Abstract: In a dye-forming imaging material comprising (a) a dye-forming coupler, and (b) an organic reducing agent that is capable in its oxidized form of reacting with the dye-forming coupler to form a dye, improvements are provided by a reducing agent that is a ureidoaniline silver halide developing agent free of strong electron withdrawing groups. Such an imaging material can be a photographic silver halide material. The imaging material can be a photothermographic material for producing a dye image comprising, in reactive association, (a) photographic silver halide, (b) a dye-forming coupler, and (c) an oxidation-reduction image forming combination comprising (1) an organic silver salt oxidizing agent, and (2) an organic reducing agent for the organic silver salt oxidizing agent, wherein the reducing agent is a ureidoaniline which is capable in its oxidized form of reacting with the dye-forming coupler to form a dye.
Abstract: A silver halide photographic light-sensitive material which comprises at least one of those pyrazole compounds represented by the following general formula: ##STR1## wherein A is a group which can be eliminated in a photographic process condition; X is ##STR2## wherein R.sub.5 is a hydrogen atom or an alkyl, an aryl, an acyl or a sulfone group, which R.sub.5 group may combine together with R.sub.1 to form a condensed ring; R.sub.1 is a hydrogen atom or an alkyl, an aryl, an acyl, a sulfone, an alkoxy, or a heterocyclic residue; R.sub.2 is a hydrogen atom or an alkyl, an aryl, an alkoxy, an amino, an acid amide, a sulfonamide, a carboxyl, an alkoxycarbonyl, a carbamoyl, a cyano, or a halogenated alkyl group, R.sub.3 and R.sub.
Abstract: A process for forming a photographic image comprising imagewise exposing a silver halide photographic light-sensitive material to light and processing the silver halide photographic light-sensitive material with an alkaline processing solution, wherein the improvement comprises the silver halide photographic light-sensitive material contains a compound represented by formula (I) ##STR1## wherein R represents an alkyl group having from 6 to 22 carbon atoms, a substituted alkyl group having from 6 to 22 carbon atoms, an aryl group having from 6 to 22 carbon atoms, a substituted aryl group having from 6 to 22 carbon atoms, an alkenyl group having from 6 to 22 carbon atoms, a substituted alkenyl group having from 6 to 22 carbon atoms or an aralkyl group having from 7 to 22 carbon atoms; X represents an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or a halogen atom; and n represents an integer from 1 to 3.
Abstract: The light-sensitive color photographic silver halide recording material contains in at least one of its light-sensitive gelatine-containing layer, color formers for the formation of the image dyes in the three primary colors, a crosslinking agent activating the carboxyl groups of gelatine selected from carbamoylonium salts, carbamoylpyridinium salts and carbamoyloxypyridinium salts and a compound acting as aldehyde-scavenger which corresponds to the general formula ##STR1## wherein Z represents the atoms required for completing a 5-6-membered substituted or unsubstituted carbocyclic ring or a substituted or unsubstituted heterocyclic ring which may contain oxygen, nitrogen or sulfur as hetero-atom.
Abstract: A silver halide color photographic light-sensitive material containing an unsubstituted or substituted glycoluril as an aldehyde gas scavenger. The silver halide color photographic light-sensitive material of the present invention can avoid the decrease in color density and the formation of fog normally present when the silver halide color photographic light-sensitive material is stored for a long period of time in contact with formaldehyde gas. In addition, the silver halide color photographic light-sensitive material of the present invention has a reduced layer thickness and good film strength.
Abstract: A process for the production of photographic color images by the silver dye bleach process, by exposure, silver development, dye formation, dye bleach, silver bleach and fixing of a photographic material which, in a light-sensitive silver halide emulsion layer or in an adjacent layer, contains, dispersed in oil, an oil-soluble triazene of the formula ##STR1## and an oil-soluble coupling component of the formula ##STR2## in which Ar.sub.1 is aryl or an aromatic heterocyclic radical, R.sub.1 is hydrogen, alkyl, aryl, hydroxyl, --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1 or --OL.sub.1, in which L.sub.1 is alkyl and r is 1, 2 or 3, or R.sub.1 is ##STR3## in which V is hydrogen or alkyl, and R.sub.2 is alkyl, aryl or --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1, or R.sub.1 and R.sub.2, conjointly with the nitrogen atom to which they are bonded, form a ring, A.sub.1 and A.sub.2 independently of one another are an amine of the formula --NT.sub.1 T.sub.2, in which T.sub.1 and T.sub.
