Silver Compound Other Than Halide, Per Se, Or Composition For Thermographic Process Patents (Class 430/617)
  • Patent number: 4775610
    Abstract: A method for the formation of a photographic image including a heating step, comprising heating a photographic material in the presence of at least one compound selected from those represented by formulae (I) and(II) ##STR1## wherein A represents a non-metallic atomic group forming a carbocyclic aromatic ring or a heterocyclic aromatic ring;X represents a nucleophilic group or a precursor thereof;Q represnts a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, or aryl group; andPUG represents a photographically useful group.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: October 4, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Kozo Sato, Masatoshi Kato
  • Patent number: 4772544
    Abstract: A heat-developable photographic material is disclosed wherein the photographic material comprising at least one of an acid or a salt thereof having an acid dissociation constant pKa of 7 or less.
    Type: Grant
    Filed: August 7, 1985
    Date of Patent: September 20, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Hirai
  • Patent number: 4760011
    Abstract: A light-sensitive material comprising a light-sensitive layer provided on a support wherein the light-sensitive layer contains silver halide, a reducing agent, a polymerizable compound and a base or base precursor which is contained in microcapsules under condition that the base or base precursor is dissolved or dispersed in an aqueous solution of a water retention agent.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: July 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fujio Kakimi
  • Patent number: 4758503
    Abstract: A heat developable light-sensitive material containing a compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, an aralkyl group, a substituted aralkyl group, an aryl group, a substituted aryl group or a heterocyclic group, or R.sub.1 and R.sub.2 are bonded to each other to form a 5-membered or 6-membered carbocyclic ring or a heterocyclic ring which may be a saturated ring, an unsaturated ring or an aromatic ring, may be condensed and may further have one or more substituents; M represents an alkali metal ion, an alkaline earth metal ion, a transition metal ion, a protonated organic base or a quaternary ammonium ion; and n represents a reciprocal of the positive charge number of M.
    Type: Grant
    Filed: March 26, 1986
    Date of Patent: July 19, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroyuki Hirai
  • Patent number: 4758496
    Abstract: A light-sensitive material comprising a light-sensitive layer provided on a support, wherein the light-sensitive layer contains silver halide, a reducing agent, a polymerizable compound, and a base or a base precursor. The base or base precursor is contained in microcapsules.
    Type: Grant
    Filed: March 11, 1987
    Date of Patent: July 19, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Fujio Kakimi
  • Patent number: 4752559
    Abstract: A photothermographic recording article comprises in sequence:(a) a substrate,(b) a prime coat/antihalation layer comprising a pigmented acrylic polymer binder system,(c) a photothermographic dispersion comprising a binder, a non-light sensitive silver source material, photographic silver halide in catalytic proximity to silver source material, and(d) optionally, a topcoat layer,said article further comprising a reducing agent for silver ion and at least one development accelerator in at least one of the layers of the substrate.
    Type: Grant
    Filed: March 24, 1987
    Date of Patent: June 21, 1988
    Inventors: Randall H. Helland, Gregory J. McCarney
  • Patent number: 4751175
    Abstract: A heat developable color light-sensitive material is disclosed, which comprises a support having provided thereon at least a light-sensitive silver halide emulsion, a binder, and a compound having a dye moiety within the molecule and which is capable of releasing, upon reduction of light-sensitive silver halide to silver at elevated temperatures, said dye moiety corresponding to or inversely corresponding to the reduction to form a dye different from said compound in terms of diffusibility, wherein said light-sensitive silver halide emulsion is prepared by forming silver halide grains in the presence of a sensitizing dye.
    Type: Grant
    Filed: March 6, 1987
    Date of Patent: June 14, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Aotsuka, Takanori Hioki, Kiyohiko Yamamuro
  • Patent number: 4740445
    Abstract: A color image is formed in an image forming reaction system comprising a photographic heat-developable silver halide light-sensitive material by reacting a difficultly soluble metal compound, for example, calcium carbonate with a compound capable of water-mediated complexing reaction with the metal ion of the difficultly soluble metal compound and having an organic base, for example, guanidine oxalate in the presence of water to increase the pH of the system.
