Abstract: An electrophotographic photoreceptor including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate and including a resin; and a surface layer including a filler and a binder resin, wherein the surface layer and the photosensitive layer have a continuous structure, and wherein the surface layer satisfies the following relationship: ??D/5, wherein D represents an average of maximum thicknesses of the surface layer in units of micrometers in 20 segments of 5 ?m wide when a portion of a cross section of the photoreceptor of 100 ?m wide is divided into the 20 segments, and ? represents a standard deviation of the 20 maximum thicknesses.
Abstract: Disclosed is an electrophotographic photoconductor including at least a photoconductive layer on a conductive substrate, wherein the surface layer of the photoconductive layer contains at least a surface crosslinked layer formed by curing a tri- or more-functional radical polymerizable monomer without having a charge transporting structure and a mono-functional radical polymerizable compound having a charge transporting structure and the surface crosslinked layer has a surface roughness Rz of 1.3 &mgr;m or less.
Abstract: Disclosed is an electrophotographic photoconductor including at least a photoconductive layer on an electroconductive substrate, which comprises at least a cross-linked surface layer formed by curing a tri- or more-functional radical polymerizable monomer without having a charge transporting structure and a mono-functional radical polymerizable compound having a charge transporting structure wherein the cross-linked surface layer has a surface roughness Rz of 1.3 &mgr;m or less.
Abstract: An electrophotographic photoconductor includes an electroconductive substrate, a charge generation layer, and a charge transport layer formed by using a halogen-free solvent, arranged in this order, in which the charge generation layer contains a charge generation material having an average particle diameter smaller than a surface roughness of a plane where the electroconductive substrate is arranged, and a polyvinyl acetal resin having a ratio Mw/Mn of a weight-average molecular weight Mw to a number-average molecular weight Mn is 2.2 or more.
Abstract: A photoreceptor including an electroconductive substrate, a photosensitive layer located overlying the substrate, and a protective layer overlying the photosensitive layer, wherein the photoreceptor has a property such that when the photoreceptor is charged so as to have a potential of −700 V and then exposed to light with exposure of 0.4 &mgr;J/cm2, the potential (PL) of a lighted portion of the photoreceptor decreases at a rate not greater than 700 V/sec during a time period of from a time 35 msec after the exposure to the transition time of the photoreceptor. An image forming apparatus and a process cartridge including the photoreceptor are also provided.
Abstract: An electrophotographic photoconductor has an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a structural unit of formula (2) and a structural unit with charge transporting properties, each of the structural units being contained in an amount of 5 wt. % or more of the total weight of the polycarbonate resin. There is disclosed an aromatic polycarbonate resin having a structural unit of formula (1) and the structural unit of formula (2), with the relationship between the composition ratios being 0<k/(k+j)<1 when the composition ratio of the structural unit (1) is k and that of the structural unit (2) is j, or an aromatic polycarbonate resin having a repeat unit of formula (3). The formulas (1) to (3) are specified in the specification.
Abstract: An electrophotographic photoreceptor including an electroconductive substrate, a photosensitive layer located overlying the electroconductive substrate, and optionally a protective layer overlying the photosensitive layer, wherein an outermost layer of the photoreceptor includes a filler, a binder resin and an organic compound having an acid value of from 10 to 700 mgKOH/g. The photosensitive layer can be the outermost layer. A coating liquid for an outermost layer of a photoreceptor including a filler, a binder resin, an organic compound having an acid value of from 10 to 700 mgKOH/g and plural organic solvents. A method for preparing a photoreceptor including forming a photosensitive layer, and coating the coating liquid on the photosensitive layer. An image forming method and apparatus and a process cartridge using the photoreceptor are also provided.
