Hetero Rings Bridged Or Fused To Carbocyclic Rings Patents (Class 430/588)
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Patent number: 4863843Abstract: A silver halide photographic emulsion comprising as major constituent silver bromide with improved gradation, density and sensitivity and decreased fog is disclosed. This emulsion contains at least one of the compounds represented by the general formula ##STR1## wherein Z represents an aromatic radical, or of the oxidized derivatives thereof, and at least one of the compounds represented by the general formula ##STR2## wherein A represents a hydroxyl group, an amino group, ##STR3## R.sub.1 and R.sub.2 form a ring jointly with the carbon atom to which R.sub.1 and R.sub.2 are attached or one of R.sub.1 and R.sub.2 represents a hydrogen atom and the other represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxyl group; n is 0 or an integer of 1 to 8, and M represents a hydrogen atom or an alkali metal.Type: GrantFiled: October 28, 1985Date of Patent: September 5, 1989Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Masao Okushima, Katsuaki Iwaosa, Susumu Baba, Tokitsugu Houjo
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Patent number: 4839265Abstract: A silver halide photosensitive material having a hydrophilic colloid layer containing a specific water-soluble dye including at least three acid radicals. The water-soluble dye in the hydrophilic colloid layer absorbs light in the infrared region but does not adversely affect the photographic characterisitics of the photographic emulsion and is discolored upon photographic processing.Type: GrantFiled: January 19, 1988Date of Patent: June 13, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Shigeru Ohno, Yuji Mihara, Keiichi Adachi
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Patent number: 4830958Abstract: A photographic material having an excellent rapid processability, a high sensitivity and a less sensitivity variation due to a change of standing of the silver halide emulsion in the course of preparation of the light-sensitive material, and its preparation process are disclosed. The silver halide photographic light-sensitive material comprises a support bearing at least one silver halide emulsion layer thereon, and at least one silver halide emulsion layer contains highly chloride-containing silver halide grains having a silver chloride content of not less than 90 mol %, a water-soluble bromide of from 0.05 mol % to 2 mol % per mol of silver halide and a high boiling organic solvent having a dielectric constant of not higher than 6.0.Type: GrantFiled: January 25, 1988Date of Patent: May 16, 1989Assignee: Konica CorporationInventors: Mitsuhiro Okumura, Keiji Ohbayashi, Shigeo Tanaka
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Patent number: 4801526Abstract: A silver halide photographic light-sensitive material comprising a specific silver halide grain is disclosed. The siliver halide grain contains a localized portion containing 20 mol % or more of silver iodide and average content of silver iodide of which grain is from 0.1 to 10.0 mol %, provided that the silver halide grain is prepared by mixing an aqueous solution containing a water soluble halide compound and an aqueous solution containing a water soluble silver salt under a condition that pAg of the mixture is raised at 9.7 or more during a period after a half amount of the silver salt to be used has been added to the mixture. The photographic light-sensitive material has improved photographic characteristics and is suitable for radiographic use.Type: GrantFiled: February 18, 1988Date of Patent: January 31, 1989Assignee: Konica CorporationInventors: Eiji Yoshida, Akio Suzuki, Satoru Nagasaki, Masumi Arai, Iku Metoki, Haruhiko Sakuma
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Patent number: 4800154Abstract: A silver halide photographic emulsion comprising at least one spectral sensitizing dye having the following general formula (I):Dye--J.sup.1 --CONH--J.sup.2 --NHNHG--R (I)wherein Dye represents a dye residue capable of becoming a spectral sensitizing dye; J.sup.1 represents a substituted or unsubstituted alkylene group, a substituted or unsubstituted arylene group, a substituted or unsubstituted aralkylene group, or a substituted or unsubstituted alkarylene group; J.sup.2 represents a substituted or unsubstituted arylene group; R represents hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or a substituted or unsubstituted iminomethylene group.Type: GrantFiled: October 16, 1986Date of Patent: January 24, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaki Okazaki, Haruo Takei
