Hetero Rings Bridged Or Fused To Carbocyclic Rings Patents (Class 430/588)
  • Patent number: 5674674
    Abstract: The invention relates to a photographic element comprising a silver halide emulsion wherein at least one layer contains a silver chloroiodide emulsion containing at least 95 mole percent chloride and contains a sensitizing dye of the following general formula (I): ##STR1## wherein: Z1 represents a halogen, a cyano group, an amide substituted aromatic group, or a heteroaromatic group that is directly appended to the benzene ring shown or an aromatic group that is attached through an amide linking group andZ2 represents a substituted or unsubstituted alkyl group, substituted or unsubstituted alkoxy group, cyano group, a substituted or unsubstituted amide group, a substituted or unsubstituted carbamoyl group, halogen, an amide substituted aromatic group, or a heteroaromatic group that is directly appended to the benzene ring shown or an aromatic group that is attached through an amide linking group andW1 is one or more ions as needed to balance the charge on the molecule andR1 and R2 are, independently, substitu
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: October 7, 1997
    Assignee: Eastman Kodak Company
    Inventors: James Lawrence Edwards, Benjamin Teh-Kung Chen, Richard Lee Parton
  • Patent number: 5665532
    Abstract: A black & white paper with variable gradation containing a silver chloride-bromide emulsion, which is divided into at least three portions, one of which is sensitised with a blue sensitiser and two further portions are sensitised both with differing quantities of blue sensitiser and with differing quantities of a green sensitiser, wherein the blue sensitiser is of the formula (I) and the green sensitiser is of the formula (II) ##STR1## in which R.sub.1 to R.sub.8, X.sup.(-) and m have the meaning stated in the specification, is distinguished by an extended gradation range.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: September 9, 1997
    Assignee: Agfa-Gevaert AG
    Inventors: Manfred Peters, Thomas Kaluschke, Hans Ohlschlager, Bruno Mucke
  • Patent number: 5654124
    Abstract: A silver halide photographic material containing at least one silver halide emulsion layer on a support is provided. The silver halide emulsion layer comprises chemically sensitized silver halide grains having a silver chloride content of 50 mol % or more, said silver halide emulsion has been spectrally sensitized with at least one dye selected from the dyes represented by one of the general formulas (1), (2) and (3) shown in the specification. The emulsion layer or at least one other hydrophilic colloidal layer contains at least one member selected from the hydrazine derivatives represented by one of the formulas (4), (5) and (6) shown in the specification and at least one compound selected from the compounds represented by one of the formulas (7), (8), (9), (10), (11) and (12) shown in the specification.A process for the formation of an image is also provided, which comprises the development of a silver halide photographic material as defined above with a developer having a pH value of 9.6 to less than 11.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 5, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Yamaguchi
  • Patent number: 5637448
    Abstract: A silver halide light-sensitive photographic material is disclosed. The material comprises a layer containing light-sensitive silver halide comprising a sensitizing dye represented by the general formula I: ##STR1## wherein W.sub.1 is a fluorine-substituted alkyl group. The spectral sensitivity in the short wavelength region of green light is enhanced and color staining due residual dye is reduced.
    Type: Grant
    Filed: September 9, 1996
    Date of Patent: June 10, 1997
    Assignee: Konica Corporation
    Inventors: Masaki Nakamura, Nobuaki Kagawa
  • Patent number: 5604088
    Abstract: A silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the silver halide emulsion layer contains a silver halide emulsion sensitized by a methine dye represented by following formula (I) and the total content of calcium in the photographic constituting layers on the support is not more than 10 mg/m.sup.2 ; ##STR1## wherein Q represents a non-metallic atomic group necessary for forming a 5-membered or 6-membered ring; R.sub.1 to R.sub.11 each represents a hydrogen atom or a substituent, however, at least one of R.sub.1 to R.sub.3 represents a group containing an aromatic group and R.sub.4 and R.sub.5 are not a hydrogen atom; L.sub.1 to L.sub.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: February 18, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masahiro Asami, Ken Kawata
  • Patent number: 5604089
    Abstract: There is disclosed a silver halide photographic material in which a residual color can be compatible with a sensitivity in a development processing. The photographic material comprises a support and provided thereon at least one silver halide emulsion layer containing at least one of the methine compounds represented by the following Formula (I) and at least one of the compounds represent-ed by the following Formula (II): ##STR1## wherein R.sup.1 represents --(CH.sub.2).sub.r --CONHSO.sub.2 --R.sup.3, --(CH.sub.2).sub.s --SO.sub.2 NHCO--R.sup.4, --(CH.sub.2).sub.t --CONHCO--R.sup.5, or --(CR.sub.2).sub.u --SO.sub.2 NHSO.sub.2 --R.sup.6, in which R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent an alkyl group, an alkoxy group, or an amino group and r, s, t and u each repre-sent an integer of 1 to 5; R.sup.2 is synonymous with R.sup.1 or represents an alkyl group which is different from R.sup.1 ; Z.sup.1 and Z.sup.
