Containing Amino Or Substituted Amino Group Patents (Class 430/73)
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Patent number: 7700251Abstract: An electrophotographic photoconductor having an excellent crack resistance and wear resistance as well as excellent sensitivity characteristics, while keeping good image characteristics of the photoconductor is provided. In addition, an image-forming apparatus equipped with such an electrophotographic photoconductor is also provided. The electrophotographic photoconductor includes a photosensitive layer containing at least a charge-generating agent, a hole-transfer agent, and a binder resin on a conductive substrate.Type: GrantFiled: October 18, 2006Date of Patent: April 20, 2010Assignee: Kyocera Mita CorporationInventors: Norio Nakai, Kazunari Hamasaki, Daisuke Kuboshima, Yoshio Inagaki, Hideki Okada, Tetsuya Ichiguchi, Keiji Maruo
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Publication number: 20100028792Abstract: A developer bearing member is provided which can charge a toner stably and uniformly during the period from the initial stage to the terminal stage of extensive operation even in various environments. The developer bearing member includes a substrate and an electrically conductive resin coating layer formed on the surface thereof. The electrically conductive resin coating layer is formed from a resin composition containing a phenolic resin having in its structure at least one of an —NH2 group, an ?NH group and an —NH— linkage, a quaternary phosphonium salt and electrically conductive fine particles and the resin composition contains 1 part by mass or more and 60 parts by mass or less of the quaternary phosphonium salt with respect to 100 parts by mass of the phenolic resin.Type: ApplicationFiled: July 23, 2009Publication date: February 4, 2010Applicant: CANON KABUSHIKI KAISHAInventors: Satoshi Otake, Masayoshi Shimamura, Yasutaka Akashi, Takuma Matsuda, Minoru Ito, Kazuhito Wakabayashi
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Publication number: 20100015542Abstract: The present invention provides p-terphenyl compounds represented by the following general formula (1) and (2): and an electrophotographic photoconductor containing the compound. According to the invention, a charge transporting agent having improved solubility in an organic solvent and an electrophotographic photoconductor excellent in drift mobility and having high sensitivity and high durability are provided.Type: ApplicationFiled: September 29, 2009Publication date: January 21, 2010Applicant: Hodogaya Chemical Co., Ltd.Inventors: Katsumi Abe, Atsushi Takesue, Shinya Nagai, Mitsutoshi Anzai
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Publication number: 20090311616Abstract: An electrophotographic photoconductor including an electroconductive support and a photoconductive layer provided thereon, wherein the photoconductive layer includes a charge generating material, an electron transporting material and a hole transporting material, the electron transporting material being a diphenoquinone compound represented by formula (1) described herein, the hole transporting material being a compound represented by formula (2) described herein.Type: ApplicationFiled: June 9, 2009Publication date: December 17, 2009Inventors: Keisuke SHIMOYAMA, Eiji KURIMOTO, Takaaki IKEGAMI, Kohsuke YAMAMOTO, Tadayoshi UCHIDA, Takumi SHINOHARA, Hajime SUZUKI
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Patent number: 7625682Abstract: An electrophotographic photoreceptor having an organic photosensitive layer at the surface layer is provided which can improve the wear resistance, durability and operation stability of the surface layer and can form images with no injury and unevenness in the density for a long period of time. The electrophotographic photoreceptor includes a conductive substrate, an undercoat layer, and a photosensitive layer having a charge generating layer and a charge transporting layer. In the photoreceptor, the photosensitive layer has a creep value CI? of 2.70% or more and an elastic ratio ?HU of 47% or more in a case where an indentation maximum load of 5 mN is loaded on the surface under a circumstance at a temperature of 25° C. and at a relatively humidity of 50%.Type: GrantFiled: August 8, 2005Date of Patent: December 1, 2009Assignee: Sharp Kabushiki KaishaInventors: Tomoko Kanazawa, Kotaro Fukushima