Abstract: In a process for hardening gelatine containing layers of color photographic multi-layered materials which have a paper laminated with a polyolefin layer arranged on both sides a substrate 1,3,5-triacrylohexahydro-1,3,5-triazine and a polyhydric aliphatic alcohol with 3 to 10 carbon atoms are added to the casting solutions and the casting solutions are then applied to a corona irradiated surface of the substrate.
Abstract: A silver halide photographic light-sensitive material is described comprising a layer containing a coupler compound represented by formula (I)A--B (I)wherein A represents a residue of a compound capable of undergoing a coupling reaction with an oxidation product of an aromatic primary amine developing agent, by the removal of one hydrogen atom from the active position of said compound, and B represents a group which is released by the coupling reaction and exhibits a development accelerating function.
Abstract: The present invention is directed towards a silver halide photographic material which has a reducing agent for silver halide or a precursor thereof and a compound M.sub.1 H.sub.m (PO.sub.n).sub.i.jH.sub.2 O which generates base when heat is applied. M is a metal from the Groups IA and IIA of the Periodic Table, 1 and i are individually integers from 1 to 3, m is an integer from 0 to 4, n is 3 or 4, and j is an integer from 0 to 12.
Abstract: A multilayer color reversal light-sensitive material is described, which can provide dye images having improved sharpness and graininess without a drop in color reproducibility, by employing a specific arrangement and construction of emulsion layers in its multi-layer structure, viz., a material comprising a support, a yellow filter layer, a group of green-sensitive emulsion layers, and a group of red-sensitive emulsion layers, wherein said emulsion layer groups are positioned nearer to the support than the yellow filter layer, each of the emulsion layer groups comprises at least two adjacent layers including a high-sensitivity silver halide emulsion layer containing silver halide grains having an average size of from 0.6.mu. to 2.0.mu. and a low-sensitivity silver halide emulsion layer containing silver halide grains having an average grain size of from 0.1.mu. to 0.5.mu.
Abstract: Photographic silver halide material which comprises at least one silver halide emulsion layer coated on a support, there being present in the silver halide emulsion layer(s), or in a layer in operative contact with at least one silver halide emulsion layer, a compound of the formula ##STR1## wherein W is hydrogen, alkyl, --NHCOR.sup.1 or --COR.sup.1, wherein R.sup.1 is alkyl or alkenyl, cycloalkyl, aralkyl, aryl, phenoxymethylamino or halogen; X is a substituent in the coupling position and is a leaving group selected from hydrogen, chlorine, bromine, --SR.sup.11 wherein R.sup.11 is alkyl, aryl or a heterocyclic group, or X is a nitrogen-containing heterocyclic residue attached at a ring nitrogen atom; Y is a group having the formula ##STR2## wherein Q is selected from the residues: (a) --COOR.sup.4 or --CONR.sup.4 R.sup.5 where R.sup.4 is hydrogen, alkyl optionally interrupted by 1 or more oxygen atoms, alkenyl, cycloalkyl, aralkyl or aryl, and R.sup.5 is hydrogen or alkyl or R.sup.4 and R.sup.
Abstract: Silver halide emulsions are prepared by precipitating a silver halide emulsion I on a more sparingly soluble silver halide emulsion II in the presence of a silver halide solvent wherein the emulsion I has been prepared in the presence of a compound inhibiting grain growth.
Type:
Grant
Filed:
May 20, 1981
Date of Patent:
April 12, 1983
Assignee:
Agfa-Gevaert Aktiengesellschaft
Inventors:
Otto Lapp, Harald von Rintelen, Franz Moll, Lothar Endres
Abstract: A photographic material for diffusion transfer photography containing a quinonoid compound, which is capable in reduced state and under alkaline conditions of releasing a photographically useful group and corresponds to one of the following general formulae: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 (same or different) represents an oxidized nucleophilic group,Z represents a bivalent atom or bivalent atomic group, which is electro-negative,Q together with the group Z represents a releasable photographically useful group,Y.sup.1 and Y.sup.2 together represent the necessary atoms to close a p-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character,Y.sup.3 represents the necessary atoms to close a o-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, andeach of R.sup.1 and R.sup.