    Type: Grant
    Filed: November 14, 1995
    Date of Patent: February 18, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akihiko Ikegawa, Yuji Mihara
  • Patent number: 5591570
    Abstract: A light-sensitive silver halide photographic emulsion is disclosed, wherein at least 70% of the total projected area of silver halide grains are tabular grains having an average aspect ratio of a diameter to a thickness of 2 or more, an average value of the longest distances between two or more parallel twin planes contained in the respective tabular grains is 0.008 .mu.m or more, and a variation coefficient of the longest distances between parallel twin planes is 35% or less, and wherein the silver halide emulsion is spectrally sensitized with a substantially slightly water-soluble sensitizing dye by adding the dye to the emulsion in the form of a dispersion of solid particles dispersed in an aqueous solution substantially free from an organic solvent or surfactant.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: January 7, 1997
    Assignee: Konica Corporation
    Inventors: Hideki Takiguchi, Hiroshi Kashiwagi, Nobuaki Tsuji, H o Socman, Katsuhiko Heki
  • Patent number: 5578439
    Abstract: A silver halide photographic material is described, which contains the methine compound represented by the following formula (I): ##STR1## wherein Z.sup.1 represents a nonmetal atomic group necessary for completing a 5- or 6-membered heterocyclic ring which may be condensed; R.sup.1 represents an aliphatic or aromatic group which may be substituted; G.sup.1 represents a hydroxyl group, an amino group, an aliphatic or aromatic primary amino group, a hydroxyamino group, an alkoxyamino group, an acylamino group, or an aliphatic or aromatic sulfonamido group; G.sup.2 is a group substituted at the position adjacent to G and is a group represented by T.sup.2 --C(.dbd.T.sup.1)--; .dbd.T.sup.1 represents .dbd.O, .dbd.NH, .dbd.NOH, an alkoxyimino group, an aliphatic or aromatic imino group, an acylimino group, or an aliphatic or aromatic sulfonylimino group; T.sup.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: November 26, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Inagaki
  • Patent number: 5538836
    Abstract: A silver halide color photographic material having an excellent color reproducibility, high sensitivity and excellent graininess.The silver halide color photographic material contains at least one of each blue-sensitive emulsion, green-sensitive emulsion, red-sensitive emulsion layer and hydrophilic colloid layers, in which the hydrophilic colloid layer contains a compound of formula (I) and the silver halide emulsion layer, which gives an interlayer effect to said red-sensitive layer, contains a silver halide emulsion spectrally sensitized with a compound represented by formulae (II) and (III).
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: July 23, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumitaka Ueda, Junji Nishigaki, Tetsuo Nakamura
  • Patent number: 5534403
    Abstract: A silver halide photographic material comprising at least one compound represented by the following formula (I) or formula (II): ##STR1## wherein R.sub.11, R.sub.12, R.sub.21 and R.sub.22 each represents a substituted or unsubstituted alkyl group; R.sub.13 and R.sub.23 each represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group; V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7, V.sub.8, V.sub.9, V.sub.10, V.sub.11, V.sub.4A, V.sub.5A, V.sub.6A, W.sub.01 and W.sub.02 each represents a hydrogen atom or a substituent, wherein at least one of V.sub.7 and V.sub.11 is a substituent; W.sub.21 represents a substituent having two or more carbon atoms; X.sub.1 and X.sub.2 each represents a charge-neutralizing counter ion; and m and n each represents a number of 0 or more necessary for neutralizing the molecular charge.
    Type: Grant
    Filed: April 15, 1994
    Date of Patent: July 9, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Nishigaki, Takashi Kato
  • Patent number: 5529896
    Abstract: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the layer contains at least one compound represented by the following formula (I) and at least one compound represented by the following formula (X): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different and each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sub.4 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; and R.sub.1 and R.sub.2, and R.sub.3 and R.sub.4 each may be combined with each other to form a ring; ##STR2## wherein Z.sub.11 represents a sulfur atom, a selenium atom or a substituted nitrogen atom represented by ##STR3## in which R.sub.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: June 25, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Tadashi Ikeda
  • Patent number: 5512428
    Abstract: Phenanthroazole cyanines and anthraazole cyanines, having not less than one acidic group, of the formula I are excellent spectral sensitizers. ##STR1## The symbols in formula I have the following meanings X.sub.1 and X.sub.2 O, S, Se or NR.sub.10 ;R.sub.1 and R.sub.2 or R.sub.2 and R.sub.3 residues of an optionally substituted phenanthroazole or anthraazole with the remaining group R.sub.3 or R.sub.1 signifying hydrogen;R.sub.4 and R.sub.6 hydrogen or together a .pi.-bond,R.sub.5 and R.sub.7 hydrogen, alkyl or aryl orR.sub.4,R.sub.5,R.sub.6 and R.sub.7 residues of an optionally substituted benzazole, naphthazole, phenanthroazole or anthraazole;R.sub.8, R.sub.9 alkyl, sulphoalkyl, carboxyalkyl, --(CH.sub.2).sub.m --CO--NR.sub.11 --SO.sub.2 --R.sub.12 or --(CH.sub.2).sub.m --SO.sub.2 --NR.sub.11 --CO--R.sub.12 ;R.sub.10 a residue as defined for R.sub.8 /R.sub.9 or aryl;R.sub.11 hydrogen or the negative charge (.sup..crclbar.) which remains when a proton is removed;R.sub.12 alkyl, aryl, --O.sup..crclbar., --N(R.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: April 30, 1996
    Assignee: Agfa-Gevaert AG
    Inventor: Michael Missfeldt
  • Patent number: 5508159
    Abstract: A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a silver halide emulsion layer containing a crown ether having a 18-membered ring condensed with at least one aromatic ring and silver halide grains having a (100) face and satisfying the following inequality:15.ltoreq.Kwherein K is defined to be (intensity of a diffraction line attributed to a (200) face)/(intensity of a diffraction line attributed to a (222) face).
