Using Mercapto Or Thione Compound Patents (Class 430/445)
  • Patent number: 4390613
    Abstract: There is disclosed a diffusion transfer photographic system wherein development of an exposed photosensitive element with an aqueous alkaline processing composition is effected in the presence of a compound represented by the formula ##STR1## wherein X represents the nonmetallic atoms necessary to form a nucleus which completes a 5- or 6-membered heterocyclic moiety on said structure including substituted rings and fused rings; R is H, an alkali metal or a group which is cleavable in a photographic aqueous alkaline processing composition; and R.sub.1 is either a group which has a pKa of from about 7 to about 14 which is ionizable to an anion whereby the silver salt of the mercaptan (resulting from cleavage or ionization of --SR) is rendered more soluble in the pH range within which R.sub.1 is ionized to an anion than it is below that pH range, or a precursor of such a group.
    Type: Grant
    Filed: January 5, 1981
    Date of Patent: June 28, 1983
    Assignee: Polaroid Corporation
    Inventors: Avinash C. Mehta, George H. Nawn, Lloyd D. Taylor
  • Patent number: 4371610
    Abstract: A process for development-processing a silver halide black-and-white photographic light-sensitive material without silver stain and fog by the use of a developing solution which contains 0.1 mole/l or more of sulfite and at least one compound represented by the following general formula (I) or (II) ##STR1## wherein M represents a hydrogen atom, an alkali metal atom or an ammonium group; R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; n represents an integer of 1 to 8; and X represents a sulfonic acid group, a sulfonate group, a carboxylic acid group or a carboxylate group.
    Type: Grant
    Filed: July 24, 1981
    Date of Patent: February 1, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Toyoda, Isamu Itoh, Minoru Yamada
  • Patent number: 4350752
    Abstract: Imidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein: J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents hydrogen, alkyl or 1 to 4 carbon atoms or aryl of 6 to 12 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the imidomethyl blocking group.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: September 21, 1982
    Assignee: Eastman Kodak Company
    Inventors: James A. Reczek, Thomas R. Welter
  • Patent number: 4350754
    Abstract: There are described novel compounds which are represented by the formula ##STR1## wherein R is ##STR2## A is sulfur or selenium; X represents the nonmetallic atoms necessary to form a nucleus which completes a five or six membered heterocyclic moiety; R.sub.1 is H or lower alkyl; R.sub.2 is H or a hydrolyzable group; and R.sub.3 is H, alkyl or a hydrolyzable group. The compounds are useful in photographic applications and provide controlled release of a photographically useful material during processing of photographic elements with an aqueous alkaline processing composition.
    Type: Grant
    Filed: June 12, 1981
    Date of Patent: September 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Anthony J. Puttick
  • Patent number: 4346166
    Abstract: For making families of steady-state heat transfer coefficient curves visible, the invisible residual moisture profile obtained by exposing a moisture photogelatin layer to a gas is immersed, in daylight, in a soluble organic sulfur compound, particularly thioacetamide, and is converted into a silver sulfide line photogram. The method is used, for example, for making visible families of steady-state heat transfer coefficient curves on forced air-cooled electronic assemblies.
    Type: Grant
    Filed: February 20, 1981
    Date of Patent: August 24, 1982
    Assignee: Siemens Aktiengesellschaft
    Inventors: Bernhard Montag, Heinrich Optiz
  • Patent number: 4343893
    Abstract: Novel nitrobenzyl compounds are incorporated into a photographic emulsion or developer for controlled release of development/image modifier compounds. This occurs imagewise only after developer oxidation products have been formed in the course of the development process. For example, nitrobenzyl-masked phenylmercaptotetrazole (PMT), incorporated into a silver halide emulsion, reacts with developer oxidation products via an electron transfer mechanism to release the potent development restrainer PMT.