    Type: Grant
    Filed: July 30, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Yoshiharu Yabuki, Kozo Sato
  • Patent number: 4740455
    Abstract: A novel heat developable light-sensitive material is provided comprising a silver halide spectrally sensitized by a polymethine containing at least one basic nucleus wherein the dye contains, as a group for substituting nitrogen atoms in said basic nucleus, at least one of the groups represented by general formulae (A) and (B): ##STR1##--(CH.sub.2 --.sub.2 NHSO.sub.2 Rwherein m represents an integer of 1 or 2; Y represents an atomic group necessary for the formation of a cyclic imide group; and R represents a C.sub.1-4 alkyl group.In a preferred embodiment, the atomic group represented by Y is selected from the group consisting of a succinic acid imido group, a phthalic acid imido group, an orthobenzosulfimido group, and a maleimido group. The atomic group may be optionally substituted by a halogen atom, a nitro group, a carboxyl group, an acylamino group such as an acetylamino group, or an alkoxycarbonyl amino group such as an ethoxycarbonyl group.
    Type: Grant
    Filed: August 6, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiiti Kubodera, Masaki Okazaki
  • Patent number: 4740446
    Abstract: Compounds corresponding to formula I are suitable for use as thermal development and diffusion promoting agents for the heat development process. The said compounds enable higher color transfer densities to be obtained and/or the development time to be reduced. ##STR1## wherein R.sup.1, R.sup.2 denote alkyl, cycloalkyl, aralkyl, aryl or acyl andZ denotes a group for completing a saturated heterocyclic ring containing 5 to 11 ring members.
    Type: Grant
    Filed: October 31, 1986
    Date of Patent: April 26, 1988
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Karl-Wilhelm Schranz, Gunther Schenk
  • Patent number: 4735884
    Abstract: A light-sensitive material comprising a light-sensitive layer which contains silver halide, a reducing agent and a polymerizable compound provided on a support, characterized in that the reducing agent is a hydrazine derivative having the following formula (I): ##STR1## in which R.sup.1 is a monovalent group selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkynyl group and a heterocyclic group, each of which may have one or more substituent groups; each of R.sup.2 and R.sup.3 independently is an aryl group which may have one or more substituent group, or R.sup.2 and R.sup.3 form, together with the neighboring carbon, a condensed aromatic ring; R.sup.4 is a monovalent group selected from the group consisting of an aryl group, a heterocyclic group, hydrogen, an alkyl group, an alkoxycarbonyl group and carbamoyl, each of which may have one or more substituent groups.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: April 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jiro Tsukahara, Taku Nakamura
  • Patent number: 4731321
    Abstract: A heat developable light-sensitive material comprising a support having thereon at least one light-sensitive layer wherein at least one layer comprises a compound represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group each of which may be substituted or unsubstituted; a carboxy group or a salt thereof; R.sub.3 and R.sub.
    Type: Grant
    Filed: December 16, 1986
    Date of Patent: March 15, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
  • Patent number: 4729936
    Abstract: An image forming process including a heating step is disclosed. The process comprises conducting said heating step in the presence of at least one compound represented by formula (I), (II), or (III). ##STR1## wherein R.sup.1 represents ##STR2## wherein R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkyloxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group or a substituted or unsubstituted amino group; R.sup.11 and R.sup.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: March 8, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Kozo Sato, Masatoshi Kato
  • Patent number: 4728600
    Abstract: A heat-developable light-sensitive material is described, comprising a support having thereon at least (1) a light-sensitive silver halide, (2) a silver salt oxidizing agent, (3) silver salt particles having adsorbed thereon at least one compound selected from a cyclic imino compound represented by formula (I) described below and a mercapto compound represented by formula (II) described below, (4) a reducing agent, and (5) a binder.Formula (I) is represented by ##STR1## wherein Z represents a non-metallic atomic group forming a heterocyclic ring containing an imino group together with the nitrogen atom of formula (I).Formula (II) is represented byR--S--M (II)wherein M represents a hydrogen atom or an alkali metal atom; and R represents a substituted or unsubstituted aliphatic hydrocarbon group, a substituted or unsubstituted aromatic hydrocarbon group, or a substituted or unsubstituted heterocyclic group.