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: April 16, 1996
    Assignee: Konica Corporation
    Inventors: Masato Okuyama, Yukio Ohya
  • Patent number: 5494788
    Abstract: The invention relates to a method of sensitizing (111) high chloride tabular grains having {111} major faces comprising providing the high chloride tabular grains, and sensitizing using temperatures greater than 70.degree. C.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: February 27, 1996
    Assignee: Eastman Kodak Company
    Inventors: Yun C. Chang, Jerzy A. Budz
  • Patent number: 5492800
    Abstract: A silver halide photographic light-sensitive material has at least one silver halide emulsion layer. 50% or more of a total projected area of silver halide grains of at least one silver halide emulsion in the silver halide emulsion layer are accounted for by tabular grains each having an average aspect ratio of 2 or more and containing dislocations.
    Type: Grant
    Filed: June 3, 1994
    Date of Patent: February 20, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Yamagami
  • Patent number: 5492802
    Abstract: A silver halide photographic element comprising a sensitizing dye of the formula: ##STR1## wherein: X1, X2, n, L, L2, R1 and R2 are as defined in the specification;Z1 represents Ar1-(L1) m, where Ar1 is a substituted or unsubstituted aromatic group, L1 is a linking group, m is 0 or 1, and the LOGP(A) of a molecule having a structure A corresponding to a portion of the dye ##STR2## is no more than 90% of LOGP(A'), where A' is the same as A except Z1 is replaced with unsubstituted phenyl, provided that L1 is not --CO-- when X1 or X2 is S or Se; andW1 is a counterion as needed to balance the charge of the molecule.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: February 20, 1996
    Assignee: Eastman Kodak Company
    Inventors: Richard L. Parton, David A. Stegman
  • Patent number: 5491055
    Abstract: The invention relates to an emulsion comprising silver halide grains said grains comprising sensitizing dyes adsorbed onto said grains during grain forming or sensitizing and at least one sulfodihydroxy aryl compound represented by the Fomulas I or II ##STR1## wherein X and Y represent an SO.sub.3 group or a hydrogen with at least one of X and Y being a sulfo group.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: February 13, 1996
    Assignee: Eastman Kodak Company
    Inventor: Sang H. Kim
  • Patent number: 5476758
    Abstract: Disclosed herein is a silver halide color photographic light-sensitive material which has a specific photographic sensitivity of 320 or more, and which comprises a support layer and silver halide emulsion layers formed thereon. The material has a film thickness of 22 .mu.m or less, measured from the light-sensitive layer closest to the support layer up to the surface of the material facing away from the support layer. At least one of the silver halide emulsion layers contains a spectral sensitizer represented by the following formula (I): ##STR1## In the formula, R.sup.1 and R.sup.2 are alkyl groups, at least one of which at least one carbon atom bonds together with at least three atoms other than hydrogen atoms, X is an anion, p is 0 or 1, k is 0, 1 or 2, L.sub.1 and L.sub.2 are a methyne group or a substituted methyne group, Z.sup.1 and Z.sup.2 are groups of atoms numerous enough to form a 5- or 6-membered nitrogen-containing heterocyclic ring.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: December 19, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoichi Suga, Masaki Okazaki
  • Patent number: 5472839
    Abstract: A photographic recording material having a photosensitive silver halide emulsion layer which is spectrally sensitized with a sensitizing dye of one of the formulae I and II ##STR1## in which R.sup.1, R.sup.2 denote sulfoalkyl;R.sup.3 denotes alkyl;R.sup.4 denotes H, F, Cl, --CN, alkoxycarbonyl, carbamoyl;R.sup.5 denotes Cl, --CN;M.sup..sym. denotes a counter ion (cation) which is optionally necessary to balance the charge exhibits a high degree of sensitivity which is stable under warm, humid conditions.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: December 5, 1995
    Assignee: Agfa-Gevaert AG
    Inventor: Michael Missfeldt
  • Patent number: 5466822
