Multiple Sensitizers Or Supersensitizing Patents (Class 430/572)
  • Publication number: 20020146653
    Abstract: A lightsensitive silver halide photographic emulsion comprises silver halide grains, a sensitizing dye having a given maximum absorption wavelength and an organic compound exhibiting no absorption in a visible light region. The addition amount of the organic compound is in the range of 1 to 50 mol % based on the sensitizing dye, and a maximum absorption wavelength of the photographic emulsion exhibited by the sensitizing dye in the presence of the organic compound is at least 2 nm shorter than the maximum absorption wavelength exhibited by the sensitizing dye in the absence of the organic compound.
    Type: Application
    Filed: August 8, 2001
    Publication date: October 10, 2002
    Inventor: Kiyoshi Morimoto
  • Patent number: 6461803
    Abstract: A silver halide color photographic lightsensitive material comprising at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support, wherein the lightsensitive material has an ISO speed of 640 or more, and has a variation, in terms of a SNGR ratio, of magenta and cyan colors of 0 dB or more when the lightsensitive material is subjected to each of white light exposure, white fluorescent lamp exposure and three band fluorescent lamp exposure.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: October 8, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Suga, Takanori Hioki, Jun Okamoto
  • Publication number: 20020086249
    Abstract: A method of processing a silver halide color photographic lightsensitive material. The material comprises a support and at least one lightsensitive silver halide emulsion layer containing a binder and lightsensitive silver halide grains comprising tabular grains on the support. The material further comprises a developing agent or its precursor, and a compound capable of forming a dye by a coupling reaction with the developing agent in an oxidized form. The method comprises (a) exposing the material under natural light of 2000-9000K color temperature or artificial light corresponding thereto, for {fraction (1/10)}-{fraction (1/1000)} sec, in an exposure amount such that 80-90% (numerical ratio) of the grains contained in the lightsensitive layer have at least one development initiating point per grain, and (b) color developing the exposed material so that the tabular grains have 3.0 or more (average) development initiating points per grain at the completion of the development.
    Type: Application
    Filed: May 2, 2001
    Publication date: July 4, 2002
    Inventors: Makoto Kikuchi, Yoshio Ishii, Toshio Kawagishi
  • Patent number: 6387610
    Abstract: A silver halide photographic emulsion which contains silver halide grains having light absorption strength of 100 or more.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: May 14, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuhiro Yamashita, Katsumi Kobayashi
  • Publication number: 20020055070
    Abstract: A silver halide photographic light-sensitive material comprising, on a support, at least one light-sensitive silver halide emulsion layer and at least one non-light-sensitive layer, wherein 60% or more of the total projected area of silver halide grains contained in said at least one light-sensitive silver halide emulsion layer are tabular silver halide grains having an average aspect ratio of 5 or more, and a film pAg on the light-sensitive silver halide emulsion layer side of said material falls within 4.0 to 8.5.
    Type: Application
    Filed: June 8, 2001
    Publication date: May 9, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Minoru Uchida
  • Patent number: 6361932
    Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein Dye 2 is other than a cyanine dye, wherein the dye layers are held together by non-covalent forces; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: March 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Thomas L. Penner, William J. Harrison, Margaret J. Helber
  • Publication number: 20020012891
    Abstract: A silver halide photographic emulsion which contains at least two sensitizing dyes represented by the following formula (I):
    Type: Application
    Filed: May 1, 2001
    Publication date: January 31, 2002
    Inventors: Tetsuo Nakamura, Takanori Hioki
  • Patent number: 6333143
    Abstract: There is disclosed a method for forming an image on a light-sensitive material having on a base at least a light-sensitive silver halide emulsion and a binder, which comprises, subjecting at least one light-sensitive layer to exposure to light, by using an exposure head that has a plurality of different light sources for emitting lights in respective specific wavelength regions correspondingly to adjacent exposure picture elements, to form an image, wherein, in the specific wavelength regions from the shortest wavelength to the longest wavelength for the respective plurality of light sources to be used, the change in sensitivity of the light-sensitive material in the spectral sensitivity curve obtained by plotting the sensitivities of the light-sensitive material in terms of the specific wavelength regions including the wavelengths in centers of gravity of respective light sources is 0.01 log E/nm or less.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: December 25, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Shibata, Yuji Mihara
  • Patent number: 6331385
    Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising tabular silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, wherein the dye layers are held together by non-covalent forces or by in situ bond formation; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: December 18, 2001
    Assignee: Eastman Kodak Company
    Inventors: Joseph C. Deaton, Richard L. Parton, Thomas L. Penner, William J. Harrison, David E. Fenton
