Polymeric Arylamine Containing Patents (Class 430/58.7)
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Patent number: 7585603Abstract: A curable resin composition for use as a constituting material of an electrophotographic photoreceptor, comprises: a phenolic resin; a charge transportable material having a reactive functional group; and at least one of an organic sulfonic acid and its derivative.Type: GrantFiled: June 1, 2006Date of Patent: September 8, 2009Assignee: Fuji Xerox Co., Ltd.Inventors: Wataru Yamada, Katsumi Nukada, Masahiro Iwasaki, Kenji Yao
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Publication number: 20090220875Abstract: The present invention provides an electrophotographic photoconductor having a support, at least an intermediate layer, and a photosensitive layer, the intermediate layer and photosensitive layer being laid in this order over the support, wherein the intermediate layer comprises an amorphous oxide semiconductor.Type: ApplicationFiled: February 27, 2009Publication date: September 3, 2009Applicant: RICOH COMPANY, LTD.Inventor: Tetsuya TOSHINE
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Publication number: 20090185821Abstract: An electrophotographic photoreceptor including a conductive substrate; a charge generation layer comprising a metal phthalocyanine pigment as a charge generation material, located overlying the conductive substrate; a charge transport layer comprising a charge transport material having a triarylamine structure, located overlying the charge generation layer; and a cross-linked charge transport layer formed by hardening a radical-polymerizable monomer having no charge transport structure and a radical-polymerizable compound having a charge transport structure, located overlying the charge transport layer. The electrophotographic photoreceptor satisfies the following equations (1) and (2): ?0.16?Ip(T)?Ip(G)?0.07 ??(1) 0.07<Ip(O)?Ip(G)?0.33 ??(2) wherein Ip(G), Ip(T), and Ip(O) represent ionization potentials of the charge generation layer, the charge transport layer, and the cross-linked charge transport layer, respectively.Type: ApplicationFiled: January 12, 2009Publication date: July 23, 2009Applicant: RICOH COMPANY, LTDInventors: Takafumi Iwamoto, Nozomu Tamoto, Hiromi Tada
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Patent number: 7563553Abstract: A process for making an electrophotographic photosensitive member is provided by forming a photosensitive layer on an electroconductive support. The photosensitive layer is provided with particularly excellent durability while retaining good electrophotographic performances when formed as a layer comprising a polymerizate of a hole-transporting compound having at least two chain polymerization function groups in its molecule represented by formula (1) below: (P1aAzP2)d)b??(1), wherein A denotes a hole-transporting group, P1 and P2 independently denote a chain polymerization function group and Z denotes a bonding organic group; a, b and d are independently an integer of at least 0 satisfying a+b×d?2 provided that if a?2, plural groups P1 can be identical or different; if b?2, plural groups Z can be identical or different; and if b×d?2, plural groups P2 can be identical or different.Type: GrantFiled: January 26, 2007Date of Patent: July 21, 2009Assignee: Canon Kabushiki KaishaInventors: Toshihiro Kikuchi, Akio Maruyama, Hiroki Uematsu
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Patent number: 7560203Abstract: An electrophotographic photoconductor that is excellent in the stability of image quality and can realize high durability is provided. In an electrophotographic photoconductor in which an underlying layer, a photoconductive layer, and a crosslinked-type charge transportation layer are stacked on an electrically conductive support in order, the underlying layer is composed of at least two layers being a layer containing an inorganic pigment and a layer including no inorganic pigment, and the crosslinked-type charge transportation layer is formed by curing, at least, a three-or-more-functional radical-polymerizable monomer having no charge transporting structure and a radical-polymerizable compound having one-functional charge transporting structure.Type: GrantFiled: December 1, 2004Date of Patent: July 14, 2009Assignee: Ricoh Company, Ltd.Inventors: Nozomu Tamoto, Tatsuya Niimi, Tetsuro Suzuki, Katsuichi Ohta
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Patent number: 7550238Abstract: An image forming process using an electrostatic latent image carrier containing a support and a photoconductive layer including: a charge generating layer, a charge transportable layer, and a cross-linked charge transportable layer which are disposed on the support in this order and the cross-linked charge transportable layer comprises a compound produced by the reaction between a trifunctional or more functional radical-polymerizable compound having no charge transportable structure, and a monofunctional radical-polymerizable compound having a charge transportable structure, and a toner produced in the form of particles by producing an adhesive base material through reacting a compound having an active hydrogen group with a polymer which can be reacted with the above-noted compound having an active hydrogen group in an aqueous medium.Type: GrantFiled: April 21, 2005Date of Patent: June 23, 2009Assignee: Ricoh Company, Ltd.Inventors: Kohichi Ohshima, Yasuo Suzuki, Tetsuro Suzuki, Michitaka Sasaki