    Abstract: A benzimidazolocarbocyanine dye represented by the following general formula (I): ##STR1## wherein R.sub.11, R.sub.12, R.sub.13 and R.sub.14 each represents a substituted or unsubstituted alkyl group; X.sub.11, X.sub.12, X.sub.13 and X.sub.14 may be the same or different and each represents a hydrogen atom, a halogen atom, an unsubstituted alkyl group, an alkoxy group, an aryloxy group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a hydroxy group, a cyano group or a halogen-substituted alkyl group; Y represents an ion required for balancing charge; and m represents 1 or 2, and when the compound forms an inner salt, m is 1, and a silver halide photographic material containing said dye.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: November 14, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiki Fujiwara
  • Patent number: 5462847
    Abstract: A silver halide color photographic material is provided comprising at least one yellow-developable silver halide emulsion layer, at least one magenta-developable silver halide emulsion layer and at least one cyan-developable silver halide emulsion layer on a support, characterized in that said at least one cyan-developable silver halide emulsion layer comprises at least one cyan dye-forming coupler represented by the following general formula (Ia) and silver bromochloride or silver chloride emulsion grains substantially free of silver iodide having a silver chloride content of 95 mol % or more spectrally sensitized with at least one sensitizing dye having a reduction potential of -1.27 V (vs. SCE) or lower: ##STR1## wherein Za represents --NH-- or --CH(R.sub.3)--; Zb and Zc each represents --C(R.sub.4).dbd. or --N.dbd.; R.sub.1, R.sub.2 and R.sub.3 each represents an electron withdrawing group having a Hammett's substituent constant .sigma..sub.p value of 0.20 or more, with the proviso that the sum of .sigma.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: October 31, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shigeaki Otani
  • Patent number: 5460937
    Abstract: Hydrophobic compounds, such as photographically useful compounds, are incorporated into an aqueous medium, such as a silver halide emulsion or a photographic coating composition, by forming a solid additive material comprising the hydrophobic compound and a solid hydrophilic material. The solid hydrophilic material is preferably a mixture of a polysaccharide and sorbitol or succinimide. The additive material is prepared by dry powder mixing the solid hydrophobic compound and solid hydrophilic material followed by a process step that heats, expells, and cools the composition to produce a high surface area uniform material having a specific surface area of at least about 10 square centimeters per gram. The additive material can then be dissolved directly and uniformly in the aqueous medium.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: October 24, 1995
    Assignee: Eastman Kodak Company
    Inventors: James W. Blease, John W. Boettcher
  • Patent number: 5460929
    Abstract: There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (Ia) and (a) a sensitizing dye containing a sulfonamide group, (b) negative-type internal latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (c) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, (d) a monodisperse silver halide emulsion, (e) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (f) a colloidal silver, or (g) a DIR-hydroquinone: ##STR1## wherein Za represents --NH-- or --CH(R.sub.3)--, Zb and Zc each represent --C(R.sub.4).dbd. or --N.dbd., R.sub.1, R.sub.2, and R.sub.3 each represent an electron-attracting group wherein the Hammett substituent constant .sigma..sub.p value is 0.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: October 24, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoshi Nagaoka, Kazuyoshi Yamakawa, Mitsuru Yamamoto, Makoto Suzuki, Yasuhiro Shimada, Katsuro Nagaoka, Hideo Ikeda, Takefumi Hara, Sadanobu Shuto
  • Patent number: 5459025
    Abstract: A novel silver halide photographic material is provided, comprising at least one methine compound having a methine dye and hydrazine covalently bonded to each other, two nitrogen atoms in said hydrazine being substituted by four substituents. In a preferred embodiment, the methine compound is represented by formula (I): ##STR1## wherein MET represents an atomic group; Q represents a divalent bonding group consisting of atoms or atomic group containing at least one of carbon atom, nitrogen atom, sulfur atom and oxygen atom; Hy represents an atomic group having a hydrazine structure represented by formula (II); k.sub.1 represents 0 or an integer 1 to 4; and k.sub.2 represents 0 or 1, and k.sub.3 represents an integer 1 to 4. ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group, an aryl group or a heterocyclic group, with the proviso that Hy is substituted by at least one --(Q).sub.k2 -(MET).sub.k1. A novel methine compound is also provided represented by the general formula (I).