  • Patent number: 6329133
    Abstract: This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith a combination of two or more dyes wherein (b) (a) a dye having at least one substituent that has a negative charge is present, a dye having at least one substituent that has a positive charge is present, wherein at least one of the dyes is further substituted with at least one hydrogen bonding donor substituent. In a preferred embodiment, at least one of the dyes is substituted with at least two hydrogen bonding donor substituents. In another preferred embodiment a silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith a dye substituted with at least one guanidinium, amidinium, or imine of urea substituent.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: December 11, 2001
    Assignee: Eastman Kodak Company
    Inventors: Andrei Andrievsky, Richard L. Parton, Thomas L. Penner, William J. Harrison
  • Patent number: 6312883
    Abstract: A silver halide photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dyes: (a) a first dye that has at least one anionic substituent and that is capable of spectrally sensitizing a silver halide emulsion; and (b) a second dye of formula II  wherein: R1 is a substituted or unsubstituted alkyl or aryl group; E3 represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus; Ar1 represents an electron-withdrawing substituted aryl, or a substituted or unsubstituted electron-withdrawing heteroaryl group; L11 through L14 are substituted or unsubstituted methine groups; s is 0 or 1; G1 is an electron-withdrawing group; G2 is O or dicyanovinyl (C(CN)2); W1 is a counterion if necessary.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: November 6, 2001
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Thomas L. Penner, Stephen A. Hershey
  • Patent number: 6300051
    Abstract: A method has been disclosed for preparing a tabular silver halide emulsion wherein tabular silver halide grains having an average aspect ratio of at least 2:1, an average crystal diameter from 0.3 &mgr;m to 3.0 &mgr;m and an average thickness of less than 0.50 &mgr;m account for at least 50% of the total projective surface area of said grains, said method comprising the steps of precipitating, spectrally sensitizing and chemically ripening said grains, characterized by spectrally sensitizing by adding to the emulsion grains before chemically ripening at least one J-band aggregating spectrally sensitizing dye and at least one non-J-band aggregating dye.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: October 9, 2001
    Assignee: Agfa-Gevaert
    Inventors: Marc Van den Zegel, Kathy Elst
  • Publication number: 20010024772
    Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a light-sensitive silver halide, a reducing agent, and a compound represented by the following formula, 6-aryl-2,4-bis(tribromomethyl)-s-triazine or a 6-heteroaryl-2,4-bis(tribromomethyl)-s-triazine.
    Type: Application
    Filed: February 13, 2001
    Publication date: September 27, 2001
    Inventors: Katsura Hirai, Kiyoshi Fukusaka
  • Patent number: 6251578
    Abstract: A photographic element comprises: a support and, coated on the support, a plurality of hydrophilic colloid layers, including radiation-sensitive silver halide emulsion layers, forming layer units for separately recording blue, green and red exposures, wherein, the red recording layer unit is comprised of at least one green-red sensitive emulsion having a peak dyed absorptance of between about 525 and about 600 nm, an overall half-peak absorptance bandwidth of between about 70 and about 150 nm, and a ratio of the bandwidths at 80% of peak absorptance to 50% of peak absorptance of greater than or equal to about 0.25. In preferred embodiments of the invention, the photographic element is especially suited for more accurately recording scenes according to the human visual system.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: June 26, 2001
    Assignee: Eastman Kodak Company
    Inventors: Lois A. Buitano, Allan F. Sowinski, Steven G. Link
  • Patent number: 6225036
    Abstract: A multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises tabular grains having {111} major faces containing greater than 50 mole percent bromide, and accounting for greater than 50 percent total grain projected area precipitated in a peptizer that is a water dispersible cationic starch, and contains a fragmentable electron donating sensitizer.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: May 1, 2001
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
  • Patent number: 6187525
    Abstract: A photographic recording element is disclosed containing in at least one dye image forming layer unit (a) a radiation-sensitive silver halide grains include tabular grains (1) having {111} major faces, (2) containing greater than 50 mole percent bromide, based on silver, and (3) accounting for greater than 50 percent total grain projected area, (b) a fragmentable electron donating sensitizer, (c) a water dispersible cationic starch peptizer, and (d) a one equivalent dye image providing coupler. Increased photographic speed is realized.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: February 13, 2001
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, Kenneth J. Reed, Victor P. Scaccia, James A. Friday
  • Patent number: 6165703
    Abstract: A silver halide color photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dye layers comprising(a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and(b) an outer dye layer adjacent to the inner dye layer and comprising at least one cyanine dye, Dye 2,wherein one of Dye 1 or Dye 2 has at least one anionic substituent and one of Dye 1 or Dye 2 has at least one cationic substituent and wherein the dye layers are held together by more than one non-covalent force; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer.
