Heterocyclic Patents (Class 430/343)
  • Patent number: 5534393
    Abstract: Certain squaric acid derivatives are useful for the thermochemical generation of acid. The squaric acid derivatives may be used in imaging media in conjunction with acid-sensitive materials which undergo a color change when contacted by the acid generated from the squaric acid derivatives. Preferably, the acid-sensitive materials undergo an irreversible color change, so that the image can be fixed by neutralizing all the acid generated with excess base, thereby preventing further color change in the image during long term storage.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: July 9, 1996
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, Jurgen M. Grasshoff, Mark R. Mischke, Anthony J. Puttick, Stephen J. Telfer, David P. Waller, Kenneth C. Waterman
  • Patent number: 5510224
    Abstract: A photosensitive microcapsule which contains a polymerizable monomer and a polymerization initiator has increased sensitivity due to the displacement of soluble water in the monomer photosensitive microcapsule comprises a polymerizable monomer contained in a microcapsule; a photopolymerization initiator comprising a hydrophobic sensitizer for initiating polymerization of the polymerizable monomer in response to incident light energy; and an image producing material such as a dye or a precursor; wherein the hydrophobic sensitizer includes at least one of 3,7-bis (octadecylmethylamino) phenothiazoniumchloride which reacts on a red color light energy, 3,7-di(octadecylmethylamino)-5-phenylphenaziniumchloride which reacts on a green color light energy, and 3,6-di(octadecylmethylamino)-acridinechloride which reacts on a blue color light energy.
    Type: Grant
    Filed: October 6, 1993
    Date of Patent: April 23, 1996
    Assignee: Seiko Instruments Inc.
    Inventors: Hiroshi Takahashi, Toshihiko Sakuhara, Fumiharu Iwasaki
  • Patent number: 5494772
    Abstract: A heat-sensitive recording material comprising on a support a heat-sensitive layer comprising color-forming component A, color-forming component B which forms a color by reacting with the color-forming component A, and a tricarbocyanine dye having at least two acidic groups, wherein the tricarbocyanine dye has an absorption maximum wavelength of 650 to 1300 nm in the heat-sensitive layer and has an absorption maximum wavelength 50 nm or more longer than that of an aqueous solution of the tricarbocyanine dye.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: February 27, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Hosoi, Koh Takeuchi, Yoshio Inagaki
  • Patent number: 5476755
    Abstract: An image forming element and an image forming method using the same are disclosed. The element comprises a support having thereon a image forming layer comprising a binder, an aromatic aldehyde, a cobalt (III) complex represented by formula I, and a compound represented by formula II or formula III;Co.sup.3 +(L)p(X)q (I)wherein L is a coordination compound capable of forming a complex compound with the cobalt cation and at least one of which is NH.sub.3 or a primary amine; X is a counter anion; p is an integer of 1 to 6; when p is 2 to 6, the plural Ls may be the same or different; and q is an integer of 1 to 3, ##STR1## wherein lig is a coordination compound capable of forming with the cobalt cation; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently an alkyl group, an aryl group, an aralkyl group, an alkenyl group, an alkinyl group, a cycloalkyl group, a heterocyclic group or a cyano group; n.sub.1 is an integer of 1 to 6, when n.sub.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: December 19, 1995
    Assignee: Konica Corporation
    Inventors: Noritaka Nakayama, Norio Miura, Yoriko Nakayama, Tawara Komamura, Toshihisa Takeyama
  • Patent number: 5432048
    Abstract: A rewritable photochromic optical disc which comprises a photochromic recording layer made of a diaryl ethene derivative capable of assuming first to third states, the first state with a first absorption band transforming into the second state with a second absorption band in response to light of a first wavelength, the second state transforming into the first state in response to light of a second wavelength in said second absorption band, the fist state transforming into the third state with a third absorption band in response to light of a third wavelength, and the third state transforming into the first state in response to light of a fourth wavelength in said third absorption band.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: July 11, 1995
    Assignee: Pioneer Electronic Corporation
    Inventors: Hitoshi Taniguchi, Fumio Matsui
  • Patent number: 5432049
    Abstract: Compounds of the formula I ##STR1## in which X is O, S, SO, SO.sub.2 or NR.sub.13, R.sub.13 is, for example, methyl, and R.sub.1 to R.sub.12, independently of one another, are, for example, H, C.sub.1 -C.sub.12 alkyl, C.sub.1 14 C.sub.12 alkoxy, halogen or --CN. The compounds are photosensitive and photochromic and as suitable are photosensitizers and simultaneously as colour indicators, and as photoswitchable colour filters.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: July 11, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Evelyn Fischer, Walter Fischer, Jurgen Finter, Kurt Meier, Martin Roth
  • Patent number: 5411929
    Abstract: There are disclosed thermally-processable image recording materials comprising a support carrying thereon; a di- or triarylmethane thiolactone dye, an organic silver salt, a binder; and a select group of substituted purine compounds for reducing a post-processed formation of a yellowish-brown color (gilding) within such materials.