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: October 17, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takanori Hioki
  • Patent number: 5456999
    Abstract: The present invention provides a photographic material comprising a silver halide emulsion layer sensitized to light above 700 nm by means of an infrared sensitizing dye having a maximum absorption between 700 nm and 850 nm characterized in that said silver halide emulsion further comprises a red sensitizing dye of the cationic type having a maximum absorption between 600 nm and 700 nm. The thus obtained photographic material shows an increased sensitivity in the infrared region. The material can be used in as silver salt diffusion transfer process to prepare a lithographic printing plate.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: October 10, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5449596
    Abstract: There is disclosed a silver halide photographic material which is rapidly processable, high sensitive and small in variations in sensitivity between production lots of the photograhic material. The silver halide photographic material comprises a silver halide emulsion layer containing a cyan dye forming coupler, a silver halide emulsion layer containing a magenta dye forming coupler, and a silver halide emulsion layer containing a yellow dye forming coupler on a reflective support, wherein at least one layer of said silver halide emulsion layers comprises silver halide emulsion grains and compounds represented by the following general formulas (I) and (II), said emulsion grains being tabular silver halide emulsion grains having (100) planes as main planes and a silver chloride content of 90 mol % or more, and further the mean bromide ion content on surfaces of said emulsion grains is twice or more that of the whole emulsion grains: ##STR1## wherein the substituents are as defined herein the specification.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: September 12, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kawai, Mitsuo Saitou
  • Patent number: 5449594
    Abstract: A silver halide color photographic light-sensitive material includes a support having provided thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, at least one red-sensitive silver halide emulsion layer, and at least one hydrophilic colloid layer. The hydrophilic colloid layer contains a compound represented by Formula I below, a silver halide emulsion layer having an interlayer effect on the red-sensitive layer is also provided, and the layer with the interlayer effect contains a silver halide emulsion spectrally sensitized with a sensitizing dye represented by Formula (III) below.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: September 12, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumitaka Ueda, Junji Nishigaki
  • Patent number: 5445930
    Abstract: A novel silver halide photographic material is provided, comprising a hydrophilic colloidal layer containing at least one dye represented by the following formula (I): ##STR1## wherein Y.sup.1 and Y.sup.2 each represents a chalcogen atom, --CH.dbd.CH--, --N(R.sup.10)--, or --C (R.sup.10)(R.sup.11)--, in which R.sup.10 and R.sup.11 each represents an alkyl group; Z.sup.1 and Z.sup.2 each represents a nonmetallic atom group necessary for forming a benzo condensed or naphtho condensed ring; R.sup.1 and R.sup.2 each represents an alkyl group; the plurality of L groups may be the same or different and each represents a methine group, with the proviso that at least one of the plurality of L groups represents a methine group substituted by --OR.sup.12, --N(R.sup.12)(R.sup.13), --SR.sup.12 or --CH(R.sup.14)(R.sup.15), in which R.sup.12 represents an alkyl or aryl group substituted by an acidic substituent, R.sup.13 represents a hydrogen atom or an alkyl or aryl group substituted by an acidic substituent, and R.sup.
    Type: Grant
    Filed: October 25, 1994
    Date of Patent: August 29, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Itsuo Fujiwara
  • Patent number: 5443948
    Abstract: An improved process for manufacturing a spectrally sensitized photographic element comprising the combination of ultrafiltration of silver halide grains in combination with a supersensitizing additive consisting of ##STR1## wherein D.sup.+ is Na.sup.+, K.sup.+, Li.sup.+, NH4.sup.+ ; n is 1-5; m is 1-10.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: August 22, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Mark D. Franke, Richard J. Legg, Alden D. West, Anna E. Doyle
  • Patent number: 5439789
    Abstract: A silver halide photographic material is disclosed which comprises at least one of methine compounds represented by the following formula (I) ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl group; V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6 and V.sub.7 are the same or different and each represents a hydrogen atom or a substituent; X.sub.1 represents a halogen atom; L.sub.1, L.sub.2 and L.sub.3 are the same or different and each represents a substituted or unsubstituted methine group; E represents an auxochrome; n represents a number of 0 or more; M.sub.1 represents an ion for neutralizing charge; and m.sub.1 represents a number of 0 or more necessary for neutralizing the molecular charge.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: August 8, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Kato, Kiyohito Takada
  • Patent number: 5437972
    Abstract: Disclosed is a novel silver halide photographic material comprising a support having thereon (a) a layer containing at least one methine compound represented by the following general formula (I) and (b) a layer containing at least one methine compound represented by the following general formula (II), (III), (IV) or (V): ##STR1## wherein the variables in the formulas are defined in the detailed description. In a preferred embodiment, the silver halide photographic material comprises at least one methine compound represented by general formula (I) and at least one methine compound represented by general formula (II) or (V) in the same layer.
    Type: Grant
    Filed: January 27, 1994
    Date of Patent: August 1, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akihiko Ikegawa, Masayuki Kuramitsu, Masaki Okazaki
  • Patent number: 5422237
    Abstract: A methine compound having a benzoxazole nucleus substituted by a meta-substituted aryl group and the methine compound represented by the following formula ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each represents a substituted or unsubstituted alkyl group; Z.sub.1 represents an atomic group necessary for forming a five-membered or six-membered nitrogen-containing heterocyclic ring; R.sub.3 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aryloxy group, a halogen atom, a substituted or unsubstituted alkylthio group, or a substituted or unsubstituted heterocyclic group; L.sub.1, L.sub.2 and L.sub.3 are the same or different and each represents a substituted or unsubstituted methine group; n represents 0, 1, 2 or 3; M.sub.1 represents an ion for neutralizing charge; and m.sub.1 represents a number of 0 or more necessary for neutralizing the molecular charge.