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Patent number: 7625681Abstract: There is provided an organic photoconductive material that can realize an electrophotographic photoreceptor which is not only excellent in charge transporting ability but also excellent in solubility in a solvent and compatibility with a resin and moreover, which is excellent in both electric properties and durability, and the organic photoconductive material that is useful also as a raw material compound for various types of functional materials. An asymmetric bis-hydroxyenamine compound represented by the following structural formula (1aa) is provided. The compound is allowed to be contained in a charge transporting layer or a surface protective layer of an electrophotographic photoreceptor. This leads realization of the electrophotographic photoreceptor which is excellent in electric properties and durability and can stably form an image of high quality being free of an image defect such as a black spot.Type: GrantFiled: May 31, 2006Date of Patent: December 1, 2009Assignee: Sharp Kabushiki KaishaInventors: Akihiro Kondoh, Hiroshi Sugimura, Takatsugu Obata
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Patent number: 7622232Abstract: An electrophotographic photoreceptor including a photosensitive layer which includes a titanyl phthalocyanine crystal having a major absorption peak at a wavelength of 780 nm±10 nm and a minor absorption peak having an intensity of ¾ or less of the major absorption peak at 690 nm±10 nm in the visible-infrared absorption spectrum and a distyryl compound having a predetermined structure. An electrophotographic image forming apparatus employing the electrophotographic photoreceptor is also provided. The electrophotographic photoreceptor and the electrophotographic image forming apparatus have good photosensitivity and charging properties and good stability over repeated charging obtained by using an optimum combination of a new crystal type of a highly photosensitive titanyl phthalocyanine and a distyryl compound which is a charge transporting material that is compatible with the titanyl phthalocyanine.Type: GrantFiled: December 14, 2006Date of Patent: November 24, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Saburo Yokota, Seung-ju Kim
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Patent number: 7615326Abstract: A charge transporting substance having three stilbene structures or butadiene structures in a molecule, represented by the following general formula is used as an organic photoconductive material. An electrophotographic photoconductor is prepared by causing a photosensitive layer which is disposed on a conductive support, to contain the organic photoconductive material in order to dispose the photoconductor to an image forming apparatus.Type: GrantFiled: June 1, 2007Date of Patent: November 10, 2009Assignee: Sharp Kabushiki KaishaInventors: Takatsugu Obata, Akihiro Kondoh
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Patent number: 7588871Abstract: An electrophotographic photoreceptor having excellent electric characteristics such as sensitivity characteristic and light responsiveness with an excellent life duration of abrasion resistance so that no flaw and density unevenness are generated on to-be-formed images for a long period of time, is provided. In an electrophotographic photoreceptor (1), an enamine compound represented by the following general formula (1), for example, an enamine compound represented by the following structural formula (1-1) is contained in a charge transporting layer (6), and a creep value (CIT) in a case where a maximum indentation load of 30 mN is put on a surface for 5 seconds under circumstances of temperature of 25° C. and relative humidity of 50%, is set to 2.70% or more and 5.00% or less, and a plastic deformation hardness value (Hplast) of the surface is set to 220 N/mm2 or more and 275 N/mm2 or less.Type: GrantFiled: October 8, 2004Date of Patent: September 15, 2009Assignee: Sharp Kabushiki KaishaInventors: Akiko Kihara, Kotaro Fukushima, Takatsugu Obata
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Publication number: 20090214968Abstract: A mixture of bisamine compounds comprising a bisamine compound represented by Formula (1) and a bisamine compound represented by Formula (2): A-X-A??Formula (1) A-X—B??Formula (2) wherein, A and B represent a different substituted amino group represented by Formula (3), X represents a bivalent linkage group: wherein, each of Ara and Arb independently represents an aryl group which may have a substituted group, and Arc represents an arylene group which may have a substituted group, and Ara, Arb and Arc may be combined to form a ring structure.Type: ApplicationFiled: February 18, 2009Publication date: August 27, 2009Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Shinichi Hamaguchi, Toyoko Shibata, Tomoko Sakimura