    Type: Grant
    Filed: June 30, 1994
    Date of Patent: May 2, 1995
    Assignee: Polaroid Corporation
    Inventors: Maureen F. Ford, Donna J. Guarrera, Mark R. Mischke, Ramdas P. Pai, John C. Warner
  • Patent number: 5401619
    Abstract: Certain squaric acid derivatives are useful for the thermochemical generation of acid. The squaric acid derivatives may be used in imaging media in conjunction with acid-sensitive materials which undergo a color change when contacted by the acid generated from the squaric acid derivatives. Preferably, the acid-sensitive materials undergo an irreversible color change, so that the image can be fixed by neutralizing all the acid generated with excess base, thereby preventing further color change in the image during long term storage.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: March 28, 1995
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, Jurgen M. Grasshoff, Mark R. Mischke, Anthony J. Puttick, Stephen J. Telfer, David P. Waller, Kenneth C. Waterman
  • Patent number: 5389489
    Abstract: An image-forming material which includes on a support a coating layer containing at least (A) a microcapsule, which encapsulates (1) a leuco dye that forms color upon oxidative development and (2) a photooxidizing agent and (B) a reducing agent, wherein the leuco dye is a xanthene derivative represented by the following formula (1): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each designates a hydrogen atom, an alkyl group, an aralkyl group, or an aryl group; R.sup.3 designates a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, a halogen atom, an alkoxy group, an aryloxy group, an alkylthio group, or an arylthio group; R.sup.4 and R.sup.5 which may be the same or different, each designates a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, a trifluoromethyl group, a substituted carbonyl group, or a substituted sulfonyl group; and R.sup.6 designates a hydrogen atom, an alkyl group, or a substituted carbonyl group; andwherein R.sup.1 and R.sup.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: February 14, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Yanagihara, Tosiaki Endo, Naotaka Wachi
  • Patent number: 5372917
    Abstract: The present invention provides a recording material utilizing a reaction between a colorless or light-colored dye precursor and a color developer capable of forming a color upon coming into contact with the dye precursor, the recording material being characterized in that the material comprises at least one compound serving as the dye precursor and represented by the formula (1), and an acidic substance serving as the color developer ##STR1## wherein R.sub.1 to R.sub.6, p and q are defined in the specification. At least one selected from the group consisting of phenolic compounds of the formulae (10), (11) and (12) and phenolic resin having a partial structure of the formula (13) can be used, as required, to further improve the color forming properties and change the color of recorded images from reddish purple or purple to blue or dark blue.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: December 13, 1994
    Assignee: Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Tetsuo Tsuchida, Tatsuya Meguro, Takaaki Kouro, Haruo Omura
  • Patent number: 5338643
    Abstract: Disclosed herein is a photosensitive composition comprising:(A) 5 to 60 wt % of an o-quinonediazide compound;(B) 0.05 to 10 wt % of an s-triazine compound(C) 0.01 to 10 wt % of a dye for changing the color tone by the interaction with the photodecomposition product of the said s-triazine compound;(D) 30 to 90 wt % of a novolak resin containing less than 5 wt % of phenols; and(E) 1 to 60 wt % of a vinyl-based polymer having at least a phenolic hydroxyl group.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: August 16, 1994
    Assignees: Mitsubishi Kasei Corporation, Konica Corporation
    Inventors: Daisuke Kanazawa, Mitsuru Sasaki, Toshiyuki Urano, Youko Yamashita, Shinichi Matsubara
  • Patent number: 5332654
    Abstract: A novel class of N-substituted triarylmethane sulfonamides is provided which undergo reversible oxidation into colored form and reversible reduction of the oxidized form into colorless form. Preferred embodiments comprise xanthene sulfonamides having N-aryl substituents, e.g., hydroquinone substituents. These compounds possess redox potentials ranging between about +200 to -500 millivolts and thus are useful as dyes for producing photographic, photothermographic, thermal, and pressure-induced images, as well as being useful as redox indicators in a wide variety of biological and chemical reactions.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: July 26, 1994