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Patent number: 7538175Abstract: A polymer having hole transport functionality and antioxidant properties is disclosed. The polymer comprises a phenolic segment and a hole transport segment. The polymer is suitable for use in the charge transport layer of an imaging member. Processes for producing the polymer are also disclosed.Type: GrantFiled: October 13, 2005Date of Patent: May 26, 2009Assignee: Xerox CorporationInventors: Yu Qi, Nan-Xing Hu, Greg McGuire, Cuong Vong
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Patent number: 7537872Abstract: An image bearing member including an electroconductive substrate, a charge blocking layer disposed overlying the electroconductive substrate, a moire prevention layer disposed overlying the charge blocking layer, and a photosensitive layer disposed overlying the moire prevention layer. The charge blocking layer contains N-alkoxymethylized nylon and optionally at least one of an aliphatic dicarboxylic acid and an aliphatic tricarboxylic acid. The moire prevention layer contains a titanium oxide having a purity not less than 99.0% and a cross-linking resin.Type: GrantFiled: April 13, 2006Date of Patent: May 26, 2009Assignee: Ricoh Company LimitedInventors: Naohiro Toda, Yasuyuki Yamashita, Takeshi Orito
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Patent number: 7507509Abstract: An electrophotographic photoreceptor, including a crosslinked material including: units obtained from a radical polymerizing monomer A having three or more radical polymerizing groups; a compound B having the following formula (1): B1—Ar1—CH?CH—Ar2—B2 ??(1) wherein Ar1 represents a substituted or an unsubstituted monovalent group or bivalent group formed of an aromatic hydrocarbon skeleton; Ar2 represents a monovalent group or a bivalent group formed of an aromatic hydrocarbon skeleton or heterocyclic compound skeleton having one or more tertiaryamino group; and at least one of B1 and B2 is a hydrogen atom, and the other is an acryloyloxy group; a methacryloyloxy group; a vinyl group; an alkyl group having an acryloyloxy group, a methacryloyloxy group or a vinyl group; or an alkoxy group having an acryloyloxy group, a methacryloyloxy group or a vinyl group; and a photo polymerization initiator.Type: GrantFiled: October 7, 2005Date of Patent: March 24, 2009Assignee: Ricoh Company, Ltd.Inventors: Kazukiyo Nagai, Tetsuro Suzuki, Hiroshi Tamura, Hongguo Li
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Patent number: 7473504Abstract: An electrophotographic photoreceptor including an electroconductive substrate; and a photosensitive layer located overlying the electroconductive substrate, wherein an outermost layer of the electrophotographic photoreceptor is a crosslinked layer, including: a urethane oligomer having a radical polymerizing functional group; and a radical polymerizing compound having one functional group with a charge transporting structure, or a radical polymerizing oligomer having a polyester structure; a radical polymerizing compound having three or more functional groups without a charge transporting structure; and a radical polymerizing compound having one functional group with a charge transport structure, and wherein the outermost layer has an elasticity power not less than 41%.Type: GrantFiled: May 25, 2005Date of Patent: January 6, 2009Assignee: Ricoh Company, Ltd.Inventors: Yoshiki Yanagawa, Hiroshi Tamura, Tetsuro Suzuki, Naohiro Toda, Yoshiaki Kawasaki
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Patent number: 7452642Abstract: Hole transport polymers are disclosed. The polymers include modified triarylamine groups attached to a polymeric material such as, for example, poly(vinyl butyral). The polymers are particularly suited for use in multilayered photoreceptors. The polymers can be readily synthesized. Also disclosed are photoreceptors containing one or more layers that include the noted polymers.Type: GrantFiled: June 3, 2005Date of Patent: November 18, 2008Assignee: Xerox CorporationInventors: Yuhua Tong, John F. Yanus
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Patent number: 7449272Abstract: An electrophotographic photoreceptor, including an electroconductive substrate; and a photosensitive layer overlying the electroconductive substrate, which includes a crosslinked layer at the surface thereof, wherein the crosslinked layer is formed by a method including: coating a coating liquid, which includes a solvent; a radical polymerizing monomer having three or more functional groups and no charge transportable structure; and a radical polymerizing compound having a charge transportable structure on the photosensitive layer; and irradiating the coating liquid to be hardened while the surface of the photosensitive layer is controlled to have a temperature not higher than a boiling point of the solvent.Type: GrantFiled: November 15, 2005Date of Patent: November 11, 2008Assignee: Ricoh Company, Ltd.Inventors: Yoshiaki Kawasaki, Tetsuro Suzuki, Hiroshi Ikuno, Tetsuya Toshine
