Phenol Or Naphthol Coupler Patents (Class 430/473)
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Patent number: 4863836Abstract: There is provided a method for processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific amino compound. According to this method the stability and color forming property of a color developer are improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened. There is also provided a color developer composition which can be used as the developer, as it is or after adjusting its composition.Type: GrantFiled: February 22, 1988Date of Patent: September 5, 1989Assignee: Fuji Photo Film, Co., Inc.Inventors: Takatoshi Ishikawa, Nobutaka Ohki, Morio Yagihara
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Patent number: 4830948Abstract: A method of forming color photographic images where a silver halide color photographic material containing a coupler which forms a dye by reaction with the oxidation product of an aromatic primary amine developing agent and containing an acid-processed gelatin in an amount of 25% by weight or more of the amount of the total gelatin coated is color developed, desilvered and then rinsed in water and/or stabilized. The total of the processing time of said desilvering, rinsing-in-water and stabilization steps is controlled to be 3 minutes or less, and/or the amount of replenisher added to the rinsing-in-water bath and stabilization bath is controlled to be from 0.5 to 50 times of the amount of the processing solution which is brought into the rinsing-in-water bath and stabilization bath from the desilvering bath together with the material which is being processed.Type: GrantFiled: March 17, 1988Date of Patent: May 16, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Genichi Furusawa, Takeshi Hirose
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Patent number: 4812389Abstract: A process for processing a DIR coupler-containing silver halide color photographic material for photographing use in a continuous manner with replenishment of a developer is disclosed in which said DIR coupler is a coupler which has in a coupling site a group that functions as a development inhibitor or a development inhibitor precursor upon being eliminated from the coupling active site by color development processing and that will be decomposed to a compound exerting substantially no influences on photographic properties after flowing into a color developing solution, said development inhibitor having a half-value period of 4 hours or shorter than that at a pH of 10.0, and in which the developing solution is replenished in an amount of 700 ml or less per m.sup.2 of developed light-sensitive materials.Type: GrantFiled: September 25, 1986Date of Patent: March 14, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kei Sakanoue, Seiji Ichijima, Shinzo Kishimoto
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Patent number: 4766060Abstract: A silver halide photographic material containing a cyan coupler represented by the formula: ##STR1## wherein, R.sub.1 is selected from the group consisting of an acylamino group, an alkylsulfonamido group, an arylsulfonamido group, a carbamoyl group, a sulfamoyl group, an alkylureido group, an arylureido group, an alkyl group, an alkoxy group, an amino group, an alkoxycarbonyl group and a arylcarbonyl group, said groups have at least one carboxy group as a substituent, R.sub.2 is selected from the group consisting of a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, a nitro group, a cyano group, a formyl group, a carboxyl group, a hydroxyl group, an amino group, an acylamino group, an alkylsulfonamido group, an arylsulfonamido group, an alkylureido group, an arylureido group, a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl group and an aryloxycarbonyl group, R.sub.3 represents an alkyl group substituted with a phenoxy group; R.sub.Type: GrantFiled: June 24, 1986Date of Patent: August 23, 1988Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Hidetaka Ninomiya, Ryosuke Sato
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Patent number: 4745047Abstract: A color image-forming process is disclosed, which comprises imagewise exposing a silver halide photographic material comprising a reflective support having provided thereon at least one light-sensitive silver halide emulsion layer constituted by at least two kinds of monodispersed silver halide grains containing substantially no silver iodide and substantially deffering from each other in mean grain size, and developing the exposed photographic material for a developing time of within 2 minutes and 30 seconds using a color developer containing substantially no benzyl alcohol.Type: GrantFiled: January 27, 1987Date of Patent: May 17, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Masahiro Asami, Kazunori Hasebe
