Silver Compound Other Than Halide, Per Se, Or Composition For Thermographic Process Patents (Class 430/617)
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Patent number: 5358843Abstract: Photothermographic elements containing image-forming emulsions with photothermographically useful compounds (e.g., stabilizers, toners, activators, developers, etc.) which are blocked with silyl groups, but become deblocked in the presence of a source of fluoride ion.Type: GrantFiled: August 20, 1993Date of Patent: October 25, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kumars Sakizadeh, Sharon M. Simpson, Omar Farooq, Sam Kalousdian
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Patent number: 5352561Abstract: A process is disclosed for forming an improved dye image in an aqueous-developable photographic dry dye-diffusion transfer element comprising the steps of:providing an aqueous-developable chromogenie photographic dry dye-diffusion transfer element comprising radiation sensitive silver halide, an aqueous-developable material containing color coupler wherein said coupler forms or releases a heat-transferable dye upon reaction of said coupler with the oxidation product of a primary amine developing agent, a hydrophilic binder, and a thermal solvent wherein said thermal solvent has the structure I ##STR1## wherein (a) Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, and Z.sub.5 are substituents, the Hammer sigma parameters of Z.sub.2, Z.sub.3, and Z.sub.4 sum to give a total, .SIGMA., of at least -0.28 and less than 1.Type: GrantFiled: April 16, 1993Date of Patent: October 4, 1994Assignee: Eastman Kodak CompanyInventors: David S. Bailey, Ronald H. White, John Texter
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Patent number: 5350669Abstract: Novel silver-carboxylate/1,2-diazine compounds having the formula: ##STR1## wherein: R.sup.1 represents either an alkyl, aralkyl, cycloalkyl, or alkenyl group of up to 29 carbon atoms; or an aryl group of up to 14 carbon atoms; andand R.sup.2 represents either hydrogen, an alkyl group, a cycloalkyl group fused to the 1,2-diazine ring, or the atoms necessary to complete a 5- or 6-membered aromatic ring fused to the 1,2-diazine ring.The novel silver-carboxylate/1,2-diazine compounds are coordination compounds of two silver-carboxylate molecules and two molecules comprising a 1,2-diazine nucleus. These compounds can serve as the silver source in a black-and-white thermographic or photothermographic element or as the oxidizing agent for a dye-based thermographic or photothermographic color-imaging construction.Type: GrantFiled: January 19, 1994Date of Patent: September 27, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: David R. Whitcomb, William C. Frank
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Patent number: 5340712Abstract: Radiation sensitive thermally developable imaging elements comprise:(a) photosensitive silver halide,(b) light insensitive silver salt oxidizing agent,(c) reducing agent for silver ions, and(d) an antifoggant compound comprising s-triazines having at least one tribromomethyl substituent. The antifoggants are effective in reducing spurious background image densities.Type: GrantFiled: April 21, 1993Date of Patent: August 23, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Susan H. Dunn, Mark P. Kirk, Roger A. Mader, Terence D. Spawn
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Patent number: 5330864Abstract: Phothermographic material capable of producing a high density cyan image upon image-wise exposure and thermal development at a relatively low temperature and for a short period of time. The photothermographic material of the invention comprise coated on a support base at least one light-sensitive emulsion layer containing: (a) a binder; (b) a silver source material; (c) a light sensitive silver halide in catalytic proximity to said silver source material, wherein said emulsion layer or an adjacent layer thereto comprises a chromogenic cyan leuco dye.The photothermographic material of the invention may be used to obtain good cyan image of suitable density in single color or multicolor photothermographic articles. At the same time the chromogenic leuco dye is stable enough not to be oxidized by oxygen of the air or by simple heating and to limit the fog formation after development.Type: GrantFiled: September 2, 1992Date of Patent: July 19, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Raffaella Biavasco, Cristina Soncini
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Patent number: 5326684Abstract: In a heat-developable color photosensitive material comprising a photosensitive silver halide, a dye providing compound, and a binder on a support, the content of calcium is controlled to 500 ppm or more based on the total weight of the binder, allowing the use of inexpensive binders. The photosensitive material is cost effective and forms an image with a low fog density (Dmin) and a high image density (Dmax).Type: GrantFiled: January 12, 1993Date of Patent: July 5, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Yasuo Aotsuka