Type:
Grant
Filed:
March 31, 1981
Date of Patent:
February 1, 1983
Assignee:
Agfa-Gevaert, N.V.
Inventors:
Christian C. Van de Sande, Wilhelmus Janssens, Wolfgang Lassig, Ernst Meier
Abstract: This invention relates to amino hydroxy cyclohexenones of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each are alkyl, usually containing 1 to 20 carbon atoms.In another embodiment, the present invention is directed to the use of the above-denoted compounds as photographic silver halide developing agents and to photographic processes, products and compositions employing the same.
Abstract: A photographic recording material contains in a silver halide layer an emulsion mixture of at least one light sensitive silver halide and a comparatively non-light sensitive silver salt and in a second layer, which is in waterpermeable arrangement, an antifogging agent or a precursor compound thereof.
Type:
Grant
Filed:
May 20, 1981
Date of Patent:
January 18, 1983
Assignee:
Agfa-Gevaert Aktiengesellschaft
Inventors:
Erwin Ranz, Heinz-Dieter Schutz, Joachim W. Lohmann
Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.
Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.
Type:
Grant
Filed:
August 12, 1981
Date of Patent:
November 9, 1982
Assignee:
Eastman Kodak Company
Inventors:
Jared B. Mooberry, William C. Archie, Jr.
Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.
Abstract: The present invention is concerned with photographic products and processes employing certain pH-sensitive xanthene compounds as light-screening dyes, which compounds may be represented by the formulae ##STR1## wherein A and A', the same or different, are selected from ##STR2## each R is hydrogen or an electron-withdrawing group; each R.sup.1 is hydrogen or alkyl; each R.sup.2 is hydrogen, alkyl or an electron-withdrawing group; R.sup.3 is hydrogen or alkyl; R.sup.4 is alkyl; and n is 0 or 1 and which compounds in their colored, i.e., ring-opened form may be represented by the formulae ##STR3## wherein A, A', R.sup.3, R.sup.4 and n have the same meaning given above and Z is an anion.
Abstract: Novel nitrobenzyl compounds are incorporated into a photographic emulsion or developer for controlled release of development/image modifier compounds. This occurs imagewise only after developer oxidation products have been formed in the course of the development process. For example, nitrobenzyl-masked phenylmercaptotetrazole (PMT), incorporated into a silver halide emulsion, reacts with developer oxidation products via an electron transfer mechanism to release the potent development restrainer PMT.
Abstract: A silver halide photographic light-sensitive element is described comprising a support having thereon at least one silver halide emulsion layer, wherein at least one compound represented by formula (I) is incorporated in the silver halide emulsion layer or in another hydrophilic colloid layer: ##STR1## wherein X represents a hydroxy group or a group represented by ##STR2## wherein R.sup.2 and R.sup.3 (which may be the same or different) each reprsents hydrogen, an alkyl group, or an aryl group; R.sup.1 represents a sulfur-containing saturated heterocyclic group or a group represented by -A-S-B, wherein A represents an alkylene group and B represents hydrogen, an alkyl group, or an aryl group; and Z represents an atomic group forming a 5-membered or 6-membered unsubstituted or substituted carbocyclic ring.In the silver halide photographic light-sensitive element, the so-called "latent image fading" phenomenon is prevented without accompanying degradation of other photograhic properties.
Abstract: A process for developing a light-sensitive material comprising a support having thereon at least one internal latent image-forming silver halide photographic emulsion layer which comprises, after imagewise exposure, developing the light-sensitive material with an alkaline solution of a developing agent in the presence of a compound represented by the formula I which is capable of selectively forming latent images in the inner portions of said silver halide upon development: ##STR1## wherein Y represents an acyl group or a cyano group and said acyl group and the 3-, 4- or 5-position of the pyridinium ring may be optionally substituted.
Abstract: A silver halide color photographic light-sensitive material which contains at least one compound represented by the following general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents a hydrogen atom or an aliphatic group; R.sup.5 represents an aliphatic group or an aromatic group, R.sup.6 and R.sup.7, which may be the same or different, each represents a cyano group, a --COR.sup.8 group, a --COOR.sup.8 group or a --SO.sub.2 R.sup.9 group; and R.sup.8 represents an aliphatic group and R.sup.9 represents an aliphatic group or an aromatic group. The silver halide color photographic light-sensitive material has improved color reproduction which is not affected by differences in the ultraviolet light absorption characteristics of the camera lens.