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Patent number: 4791053Abstract: A silver halide photographic material comprising a support having thereon at least one emulsion layer which contains a silver chlorobromide or silver chloride each having an iodide content of 3 mol % or less. The monodispersed emulsion is prepared in a process comprising the steps of, in sequence, forming silver halide grains which have a grain size distribution represented by a variation coefficient of 0.2 or less, causing halogen replacement in silver halide grains by addition of a water-soluble bromide in a proportion of from 0.6 to 20 mol % with respect to the total silver halide in the presence of at least one sensitizing dye selected from among simple cyanine dyes, carbocyanine dyes, and dicarbocyanine dyes at individual surfaces of the silver halide grains, and then subjecting the resulting silver halide grains to chemical sensitization, thereby achieving enhanced sensitivity and improved pressure characteristics.Type: GrantFiled: December 3, 1986Date of Patent: December 13, 1988Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadashi Ogawa
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Patent number: 4778748Abstract: A method for processing a light-sensitive silver halide photographic material, which comprises processing a light-sensitive silver halide photographic material subjected to imagewise exposure with a processing solution having fixing ability, and thereafter processing the material with a first stabilizing solution having a surface tension of 20 to 78 dyne/cm and a second stabilizing solution having a surface tension of 8 to 60 dyne/cm substantially without performing the water washing step.Type: GrantFiled: January 22, 1987Date of Patent: October 18, 1988Assignee: Konishiroku Photo Industries, Co., Ltd.Inventors: Satoru Kuse, Shigeharu Koboshi, Kazuhiro Kobayashi
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Patent number: 4764456Abstract: A silver halide color photographic material is described, comprising at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support, wherein at least one coupler represented by general formula (I) is contained in at least the green-sensitive emulsion layer: ##STR1## Moieties in the couplers are defined in the specification. The wavelength of the red-sensitive emulsion layer shows a defined maximum spectral sensitivity in the short wavelength side and wavelengths corresponding to 80%, 50%, 40%, 20% and 10% of the maximum sensitivity in defined wavelength regions. Similar values are given for the long wavelength side of spectral sensitivity.Type: GrantFiled: August 28, 1986Date of Patent: August 16, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiyuki Watanabe, Naoyasu Deguchi
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Patent number: 4753868Abstract: A process for processing a silver halide color photographic material is described, comprising developing an imagewise exposed light-sensitive material and then bleach-fixing it, wherein the light-sensitive material contains at least one sensitizing dye selected from three particular types of sensitizing dye compounds, and a bleach-fixing solution contains iodide ions in an amount exceeding 1.2.times.10.sup.-3 gram ion per liter of solution.Type: GrantFiled: April 7, 1987Date of Patent: June 28, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Kensuke Goda, Akio Mitsui
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Patent number: 4741995Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide emulsion layer contains a silver halide emulsion which is spectrally sensitized by adding a spectral sensitizing dye prior to the completion of formation of silver halide particles and at least one kind of pyrazoloazole type magenta coupler represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituent; X represents a hydrogen atom or a group capable of being released upon a coupling reaction with an oxidation product of an aromatic primary amine developing agent; Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--, one of the Za--Zb bond and the Zb--Zc bond being a double bond and the other being a single bond, and when the Zb--Zc bond is a carbon-carbon double bond, it may form a part of an aromatic ring; R.sup.Type: GrantFiled: April 28, 1986Date of Patent: May 3, 1988Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadaaki Tani, Mikio Ihama, Kiyoshi Nakazyo
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Patent number: 4693965Abstract: A method for manufacturing a chemically and spectrally sensitized silver halide emulsion is described, which comprises carrying out chemical ripening of the emulsion in the presence of an iridium salt and a photographic spectral sensitizing dye.Type: GrantFiled: November 27, 1985Date of Patent: September 15, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Mikio Ihama, Tadaaki Tani
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Patent number: 4690883Abstract: A process for forming an image is provided, comprising imagewise exposing a photosensitive material comprising on a support a photosensitive silver halide, a sensitizing dye having general formula (I) and/or (II), and a compound which forms or releases a mobile dye in proportion or counter-proportion to the reduction of the photosensitive silver halide into silver by heating, and transferring the resulting mobile dye to a dye-fixing element in the presence of a hydrophilic solvent,wherein formulas (I) and (II) are: ##STR1## wherein Z.sup.1 and Z.sup.2 represent a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring; R.sup.1 and R.sup.2 represent a substituted or unsubstituted alkyl group; L.sup.1, L.sup.2, and L.sup.3 represent a substituted or unsubstituted methine group; p and q are equal to 0 or 1; m is equal to 0, 1, 2, or 3; X1.sup..crclbar. represents an anion; k is equal to 0 or 1, with the proviso that the number of organic acid groups contained in the molecule except X1.Type: GrantFiled: December 13, 1985Date of Patent: September 1, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiiti Kubodera, Masaki Okazaki
