Stabilizing Or Fog Inhibiting Ingredient Containing Patents (Class 430/607)
  • Patent number: 6426181
    Abstract: The present invention is directed to the use of a mixture of non-light sensitive organic silver salts in a color photothermographic system comprising a blocked developing agent for color imaging. At least one of the organic silver salts is the sole or primary silver donor during thermal development and at least one other organic silver salt, present at levels in the range of 30,000 to 60,000 mg/mol of silver halide, effectively inhibits fog during thermal development of the photothermographic element. In one embodiment, and the system comprises a mixture of at least two organic silver salts, wherein the first organic silver salts exhibits a cLogP of 0.1 to 10 and a Ksp of 7 to 14 and wherein the second organic silver salt exhibits a cLogP of 0.1 to 10 and a Ksp of 14 to 21.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: July 30, 2002
    Assignee: Eastman Kodak Company
    Inventors: Lyn M. Irving, David H. Levy, Mark E. Irving
  • Patent number: 6403293
    Abstract: A silver halide color photographic light sensitive material is disclosed, comprising a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layers, wherein at least one of the silver halide emulsion layers contains a coupler represented by the following formula:
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: June 11, 2002
    Assignee: Konica Corporation
    Inventors: Osamu Ishige, Emiko Kataoka, Hiroyuki Hoshino
  • Patent number: 6403296
    Abstract: A color photographic silver halide material containing gelatine, comprising a support and at least one photosensitive silver halide emulsion layer and at least one non-photosensitive layer, which material contains at least one compound of the formula (I) or (II) and is hardened with a vinylsulfonyl compound in which R1, R2, R3, m and n have the meanings stated in the description and wherein two residues R2 or R3 may in each case mean a fused carbo- or heterocyclic ring or the compound of the formula I is attached to a polymer chain via one of the residues R1, R2 or R3, in which R11, R12, R13, R14, o and p have the meanings stated in the description wherein two residues R13 or R14 may in each case mean a fused carbo- or heterocyclic ring or the compound of the formula II is attached to a polymer chain via a residue R13 or R14, is distinguished by improved storage stability.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: June 11, 2002
    Assignee: Agfa-Gevaert
    Inventors: Jörg Hagemann, Markus Geiger, Heinrich Odenwälder
  • Publication number: 20020061483
    Abstract: A black and white graphic arts film comprising a support having thereon at least one emulsion layer, said emulsion layer comprising:
    Type: Application
    Filed: August 10, 2001
    Publication date: May 23, 2002
    Applicant: Eastman Kodak Company
    Inventor: Julie Baker
  • Publication number: 20020058211
    Abstract: A photothermographic material is disclosed, comprising a support, a silver halide, an organic silver salt and a reducing agent, wherein the photothermographic material meets the following requirement:
    Type: Application
    Filed: March 12, 2001
    Publication date: May 16, 2002
    Inventor: Takeshi Sampei
  • Patent number: 6387605
    Abstract: Novel co-developer compounds are useful in combination with hindered phenol developers to produce high contrast black-and-white photothermographic elements. The co-developer compounds have the formula wherein: Y is H, a metal (preferably, an alkali metal), or an alkyl group (preferably, an alkyl group having from 1 to 4 carbon atoms), and the solid curved line represents the atoms and bonds necessary to complete a ring structure (preferably a 5 or 6 membered ring structure). The photothermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: January 28, 1999
    Date of Patent: May 14, 2002
    Assignee: Eastman Kodak Company
    Inventors: Doreen C. Lynch, Paul G. Skoug
  • Publication number: 20020055068
    Abstract: In a photothermographic material having an image-forming layer and a protective layer on a support, (A) a nucleating agent having a particular structure is added to at least one of the layers formed on the image-forming layer side of the support and NH4+ content in all the layers formed on the image-forming layer side is controlled to be 0.06 mmol/m2 or less, or (B) a nucleating agent and an organic acid compound having a particular structure are added to at least one of the layers formed on the image-forming layer side so that film surface pH is substantially unchanged. This photothermographic material is characterized by low fog, high Dmax, little increase of fog during storage and little temperature and humidity dependency upon heat development.