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Patent number: 7563553Abstract: A process for making an electrophotographic photosensitive member is provided by forming a photosensitive layer on an electroconductive support. The photosensitive layer is provided with particularly excellent durability while retaining good electrophotographic performances when formed as a layer comprising a polymerizate of a hole-transporting compound having at least two chain polymerization function groups in its molecule represented by formula (1) below: (P1aAzP2)d)b??(1), wherein A denotes a hole-transporting group, P1 and P2 independently denote a chain polymerization function group and Z denotes a bonding organic group; a, b and d are independently an integer of at least 0 satisfying a+b×d?2 provided that if a?2, plural groups P1 can be identical or different; if b?2, plural groups Z can be identical or different; and if b×d?2, plural groups P2 can be identical or different.Type: GrantFiled: January 26, 2007Date of Patent: July 21, 2009Assignee: Canon Kabushiki KaishaInventors: Toshihiro Kikuchi, Akio Maruyama, Hiroki Uematsu
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Patent number: 7563548Abstract: An amine compound represented by the general formula (1), which is incorporated as a charge-transporting substance to a charge-transporting layer of an electrophotographic photoreceptor: (in which Ar1, Ar2 and Ar3 each represents an optionally-substituted aryl group, or an optionally-substituted monovalent heterocyclic ring residue. Ar4 represents an optionally-substituted arylene group, or an optionally-substituted bivalent heterocyclic ring residue. R1 represents an optionally-substituted alkyl group, an optionally-substituted aryl group, an optionally-substituted monovalent heterocyclic ring residue, or an optionally-substituted aralkyl group. R2 and R3 each represents a hydrogen atom, an optionally-substituted alkyl group, an optionally-substituted aryl group, an optionally-substituted monovalent heterocyclic ring residue, or an optionally-substituted aralkyl group. n represents an integer of 1 or 2.Type: GrantFiled: November 30, 2004Date of Patent: July 21, 2009Assignee: Sharp Kabushiki KaishaInventors: Akihiro Kondoh, Takatsugu Obata
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Publication number: 20090053634Abstract: To provide a toner excellent in the image stability, whereby the image quality can be improved while suppressing soiling of image white parts, residual images (ghosts), fading (blotted image follow-up properties), etc., cleaning properties are good, and even when a high speed printing machine is used, it is possible to reduce a problem of soiling, etc. An image forming apparatus comprising an electrophotographic photoreceptor and a toner for developing an electrostatic charge image, wherein a photosensitive layer of the electrophotographic photoreceptor contains a resin having a structural unit represented by the following formula (A); the toner for developing an electrostatic charge image is a toner for developing an electrostatic charge image containing toner matrix particles formed in an aqueous medium; the toner has a volume median diameter (Dv50) of from 4.0 ?m to 7.Type: ApplicationFiled: March 30, 2007Publication date: February 26, 2009Applicant: Mitsubishi Chemical CorporationInventors: Teruyuki Mitsumori, Kozo Ishio, Hiroaki Takamura, Masaya Oota, Shiho Sano, Takeshi Oowada, Masakazu Sugihara, Teruki Senokuti, Shiro Yasutomi, Yumi Hirabaru
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Publication number: 20080286673Abstract: The present invention provides a single layer type electrophotographic photoconductor which exhibits the small number of generated black spots in a formed image and exhibits the excellent sensitivity characteristic even when the photoconductor is used for a long time or a photoconductor drum is rotated at a high speed and an image display device which includes the single layer type electrophotographic photoconductor. In the single layer type electrophotographic photoconductor which includes a photoconductive layer containing a binding resin, a hole transporting agent and an charge generating agent, the photoconductor contains a water-repellant polycarbonate resin as the binding resin, and a contact angle of pure water (measured temperature: 25° C.) with respect to the photoconductive layer is set to 100° or more.Type: ApplicationFiled: July 18, 2008Publication date: November 20, 2008Inventors: Daisuke Kuboshima, Kazunari Hamasaki, Norio Nakai
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Patent number: 7452640Abstract: An object of the present invention is to provide an electrophotographic photoconductor for liquid development, having high resistance to a carrier solvent for use in a liquid developing method and having practically high sensitivity, an image-forming apparatus including the photoconductor, and an image forming method. To achieve this object, the present invention provides an electrophotographic photoconductor for liquid development including a support, and a photosensitive layer on or above the support, wherein the photosensitive layer includes a charge-generating material, a charge-transporting material, and an acceptor compound, and the charge-transporting material includes a charge-transporting polymer having a specified structure.Type: GrantFiled: July 28, 2005Date of Patent: November 18, 2008Assignee: Ricoh Company, Ltd.Inventors: Masayuki Shoshi, Masaomi Sasaki, Akio Kojima