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Patent number: 5324627Abstract: A thermal-dye-bleach construction comprising a dye in association with a thermal dye-bleaching agent of general formula I: ##STR1## wherein: each of R.sup.a and R.sup.b are individually selected from: hydrogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group, and a heterocyclic group, and preferably, both R.sup.a and R.sup.b represent hydrogen;p is one or two, and when p is one, Z is a monovalent group selected from: an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, and a heterocyclic group, and when p is two, Z is a divalent group selected from: an alkylene group, an arylene group, an alkenylene group, an alkynylene group, an aralkylene group, a cycloalkene group, and a heterocyclic group; and,M.sup.+ is cation which will not react with acarbanion generated from the thermal-carbanion-generating agent in such manner as to render the carbanion ineffective as a bleaching agent for the dye.Type: GrantFiled: December 21, 1992Date of Patent: June 28, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dian E. Stevenson, Mark P. Kirk, Sylvia A. Farnum, William C. Frank, Randall H. Helland, Jonathan P. Kitchin, Roger A. Mader, Mark B. Mizen, Richard A. Newmark, William D. Ramsden, Kumars Sakizadeh, Terence D. Spawn, George V. Tiers
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Patent number: 5324622Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.Type: GrantFiled: July 29, 1992Date of Patent: June 28, 1994Assignee: AGFA-Gevaert, N.V.Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
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Patent number: 5312721Abstract: The invention involves a bleachable antihalation system, particularly for use in thermally developable photographic recording materials. This antihalation system contains, besides an antihalation dye, a bleaching agent that forms sulfurous acid or sulfurous acid derivatives on treatment with heat or irradiation with actinic radiation.Type: GrantFiled: December 18, 1992Date of Patent: May 17, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventor: Ingrid Gesing
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Patent number: 5310640Abstract: Thermally processable imaging elements in which the image is formed by imagewise heating or by imagewise exposure to light followed by uniform heating are provided with both a backing layer and an electroconductive layer to reduce static electricity effects and improve conveyance through processing equipment. The backing layer is an outermost layer and is located on the side of the support opposite to the imaging layer whereas the electroconductive layer is an inner layer and can be disposed on either side of the support.Type: GrantFiled: June 2, 1993Date of Patent: May 10, 1994Assignee: Eastman Kodak CompanyInventors: Louis J. Markin, Diane E. Kestner, Wojciech M. Przezdziecki, Peter J. Cowdery-Corvan
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Patent number: 5310634Abstract: A p-phenylenediamine series color developing agent or a precursor thereof having a substituent A at the ortho-position; Substituent A: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and X represents --O--R.sup.7 or ##STR2## wherein R.sup.7 represents an alkyl group, an aryl group, or a heterocyclic ring and R.sup.8 and and R.sup.9, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic ring, R.sup.8 and R.sup.9 may combine with each other to form a heterocyclic ring, and a process for forming an image which comprises imagewise exposing a silver halide color photographic material and thereafter color developing the color photographic material in the presence of a p-phenylenediamine series color developing agent or a precursor thereof having the aforesaid substituent A.Type: GrantFiled: October 30, 1991Date of Patent: May 10, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisashi Mikoshiba, Mitsugu Tanaka, Kei Sakanoue
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Patent number: 5300420Abstract: Photothermographic compositions comprising a photographic silver halide, an organic silver salt, and a reducing agent for the organic silver salt, display improved stabilty in the presence of a compound having a nucleus of the formula: ##STR1## wherein: A represents any monovalent group for which the corresponding compound AH functions as a post-processing stabilizer,R.sup.1, R.sup.2, and R.sup.3, are independently hydrogen or methyl and with the proviso that R.sup.1 can represent an aryl group when R.sup.2 and R.sup.3 are hydrogen;R.sup.4 is hydrogen or lower alkyl of from 1 to 4 carbon atoms;R.sup.5 and R.sup.6 independently represent hydrogen, an alkyl group, a cycloalkyl group, an aryl group or R.sup.5 and R.sup.6 taken together with the carbon atom to which they are joined form a ring of 4 to 12 atoms;R.sup.7 and R.sup.8 are independently hydrogen or lower alkyl of 1 to 4 carbon atoms; andn is 0 or 1.Type: GrantFiled: June 1, 1993Date of Patent: April 5, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Raymond J. Kenney, Larry R. Krepski
