Stabilizing Or Fog Inhibiting Ingredient Containing Patents (Class 430/607)
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Patent number: 6426181Abstract: The present invention is directed to the use of a mixture of non-light sensitive organic silver salts in a color photothermographic system comprising a blocked developing agent for color imaging. At least one of the organic silver salts is the sole or primary silver donor during thermal development and at least one other organic silver salt, present at levels in the range of 30,000 to 60,000 mg/mol of silver halide, effectively inhibits fog during thermal development of the photothermographic element. In one embodiment, and the system comprises a mixture of at least two organic silver salts, wherein the first organic silver salts exhibits a cLogP of 0.1 to 10 and a Ksp of 7 to 14 and wherein the second organic silver salt exhibits a cLogP of 0.1 to 10 and a Ksp of 14 to 21.Type: GrantFiled: May 23, 2001Date of Patent: July 30, 2002Assignee: Eastman Kodak CompanyInventors: Lyn M. Irving, David H. Levy, Mark E. Irving
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Patent number: 6403293Abstract: A silver halide color photographic light sensitive material is disclosed, comprising a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layers, wherein at least one of the silver halide emulsion layers contains a coupler represented by the following formula:Type: GrantFiled: December 8, 2000Date of Patent: June 11, 2002Assignee: Konica CorporationInventors: Osamu Ishige, Emiko Kataoka, Hiroyuki Hoshino
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Patent number: 6403296Abstract: A color photographic silver halide material containing gelatine, comprising a support and at least one photosensitive silver halide emulsion layer and at least one non-photosensitive layer, which material contains at least one compound of the formula (I) or (II) and is hardened with a vinylsulfonyl compound in which R1, R2, R3, m and n have the meanings stated in the description and wherein two residues R2 or R3 may in each case mean a fused carbo- or heterocyclic ring or the compound of the formula I is attached to a polymer chain via one of the residues R1, R2 or R3, in which R11, R12, R13, R14, o and p have the meanings stated in the description wherein two residues R13 or R14 may in each case mean a fused carbo- or heterocyclic ring or the compound of the formula II is attached to a polymer chain via a residue R13 or R14, is distinguished by improved storage stability.Type: GrantFiled: August 9, 2000Date of Patent: June 11, 2002Assignee: Agfa-GevaertInventors: Jörg Hagemann, Markus Geiger, Heinrich Odenwälder
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Publication number: 20020061483Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising:Type: ApplicationFiled: August 10, 2001Publication date: May 23, 2002Applicant: Eastman Kodak CompanyInventor: Julie Baker
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Publication number: 20020058211Abstract: A photothermographic material is disclosed, comprising a support, a silver halide, an organic silver salt and a reducing agent, wherein the photothermographic material meets the following requirement:Type: ApplicationFiled: March 12, 2001Publication date: May 16, 2002Inventor: Takeshi Sampei
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Patent number: 6387605Abstract: Novel co-developer compounds are useful in combination with hindered phenol developers to produce high contrast black-and-white photothermographic elements. The co-developer compounds have the formula wherein: Y is H, a metal (preferably, an alkali metal), or an alkyl group (preferably, an alkyl group having from 1 to 4 carbon atoms), and the solid curved line represents the atoms and bonds necessary to complete a ring structure (preferably a 5 or 6 membered ring structure). The photothermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.Type: GrantFiled: January 28, 1999Date of Patent: May 14, 2002Assignee: Eastman Kodak CompanyInventors: Doreen C. Lynch, Paul G. Skoug
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Publication number: 20020055068Abstract: In a photothermographic material having an image-forming layer and a protective layer on a support, (A) a nucleating agent having a particular structure is added to at least one of the layers formed on the image-forming layer side of the support and NH4+ content in all the layers formed on the image-forming layer side is controlled to be 0.06 mmol/m2 or less, or (B) a nucleating agent and an organic acid compound having a particular structure are added to at least one of the layers formed on the image-forming layer side so that film surface pH is substantially unchanged. This photothermographic material is characterized by low fog, high Dmax, little increase of fog during storage and little temperature and humidity dependency upon heat development.Type: ApplicationFiled: August 14, 2001Publication date: May 9, 2002Inventor: Tokuju Oikawa