    Type: Grant
    Filed: September 11, 1998
    Date of Patent: December 26, 2000
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Thomas L. Penner, Andrei Andrievsky, William J. Harrison
  • Patent number: 6159678
    Abstract: A photographic element comprising at least one silver halide emulsion layer in which the silver halide has been sensitized with a first blue sensitizing dye having a .lambda..sub.1 less than or equal to about 475 nm and a second blue sensitizing dye having a .lambda..sub.2, wherein .lambda..sub.1 is longer than .lambda..sub.2 and .lambda..sub.1 and .lambda..sub.2 are separated by an energy gap, .DELTA.E, which does not exceed 0.12 eV, where .DELTA.E is defined by the following relationship: ##EQU1## wherein .lambda..sub.1 is the wavelength in nanometers (nm) of maximum absorption of a silver halide emulsion sensitized with the first dye and .lambda..sub.2 is the wavelength of maximum absorption of a silver halide emulsion sensitized with the second dye, with the proviso that neither the first nor the second dye contains selenium.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: December 12, 2000
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, Thomas R. Dobles, David A. Stegman, Teresa A. Smith, John D. Lewis
  • Patent number: 6156466
    Abstract: The present invention relates to photoconductors which exhibit excellent electrical properties which are not appreciably affected by environmental changes or by repeated use. Having excellent durability during repeated printing, these photoconductors can be used to obtain large quantities of high-quality output images.The photoconductor according to the invention includes a conductive substrate and a photoconductive film on the conductive substrate. The photoconductive film includes a plurality of charge generation and transport layers, wherein each layer contains a phthalocyanine compound described in the specification by chemical formula (I) as a charge generation agent and a charge transport agent dispersed or dissolved into a binder. The concentration of the charge generation agent in an upper layer is higher than in a lower layer.
    Type: Grant
    Filed: July 8, 1998
    Date of Patent: December 5, 2000
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Shinichi Tamura, Tadashi Mimura, Yoji Yamada, Tadashi Asakawa, Hiroshi Kimura
  • Patent number: 6153362
    Abstract: A photographic element containing a support; at least two contiguous layers, at least one of which is a silver halide emulsion layer superposed on a side of said support; a processing solution permeable protective overcoat containing a urethane-vinyl copolymer having acid functionalities wherein a weight ratio of a urethane component in the copolymer comprises from 20 to 100 percent and a weight ratio of a vinyl component in the copolymer comprises from 0 to 80 percent; a crosslinker for the said copolymer; and a second polymer selected from the group consisting of polyvinyl alcohol, cellulose ethers, n-vinyl amides, polyesters, poly(ethylene oxide), starch, proteins, whey, albumin, poly(acrylic acid), alginates and gums overlying the said at least two contiguous layers; and wherein the ratio of the gelatin to non-gelatin content of the dried layers immediately underlying the uppermost gelatin layer is less than 1.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: November 28, 2000
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Lloyd A. Lobo, Tamara K. Jones
  • Patent number: 6150082
    Abstract: A silver halide photographic material is disclosed which contains at least one compound represented by the following formula (I) and at least one dye having the absorption maximum in a methanol solution at from 510 to 535 nm: ##STR1## wherein R.sup.1 and R.sup.2 each represents an alkyl group; Y represents an aryl group or a heterocyclic group; V.sup.1, V.sup.2, V.sup.3 and V.sup.4 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxyl group, a hydroxyl group, an alkylthio group, a mercapto group, a cyano group, an acyl group, a carboxyl group, or an alkoxycarbonyl group; X.sup.1 represents a counter ion; and m.sup.1 represents a number of 0 or more necessary for neutralizing a charge in the molecule.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: November 21, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuo Nakamura, Ryuji Abe, Takanori Hioki
  • Patent number: 6120982
    Abstract: A silver halide photographic material comprises a red sensitive layer which contains a high chloride emulsion sensitized with at least two red sensitizing dyes. By adjusting the relative amounts of the two dyes the heat sensitivity of the red layer can be adjusted to match that of the blue sensitive and green sensitive layers to maintain color balance despite thermal fluctuations.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: September 19, 2000
