Silver Compound Other Than Halide, Per Se, Or Composition For Thermographic Process Patents (Class 430/617)
  • Patent number: 4239846
    Abstract: Disclosed are tellurium (IV) compounds represented by the formula: ##STR1## wherein: D is a Lewis base function containing a group VA or VIA donor atom;Q represents the atoms necessary to complete a 5- or 6-membered ring, when taken together with C, D and Te, when m is 1 and represents the atoms linking C and D when m is greater than 1;R.sub.1 and R.sub.2 are independently selected from the group consisting of hydrogen, alkyl and aryl;X is an anion;n is 1 or 2; andm is an integer from 1 to 500.These compounds are useful in an image-forming combination comprising the described Te(IV) compound and a reducing agent. The image-forming combination is useful in a variety of materials, including a dry amplification element.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: December 16, 1980
    Assignee: Eastman Kodak Company
    Inventors: Henry J. Gysling, Sylvia A. Gardner
  • Patent number: 4210715
    Abstract: Light-sensitive silver halide photographic materials to be treated with a hydroquinones-containing developing solution which material comprises a support and at least one hydrophilic colloidal layer coated thereon which contains silver halide grains having an average grain size of 0.05 to 1.5.mu., a tetrazolium compound and a sensitizing dye.
    Type: Grant
    Filed: March 2, 1979
    Date of Patent: July 1, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki
  • Patent number: 4208478
    Abstract: A Te(II) complex represented by the formula: RTeM(R').sub.3 wherein M is lead, tin, germanium or silicon; R and R' are alkyl or aryl is useful in an imaging material to provide a non-silver image. The imaging material can be a photographic material, especially a heat-developable photographic material containing, for example, a photosensitive metal salt other than the Te(II) material or other sources of developable nuclei.
    Type: Grant
    Filed: October 13, 1977
    Date of Patent: June 17, 1980
    Assignee: Eastman Kodak Company
    Inventors: Sylvia A. Gardner, Henry J. Gysling
  • Patent number: 4207392
    Abstract: An activator-stabilizer precursor which comprises a certain acylhydrazine which releases a base moiety upon being heated to a temperature above about 130.degree. C. provides improved heat developable and heat stabilizable photographic materials comprising, in binder, and in reactive association, (a) a photosensitive silver salt, (b) a photosensitive silver salt developing agent, and (c) a stabilizing concentration of the described activator-stabilizer precursor having an acid portion and a base portion. The heat developable and heat stabilizable photographic element provides essential freedom from visual crystal formation in the processed photographic element. After imagewise exposure, a developed and stabilized image can be produced in the photographic element by heating the element to processing temperature.
    Type: Grant
    Filed: October 30, 1978
    Date of Patent: June 10, 1980
    Assignee: Eastman Kodak Company
    Inventors: Daniel D. Shiao, Lawrence R. Morrow
  • Patent number: 4207112
    Abstract: A heat developable light-sensitive material comprising a support carrying at least one layer containing at least (a) an organic silver salt, (b) a light-sensitive halide or a light-sensitive silver halide-forming component, (c) a reducing agent and (d) phthalazinone, and which further has on another surface of the support opposite the above layer one layer containing a compound comprising a ##STR1## moiety, wherein M represents a hydrogen atom or a monovalent metal atom. The material shows improved retention of its as manufactured properties, especially in the superposed state.
    Type: Grant
    Filed: November 3, 1975
    Date of Patent: June 10, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinpei Ikenoue, Takao Masuda, Shinichi Sakawaki
  • Patent number: 4201590
    Abstract: A heat bleachable material comprises (i) at least one hexaarylbiimidazole with (ii) at least one dye, especially an antihalation or filter dye, that is reactive with the product of the hexaarylbiimidazole formed upon heating the material to a temperature above about 90.degree. C. This provides a material that becomes at least 40% colorless within about 20 minutes, typically within about 30 seconds, upon heating to a temperature as described. The dye-containing material is especially useful for antihalation and filter purposes in a photographic element. The material can be a heat bleachable dye layer of a photothermographic element. The heat bleachable dye layer can also be useful in a thermographic element.
