Coupler Containing Patents (Class 430/470)
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Patent number: 7384731Abstract: A method for forming color images comprising subjecting a silver halide color photosensitive material to a development processing in the presence of a compound (A) defined below, wherein the silver halide color photosensitive material having a blue-sensitive unit, a green-sensitive unit and a red-sensitive unit, each of which comprises at least one silver halide emulsion layer, and at least one non-light-sensitive layer on a support, compound (A): a heterocyclic compound having one or two hetero atoms, the heterocyclic compound being capable of increasing speed of the silver halide color photosensitive material by the presence thereof in comparison to the case where the heterocyclic compound is absent.Type: GrantFiled: September 21, 2004Date of Patent: June 10, 2008Assignee: FUJIFILM CorporationInventors: Junichiro Hosokawa, Naoharu Kiyoto, Yoshio Ishii, Takanori Hioki, Katsumi Kobayashi, Takashi Hoshimiya
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Publication number: 20030215757Abstract: A method of processing photosensitive materials in which one or more chemical compounds are at least partially retained after processing. The chemical compounds are unique to a particular process used by a copyright owner. The absence of the unique compounds in a processed material thus indicates that the processing has been without the authorization of the copyright owner.Type: ApplicationFiled: May 13, 2003Publication date: November 20, 2003Applicant: Eastman Kodak CompanyInventor: John R. Fyson
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Patent number: 6645711Abstract: A silver halide color photographic light-sensitive material containing a compound of the formula: wherein R1, R2 and R3 each represent a hydrogen atom or a substituent; R4 represents an alkyl, aryl or heterocyclic group; R1 and R2, or/and R2 and R4 may combine with each other to form a 5-membered, 6-membered or 7-membered ring; Z represents a group of non-metallic atoms that form a 5-membered, 6-membered or 7-membered ring together with the nitrogen atom and two carbon atoms in the benzene ring; R5 represents an alkyl, aryl or heterocyclic group, in which the compound of the formula contains none of a hydroxyl group, a carboxyl group and a sulfo group in each of R1, R2, R3 and R4.Type: GrantFiled: July 18, 2002Date of Patent: November 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Osamu Uchida, Toshio Kawagishi, Masaaki Tsukase, Kazuhiko Matsumoto
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Patent number: 6410216Abstract: Method of forming a photographic color image which comprises imagewise exposing a photographic silver halide color material and processing it with an alkaline processing solution in the presence of a sulphonhydrazide color developing agent and a 3-pyridinol color coupler optionally containing in the 2-position a ballasting group of such size and configuration as to render the coupler non-diffusible in photographic materials thus forming a dye image by reaction of the oxidized color developing agent and the color coupler.Type: GrantFiled: July 14, 1994Date of Patent: June 25, 2002Assignee: Eastman Kodak CompanyInventors: David Clarke, Paul Louis Reginald Stanley
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Patent number: 6265142Abstract: A heat developable color photographic light-sensitive material comprising at least one dye providing compound represented by the formula (L1) shown below and at least one developing agent represented by the formula (1) or (2) shown below: The symbols in the above formulae are defined and described in detail in the specification.Type: GrantFiled: February 22, 1999Date of Patent: July 24, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Hajime Nakagawa, Toshiki Taguchi
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Patent number: 6252025Abstract: Photographically useful materials are disclosed comprising a hyperbranched polymer segment and multiple pendant photographically useful groups. Such materials may be prepared by forming an active hyperbranched polymer segment with multiple functionalized end group sites, and reacting the active hyperbranched polymer segment with an active compound comprising a photographically useful group to form a hyperbranched polymer ended with photographically useful groups. The hyperbranched segment may comprise any kind of polymer segment with hyperbranched architecture, and the active end groups may comprise any kind of reactive site. The active hyperbranched polymer may comprise any kind of other functional groups which are located in either backbone or the ends.Type: GrantFiled: August 11, 1998Date of Patent: June 26, 2001Assignee: Eastman Kodak CompanyInventors: Jin-Shan Wang, Yanong Wang