    Assignee: Eastman Kodak Company
    Inventors: Richard Lee Parton, Paul Timothy Hahm
  • Patent number: 6117629
    Abstract: A silver halide photographic emulsion which contains silver halide grains having light absorption strength of 100 or more.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: September 12, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuhiro Yamashita, Katsumi Kobayashi
  • Patent number: 6090511
    Abstract: An improved photoreceptor is disclosed which contains a multi-layered charge generation layer formed on a substrate and a charge transport layer formed on the multi-layered charge generation layer. The multi-layered charge generation member is formed by sequentially forming a plurality of charge generation sub-layers first on the substrate then on the charge generation sub-layer that was already formed, so as to create at least one interface between the charge generation layers. The charge generation materials in the plurality of charge generation layers must satisfy the following relationship:(IP).sub.CGL1 .gtoreq.(IP).sub.CGL2 .gtoreq.(IP).sub.CGL3 . . . .gtoreq.(IP).sub.CGLnwherein: (IP).sub.CGLi, i=1, 2, . . . , n, represents an ionization potential of the charge generation material in charge generation layer i; and (b) a lower value of i indicating closer proximity to the substrate, and a greater value i indicates further away from the substrate.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: July 18, 2000
    Assignee: Sinonar Corp.
    Inventors: Chen-Jen Yang, Kuo-Chu Yeh
  • Patent number: 6074814
    Abstract: A photothermographic recording material comprising a photo-addressable thermally developable element including a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt, in a quantity of 0.1 to 35 mol % relative to the organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder comprises a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer and the dye is represented by formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: June 13, 2000
    Assignee: Agfa-Gevaert
    Inventors: Geert Deroover, Herman Uytterhoeven, Paul Callant, Johan Loccufier
  • Patent number: 6040131
    Abstract: A camera-speed color photothermographic imaging method is disclosed. A photothermographic film is employed that contains a photographically responsive, thermally developable panchromatically sensitized emulsion layer unit capable of concurrently forming silver and dye image densities. The emulsion layer unit is exposed in three separate image capture areas to blue, green or red light received from the photographic subject to create latent images of blue, green and red light exposure. The photothermographic element is thermally processed to produce images of the same hue in each of the three separate image capture areas. The images of blue, green and red light exposures are then converted into a corresponding additive or subtractive primary hue, and integrated to provide a positive or negative color image of the photographic subject.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: March 21, 2000
    Assignee: Eastman Kodak Company
    Inventors: Lyn M. Eshelman, Timothy W. Stoebe
  • Patent number: 6040125
    Abstract: A color photographic recording material having at least one red-sensitive silver halide emulsion layer unit with which a cyan coupler is associated, at least one green-sensitive silver halide emulsion layer unit with which a magenta coupler is associated, at least one blue-sensitive silver halide emulsion layer unit with which a yellow coupler is associated, and optionally further light-insensitive layers, the blue-sensitive silver halide emulsion layer unit of which comprises at least two blue-sensitive partial layers which are sensitized with sensitizing dyes in such a way that a sensitivity curve ensues which is characterized by the following parameters:460 nm.ltoreq..lambda.(S.sub.max).ltoreq.480 nmb.sub.80 .gtoreq.24 nmb.sub.50 .gtoreq.91 nm,b.sub.20 .gtoreq.106 nm,wherein.lambda.(S.sub.max) denotes the wavelength of the sensitivity maximum (100 % sensitivity);b.sub.80 denotes the width of the sensitivity curve at 80% of the maximum sensitivity;b.sub.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: March 21, 2000
    Assignee: Agfa-Gevaert NV
    Inventors: Jorg Siegel, Hans-Ulrich Borst, Peter Bell, Ralf Buscher, Heinz Reif, Jurgen Jung
  • Patent number: 5965345
    Abstract: A method of sensitizing a silver halide emulsion comprises the steps of:a) forming a co-dispersion of a first sensitizing dye and a second sensitizing dye in an aqueous medium, wherein the peak absorptance of the second dye is at least 10 nm different from the peak absorptance of the first dye, and wherein the ratio of the first dye to the second dye is from about 0.1 to 20; andb) incorporating the resulting co-dispersion in a silver halide emulsion.
