Open-chain Keto Methylene Coupler Patents (Class 430/475)
  • Patent number: 7425408
    Abstract: A silver halide color photographic light-sensitive material, having at least one each of blue-, green-, and red-sensitive emulsion layers containing yellow, magenta, and cyan couplers, respectively, on a support; wherein said blue-sensitive emulsion layer contains at least one coupler of formula (I); and wherein the light-sensitive material satisfies expression a-1) and/or b-1): wherein, Q forms a 5- to 7-membered ring with the —N?C—N(R1)—; R1 and R2 each are a substituent; m is 0 to 5; and X is a hydrogen atom, or a coupling split-off group; 0.5?Dmax(UV)/Dmin(UV)?1.1: ??a-1) wherein Dmax(UV)/Dmin(UV) is the smallest of the value in a wavelength range of 340 to 450 nm; 1300?(B?C)/A?20000: ??b-1) wherein B is yellow Dmax, C is yellow Dmin; and A is an amount mol/m2 of the coupler of formula (I).
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: September 16, 2008
    Assignee: FUJIFILM Corporation
    Inventors: Hiroyuki Yoneyama, Akira Ikeda, Shin Soejima, Kiyoshi Takeuchi, Naoto Matsuda
  • Patent number: 5776664
    Abstract: A silver halide photographic material comprising: (a) a silver chloride-containing emulsion comprising a dispersion medium and a silver halide grain, wherein the silver halide grain contains a tabular grain having an average aspect ratio of not less than 2 accounting for at least 50% of the entire projected area thereof and has a silver chloride content of not less than 20 mol%; (b) a developing agent; and (c) a compound capable of forming a dye image upon development.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: July 7, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Yamashita, Koki Nakamura, Koichi Nakamura
  • Patent number: 5549953
    Abstract: The prevention of counterfeiting of currencies, passports, cheques, bank cards, credit cards, optical disks and the like is addressed by introducing thin film structures having both optically-variable security properties and encoded optical data decodable by optical means. The thin film structures comprise a substrate and a multilayer interference coating carried by the substrate, producing an inherent color shift with a change of viewing angle. The multilayer interference coating has a dielectric material which is transparent and the recording layer made of a light absorbing material, a crystalline-structural changing material or a magneto-optic material. The encoded data is in the form of bar codes or digital data. The information is encoded by photolithographic means or by optical recording means. The encoded data is retrieved by an optical recording system having a light source and an optical guiding system and a light detector.
    Type: Grant
    Filed: April 29, 1993
    Date of Patent: August 27, 1996
    Assignee: National Research Council of Canada
    Inventor: Li Li
  • Patent number: 5380625
    Abstract: A method for processing a silver halide color photographic material, which comprises processing an image-wise exposed silver halide color photographic material comprising at least one silver halide emulsion layer and containing an N,N-substituted malondiamide type coupler with a color developer containing an aromatic primary amine color developing agent represented by the following general formula (D) or (E): ##STR1## In a preferred embodiment, the photographic light-sensitive material contains a cyan coupler represented by the following general formula (C): ##STR2##
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: January 10, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Masato Taniguchi, Naoki Saito
  • Patent number: 5328812
    Abstract: A dye image-forming method comprising color developing an image wise exposed silver halide color photographic material comprising a support having thereon a layer containing an acylacetamide yellow coupler having an acyl group represented by a following formula (YI) ##STR1## wherein R.sub.1 represents a monovalent group; Q represents a group of atoms necessary to form 3- or 5-membered hydrocarbon ring or a 3- to 5-membered heterocylcic ring; provided that R.sub.1 is not a hydrogen atom and is not combined with Q to form a ring; with a developing solution containing at least one aromatic primary amine color developing agent represented by formula (D) or (E): ##STR2## wherein R.sub.4 represents a linear or branched alkyl group having 1 to 6 carbon atoms or a linear or branched hydroxyalkyl group having 3 to 6 carbon atoms; R.sub.5 represents a linear or branched alkylene group having 3 to 6 carbon atoms or a linear or branched hydroxyalkylene group having 3 to 6 carbon atoms; R.sub.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: July 12, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akimitsu Haijima, Masato Taniguchi
  • Patent number: 4994345
    Abstract: A method for making a color proof in a photo-mechanical process. The method comprises a step for exposing a silver halide color photographic light-sensitive material to light through a black-and-white halftone dot image, and a step for developing said silver halide color photographic light-sensitive material with a color developer. The photographic material is comprised of at least three silver halide emulsion layers which are different from each other in spectral sensitivity thereof, and at least one of these silver halide emulsion layers contains a specific yellow coupler and the color developer contains a specific color developing agent. A halftone color image having a color tone similar to that of image printed with printing inks can be obtained by the simplified process.