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Patent number: 7445877Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 comprise, independently, an aromatic group; X1 and X2 are each a linking group; W1 and W2 are each a —(CH2)n— group or a —(CH2)n-1—C(?O)— group, where n is an integer between 1 and 10; Ar1 and Ar2 comprise each a divalent aromatic group; Q1 and Q2 are each O, S, or NR; Z1 and Z2 comprise, independently, a bond, a vinyl group, a —CR1?N—NR2— group, or a —CR3?N—N?CR4— group; and R, R1, R2, R3, and R4 comprise, independently, H, an alkyl group, an alkenyl group, an alkynyl group, an acyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: June 10, 2004Date of Patent: November 4, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Maryte Daskeviciene, Valentas Gaidelis, Vytautas Getautis, Edmundas Montrimas, Albina Stanisauskaite
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Patent number: 7427460Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Ar is an aryl group; X comprises a bond or a linking group; R1, R2, and R3 each comprise H, a carboxyl, an amino group, a halogen, an alkyl group, an acyl group, an alkoxy group, an alkylsulfanyl group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; R4 comprises H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and R5, R6, R7, and R8 each comprise an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: July 30, 2004Date of Patent: September 23, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Ruta Budreckiene, Gintaras Buika, Vygintas Jankauskas, Juozas V. Grazulevicius, Jonas Sidaravicius, Nusrallah Jubran, Zbigniew Tokarski
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Patent number: 7416824Abstract: According to the present invention, an enamine compound having a specific structure is used as an organic photoconductive material. This enamine compound is obtained based on asymmetrical secondary naphtylamine which is readily available at a lowest price, by introducing phenyl groups containing substituents, as constituents units of the enamine part and presents excellent compatibility with binder resins, will not present detrimental effects such as partial crystallization at film forming and have a high charge mobility. The compound is able to realize highly reliable electrophotographic photoreceptor and an image forming apparatus which present a high electrostatic potential, high sensitivity and high enough light response and are excellent in durability and will not degrade in these characteristics under a low-temperature environment or in a high-speed process and will not lower in these characteristics even due to exposure to light.Type: GrantFiled: May 10, 2004Date of Patent: August 26, 2008Assignee: Sharp Kabushiki KaishaInventors: Akihiro Kondoh, Takatsugu Obata, Kazuya Ishida
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Patent number: 7416825Abstract: The present invention provides a single layer type electrophotographic photoconductor which exhibits the small number of generated black spots in a formed image and exhibits the excellent sensitivity characteristic even when the photoconductor is used for a long time or a photoconductor drum is rotated at a high speed and an image display device which includes the single layer type electrophotographic photoconductor. In the single layer type electrophotographic photoconductor which includes a photoconductive layer containing a binding resin, a hole transporting agent and an charge generating agent, the photoconductor contains a water-repellant polycarbonate resin as the binding resin, and a contact angle of pure water (measured temperature: 25° C.) with respect to the photoconductive layer is set to 100° or more.Type: GrantFiled: January 4, 2006Date of Patent: August 26, 2008Assignee: Kyocera Mita CorporationInventors: Daisuke Kuboshima, Kazunari Hamasaki, Norio Nakai
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Patent number: 7387862Abstract: An electrophotographic photoreceptor is provided that in excellent in the electrical characteristics such as the charging property, the sensitivity and the responsiveness, the oxidizing gas resistance such as the ozone resistance and the nitrogen oxide resistance, and the electrical durability such that even after repetition use the foregoing excellent electrical characteristics are not deteriorated. A photosensitive layer of an electrophotographic photoreceptor contains an amine compound represented by the general formula (1).Type: GrantFiled: May 23, 2005Date of Patent: June 17, 2008Assignee: Sharp Kabushiki KaishaInventors: Koichi Toriyama, Kotaro Fukushima, Hisayuki Utsumi