    Type: Grant
    Filed: April 17, 1986
    Date of Patent: March 1, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Toshiaki Aono
  • Patent number: 4725534
    Abstract: A process for producing a heat-developable photosensitive material containing fine photosensitive silver halide particles having a uniform particle form and particle size, said silver halide being prepared by reacting a silver salt of an organic fatty acid stoichiometrically with an inorganic or organic halogen compound.
    Type: Grant
    Filed: February 26, 1985
    Date of Patent: February 16, 1988
    Assignee: Oriental Photo Industrial Co., Ltd.
    Inventors: Kenji Kagami, Kenichi Nishio, Yukio Takegawa, Kazunori Shigemori
  • Patent number: 4716100
    Abstract: A heat developable light-sensitive material containing a novel base precursor (I), which is stable during storage and rapidly decomposes to release a basic component upon heating higher than a certain temperature, has excellent storability and provides an image having a good image quality, i.e., a low fog density and a high image density within a short period of developing time.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: December 29, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
  • Patent number: 4713316
    Abstract: A heat-developable photographic material having improved preservability, which comprises a support having thereon at least one heat-developable photographic layer, said photographic material containing a dye represented by formula (I) ##STR1## wherein n and m each represents 0, 1, 2 or 3;p and q each represents 0 or 1;L represents a methine group or a substituted methine group;R.sub.1 and R.sub.2 are same or different and each represents an unsubstituted or substituted alkyl group;R.sub.3 and R.sub.4 are same or different and each represents a hydrogen atom, an alkyl group, an alkoxy group, a hydroxyl group, an unsubstituted or substituted amino group or a halogen atom; or said R.sub.3 and R.sub.4 form a condensed 6-membered ring;Z and Z' are same or different and each represents a non-metallic atomic group necessary for forming a substituted or unsubstituted 5-membered or 6-membered ring, or substituted or unsubstituted 5-membered or 6-membered ring which is condensed with another ring;X.sup..crclbar.
    Type: Grant
    Filed: December 4, 1985
    Date of Patent: December 15, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiiti Kubodera, Toshinao Ukai, Hisashi Okada
  • Patent number: 4705737
    Abstract: A heat developable photographic material comprising a support having thereon at least a photosensitive silver halide, a binder, and at least on of base precursors represented by following formula (I) or (II): ##STR1## wherein R represents an alkyl group, an alkylene group, an aryl group, an arylene group, a monovalent or divalent heterocyclic group, each of which may be unsubstituted or substituted; B represents a mono- or di-acidic, nitrogen-containing, sulfur-free base having a pKa of not lower than about 7 and containing 12 carbon atoms or less; x is an integer of 1 when R represents a monovalent group or an integer of 2 when R represents a divalent group, y is the same as x when B represents the mono-acidic base or an integer of 1 when B represents the di-acidic base; and z is an integer of 2 when R represents a monovalent group and B represents the di-acidic base or otherwise an integer of 1; R' represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl g
    Type: Grant
    Filed: August 20, 1985
    Date of Patent: November 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Kozo Sato, Yoshiharu Yabuki, Ken Kawata
  • Patent number: 4704344
    Abstract: A heat developable light-sensitive material is disclosed which is provided with a protective layer comprising, as a major constituent, a nonionic, hydrophilic polymer. On heat developing the light-sensitive material, a mobile dye image is formed which can be transferred to a dye fixing material superposed on the light-sensitive material. After the transfer of the dye image, the light-sensitive material can be readily separated from the dye fixing material due to the presence of the protective layer, and thus a sharp image can be formed in the dye fixing material.