    Type: Grant
    Filed: June 5, 1989
    Date of Patent: February 19, 1991
    Assignee: Konica Corporation
    Inventors: Tomomi Yoshizawa, Keiji Ogi, Nariko Kimura
  • Patent number: 4830948
    Abstract: A method of forming color photographic images where a silver halide color photographic material containing a coupler which forms a dye by reaction with the oxidation product of an aromatic primary amine developing agent and containing an acid-processed gelatin in an amount of 25% by weight or more of the amount of the total gelatin coated is color developed, desilvered and then rinsed in water and/or stabilized. The total of the processing time of said desilvering, rinsing-in-water and stabilization steps is controlled to be 3 minutes or less, and/or the amount of replenisher added to the rinsing-in-water bath and stabilization bath is controlled to be from 0.5 to 50 times of the amount of the processing solution which is brought into the rinsing-in-water bath and stabilization bath from the desilvering bath together with the material which is being processed.
    Type: Grant
    Filed: March 17, 1988
    Date of Patent: May 16, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Genichi Furusawa, Takeshi Hirose
  • Patent number: 4812389
    Abstract: A process for processing a DIR coupler-containing silver halide color photographic material for photographing use in a continuous manner with replenishment of a developer is disclosed in which said DIR coupler is a coupler which has in a coupling site a group that functions as a development inhibitor or a development inhibitor precursor upon being eliminated from the coupling active site by color development processing and that will be decomposed to a compound exerting substantially no influences on photographic properties after flowing into a color developing solution, said development inhibitor having a half-value period of 4 hours or shorter than that at a pH of 10.0, and in which the developing solution is replenished in an amount of 700 ml or less per m.sup.2 of developed light-sensitive materials.
    Type: Grant
    Filed: September 25, 1986
    Date of Patent: March 14, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kei Sakanoue, Seiji Ichijima, Shinzo Kishimoto
  • Patent number: 4738917
    Abstract: A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.
    Type: Grant
    Filed: May 15, 1986
    Date of Patent: April 19, 1988
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeharu Koboshi, Satoru Kuse, Kazuhiro Kobayashi, Masao Ishikawa, Masayuki Kurematsu
  • Patent number: 4481268
    Abstract: A method of forming a photographic azo or azamethine dye image in an exposed photographic silver halide element, the method of comprising the steps of (a) developing the imagewise exposed material to form an imagewise pattern of oxidized color developing agent, (b) reacting the oxidized color developing agent with a color coupler to produce an image dye, characterized in that at least one of the color developing agent and the color coupler possesses a metal chelating site such that the image dye is capable of forming a bi-, tri- or higher-dentate metallized dye, and (c) contacting the image dye with polyvalent metal ions to form a metallized dye image. Specified color developing agents include heterocyclic substituted hydrazides and specified couplers include benziso-oxazolones and 2H-pyrazolo-[3,4-b]pyridines in addition to more conventional compounds.