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Patent number: 4677051Abstract: A heat-developable color light-sensitive material is provided comprising on a support at least a light-sensitive silver halide emulsion, a binder, a compound capable of producing or releasing a mobile dye in direct or inverse proportion to the reaction of the light-sensitive silver halide being reduced into silver at elevated temperatures, and a dye having the general formula: ##STR1## wherein each of R.sup.1 and R.sup.2 is a substituted or unsubstituted alkyl or alkenyl group,R.sup.3 is a hydrogen atom, or substituted or unsubstituted alkyl, alkoxy, aryl or alkenyl group,each of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 is a hydrogen atom, halogen atom, hydroxyl, carboxyl, or substituted or unsubstituted alkyl, alkoxy, alkoxycarbonyl, acyl, acyloxyl, aryl, amino, or acylamino group,X.sup.1 and X.sup.2, and X.sup.3 and X.sup.4 can be mutually combined to form a benzene ring,A.sup.- is an anion, andn is equal to 0 or 1.Type: GrantFiled: November 26, 1985Date of Patent: June 30, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Seiiti Kubodera, Takanori Hioki, Masaki Okazaki
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Patent number: 4659654Abstract: A silver halide photographic light-sensitive emulsion contains silver halide particles, chemically sensitized, the average concentration of the silver iodide of which is from 0.5 to 10 mole % and which have inside part wherein not less than 20 mole percent silver iodide is present locally; and at least one cyanine dyes having the Formulas [I], [II] and [III] as herein described.Type: GrantFiled: September 26, 1985Date of Patent: April 21, 1987Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Iku Metoki, Akio Suzuki, Eiji Yoshida, Kiyoshi Sato, Masumi Hosaka
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Patent number: 4657846Abstract: A silver halide photographic light-sensitive materials are described. In silver halide photographic printing paper comprising at least one silver halide photographic emulsion layer applied to a water impermeable reflective base, the printing paper of the present invention is in the improvement wherein said silver halide emulsion layer is spectrally sensitized with at least one cyanine dye represented by general formulae I and II, and an emulsified dispersion or latex dispersion of a water insoluble fluorescent whitening agent contained in a hydrophilic vehicle of at least one layer applied to the base on the same side as said silver halide emulsion layer: ##STR1## wherein Y.sub.1 and Y.sub.2 each represents an O atom, --N--R.sub.7 or a S atom, wherein R.sub.7 represents a lower alkyl group, A represents H or a lower alkyl group having 4 or less carbon atoms, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents --H, --CH.sub.3, --OCH.sub.3, --C.sub.2 H.sub.5, --OC.sub.2 H.sub.5, --CN, --Cl, --F, --CF.sub.Type: GrantFiled: December 20, 1984Date of Patent: April 14, 1987Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadayoshi Kokubo, Tadashi Ikeda, Keiichi Adachi, Masaki Okazaki, Tetsuo Yoshida
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Patent number: 4622290Abstract: Disclosed is a silver halide photographic emulsion made highly sensitive to white light by use of a combination of at least one sensitizing dye represented by the general formula: ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, or an aralkyl group, R.sub.2 represents a sulfoalkyl group, or a sulfoaralkyl group, and R.sub.3 represents an unsubstituted or substituted alkyl group, and at least one sensitizing dye represented by the general formula: ##STR2## wherein W.sub.1 to W.sub.4 represent each an alkyl group, an alkoxy group, or a hydroxyl group, or a pair of W.sub.1 and W.sub.2 or a pair of W.sub.3 and W.sub.4 forms an alkylenedioxy group, provided that said pair of W.sub.1 and W.sub.2 and said pair of W.sub.3 and W.sub.4 have each at least one alkoxy or hydroxyl group or said alkylenedioxy group; R.sub.4 represents a hydrogen atom, an alkyl group, an aralkyl group, or an aryl group; R.sub.5 represents a sulfoalkyl group or a sulfoaralkyl group; and R.sub.Type: GrantFiled: November 5, 1985Date of Patent: November 11, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Akira Tanaka, Hidetoshi Miura
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Patent number: 4621041Abstract: Disclosed is a method for plate-making which comprises imagewise exposing by scanning type flash exposure a lithographic printing plate comprising a support and at least a silver halide emulsion layer containing at least 70 mol % of silver chloride and prepared with addition of a water soluble iridium compound during emulsification or physical ripening of silver halide and a water soluble gold compound at any time before coating of the emulsion and thereafter subjecting the exposed emulsion to diffusion transfer development.Type: GrantFiled: July 11, 1984Date of Patent: November 4, 1986Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Masahiko Saikawa, Eiji Kanada, Kazunaka Endo