    Type: Application
    Filed: August 14, 2001
    Publication date: May 9, 2002
    Inventor: Tokuju Oikawa
  • Patent number: 6383711
    Abstract: A high contrast photographic material comprises a support bearing a silver halide emulsion layer, containing in the emulsion layer or in an adjacent hydrophilic layer, a hydrazide nucleating agent characterized in that the emulsion layer contains silver halide grains of octahedral character which are spectrally sensitized and silver halide grains which are not octahedral in character eg cubic. Preferably only the grains which are octahedral in character are spectrally sensitized. Preferably the emulsion layer or an adjacent hydrophilic colloid layer contains a booster compound eg an amine rendering the material developable in a developer solution having a pH below 11. Preferably both types of grain are chemically sensitized. The use of tabular grains as causer emulsions enhances the absorption characteristics of the dyes so that as well as providing high photographic sensitivity the dye peaks are broadened.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: May 7, 2002
    Assignee: Eastman Kodak Company
    Inventors: Jurjen F. Winkel, Michael B. Ledger
  • Patent number: 6383731
    Abstract: The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: wherein Z1 and Z2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: May 7, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaru Takasaki, Katsuyuki Watanabe, Hisashi Okamura
  • Patent number: 6379880
    Abstract: A heat-developable photosensitive material having: (a) at least one layer of photosensitive image-forming layer containing an organic silver salt, a photosensitive silver halide, a reducing agent and an organic binder; and (b) a functional layer containing a binder and a solid dispersion; the binder consisting of a water-dispersed thermoplastic resin, and the solid dispersion being made of a precursor of a photographically useful compound capable of releasing the photographically useful compound when heated to 100° C. or higher and not higher than heat development temperature is disclosed.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: April 30, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Publication number: 20020048716
    Abstract: Disclosed in an image recording material comprising, on a support, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following Formula (1): 1
    Type: Application
    Filed: July 24, 2001
    Publication date: April 25, 2002
    Inventors: Katsuyuki Watanabe, Masaru Takasaki
  • Publication number: 20020048734
    Abstract: The object of the invention is to provide a photothermographic material high in sensitivity and image quality, and excellent in storability in the undeveloped state, which is used for medical images or photomechanical processes.
    Type: Application
    Filed: August 14, 2001
    Publication date: April 25, 2002
    Inventors: Kouta Fukui, Masaru Takasaki, Katsuyuki Watanabe
  • Patent number: 6376167
    Abstract: A photothermographic material is disclosed, comprising on a support an organic silver salt, a photosensitive silver halide, a reducing agent, a binder and a compound represented by the following formula R1—SO2—O—L1—COOM1. The photothermographic material may further comprise a compound respresented by following formula: R2—COOM2 or R3—CO—L2—COOM3.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: April 23, 2002
    Assignee: Konica Corporation
    Inventor: Hiroto Ito
  • Patent number: 6368782
    Abstract: A photothermographic material comprising, on one side of a support, at least one kind of photosensitive silver halide, a light insensitive silver salt of an organic acid, a reducing agent for silver ions and a binder, wherein the photosensitive silver halide has a mean grain size of 0.001 &mgr;m to 0.06 &mgr;m and the material comprises at least two kinds of organic polyhalogenated compounds at least one of which is an organic polyhalogenated compound represented by the following formula (1): wherein Z1 and Z2 independently represent a halogen atom, X1 represents a hydrogen atom or an electron withdrawing group, Y1 represents —CO— group or —SO2— group, Q represents an arylene group or a divalent heterocyclic group, L represents a bridging group, W1 and W2 independently represent a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, and n represents 0 or 1.