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Patent number: 7439002Abstract: A silicone overcoat (SOC) layer having a crosslinked polysiloxane composition comprising a perfluoropolyether segment are disclosed. The polysiloxane composition is the product of the hydrolysis and condensation of a SOC formulation comprising a perfluoropolyether compound, an aromatic silicon-containing compound, and a silicon-containing hole transport compound. An electrophotographic imaging member having such a SOC layer has improved properties.Type: GrantFiled: July 12, 2005Date of Patent: October 21, 2008Assignee: Xerox CorporationInventors: Nan-Xing Hu, John Graham, Ah-Mee Hor, Yvan Gagnon, Cheng-Kuo Hsiao
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Patent number: 7432028Abstract: This invention relates to a novel organophotoreceptor that includes: (a) a charge transport composition comprising molecules having the formula where n is an average of a distribution of integers generally between 2 and 50,000, and in which n is at least 2; R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X comprises an (N,N-disubstituted)arylamine group; and Y is a bridging group; (b) a charge generating compound; and (c) an electrically conductive substrate over which the charge transport composition and the charge generating compound are located.Type: GrantFiled: February 4, 2004Date of Patent: October 7, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Vytautas Getautis, Tadas Malinauskas, Juozas V. Grazulevicius, Valentas Gaidelis, Vygintas Jankauskas, Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law
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Patent number: 7416823Abstract: An electrophotographic photoconductor having at least a photoconductive layer on an electrically conductive support, in which a surface layer of the photoconductive layer can be obtained by curing at least a free-radical-polymerizable monomer having no charge transporting structure, represented by general formula (A) and a one-functional free-radical-polymerizable compound having a charge transporting structure, wherein R71, R72, R73, R74, R75, and R76 are described in the specification.Type: GrantFiled: January 13, 2005Date of Patent: August 26, 2008Assignee: Ricoh Company, Ltd.Inventors: Yoshiki Yanagawa, Hiroshi Ikuno, Hongguo Li, Kazukiyo Nagai, Hiroshi Tamura, Tetsuro Suzuki, Naohiro Toda, Yoshiaki Kawasaki
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Publication number: 20080166642Abstract: The present invention provides an electrophotographic photoconductor comprising an electroconductive substrate and a photosensitive layer provided on the electroconductive substrate, wherein the photosensitive layer comprises a charge-generating material and a charge-transporting material, the charge-transporting material comprising a compound represented by the general formula (1): wherein Ar1 and Ar2 each independently represent an optionally-substituted arylene or bivalent heterocyclic group; Ar3 and Ar4 each independently represent a hydrogen atom, or an optionally-substituted aryl or monovalent heterocyclic group, but are not simultaneously hydrogen atoms; or Ar3 and Ar4 may be taken together to form an optionally-substituted bivalent cyclic hydrocarbon or heterocyclic group; and n is 0 or 1.Type: ApplicationFiled: December 17, 2007Publication date: July 10, 2008Applicant: SHARP KABUSHIKI KAISHAInventors: Takatsugu Obata, Akihiro Kondoh
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Patent number: 7390600Abstract: An object is to provide a latent electrostatic image bearing member that can provide high-quality images for prolonged periods, owing to photosensitive layers and crosslinked surface layers having excellent flaw and wear resistance and appropriate electric properties, image forming method, image forming apparatus and process cartridge that employ latent electrostatic image bearing member respectively. Accordingly, provided is a latent electrostatic image bearing member that comprises a support and at least a photosensitive layer and a crosslinked surface layer disposed on the support, wherein the crosslinked surface layer comprises a reactant from radical polymerizable compounds having three or more functionalities with no charge transport structure and radical polymerizable compounds having one functionality with charge transport structure, and at least two different antioxidants.Type: GrantFiled: September 2, 2005Date of Patent: June 24, 2008Assignee: Ricoh Company, Ltd.Inventors: Naohiro Toda, Hiroshi Tamura, Yoshiki Yanagawa, Tetsuro Suzuki
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Patent number: 7381511Abstract: A photoreceptor including an electroconductive substrate; a photosensitive layer; and optionally a protective layer, wherein an outermost layer thereof includes a filler, an organic compound having an acid value of from 10 to 700 mg KOH/g and at least one compound selected from the group consisting of compounds having the following formulae (1) and (2): wherein R1 (R3) and R2 (R4) independently represent a substituted or an unsubstituted aromatic hydrocarbon group, or a substituted or an unsubstituted alkyl group, and optionally share bond connectivity to form a heterocyclic group including a nitrogen atom; Ar1 (Ar3) and Ar2 (Ar4) independently represent a substituted or a unsubstituted aromatic ring group; k (K) and m (M) independently represent 0 or an integer of from 1 to 3, wherein k (K) and m (M) are not 0 at the same time; and n (n?) represents an integer of from 1 to 3.Type: GrantFiled: June 1, 2004Date of Patent: June 3, 2008Assignee: Ricoh Company, Ltd.Inventors: Takaaki Ikegami, Tomoyuki Shimada, Yasuo Suzuki, Nozomu Tamoto, Hidetoshi Kami, Yuuji Takana