    Assignee: Polaroid Corporation
    Inventors: Myron S. Simon, Marcis M. Kampe, David P. Waller
  • Patent number: 5330864
    Abstract: Phothermographic material capable of producing a high density cyan image upon image-wise exposure and thermal development at a relatively low temperature and for a short period of time. The photothermographic material of the invention comprise coated on a support base at least one light-sensitive emulsion layer containing: (a) a binder; (b) a silver source material; (c) a light sensitive silver halide in catalytic proximity to said silver source material, wherein said emulsion layer or an adjacent layer thereto comprises a chromogenic cyan leuco dye.The photothermographic material of the invention may be used to obtain good cyan image of suitable density in single color or multicolor photothermographic articles. At the same time the chromogenic leuco dye is stable enough not to be oxidized by oxygen of the air or by simple heating and to limit the fog formation after development.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: July 19, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Raffaella Biavasco, Cristina Soncini
  • Patent number: 5322750
    Abstract: An optical recording medium and a method of writing, reading and erasing information in an optical recording medium are provided in which the optical recording medium comprises a carrier and a recording layer which contains at least one optically active organic compound, wherein said optically active organic compound is an inherently chiral dissymmetric olefinic chromophore.
    Type: Grant
    Filed: April 24, 1991
    Date of Patent: June 21, 1994
    Assignee: U.S. Philips Corporation
    Inventors: Egbert W. Meijer, Bernard L. Feringa, Wolter F. Jager, Ben De Lange
  • Patent number: 5320936
    Abstract: Thiophene derivatives represented by the general formula (I): ##STR1## where R is an aldehyde, carboxyl, C.sub.1-5 -alkyl ester or C.sub.1-5 -alkyl acetal group and n is 3 to 5, are prepared. These compounds are reversibly converted to their respective isomers by light irradiation, accompanied with a large shift of absorption and emission bands, thus suitable for a photo-responsive material.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: June 14, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroaki Kumagai, Tomokazu Iyoda, Takeo Shimizu
  • Patent number: 5294522
    Abstract: A novel photochromic compound as a photoreactive material making use of photochromism is provided, which compound is expressed by the following formula (1) or (2)): ##STR1## wherein R is alkyl, alkoxy, perfluoroalkyl or cyano; X.sub.1, X.sub.2, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are each H, halogen, alkyl, alkoxy, cyano, alkanoyloxy or alkyloxycarbonyl, or a substituted or unsubstituted benzene ring is formed by condensation between at adjacent groups among X.sub.1 to X.sub.6 ; Y is Y.sub.1 C=CY.sub.2, O, S, SO, SO.sub.2 or NY.sub.3 wherein Y.sub.1 and Y.sub.2 are each as defined in the case of the above X.sub.1 to X.sub.6 and Y.sub.3 is H, alkyl, alkanoyl, alkyloxycarbonyl or aryl; and the symbol refers to occurrence of E- or Z-isomer, and which compound is useful as rewritable optical memory element or photo-display element and also as solar energy-storage material, duplicating material, masking material, optical filter, toys, etc.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: March 15, 1994
    Assignee: Chisso Corporation
    Inventors: Manabu Uchida, Masahiro Irie
  • Patent number: 5244769
    Abstract: A light-sensitive image-forming material is disclosed, comprising a support having thereon a recording layer containing a leuco dye which forms color upon oxidative development, a photo-oxidizing agent and a reducing agent, wherein the leuco dye is an xanthene compound having a cyclic amino group at the 2-position. The light-sensitive image-forming material of the present invention provides an image having satisfactory color density and stability to light after imagewise exposure and fixation.