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Patent number: 5298390Abstract: Photothermographic compositions comprising a photographic silver halide, an organic silver salt, and a reducing agent for the organic silver salt, display improved stability in the presence of a compound having a nucleus of the formula:A--(CH.sub.2).sub.n --X--(CH.sub.2).sub.n --Awherein:A represents any monovalent group for which the corresponding compound AH functions as a post-processing stabilizer,X is S, SO, or SO.sub.2, and n is 1 to 10.Type: GrantFiled: June 7, 1993Date of Patent: March 29, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kumars Sakizadeh, Frank J. Manganiello, Sharon M. Simpson, Alan R. Katritzky
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Patent number: 5298369Abstract: When color reversal materials are developed by a process that comprises prolonged contact with the first, or black-and-white developer, images with a color mismatch or speed deficiency can occur. Such undesirable results can be reduced or eliminated by including in the reversal material, a layer of colloidal elemental silver. The layer can be adjacent to a light sensitive, silver halide-containing layer, which is present within a color record who's speed is to be increased in order to reduce the color mismatch. The amount of colloidal elemental silver employed is less than that used in the art to protect an underlying light sensitive, silver halide layer from exposure by unwanted light.Type: GrantFiled: June 14, 1993Date of Patent: March 29, 1994Assignee: Eastman Kodak CompanyInventors: Jal F. Munshi, Henry J. Sniadoch, Richard C. Tuites
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Patent number: 5292611Abstract: A method for forming a dye image with high contrast is provided, wherein a heat-processable light-sensitive material comprising a support having thereon a non-light-sensitive layer and a light-sensitive layer containing a light-sensitive silver halide and a dye-providing material capable of releasing or forming a diffusible dye upon heat development is subjected to heat development to release or form the diffusible dye, which is transferred to a dye-receiving material having a dye-receiving layer to form a dye image on the dye-receiving layer, wherein the heat development or the transfer of the dye is carried out in the presence of a compounds represented by formula 1 or 2 and a compound represented by formula 3 or 4,(X.sub.1).sub.t --Q formula 1 ##STR1##R.sub.31 --X.sub.2 formula 3R.sub.41 --CO--Y.sub.1 --W.Type: GrantFiled: December 1, 1992Date of Patent: March 8, 1994Assignee: Konica CorporationInventors: Keiji Ohbayashi, Masaru Tsuchiya, Kazuhiro Miyazawa
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Patent number: 5285517Abstract: The invention relates to a high energy beam-sensitive glass (HEBS glass) exhibiting insensitivity and/or inertness to actinic radiation. Silver ion exchange in acidic aqueous solution results in a slab waveguide having a constant refractive index in the thickness dimension. Low loss single mode as well as multimode waveguides were fabricated with a great precision in the designed thickness and step index .DELTA.n. Channel waveguides were patterned and fabricated in one process step within a HEBS glass via a lithographic printing method using a high energy beam. Alternatively, predesigned pattern of channel waveguides were fabricated instantaneously upon direct write with a laser beam pattern generator employing a focused laser beam, within a HEBS glass which has been flood exposed to a high energy beam.Type: GrantFiled: June 26, 1992Date of Patent: February 8, 1994Assignee: Canyon Materials, Inc.Inventor: Che-Kuang Wu
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Patent number: 5275932Abstract: Thermal recording material containing a suitable substrate coated with an image forming layer. The image forming layer contains a thermally reducible source of silver, a 3-indazolinone or urea compound; a polymeric binder; and optionally, an auxiliary reducing agent and toner. Preferably, an anti-stick layer is coated on top of the imaging layer.The 3-indazolinone and urea compounds have been found to enhance the thermal image forming capability of thermal recording material.Type: GrantFiled: July 22, 1992Date of Patent: January 4, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: David C. Weigel, Oanh V. Pham
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Patent number: 5264316Abstract: A light-sensitive material comprises a support and a light-sensitive layer. The light-sensitive layer contains silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound and a base precursor. According to the present invention, the light-sensitive layer further contains a urethane polymer having an amino or imino group. The urethane polymer is dissolved in the ethylenically unsaturated polymerizable compound. The polymer has a molecular weight of not less than 2,000. The silver halide, the reducing agent, the polymerizable compound, the base precursor and the urethane polymer are preferably contained in light-sensitive microcapsules which are dispersed in the light-sensitive layer.Type: GrantFiled: July 27, 1992Date of Patent: November 23, 1993Assignee: Fuji Photo Film Co. Ltd.Inventors: Makoto Yamada, Yoshiharu Yabuki