    Type: Grant
    Filed: October 23, 1978
    Date of Patent: May 6, 1980
    Assignee: Eastman Kodak Company
    Inventors: Steven R. Levinson, Anthony Adin
  • Patent number: 4197131
    Abstract: Dry silver photo-sensitive compositions comprising an intimate mixture of a substantially light-insensitive silver compound which upon reduction gives a visible change and sufficient of a silver halide to catalyse said reduction to give a visible change in those areas where the silver halide has been exposed to light and when the mixture is heated in the presence of a reducing agent, and as a yellow acutance dye a 1-alkyl-4-nitro-methylene-quinolane, the alkyl substituent containing 1 to 4 carbon atoms.
    Type: Grant
    Filed: November 29, 1978
    Date of Patent: April 8, 1980
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Bernard D. Lea, Jack E. Reece
  • Patent number: 4196002
    Abstract: A photothermographic element can comprise a support and on the support or in the support an antihalation or filter component that comprises a heat bleachable material comprising (i) at least one hexaarylbiimidazole with (ii) at least one dye, especially an antihalation or filter dye, that is reactive with the product of the hexaarylbiimidazole formed upon heating the material to a temperature above about 90.degree. C. This provides an antihalation or filter material that becomes at least 40% colorless within about 20 minutes, typically within about 30 seconds, upon heating to a temperature as described. The antihalation or filter material can be a heat bleachable dye layer of a photothermographic element.
    Type: Grant
    Filed: October 23, 1978
    Date of Patent: April 1, 1980
    Assignee: Eastman Kodak Company
    Inventors: Steven R. Levinson, Anthony Adin
  • Patent number: 4188218
    Abstract: Tellurium images are formed by the decomposition of tellurium (II) coordination complexes in the presence of a catalyst. The complexes are characterized in that at least one of the four coordination positions of the tellurium (II) is occupied by a sulfur containing ligand. Preferred ligands that can be coordinated with tellurium are sulfur containing bidentate anionic ligands. Complexes formed using these preferred ligands are more hydrolytically stable than other tellurium (II) complexes having sulfur containing ligands and yet are still capable of providing catalytic amplification.
    Type: Grant
    Filed: December 22, 1977
    Date of Patent: February 12, 1980
    Assignee: Eastman Kodak Company
    Inventor: Henry J. Gysling
  • Patent number: 4187108
    Abstract: In a heat developable photographic material and process for providing a dye enhanced silver image, an element comprising a support having thereon in reactive association: (A) at least one heat developable photographic layer comprising (i) photosensitive silver halide, (ii) at least one active silver halide developing agent, (iii) an activating concentration of a development activator precursor, and (iv) a polymeric binder and (B) at least one layer comprising an azoaniline dye that is bleached in the non-image areas of the described element upon development of a latent image in the layer (A) by uniformly heating, can provide an improved image. After imagewise exposure of the described heat developable material, a dye enhanced silver image can be provided by heating the element containing the described combination of layers and materials.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: February 5, 1980
    Assignee: Eastman Kodak Company
    Inventor: Roland G. Willis
  • Patent number: 4186009
    Abstract: A covering power, heat developable photographic material comprising, in binder, and in reactive association (a) negative-working photosensitive silver halide, (b) an image-forming combination comprising (i) an organic silver salt oxidizing agent containing a heterocyclic thione ligand or 1,2,4-mercaptotriazole ligand with (ii) an organic reducing agent and (c) a nucleating concentration of a hydrazino thiourea nucleating agent, enables a positive image to be developed and, in most cases, stabilized even though the photothermographic material contains no separate post-processing image stabilizer. The heat developable silver halide photographic material also enables development efficiency that is better than in those photothermographic silver halide materials not based on covering power imaging. A positive image can be developed in the heat developable photographic material after imagewise exposure by merely heating the material to moderately elevated temperatures.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: January 29, 1980
    Assignee: Eastman Kodak Company
    Inventor: Cynthia G. Jones
  • Patent number: 4173478
    Abstract: Certain azo compounds are useful as spectral sensitizing dyes in photographic silver halide materials, and particularly in photothermographic materials. These azo compounds comprise moieties capable of forming substantially insoluble silver salts thereby substantially improving sensitization of silver halides.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: November 6, 1979
    Assignee: Eastman Kodak Company
    Inventors: Colin Holstead, Kenneth N. Kilminster, Michael J. Simons