    Type: Grant
    Filed: August 24, 2000
    Date of Patent: April 9, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Masaru Takasaki, Katsuyuki Watanabe
  • Patent number: 6368778
    Abstract: Photothermographic materials provide images having improved image stability due to the presence of certain image stabilizing compounds in a silver-containing layer. These image stabilizing compounds are fluorenone, fluorene, coumarin, naphthalic acid imide, pyrazoline, or anthracene compounds. In particular, they reduce image browning that may occur from the presence of various components in the materials.
    Type: Grant
    Filed: August 15, 2000
    Date of Patent: April 9, 2002
    Assignee: Eastman Kodak Company
    Inventors: Steven H. Kong, Paul G. Skoug, Kumars Sakizadeh
  • Patent number: 6361920
    Abstract: A high contrast silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. The photographic material is preferably a graphic arts material for pre-press applications. High gradation and excellent dot quality, exposure latitude and stability on continuous processing are obtained.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: March 26, 2002
    Assignee: AGFA Gevaert
    Inventors: Johan August Loccufier, Stefaan Lingier, Pascal Frans Meeus
  • Patent number: 6355394
    Abstract: A high contrast silver halide photographic material is disclosed containing a new type of hydrazide compound represented by following general formula I, the different symbols of which are defined in the description. The photographic material is preferably a graphic arts material for pre-press applications. High gradation and excellent dot quality, exposure latitude and stability on continuous processing are obtained.
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: March 12, 2002
    Assignee: Agfa Gevaert
    Inventors: Johan August Loccufier, Stefaan Lingier, Pascal Frans Meeus
  • Publication number: 20020028414
    Abstract: A silver salt photothermographic material is disclosed, comprising at least a light sensitive layer and at least a light insensitive layer, the light sensitive layer comprising organic silver salt grains, a light sensitive emulsion containing light sensitive silver halide grains and medium, a reducing agent and a binder, wherein at least one of the light sensitive layer and the light insensitive layer contains a silver-saving agent and the photothermographic material which has been subjected to thermal development at 123° C. for 13.5 sec. exhibits an average contrast of 2.0 to 6.0 within the density range of 0.25 to 2.0 on a characteristic curve of the photothermographic material.
    Type: Application
    Filed: June 21, 2001
    Publication date: March 7, 2002
    Inventors: Hiroyuki Yanagisawa, Socmen Ho Kimura
  • Publication number: 20020028413
    Abstract: A method for forming a dispersion of an oil-soluble photographically useful compound in water or a hydrophilic colloid composition is disclosed, comprising dispersing the compound in the presence of a water-soluble anionic group containing polymeric surfactant, wherein the polymeric surfactant comprises a copolymer obtained from the copolymerization of a maleic anhydride monomer and a copolymerizable ethylenically unsaturated hydrophobic monomer and the anionic groups of the polymeric surfactant comprise primarily carboxy groups obtained upon base hydrolysis of the anhydride groups of the copolymer. The use of hydrolyzed maleic anhydride derived copolymers in place of conventional small-molecule surfactants as a dispersing agent to stabilize photographically active water-insoluble dye couplers or other organic oil-soluble photographically useful compounds enables a dramatic reduction of crystallization of such organic molecules on long-term keeping.