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Patent number: 5258274Abstract: A thermal-dye-bleach construction comprising a thermal nucleophile-generating agent in association with a styryl dye having a nucleus of general formula (I): ##STR1## representing the nucleus of a styryl dye in which R=methyl or ethyl groupY=alkoxy of 1 to 20 carbon atomsm=1 or 2,n=1, 2, or 3, andx.sup..crclbar. =an anionThe aromatic fused benzene portion of the indolenine ring may be further substituted with commonly acceptable dye substituents such as alkyl and substituted alkyl (of 1 to 10 carbon atoms) groups, alkoxy groups (preferably of 1 to 10 carbon atoms), fused aromatic rings (as to make the benzene ring a fused naphthalene ring), halogen (including fluoro), cyano, nitro, carboxamido, amido, etc. One or two substituents chosen variously from said group may also be present on the phenyl ring to which the alkoxy group is attached.Type: GrantFiled: May 22, 1992Date of Patent: November 2, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Randall H. Helland, George V. D. Tiers, Dian E. Stevenson
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Patent number: 5258281Abstract: A heat-developable photosensitive material which comprises an organic silver salt, a silver halide, a reducing agent and a heat development accelerator having a redox potential ranging from -1.2 V to +1.0 V on the basis of an AgCl/Ag electrode.Type: GrantFiled: November 12, 1991Date of Patent: November 2, 1993Assignee: Canon Kabushiki KaishaInventors: Hiromi Tanaka, Tetsuro Fukui, Motokazu Kobayashi, Kenji Kagami, Masao Suzuki, Tetsuya Higuchi
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Patent number: 5252423Abstract: A light-sensitive material comprises a support and a light-sensitive layer provided thereon which contains silver halide, a reducing agent, a polymerizable compound, a color image forming substance and a base precursor. The silver halide, the reducing agent, the polymerizable compound, the color image forming substance and the base pre cursor are contained in microcapsules which are dispersed in the light-sensitive layer. According to the present invention, the color image forming substance is a coloredsubstance, namely a dye or a pigment, and the microcapsules further contain a polar compound such as an alcohol, an ether, an amide, an urea, an urethane and a sulfonamide. Most of the polar compounds preferably have a molecular weight in the range of 100 to 400. An exceptional polar compound is polyethylene glycol or its derivative, which preferably has a molecular weight in the range of 200 to 20,000.Type: GrantFiled: June 30, 1992Date of Patent: October 12, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Fujio Kakimi, Makoto Yamada
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Patent number: 5238802Abstract: Disclosed is a heat developable light-sensitive material that comprises a support having thereon at least one light-sensitive layer containing a silver halide emulsion, a dye-donating substance and a reducing agent, wherein at least one subbing layer comprised of a hydrophobic polymer is provided between the light-sensitive layer nearlest to the support and the support, and at least one said subbing layer contains a photographic useful reagent.A heat developable light-sensitive material according to this invention, can provide control fogging and raise the maximum density, or can improve the maximum density difference without exerting adverse effects on sensitivity and preservability.Type: GrantFiled: April 13, 1992Date of Patent: August 24, 1993Assignee: Konica CorporationInventors: Keiji Ohbayashi, Masaru Tsuchiya
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Patent number: 5206112Abstract: A photothermographic composite structure for use in a solvent-free dye thermal positive imaging diffusion-transfer process comprising:(a) an image-receiving element comprising a polymeric dyeable image-receiving layer having a glass transition temperature in the range of 20.degree. to 200.degree. C., and(b) strippably adhered to said image-receiving element, an imageable photothermographic element comprising in at least one layer thereof a binder, a silver source material, photosensitive silver halide in catalytic proximity to said silver source material, and a formazan dye.Type: GrantFiled: June 27, 1991Date of Patent: April 27, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard C. Cotner, David C. Weigel, Kumars Sakizadeh
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Patent number: 5196301Abstract: The addition of 3-substituted-5-alkylthio-1,2,4-triazoles to silver halide photothermographic emulsions improves the post-processing stability of the emulsion.Type: GrantFiled: July 30, 1990Date of Patent: March 23, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sharon M. Simpson, John R. Boon, Marco Bucci, Massino Bertoldi, Cristina Soncini, Kumars Sakizadeh
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Patent number: 5192639Abstract: A light-sensitive material comprises a support and a light-sensitive layer provided thereon. The light-sensitive layer contains silver halide, a reducing agent and an ethylenically unsaturated polymerizable compound. According to the present invention, the light-sensitive layer further contains a chromium (VI) compound, a molybdenum (VI) compound or a tungsten (VI) compound.Type: GrantFiled: October 10, 1991Date of Patent: March 9, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroyuki Hirai