Abstract: Disclosed are polymers which include tertiary aryl amine moieties that can function as hole transport agents and which also have reactive silane groups thereon capable of being condensed to a silsesquioxane composition, as well as the silsesquioxane compositions prepared therefrom. The silsesquioxanes can be coated onto substrates to form abrasion-resistant layers having hole transport properties useful in devices that require charge transport properties, such as light-emitting diodes and organic electrophotographic elements such as photoreceptors or photoconductors. Also disclosed are electrophotographic elements which comprise an electrically conducting layer, a charge generating layer overlying the electrically conducting layer, and a charge transport layer overlying the electrically conducting layer. The charge transport layer, which can be an overcoat overlying the charge generating layer, comprises the condensed reaction product of the disclosed polymers.
Type:
Application
Filed:
July 8, 2003
Publication date:
July 1, 2004
Inventors:
Xin Jin, Wayne T. Ferrar, David S. Weiss, Louis J. Sorriero
Abstract: Disclosed is a positive charging single-layer organic photoreceptor for liquid development which comprises a conductive substrate having thereon a photosensitive layer containing a charge generating material, an electron transport material and an organic binder resin comprising a polymer represented by formula (I):
wherein R1 and R2 each represent a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, or R1 and R2 may form a cycloalkyl group in combination; R3, R4, R5, R6, R7, R8, R9, R10 and R11, each represent a hydrogen atom, a halogen atom, an aryl group or an alkyl group; and m and n each represent a molar percentage giving a total of 70 to 95 mol %.
Abstract: A photoreceptor including an electroconductive substrate; a charge generation layer located overlying the electroconductive substrate optionally with an intermediate layer therebetween; and a charge transport layer formed overlying the charge generation layer using a non-halogenated solvent and including a charge transport material and a resin, wherein the charge generation layer includes a polyvinyl acetal resin and a charge generation material having an average particle diameter less than a roughness of a surface of either the electroconductive substrate or the intermediate layer, on which the charge generation layer is located.
Abstract: An electrophotographic photoconductor having a layer of a crosslinked resin obtained by reacting an epoxy group-containing amine compound having a charge transferability-imparting group with at least one silicon compound selected from an epoxy ring-free alkoxysilane compound, an epoxy ring-free silanol compound, an epoxy ring-containing alkoxysilane compound and an epoxy ring-containing silanol compound.
Abstract: In an electrophotographic photosensitive member having a support, and provided thereon a photosensitive layer, a surface layer of the electrophotographic photosensitive member contains an electrically insulating binder resin and a random-copolymer type high-molecular-weight charge-transporting material having two kinds of specific repeating structural units. Also disclosed are a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.
Abstract: In an electrophotographic photosensitive member having a support, and provided thereon a photosensitive layer, a surface layer of the electrophotographic photosensitive member contains a high-molecular-weight charge-transporting material having a weight-average molecular weight Mw of from 1,000 or more to 9,000 or less, and the ratio of the weight-average molecular weight Mw of the high-molecular-weight charge-transporting material to a number-average molecular weight Mn of the high-molecular-weight charge-transporting material, Mw/Mn, is from more than 1.00 to 1.10 or less. Also disclosed are a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.
Abstract: An electrophotographic photoreceptor including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate and including a resin; and a surface layer including a filler and a binder resin, wherein the surface layer and the photosensitive layer have a continuous structure, and wherein the surface layer satisfies the following relationship: &sgr;≦D/5, wherein D represents an average of maximum thicknesses of the surface layer in units of micrometers in 20 segments of 5 &mgr;m wide when a portion of a cross section of the photoreceptor of 100 &mgr;m wide is divided into the 20 segments, and &sgr; represents a standard deviation of the 20 maximum thicknesses.
Abstract: An aromatic block polycarbonate resin is prepared by polymerizing a diphenol compound of formula (2) or (4), a diol compound of formula (1) or (5), and a halogenated carbonyl compound. The diphenol compound of formula (4) is produced by polymerizing the diphenol compound of formula (2) and a halogenated carbonyl compound by solution or interfacial polymerization. An electrophotographic photoconductor has an electroconductive support and a photoconductive layer formed thereon containing the above-mentioned aromatic block polycarbonate resin. An electrophotographic image forming method or apparatus employs the above-mentioned photoconductor. A process cartridge holds therein the photoconductor and at least one of the electrophotographic image forming units.