    Type: Grant
    Filed: March 7, 1991
    Date of Patent: September 14, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Yanagihara, Akihiko Takeda, Akira Igarashi
  • Patent number: 5227495
    Abstract: A cyanine compound of the following formula: ##STR1## wherein T.sup.1 and T.sup.2 each independently represents an atomic group which is necessary for forming a condensed benzene ring; L.sup.3 represents a methine group or a trivalent connecting group formed by conjugated double bonding of 3, 5 or 7 methine groups; R.sup.21, R.sup.22, R.sup.23 and R.sup.24 each independently represents an alkyl group having 1 to 12 carbon atoms or a phenyl group both of which may or may not be substituted; Y is an anion and q is a number which is necessary for neutralizing a positive charge; provided that at least one of R.sup.21, R.sup.22, R.sup.23 and R.sup.24 is an alkyl group having 3 or more carbon atoms and which may or may not be substituted when L.sup.3 consists of 1, 3 or 5 methine groups.The cyanine compound can be used as a coloring material, a sensitizing dye for photographic use, a recording dye for use in optical information recording media, a staining agent, a pharmaceutical agent, and the like.
    Type: Grant
    Filed: January 10, 1991
    Date of Patent: July 13, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Inagaki, Masao Yabe
  • Patent number: 5219700
    Abstract: A photosensitive composition comprising (a) a 1,2-naphthoquinone-2-diazido-4-sulfonic acid ester compound, (b) alkali-soluble resin, (c) a halomethyloxadiazole compound which releases halogen free radicals by irradiation with actinic rays and (a) a dye which interacts withthe decomposition product of said halomethyloxydiazole compound and discolors or develops color. The composition exhibits excellent development latitude, light safety, visible-on-exposure characteristic and printing resistance.
    Type: Grant
    Filed: March 24, 1992
    Date of Patent: June 15, 1993
    Assignees: Mitsubishi Kasei Corporation, Konica Corporation
    Inventors: Hideyuki Nakai, Kiyoshi Goto, Hiroshi Tomiyasu, Yoshiko Fujita
  • Patent number: 5206118
    Abstract: A color-change dosimeter film made of a halogen-containing polymer in which is dispersed an acid-sensitive leuco dye, which dye a) is substantially free from groups that are sensitive to high-energy radiation and b) becomes colored in acid. This color-change dosimeter film (1) remains substantially colorless upon exposure to artificial illumination, including fluorescent light, for at least several months, (2) becomes colored upon exposure to high-energy radiation and accurately indicates small changes in dosage by the intensity of its color, and (3) remains substantially unchanged in its intensity of that color after being stored for several months, whether or not exposed to artificial illumination. An article of either quantitative or qualitative determination of the extent of high-energy radiation exposure is also provided, displaying a colored message of words, codes, symbols, or patterns on a substrate after exposure to the high-energy radiation.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: April 27, 1993
    Assignee: Minnesota-Mining & Manufacturing Company
    Inventors: Lu Ann N. Sidney, Doreen C. Lynch, Peggy S. Willett
  • Patent number: 5198323
    Abstract: A resist composition comprising an alkali-soluble resin, a 1,2-quinone diazide compound and a compound of the general formula (I): ##STR1## wherein Z is an oxygen or sulfur atom or a group of the formula: >N--R.sub.4 in which R.sub.4 is a hydrogen atom or an alkyl group; R.sub.1, R.sub.2 and R.sub.3 are the same or different and independently a hydrogen atom, a substituted or unsubstituted alkyl group, a halogen atom, a hydroxyl group, a cyano group or a group of the formula: --OCOR" in which R" is a substituted or unsubstituted alkyl group; and X and Y are independently a cyano group or a group of the formula: ##STR2## --COOR or --CONHR' in R is an alkyl group and R' is a hydrogen atom or an aryl group, which is suitable for the formation of very fine patterns on a substrate having a high reflectance.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: March 30, 1993
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Teijiro Kitao, Masaru Matsuoka, Ryotaro Hanawa, Yasunori Uetani, Naoki Takeyama, Takeshi Hioki, Hiroshi Takagaki
  • Patent number: 5196297
    Abstract: This invention relates to novel recording materials which employ color-forming di- and triarylmethane compounds possessing certain S-containing ring-closing moieties, namely, or thiolactone, dithiolactone or thioether ring-closing moiety and to a method of forming color by contacting these dye precursor compounds with a Lewis acid material capable of opening the thiolactone, dithiolactone or thioether ring-closing moiety whereby the compound is rendered colored, that is, converted to its chromophore color.