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Patent number: 4576905Abstract: Compounds containing an aromatic ring portion fused with a tellurazolium or derivative tellurazole, tellurazoline (including tellurazolinylidene), or tellurazolinium ring portion are disclosed together with processes and intermediates for their preparation. With properly selected pendant groups these tellurazolium and derivative compounds can be usefully employed as dyes, antifoggants or stabilizers, nucleating agents, latent image keeping addenda, or speed or contrast altering addenda in silver halide photographic systems.Type: GrantFiled: October 12, 1984Date of Patent: March 18, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, Ronald E. Leone, Rosemary Przyklek
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Patent number: 4575483Abstract: Polymethine dyes are disclosed containing a tellurazolium nucleus which is substituted at its 2-position with methine chain which is in turn substituted at its .beta. position with a dye property modifier. These dyes can be used in photographic elements to facilitate image formation.Type: GrantFiled: February 19, 1985Date of Patent: March 11, 1986Assignee: Eastman Kodak CompanyInventors: Wolfgang H. H. Gunther, John D. Mee
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Patent number: 4555481Abstract: A silver halide photographic emulsion is disclosed which contains at least one of benzimidazolocarbocyanine dyes represented by the general formula (I) or (II): ##STR1## wherein a represents an integer of 1 to 8, R.sub.1, R.sub.2 and which may be identical with or different from one another, represent each --CH.sub.2 (CF.sub.2).sub.b H or a substituted or unsubstituted alkyl group, but at least one of R.sub.1, R.sub.2 and R.sub.3 contains an acid group-containing alkyl group, wherein b, which may be identical with or different from a, represents an integer of 1 to 8, l represents 0 or an integer of 1 to 8, and m represents 0 or an integer of 1 to 8, but l+m>0; R.sub.4, R.sub.5 and R.sub.6, which may be identical or different from one another, represent each --(CH.sub.2).sub.j (CF.sub.2).sub.k F or a substituted or unsubstituted alkyl group, but at least one of R.sub.4, R.sub.5 and R.sub.6 represents an acid group (for example, sulfo group or carboxyl group, etc.Type: GrantFiled: January 25, 1984Date of Patent: November 26, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshinao Ukai, Masaki Okazaki, Haruo Takei, Ichizo Toya
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Patent number: 4555482Abstract: A silver halide photographic emulsion is disclosed. The emulsion includes a silver halide emulsion which has dispersed therein at least three types of sensitizing dyes. The emulsion includes at least one dye represented by the formula (I), at least one dye represented by the formula (II) and at least one dye represented by the formula (III). Each of the structural formulae and their substituents are defined within the specification. The resulting silver halide photographic emulsion shows a small decrease in the inherent sensitivity of the silver halide due to the sensitizing dye used.Type: GrantFiled: December 20, 1983Date of Patent: November 26, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Noriyuki Inoue, Masaki Okazaki, Kiyohiko Yamamuro, Haruo Takei
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Patent number: 4551424Abstract: A silver halide photographic light-sensitive material is described, comprising a support and at least one silver halide emulsion layer on the support, wherein the silver halide emulsion layer contains at least one specific type of sensitizing dye, at least one of the silver halide emulsion layer and other hydrophilic colloid layers contains at least one compound of four specific types of compounds and the silver halide grains contained in the silver halide emulsion are substantially tetradecahedral grains in which the proportion of (100) faces is at least 50%; this material is superior in both sensitivity and stain resistance.Type: GrantFiled: December 14, 1984Date of Patent: November 5, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Tadashi Ikeda, Kenichi Kuwabara, Kiyohiko Yamamuro, Tadayoshi Kokubo
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Patent number: 4524128Abstract: Photographic silver halide is spectrally sensitized by means of at least one bleachable spectral sensitizing dye comprising a cyanine dye nucleus and a particular N-methylene substituent. The spectrally sensitized photographic silver halide is useful in a photothermographic material. An image in the photothermographic material, after exposure, is developed and the spectral sensitizing dye is bleached, especially at elevated pH, by heating the photothermographic material to processing temperature.Type: GrantFiled: October 24, 1983Date of Patent: June 18, 1985Assignee: Eastman Kodak CompanyInventors: Larry D. Edwards, Frederick J. Sauter, George J. Burgmaier