Type:
Application
Filed:
January 22, 2003
Publication date:
January 1, 2004
Applicants:
RICOH COMPANY, LTD., Hodogaya Chemical Co., Ltd.
Abstract: The present invention relates to an electrophotographic photosensitive member having a support and provided thereon a photosensitive layer. The photosensitive layer contains a high-molecular weight charge-transporting material having a specific repeating structural unit. The high-molecular weight charge-transporting material has a weight-average molecular weight Mw of 1,500 or more and an energy level of highest occupied molecular orbital, EHOMO, of from −8.3 eV or more to −8.0 eV or less as found by semiempirical molecular-orbital calculation. The present invention also relates to a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member.
Abstract: An electrophotographic photoconductor having an electroconductive support, and a photoconductive layer formed thereon and containing an aromatic polycarbonate resin having a structural unit of formula (3) shown in the specification. The polycarbonate resin is produced from a diphenol compound of the formula (1) shown in the specification.
Abstract: The invention relates to a process for isolating, from a polymer comprising repeating units which are individually of Formula X
in which
Y is P or N,
Ar1 & Ar2 are bivalent aromatic groups,
Ar3 is a monovalent aromatic group, and
the units of Formula X may be the same or different,
a molecular weight fraction which is especially suitable for use as a charge transport material.
Type:
Grant
Filed:
November 28, 2001
Date of Patent:
November 25, 2003
Assignee:
Avecia Limited
Inventors:
Beverley Anne Brown, Janos Veres, Joanne Victoria Allen, John Dylan Morgan, Stephen William Leeming
Abstract: Electrophotographic photoreceptor having a photosensitive layer containing an amino compound selected from formulae 1 to 22 in the specification.
Abstract: An image forming apparatus including a photoreceptor, wherein the photoreceptor includes an image forming portion having two ends substantially parallel to the rotating direction and a gap forming member located outside of each of the two ends of the image forming portion; a charging roller configured to charge the photoreceptor, wherein the charging roller contacts the gap forming members of the photoreceptor to form a gap g between the surface of the image forming portion and the peripheral surface thereof; an imagewise light irradiator; an image developer; and an image transfer device, wherein the relationship t≧2g is satisfied, where g represents the gap and t represents a distance between an inside edge of one of the gap forming members and nearer one of the two ends of the image forming portion of the photoreceptor.
Abstract: A phenolic compound having a plurality of substituted hydroxyphenyl groups and charge-transportable structure, the substituted hydroxyphenyl groups of which have a hydroxymethyl group; and a resol resin obtained by allowing a phenolic compound having hydroxyphenyl groups and charge-transportable structure, to react with formaldehyde in the presence of a basic catalyst, and having charge-transportable structure. Also disclosed are a cured product and an electrophotographic photosensitive member which make use of the above, and a process cartridge and an electrophotographic apparatus which have the electrophotographic photosensitive member.
Abstract: A charge transport composition containing aromatic amines with crosslinkable silanes as represented by the formula
wherein A represents a hole transporting aromatic tertiary amine moiety; L1 and L2 represents charge such as a divalent group; X represents oxygen or an imino group; Y represents an alkoxy group, or a halide atom; R is a hydrogen atom or an alkyl group; and n represents the number of repeating segments.
Abstract: An electrophotographic photoreceptor for an electrophotographic image forming apparatus which has a laser diode or a light emitting diode emitting a light having a wavelength of 350 to 500 nm as an image writing light source, wherein the photoreceptor includes a photosensitive layer including a deactivating agent.
Abstract: An aromatic block polycarbonate resin is prepared by polymerizing a diphenol compound of formula (2) or (4), a dial compound of formula (1) or (5), and a halogenated carbonyl compound. The diphenol compound of formula (4) is produced by polymerizing the diphenol compound of formula (2) and a halogenated carbonyl compound by solution or interfacial polymerization. An electrophotographic photoconductor has an electroconductive support and a photoconductive layer formed thereon containing the above-mentioned aromatic block polycarbonate resin. An electrophotographic image forming method or apparatus employs the above-mentioned photoconductor. A process cartridge holds therein the photoconductor and at least one of the electrophotographic image forming units.