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Patent number: 6124082Abstract: Recovering the dye image on film in electronic film development following a latent holding stage obviates the problem common in prior art electronic film development of film image destruction. Recovery of the image is accomplished using a developing agent containing couplers to form a dye image. These dyes do not affect the infrared scans of the image. Upon complete development of the dye image, further dye formation is halted by the application of a coupler blocking agent, while silver development and electronic scanning may continue or halt. After halting dye formation, the film is stable for an arbitrary time in a latent stage and may be dried and stored. Following this latent stage, silver is removed from the film with a bleach-fix leaving a conventionally usable film image.Type: GrantFiled: April 14, 1999Date of Patent: September 26, 2000Assignee: Applied Science Fiction, Inc.Inventor: Albert D. Edgar
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Patent number: 6017688Abstract: Recovering the dye image on film in electronic film development following a latent holding stage obviates the problem common in prior art electronic film development of film image destruction. Recovery of the image is accomplished using a developing agent containing couplers to form a dye image. These dyes do not affect the infrared scans of the image. Upon complete development of the dye image, further dye formation is halted by the application of a coupler blocking agent, while silver development and electronic scanning may continue or halt. After halting dye formation, the film is stable for an arbitrary time in a latent stage and may be dried and stored. Following this latent stage, silver is removed from the film with a bleach-fix leaving a conventionally usable film image.Type: GrantFiled: January 27, 1998Date of Patent: January 25, 2000Assignee: Applied Science Fiction, Inc.Inventor: Albert D. Edgar
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Patent number: 5908705Abstract: Lithographic plate compositions and a method for their production have been discovered that are especially useful in conjunction with digitally controlled lasers to directly construct printable images on lithographic plates. The plates comprise a substrate and an ablatable polymeric coating on the substrate where the ablatable, imageable coating is prepared by in situ or solution polymerization of conjugated monomers deposited on the plate by vapor deposition or in solution. Examples of such monomers are thiophene, pyrrole and aniline.Type: GrantFiled: March 10, 1997Date of Patent: June 1, 1999Assignee: Kodak Polychrome Graphics, LLCInventors: My T. Nguyen, Hui Zhu, S. Peter Pappas, Ken-ichi Shimazu, Robert Hallman
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Patent number: 5849469Abstract: The invention provides a novel magenta coupler of the formula (I) ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are selected from H, alkyl, substituted alkyl, aryl, substituted aryl, heteroaryl, alkylthio, carboxylic acid or ester, primary or secondary amido, sulphonamido, mono or disubstituted amino, alkoxy or aryloxy; andX is H or a group capable of being released on oxidative coupling with a colour coupler.These magenta couplers do not have secondary dye absorptions in the blue region of the spectrum which leads to a better colour reproduction and are readily and economically synthesized.Type: GrantFiled: October 6, 1997Date of Patent: December 15, 1998Assignee: Eastman Kodak CompanyInventor: Michael William Crawley
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Patent number: 5445925Abstract: A color image can be obtained from a color photographic element by multiple color development steps. The first color development is carried out in the usual manner after imagewise exposure. The second color development step is carried out after bleaching with a rehalogenating bleaching agent, and is used to develop only rehalogenated silver halide. This specific development is possible by either using a chloride rehalogenating agent in the bleaching solution, using a sulfite fixing agent before bleaching, or by fogging the element between bleaching and the second color development step.Type: GrantFiled: April 7, 1994Date of Patent: August 29, 1995Assignee: Eastman Kodak CompanyInventors: Peter D. Marsden, Gareth B. Evans