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: October 12, 1999
    Assignee: Eastman Kodak Company
    Inventors: Steven George Link, John William Boettcher, Frederick Charles Derks, Heidi Melissa Viterise
  • Patent number: 5955255
    Abstract: A black and white silver halide motion picture sound recording film is disclosed comprising a support bearing at least one silver halide emulsion layer, wherein said film is spectrally sensitized both above and below 600 nm. Such film may be used for recording multiple optical soundtracks by exposing said film with a first source of radiation having a peak wavelength of less than or equal to 600 nm, recording a second digital soundtrack by exposing said film with a second source of radiation having a peak wavelength of greater than 600 nm, and processing said exposed film to form first and second digital soundtrack silver images.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: September 21, 1999
    Assignee: Eastman Kodak Company
    Inventors: Steven Mark Gerlach, Gregory Edward Farrell
  • Patent number: 5925509
    Abstract: A silver halide photographic material having improved heat sensitivity comprises a red sensitive silver halide emulsion layer the silver halide of which is prepared in the presence of a hexacoordination complex of rhenium, ruthenium or osmium with at least four cyanide ligands and comprising at least about 90 mole percent silver chloride, wherein the emulsion contains at least one red sensitizing dye.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: July 20, 1999
    Assignee: Eastman Kodak Company
    Inventors: Richard Paul Garnsey, Pamela McCue Ferguson, Richard Lee Parton, Paul Timothy Hahm
  • Patent number: 5922525
    Abstract: A silver halide photographic material having improved heat sensitivity comprises a red sensitive silver halide emulsion layer the silver halide of which is prepared in the presence of a hexacoordination complex of rhenium, ruthenium or osmium with at least four cyanide ligands and comprising at least about 90 mole percent silver chloride, wherein the emulsion contains a thiosulfonate and a sulfinate or seleninate and at least one red sensitizing dye.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: July 13, 1999
    Assignee: Eastman Kodak Company
    Inventors: Richard Paul Garnsey, Pamela McCue Ferguson, Richard Lee Parton, Paul Timothy Hahm
  • Patent number: 5876915
    Abstract: A photothermographic recording material comprising a support and a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a binder, characterized in that the dye is represented by formula (I): ##STR1## with an anion if necessary for charge compensation, wherein Z.sup.1 and Z.sup.2 independently represent S, O or Se; R.sup.1 and R.sup.13 independently represent an alkylene group; X.sup.1 and X.sup.2 independently represent a --(C.dbd.O)--R.sup.18, a --(SO.sub.2)R.sup.19 or a (S.dbd.O)--R.sup.20 group where R.sup.18, R.sup.19, and R.sup.20 independently represent an alkoxy-, aryloxy-, amino- or substituted amino-group.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: March 2, 1999
    Assignee: Agfa-Gevaert
    Inventors: Geert Deroover, Ivan Hoogmartens, Hans Strijckers
  • Patent number: 5858639
    Abstract: A photographic recording material with at least one light-sensitive silver halide emulsion layer, the silver halide of which is spectrally sensitised with at least one cyanine dye having the general formula (I) ##STR1## wherein X means O, S, Se, NR.sub.3 or --CH.dbd.CH--,R means alkyl,n means 1, 3, 5, 7R.sub.1, R.sub.2, R.sub.3 mean alkyl, arylalkyl, sulphoalkyl, carboxyalkyl, --(CH.sub.2).sub.m --SO.sub.2 --NH--SO.sub.2 -alkyl, --(CH.sub.2).sub.m --SO.sub.2 --NH--CO-alkyl, --(CH.sub.2).sub.m --CO--NH--SO.sub.2 -alkyl, --(CH.sub.2).sub.