    Type: Grant
    Filed: May 10, 1994
    Date of Patent: June 6, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Kato, Kiyohito Takada
  • Patent number: 5422238
    Abstract: A novel silver halide photographic material comprising at least one methine compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents --(CH.sub.2).sub.r --CONHSO.sub.2 --R.sup.3, --(CH.sub.2).sub.s --SO.sub.2 NHCO--R.sup.4, --(CH.sub.2).sub.t --CONHCO--R.sup.5 or --(CH.sub.2).sub.u --SO.sub.2 NHSO.sub.2 --R.sup.6 in which R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represents an alkyl group, alkoxy group or amino group, r, s, t and u each represents an integer 1 to 5; and R.sup.2 represents has the same meaning as R.sup.1 or represents an alkyl group; Z.sup.1 and Z.sup.2 each represents a nonmetallic atom group required to form a 5- or 6-membered heterocyclic group; p and q each represents an integer 0 or 1; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; m represents an integer 0 to 2; X represents an anion; and k represents an integer required to adjust the charge in the molecule to 0.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: June 6, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akihiko Ikegawa, Masayuki Kuramitsu, Masaki Okazaki
  • Patent number: 5418126
    Abstract: Spectral sensitizing dyes, and silver halide photographic elements incorporating them, which dyes have the formula: ##STR1## wherein: X1 and X2 each independently represent the atoms necessary to complete a 5- or 6-membered heterocyclic nucleus (preferably benzo-condensed), and X1 may be further substituted and X2 substituted or unsubstituted;n is a positive integer from 1 to 4,p and q each independently represents 0 or 1,each L independently represents a substituted or unsubstituted methine group,R1 and R2 each independently represents substituted or unsubstituted aryl or substituted or unsubstituted alkyl,Z1 represents a substituted or unsubstituted pyrrole or furan containing group;W1 is a counterion as needed to balance the charge of the molecule.
    Type: Grant
    Filed: January 19, 1994
    Date of Patent: May 23, 1995
    Assignee: Eastman Kodak Company
    Inventors: David A. Stegman, Richard L. Parton, Steven G. Link, Pamela M. Ferguson
  • Patent number: 5415980
    Abstract: A method of forming a photographic image comprising imagewise exposing a silver halide color photographic material comprising a support having thereon a cyan color image forming layer, a magenta color image forming layer and an yellow color image forming layer, wherein the cyan color image forming layer in the photographic material contains silver halide emulsion grains having a silver chloride content of 95 mol % or more and containing substantially no silver iodide and contains a color sensitizing dye of the following general formula (I), ##STR1## wherein the terms are as defined in the specification and color developing the exposed material with a color developer, wherein the color developer has a chloride ion content of from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/liter and a bromide ion content of from 1.5.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/liter.
    Type: Grant
    Filed: March 25, 1994
    Date of Patent: May 16, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoto Ohshima
  • Patent number: 5411854
    Abstract: The invention is accomplished by providing a combined process of chemical and spectral sensitization comprising providing a silver halide emulsion, adding a sulfur or gold chemical sensitizer, adding a finish modifier ##STR1## wherein X is --O--, --S--, --Se--, ##STR2## Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus or together represent the atoms completing a fused aromatic nucleus; R is hydrogen or lower alkyl of from 1 to 5 carbon atoms; and R.sub.1 is a hydrogen or methyl, provided that Y.sup.1 and Y.sup.2 individually represent hydrogen or an aromatic nucleus when R.sub.1 is hydrogen, adding dye, andadding a hydrolyzable quaternized chalcogenazolium salt of a middle chalcogen,heating to a temperature sufficient to cause sensitization of said silver halide to take place, and cooling to recover the sensitized emulsion.