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Patent number: 5434034Abstract: There is disclosed a silver halide color photographic material and a method for forming a color image using said color photographic material. The silver halide color photographic material comprises silver halide emulsion grains comprising silver chlorobromide having a high silver chloride content and being substantially free from silver iodide, and a cyan dye-forming coupler represented by formula (I) or (II), and said silver halide emulsion grains being formed by adding a water-soluble bromide at the grain formation step, and/or during the period from the completion of the formation of the grains to the coating of the cyan dye-forming layer onto the support: ##STR1## wherein Za and Zb each represent --N.dbd. or --C(R.sub.3).dbd., with one of Za and Zb being --N.dbd. and the other being --C(R.sub.3).dbd.; R.sub.1 and R.sub.2 each represent an electron-attracting group, whose Hammett substituent constant .sigma..sub.p value is 0.20 or more, with the sum of the .sigma..sub.p values of R.sub.1 and R.sub.Type: GrantFiled: April 15, 1993Date of Patent: July 18, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5155004Abstract: A chitosan or chitin compound having a photographically useful residue. There is also disclosed a method for processing a silver halide photographic material which comprises processing a silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer in the presence of said chitosan or chitin compound represented by the following general formula (I) ##STR1## wherein the substituents are defined in the instant specification.Type: GrantFiled: March 13, 1991Date of Patent: October 13, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Tetsuro Kojima
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Patent number: 4994345Abstract: A method for making a color proof in a photo-mechanical process. The method comprises a step for exposing a silver halide color photographic light-sensitive material to light through a black-and-white halftone dot image, and a step for developing said silver halide color photographic light-sensitive material with a color developer. The photographic material is comprised of at least three silver halide emulsion layers which are different from each other in spectral sensitivity thereof, and at least one of these silver halide emulsion layers contains a specific yellow coupler and the color developer contains a specific color developing agent. A halftone color image having a color tone similar to that of image printed with printing inks can be obtained by the simplified process.Type: GrantFiled: June 5, 1989Date of Patent: February 19, 1991Assignee: Konica CorporationInventors: Tomomi Yoshizawa, Keiji Ogi, Nariko Kimura
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Patent number: 4965175Abstract: A method for continuous processing of a silver halide color photosensitive material is disclosed. The process steps comprise developing a color photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing a silver halide comprising at least 80 mol % silver chloride, in a color developer solution containing a chloride ion concentration of from 3.5.times.10.sup.-2 to 2.0.times.10.sup.-1 mol/l, said developing step being conducted in a developer bath having a bath opening ratio (S/V) of at most 0.015 cm.sup.-1 wherein S is air-contacting area of the bath in cm.sup.2 and V is a total volume of the bath in cm.sup.3.Type: GrantFiled: October 3, 1989Date of Patent: October 23, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Fujimoto, Kazuaki Yoshida
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Patent number: 4863836Abstract: There is provided a method for processing a silver halide color photographic material which comprises processing the silver halide color photographic material with a color developer containing an aromatic primary amine color developing agent and a specific amino compound. According to this method the stability and color forming property of a color developer are improved so that the increased fogging problem in continuous processing is lessened and the processing time is shortened. There is also provided a color developer composition which can be used as the developer, as it is or after adjusting its composition.Type: GrantFiled: February 22, 1988Date of Patent: September 5, 1989Assignee: Fuji Photo Film, Co., Inc.Inventors: Takatoshi Ishikawa, Nobutaka Ohki, Morio Yagihara
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Patent number: 4830948Abstract: A method of forming color photographic images where a silver halide color photographic material containing a coupler which forms a dye by reaction with the oxidation product of an aromatic primary amine developing agent and containing an acid-processed gelatin in an amount of 25% by weight or more of the amount of the total gelatin coated is color developed, desilvered and then rinsed in water and/or stabilized. The total of the processing time of said desilvering, rinsing-in-water and stabilization steps is controlled to be 3 minutes or less, and/or the amount of replenisher added to the rinsing-in-water bath and stabilization bath is controlled to be from 0.5 to 50 times of the amount of the processing solution which is brought into the rinsing-in-water bath and stabilization bath from the desilvering bath together with the material which is being processed.Type: GrantFiled: March 17, 1988Date of Patent: May 16, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Takatoshi Ishikawa, Genichi Furusawa, Takeshi Hirose