Abstract: A photoreceptor including an electroconductive substrate and a photosensitive layer which is formed on the electroconductive substrate and which includes a charge generation material, wherein the charge generation material comprises an organic pigment and wherein the photosensitive layer further includes at least one ion selected from the group consisting of K+, Na+, NO3−, HCOO−, NO2−, Cl−, Br−, and NH4+ or one or more water-soluble inorganic salts.
Abstract: An electrophotographic photoconductor comprising at least an electroconductive support and a photoconductive layer which is formed on said electroconductive support, the outermost layer of the photoconductor contains particles comprising a polyorganosiloxane-containing phase which contains polyorganosiloxane and an organic polymer-containing phase which contains organic polymer without silicon and has a polyorganosiloxane content which is less than the polyorganosiloxane-containing phase, each phase being exposed at the top surface of the photoconductor.
Abstract: An image forming method is disclosed. The method comprises processes in which a latent image on an electrophotographic photoreceptor is developed employing a developer material, and after transferring the visualized toner image to a recording material, the remaining toner on said photoreceptor is removed employing an elastic body cleaning blade. The electrophotographic photoreceptor comprises a surface layer containing a charge transportable polysiloxane hardenable resin, and said developer material comprises a fatty acid metal salt.
Abstract: An electrophotographic photoreceptor including an electroconductive substrate and a photoreceptive layer, which is formed overlying the substrate, wherein the photoreceptive layer includes a charge carrier generation layer including a charge carrier generation material and a charge carrier transport layer including a charge carrier transport material, and wherein when an electric field of from 2.5×105 V/cm to 5.5×105 V/cm is applied to the charge carrier transport layer, the relationship, tCTL/&mgr;CTL≦1.5×103 V·s/m, is satisfied, wherein tCTL represents a thickness of the charge carrier transport layer and &mgr;CTL represents a charge mobility of the charge carrier transport layer.
Abstract: An electrophotographic photoreceptor including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate and including a resin; and a surface layer including a filler and a binder resin, wherein the surface layer and the photosensitive layer have a continuous structure, and wherein the surface layer satisfies the following relationship: &sgr;≦D/5, wherein D represents an average of maximum thicknesses of the surface layer in units of micrometers in 20 segments of 5 &mgr;m wide when a portion of a cross section of the photoreceptor of 100 &mgr;m wide is divided into the 20 segments, and &sgr; represents a standard deviation of the 20 maximum thicknesses.
Abstract: An electrophotographic photosensitive member is provided by forming a photosensitive layer on an electroconductive support. The photosensitive layer is provided with particularly excellent durability while retaining good electrophotographic performances when formed as a layer comprising a polymerizate of a hole-transporting compound having at least two chain polymerization function groups in its molecule represented by formula (1) below:
&Parenopenst;P1&Parenclosest;aA&Parenopenst;Z—(P2)d)b (1),
wherein A denotes a hole-transporting group, P1 and P2 independently denote a chain polymerization function group and Z denotes a bonding organic group; a, b and d are independently an integer of at least 0 satisfying a+b×d≧2 provided that if a≧2. plural groups P1 can be identical or different; if b≧2, plural groups Z can be identical or different; and if b×d≧2, plural groups P2 can be identical or different.
Abstract: An electrophotographic photosensitive member comprising a support and a photosensitive layer provided thereon. The photosensitive layer fulfilling at least one of the following conditions (A) and (B):
(A) containing a polymerization product of a monomer having a reactive group represented by the following Formula (1):
—O—(—CH2—)n—CH═CH—R0 (1);
and
(B) containing a copolymerization product of a monomer having a reactive group represented by the following Formula (2):
—O—CH═CH2 (2)
with a charge-transporting material having a reactive group capable of reacting with the monomer.