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Patent number: 7371490Abstract: The object of the present invention is to provide a photoconductor that is highly sensitive, stable in image quality under repeated usages, and affords prolonged life. In order attain the object, a photoconductor is provided that comprises a charge generating layer, a charge transporting layer, and a crosslinked charge transporting layer, on an substrate in order, the charge generating layer contains titanyl phthalocyanine crystal particles that exhibit a highest peak at 27.2°, main peaks at 9.4°, 9.6° and 24.0°, a peak at 7.3° as the lowest angle, and with no peaks in a range between 7.3° and 9.4°, and with no peak at 26.3° as Bragg 2?angles (±0.2°) in terms of CuK-? characteristic X-ray wavelength at 1.542 ?, and the averaged primary particle size of the titanyl phthalocyanine crystal particles is 0.Type: GrantFiled: October 28, 2004Date of Patent: May 13, 2008Assignee: Ricoh Company, Ltd.Inventors: Nozomu Tamoto, Tatsuya Niimi, Tetsuro Suzuki, Katsuichi Ohta
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Patent number: 7364824Abstract: An electrophotographic photosensitive member, a process cartridge and an electrophotographic apparatus are provided which not only secure mechanical strength sufficiently but also bring a vast improvement in charge transport performance and which can well satisfy electrical properties. An electrophotographic photosensitive member is provided an outermost surface layer of which contains at least a charge transporting compound having chain polymerizable functional groups which is represented by the following general formula (1-1) or (1-2); the charge transporting compound having been polymerized or cross-linked and cured. Also provided are a process cartridge and an electrophotographic apparatus which have such a photosensitive member.Type: GrantFiled: December 28, 2006Date of Patent: April 29, 2008Assignee: Canon Kabushiki KaishaInventors: Toshihiro Kikuchi, Atsushi Ochi, Harumi Sako, Kimihiro Yoshimura, Hideaki Tamai, Nobuo Kosaka
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Patent number: 7361438Abstract: Disclosed is an electrophotographic photoconductor including at least a photoconductive layer on a conductive substrate, wherein the surface layer of the photoconductive layer contains at least a surface crosslinked layer formed by curing a tri- or more-functional radical polymerizable monomer without having a charge transporting structure and a mono-functional radical polymerizable compound having a charge transporting structure and the surface crosslinked layer has a surface roughness Rz of 1.3 ?m or less.Type: GrantFiled: December 26, 2006Date of Patent: April 22, 2008Assignee: Ricoh Company, Ltd.Inventors: Tetsuro Suzuki, Hiroshi Tamura, Hiroshi Ikuno, Kazukiyo Nagai, Hongguo Li
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Patent number: 7354686Abstract: An electrophotographic photoconductor includes an electroconductive substrate, a charge generation layer, and a charge transport layer formed by using a halogen-free solvent, arranged in this order, in which the charge generation layer contains a charge generation material having an average particle diameter smaller than a surface roughness of a plane where the electroconductive substrate is arranged, and a polyvinyl acetal resin having a ratio Mw/Mn of a weight-average molecular weight Mw to a number-average molecular weight Mn is 2.2 or more.Type: GrantFiled: March 19, 2004Date of Patent: April 8, 2008Assignee: Ricoh Company, Ltd.Inventors: Naohiro Toda, Tatsuya Niimi, Ryohichi Kitajima, Yoshiaki Kawasaki
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Patent number: 7348112Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a polymeric charge transport material having the formula where n is a distribution of integers between 1 and 100,000 with an average value of greater than one; Y comprises an aromatic group; X1 and X2, each independently, is a bond or a linking group; Q1 and Q2 are, each independently, O, S, or NR; and R, R1, and R2 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of preparing the polymeric charge transport material are described.Type: GrantFiled: July 1, 2004Date of Patent: March 25, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Valentas Gaidelis, Vytautas Getautis, Tadas Malinauskas, Edmundas Montrimas, Kam W. Law
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Patent number: 7348113Abstract: A polycarbonate resin has a constitutional unit expressed by the following general formula (I): A1 represents an alkyl group which is substitutional or nonsubstitutional, and an aryl group which is substitutional or nonsubstitutional. A2, A3, A4, A5, A6 and A7 each represent one of a hydrogen atom, a halogen atom, an alkyl group which has 1 to 6 carbon atoms and is substitutional or nonsubstitutional.Type: GrantFiled: September 10, 2004Date of Patent: March 25, 2008Assignee: Ricoh Company, Ltd.Inventors: Masayuki Shoshi, Yuko Komai, Hiroshi Tamura, Masaomi Sasaki