    Type: Application
    Filed: September 5, 2001
    Publication date: March 7, 2002
    Applicant: Eastman Kodak Company
    Inventors: Julia S. Tan, Kurt M. Schroeder, Delaina A. Amos
  • Patent number: 6350569
    Abstract: A heat-developable photographic material which contains a particular class of polyhalogenated organic compound having a water-soluble group in one or more layers on the side of the image-forming layer. The heat-developable photographic material can be obtained at a low cost and has much reduced fog and excellent storage stability.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: February 26, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuyuki Watanabe, Hiroyuki Suzuki, Masaru Takasaki, Shigeo Hirano
  • Patent number: 6350567
    Abstract: A silver halide photographic element comprising a silver halide emulsion which is greater than 50 mole-% silver chloride, said emulsion containing an isothiazolone compound represented by the formula wherein R1 is a substituent; and Z contains the carbon atoms necessary to form a substituted or unsubstituted non-aromatic ring, wherein the isothiazolone compound was added before or during precipitation of the emulsion.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: February 26, 2002
    Assignee: Eastman Kodak Company
    Inventors: Benjamin T. Chen, Roger L. Klaus, Jeri L. Mount
  • Publication number: 20020015926
    Abstract: Image recording materials, especially photothermographic light-sensitive image recording materials, that comprise a compound of formula (1) to acquire excellent image storage stability: 1
    Type: Application
    Filed: June 11, 1999
    Publication date: February 7, 2002
    Inventors: TOSHIKI FUJIWARA, RIKIO INOUE
  • Patent number: 6344313
    Abstract: An object of the present invention is to provide a heat-developable photosensitive material of improved fluctuation of photographic performance (sensitivity, Dmin) arisen from fluctuation of development temperature condition (temperature, time) and storage time after heat development.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: February 5, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takahiro Goto, Toshihide Ezoe, Hiroyuki Suzuki, Minoru Sakai, Hideki Maeta, Nobuaki Inoue, Masaru Takasaki
  • Publication number: 20020009681
    Abstract: A silver halide photographic lightsensitive material comprises at least one lightsensitive silver halide emulsion layer on a support. The lightsensitive material exhibits a speed at 3×10−9 sec exposure time being lower than a speed at 10−5 sec exposure time by 30 or more in terms of speed unit.
    Type: Application
    Filed: March 29, 2001
    Publication date: January 24, 2002
    Inventor: Naoharu Kiyoto
  • Patent number: 6340562
    Abstract: A silver halide photographic emulsion, wherein silver halide grains are prepared by adding a compound capable of forming cross-linkage with gelatin to said silver halide grains in any of processes before the completion of chemical sensitization after the formation of the silver halide grains.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: January 22, 2002
    Assignee: Konica Corporation
    Inventor: Yasuo Taima
  • Patent number: 6331386
    Abstract: A photothermographic element has a non-photosensitive organic silver salt, a photosensitive silver halide, and a binder on a support. A polymer latex constitutes at least 50% by weight of the binder in an image forming layer containing the photosensitive silver halide. The image forming layer has been formed by applying a coating solution in which at least 60% by weight of a solvent is water. The image forming layer contains a specific compound as a nucleating agent and has been formed by applying a coating solution having added thereto a water dispersion of the compound. The element exhibits a high contrast, long-term storage stability, and no increase of Dmin upon printing to PS plates.
    Type: Grant
    Filed: April 28, 1999
    Date of Patent: December 18, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihide Ezoe, Kohzaburoh Yamada
  • Publication number: 20010051319
    Abstract: A photothermographic material comprising at least (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing agent represented by the following formula (1), (d) a binder, and (e) a phenol compound represented by the following formula (2) on the same side of a support: 1
    Type: Application
    Filed: March 16, 2001
    Publication date: December 13, 2001
    Inventors: Toyohisa Oya, Kazunobu Katoh
  • Patent number: 6329132
    Abstract: In a method of preparing a silver halide photographic emulsion by performing spectral sensitization by adding a cyanine dye during or before chemical sensitization, a substantially insoluble silver iodobromide fine-grain emulsion is added during or after chemical sensitization of the silver halide photographic emulsion.