    Type: Grant
    Filed: July 29, 1986
    Date of Patent: November 3, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiaki Aono, Koichi Nakamura
  • Patent number: 4696887
    Abstract: A novel method for formation of an image comprising a heating step, comprising the heating carried out in the presence of a compound of general formula (I):X--SO.sub.2 (DI) (I)wherein X represents a reducing group capable of reducing a silver salt and capable of being oxidized by heating and in its oxidized state capable of releasing a compound represented by (DI)--SO.sub.2 NH.sub.2 by reaction with a nucleophilic agent; and (DI) represents a development inhibiting group capable of inhibiting the oxidation reduction reaction of the silver salt and a reducing aent.The compound of the formula (I) functions to inhibit development after a certain period of time from the beginning of heat development.The present method provides a stable image with reduced fog and image mottle.
    Type: Grant
    Filed: February 13, 1986
    Date of Patent: September 29, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4695525
    Abstract: A process of forming images by heat developing a heat developable light-sensitive material after imagewise exposure is described, comprising heating a heat developable light-sensitive material in the presence of a compound represented by general formula (I) ##STR1##
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: September 22, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaaki Tsukase, Kozo Sato, Hiroshi Kitaguchi, Masashi Takeuchi, Masatoshi Kato
  • Patent number: 4693954
    Abstract: A heat developable light-sensitive material having both (a) a light-sensitive element which contains at least one light-sensitive silver halide emulsion layer and at least one image forming substance capable of forming a diffusible dye and (b) a dye fixing element capable of fixing the formed diffusible dye on the same side of one support, in such relation that a diffusible dye may permeate the dye fixing element (b) by diffusing from the light-sensitive element (a).The light-sensitive material of the present invention has a simple structure and does not require complicated procedures for its use or excess structural elements. Photographic images can be formed using the light-sensitive material in a short period of time by means of a simple photographic treatment.
    Type: Grant
    Filed: September 27, 1985
    Date of Patent: September 15, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hideki Naito
  • Patent number: 4689286
    Abstract: A color photographic recording material developable by heat treatment and comprising at least one binder layer, which contains photosensitive silver halide, optionally a substantially non-photosensitive silver salt and a color providing compound (dye releaser), can be improved in regard to the Dmin/max relation and in regard to sensitivity by addition of a compound corresponding to formula IR.sup.1 --S--CO--O--R.sup.2in which R.sup.1 and R.sup.2 independently of one another represent alkyl, alkenyl, cycloalkyl, aralkyl or aryl.
    Type: Grant
    Filed: April 7, 1986
    Date of Patent: August 25, 1987
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Karl-Wilhelm Schranz, Gunther Schenk, Hans hlschlager
  • Patent number: 4678739
    Abstract: A method for forming an image which has a step of heating an image-forming material in the presence of a compound represented by formula (I), whereby unevenness of image density and increase in fog due to fluctuation of development temperature, which have so far been caused in heat-developable photosensitive materials, can be prevented from occurring: ##STR1## wherein R represents a hydrogen atom, or a group selected from a class consisting of groups represented by formulae (A) to (C) ##STR2## wherein R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a cycloalkyl group, a substituted or unsubstituted alkenyl group, an aralkyl group, a substituted or unsubstituted aryl group, a heterocyclic group, an alkyloxy group, an aryloxy group, an alkylthio group, an arylthio group, or a substituted or unsubstituted amino group, or R.sup.11 and R.sup.
    Type: Grant
    Filed: December 18, 1985
    Date of Patent: July 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masashi Takeuchi, Kozo Sato, Masaaki Tsukase, Masatoshi Kato
  • Patent number: 4678735
    Abstract: A heat developable light-sensitive material containing a compound represented by general formula (I) described below in a light-sensitive layer or an image receiving layer thereof: ##STR1## wherein X represents an atomic group necessary to complete a benzene ring or a naphthalene ring; R represents a group convertible to a hydroxy group or a dissociation form thereof at the time of heat development; Y represents an atomic group necessary to complete a 5-membered or 6-membered heterocyclic group containing at least one nitrogen atom; Q represents a hydrogen atom, an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group; TIME represents a timing group; and n represents 0 or a positive integer.