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Patent number: 6383711Abstract: A high contrast photographic material comprises a support bearing a silver halide emulsion layer, containing in the emulsion layer or in an adjacent hydrophilic layer, a hydrazide nucleating agent characterized in that the emulsion layer contains silver halide grains of octahedral character which are spectrally sensitized and silver halide grains which are not octahedral in character eg cubic. Preferably only the grains which are octahedral in character are spectrally sensitized. Preferably the emulsion layer or an adjacent hydrophilic colloid layer contains a booster compound eg an amine rendering the material developable in a developer solution having a pH below 11. Preferably both types of grain are chemically sensitized. The use of tabular grains as causer emulsions enhances the absorption characteristics of the dyes so that as well as providing high photographic sensitivity the dye peaks are broadened.Type: GrantFiled: August 21, 2000Date of Patent: May 7, 2002Assignee: Eastman Kodak CompanyInventors: Jurjen F. Winkel, Michael B. Ledger
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Patent number: 6383731Abstract: The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: wherein Z1 and Z2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.Type: GrantFiled: August 20, 2001Date of Patent: May 7, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Masaru Takasaki, Katsuyuki Watanabe, Hisashi Okamura
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Patent number: 6379880Abstract: A heat-developable photosensitive material having: (a) at least one layer of photosensitive image-forming layer containing an organic silver salt, a photosensitive silver halide, a reducing agent and an organic binder; and (b) a functional layer containing a binder and a solid dispersion; the binder consisting of a water-dispersed thermoplastic resin, and the solid dispersion being made of a precursor of a photographically useful compound capable of releasing the photographically useful compound when heated to 100° C. or higher and not higher than heat development temperature is disclosed.Type: GrantFiled: March 3, 2000Date of Patent: April 30, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazunobu Katoh
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Publication number: 20020048716Abstract: Disclosed in an image recording material comprising, on a support, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following Formula (1): 1Type: ApplicationFiled: July 24, 2001Publication date: April 25, 2002Inventors: Katsuyuki Watanabe, Masaru Takasaki
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Publication number: 20020048734Abstract: The object of the invention is to provide a photothermographic material high in sensitivity and image quality, and excellent in storability in the undeveloped state, which is used for medical images or photomechanical processes.Type: ApplicationFiled: August 14, 2001Publication date: April 25, 2002Inventors: Kouta Fukui, Masaru Takasaki, Katsuyuki Watanabe
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Patent number: 6376167Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following formula R1—SO2—O—L1—COOM1. The photothermographic material may further comprise a compound respresented by following formula: R2—COOM2 or R3—CO—L2—COOM3.Type: GrantFiled: November 6, 2000Date of Patent: April 23, 2002Assignee: Konica CorporationInventor: Hiroto Ito
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Patent number: 6368782Abstract: A photothermographic material comprising, on one side of a support, at least one kind of photosensitive silver halide, a light insensitive silver salt of an organic acid, a reducing agent for silver ions and a binder, wherein the photosensitive silver halide has a mean grain size of 0.001 &mgr;m to 0.06 &mgr;m and the material comprises at least two kinds of organic polyhalogenated compounds at least one of which is an organic polyhalogenated compound represented by the following formula (1): wherein Z1 and Z2 independently represent a halogen atom, X1 represents a hydrogen atom or an electron withdrawing group, Y1 represents —CO— group or —SO2— group, Q represents an arylene group or a divalent heterocyclic group, L represents a bridging group, W1 and W2 independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, and n represents 0 or 1.Type: GrantFiled: August 24, 2000Date of Patent: April 9, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Kouta Fukui, Masaru Takasaki, Katsuyuki Watanabe
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Patent number: 6368778Abstract: Photothermographic materials provide images having improved image stability due to the presence of certain image stabilizing compounds in a silver-containing layer. These image stabilizing compounds are fluorenone, fluorene, coumarin, naphthalic acid imide, pyrazoline, or anthracene compounds. In particular, they reduce image browning that may occur from the presence of various components in the materials.Type: GrantFiled: August 15, 2000Date of Patent: April 9, 2002Assignee: Eastman Kodak CompanyInventors: Steven H. Kong, Paul G. Skoug, Kumars Sakizadeh
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Patent number: 6361920Abstract: A high contrast silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. The photographic material is preferably a graphic arts material for pre-press applications. High gradation and excellent dot quality, exposure latitude and stability on continuous processing are obtained.Type: GrantFiled: September 13, 2000Date of Patent: March 26, 2002Assignee: AGFA GevaertInventors: Johan August Loccufier, Stefaan Lingier, Pascal Frans Meeus