    Type: Grant
    Filed: December 5, 1986
    Date of Patent: March 23, 1993
    Assignee: Polaroid Corporation
    Inventors: Edward J. Dombrowski, Jr., James R. Freedman, Patrick F. King
  • Patent number: 5192645
    Abstract: A thermal imaging method for forming color images is provided which employs as the color image-forming material, a colorless precursor of a preformed image dye possessing at least one thermal protecting group that undergoes fragmentation upon heating and at least one leaving group that undergoes irreversible elimination upon heating, said protecting and leaving groups maintaining the precursor in its colorless form until heat is applied to effect removal of these groups whereby the precursor is converted to an image dye.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: March 9, 1993
    Assignee: Polaroid Corporation
    Inventors: Roger A. Boggs, Alan L. Borror, Patrick R. Conlon, Richard L. Cournoyer, Ernest W. Ellis, David P. Waller
  • Patent number: 5192644
    Abstract: An improved optical memory device comprising a substrate and a plurality of optical memory layers made of a photochromic material and formed over the substrate, the plurality of optical memory layers being laminated to each other through a heat conductive transparent film, which is adaptable for high density and/or high capacity recording of information.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: March 9, 1993
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kenji Ohta, Kazuo Van
  • Patent number: 5187049
    Abstract: A photothermographic composition is disclosed comprising a sensitizing dye and the salt of an oxidizing acid and a leuco dye, wherein said acid consists of a Group V, VI, or VII element and oxygen.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: February 16, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Frank T. Sher, David R. Whitcomb
  • Patent number: 5183726
    Abstract: A light-sensitive recording medium using a photochromic material produced at a low cost, without necessity of fixing free rotation of bonds in its cis compound and removing its trans compound, is disclosed, the recording medium comprising a substrate having thereon a recording layer which contains a photochromic material capable of cis-trans isomerization upon irradiation with light, wherein not more than 50 mol % of the photochromic material has a trans configuration when the recording layer is in a color-disappearing state.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: February 2, 1993
    Assignee: Pioneer Electronic Corporation
    Inventors: Hitoshi Taniguchi, Fumio Matsui
  • Patent number: 5180652
    Abstract: A light- and heat-sensitive composition which contains a photo-hardenable composition and at least one dye, a light- and heat-sensitive recording material which contains a support having the composition provided on at least one side thereof, and an image-forming process using the recording material are disclosed.
    Type: Grant
    Filed: January 18, 1990
    Date of Patent: January 19, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jun Yamaguchi, Sadao Ishige, Kozo Sato, Shintaro Washizu, Isamu Itoh
  • Patent number: 5175079
    Abstract: An optical memory device comprising:a transparent substrate; anda recording film deposited on the transparent substrate, the recording film being formed by preparing a composition in which a diarylethene-type photochromic compound is dispersed in an ultraviolet-curing polyurethaneacrylate resin of solventless type and by curing the composition by an ultraviolet ray irradiation.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: December 29, 1992
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kazuo Van, Kenji Ohta, Yoshiteru Murakami
  • Patent number: 5145767
    Abstract: Novel thermally sensitive imageable layers comprising a leuco dye oxidizing acid salt are disclosed, wherein said acid consists of a Group V, VI, or VII element and oxygen.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: September 8, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: David R. Whitcomb, Frank T. Sher
  • Patent number: 5145760
    Abstract: High resolution, photosensitive electrostatic master which is positive-working with a single imagewise exposure comprising a conductive support bearing a layer of a photosensitive composition consisting essentially of (a) at least two polymeric binders, at least one binder having a Tg greater than 80.degree. C. and at least one binder having a Tg of 70.degree. C. or less such that the shift in transit time (a.sub.T) of the photosensitive layer in the range of 30%.ltoreq.relative humidity.ltoreq.60% and 65.degree. F. (18.3.degree. C.).ltoreq.temperature .ltoreq.80.degree. F. (26.7.degree. C.) is 10 or less, (b) a hexaarylbiimidazole photooxidant, (c) leuco dye, preferably stabilized, oxidized by (b), (d) a nonionic halogenated compound, preferably a hydrocarbon, and (e) at least one compatible plasticizer. A process of making positive images by a single imagewise exposure is described.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: September 8, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Graciela B. Blanchet-Fincher, Catherine T. Chang, Richard J. Kempf