    Type: Grant
    Filed: September 10, 1985
    Date of Patent: July 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato, Kozo Sato, Masasi Takeuchi, Masaaki Tsukase
  • Patent number: 4677051
    Abstract: A heat-developable color light-sensitive material is provided comprising on a support at least a light-sensitive silver halide emulsion, a binder, a compound capable of producing or releasing a mobile dye in direct or inverse proportion to the reaction of the light-sensitive silver halide being reduced into silver at elevated temperatures, and a dye having the general formula: ##STR1## wherein each of R.sup.1 and R.sup.2 is a substituted or unsubstituted alkyl or alkenyl group,R.sup.3 is a hydrogen atom, or substituted or unsubstituted alkyl, alkoxy, aryl or alkenyl group,each of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 is a hydrogen atom, halogen atom, hydroxyl, carboxyl, or substituted or unsubstituted alkyl, alkoxy, alkoxycarbonyl, acyl, acyloxyl, aryl, amino, or acylamino group,X.sup.1 and X.sup.2, and X.sup.3 and X.sup.4 can be mutually combined to form a benzene ring,A.sup.- is an anion, andn is equal to 0 or 1.
    Type: Grant
    Filed: November 26, 1985
    Date of Patent: June 30, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiiti Kubodera, Takanori Hioki, Masaki Okazaki
  • Patent number: 4675277
    Abstract: A heat developable light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide, a binder, and a compound capable of ring-closure to produce a benzimidazole ring upon heat development can be developed to an increased maximum density with less fogging at a relatively low temperature in a short period of time.
    Type: Grant
    Filed: September 25, 1985
    Date of Patent: June 23, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Hiroyuki Hirai
  • Patent number: 4670366
    Abstract: The invention relates to high energy beam-sensitive glass articles exhibiting insensitivity and/or inertness to actinic radiation, i.e., glass articles which are darkened and/or colored within a thin surface layer of, e.g., about 0.1-3 .mu.m upon exposure to a high energy beam, electron beam, and ion beams in particular, without a subsequent development step, and which need no fixing to stabilize the colored image, since both the recorded image and the glass article are sensitive to radiation in the spectral range of uv and longer wavelengths. More particularly, the instant invention is concerned with Ag.sup.+ ion-exchanged glass articles having base glass within alkali metal silicate composition fields containing at least one of the oxides of transition metals which have one to four d-electrons in an atomic state. Whereas the base glass composition can be varied widely, spontaneous reduction as well as photo-reduction of Ag.sup.
    Type: Grant
    Filed: June 12, 1984
    Date of Patent: June 2, 1987
    Assignee: Canyon Materials Research & Engineering
    Inventor: Che-Kuang Wu
  • Patent number: 4670373
    Abstract: An organic acid precursor having a structural moiety of the following formula ##STR1## bonded to a carbon atom. This acid precursor is useful as a development stopping agent in a photographic heat-developable process.
    Type: Grant
    Filed: November 19, 1984
    Date of Patent: June 2, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato
  • Patent number: 4670374
    Abstract: A photothermographic construction comprises a light-sensitive color-forming element on a support base, the element comprising a silver source, optionally silver halide, a binder, and an oxidizable leuco phenazine, phenoxazine, or phenothiazine dye, and as development accelerator a carboxylic acid, Lewis acid, or Bronsted acid.
    Type: Grant
    Filed: February 12, 1986
    Date of Patent: June 2, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Peter A. Bellus, Robert A. Frenchik
  • Patent number: 4668612
    Abstract: A novel heat-developable color photosensitive material containing at least a light-sensitive silver halide, a binder, a dye providing substance capable of forming or releasing a diffusible dye by an oxidation-reduction reaction under heat and a transition metal ion, on a support.The present photosensitive materials provide a color image of high density with low fog in a short period of time, and have a good preservation-stability.