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Patent number: 5176990Abstract: A method for forming a photographic element includes steps of heating an emulsion containing grains of a radiation sensitive silver haloiodide to form a first melt, heating an emulsion containing grains of a silver salt effective to enhance the photographic properties of the silver haloiodide emulsion to form a second melt, and coating the first and second melts onto a photographic support to form an image recording layer. The silver salt grains are substantially insensitive to radiation at wavelengths at which said silver haloiodide grains are sensitive. The coating step is preferably carried out by blending the first and second melts together, then immediately coating the silver haloiodide emulsion onto the support. In a preferred embodiment, the silver salt is essentially silver chloride in the form of relatively fine cubic grains, and the silver haloiodide is in the form of tabular grains larger than the cubic grains.Type: GrantFiled: December 21, 1990Date of Patent: January 5, 1993Assignee: Eastman Kodak CompanyInventor: Sang H. Kim
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Patent number: 5175081Abstract: The post-processing stability of silver halide photothermographic emulsions is enhanced by the presence of stabilizing amounts of certain azlactones.Type: GrantFiled: May 6, 1992Date of Patent: December 29, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Larry R. Krepski, Kumars Sakizadeh, Sharon M. Simpson, David R. Whitcomb
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Patent number: 5167875Abstract: An aqueous silver sulfide sol is prepared which has an absorption spectrum such that its optical density at 360 nm is at least 100 times its optical density at 700 nm. The sol is ultrafine in particle size and is useful for the chemical sensitization of silver halide emulsions and for the preparation of development layers for the silver complex diffusion transfer copying process or the production of optical filters.Type: GrantFiled: October 23, 1989Date of Patent: December 1, 1992Assignee: Agea-Gevaert N. V.Inventors: Gino L. De Rycke, Freddy Henderickx
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Patent number: 5158866Abstract: The post-processing stability of silver halide photothermographic emulsions is enhanced by the presence of stabilizing amounts of certain structurally defined amido compounds.Type: GrantFiled: August 31, 1990Date of Patent: October 27, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sharon M. Simpson, Larry R. Krepski, Kumars Sakizadeh, David R. Whitcomb
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Patent number: 5151357Abstract: A novel silver halide photographic material is described, comprising a compound represented by formula (I): ##STR1## wherein Q represents a nonmetallic atomic group required to be connected to carbon atom and nitrogen atom to form a monocyclic or condensed heterocyclic ring therewith; L represents a divalent group; n represents an integer of 0 to 2; M.sup.1 represents a hydrogen atom, ammonium ion or metallic ion; and R.sup.1 and R.sup.2 each represents a hydrogen atom, alkyl group, ammonium ion or metallic ion and may be the same or different or may be connected to each other to form a 5- or 6-membered ring. In a preferred embodiment, at least one of R.sup.2 and R.sup.1 represents a hydrogen atom, ammonium ion or metallic ion.Type: GrantFiled: October 31, 1990Date of Patent: September 29, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Tomoyuki Koide, Naoto Matsuda, Koki Nakamura, Tetsuro Kojima
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Patent number: 5149620Abstract: The addition of certain 5-mercapto-1,2,4-triazoles to silver halide photothermographic emulsions improves the post-processing image stability of those emulsions.Type: GrantFiled: July 30, 1990Date of Patent: September 22, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Sahron M. Simpson, John R. Boon, Marco Bucci, Massimo Bertoldi, Cristina Soncini, Kumars Sakizadeh
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Patent number: 5116716Abstract: Disclosed is a heat-developable color photographic material containing a compound represented by Formula (1) shown below: ##STR1## wherein X represents a halogen atom, and Y represents a group of nonmetallic atoms necessary for forming a nitrogen-containing heterocyclic ring bearing on the ring at least one substituent having 4 or more carbon atoms.Disclosed is also a process for forming an image on a heat-developable color photographic material, which comprises carrying out heat-development processing in the presence of the compound represented by Formula (1) mentioned above.Type: GrantFiled: April 29, 1991Date of Patent: May 26, 1992Assignee: Konica CorporationInventors: Tawara Komamura, Masaru Iwagaki, Hiroyuki Kaguchi
