formula (1 ) shown in the specification and functions as a color former, and a hydroquinone derivative and an acidic substance which function as a color forming auxiliary agent or fixing auxiliary agent are dissolved mutually therein.Further, a binder can be added as required to the recording layer, thereby four components are dissolved mutually therein.Type: GrantFiled: January 30, 1995Date of Patent: October 15, 1996Assignee: New OJI Paper Co., Ltd.Inventors: Tatsuya Meguro, Nobuhisa Danou, Tetsuo Tsuchida, Naoto Arai