    Type: Grant
    Filed: March 13, 1997
    Date of Patent: January 12, 1999
    Assignee: Agfa-Gevaert AG
    Inventor: Michael Missfeldt
  • Patent number: 5856057
    Abstract: A motion picture sound recording chromogenic photographic film element for forming non-neutral images is disclosed comprising a film support bearing at least one silver halide emulsion layer comprising at least one dye-forming coupler which forms a dye which absorbs primarily in the green or red light region of the electromagnetic spectrum upon processing with color negative developer, wherein the element does not comprise a neutral-balanced combination of cyan, magenta, and yellow dye-forming couplers.
    Type: Grant
    Filed: May 5, 1997
    Date of Patent: January 5, 1999
    Assignee: Eastman Kodak Company
    Inventors: Vicky Sinn, Richard C. Sehlin, Mitchell J. Bogdanowicz, Patricia R. Greco, Gary N. Barber
  • Patent number: 5853968
    Abstract: The invention provides a color negative photographic element comprising a transparent support bearing at least two light sensitive silver halide emulsion layers sensitive to blue light, at least two such layers sensitive to green light, and at least two such layers sensitive to red light, wherein at least one of the red sensitive emulsion layers is spectrally sensitized with both a particular first carbocyanine dye (I) which contains both a thiazole and an oxazole ring and a particular second carbocyanine dye (II) which contains two thiazole rings.The element of the invention is advantageous in allowing an increased efficiency of silver removal during the bleaching step of the development process.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: December 29, 1998
    Assignee: Eastman Kodak Company
    Inventors: Daniel R. English, Steven G. Link, Hans G. Ling
  • Patent number: 5851755
    Abstract: A photothermographic recording material comprising a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt and spectrally sensitized to infra-red light with a dye, a supersensitizer for the dye, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, wherein the binder includes a water soluble polymer, a water-dispersible polymer or a water soluble polymer and a water-dispersible polymer; the dye absorbs electromagnetic radiation in the wavelength range from 700 to 1100 nm; and the supersensitizer is a stilbene compound represented by general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or alkyl, aryl, aralkyl, alkaryl, alkoxy or aryloxy groups; and R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11 and R.
    Type: Grant
    Filed: July 8, 1997
    Date of Patent: December 22, 1998
    Assignee: Agfa-Gevaert
    Inventors: Herman Uytterhoeven, Johan Loccufier, Geert Deroover, Paul Callant
  • Patent number: 5851752
    Abstract: Disclosed is a silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer comprising a substantially surface-latent-image-type silver halide emulsion which comprises hole-injection-type sensitizing dye(s) in an amount of 4.times.10.sup.-4 mol or more per mol of silver in the emulsion and further comprises supersensitizing compound(s), wherein the hole-injection-type sensitizing dye and the supersensitizing compound satisfy the requirements defined herein. The photographic material, thus comprising at least one silver halide emulsion that has been spectrally sensitized with a large amount of sensitizing dyes in a wavelength range longer than 545 nm and has been further sensitized by reduction sensitization, has a much increased sensitivity, while being fogged poorly, and has excellent storage stability.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: December 22, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsuhiro Uchida, Shunji Takada
  • Patent number: 5837440
    Abstract: A black and white silver halide motion picture sound recording film is disclosed comprising a support bearing at least one silver halide emulsion layer, wherein said film is spectrally sensitized both above and below 600 nm. Such film may be used for recording multiple optical soundtracks by exposing said to film with a first source of radiation having a peak wavelength of less than or equal to 600 nm, recording a second digital soundtrack by exposing said film with a second source of radiation having a peak wavelength of greater than 600 nm, and processing said exposed film to form first and second digital soundtrack silver images.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: November 17, 1998
    Assignee: Eastman Kodak Company
    Inventors: Steven Mark Gerlach, Gregory Edward Farrell
  • Patent number: 5780198
    Abstract: A silver halide photographic material comprising a plurality of light-sensitive silver halide emulsion layers, wherein (A) at least one of the layers contains a hydrazine nucleating agent represented by formula (II): ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a hydrazine group, a carbamoyl group, or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfinyl group, a sulfoxy group, ##STR2## a thiocarbonyl group, or an iminomethylene group; and A.sub.3 and A.sub.4 each represents a hydrogen atom, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group, provided that at least one of A.sub.3 and A.sub.