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Patent number: 5093229Abstract: A heat developable light-sensitive material comprising a support having thereon at least one layer containing a base precursor, a lgiht-sensitive silver halide, a binder, and a dye-providing substance which produces or releases a diffusible dye in correspondence or countercorrespondence to the reduction of the light-sensitive silver halide to silver at an elevated temperature, the base precursor comprising a salt of a carboxylic acid and a diacidic, triacidic or tetraacidic organic base comprising a hydrocarbon group or a heterocyclic group substituted with 2 to 4 amidine groups represents by formula (I-2): ##STR1## wherein R.sup.15, R.sup.16 and R.sup.17 are as defined in the specification. The heat developable light-sensitive material has excellent age preservability and provides a high sensitivity and low-fog image.Type: GrantFiled: August 25, 1988Date of Patent: March 3, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshiharu Yabuki, Hiroyuki Hirai
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Patent number: 5089378Abstract: A method for forming an image comprising heating a heat-developable light-sensitive material comprising a support having thereon at least a light-sensitive silver halide and a binder, simultaneously with or after imagewise exposure thereof in the presence of water, at least one of a base and a base precursor, and an acetylene compound represented by formula (I):R.sub.1 --C.tbd.C--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, a carboxyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, or a substituted or unsubstituted carbamoyl group; provided that both R.sub.1 and R.sub.2 do not represent hydrogen atoms at the same time.Type: GrantFiled: March 20, 1991Date of Patent: February 18, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Ozaki, Ken Kawata, Hideki Ohmatsu
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Patent number: 5084376Abstract: There is disclosed a heat-developable color light-sensitive material having an excellent preservability and capable of providing images having a superior discrimination and only a slight fluctuation of Dmin against that of the development conditions. The material comprises a support having thereon a light-sensitive silver halide, a dye donor and a compound represented by following Formula I: ##STR1## wherein X represents a group capable of splitting off in heat-development; Y represents the group of atoms necessary to form 5- or 6-membered heterocyclic ring; Z represents a substituent; and n represents an integer of 0 to 4.Type: GrantFiled: May 14, 1991Date of Patent: January 28, 1992Assignee: Konica CorporationInventors: Yoshihiko Suda, Hidenobu Ohya, Kazuhiro Miyazawa, Tawara Komamura, Norio Miura
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Patent number: 5082763Abstract: A heat developable photosensitive material comprising a support having thereon at least one photosensitive silver halide emulsion layer, which contains at least one compound selected from those represented by the following general formulae (I) and (II) to acquire a high S/N ratio and high sensitivity: ##STR1## wherein R represents an alkylene group, an alkenylene group, an aralkylene group or an arylene group, which each may be substituted; Y represents ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9 and R.sub.Type: GrantFiled: March 5, 1991Date of Patent: January 21, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuro Kojima, Tomoyuki Koide
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Patent number: 5079137Abstract: A heat-developable color photographic light-sensitive material capable of giving positive color images having high maximum density, low minimum density, and less strain, comprising at least a light-sensitive silver halide, a binder, a dye-providing non-diffusible compound capable of releasing a diffusible dye on being reduced, and a reducing agent, wherein the light-sensitive material further contains at least one compound represented by the following formula (I), (II), or (III); ##STR1## wherein R.sup.1 and R.sup.2 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group, with a proviso that R.sup.1 and R.sup.2 each represents a group having no redox activity after its cleavage and R.sup.3 and R.sup.4 each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group.Type: GrantFiled: August 1, 1990Date of Patent: January 7, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Takayuki Ito
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Patent number: 5071740Abstract: A heat developable color photosensitive material capable of forming color images in a heat development, more particularly, capable of obtaining heat developable color diffusion transfer images substantially high in a maximum density. The heat developable color photosensitive material contains at least two photosensitive layers which are different from each other in color sensitivity and a non-photosensitive interlayer containing particles interposed between the photosensitive layers.Type: GrantFiled: June 20, 1990Date of Patent: December 10, 1991Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Ken Okauchi, Toyoaki Masukawa
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Patent number: 5064753Abstract: The present invention relates to a heat-developable light-sensitive material, or a light-sensitive material that produces image by development through dry heat treatment. The present invention provides a heat-developable light-sensitive material that achieves high sensitivity while experiencing a reduced degree of thermal fogging by employing core/shell type silver halide grains that contain 4-40 mol % of silver iodide and which have a lower silver iodide content in the surface layer than in the internal phase.Type: GrantFiled: August 30, 1990Date of Patent: November 12, 1991Assignee: Konica CorporationInventors: Goto Sohei, Okauchi Ken, Kohno Junichi, Iwagaki Masaru