    Type: Grant
    Filed: December 29, 1993
    Date of Patent: May 2, 1995
    Assignee: Eastman Kodak Company
    Inventors: Thomas B. Brust, Robert J. Newmiller
  • Patent number: 5405739
    Abstract: A silver halide photographic light-sensitive material comprises a support and provided thereon, a silver halide emulsion layer containing silver halide grains and a macrocyclic compound in an amount of 1.times.10.sup.-6 to 1.times.10.sup.-1 mol per mol of silver, said macrocyclic compound comprising a 9- or more-membered ring containing at least one of a nitrogen atom, an oxygen atom, a sulfur atom and a selenium atom, and said silver halide grains having a silver chloride content of not less than 90 mol % and containing at least one metal selected from the group consisting of metals of VIB group, VIIB group, VIII group, IIB group, IIIA group and IVA group from the Periodic Table.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: April 11, 1995
    Assignee: Konica Corporation
    Inventors: Yukio Ohya, Masato Okuyama
  • Patent number: 5397693
    Abstract: A silver halide photographic light-sensitive material contains a methine compound represented by the following formula: ##STR1## wherein Y.sup.1 is a group which is cleavable by a nucleophile; Z.sup.1 is --O--, --S--, or other; Z.sup.2 is --O--, --S--, --CR.sup.3 R.sup.4 (wherein each of R.sup.3 and R.sup.4 is alkyl or other), or other; A and B are each independently hydrogen, halogen, alkyl, aryl or a heterocyclic group; A and B may be linked to each other to form an unsaturated aliphatic ring, an aromatic ring or a heterocyclic ring; and Q.sup.1 is a methine or polymethine group which may have a heterocyclic group. A novel methine compound is also disclosed.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: March 14, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Kawata, Tadashi Ikeda
  • Patent number: 5391475
    Abstract: Disclosed is a silver halide color photographic photosensitive material in which the spectral sensitivity in the green short wavelength region is increased and which has excellent storage stability. The photosensitive material is sensitized by a selenium sensitizer represented by formula (I). Also, a green light sensitive photosensitive silver halide emulsion layer has been spectrally sensitized with a sensitizing dye represented by formula (II).
    Type: Grant
    Filed: May 4, 1993
    Date of Patent: February 21, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Nishigaki, Fumitaka Ueda, Akihiko Ikegawa
  • Patent number: 5387502
    Abstract: A silver halide photographic material comprises on a support at least one silver halide emulsion layer containing a trimethine dye or a pentamethinecyanine dye each containing an alkylthio-substituted benzoazole nucleus. The photographic material is suitable for forming images using a scanning system that employes a semiconductor laser as a light source. The photographic material has a high sensitivity which does not degrade during storage, and the material does not tend to fog during storage.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: February 7, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Inagaki
  • Patent number: 5376523
    Abstract: A process for controlling the silver halide grain-to-grain distribution of a variable contrast dye in a light sensitive silver halide emulsion layer of a variable contrast photographic element, and thereby adjusting the low contrast characteristic curve of the element, is disclosed comprising the process steps of adding a green variable contrast sensitizing dye of the following formula (I) to a silver halide emulsion for a variable contrast photographic element, adding a blue sensitizing dye of the following formula (II) to the same silver halide emulsion, and coating the emulsion on a support. In the process, the green and blue sensitizing dyes are added to the emulsion at substantially the same time, and the green dye is added in an amount less than that required to impart maximum sensitivity to all of the silver halide in the emulsion. ##STR1## In formula (I), R.sup.1, R.sup.2, R.sup.6 and R.sup.
    Type: Grant
    Filed: October 4, 1993
    Date of Patent: December 27, 1994
    Assignee: Eastman Kodak Company
    Inventors: Marian S. Henry, Sandra M. Finn, Harry J. Price
  • Patent number: 5364755
    Abstract: A silver halide photographic light-sensitive material have at least one silver halide emulsion layer on a support, wherein at least one of the silver halide emulsion layers comprises an emulsion subjected to chemical sensitization with a selenium compound and spectral sensitization with at least one type of a methine compound represented by Formula (I) below: ##STR1## wherein R.sup.1 represents --(CH.sub.2).sub.r --CONHSO.sub.2 --R.sub.3, --(CH.sub.2).sub.s --SO.sub.2 NHCO--R.sup.4, --(CH.sub.2).sub.t --CONHCO--R.sup.5, or --(CH.sub.2).sub.u --SO.sub.2 NHSO.sub.2 --R.sup.6 ; R.sup.3, R.sup.4, R.sup.5, and R.sup.6 each represent an alkyl group, an alkoxy group, or an amino group; R.sup.2 has the same meaning as R.sup.1 or represents an alkyl group; Z.sup.1 and Z.sup.2 each represent a nonmetal atom group required to form a 5- or 6-membered heterocyclic ring; each of L.sub.1, L.sub.2, and L.sub.3 represents a methine group; X.sub.
    Type: Grant
    Filed: April 16, 1993
    Date of Patent: November 15, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasushi Miyamoto, Akihiko Ikegawa
  • Patent number: 5362611
    Abstract: There is provided a silver halide photographic material which comprises a support having thereon at least three kinds of silver halide light-sensitive emulsion layers differing from one another in color sensitivity, at least two kinds of which comprise silver halide emulsion grains sensitized spectrally with sensitizing dyes providing their respective spectral sensitivity maxima at wavelength of longer than about 570 nm, with the photographic material further containing at least one water-soluble dye which is selected from eight groups having specified structural formulae respectively and has an absorption maximum at wavelengths longer than about 570 nm, thereby acquiring an aptitude with scanning exposure using at least two kinds of light sources capable of emitting monochromatic high-intensity beams of wavelengths longer than 570 nm and ensuring high resolving power without attended by aggravation of color separation.