    Type: Grant
    Filed: February 15, 1995
    Date of Patent: July 14, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Kazunobu Katoh, Minoru Sakai
  • Patent number: 5747230
    Abstract: A photographic silver halide color print material comprising a support and yellow, magenta and cyan dye image forming layer units comprising at least one silver halide emulsion layer and at least one dye image-forming coupler which material contains a total silver halide coating weight less than 150 mg/m.sup.2 (as silver) and wherein the grain size (average volume in cubic microns) of the emulsion(s) is less than 1.0 (.mu.m).sup.3 in the yellow image forming unit and less than 0.125 (.mu.m).sup.3 in the magenta image forming unit and wherein each layer unit of the material has a dye image-forming efficiency (E) under conditions of use of above 30 where: ##EQU1## wherein the emulsion(s) of the cyan dye image forming layer unit have a silver coating weight less than 50 mg/m.sup.2, and an average grain size less than 0.064 (.mu.m).sup.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: May 5, 1998
    Assignee: Eastman Kodak Company
    Inventors: John Arthur Bee, John Kenneth Charles Kempster, Gareth Evans
  • Patent number: 5707794
    Abstract: Improved spectral sensitization with a synergistic combination of dyes is described. The two dyes include a first sensitizing dye is represented by Formula 1. ##STR1## and a second dye represented by Formula 2. ##STR2## The substituents of are defined in the description.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: January 13, 1998
    Assignee: Sterling Diagnostic Imaging, Inc.
    Inventor: Dietrich Max Fabricius
  • Patent number: 5700608
    Abstract: A photographic element is described which comprises a silver halide emulsion having incorporated therein a latent image forming unit, said unit being comprised of an agglomeration of silver halide in conductive contact with a light absorbing center, wherein the center is comprised of:(i) an amorphous or liquid crystalline spectral sensitizing dye; or(ii) a plurality of spectral sensitizing dye crystals.Also described is a process for forming a silver halide emulsion and the emulsion prepared by such process.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: December 23, 1997
    Assignee: Eastman Kodak Company
    Inventors: Lyn Marie Eshelman, David Darrell Miller, David Howard Levy
  • Patent number: 5665532
    Abstract: A black & white paper with variable gradation containing a silver chloride-bromide emulsion, which is divided into at least three portions, one of which is sensitised with a blue sensitiser and two further portions are sensitised both with differing quantities of blue sensitiser and with differing quantities of a green sensitiser, wherein the blue sensitiser is of the formula (I) and the green sensitiser is of the formula (II) ##STR1## in which R.sub.1 to R.sub.8, X.sup.(-) and m have the meaning stated in the specification, is distinguished by an extended gradation range.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: September 9, 1997
    Assignee: Agfa-Gevaert AG
    Inventors: Manfred Peters, Thomas Kaluschke, Hans Ohlschlager, Bruno Mucke
  • Patent number: 5543278
    Abstract: An infrared sensitive silver halide photographic element is disclosed comprising a support and at least one silver halide emulsion layer spectrally sensitized to the infrared portion of the electromagnetic spectrum. In particular, an infrared sensitive color photographic element, capable of providing full color images without exposure to corresponding visible radiation, is disclosed, said element comprising at least three silver halide emulsion layers on a substrate, each associated with different photographic color image forming materials, such as color couplers capable of forming dyes of different colors upon reaction with an oxidized color photographic developer, diffusing dyes, bleachable dyes, or oxidized leuco dyes. The three emulsion layers are sensitized to three different portions of the electromagnetic spectrum with at least two layers sensitized to different regions of the infrared region of the electromagnetic spectrum.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: August 6, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Bucci, Ivano Delprato, Giorgio Spazzapan