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Patent number: 7341814Abstract: An electrophotographic photoconductor includes an electroconductive substrate, a photoconductive layer arranged over the electroconductive layer with or without the interposition of an undercoat layer, and a surface top layer containing a crosslinkable resin arranged over the photoconductive layer, the photoconductive layer includes a charge generation layer containing a charge generating material, and a charge transport layer containing a charge transporting material, in which the surface top layer is substantially free from hydroxyl groups and residual uncured portions.Type: GrantFiled: January 7, 2005Date of Patent: March 11, 2008Assignee: Ricoh Company, Ltd.Inventors: Hidetoshi Kami, Naohiro Toda, Yoshiaki Kawasaki, Maiko Kondo, Ryoichi Kitajima, Narihito Kojima, Hiroshi Nagame
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Publication number: 20080057424Abstract: Disclosed herein is an electrophotographic imaging member comprising a substrate, a charge transport layer and an overcoat layer formed by combining a film forming binder and a hole transporting hydroxy triarylamine compound having at least one hydroxyl functional group that is linked to a ring carbon of an aryl group by an alkyl group having 1 to 12 carbon atoms and is capable of forming at least one of a chemical bond and a physical bond with the film forming binder. Also disclosed is an electrophotographic imaging member with an overcoat layer formed by combining a film forming polycarbonate binder, a hole transport material, a surface energy reducing silicone material comprising a crosslinkable acrylate monomer, and a solvent. Coatings and methods of forming imaging members also are disclosed.Type: ApplicationFiled: August 31, 2006Publication date: March 6, 2008Inventors: Yuhua Tong, Cindy C. Chen, Susan M. VanDusen
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Publication number: 20080038648Abstract: An electrophotographic imaging member includes a substrate, a photogenerating layer, and an optional overcoating layer, where the photogenerating layer includes a multi-block polymeric charge transport material at least partially embedded within a carbon nanotube material.Type: ApplicationFiled: August 8, 2006Publication date: February 14, 2008Applicant: XEROX CORPORATIONInventors: Timothy P. BENDER, Nan-Xing HU
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Publication number: 20080026308Abstract: A photoconductive having an overcoat layer that includes a cured or substantially crosslinked product of at least a melamine-formaldehyde resin and a charge transport compound, and an optional phenol compound.Type: ApplicationFiled: July 25, 2006Publication date: January 31, 2008Applicant: Xerox CorporationInventors: Yu Qi, Nan-Xing Hu
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Publication number: 20070281228Abstract: An electrophotographic imaging member includes a substrate, a charge generating layer, a charge transport layer, and an overcoating layer, the overcoating layer being a cured film formed from a composition including at least a hydroxyl group-containing polymer or oligomer, a benzoguanamine compound containing at least one —CH2OR group, wherein each such R is independently an H atom or an alkyl group having from 1 to about 20 carbon atoms, and a charge transport compound.Type: ApplicationFiled: June 1, 2006Publication date: December 6, 2007Applicant: XEROX CORPORATIONInventors: Nan-Xing Hu, Kathy L. De Jong, Hany Aziz
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Patent number: 7297456Abstract: A member comprised of a photogenerating layer and a charge transport layer, and wherein the charge transport layer is comprised of a charge transport component or components, and a crosslinked polycarbonate polymer of the formula wherein X and Y represent the number of segments.Type: GrantFiled: August 4, 2004Date of Patent: November 20, 2007Assignee: Xerox CorporationInventors: Nan-Xing Hu, Timothy P. Bender, Ah-Mee Hor, H. Bruce Goodbrand, Yvan Gagnon
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Publication number: 20070254224Abstract: An electrostatic latent image bearing member is provided including a substrate and a photosensitive layer located overlying the substrate, wherein the outermost layer of the electrostatic latent image bearing member includes a cross-linked resin formed from a cross-linking reaction between a polyol having 2 or more hydroxyl groups including a reactive charge transport material having a specific formula and an isocyanate compound including an aromatic isocyanate compound having an isocyanate group and an aromatic ring; and the use of the electrostatic latent image bearing member in an image forming apparatus and a process cartridge.Type: ApplicationFiled: April 5, 2007Publication date: November 1, 2007Inventor: Akihiro SUGINO