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Patent number: 7365230Abstract: The present invention relates to novel cross-linkable polymers and a wide variety of electronic devices containing at least one layer having the polymer. The compounds can function as monomers, and copolymers can be formed from such monomers, such copolymers comprising, as polymerized units, a plurality of units of the compounds.Type: GrantFiled: February 20, 2004Date of Patent: April 29, 2008Assignee: E.I. du Pont de Nemours and CompanyInventors: Norman Herron, Gary A. Johansson, Nora Sabina Radu
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Patent number: 7351508Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y comprises an aromatic group; V1 and V2 comprise, each independently, a vinyl containing group; and R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an acyl group, an ether group, an ester group, an alkenyl group, an alkynyl group, a heterocyclic group, an aromatic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, electrophotographic imaging methods, and charge transport materials are also described.Type: GrantFiled: October 12, 2004Date of Patent: April 1, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Juozas V. Grazulevicius, Gintaras Buika, Vygintas Jankauskas, Valentas Gaidelis, Ruta Budreckiene, Zbigniew Tokarski, Nusrallah Jubran
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Patent number: 7345141Abstract: The present invention provides a polymer material having a carrier transport property. The polymer material has first and second states in which degrees of the carrier transport property are different from each other, microscopic structures in the first and second states are different from each other, and one of the first and second states can be changed into the other state.Type: GrantFiled: November 15, 2002Date of Patent: March 18, 2008Assignee: Sharp Kabushiki KaishaInventors: Masanobu Mizusaki, Motohiro Yamahara
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Patent number: 7344811Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a polymeric charge transport material having the formula where n and m are each a distribution of integers, and the n units of R1—Si—X1—Ar1 and m units of R2—Si—X2—Ar2—X3-Z form either a random, an alternative, or a block copolymer; R1 and R2 comprise, each independently, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; X1, X2, and X3 comprise, each independently, a bond or a linking group; A1 and A2 are each a terminal group; Ar1 and Ar2 comprise, each independently, an aromatic group; and Z comprises a functional group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of preparing the polymeric charge transport material are described.Type: GrantFiled: October 28, 2004Date of Patent: March 18, 2008Assignee: Samsung Electronic Co., Ltd.Inventors: Asta Michaleviciute, Gintaras Buika, Juozas V. Grazulevicius, Zaimantas Peleckas, Edmundas Montrimas, Jonas Sidaravicius
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Patent number: 7320849Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Y1 and Y2 are, each independently, an arylamine group; R1 and R2 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X1 and X2, each independently, are bridging groups; E1 and E2 are, each independently, an epoxy group; and Z is a linking group comprising an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound. The charge transport materials can be crosslinked to a polymeric bind, either directly or through a crosslinking agent. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: December 31, 2003Date of Patent: January 22, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Vytautas Getautis, Tadas Malinauskas, Vygintas Jankauskas, Valentas Gaidelis
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Patent number: 7316878Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where Ar comprises an aromatic group; X comprises a bond or a linking group; and R1, R2, R3, R4, and R5 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: August 30, 2004Date of Patent: January 8, 2008Assignee: Samsung Electronics Co., Ltd.Inventors: Ruta Budreckiene, Gintaras Buika, Juozas V. Grazulevicius, Vygintas Jankauskas, Jonas Sidaravicius, Nusrallah Jubran, Zbigniew Tokarski