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Patent number: 4661601Abstract: New compounds having the formula 1 ##STR1## wherein W is hydrogen, halogen, n-alkyl, --NHCOR.sup.1, --COR.sup.1, or phenoxyacetylamino optionally substituted by one or two C.sub.1-12 straight- or branched chain alkyl, X is a substituent in the coupling position and is selected from hydrogen, chlorine, bromine, --SR.sup.11 or a nitrogen-containing heterocyclic residue attached at a ring nitrogen atom, and Y is a group having the formula 2 ##STR2## wherein Q is selected from the residues: --COOR.sup.4 or --CONR.sup.4 R.sup.5, --OM, --NR.sup.7 R.sup.8, --PO(OR.sup.9)[O].sub.x R.sup.10 with X=0 or 1, --SO.sub.2 OH, --SO.sub.2 NR.sup.4 R.sup.5 or CN. The groups R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, M, k and n are defined hereinafter.These compounds are used as black color couplers in photographic materials.Type: GrantFiled: April 3, 1985Date of Patent: April 28, 1987Assignee: Ciba-Geigy AGInventor: Frederick H. Howell
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Patent number: 4639413Abstract: A silver halide color photographic material is described, comprising a support having formed thereon at least one silver halide emulsion layer having dispersed therein, in a coexisting state, at least one magenta coupler represented by formula (I) and at least one high-boiling point organic solvent represented by the formula (II) ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent and x represents a hydrogen atom or a group capable of being released by a coupling reaction with the oxidation product of an aromatic primary amine developing agent; andwherein R.sup.3, R.sup.4, and R.sup.5 each represents an alkyl group, a cycloalkyl group, or an alkenyl group, and the total number of carbon atom of the groups R.sup.3, R.sup.4 and R.sup.5 is from 12 to 60.Type: GrantFiled: August 14, 1985Date of Patent: January 27, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshio Kawagishi, Kiyoshi Nakazyo
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Patent number: 4481268Abstract: A method of forming a photographic azo or azamethine dye image in an exposed photographic silver halide element, the method of comprising the steps of (a) developing the imagewise exposed material to form an imagewise pattern of oxidized color developing agent, (b) reacting the oxidized color developing agent with a color coupler to produce an image dye, characterized in that at least one of the color developing agent and the color coupler possesses a metal chelating site such that the image dye is capable of forming a bi-, tri- or higher-dentate metallized dye, and (c) contacting the image dye with polyvalent metal ions to form a metallized dye image. Specified color developing agents include heterocyclic substituted hydrazides and specified couplers include benziso-oxazolones and 2H-pyrazolo-[3,4-b]pyridines in addition to more conventional compounds.Type: GrantFiled: April 29, 1983Date of Patent: November 6, 1984Assignee: Eastman Kodak CompanyInventors: Joseph Bailey, David Clarke, Michael W. Crawley, Peter D. Marsden, Jasbir Sidhu
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Patent number: 4345025Abstract: A color photographic silver halide light-sensitive material containing a colorless photographic cyan color-forming coupler having, in a position for coupling with the oxidation product of an aromatic primary amine developing agent, a coupling-off group represented by the following general formula (I):--O--R--SO--R.sub.1 (I)wherein R represents a substituted straight or branched chain alkylene group or a substituted straight or branched chain alkenylene group; R.sub.1 represents a substituted or unsubstituted straight or branched chain alkyl group, a straight or branched chain alkenyl group, a straight or branched chain aralkyl group, a straight or branched chain aralkenyl group, a cycloalkyl group, an aryl group or a heterocyclic group, and R and R.sub.1 may be bonded to each other directly or through a connecting group to form a ring. The 2-equivalent photographic cyan couplers have high coupling speed and excellent dispersibility.Type: GrantFiled: March 11, 1981Date of Patent: August 17, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Morio Yagihara, Yukio Yokota
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Patent number: 4284714Abstract: A method is described for forming a black-and-white photographic image consisting essentially of a silver image and a coextensive dye image, in which the maximum density of the image and the fastness of the image to light are greatly improved, by processing a silver halide photosensitive material which contains silver halide in a reduced amount (compared with conventional materials) that has been imagewise exposed to light in the presence of a naphthalene compound containing at least two hydroxy substituents groups on the nucleus thereof and a p-phenylenediamine type developing agent or a precursor of the p-phenylenediamine compound.Type: GrantFiled: May 9, 1980Date of Patent: August 18, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Junkichi Ogawa, Mitsugu Tanaka, Minoru Yamada