  • Patent number: 5541047
    Abstract: A silver halide photographic light-sensitive material is disclosed, comprising tabular grains having an average aspect ratio of diameter to thickness of 2 or more, having an average overall iodide content of 2 mol % or less, and having a surface phase containing 3 to 20 mol % iodide on the average.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: July 30, 1996
    Assignee: Konica Corporation
    Inventors: Hiroshi Kashiwagi, Hideki Takiguchi
  • Patent number: 5541054
    Abstract: The present invention provides heat-developable, photothermographic elements comprising a support bearing at least one photosensitive, image-forming layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible silver source;(c) a reducing agent for silver ions;(d) a binder; and(e) a spectrally sensitizing amount of a compound having the central nucleus: ##STR1## wherein: Z is S, O, Se or N--R.sup.3 ;R.sup.1 and R.sup.2 represent an alkyl group of from 1 to 20 carbon atoms other than carboxy-substituted alkyl, preferably an alkyl group of from 1 to 8 carbon atoms, and most preferably an ethyl group; andR.sup.3 is H or alkyl group;X and Y are thioalkyl groups of from 1 to 20 carbon atoms;n=0 to 4;m=0 to 4; the sum of n plus m equals at least 1;D.sup.1 to D.sup.7 each independently represents a methine group and adjacent methine groups selected from D.sup.2, D.sup.3, D.sup.4, D.sup.5 and D.sup.6 may form cyclic groups;p=0 or 1; andA.sup.- is an anion.
    Type: Grant
    Filed: April 20, 1995
    Date of Patent: July 30, 1996
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: James R. Miller, Brian C. Willett, Doreen C. Lynch, Becky J. Kummeth
  • Patent number: 5538836
    Abstract: A silver halide color photographic material having an excellent color reproducibility, high sensitivity and excellent graininess.The silver halide color photographic material contains at least one of each blue-sensitive emulsion, green-sensitive emulsion, red-sensitive emulsion layer and hydrophilic colloid layers, in which the hydrophilic colloid layer contains a compound of formula (I) and the silver halide emulsion layer, which gives an interlayer effect to said red-sensitive layer, contains a silver halide emulsion spectrally sensitized with a compound represented by formulae (II) and (III).
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: July 23, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumitaka Ueda, Junji Nishigaki, Tetsuo Nakamura
  • Patent number: 5536634
    Abstract: The invention provides a method of forming a spectrally sensitized emulsion comprising providing a silver bromoiodide emulsion, adding sensitizing dye ##STR1## X.sup.+ is a cation other than N-alkyl pyridinium, adding an N-alkyl pyridinium salt, and completing the heat cycle for sensitization.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: July 16, 1996
    Assignee: Eastman Kodak Company
    Inventor: Sang H. Kim
  • Patent number: 5529896
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the layer contains at least one compound represented by the following formula (I) and at least one compound represented by the following formula (X): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sub.4 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; and R.sub.1 and R.sub.2, and R.sub.3 and R.sub.4 each may be combined with each other to form a ring; ##STR2## wherein Z.sub.11 represents a sulfur atom, a selenium atom or a substituted nitrogen atom represented by ##STR3## in which R.sub.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: June 25, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Tadashi Ikeda
  • Patent number: 5478712
    Abstract: A ballasted amine is incorporated in a silver halide photographic element which contains a 2,4-disulfonamidophenol which functions as a scavenger for oxidized developing agent. The 2,4-disulfonamidophenol serves to avoid color contamination while the ballasted amine serves to reduce dye stain.
    Type: Grant
    Filed: November 22, 1993
    Date of Patent: December 26, 1995
    Assignee: Eastman Kodak Company
    Inventors: Stephen P. Singer, Susan D. Hill