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Patent number: 4791048Abstract: A color image is formed by subjecting a silver halide photosensitive material comprising at least a photosensitive silver halide, a two equivalent coupler, a binder, and a substantially water-insoluble basic metal compound on a support, to development with a processing solution comprising a complexing compound capable of complexing reaction with the metal in ionic form of said substantially water-insoluble basic metal compound in the presence of water to release a base.Type: GrantFiled: February 19, 1987Date of Patent: December 13, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Haruhiko Iwano
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Patent number: 4426441Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.Type: GrantFiled: December 3, 1982Date of Patent: January 17, 1984Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Roy C. DeSelms
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Patent number: 4371609Abstract: A method of forming dye images by processing a photographic material containing imagewise distributed catalyzer substance in the presence of hydrogen peroxide, a coupler and certain aromatic primary amine compounds.Type: GrantFiled: July 16, 1981Date of Patent: February 1, 1983Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Makoto Kajiwara, Akihiko Miyamoto, Keiji Ohbayashi, Masaru Iwagaki
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Patent number: 4351898Abstract: A single emulsion layer photographic material such as a film or print material composed of a mixture of separate silver halide grains that are separately responsive to different colors of light and thereafter are treated to provide a colored image of the subject.Type: GrantFiled: January 3, 1978Date of Patent: September 28, 1982Inventor: Richard J. Goldberg
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Patent number: 4203768Abstract: A silver halide color photographic material comprising a photographic silver halide emulsion containing a yellow dye-forming coupler represented by the following general formula (I) or (II): ##STR1## wherein R.sub.1 represents an alkyl group or an aryl group; R.sub.2 represents a chlorine atom or a lower alkoxy group having 1 to 4 carbon atoms; R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group having 1 to 22 carbon atom, a phenoxyalkyl group having 7 to 32 carbon atoms, a monocyclic aralkyl group or a phenyl group, a phenyl group which is substituted with an alkoxy group, an alkyl group, an acyl group, or an alkoxycarbonyl group; and X is selected from the group consisting of groups represented by the following general formulae (III) to (V): ##STR2## wherein Z.sub.1 represents the non-metallic atoms necessary to form together with the ##STR3## moiety a 5-membered ring or a 6-membered ring, ##STR4## wherein Z.sub.Type: GrantFiled: September 26, 1978Date of Patent: May 20, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Inouye, Hideki Naito
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Patent number: 4193802Abstract: A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, with the photographic light-sensitive material having a hydrophilic organic colloid layer containing a dispersion of a scarcely water-soluble photographic additive dissolved in an aromatic ester represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an alkyl group, an alkoxy group, an acyloxy group, an aryloxy group, an alkoxycarbonyl group or a halogen atom; R.sub.2 represents a cyclic saturated hydrocarbon group; m represents an integer of 0 to 5; n represents an integer of 1 to 6; and when m and n each represents an integer of 2 or more, the substituents represented by R.sub.1 or R.sub.2 can be the same or different.Type: GrantFiled: August 15, 1978Date of Patent: March 18, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Yasuo Mukunoki, Hideki Naito, Akio Mitsui
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Patent number: H1112Abstract: A silver halide color photographic light-sensitive material improved in graininess, comprising a support having thereon a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, wherein at least one of the red-sensitive emulsion layer and the green-sensitive emulsion layer has the three-layered structure, in which the low speed silver halide emulsion layer, medium speed silver halide emulsion layer and high speed silver halide emulsion layer are coated on the support in this order; and the coating amount of silver in the layer increases in the order of the medium speed layer, low speed layer and high speed layer.Type: GrantFiled: October 16, 1990Date of Patent: November 3, 1992Assignee: Konica CorporationInventors: Atsuo Ezaki, Keisuke Tobita, Hiroshi Ikeda, Hideaki Haraga