  • Patent number: 5141841
    Abstract: A radiation-sensitive compound has the general formula ##STR1## wherein A represents the ring members required to complete a 5- or 6-membered heterocyclic ring which may optionally be fused to an optionally substituted aromatic nucleus,B represents H, acyl, aroyl, heterocyclyl carbonyl or ##STR2## R represents an optionally substituted alkyl group, E and G, which may be the same or different, each represents H or CH.sub.p X.sub.3-p,J and K, which may be the same or different, each represents an aryl or heterocyclic group, which may optionally include a substituent additional to E or G,X represents Cl or Br, and m,n and p, which may be the same or different, each represents an integer equal to 0, 1 or 2.The compound can be used to form radiation sensitive compositions for the production of radiation sensitive plates in lithographic printing plate manufacture.
    Type: Grant
    Filed: August 17, 1989
    Date of Patent: August 25, 1992
    Assignee: Vickers PLC
    Inventor: John R. Wade
  • Patent number: 5126233
    Abstract: This invention is directed to a compound which is 4-(4'-(N',N'-dimethylamino)phenyl)-2-(2'-n-octyloxyphenyl)-6-phenyl pyridine.
    Type: Grant
    Filed: February 20, 1991
    Date of Patent: June 30, 1992
    Assignee: The Mead Corporation
    Inventors: Ramamurthi Kannan, Steven L. Yeager
  • Patent number: 5091535
    Abstract: An organic photochromic compound with improved long term preservability, thermal stability, the repetition character of the record and the like and useful as recording-memory materials or photosensitizers, comprising dimers of the compounds selected from the group consisting of pyrido[3,4-g]isoquinoline, pyrido[2,3-g]quinoline, pyrido[3,2-g]quinoline and pyrido[3,2-g]quinoline derivatives.
    Type: Grant
    Filed: April 24, 1990
    Date of Patent: February 25, 1992
    Assignee: Seikisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shigeru Nomura, Takahiro Hidaka
  • Patent number: 5077178
    Abstract: Disclosed are photothermographic constructions containing at least a plurality of light-sensitive layers which are separated by barrier layers composed of a polymer, e.g., ethyl cellulose and polyethylene terephthalate, having an energy activation of permeability (E.sub.p) of less than about 30 kJ/mole. The barrier layers must be substantially insoluble in the light sensitive layers and vice versa. Each light sensitive layer contains a nitrate salt, leuco dye, binder, and optionally, a photoinitiator. The photothermographic construction is capable of effectively reproducing full color images.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: December 31, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Alan J. Herbert, Susan K. Jongewaard, David R. Whitcomb
  • Patent number: 5064741
    Abstract: A light-sensitive composition is herein disclosed, which comprises at least one free radical generator represented by the following general formula: ##STR1## and at least one discoloring agent which interacts with products generated through the photolytic degradation of the free radical generator to change the color tone of the composition. The composition has a high stability with time and a good printing out property and therefore it can be used in making light-sensitive layer of PS plates, photoresists, proof plates for printing and films for overhead projector, intermediate print and photomask having high sensitivity long shelf life.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: November 12, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akinobu Koike, Yukio Abe, Koichi Kawamura
  • Patent number: 5061582
    Abstract: The invention describes an optical data storage medium in which the optical contrast of stored data bits is enhanced by the use, as a photosensitive material or as an additional photosensitive material, of a layer of a photochromic fulgide.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: October 29, 1991
    Assignee: Plessey Overseas Limited
    Inventors: Jack Brettle, Ian Bennion, Christopher J. Groves-Kirkby
  • Patent number: 5051333
    Abstract: An optical image-recording material comprising:(a) microcapsules, in which at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules, or(c) microcapsules, in which at least one reducing agent is enclosed, and (d) both at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent not enclosed in the microcapsules,wherein the microcapsules have capsule walls made from a material which lowers its permeability barrier to at least one component selected from the photo-oxidizing agent and the reducing agent when the capsule wall material is heated above its glass transition temperature, and the leuco dye is a xanthene compound having an N-substituted anilino group substituted by an electron attracting group.