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Patent number: 5064744Abstract: A photosensitive material comprises a photosensitive and heat-developable element and a photopolymerizable element which are contained in the same layer. The photopolymerizable element comprises at least a polymerizable polymer precursor having a melting point of 35.degree. C. or more. The photosensitive material is exposed to light with at least one wavelength within the wavelength region of from 400 nm to 900 nm, heated at 60.degree. to 180.degree. C., and exposed to light with at least one wavelength within the wavelength region of from 250 to 700 nm, and thus an unexposed area in the photosensitive layer which is an area not exposed to light with at least one wavelength within the wavelength region of from 400 nm to 900 nm is polymerized.Type: GrantFiled: February 7, 1990Date of Patent: November 12, 1991Assignee: Canon Kabushiki KaishaInventors: Tetsuro Fukui, Hiroshi Fukumoto, Masato Katayama, Kozo Arahara, Kenji Kagami
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Patent number: 5051349Abstract: A heat developable color photographic material is disclosed, comprising a support having thereon at least a photosensitive silver halide, a binder, and a dye providing compound capable of releasing or forming a diffusible dye in correspondence or counter-correspondence to reduction of the silver halide to silver, said heat developable color photosensitive material further comprising a compound represented by formula (I):C.sub.6n (H.sub.2 O).sub.5n+1 (I)wherein n represents an integer of 1 or more. The material exhibits excellent raw preservability and provides a stain-free color image having a high maximum density.Type: GrantFiled: March 8, 1990Date of Patent: September 24, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Hiroyuki Hirai
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Patent number: 5051335Abstract: A novel heat developable light-sensitive material is disclosed, comprising light-sensitive silver halide emulsion layers on a paper support, wherein at least one subbing layer capable of inhibiting fog is provided interposed between the undermost layer among said light-sensitive silver halide emulsion layers and said paper support. In a preferred embodiment, the subbing layer comprises a binder and at least one material capable of inhibiting fog.Type: GrantFiled: January 26, 1989Date of Patent: September 24, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Masatoshi Kato
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Patent number: 5051348Abstract: A heat-developable color light-sensitive material comprising a support having thereon at least a light-sensitive silver halide, a binder, a dye providing compound capable of releasing or forming a diffusible dye in correspondence or counter-correspondence to a reaction in which silver halide is reduced to silver, a basic metal salt compound which is sparingly soluble in water, and at least one acid precursor compound represented by formula (I) or formula (II): ##STR1## wherein the total number of carbon atoms included in R.sup.1 and R.sup.2 is at least 10, and R.sup.1 and R.sup.2 each represents a group represented by formula (III) or formula (IV): ##STR2## wherein R.sup.11, R.sup.12, R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17 and R.sup.18 each represents a substituent, provided that R.sup.1 and R.sup.2 are selected such that the sum of the aliphatic Taft's constants (.sigma.* value) of the substituents represented by formula (III), the Taft's constants (.sigma.-value) of R.sup.14 and R.sup.Type: GrantFiled: May 25, 1990Date of Patent: September 24, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Toshiki Taguchi, Ken Kawata
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Patent number: 5045427Abstract: The present invention provides a photographic material containing a non-photosensitive silver salt comprising a photosensitive silver halide, a non-photosensitive silver salt, a reducing agent, a polymerizable compound and a color image-forming substance provided on a support, wherein at least said polymerizable compound and said color image-forming substance are contained in the same microcapsules so that said color image-forming substance may be converted into an imagewise immobile state after the material has been imagewise exposed to light and then heated. Said material has a high sensitivity and may form a color image having an absorption in a visible range, by light-exposure for a short period of time followed by a dry and rapid photographic treatment.Type: GrantFiled: June 7, 1989Date of Patent: September 3, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Hiroshi Hara