Abstract: This invention relates to photographic materials containing an ion pair compound which has a quaternary nitrogen atom as a cation and a boron compound as an anion.
Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide emulsion layer, at least one of the layers of said photographic sensitive material containing at least one compound selected from the group consisting of those compounds represented by the formulae (I), (II), (III) and (IV):[Co(NH.sub.3).sub.6 ][R.sup.1 COO].sub.3 (I)[Co(NH.sub.3).sub.6 ][R.sup.2 OOCR.sup.3 COO].sub.3 (II)[Co(NH.sub.3).sub.5 (R.sup.4 COO)]X.sub.2 (III)[Co(NH.sub.3).sub.5 (R.sup.5 NH.sub.2)]X.sub.3 (IV)wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group having at least 3 carbon atoms or a fluorine-substituted alkyl group having at least 1 carbon atom; R.sup.3 is an alkylene group; R.sup.5 is an alkyl group having at least 1 carbon atom; X is a halogen atom, a nitrate ion, a sulfate ion, or a carboxylate ion is disclosed.
Abstract: A silver halide photographic light-sensitive material containing at least one photographic layer containing acid-processed gelatin and a matting agent.
Abstract: Hydroquinone esters are incorporated in photographic elements for color diffusion transfer assemblages and release a competing developer upon contact with a processing composition, to terminate further dye release. The hydroquinone esters are employed in a concentration sufficient, upon hydrolysis, to reduce substantially all the silver in the silver halide emulsion.
Abstract: Said material contains a quinone-type compound which corresponds to one of the formulae (A) or (B) and which is capable in reduced state and under alkaline conditions of releasing a photographically useful group e.g. a dye: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 represents an oxidized nucleophilic group,Z represents a bivalent atomic group which is electronegative,Q together with the Z group represents a releasable photographically useful group,each of R.sup.1, R.sup.2 and R.sup.3 is hydrogen, halogen, alkyl, alkoxy, or an acylamino group or R.sup.1 and R.sup.2 in adjacent positions on the ring form a ring fused with the remainder of the molecule, or R.sup.2 and R.sup.3 together are fused with the remainder of the molecule.each of R.sup.4 and R.sup.5 represents hydrogen or a hydrocarbon group.At least one of the substituents R.sup.1, R.sup.2, R.sup.3, R.sup.4 or R.sup.5 is a ballasting group X.
Abstract: A silver halide photo-sensitive material is provided having a hydrophilic colloid layer containing dispersed therein finely divided particles of a substantially water-immiscible mixture containing a hydrophobic photographic substance. The aforesaid mixture contains a polymer having recurring units represented by the following general formula (I) ##STR1## where, in the above formula, R.sub.1 represents a hydrogen atom or methyl group, R.sub.2 represents a hydrogen atom or substituted or unsubstituted aliphatic hydrocarbon radical containing 1 to 12 carbon atoms, X represents a bivalent substituted or unsubstituted aliphatic hydrocarbon radical containing 2 to 8 carbon atoms, and n is an integer of 1 to 50.
Type:
Grant
Filed:
April 20, 1979
Date of Patent:
May 6, 1980
Assignees:
Fuji Photo Film Co., Ltd., National Patent Development Corporation
Abstract: A light-sensitive silver halide photographic material comprising a m-aminophenol type coupler of the structure particularly defined therein is disclosed, which can successfully yield an excellent image stable against oxidation.
Abstract: A photographic light-sensitive material comprising a support having thereon at least one silver halide photographic emulsion layer and containing an emulsified dispersion comprising an organic solvent and an organic solvent gelling agent in at least one hydrophilic colloid layer thereof, a process for producing an emulsified dispersion using an organic solvent gelling agent and a process for stabilizing a photographic light-sensitive material containing an emulsion of an oleophilic photographic additive in a hydrophilic colloid layer thereof using an organic solvent gelling agent.
Abstract: Undesired color fog obtained on color development of a color photographic material with a primary aromatic amino color developing agent may be reduced when the development is carried out in the presence of an antifogging agent (antistaining agent) of the formula ##STR1## in which R.sup.1 is an acyl group and R.sup.2 and R.sub.3 are (same or different) hydrogen, alkyl, halogen, sulfo or carboxyl.The antistaining agent is preferable incorporated in non-diffusible form in one or more of the layers of the photographic material.