    Type: Grant
    Filed: April 29, 1983
    Date of Patent: November 6, 1984
    Assignee: Eastman Kodak Company
    Inventors: Joseph Bailey, David Clarke, Michael W. Crawley, Peter D. Marsden, Jasbir Sidhu
  • Patent number: 4404274
    Abstract: A photographic light-sensitive element comprising a support and having thereon at least one silver halide emulsion layer containing an .alpha.-diacylamino substituted (aliphatic acyl) acetamide yellow dye forming coupler and a method for forming yellow dye images which comprises processing a silver halide photographic emulsion with an aromatic primary amino developing agent in the presence of an .alpha.-diacylamino substituted (aliphatic acyl) acetamide compound are disclosed. The coupler is an excellent two-equivalent coupler.
    Type: Grant
    Filed: April 6, 1981
    Date of Patent: September 13, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Atsuaki Arai, Yasushi Oishi, Akio Okumura, Kiyoshi Nakazyo
  • Patent number: 4394440
    Abstract: A yellow-dye-forming photographic developing composition having improved stability comprises a haloacetanilide coupler, such as alpha-pivalyl-alpha-(4-carboxyphenoxy)-2,4-dichloroacetanilide, an N-alkyl-N-alkoxyalkyl-p-phenylenediamine developing agent, such as 4-amino-N-ethyl-N-(2-methoxyethyl)-m-toluidine di-p-toluene sulfonate, and a 4,4-disubstituted-1-aryl-3-pyrazolidinone, such as 4,4-dimethyl-1-phenyl-3-pyrazolidinone.
    Type: Grant
    Filed: January 22, 1982
    Date of Patent: July 19, 1983
    Assignee: Eastman Kodak Company
    Inventor: Carl R. Cappel
  • Patent number: 4314023
    Abstract: A photographic yellow coupler having a general formula selected from the group consisting of (I), (II) and (III) ##STR1## wherein A is a yellow coupler residue defined by removing one hydrogen atom of a active methylene group from a yellow coupler having the active methylene group; Q is a group having a formula selected from the group consisting of ##STR2## and ##STR3## (where X and Y are individually a hydrogen atom or an alkyl, acyl, aryl or aralkyl group; Z is a hydrogen atom or an alkyl, aryl or aralkyl group; and R.sub.1 and R.sub.2 are individually a hydrogen atom or an alkyl, aryl or aralkyl group or both of R.sub.1 and R.sub.2 together may form a benzylidene group or a cycloalkyl group); and Q' is a group of the formula --CH.sub.2 --CH.sub.2 -- or ##STR4## (wherein R.sub.3 is a hydrogen or halogen atom or an alkoxy group; R.sub.4 is a hydrogen or halogen atom, an amino, acylamino, ureido, lower alkyl, alkoxy or hydroxy group; and R.sub.4 and R.sub.5 are individually a lower alkyl group).
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: February 2, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Tamotsu Kojima, Hiroyuki Imamura, Mitsuto Fujiwhara, Wataru Fujimatsu, Takaya Endo
  • Patent number: 4304845
    Abstract: The present invention relates to a process for forming a yellow color image which requires contacting exposed silver halide grain with a developer in the presence of a particular yellow coupler.
    Type: Grant
    Filed: June 20, 1980
    Date of Patent: December 8, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Wataru Fujimatsu, Shui Sato, Tamotsu Kojima, Shigemasa Itoh, Takaya Endo
  • Patent number: 4201588
    Abstract: A radiation-sensitive element is disclosed including a radiation-sensitive layer comprised of a cobalt(III)complex and a photoreductant. A process is disclosed in which the photoreductant is converted to a reducing agent by exposure to electromagnetic radiation longer than 300 nanometers. The reducing agent is then reacted with a cobalt(III)complex. Images can be recorded directly within the radiation-sensitive layer or in a separate image-recording element or layer by use of the residual cobalt(III)complex not exposed or one or more of the reaction products produced by exposure. By using the ammonia liberated from ammine ligand containing cobalt(III)complexes on exposure in combination with imagewise and uniform exposures, positive or negative images can be formed in diazo image-recording layers or elements associated with the radiation-sensitive layer. By the selection of amine-responsive reducing agent precursors, the amines released by the cobalt(III) complexes cause an amplified image.
    Type: Grant
    Filed: September 7, 1976
    Date of Patent: May 6, 1980
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, James C. Fleming