Abstract: An image forming method is disclosed. The method comprises processes in which a latent image on an electrophotographic photoreceptor is developed employing a developer material, and after transferring the visualized toner image to a recording material, the remaining toner on said photoreceptor is removed employing an elastic body cleaning blade. The electrophotographic photoreceptor comprises a surface layer containing a large transportable polysiloxane hardenable resin, and said developer material comprises a fatty acid metal salt.
Abstract: An electrophotographic photoreceptor having a bipolar charge transport layer with a hole-transporting property and an electron-transporting property, the bipolar charge transport layer containing a block copolymer or a graft copolymer, and a process cartridge and an electrophotographic apparatus using the electrophotographic photoreceptor. The electrophotographic photoreceptor has a high performance and a long life and can provide various properties required for a photoreceptor by forming, the bipolar charge transport layer which is excellent in hole- and electron-transporting properties, mechanical strengths, a discharge product resistance and a coating dispersion stability, and the process cartridge and the electrophotographic apparatus using the electrophotographic photoreceptor can provide a high performance and a high durability.
Abstract: A process for producing an electrophotographic photoreceptor, which includes contacting a solution containing at least one of optically functional organosilicon compounds represented by formula (I)
F—[D—A]b (I)
with a solid catalyst for reaction, then separating the solid catalyst to form an optically functional coating solution, and coating and curing the optically functional coating solution to form a cured film, an electrophotographic photoreceptor having at least one layer made of the cured film produced by this process, and an image-forming apparatus having the same.
Abstract: An electroluminescent device comprising: a first charge-carrier injecting layer for injecting positive charge carriers and a second charge-carrier injecting layer for injecting negative charge carriers, at least one of the charge-carrier injecting layers being patterned so as to comprise spaced-apart charge-injecting regions; an organic light-emitting layer located between the first and second charge-carrier injecting layers; and an unpatterned conductive polymer layer located between the organic light-emitting layer and the patterned charge-carrier injecting layer, the resistivity of the conductive polymer layer being sufficiently low to allow charge carriers to flow through it from the charge-injecting regions to generate light in the organic light-emitting layer but sufficiently high to resist lateral spreading of charge carriers beyond the charge-injecting regions.
Type:
Application
Filed:
October 15, 2001
Publication date:
January 31, 2002
Applicant:
Cambridge Display Technology Ltd.
Inventors:
Carl Robert Towns, Stephen Karl Heeks, Julian Charles Carter
Abstract: An electrophotographic photoreceptor which includes an electroconductive substrate, and a photosensitive layer which is formed overlying the substrate, wherein the photosensitive layer includes a charge generation material, a charge transport polymer material including triarylamine structure and a soft segment in a main chain thereof, and a filler.
Abstract: An electrophotographic photoreceptor is disclosed. The photoreceptor has a difference in ionization potential between the photosensitive layer and the hardenable resinous layer of not more than 0.4 eV, and a response time T10 defined in the specification is not more than 0.25 second. An image forming method and apparatus employing the photoreceptor are also disclosed.
Abstract: A photoconductor comprises a substrate and at least one layer. The at least one layer is selected from the group consisting of charge transfer layers comprising a charge transfer molecule, polycarbonate and a first polyaryl ether selected from the group consisting of polyaryletherketones, poly(aryl-perfluoroaryl ether)s, polyaryletherketone-hydrazones, polyaryletherketone-azines and mixtures and copolymers thereof; charge generating layers comprising a pigment, a polyvinylbutyral and a second polyaryl ether selected from the group consisting of polyaryletherketones, polyarylethersulfones and mixtures and copolymers thereof; and mixtures thereof.
Abstract: A photoreceptor including an electroconductive substrate and a photosensitive layer which is formed on the electroconductive substrate and which includes a charge generation material, wherein the charge generation material comprises an organic pigment and wherein the photosensitive layer further includes at least one ion selected from the group consisting of K+, Na+, NO3−, HCOO−, NO2−, Cl−, Br−, and NH4+ or one or more water-soluble inorganic salts.