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Patent number: 4510235Abstract: A silver halide photographic emulsion containing a particular combination of dyes is described which prevents aggravated fogging of the emulsion under the influence of high temperature or the combination of high temperature and high humidity, and minimizes the degradation of sensitivity of the emulsion thus providing an emulsion of high stability to withstand the adverse effects of aging.Type: GrantFiled: April 26, 1984Date of Patent: April 9, 1985Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshinao Ukai, Masaki Okazaki, Haruo Takei, Ichizo Toya, Sadanobu Syuto
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Patent number: 4501811Abstract: Disclosed is a process for making a lithographic printing plate by utilizing the silver complex diffusion transfer process and using a neon-helium laser or an LED which comprises imagewise exposing to the radiation a photosensitive element including an emulsion layer which is spectrally sensitized with an anion- or betaine-type meso-substituted trimethine cyanine dye having at least one .beta.-naphthothiazole nucleus and developing the element by the silver complex diffusion transfer process.Type: GrantFiled: October 13, 1983Date of Patent: February 26, 1985Assignee: Mitsubishi Paper Mills, Ltd.Inventors: Masahiko Saikawa, Eiji Kanada, Akira Tanaka, Kazunaka Endo
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Patent number: 4387155Abstract: Photosensitive silver halide emulsions containing a green-sensitive dye of the formula ##STR1## wherein R is hydrogen or chlorine. The invention is also directed to the novel sensitizing dyes.Type: GrantFiled: May 26, 1981Date of Patent: June 7, 1983Assignee: Polaroid CorporationInventors: Ruth L. Hill, Roger E. Jerry
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Patent number: 4376817Abstract: Direct-positive photographic material having at least one layer which contains a silver halide emulsion surface-fogged by chemical means or by exposure and a tri-nuclear cyanine dye, which has the formula ##EQU1## in which A.sub.1 is .dbd.CH-- or .dbd.CH--CH.dbd.CH--, Z.sub.1 is a monocyclic or polycyclic heterocyclic radical which is linked by a double bond to the adjacent methine group, Z.sup..sym. is a positively charged radical which is mesomeric to Z.sub.1 and is linked by a single bond to the adjacent methine group, Z.sub.2 --is a nitrogen-heterocyclic radical which has its single positive charge on the nitrogen atom and Z.sub.3 .dbd. is a radical which has no charge on the nitrogen atom and is mesomeric to Z.sub.2, at least one of the radicals Z.sub.Type: GrantFiled: July 27, 1981Date of Patent: March 15, 1983Assignee: Ciba-Geigy AGInventors: Rolf Steiger, Jean F. Reber
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Patent number: 4375508Abstract: Photographic silver halide compositions and elements are provided which are spectrally sensitized with new methine dyes. The dyes are prepared from new intermediate compounds which have an acetylenically unsaturated hydrocarbon chain terminated with a nucleophilic group, the acetylenically unsaturated hydrocarbon chain being bonded to a nitrogen atom in a heterocyclic ring system of the type used in cyanine dyes. The new intermediates also provide alternative synthetic routes to known dyes.Type: GrantFiled: October 15, 1981Date of Patent: March 1, 1983Assignee: Eastman Kodak CompanyInventor: Yasushi S. Yamamoto
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Patent number: 4332889Abstract: A novel heat-activatable and heat-developable dry image forming material comprising (a) a silver salt of long chain fatty acid with at least 16 carbon atoms, (b) a reducing agent for silver ions, (c) a silver halide component including silver iodide or a silver halide-forming component including silver iodide-forming compound, (d) an oxidizing agent for free silver, (e) a photoreactive halogeno oxidizing agent, (f) a binder, and (g) a specific spectral sensitizing dye has been found to have improved spectral sensitivity as well as excellent storage stability.Type: GrantFiled: May 19, 1981Date of Patent: June 1, 1982Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Tetsuo Siga, Shozo Kinoshita, Yoshinobu Ito, Minoru Akiyama
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Patent number: 4326023Abstract: Photographic emulsions are sensitized to the red region of the spectrum with a combination of three sensitizing dyes.Type: GrantFiled: September 15, 1976Date of Patent: April 20, 1982Assignee: Eastman Kodak CompanyInventor: Mary K. DeSeyn