    Type: Grant
    Filed: July 25, 1980
    Date of Patent: August 10, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Dennis S. Donald, Ross A. Lee
  • Patent number: 4328302
    Abstract: A lithographic silver halide photographic light-sensitive material is described which scarcely exhibits colored fringe and black pepper, forms halftone dots of good quality whether a fresh or an exhausted developer is used for processing thereof, and which scarcely shows a drop in sensitivity even when a developer contaminated by a fixing solution is used; said material comprises a support and at least one lithographic silver halide emulsion layer, and containing in said emulsion layer or in another hydrophilic colliodal layer which does not contain silver halide emulsion at least one compound represented by formula (I) ##STR1## wherein M represents hydrogen, an alkali metal ion or --NH.sub.4.sup..sym. ; X represents --SO.sub.2 NHR', --COOM', --SO.sub.3 M', --OH or --CONH.sub.2, wherein M' represents hydrogen, an alkali metal ion or --NH.sub.4.sup..sym.
    Type: Grant
    Filed: February 9, 1981
    Date of Patent: May 4, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuo Nishimura, Hiroyuki Mifune, Yoshiharu Fuseya, Yukihide Urata, Tadao Shishido, Yasuo Kasama
  • Patent number: 4323643
    Abstract: A silver halide photographic light-sensitive material is described, comprising at least one silver halide photographic emulsion layer, wherein at least one layer contains a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents hydrogen, an aliphatic group, an aromatic group, or a heterocyclic group;R.sup.3 represents hydrogen or an aliphatic group, andX represents a divalent aromatic group.The light-sensitive material provides high-contrast negative images and good dot image quality.
    Type: Grant
    Filed: November 6, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano, Yoshitaka Akimura
  • Patent number: 4310621
    Abstract: New DIR-compounds of the formula ##STR1## are useful in photographic materials and processes.
    Type: Grant
    Filed: December 16, 1980
    Date of Patent: January 12, 1982
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Karl Frank, Reinhard Muller
  • Patent number: 4310622
    Abstract: A process is described for developing a black-and-white silver halide photosensitive material comprising treating the material with a developing solution containing a sludge preventing compound represented by the formula (I) ##STR1## wherein X represents hydrogen, a hydroxyl group, a lower alkyl group, a lower alkoxy group, a halogen atom, a carboxyl group or a sulfo group, and M.sup.1 and M.sup.2, which may be the same or different, each represents hydrogen, an alkali metal atom, or an ammonium group.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: January 12, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinzaburo Onda, Eiichi Okutsu, Isamu Itoh, Hiroyuki Mifune
  • Patent number: 4272606
    Abstract: A method of forming an extremely high-contrast negative photographic image which comprises image-wise exposing a photographic light-sensitive material comprising a support having thereon a mono-disperse silver halide emulsion layer containing surface latent image type silver halide grains and also containing a compound represented by the following general formula (1):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group, R.sup.2 represents a hydrogen atom, a phenyl group or an unsubstituted alkyl group having 1 to 3 carbon atoms, and then processing the exposed light-sensitive material in the presence of a compound having a thioamido moiety in the molecule thereof.
    Type: Grant
    Filed: February 1, 1980
    Date of Patent: June 9, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Yoshiharu Fuseya
  • Patent number: 4250252
    Abstract: In a color photographic material wherein by color development there are produced either non-diffusing image dyes or diffusing image dyes (the latter being transferred to an image-receiving layer) the color development is controlled by means of non-diffusing thioether compounds which on color development release a diffusing mercapto compound but do not themselves form a dye. The mercapto compound inhibits the development of the silver halide and the thioether compound has the formula ##STR1## R.sub.1 =hydrogen or alkyl with 1-3 carbon atoms R.sub.2 =alkyl with up to 22 carbon atoms the group --S--Y is split off during color development and forms a mercaptane, e.g. 5-mercapto-1-phenyltetrazole, which inhibits the development.