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Patent number: 7271288Abstract: Disclosed is an aromatic compound expressed by the general formula (I), wherein A represents of a fused aromatic hydrocarbon moiety such as triphenylene, X represents a hydrogen-bonding site such as an atomic group containing an amide linkage, Y represents a chain functional group such as an alkyl group having 3 to 18, preferably 10 to 18 carbon atoms, and n represents an integer ranging from 2 to 10. The aromatic compound forms a molecular assembly in which the aromatic rings mutually overlap and exhibits an excellent charge carrier transfer property AX—Y)n.Type: GrantFiled: December 11, 2003Date of Patent: September 18, 2007Assignee: Kyushu University, National University CorporationInventors: Masayuki Takeuchi, Masato Ikeda, Seiji Shinkai
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Patent number: 7270924Abstract: A photoreceptor including an electroconductive substrate, a photosensitive layer located overlying the substrate, and a protective layer overlying the photosensitive layer, wherein the photoreceptor has a property such that when the photoreceptor is charged so as to have a potential of ?700 V and then exposed to light with exposure of 0.4 ?J/cm2, the potential (PL) of a lighted portion of the photoreceptor decreases at a rate not greater than 700 V/sec during a time period of from a time 35 msec after the exposure to the transition time of the photoreceptor. An image forming apparatus and a process cartridge including the photoreceptor are also provided.Type: GrantFiled: March 19, 2004Date of Patent: September 18, 2007Assignee: Ricoh Company LimitedInventor: Hidetoshi Kami
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Publication number: 20070212626Abstract: An electrophotographic photoreceptor is provided including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate; and an outermost layer located overlying the photosensitive layer, wherein the outermost layer is formed by a reaction between a radical polymerizable compound having no charge transport structure including a compound having a specific formula, and a radical polymerizable compound having a charge transport structure, while applying heat, light, or ionizing radiation to the reaction, and wherein at least one of the photosensitive layer and the outermost layer includes at least an arylmethane compound having an alkylamino group or a compound having a specific formula.Type: ApplicationFiled: March 9, 2007Publication date: September 13, 2007Inventors: Tetsuya Toshine, Yasuo Suzuki, Tetsuro Suzuki, Hidetoshi Kami, Yukio Fujiwara, Yoshinori Inaba
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Publication number: 20070212625Abstract: The present invention provides an image bearing member that includes: a photoconductor; and a heating unit which heats the photoconductor, wherein the photoconductor includes: a support; a charge generating layer on the support, a charge transport layer, and a crosslinked charge transport layer in this order, wherein the crosslinked charge transport layer includes a reaction product of a radically polymerizable compound with three or more functional groups which does not have a charge transporting structure, and a radically polymerizable compound with one functional group, which compound has a charge transporting structure.Type: ApplicationFiled: January 10, 2007Publication date: September 13, 2007Inventors: Yasuo Suzuki, Kohichi Ohshima, Tetsuro Suzuki, Michitaka Sasaki
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Publication number: 20070141488Abstract: In imaging member comprising a charge generating layer, a charge transport layers and an optional barrier layer between the charge generating layer and the charge transport layer. The charge transport layer may comprise a first and a second or more layers, wherein the first layer comprises a film-forming polymer having hole-transporting capability, but does not contain charge transport molecules.Type: ApplicationFiled: June 20, 2006Publication date: June 21, 2007Inventor: Robert C.U. Yu
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Patent number: 7226711Abstract: An object of the present invention is to improve a phenomenon of the life-shortening of the endurance life due to scratch occurring when recesses of a fixed dimple shape are formed on the surface of the surface layer, in order to inhibit the chattering and folding back of a cleaning blade and the fracture of an edge, which occurs because friction between the surface layer of the surface of an electrophotographic photosensitive member and an abutting member is high; and particularly to improve the above described problems, from initial printing through printing on many sheets, which become particularly remarkable when using an electrophotographic photosensitive member with the use of a curable resin that is improved so as to have a high elastic deformation rate for the surface layer, in order to improve the strength of the surface layer, for the purpose of increasing the durability of an electrophotographic photosensitive member.Type: GrantFiled: September 28, 2005Date of Patent: June 5, 2007Assignee: Canon Kabushiki KaishaInventors: Shoji Amamiya, Koichi Nakata, Tatsuya Ikezue, Takahiro Mitsui, Akira Shimada, Hiroki Uematsu, Shuji Ishii, Akio Maruyama