    Type: Grant
    Filed: September 4, 1985
    Date of Patent: May 26, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Hiroyuki Hirai
  • Patent number: 4668615
    Abstract: A heat developable light-sensitive material containing a compound represented by the general formula (I):[Ar.sub.n (R).sub.3-n CCO.sub.2 H].sub.l .multidot.B.sub.m (I)wherein ar represents an aryl group or a heterocyclic group; R represents a substituent other than an aryl group and a heterocyclic group; Ar and R may be bonded in a part thereof to form a ring; B represents a mono- or diacidic base which has a pKa of 7 or more and contains 12 or less carbon atoms; n represents an integer from 1 to 3; l and m each represents an integer of 1 or 2 and maintain a relationship in that a number of positive charge and a number of negative charge are equal; when n represents 1 or 2, two R's or Ar's may be the same or different, when n represents 3, three Ar's may be the same or different; and the substituent represented by Ar or R may be further substituted with a substituent.
    Type: Grant
    Filed: August 21, 1985
    Date of Patent: May 26, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
  • Patent number: 4659653
    Abstract: A heat developable light-sensitive material comprising a support having thereon at least a layer containing a novel compound having a group accelerating a reaction of decarboxylation, which releases a base by decarboxylation on heating. The heat developable light-sensitive material provides an image having a high density in a short time and has an improved storage stability.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: April 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
  • Patent number: 4657848
    Abstract: A heat-developable light-sensitive material is described, containing a compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted alkenylene group, a substituted or unsubstituted alkynylene group, a substituted or unsubstituted aralkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted divalent heterocyclic group; R.sub.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group; R.sub.
    Type: Grant
    Filed: October 2, 1985
    Date of Patent: April 14, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
  • Patent number: 4656124
    Abstract: A heat-developable color photo-sensitive material having a support. A photographic component layer is on the support and contains at least a photo-sensitive silver halide, a reducing agent, a binder and a dye-providing material. At least one of the dye-providing materials is a polymer having a repetition unit being derived from a monomer represented by the Formula I.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: April 7, 1987
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventor: Tawara Komamura
  • Patent number: 4656121
    Abstract: This invention relates to an optical information recording medium having an organic thin film recording layer, and optionally having an underlayer and/or protective layer, characterized in that at least one of said recording layer, underlayer and protective layer contains a compound expressed by the general formula (1), ##STR1## wherein R represents hydrogen or a lower alkyl group; X represents acid anion; m represents 0, 1 or 2; and A represents ##STR2## (n being 1 or 2) or ##STR3## (when m is 2); all the aromatic rings optionally having a substituent selected from the group of a lower alkyl group, lower alkoxy group, halogen and hydroxyl group.
    Type: Grant
    Filed: February 6, 1985
    Date of Patent: April 7, 1987
    Assignee: Ricoh Co., Ltd.
    Inventors: Tsutomu Sato, Masaakira Umehara, Michiharu Abe, Hideaki Oba, Yutaka Ueda
  • Patent number: 4656126
    Abstract: A heat-developable color light-sensitive material is described, comprising a support having thereon at least (1) a light-sensitive silver halide emulsion, (2) a dye providing substance which releases a dye having a different diffusibility from that of the dye providing substance in correspondence or countercorrespondence to the light-sensitive silver halide when the light-sensitive silver halide is reduced under the condition of high temperature and (3) an organic acid precursor containing a structural moiety bonded to carbon atoms that is represented by formula (I) ##STR1## The heat-developable color light-sensitive material can provide color images having a high S/N ratio and a high image density.