Abstract: An image bearing material including a matrix resin and, within the matrix resin, a core/shell graft copolymer including a core including one or more polymers and a shell including a graft polymer which has a linear chain connected with the core and which is formed from one or more monomers. The image bearing material is preferably used for a surface layer of an electrophotographic photoreceptor, an intermediate transfer medium, and the like image bearing members to improve the abrasion resistance thereof.
Abstract: A cylindrical electrophotoreceptor is disclosed. The layer thickness decreasing amount &Dgr;Hd (in &mgr;m) is 0≦&Dgr;Hd<5×10−6 per rotation and residual potential variation amount per cm2 is 0≦&Dgr;Vr<100 (in V) for 1 A of an electric current generated by charging and exposure.
Abstract: A method of manufacturing an organic pigment including the steps of providing an organic pigment wet cake which includes at least an organic pigment and a solvent and drying the organic pigment wet cake while the wet cake is heated at a temperature higher than room temperature to prepare a powder of the organic pigment, wherein the organic pigment is present in the organic pigment wet cake in an amount of not greater than about 70% by weight.
Abstract: An electrophotographic photoconductor has an electroconductive support and a photoconductive layer formed thereon, a surface top portion of the photoconductor containing a high-molecular charge transport material including a polycarbonate copolymer synthesized from (a) a bisphenol monomer with an ionization potential of 6.0 eV or less, having a positive hole transporting function, and (b) a bisphenol monomer having a substituent at the o-position with respect to at least one hydroxyl group thereof, the substituent being bulkier than a fluorine atom. A process cartridge holds the above-mentioned photoconductor therein, and an electrophotographic image forming apparatus is provided with the above-mentioned photoconductor or process cartridge.
Abstract: An image-forming apparatus of an electrophotographic system equipped with an electrophotographic photoreceptor, an electrostatically charger, a light-exposure, a developing device, and a transferring device, wherein the electrophotographic photoreceptor is an electrophotographic photoreceptor having at least a charge generating layer, a charge transport layer, and an uppermost surface layer successively laminated on an electrically conductive substrate, the charge transport layer having a layer containing at least 45% by weight a charge transporting material, and the wear rate of the uppermost surface layer being less than the wear rate of said layer, and the time from a light-exposure to a development is not longer than 150 m sec. The image-forming apparatus is excellent in the printing durability and the stability, gives less image flowing, and is small-sized and high-speed.
Abstract: A photoconductive imaging member containing a photogenerating layer comprised of a mixture of perylenes, wherein the mixture comprises, for example, (1) 1,3-bis(n-pentylimidoperyleneimido) propane (Formula A), 1,3-bis(2-methylbutylimido peryleneimido)propane (Formula B) and 1-(n-pentylimidoperyleneimido)-3-(2-methylbutylimidoperyleneimido)-propane (Formula C), and (2) an electron acceptor component
Formula A
1,3-bis(n-pentylimidoperyleneimido)propane
Formula B
1,3-bis(2-methylbutylimidoperyleneimido)propane
Formula C
1-(n-pentylimidoperyleneimido)-3-(2-methylbutylimidoperyleneimido)propane
Type:
Grant
Filed:
July 13, 2000
Date of Patent:
February 27, 2001
Assignee:
Xerox Corporation
Inventors:
Cheng-Kuo Hsiao, Ah-Mee Hor, Giuseppa Baranyi, H. Bruce Goodbrand
Abstract: A crack resistant, curl-free electrophotographic imaging member includes a charge transport layer comprising an active charge transporting polymeric tetraaryl-substituted biphenyidiamine and a plasticizer.
Type:
Grant
Filed:
December 6, 1996
Date of Patent:
February 6, 2001
Assignee:
Xerox Corporation
Inventors:
Robert C. U. Yu, William W. Limburg, Merlin E. Scharfe, David H. Pan, Dale S. Renfer, Richard L. Schank, Surendar Jeyadev