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Publication number: 20070281226Abstract: An electrophotographic imaging member includes at least one layer including a hole transport material and a strong electron acceptor material, such as an electro photographic imaging member including a substrate, a charge generating layer, a hole transport layer, and an optional overcoating layer, wherein at least one layer of the electrophotographic imaging member comprises a strong electron acceptor material.Type: ApplicationFiled: June 5, 2006Publication date: December 6, 2007Applicant: XEROX CORPORATIONInventors: Hany AZIZ, Gregory McGuire, Johann Junginger
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Publication number: 20070281229Abstract: A charge transporting substance having three stilbene structures or butadiene structures in a molecule, represented by the following general formula is used as an organic photoconductive material. An electrophotographic photoconductor is prepared by causing a photosensitive layer which is disposed on a conductive support, to contain the organic photoconductive material in order to dispose the photoconductor to an image forming apparatus.Type: ApplicationFiled: June 1, 2007Publication date: December 6, 2007Applicant: SHARP KABUSHIKI KAISHAInventors: Takatsugu Obata, Akihiro Kondoh
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Publication number: 20070275314Abstract: The present invention provides a diphenyl amine derivative having the excellent solubility to a solvent and compatibility to a binding resin, an efficient production method therefor, and an electrophotographic photoconductor having the excellent sensitivity, capable of effectively preventing generation of the black dots. A diphenyl amine derivative represented by the following general formula (1) is used: (In the general formula (1), R1 to R12 each are a hydrogen atom, an alkyl group which may have a substituent, or the like, Z is a ring structure linked with a benzene ring, which is a 4 to 8-membered ring including a hydrogen atom, a nitrogen atom, an oxygen atom, a carbon atom or a sulfur atom, m1, m2, n1, n2 each are 0 or 1, m1+n1 is 1 or 2, and m2+n2 is 1 or 2.Type: ApplicationFiled: April 26, 2007Publication date: November 29, 2007Inventor: Hideki Okada
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Patent number: 7300732Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula, where R comprises a hydrogen, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X comprises an arylamine group; and Y comprises a 9-fluorenylidene group having at least a solubilizing substituent; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: February 10, 2004Date of Patent: November 27, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Kam W. Law
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Patent number: 7291431Abstract: This invention relates to a novel organophotoreceptor that comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a novel charge transport compound having the formula where X is a divalent hydrocarbon group of 1 to 30 carbon atoms, or a divalent hydrocarbon group of 1 to 30 carbon atoms where there is at least one substitution of a carbon atom by a heteroatom provided that no two heteroatoms may be adjacent within the backbone of an aliphatic divalent hydrocarbon radical, R1 is an aryl group or a heterocyclic group, R2 is a (N,N-disubstituted)arylamine group, and R3 is an epoxy group; and (b) a charge generating compound. The epoxy group can be reacted with a functional group within the polymer to form a polymeric charge transport compound either directly or through a crosslinking agent.Type: GrantFiled: March 2, 2006Date of Patent: November 6, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law, Vytautas Getautis, Jonas V. Sidaravicius, Maryte Daskeviciene, Vygintas Jankauskas, Edmundas Montrimas, Valentas Gaidelis, Albina Stanisauskaite
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Publication number: 20070248901Abstract: An electrophotographic photoconductor contains a photosensitive layer and a conductive substrate, wherein the photosensitive layer is disposed on the conductive substrate, and the photosensitive layer is a single layer containing a charge generating material, an electron transporting material expressed by the General Formula (1) and a hole transporting material expressed by the General Formula (2): wherein R1 and R2 independently represent any one of a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted cycloalkyl group and substituted or unsubstituted aralkyl group, and R3, R4, R5, R6, R7, R8, R9 and R10 independently represent any one of a hydrogen atom, halogen atom, cyano group, nitro group, amino group, hydroxyl group, substituted or unsubstituted alkyl group, substituted or unsubstituted cycloalkyl group and substituted or unsubstituted aralkyl group; and wherein R11, R12, R13, R14, R17, R18, R19 and R20 each represents a hydrogen atom, halogen atom, alkoxy grouType: ApplicationFiled: April 18, 2007Publication date: October 25, 2007Inventors: Keisuke Shimoyama, Eiji Kurimoto, Shinichi Kawamura