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Patent number: 6355394Abstract: A high contrast silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. The photographic material is preferably a graphic arts material for pre-press applications. High gradation and excellent dot quality, exposure latitude and stability on continuous processing are obtained.Type: GrantFiled: September 7, 2000Date of Patent: March 12, 2002Assignee: Agfa GevaertInventors: Johan August Loccufier, Stefaan Lingier, Pascal Frans Meeus
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Publication number: 20020028414Abstract: A silver salt photothermographic material is disclosed, comprising at least a light sensitive layer and at least a light insensitive layer, the light sensitive layer comprising organic silver salt grains, a light sensitive emulsion containing light sensitive silver halide grains and medium, a reducing agent and a binder, wherein at least one of the light sensitive layer and the light insensitive layer contains a silver-saving agent and the photothermographic material which has been subjected to thermal development at 123° C. for 13.5 sec. exhibits an average contrast of 2.0 to 6.0 within the density range of 0.25 to 2.0 on a characteristic curve of the photothermographic material.Type: ApplicationFiled: June 21, 2001Publication date: March 7, 2002Inventors: Hiroyuki Yanagisawa, Socmen Ho Kimura
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Publication number: 20020028413Abstract: A method for forming a dispersion of an oil-soluble photographically useful compound in water or a hydrophilic colloid composition is disclosed, comprising dispersing the compound in the presence of a water-soluble anionic group containing polymeric surfactant, wherein the polymeric surfactant comprises a copolymer obtained from the copolymerization of a maleic anhydride monomer and a copolymerizable ethylenically unsaturated hydrophobic monomer and the anionic groups of the polymeric surfactant comprise primarily carboxy groups obtained upon base hydrolysis of the anhydride groups of the copolymer. The use of hydrolyzed maleic anhydride derived copolymers in place of conventional small-molecule surfactants as a dispersing agent to stabilize photographically active water-insoluble dye couplers or other organic oil-soluble photographically useful compounds enables a dramatic reduction of crystallization of such organic molecules on long-term keeping.Type: ApplicationFiled: September 5, 2001Publication date: March 7, 2002Applicant: Eastman Kodak CompanyInventors: Julia S. Tan, Kurt M. Schroeder, Delaina A. Amos
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Patent number: 6350569Abstract: A heat-developable photographic material which contains a particular class of polyhalogenated organic compound having a water-soluble group in one or more layers on the side of the image-forming layer. The heat-developable photographic material can be obtained at a low cost and has much reduced fog and excellent storage stability.Type: GrantFiled: March 30, 2000Date of Patent: February 26, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuyuki Watanabe, Hiroyuki Suzuki, Masaru Takasaki, Shigeo Hirano
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Patent number: 6350567Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole-% silver chloride, said emulsion containing an isothiazolone compound represented by the formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring, wherein the isothiazolone compound was added before or during precipitation of the emulsion.Type: GrantFiled: October 7, 1999Date of Patent: February 26, 2002Assignee: Eastman Kodak CompanyInventors: Benjamin T. Chen, Roger L. Klaus, Jeri L. Mount
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Publication number: 20020015926Abstract: Image recording materials, especially photothermographic light-sensitive image recording materials, that comprise a compound of formula (1) to acquire excellent image storage stability: 1Type: ApplicationFiled: June 11, 1999Publication date: February 7, 2002Inventors: TOSHIKI FUJIWARA, RIKIO INOUE
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Patent number: 6344313Abstract: An object of the present invention is to provide a heat-developable photosensitive material of improved fluctuation of photographic performance (sensitivity, Dmin) arisen from fluctuation of development temperature condition (temperature, time) and storage time after heat development.Type: GrantFiled: March 30, 2000Date of Patent: February 5, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Takahiro Goto, Toshihide Ezoe, Hiroyuki Suzuki, Minoru Sakai, Hideki Maeta, Nobuaki Inoue, Masaru Takasaki
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Publication number: 20020009681Abstract: A silver halide photographic lightsensitive material comprises at least one lightsensitive silver halide emulsion layer on a support. The lightsensitive material exhibits a speed at 3×10−9 sec exposure time being lower than a speed at 10−5 sec exposure time by 30 or more in terms of speed unit.Type: ApplicationFiled: March 29, 2001Publication date: January 24, 2002Inventor: Naoharu Kiyoto
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Patent number: 6340562Abstract: A silver halide photographic emulsion, wherein silver halide grains are prepared by adding a compound capable of forming cross-linkage with gelatin to said silver halide grains in any of processes before the completion of chemical sensitization after the formation of the silver halide grains.Type: GrantFiled: February 10, 1999Date of Patent: January 22, 2002Assignee: Konica CorporationInventor: Yasuo Taima