    Type: Grant
    Filed: December 12, 1995
    Date of Patent: December 11, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mikio Ihama
  • Patent number: 6326135
    Abstract: This invention concerns a non-spectral sensitized radiographic product for exposure to ionizing radiation of energy equal to at least 40 keV containing at least 50 mg/dm2, which comprises a support covered with on at least one of its sides with a layer of silver halide emulsion in which at least 50% of the grains are tabular grains, and at least 0.05 mmol/mol Ag of a compound of formula wherein R1 and R2 are each independently an atom of hydrogen, an alkyl group comprising from 1 to 5 atoms of carbon, substituted or not, a hydroxyl group, or a benzyl group; R3 and R4 are each independently a hydrogen, or an alkyl group from 1 to 5 atoms of carbon, or jointly comprise the atoms necessary to form a heterocycle of 4 to 6 atoms, substituted or not. The product for industrial radiography of the invention provides an improved keeping of the latent image and higher speed.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: December 4, 2001
    Assignee: Eastman Kodak Company
    Inventors: Gerard M. Droin, Jacques Roussilhe
  • Patent number: 6319640
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: November 20, 2001
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, David H. Levy
  • Patent number: 6316177
    Abstract: Disclosed is a color silver halide photographic element comprising a light-sensitive silver halide emulsion layer or a non-silver containing light-insensitive layer, said light-sensitive or light-insensitive layer containing a polymer compound comprising a heterocycle unit derived from: (a) a heterocycle monomer (1) comprising two or more annulated rings containing, in total, a minimum of three ring heteroatoms of which no more than two of the heteroatoms are connected in sequence to each other and (2) having a ClogP less than 6.2; or (b) a monocyclic heterocycle monomer having exactly three ring heteroatoms and having a ClogP less than 8.75; with the proviso that the heterocycle unit does not contain a hydroxy or mercapto group (or their tautomeric equivalent), and does not react with oxidized developer; and the amount of the polymer compound in the element being sufficient to increase the photographic speed of the element compared to the same element without the compound.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: November 13, 2001
    Assignee: Eastman Kodak Company
    Inventors: Philip A. Allway, Tienteh Chen, David S. Ross, Stephen P. Singer
  • Publication number: 20010038977
    Abstract: A heat-developable image-recording material comprising, on a support, a silver-supplying layer containing an organic silver salt, a reducing agent and an organic binder, and a separate photosensitive layer containing a photosensitive silver halide, the heat-developable image-recording material further containing an electron-transfer agent; and a method for forming an image by heat development comprising; imagewise exposing the heat-developable image-recording material and then heat-developing, whereby development of the photosensitive layer forms a silver image in the silver-supplying layer.
    Type: Application
    Filed: January 24, 2001
    Publication date: November 8, 2001
    Inventor: Kazunobu Katoh
  • Patent number: 6309811
    Abstract: Disclosed is a color photographic element comprising: a) a first light sensitive silver halide emulsion layer containing a compound with an aromatic bicyclic nitrogen nucleus of which at least one ring is six-membered and with two nitrogen ring atoms in each ring and with at least one N—H bond provided that the ClogP for the compound is at least 2.0 and less than 7.2; and (b) a second light sensitive silver halide emulsion layer, having a spectral sensitivity different from that of the first light sensitive silver halide emulsion layer, containing a compound of Formula III: COUP-(TIME)j-INH  III  wherein: COUP is a coupler parent group capable of forming a dye upon reaction with an oxidized developer; TIME is a timing group and j is 0,1 or 2; and INH is a mild silver development inhibitor fragment. The invention provides improved color reproduction.
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: October 30, 2001
    Assignee: Eastman Kodak Company
    Inventors: Philip A. Allway, Louis E. Friedrich, Stephen P. Singer
  • Patent number: 6309814
    Abstract: A heat developable photosensitive material having on a support a non-photosensitive sliver salt, a photosensitive sliver halide, and a binder, which has an image forming layer containing the photosensitive sliver halide and comprises cyclic ketone or cyclic imine compound having a specific structure in combination with a nucleation agent on the side that the image forming layer is formed. This heat developable photosensitive material is an excellent high contrast sensitive material having a good stability.
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: October 30, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tadashi Ito
  • Patent number: 6306570
    Abstract: A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment of the invention, the radical X• has an oxidation potential ≦−0.7 V.
    Type: Grant
    Filed: March 27, 2000
    Date of Patent: October 23, 2001
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Jerome J. Looker, Samir Y. Farid, Ian R. Gould, Stephen A. Godleski, Jerome R. Lenhard, Annabel A. Muenter, Lal C. Vishwakarma, Paul A. Zielinski
  • Patent number: 6306551
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein the substituents are as defined in the specification.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: October 23, 2001
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owczarczyk, Xiqiang Yang, David H. Levy, Mark E. Irving
  • Publication number: 20010031435
    Abstract: A photosensitive element comprising a silver halide emulsion having silver halide grains containing an organic hole-trapping dopant.