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Patent number: 7179573Abstract: Disclosed is an electrophotographic photoconductor including at least a photoconductive layer on an electroconductive substrate, which comprises at least a cross-linked surface layer formed by curing a tri- or more-functional radical polymerizable monomer without having a charge transporting structure and a mono-functional radical polymerizable compound having a charge transporting structure wherein the cross-linked surface layer has a surface roughness Rz of 1.3 ?m or less.Type: GrantFiled: March 19, 2004Date of Patent: February 20, 2007Assignee: Ricoh Company, Ltd.Inventors: Tetsuro Suzuki, Hiroshi Tamura, Hiroshi Ikuno, Kazukiyo Nagai, Hongguo Li
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Patent number: 7175958Abstract: An electrophotographic photoconductor contains a conductive support; and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>> ArN?N—Cp)n,??(<<1>>) wherein in the general formula <<1>>, Ar is a substituted or non-substituted aromatic series hydrocarbon group or an aromatic series heterocyclic ring group which can be bonded by way of a bonding group; Cp is a coupler residual group; n represents an integer of 1, 2, 3, or 4, at least one of the Cp is a coupler residual group selected from the group consisting of general formulae <<2>>, <<3>>, and <<4>> wherein in the general formulae <<2>>, <<3>>, and <<4>>, all substituents are as defined in the specification.Type: GrantFiled: November 5, 2004Date of Patent: February 13, 2007Assignee: Ricoh Company, Ltd.Inventors: Masayuki Shoshi, Yuuko Komai, Hongguo Li, Masaomi Sasaki
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Patent number: 7175957Abstract: Disclosed is an electrophotographic photoconductor including at least a photoconductive layer on a conductive substrate, wherein the surface layer of the photoconductive layer contains at least a surface crosslinked layer formed by curing a tri- or more-functional radical polymerizable monomer without having a charge transporting structure and a mono-functional radical polymerizable compound having a charge transporting structure and the surface crosslinked layer has a surface roughness Rz of 1.3 ?m or less.Type: GrantFiled: March 19, 2004Date of Patent: February 13, 2007Assignee: Ricoh Company, Ltd.Inventors: Tetsuro Suzuki, Hiroshi Tamura, Hiroshi Ikuno, Kazukiyo Nagai, Hongguo Li
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Patent number: 7094511Abstract: The present invention relates to an electrophotographic photoreceptor comprising a conductive support having formed thereon a specific photosensitive layer. The photosensitive layer comprises a siloxane resin-containing layer containing a siloxane resin having a structural unit represented by general formula (1) shown below, a structural unit represented by general formula (2) shown below, and an organic group derived from a compound having hole transport capability, or comprises a siloxane resin-containing layer containing a siloxane resin obtained by using an organic silicon compound having a structural unit represented by general formula (1) shown below and a hydrolytic group, and a compound represented by general formula (3) shown below: The formulas are defined in the specification.Type: GrantFiled: September 25, 2003Date of Patent: August 22, 2006Assignee: Fuji Xerox Co., Ltd.Inventors: Wataru Yamada, Katsumi Nukada, Kazuhiro Koseki, Masahiro Iwasaki, Takayuki Yamashita
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Patent number: 7071285Abstract: An electrophotographic photoconductor has an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a structural unit of formula (2) and a structural unit with charge transporting properties, each of the structural units being contained in an amount of 5 wt. % or more of the total weight of the polycarbonate resin. There is disclosed an aromatic polycarbonate resin having a structural unit of formula (1) and the structural unit of formula (2), with the relationship between the composition ratios being 0<k/(k+j)<1 when the composition ratio of the structural unit (1) is k and that of the structural unit (2) is j, or an aromatic polycarbonate resin having a repeat unit of formula (3). The formulas (1) to (3) are specified in the specification.Type: GrantFiled: July 1, 2004Date of Patent: July 4, 2006Assignee: Ricoh Company, Ltd.Inventors: Shinichi Kawamura, Masaomi Sasaki, Kazukiyo Nagai, Kohkoku Ri, Susumu Suzuka, Katsuhiro Morooka
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Patent number: 7045261Abstract: In an electrophotographic photosensitive member having a support, and provided thereon a photosensitive layer, a surface layer of the electrophotographic photosensitive member contains a high-molecular-weight charge-transporting material having a weight-average molecular weight Mw of from 1,000 or more to 9,000 or less, and the ratio of the weight-average molecular weight Mw of the high-molecular-weight charge-transporting material to a number-average molecular weight Mn of the high-molecular-weight charge-transporting material, Mw/Mn, is from more than 1.00 to 1.10 or less. Also disclosed are a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.Type: GrantFiled: August 26, 2003Date of Patent: May 16, 2006Assignee: Canon Kabushiki KaishaInventors: Takakazu Tanaka, Itaru Takaya, Harunobu Ogaki, Kenichi Kaku