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Patent number: 6331386Abstract: A photothermographic element has a non-photosensitive organic silver salt, a photosensitive silver halide, and a binder on a support. A polymer latex constitutes at least 50% by weight of the binder in an image forming layer containing the photosensitive silver halide. The image forming layer has been formed by applying a coating solution in which at least 60% by weight of a solvent is water. The image forming layer contains a specific compound as a nucleating agent and has been formed by applying a coating solution having added thereto a water dispersion of the compound. The element exhibits a high contrast, long-term storage stability, and no increase of Dmin upon printing to PS plates.Type: GrantFiled: April 28, 1999Date of Patent: December 18, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshihide Ezoe, Kohzaburoh Yamada
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Publication number: 20010051319Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing agent represented by the following formula (1), (d) a binder, and (e) a phenol compound represented by the following formula (2) on the same side of a support: 1Type: ApplicationFiled: March 16, 2001Publication date: December 13, 2001Inventors: Toyohisa Oya, Kazunobu Katoh
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Patent number: 6329132Abstract: In a method of preparing a silver halide photographic emulsion by performing spectral sensitization by adding a cyanine dye during or before chemical sensitization, a substantially insoluble silver iodobromide fine-grain emulsion is added during or after chemical sensitization of the silver halide photographic emulsion.Type: GrantFiled: December 12, 1995Date of Patent: December 11, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Mikio Ihama
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Patent number: 6326135Abstract: This invention concerns a non-spectral sensitized radiographic product for exposure to ionizing radiation of energy equal to at least 40 keV containing at least 50 mg/dm2, which comprises a support covered with on at least one of its sides with a layer of silver halide emulsion in which at least 50% of the grains are tabular grains, and at least 0.05 mmol/mol Ag of a compound of formula wherein R1 and R2 are each independently an atom of hydrogen, an alkyl group comprising from 1 to 5 atoms of carbon, substituted or not, a hydroxyl group, or a benzyl group; R3 and R4 are each independently a hydrogen, or an alkyl group from 1 to 5 atoms of carbon, or jointly comprise the atoms necessary to form a heterocycle of 4 to 6 atoms, substituted or not. The product for industrial radiography of the invention provides an improved keeping of the latent image and higher speed.Type: GrantFiled: May 4, 1999Date of Patent: December 4, 2001Assignee: Eastman Kodak CompanyInventors: Gerard M. Droin, Jacques Roussilhe
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Patent number: 6319640Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.Type: GrantFiled: November 13, 2000Date of Patent: November 20, 2001Assignee: Eastman Kodak CompanyInventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
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Patent number: 6316177Abstract: Disclosed is a color silver halide photographic element comprising a light-sensitive silver halide emulsion layer or a non-silver containing light-insensitive layer, said light-sensitive or light-insensitive layer containing a polymer compound comprising a heterocycle unit derived from: (a) a heterocycle monomer (1) comprising two or more annulated rings containing, in total, a minimum of three ring heteroatoms of which no more than two of the heteroatoms are connected in sequence to each other and (2) having a ClogP less than 6.2; or (b) a monocyclic heterocycle monomer having exactly three ring heteroatoms and having a ClogP less than 8.75; with the proviso that the heterocycle unit does not contain a hydroxy or mercapto group (or their tautomeric equivalent), and does not react with oxidized developer; and the amount of the polymer compound in the element being sufficient to increase the photographic speed of the element compared to the same element without the compound.Type: GrantFiled: March 31, 2000Date of Patent: November 13, 2001Assignee: Eastman Kodak CompanyInventors: Philip A. Allway, Tienteh Chen, David S. Ross, Stephen P. Singer
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Publication number: 20010038977Abstract: A heat-developable image-recording material comprising, on a support, a silver-supplying layer containing an organic silver salt, a reducing agent and an organic binder, and a separate photosensitive layer containing a photosensitive silver halide, the heat-developable image-recording material further containing an electron-transfer agent; and a method for forming an image by heat development comprising; imagewise exposing the heat-developable image-recording material and then heat-developing, whereby development of the photosensitive layer forms a silver image in the silver-supplying layer.Type: ApplicationFiled: January 24, 2001Publication date: November 8, 2001Inventor: Kazunobu Katoh