    Type: Grant
    Filed: June 21, 1990
    Date of Patent: September 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Yanagihara, Ken Iwakura, Tosiaki Endo, Keiso Saeki
  • Patent number: 5004674
    Abstract: A silver halide photosensitive material comprising a support having thereon a layer containing (a) an organic compound which releases a free radical on contact with light rays and (b) a compound which undergoes a change in the absorption spectrum due to the action of the released free radical.
    Type: Grant
    Filed: October 13, 1989
    Date of Patent: April 2, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiichi Adachi, Kazunobu Katoh, Kouichi Kawamura
  • Patent number: 4997745
    Abstract: A photosensitive composition comprising a trihalomethyl-s-triazine compound and a photosensitizer, wherein the photosensitizer being a dye having a reduction potential not more than 0.10 volt higher than the reduction potential of the trihalomethyl-s-triazine compound, and a photopolymerizable composition employing the photosensitive composition.
    Type: Grant
    Filed: August 11, 1989
    Date of Patent: March 5, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouichi Kawamura, Hirotaka Matsumoto, Jun Yamaguchi
  • Patent number: 4966828
    Abstract: Disclosed is a compound of the general formula ##STR1## wherein L=H or CO--(R.sup.1).sub.n (CX.sub.3).sub.m, M=alkylene, alkenylene, Q=S, Se, O, dialkylmethylene, alken-1,2-ylene, 1,2-phenylene or N-R, with M+Q together forming 3 or 4 ring members, R=alkyl, aralkyl or alkoxyalkyl, R.sup.1 is an aromatic group and X=Cl, Br or I, with n=O and m=1 or n=1 and m=1 or 2. The compounds, on exposure, eliminate HX and form free radicals and are therefore highly effective as acid donors and free radical initiators for photochemical processes.
    Type: Grant
    Filed: September 13, 1984
    Date of Patent: October 30, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Reinhard Doenges, Hans Ruckert, Ulrich Geissler, Hartmut Steppan
  • Patent number: 4962011
    Abstract: Novel photopolymerizable recording materials suitable in particular for producing photoresist layers and lithographic printing plates are composed of one or more photopolymerizable, olefinically unsaturated organic compounds, optionally a polymeric binder, a photopolymerization initiator, a color-forming system composed of a color former and a photooxidant, a certain benzotriazole compound as a sensitizer and optionally further additive and/or auxiliary substances.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: October 9, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhard Aldag, Peter Neumann, Andreas Boettcher, Thomas Bluemel, Friedrich Seitz
  • Patent number: 4960678
    Abstract: A compound represented by the following general formula [I] ##STR1## wherein ##STR2## represents a norbornylidene group or an adamantylidene group each of which may have a substituent, andX represents an oxygen atom, the group >N--R.sub.2, the group >N--A.sub.1 --B.sub.1 --A.sub.2).sub.m (B.sub.2).sub.n R.sub.3, the group >N--A.sub.3 --A.sub.4, or the group >N--A.sub.3 --A.sub.4, provided that when ##STR3## is an adamantylidene group, X is selected from the above groups excepting the oxygen atom and the group >N--R.sub.2 ; and plastic lens containing the compound of the above formula [I].
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: October 2, 1990
    Assignee: Tokuyama Soda Kabushiki Kaisha
    Inventors: Takashi Tanaka, Satoshi Imura, Yasuji Kida
  • Patent number: 4942113
    Abstract: The contrast and sharpness of photoresist images is enhanced by depositing a layer of a photobleachable compound onto the photoresist layer. The photobleachable layer is sensitive to the light used to expose the photoresist and forms a contrast enhancement layer (CEL) on the photoresist layer. Fulgides and photochromic butyrolactones are selected for forming the photobleachable layer. Such compounds can be deposited from a hydrocarbon solution, such as toluene, and are soluble in the standard alkali, photoresist developers. The process is particularly advantageous for producing integrated circuits.