    Type: Grant
    Filed: March 14, 1985
    Date of Patent: April 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masatoshi Kato, Hiroshi Kitaguchi
  • Patent number: 4650749
    Abstract: A heat developable light-sensitive material containing a compound represented by formula (I) or (II) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, a heterocyclic group, a carboxyl group or a salt thereof, a halogen atom, a cyano group, an alkylsulfonyl or arylsulfonyl group, a sulfamoyl group, a carbamoyl group, an alkoxycarbonyl or aryloxycarbonyl group, a di- or mono-alkylphosphoryl or arylphosphoryl group, a di- or mono-alkylphosphinyl or arylphosphinyl group, an alkylsulfinyl or arylsulfinyl group, an acyl group, an amino group, an acylamino group, an acyloxy group or a group represented by X; X represents a decarboxylation accelerating group; or any two of R.sub.1, R.sub.2, and X may combine to form a ring; and the groups represented by R.sub.1, R.sub.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: March 17, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Yoshiharu Yabuki, Hiroyuki Hirai, Ken Kawata
  • Patent number: 4649103
    Abstract: A heat-developable light-sensitive material is disclosed, comprising a support and at least one layer containing a novel base precursor releasing a base by thermal decomposition. The heat-developable light-sensitive material of the invention has an improved long-term stability and can provide a high density image in a short time.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: March 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
  • Patent number: 4649104
    Abstract: A heat developable light-sensitive material is described, comprising a polymer containing as a constituent a repeating unit represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group having from 1 to 6 carbon atoms; L represents a divalent connecting group having from 1 to 20 carbon atoms; M represents a cation and x represents a number which is the same as the charge number of the cation represented by M.The polymer containing the repeating unit represented by formula (I) is a base precursor which is stable at normal temperature, but rapidly decomposes to release a base by heating; therefore, the heat developable light-sensitive material containing the base precursor has excellent preservability and provides images having good image quality, i.e., low fog density and high image density, upon a short period of developing time.
    Type: Grant
    Filed: October 30, 1985
    Date of Patent: March 10, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Taku Nakamura, Hiroyuki Hirai
  • Patent number: 4647526
    Abstract: A heat-developable light-sensitive material is described which is capable of providing images of high density and low fog in a short period of time, and which is excellent in stability. The heat-developable light-sensitive material comprises a support and formed thereon a heat developable light-sensitive layer, wherein said light-sensitive material contains at least one compound selected from the group consisting of compounds represented by formulae (I), (II), (III) and (IV) as a base precursor ##STR1## wherein symbols represent the same groups as defined in claim 1.
    Type: Grant
    Filed: August 22, 1985
    Date of Patent: March 3, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
  • Patent number: 4643964
    Abstract: A heat-developable light-sensitive material is described, comprising a support having thereon a heat-developable silver halide emulsion layer capable of being developed by heating and further comprising said same support or the other support having thereon an electrically conductive layer, wherein the electrically conductive layer comprises at least (1) a compound imparting electrical conductivity, (2) a compound having a melting point of 100.degree. C. or more, and (3) a hydrophilic binder.
    Type: Grant
    Filed: July 22, 1985
    Date of Patent: February 17, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoru Sawada, Hideki Naito, Hiroshi Kitaguchi
  • Patent number: 4640891
    Abstract: A heat developable light-sensitive material having an excellent stability with time and capable of providing a high quality image is disclosed, which contains a base precursor represented by the following general formula (I): ##STR1## wherein A represents an organic residue represented by the following formula (II): ##STR2## X represents an electron attractive substituent having a Hammett's sigma value of more than 0;l represents an integer of 1 to 5 and, when l represents 2 or more, a plurality of Xs may be the same or different;Y represents a substituent having a Hammett's sigma value of 0 or less;k represents an integer of 0 to 5 and, when k represents 2 or more, a plurality of Ys may be the same or different;Z represents a divalent organic residue selected from the group consisting of --C.dbd.
    Type: Grant
    Filed: August 23, 1985
    Date of Patent: February 3, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
  • Patent number: 4640892
    Abstract: A heat-developable color photographic light-sensitive material comprises a support having thereon at least one layer containing the novel base precursor. This heat-developable color photographic light-sensitive material provides a high maximum density and low fog by heat-developing at a relatively low temperature and for a short period of time.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: February 3, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Ken Kawata, Yoshiharu Yabuki, Kozo Sato, Hiroyuki Hirai
  • Patent number: 4639408
    Abstract: A process for forming an image comprising a heating step is described, wherein a photographic material is heated in the presence of a compound represented by formula (I) ##STR1## wherein X represents an atomic group completing a carbocyclic aromatic ring or a heterocyclic aromatic ring; R.sup.1 is selected from groups represented by formulae (A), (B), and (C) ##STR2## in which R.sup.11 and R.sup.12 each represents a substituted or unsubstituted alkyl group, a cycloalkyl group, a substituted or unsubstituted alkenyl group, an aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, an alkyloxy or aryloxy group, an alkylthio or arylthio group, or a substituted or unsubstituted amino group, or R.sup.11 and R.sup.12 together form a 5-membered or 6-membered ring; R.sup.2 represents a group selected from the groups represented by R.sup.11 ; R.sup.1 and R.sup.