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Patent number: 6309811Abstract: Disclosed is a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a compound with an aromatic bicyclic nitrogen nucleus of which at least one ring is six-membered and with two nitrogen ring atoms in each ring and with at least one N—H bond provided that the ClogP for the compound is at least 2.0 and less than 7.2; and (b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula III: COUP-(TIME)j-INH III wherein: COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; TIME is a timing group and j is 0,1 or 2; and INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.Type: GrantFiled: July 21, 1999Date of Patent: October 30, 2001Assignee: Eastman Kodak CompanyInventors: Philip A. Allway, Louis E. Friedrich, Stephen P. Singer
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Patent number: 6309814Abstract: A heat developable photosensitive material having on a support a non-photosensitive sliver salt, a photosensitive sliver halide, and a binder, which has an image forming layer containing the photosensitive sliver halide and comprises cyclic ketone or cyclic imine compound having a specific structure in combination with a nucleation agent on the side that the image forming layer is formed. This heat developable photosensitive material is an excellent high contrast sensitive material having a good stability.Type: GrantFiled: February 1, 2000Date of Patent: October 30, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Tadashi Ito
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Patent number: 6306570Abstract: A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment of the invention, the radical X• has an oxidation potential ≦−0.7 V.Type: GrantFiled: March 27, 2000Date of Patent: October 23, 2001Assignee: Eastman Kodak CompanyInventors: Anthony Adin, Jerome J. Looker, Samir Y. Farid, Ian R. Gould, Stephen A. Godleski, Jerome R. Lenhard, Annabel A. Muenter, Lal C. Vishwakarma, Paul A. Zielinski
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Patent number: 6306551Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein the substituents are as defined in the specification.Type: GrantFiled: December 30, 1999Date of Patent: October 23, 2001Assignee: Eastman Kodak CompanyInventors: Zbyslaw R. Owczarczyk, Xiqiang Yang, David H. Levy, Mark E. Irving
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Publication number: 20010031435Abstract: A photosensitive element comprising a silver halide emulsion having silver halide grains containing an organic hole-trapping dopant.Type: ApplicationFiled: May 29, 2001Publication date: October 18, 2001Applicant: Agfa-GevaertInventors: Rene De Keyzer, Mona Treguer, Jacqueline Belloni, Hynd Remita
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Publication number: 20010029000Abstract: A photothermographic material comprising a defined amount of a compound represented by the following general formula as a reducing agent is disclosed. In the following general formula, R1 and R1′ each independently represent an alkyl group, at least one of which is a secondary or tertiary alkyl group; R2 and R2′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring; L represents —S— group or a —CH(R3)— group where R3 represents hydrogen atom or an alkyl group; and X and X′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring. The photothermographic material is characterized by providing sufficient image density by heat development, and showing good silver color tone and little change with time after the development.Type: ApplicationFiled: January 5, 2001Publication date: October 11, 2001Inventors: Yasuhiro Yoshioka, Kouta Fukui, Makoto Suzuki
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Patent number: 6300044Abstract: A production method for a photothermographic recording material comprising the steps of: (i) providing a support; (ii) coating the support with a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, characterized in that the photosensitive silver halide is formed by reacting an aqueous emulsion of particles of the substantially light-insensitive organic silver salt with at least one onium salt with halide or polyhalide anion(s) and that the photo-addressable thermally developable element is coated from an aqueous dispersion medium; and a recording process therefor.Type: GrantFiled: June 18, 1999Date of Patent: October 9, 2001Assignee: Agfa-GevaertInventors: Herman Uytterhoeven, Yvan Gilliams, Johan Loccufier, Sabine Emmers, Ronny De Clercq
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Patent number: 6297001Abstract: A photothermographic material is disclosed, comprising a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent a binder and a cross-linking agent; the photothermographic material further comprising a compound capable of generating a labile species other than a halogen atom upon exposure to ultraviolet radiation or visible radiation to deactivate the reducing agent.Type: GrantFiled: February 28, 2000Date of Patent: October 2, 2001Assignee: Konica CorporationInventors: Hideki Takiguchi, Katsura Hirai
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Publication number: 20010021493Abstract: A photothermographic material comprising, on one surface of a support, at least one kind of photosensitive silver halide, a silver salt of an organic acid, a reducing agent for silver ions, and a binder, wherein (1) said material further comprises two or more kinds of organic polyhalogenated compounds, and (2) a melting point of a mixture which consists of the organic polyhalogenated compounds in the same content ratio as the content ratio of said compounds in the photothermographic material is in the range of from −10° C. to 50° C. relative to a heat development temperature for the photothermographic material. The photothermographic material of the present invention shows high sensitivity and superior storability before heat development, and the material can be used for medical images, photoengraving and the like.Type: ApplicationFiled: January 11, 2001Publication date: September 13, 2001Inventor: Kouta Fukui