    Type: Grant
    Filed: March 6, 1989
    Date of Patent: July 17, 1990
    Assignee: Plessey Overseas Limited
    Inventor: Clive Trundle
  • Patent number: 4940649
    Abstract: Novel photopolymerizable recording materials suitable in particular for producing photoresist layers and lithographic printing plates are composed of one or more photopolymerizable, olefinically unsaturated organic compounds, optionally a polymeric binder, a photopolymerization initiator, a color-forming system composed of a color former and a photooxidant, a certain 4-phenylpyridine as sensitizer and optionally further additive and/or auxiliary substances.
    Type: Grant
    Filed: May 17, 1988
    Date of Patent: July 10, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Reinhard Aldag, Peter Neumann, Andreas Boettcher, Thomas Bluemel, Friedrich Seitz, Friedrich-Wilhelm Raulfs
  • Patent number: 4882438
    Abstract: A compound represented by the following general formula [I] ##STR1## wherein ##STR2## represents a norbornylidene group or an adamantylidene group each of which may have a substituent, andX represents an oxygen atom, the group >N-R.sub.2, the group >N-A.sub.1 -B.sub.1 --A.sub.2).sub.m (B.sub.2).sub.n R.sub.3, the group >N-A.sub.3 -A.sub.4, or the group >N-A.sub.3 -R.sub.4, provided that when ##STR3## is an adamantylidene group, X is selected from the above groups excepting the oxygen atom and the group >N-R.sub.2 ; and plastic lens containing the compound of the above formula [I].
    Type: Grant
    Filed: November 8, 1988
    Date of Patent: November 21, 1989
    Assignee: Tokuyama Soda Kabushiki Kaisha
    Inventors: Takashi Tanaka, Satoshi Imura, Yasuji Kida
  • Patent number: 4874685
    Abstract: The present invention provide a dye-sensitized photopolymerizable composition comprising a free radical addition polymerizable material, and a photoinitiator, the photoinitiator consisting essentially of a photoreducible dye, a thiol, and an N,N'-dialkylaniline.
    Type: Grant
    Filed: November 27, 1987
    Date of Patent: October 17, 1989
    Assignee: The Mead Corporation
    Inventor: Paul C. Adair
  • Patent number: 4861700
    Abstract: Photographic elements comprising filter dyes of the formula: ##STR1## wherein A is a pyrrole or indole nucleus, with the tricyanovinyl radical occupying the 2 or 3 position of the nucleus.
    Type: Grant
    Filed: November 19, 1987
    Date of Patent: August 29, 1989
    Assignee: Eastman Kodak Company
    Inventors: Leslie Shuttleworth, Paul B. Merkel
  • Patent number: 4857438
    Abstract: A photochromic system contains an oxidizable leuco dye and a photochemically activated initiator which converts the leuco dye to the dye, the initiator being a phenanthroimidazole derivative.The photochromic system is useful for the production of photochromic layers for photoresists and printing plates.
    Type: Grant
    Filed: March 20, 1987
    Date of Patent: August 15, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Loerzer, Reinhold J. Leyrer
  • Patent number: 4853361
    Abstract: A heat- and light-sensitive recording material has a substrate and a color-forming layer which comprises a particular fluoran-type leuco dye.This heat- and light-sensitive recording material provides a clear image a superior contamination-resistance and an excellent readability in visible and near infrared range.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: August 1, 1989
    Assignee: Jujo Paper Co., Ltd.
    Inventors: Toshimi Satake, Toshiaki Minami, Tomoaki Nagai, Fumio Fujimura
  • Patent number: 4845011
    Abstract: A photo polymerization initiator composition is disclosed. The composition is comprised of an in admixture with an acridine, initiator compound. The initiator composition is useful is preparing photopolymerizable compositions having increased effective photospeed.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: July 4, 1989
    Assignee: Hoechst Celanese Corporation
    Inventors: Wojciech A. Wilczak, Margaret W. Geiger