    Type: Grant
    Filed: October 3, 1975
    Date of Patent: February 10, 1981
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Heinrich Odenwalder, Hans Vetter, Walter Puschel, Erwin Ranz
  • Patent number: 4234678
    Abstract: A photographic material having a light-sensitive silver halide emulsion layer coated on a support and containing a compound, useful as a development inhibitor of the formula: ##STR1## wherein X, Y and Z are as herein defined, is described.
    Type: Grant
    Filed: November 20, 1978
    Date of Patent: November 18, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shinji Yoshimoto, Mitsuto Fujiwhara, Shoji Kikuchi, Ryosuke Satoh, Takaya Endo, Satoshi Nakagawa
  • Patent number: 4226934
    Abstract: A light-sensitive photographic material is provided which comprises, coated on a photobase, at least one silver halide emulsion layer, said emulsion layer or a layer adjacent thereto containing a development inhibitor releasing compound of the formula ##STR1## wherein R.sub.1 is substituted phenyl which contains a ballasting alkyl group, R.sub.2 represents the atoms necessary to complete a five or six membered heterocyclic ring system which may be further substituted and R.sub.3 is an aryl or heterocyclic radical, any of which ring systems may be further substituted, the group --S--R.sub.3 being a development inhibiting group.
    Type: Grant
    Filed: July 26, 1978
    Date of Patent: October 7, 1980
    Assignee: Ciba-Geigy AG
    Inventors: Terence C. Webb, David L. R. Reeves
  • Patent number: 4210714
    Abstract: Process for the preparation of silver images by imagewise exposure of a photographic material comprising at least one light-sensitive silver halide emulsion layer and treatment of the material with a developer composition, wherein the improvement comprises the development is carried out in the presence of 3-mercapto-5-(2-furyl)-1,2,4-triazole. The 3-mercapto-5-(2-furyl)-1,2,4-triazole decreases the fog during development, and when this is the first development in a black-and-white or color reversal process, increases the reversal silver or color density.
    Type: Grant
    Filed: March 15, 1978
    Date of Patent: July 1, 1980
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Heinrich Odenwalder, Anita von Konig, Franz Moll, Walter Patzold, Lothar Rosenhahn, Friedhelm Sommer
  • Patent number: 4202695
    Abstract: Fine-grain silver halide emulsions of the Lippmann-type are described which comprise derivatives of heterocyclic mercaptans corresponding to the formulae: ##STR1## wherein: each of Z.sub.1 and Z.sub.2 represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring system,n is 0 or 1,X is --CO-- or --CS--,R is an alkyl group or an aryl group, andY is --CO--, --COO--, --CS--, --SO.sub.2 --, --CON(R.sub.1)-- or --CSN(R.sub.1)--, R.sub.1 being hydrogen, alkyl or aryl.Both in reversal and negative processing sharpness of fine detail is improved and the distortion of image-details is reduced. Upon reversal processing yellow staining is also reduced.
    Type: Grant
    Filed: January 30, 1975
    Date of Patent: May 13, 1980
    Assignee: AGFA-GEVAERT N.V.
    Inventors: Herman A. Philippaerts, Robert J. Pollet, Wolfgang Muller-Bardorff, Wilhelm Saleck, Anita von Konig, Walter Gauss, Franz Moll, Theofiel H. Ghys
  • Patent number: 4199354
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photograhically useful group.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Paul B. Condit
  • Patent number: 4174969
    Abstract: For controlling in a color photographic material the gradation, graininess, sharpness, edge and interimage effect and thus improving the overall color reproduction thioether DIR compounds of the following formula are particularly useful: ##STR1## in which X is a group that if split off together with the sulfur atom forms a diffusing development inhibiting mercaptan, Y represents --O--, ##STR2## or --S--, Z represents the ring members completing a 6-membered heterocyclic ring, R.sup.1 is an aliphatic, araliphatic or aromatic hydrocarbon group, a heterocyclic group or acyl, and R.sup.2 is the same as R.sup.1 or hydrogen.
    Type: Grant
    Filed: April 15, 1977
    Date of Patent: November 20, 1979
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Heinrich Odenwalder, Erwin Ranz