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Patent number: 4308345Abstract: A silver halide photographic emulsion selectively spectrally sensitized, particularly to red light, with a combination of at least one sensitizing dye represented by general formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 each represents the atoms necessary to form a benzothiazole nucleus or a benzoselenazole nucleus, R.sup.1 and R.sup.2 l each represents an alkyl group or a substituted alkyl group, wherein at least one of R.sup.1 or R.sup.2 should represent a sulfo group-containing substituted alkyl group, a carboxyalkyl group or a hydroxyalkyl group, R.sup.3 represents an alkyl group, X.sub.1 represents an acid anion, and m represents 1 or 2, wherein m equals 1 when the dye forms an intramolecular salt (betaine-like structure); at least one sensitizing dye represented by general formula (II): ##STR2## wherein Z.sup.3 represents a sulfur atom or a selenium atom, Z.sup.Type: GrantFiled: October 8, 1976Date of Patent: December 29, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
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Patent number: 4307185Abstract: A silver halide photographic emulsion spectrally sensitized with a sensitizing combination of at least one sensitizing dye represented by General formula (I), at least one sensitizing dye represented by General formula (II) and at least one sensitizing dye represented by General formula (III): ##STR1## wherein Z.sup.1 and Z.sup.2 each is the atoms necessary to form a benzothiazole nucleus or a benzoselenazole nucleus, R.sup.1 and R.sup.2 each is an alkyl group or a substituted alkyl group, wherein at least one of R.sup.1 and R.sup.2 is a substituted alkyl group having a sulfo group, R.sup.3 is an alkyl group, X.sub.1 is an acid anion and m is 1 or 2 and when the dye forms an intermolecular salt (betaine like structure), m is 1; ##STR2## wherein Z.sup.3 is a sulfur atom or a selenium atom, Z.sup.4 is the atoms necessary to form a benzothiazole nucleus, a benzoselenazole nucleus, a naphtho[1,2-d]thiazole nucleus or a naphtho[1,2-d]selenazole nucleus, R.sup.4 and R.sup.Type: GrantFiled: September 3, 1976Date of Patent: December 22, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
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Patent number: 4283488Abstract: Photo-sensitive silver halide compositions and elements are spectrally sensitized with new mathine dyes having a trialkylsilylalkyl group attached to a nitrogen atom in a heterocyclic nucleus of the dye.Type: GrantFiled: August 22, 1980Date of Patent: August 11, 1981Assignee: Eastman Kodak CompanyInventor: Earl J. VanLare
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Patent number: 4263397Abstract: A photographic product comprising, in a package, a light-sensitive silver halide photographic material having a silver halide emulsion layer coated on a support, characterized in that said silver halide emulsion layer contains a sensitizing or desensitizing dye and that the oxygen permeability of the package is below 5.times.10.sup.2 cc/m.sup.2. 24 hrs. atm. under a condition at 20.degree. C. and 0% of relative humidity and further that the sealed package is under a condition that a partial pressure of an oxygen-gas in the package is not more than 1/6 atmospheres at an initial stage.Type: GrantFiled: May 19, 1978Date of Patent: April 21, 1981Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Akira Horikoshi, Zene Kumagai
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Patent number: 4179296Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, a combination ofat least one benzimidazolocarbocyanine dye wherein an aralkyl group substituted with an acidic group is connected to at least one nitrogen atom in the imidazole ring, which is represented by the following general formula (I): ##STR1## wherein V.sub.1, V.sub.2, V.sub.3 and V.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a trifluoromethyl group or a hydroxy group; R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents an aliphatic group; A represents a sulfo group of a carboxy group; X.sub.1 represents an acid residue; h represents an integer from 1 to 6; and i represents 0 or 1; andat least one cyanine dye represented by the following general formula (II): ##STR2## wherein Z.sub.Type: GrantFiled: December 15, 1977Date of Patent: December 18, 1979Assignee: Fuji Photo Film Co., Ltd.Inventors: Akira Sato, Atsuo Iwamoto, Takeo Sakai, Haruo Takei
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Patent number: H674Abstract: A silver halide photographic light-sensitive material comprising a support having the first photographic structural layer comprising one or more layers on a side of the support and the second photographic structural layer comprising one or more layers on the other side of the support, in which at least one of the photographic structural layers comprises a silver halide light-sensitive emulsion layer, and the total amount of gelatin contained in the photographic structural layer comprising the silver halide emulsion layer is within the range of from 2.25 g/m.sup.2 to 3.15 g/m.sup.2. The uppermost layer of the photographic structural layer comprising the silver halide emulsion is formed by coating of a solution having a surface tension of from 15 to 26 dyn/cm, and the second photographic structural layer is coated and gelled simultaneously with coating and drying of the first photographic structural layer.Type: GrantFiled: November 3, 1987Date of Patent: September 5, 1989Assignee: Konica CorporationInventors: Satoru Nagasaki, Akio Suzuki, Eiji Yoshida, Masumi Arai, Nobuaki Tsuji