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Patent number: 7029810Abstract: An electrophotographic image forming apparatus comprising: an electrophotographic photoreceptor comprising: an electroconductive substrate; a charge generation layer; and a charge transport layer in this order, a charger; an irradiator; an image developer; and a transferer applying an electric current not less than 65 ?A to the electrophotographic photoreceptor, wherein the charge generation layer comprises titanylphthalocyanine crystals having a CuK? 1.542 ? X-ray diffraction spectrum having plural diffraction peaks, wherein a maximum diffraction peak is observed at a Bragg (2 ?) angle of 27.2°; main peaks are observed at 9.4°, 9.6° and 24.0°; and a minimum diffraction peak is observed at 7.3°; and no diffraction peak is observed at an angle greater than 7.3° and less than 9.4°, wherein said angles may vary by ±0.2° and the minimum interval where no peak is observed between required peaks at 7.3 and 9.4 is 2.0 degrees absolute or more.Type: GrantFiled: September 22, 2003Date of Patent: April 18, 2006Assignee: Ricoh Company, Ltd.Inventors: Naohiro Toda, Tatsuya Niimi
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Patent number: 7001699Abstract: In an electrophotographic photosensitive member having a support, and provided thereon a photosensitive layer, a surface layer of the electrophotographic photosensitive member contains an electrically insulating binder resin and a random-copolymer type high-molecular-weight charge-transporting material having two kinds of specific repeating structural units. Also disclosed are a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.Type: GrantFiled: August 26, 2003Date of Patent: February 21, 2006Assignee: Canon Kabushiki KaishaInventors: Takakazu Tanaka, Akira Yoshida, Hidetoshi Hirano, Yuka Ishiduka, Harunobu Ogaki
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Patent number: 6991881Abstract: The present invention relates to an electrophotographic photosensitive member having a support and provided thereon a photosensitive layer. The photosensitive layer contains a high-molecular weight charge-transporting material having a specific repeating structural unit. The high-molecular weight charge-transporting material has a weight-average molecular weight Mw of 1,500 or more and an energy level of highest occupied molecular orbital, EHOMO, of from ?8.3 eV or more to ?8.0 eV or less as found by semiempirical molecular-orbital calculation. The present invention also relates to a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.Type: GrantFiled: April 25, 2003Date of Patent: January 31, 2006Assignee: Canon Kabushiki KaishaInventors: Harunobu Ogaki, Akira Yoshida, Takakazu Tanaka, Itaru Takaya, Yuka Ishiduka
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Patent number: 6939651Abstract: An electrophotographic photoconductor comprising at least an electroconductive support and a photoconductive layer which is formed on said electroconductive support, the outermost layer of the photoconductor contains particles comprising a polyorganosiloxane-containing phase which contains polyorganosiloxane and an organic polymer-containing phase which contains organic polymer without silicon and has a polyorganosiloxane content which is less than the polyorganosiloxane-containing phase, each phase being exposed at the top surface of the photoconductor.Type: GrantFiled: June 21, 2002Date of Patent: September 6, 2005Assignee: Ricoh Company, Ltd.Inventors: Hongguo Li, Kazukiyo Nagai, Masaomi Sasaki, Shinichi Kawamura, Yasuo Suzuki, Nozomu Tamoto, Kawori Tanaka
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Patent number: 6936679Abstract: A charge-transporting polymer is represented by the following general formula (I-1) or (I-2): wherein A represents a group represented by the following general formula (II-1):Type: GrantFiled: September 10, 2002Date of Patent: August 30, 2005Assignee: Fuji Xerox Co., Ltd.Inventors: Mieko Seki, Hirohito Yoneyama, Daisuke Okuda, Hidekazu Hirose, Tadayoshi Ozaki, Takeshi Agata, Toru Ishii, Kiyokazu Mashimo, Katsuhiro Sato
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Patent number: 6913862Abstract: A phenolic compound having a plurality of substituted hydroxyphenyl groups and charge-transportable structure, the substituted hydroxyphenyl groups of which have a hydroxymethyl group; and a resol resin obtained by allowing a phenolic compound having hydroxyphenyl groups and charge-transportable structure, to react with formaldehyde in the presence of a basic catalyst, and having charge-transportable structure. Also disclosed are a cured product and an electrophotographic photosensitive member which make use of the above, and a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member.Type: GrantFiled: December 18, 2002Date of Patent: July 5, 2005Assignee: Canon Kabushiki KaishaInventors: Kouichi Nakata, Yosuke Morikawa, Tatsuya Ikezue, Kimihiro Yoshimura, Daisuke Tanaka
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Patent number: 6861188Abstract: Electrophotographic photoreceptor having a photosensitive layer containing an amino compound selected from formulae 1 to 22 in the specification.Type: GrantFiled: September 6, 2002Date of Patent: March 1, 2005Assignee: Ricoh Company LimitedInventors: Takaaki Ikegami, Yasuo Suzuki, Tomoyuki Shimada, Nozomu Tamoto, Hidetoshi Kami