    Type: Application
    Filed: May 29, 2001
    Publication date: October 18, 2001
    Applicant: Agfa-Gevaert
    Inventors: Rene De Keyzer, Mona Treguer, Jacqueline Belloni, Hynd Remita
  • Publication number: 20010029000
    Abstract: A photothermographic material comprising a defined amount of a compound represented by the following general formula as a reducing agent is disclosed. In the following general formula, R1 and R1′ each independently represent an alkyl group, at least one of which is a secondary or tertiary alkyl group; R2 and R2′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring; L represents —S— group or a —CH(R3)— group where R3 represents hydrogen atom or an alkyl group; and X and X′ each independently represent hydrogen atom or a group that can be a substituent on benzene ring. The photothermographic material is characterized by providing sufficient image density by heat development, and showing good silver color tone and little change with time after the development.
    Type: Application
    Filed: January 5, 2001
    Publication date: October 11, 2001
    Inventors: Yasuhiro Yoshioka, Kouta Fukui, Makoto Suzuki
  • Patent number: 6300044
    Abstract: A production method for a photothermographic recording material comprising the steps of: (i) providing a support; (ii) coating the support with a photo-addressable thermally developable element comprising a substantially light-insensitive organic silver salt, photosensitive silver halide in catalytic association with the substantially light-insensitive organic silver salt, a reducing agent in thermal working relationship with the substantially light-insensitive organic silver salt and a binder, characterized in that the photosensitive silver halide is formed by reacting an aqueous emulsion of particles of the substantially light-insensitive organic silver salt with at least one onium salt with halide or polyhalide anion(s) and that the photo-addressable thermally developable element is coated from an aqueous dispersion medium; and a recording process therefor.
    Type: Grant
    Filed: June 18, 1999
    Date of Patent: October 9, 2001
    Assignee: Agfa-Gevaert
    Inventors: Herman Uytterhoeven, Yvan Gilliams, Johan Loccufier, Sabine Emmers, Ronny De Clercq
  • Patent number: 6297001
    Abstract: A photothermographic material is disclosed, comprising a non-photosensitive organic silver salt, a photosensitive silver halide, a reducing agent a binder and a cross-linking agent; the photothermographic material further comprising a compound capable of generating a labile species other than a halogen atom upon exposure to ultraviolet radiation or visible radiation to deactivate the reducing agent.
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: October 2, 2001
    Assignee: Konica Corporation
    Inventors: Hideki Takiguchi, Katsura Hirai
  • Publication number: 20010021493
    Abstract: A photothermographic material comprising, on one surface of a support, at least one kind of photosensitive silver halide, a silver salt of an organic acid, a reducing agent for silver ions, and a binder, wherein (1) said material further comprises two or more kinds of organic polyhalogenated compounds, and (2) a melting point of a mixture which consists of the organic polyhalogenated compounds in the same content ratio as the content ratio of said compounds in the photothermographic material is in the range of from −10° C. to 50° C. relative to a heat development temperature for the photothermographic material. The photothermographic material of the present invention shows high sensitivity and superior storability before heat development, and the material can be used for medical images, photoengraving and the like.