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Patent number: 5041368Abstract: Radiation sensitive thermally developable imaging elements comprise:(a) photosensitive silver halide,(b) light insensitive silver salt oxidizing agent,(c) reducing agent for silver ions, and(d) an antifoggant or speed enhancing compound comprising iodophthalazinone compounds. The antifoggants are effective in reducing spurious background image densities.Type: GrantFiled: June 7, 1990Date of Patent: August 20, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventor: Oanh V. Pham
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Patent number: 5041353Abstract: A process for preparation of a light-sensitive material is disclosed. The light-sensitive material comprises a support and a light-sensitive layer which contains light-sensitive silver halide, a reducing agent, a base precursor and an ethylenic unsasturated polymerizable compound. The process comprises emulsifying an aqueous dispersion of a base precursor in an oily medium containing the polymerizable compound in the range of 0.1 to 100 weight %.Type: GrantFiled: December 31, 1990Date of Patent: August 20, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiji Takeda
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Patent number: 5041369Abstract: A photosensitive material comprises a photosensitive and heat-developable element, and further a light-to-heat conversion element or a nonlinear optical function element. The photosensitive and heat-developable element comprises at least a photosensitive silver halide, an organic silver salt and a reducing agent. The light-to-heat conversion element comprises at least one of an inorganic metal and an organic coloring matter. The nonlinear optical function element comprises a comprises a compound selected from the group consisting of an inorganic crystal, an organic crystal, a polymer, a polymeric liquid crystal, a polymeric composition and a polymeric liquid crystal composition. An image forming method employing the photosensitive material comprises the steps of imagewise exposing the material by use of a laser beam, heating the material and forming a polymer image on the material.Type: GrantFiled: March 13, 1989Date of Patent: August 20, 1991Assignee: Canon Kabushiki KaishaInventors: Tetsuro Fukui, Kazuo Yoshinaga, Hideaki Mitsutake, Katsuya Oikawa, Shinsuke Takeuchi, Takeshi Miyazaki, Yoshio Takasu, Akihiro Mouri, Masato Katayama, Kazuo Isaka
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Patent number: 5039589Abstract: A light-sensitive material comprising a support and a light-sensitive layer provided thereon is disclosed. The light-sensitive layer contains silver halide, a reducing agent, an ethylenically unsaturated polymerizable compound and a base precursor composed of a salt of a carboxylic acid with an organic base. The silver halide, reducing agent, polymerizable compound and base precursor are contained in microcapsules which are dispersed in the light-sensitive layer. The microcapsules are obtained by (1) dispersing the base precursor in water, (2) emulsifying the resulting dispersion in the polymerizable compound, (3) further emulsifying the resulting emulsion in an aqueous medium containing a nonionic water-soluble polymer and (4) forming the shell of the microcapsules. It is preferred that the base precursor is dispersed in water in the presence of a nonionic water-soluble polymer or an emphoteric water-soluble polymer, and the resulting dispersion is emulsified in the polymerizable compound.Type: GrantFiled: June 20, 1990Date of Patent: August 13, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Ryuichi Takahashi
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Patent number: 5037719Abstract: An image-forming method for a light-sensitive material comprising a support and a light-sensitive layer containing silver halide, an ethylenically unsaturated polymerizable compound, a base or base precursor and a salt of a reducing agent, wherein a heat development process is performed simultaneously with or after an imagewise exposure in the presence of the base or base precursor activator to release the reducing agent from the salt and to imagewise polymerize the polymerizable compound.Type: GrantFiled: August 9, 1990Date of Patent: August 6, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Koichi Nakamura
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Patent number: 5032499Abstract: There is disclosed a thermal developing light-sensitive material comprising a support and, provided thereon, photographic structural layers comprising at least one layer containing light-sensitive silver halide, said photographic structural layer comprising a compound represented by general formula (1);Formula (1)X.sub.1 --L.sub.1 --Awherein X.sub.1 represents a residual group of a photographic restrainer, L.sub.1 is a mere bonding hand or a divalent group and A is selected from the group consisting of a hydrogen atom, an amino group, a hydroxyl group, a carboxyl group or a salt thereof, a sulfo group or a salt thereof and a sulfin group or a salt thereof;and a compound represented by general formula (2);Formula (2)X.sub.2 --L.sub.2 --Bwherein X.sub.2 represents a residual group of a photographic restrainer, L.sub.2 is a divalent group and B is a ballast group.Type: GrantFiled: July 25, 1989Date of Patent: July 16, 1991Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Junichi Kohno, Tawara Komamura, Ken Okauchi