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Patent number: 6284447Abstract: A color photographic silver halide material which is developed as a negative, at least 90 mol % of the silver halides of which consist of AgCl, and which contains a compound of formula (I) or formula (II) in a light-insensitive layer which is further from the support than is each light—light sensitive layer, is distinguished by its improved color reproduction.Type: GrantFiled: April 7, 2000Date of Patent: September 4, 2001Assignee: Agfa-GevaertInventors: Cuong Ly, Dieter Rockser, Edgar Draber, Markus Geiger, Jürgen Heinecke, Randolph Trommer
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Patent number: 6277554Abstract: In a thermographic recording element comprising an organic silver salt, a photosensitive silver halide, and a reducing agent, there are further included a specific compound and a hydrazine derivative. The element exhibits a high contrast and the minimized dependency of photographic properties on developing temperature.Type: GrantFiled: May 11, 1999Date of Patent: August 21, 2001Assignee: Fuji Photo Film, Co., Ltd.Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe
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Patent number: 6274302Abstract: A photothermographic element comprising on a support (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing agent, (d) an ultrahigh contrast-providing agent, (e) a binder, (f) a specific salicylic acid type antifoggant, and optionally (g) phosphoric acid or a salt thereof has a low fog, high sensitivity, high contrast, and storage stability.Type: GrantFiled: May 14, 1999Date of Patent: August 14, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsuyuki Watanabe, Kouta Fukui
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Publication number: 20010010895Abstract: Disclosed is a color photographic element comprising:Type: ApplicationFiled: July 21, 1999Publication date: August 2, 2001Inventors: PHILIP A. ALLWAY, LOUIS E. FRIEDRICH, STEPHEN P. SINGER
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Patent number: 6258518Abstract: A silver halide photosensitive material comprises a compound represented by formula (S1): wherein R1 represents a substituent group, n represents an integer from 0 to 4, R2 and R3 can be the same or different and represent a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group.Type: GrantFiled: March 30, 1999Date of Patent: July 10, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Masato Taniguchi, Hideo Ikeda
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Patent number: 6258521Abstract: There is disclosed a silver halide color photographic light-sensitive material that is improved in such aspects as fastness of dye images, color reproduction, cyan stain, processing cyan color contamination, and the like, by the combination use of a phenidone compound having a specific structure as in the following general formula (VIII) and a pyrrolotriazole cyan coupler. The phenidone compound (VIII) can be produced industrially in low cost, by reacting an &agr;-alkyl or alkenyl acrylate with a compound represented by the following general formula (VII): wherein, R4, R5, R6, R7, R8, and R9, each represent a hydrogen atom, an alkyl group, or the like; R2a represents an alkyl group having 6 to 30 carbon atoms, or the like.Type: GrantFiled: September 24, 1998Date of Patent: July 10, 2001Assignee: Fuji Photo Film, Co., Ltd.Inventors: Hisashi Mikoshiba, Yasuhiro Yoshioka, Shin Soejima, Osamu Takahashi, Naoki Saito, Masakazu Morigaki
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Patent number: 6248512Abstract: An image forming method for a thermally processable photosensitive material is disclosed, comprising exposing a thermally processable photosensitive material to light using a laser light source, and subjecting the exposed photosensitive material to thermal processing, wherein the thermally processable photosensitive material comprises a support having thereon an organic silver salt, a binder, a photosensitive silver halide, and a compound containing nitrogen covalently bonded to halogen represented by the following formula or a nitrogen-containing acyclic compound associated with a pair of halogen atoms represented by the following formulaType: GrantFiled: April 8, 1999Date of Patent: June 19, 2001Assignee: Konica CorporationInventors: Norio Miura, Keiko Ishidai
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Patent number: 6245497Abstract: A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.Type: GrantFiled: December 20, 1999Date of Patent: June 12, 2001Assignee: Eastman Kodak CompanyInventors: Jon N. Eikenberry, David T. Southby
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Patent number: 6242170Abstract: This invention provides a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises large tabular grains having an average equivalent circular diameter of greater than 3 &mgr;m and contains a one equivalent image dye-forming coupler and a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton HType: GrantFiled: December 20, 1999Date of Patent: June 5, 2001Assignee: Eastman Kodak CompanyInventors: Joseph P. Pepe, Jeffrey C. Hansen, James A. Friday, Annabel A. Muenter, David T. Southby