    Type: Application
    Filed: January 11, 2001
    Publication date: September 13, 2001
    Inventor: Kouta Fukui
  • Patent number: 6284447
    Abstract: A color photographic silver halide material which is developed as a negative, at least 90 mol % of the silver halides of which consist of AgCl, and which contains a compound of formula (I) or formula (II) in a light-insensitive layer which is further from the support than is each light—light sensitive layer, is distinguished by its improved color reproduction.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: September 4, 2001
    Assignee: Agfa-Gevaert
    Inventors: Cuong Ly, Dieter Rockser, Edgar Draber, Markus Geiger, Jürgen Heinecke, Randolph Trommer
  • Patent number: 6277554
    Abstract: In a thermographic recording element comprising an organic silver salt, a photosensitive silver halide, and a reducing agent, there are further included a specific compound and a hydrazine derivative. The element exhibits a high contrast and the minimized dependency of photographic properties on developing temperature.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: August 21, 2001
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Kohzaburoh Yamada, Hiroyuki Suzuki, Toshihide Ezoe
  • Patent number: 6274302
    Abstract: A photothermographic element comprising on a support (a) a photosensitive silver halide, (b) a reducible silver salt, (c) a reducing agent, (d) an ultrahigh contrast-providing agent, (e) a binder, (f) a specific salicylic acid type antifoggant, and optionally (g) phosphoric acid or a salt thereof has a low fog, high sensitivity, high contrast, and storage stability.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: August 14, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsuyuki Watanabe, Kouta Fukui
  • Publication number: 20010010895
    Abstract: Disclosed is a color photographic element comprising:
    Type: Application
    Filed: July 21, 1999
    Publication date: August 2, 2001
    Inventors: PHILIP A. ALLWAY, LOUIS E. FRIEDRICH, STEPHEN P. SINGER
  • Patent number: 6258518
    Abstract: A silver halide photosensitive material comprises a compound represented by formula (S1): wherein R1 represents a substituent group, n represents an integer from 0 to 4, R2 and R3 can be the same or different and represent a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group.
    Type: Grant
    Filed: March 30, 1999
    Date of Patent: July 10, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Taniguchi, Hideo Ikeda
  • Patent number: 6258521
    Abstract: There is disclosed a silver halide color photographic light-sensitive material that is improved in such aspects as fastness of dye images, color reproduction, cyan stain, processing cyan color contamination, and the like, by the combination use of a phenidone compound having a specific structure as in the following general formula (VIII) and a pyrrolotriazole cyan coupler. The phenidone compound (VIII) can be produced industrially in low cost, by reacting an &agr;-alkyl or alkenyl acrylate with a compound represented by the following general formula (VII): wherein, R4, R5, R6, R7, R8, and R9, each represent a hydrogen atom, an alkyl group, or the like; R2a represents an alkyl group having 6 to 30 carbon atoms, or the like.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: July 10, 2001
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Hisashi Mikoshiba, Yasuhiro Yoshioka, Shin Soejima, Osamu Takahashi, Naoki Saito, Masakazu Morigaki
  • Patent number: 6248512
    Abstract: An image forming method for a thermally processable photosensitive material is disclosed, comprising exposing a thermally processable photosensitive material to light using a laser light source, and subjecting the exposed photosensitive material to thermal processing, wherein the thermally processable photosensitive material comprises a support having thereon an organic silver salt, a binder, a photosensitive silver halide, and a compound containing nitrogen covalently bonded to halogen represented by the following formula or a nitrogen-containing acyclic compound associated with a pair of halogen atoms represented by the following formula
    Type: Grant
    Filed: April 8, 1999
    Date of Patent: June 19, 2001
    Assignee: Konica Corporation
    Inventors: Norio Miura, Keiko Ishidai
  • Patent number: 6245497
    Abstract: A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: June 12, 2001
    Assignee: Eastman Kodak Company
    Inventors: Jon N. Eikenberry, David T. Southby
  • Patent number: 6242170
    Abstract: This invention provides a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises large tabular grains having an average equivalent circular diameter of greater than 3 &mgr;m and contains a one equivalent image dye-forming coupler and a fragmentable electron donating compound of the formula: X—Y′ or a compound which contains a moiety of the formula —X—Y′; wherein X is an electron donor moiety, Y′ is a leaving proton H
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: June 5, 2001
    Assignee: Eastman Kodak Company
    Inventors: Joseph P. Pepe, Jeffrey C. Hansen, James A. Friday, Annabel A. Muenter, David T. Southby