    Type: Grant
    Filed: November 20, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Kitaguchi, Masatoshi Kato
  • Patent number: 4639414
    Abstract: A heat developable light-sensitive material comprising a support having thereon (1) a light-sensitive silver halide emulsion, (2) at least one of a base and a base precursor, and (3) a binder, wherein the silver halide emulsion is one which is chemically sensitized in the presence of a sensitizing dye. With the heat developable light-sensitive material, decrease in sensitivity and formation of fog during preservation thereof are prevented.
    Type: Grant
    Filed: June 13, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yukihiko Sakaguchi
  • Patent number: 4639418
    Abstract: A heat developable photosensitive material comprising a support having thereon at least one light-sensitive layer comprising light-sensitive silver halide and a binder, wherein at least one layer contains a base precursor represented by the following general formula (I): ##STR1## wherein at least one of X, Y and Z, which may be the same or different, represents an electron-attractive substituent selected from the group (a) consisting of a halogen atom, a nitro group, an alkysulfinyl group, an arylsulfinyl group, an acyl group, a sulfamoyl group, a sulfamoyl group substituted with an aryl group, a substituted aryl group, an alkyl group or a substituted alkyl group, a carbamoyl group, a substituted carbamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an aryloxysulfonyl groups ##STR2## a nitroso group, ##STR3## wherein B is defined as in general formula (I), and R, R.sup.1 and R.sup.
    Type: Grant
    Filed: August 22, 1985
    Date of Patent: January 27, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Kozo Sato, Ken Kawata, Hiroyuki Hirai
  • Patent number: 4639412
    Abstract: The use of a reflective white substrate comprising a polymeric film containing both vesicles and white pigment provides a good background layer for photothermographic emulsions which improves image properties.
    Type: Grant
    Filed: June 13, 1986
    Date of Patent: January 27, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gary E. LaBelle, David T. Ask
  • Patent number: 4637902
    Abstract: A base precursor represented by the following general formula (A) or (B): ##STR1## wherein A.sub.1, A.sub.2, A.sub.5, A.sub.6, A.sub.7, and A.sub.8 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, an alkenyl group, an aralkyl group, an aryl group, a substituted aryl group, an acyl group, or a heterocyclic group, and A.sub.1 and A.sub.2 can combine to form a ring and two of A.sub.5, A.sub.6, A.sub.7, and A.sub.8 can combine to form a ring, A.sub.3 and A.sub.4 each represents a hydrogen atom, an alkyl group, a substituted alkyl group, a cycloalkyl group, or an aralkyl group, and A.sub.3 and A.sub.4 can combine to form a ring or A.sub.3 and A.sub.4 can be a double bond forming an imino group from ##STR2## and X represents a nucleophilic group.
    Type: Grant
    Filed: March 14, 1984
    Date of Patent: January 20, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Ken Kawata
  • Patent number: H456
    Abstract: A thermodevelopable photographic material is described, comprising a support, at least one photographic silver halide emulsion layer coated thereon, and a dye donating substance capable of forming or releasing a mobile dye in response to, or in inverse response to, the reduction of silver halide in said emulsion to silver by heating, wherein the color of an image formed by the fixing of each of said mobile dyes released by exposure and heating to a dye fixing layer is within the range of a*=10 to -18 and b*=10 to -18 determined from tristimulus values in the 10 degree visual field XYZ system under standard light C.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: April 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Hara, Noboru Ohta, Tsuneo Suzuki