    Type: Grant
    Filed: October 27, 1992
    Date of Patent: November 8, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Kawai, Toru Harada
  • Patent number: 5362601
    Abstract: A heat-developable photosensitive material includes an infrared-sensitive layer having a maximum spectral sensitivity at a wavelength of 700 nm or longer. A silver chlorobromide emulsion from which the infrared-sensitive layer is formed is prepared by adding an iodide at an intermediate stage during silver halide grain formation or later. The photosensitive material exhibits high sensitivity and low fog while the corresponding emulsion coating composition in solution form remains stable with time.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: November 8, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kiyoteru Miyake
  • Patent number: 5356768
    Abstract: Light-sensitive silver halide color photographic elements comprising a silver halide photographic emulsion layer including a) at least one 2,5-diacylamino phenol cyan coupler dissolved in low-boiling water-immiscible organic solvent droplets dispersed in said emulsion layer in reactive association with at least one non-ionic surfactant compound having a HLB higher than 20 and at least one anionic surfactant compound and b) at least one cationic carbocyanine spectral sensitizing dye.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: October 18, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Walter Bertramini, Agostino Baldassarri
  • Patent number: 5354651
    Abstract: Spectral sensitizing dyes, and silver halide photographic elements incorporating them, which dyes have the formula: ##STR1## wherein: X1 and X2 each independently represent the atoms necessary to complete a 5- or 6-membered heterocyclic nucleus, wherein X1 may be further substituted and X2 may be substituted or unsubstituted;n is a positive integer from 1 to 4;p and q each independently represents 0 or l,each L independently represents a substituted or unsubstituted methine group,R1 and R2 each independently represents substituted or unsubstituted aryl or substituted or unsubstituted aliphatic groups;Z1 represents a substituent containing an hydroxyarylacyl group (preferably an .alpha.-hydroxyarylacyl group), an aromatic ring of which may be appended or fused to X1; andW1 is a counterion as needed to balance the charge of the molecule.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: October 11, 1994
    Assignee: Eastman Kodak Company
    Inventor: Richard L. Parton
  • Patent number: 5350665
    Abstract: A silver halide color photographic material comprising a reflective support having thereon a yellow dye image forming silver halide emulsion layer, a magenta dye image forming silver halide emulsion layer and a cyan dye image forming silver halide emulsion layer, wherein said yellow dye image forming layer, magenta dye image forming layer and cyan dye image forming layer exhibit a maximum spectral sensitivity in the range of 400 to 490 nm, 530 to 570 nm and 660 to 720 nm, respectively, said silver halide emulsion of said cyan dye image forming layer comprises a silver chloride, silver bromochloride or silver bromochloroiodide emulsion having a silver chloride content of 90 mol % or more with a maximum spectral sensitivity given by J-band absorption of a compound represented by the general formula (I), ##STR1## wherein the variables are described in the specification.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: September 27, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hasebe, Shigeaki Otani, Yasuhiro Hayashi
  • Patent number: 5340694
    Abstract: A silver halide photographic material contains at least one hydrazine compound of formula (I): ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group, an aryl group or a heterocyclic group; and R.sub.1 and R.sub.2, R.sub.3 and R.sub.4, R.sub.1 and R.sub.3, and R.sub.2 and R.sub.4 each may be bonded to each other to form a non-aromatic ring; provided that the carbon atom of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 which is directly bonded to a nitrogen atom of the hydrazine core of the compound is not substituted by an oxo group. The material has a high sensitivity and does not tend to fog. After storage, depression of the sensitivity of the material is small.
    Type: Grant
    Filed: February 2, 1993
    Date of Patent: August 23, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takanori Hioki, Ryoji Nishimura
  • Patent number: 5340711
    Abstract: A silver halide photographic element having a green sensitive layer the silver halide of which is sensitized by a combination of three sensitizing dyes of the formula I, II and III: ##STR1## wherein: each of the benzo-rings of I, II or III may be substituted or unsubstituted;each L is a substituted or unsubstituted methine; andR1 through R9 are substituted or unsubstituted alkyl or aryl.
    Type: Grant
    Filed: January 15, 1993
    Date of Patent: August 23, 1994
    Assignee: Eastman Kodak Company
    Inventor: Sang H. Kim
  • Patent number: 5338657
    Abstract: A novel silver halide photographic material is disclosed, which comprises at least one methine dye represented by the following formula (I): ##STR1## wherein R.sup.1 represents an alkyl, aryl or heterocyclic group; R.sup.2 and R.sup.3 each represents an alkyl group; R.sup.4 and R.sup.5 each independently represents an alkyl group, an alkoxy group, an aryloxy group, a hydrogen atom, a halogen atom, or a hydroxyl group, provided that at least one of R.sup.4 and R.sup.5 represents an alkyl, alkoxy, or aryloxy group; V.sup.1 and V.sup.2 each independently represents a hydrogen atom, a halogen atom, or an atomic group; L.sup.1, L.sup.2, and L.sup.3 each represents a methine group; M represents a charge neutralizing ion; and m represents 0 or a higher number required for the neutralization of electric charge in the dye.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: August 16, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takashi Kato