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Patent number: 7267917Abstract: A charge transport layer composition for a photoreceptor includes at least a binder, at least one arylamine charge transport material, e.g., N,N?-diphenyl-N,N?-bis(3-methylphenyl)-(1,1?-biphenyl)-4,4?-diamine, and at least one polymer containing carboxylic acid groups or groups capable of forming carboxylic acid groups. The charge transport layer forms a layer of photoreceptor, which also includes an optional anti-curl layer, a substrate, an optional hole blocking layer, an optional adhesive layer, a charge generating layer, and optionally one or more overcoat or protective layers.Type: GrantFiled: September 21, 2004Date of Patent: September 11, 2007Assignee: Xerox CorporationInventors: Yuhua Tong, Kenny-Tuan T. Dinh, Markus R. Silvestri, Michael E. Zak, John F. Yanus, Min-Hong Fu, David M. Skinner, Kathleen M. Carmichael, Colleen A. Helbig, Dale S. Renfer, John A. Bergfjord, Sr., Susan M. Van Dusen, Anthony M. Horgan, Jin Wu, Steven M. Sterling
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Publication number: 20070207395Abstract: An organic photoconductive material which is useful as a raw material compound for a variety of functional materials and makes it possible to implement an electrophotoconductor which is excellent in terms of the charge transporting performance, excellent in terms of dissolution in solvents and compatibility with resins, and excellent in terms of both the electrical properties and durability is provided. An example is an asymmetric bishydroxy compound which can be represented by the following structural formula (1aa). This compound is contained in a charge transforming layer 4 or a surface protective layer 5 of an electrophotoconductor 18. As a result, an electrophotoconductor 18 which is excellent in terms of the electrical properties and durability and can stably form high quality images without image defects such as black dots can be implemented.Type: ApplicationFiled: February 21, 2007Publication date: September 6, 2007Applicant: SHARP KABUSHIKI KAISHAInventors: Akihiro Kondoh, Hiroshi Sugimura, Takatsugu Obata
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Patent number: 7261988Abstract: An improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where X comprises a linking group; R1 and R1? comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; and R2, R3, R2?, and R3? comprise, each independently, an arylamine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses, imaging methods, and methods of forming the charge transport material are described.Type: GrantFiled: April 27, 2004Date of Patent: August 28, 2007Assignee: Samsung Electronics Co. LtdInventors: Zbigniew Tokarski, Nusrallah Jubran, Vytautas Getautis, Maryte Daskeviciene, Ingrida Paulauskaite, Robertas Maldzius, Jonas Sidaravicius
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Publication number: 20070190439Abstract: An electrophotographic photoreceptor including a photosensitive layer which includes a titanyl phthalocyanine crystal having a major absorption peak at a wavelength of 780 nm±10 nm and a minor absorption peak having an intensity of ¾ or less of the major absorption peak at 690 nm±10 nm in the visible-infrared absorption spectrum and a distyryl compound having a predetermined structure. An electrophotographic image forming apparatus employing the electrophotographic photoreceptor is also provided. The electrophotographic photoreceptor and the electrophotographic image forming apparatus have good photosensitivity and charging properties and good stability over repeated charging obtained by using an optimum combination of a new crystal type of a highly photosensitive titanyl phthalocyanine and a distyryl compound which is a charge transporting material that is compatible with the titanyl phthalocyanine.Type: ApplicationFiled: December 14, 2006Publication date: August 16, 2007Inventors: Saburo Yokota, Seung-ju Kim
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Patent number: 7244541Abstract: Improved organophotoreceptors comprise: (a) a charge transport compound having the formula ?where n is an integer from 0 to 1; X is an (N,N-disubstituted)arylamine group; Ar is an aryl group or a heterocyclic group; A is a first linking group with the formula —(CH2)p — which can be branched or linear, where p is an integer from 3 to 20 inclusive; and B is a second linking group having the formula -Q-Z-Q?, where Q and Q? are, independently, O, S, or NR1; wherein when Q or Q? is NR1 or Q=O and Q?=S, Z comprises an aryl group, and wherein when Q=Q?S or Q=Q?=O, Z comprises a multi-ring conjugated group; (b) a charge generating compound; and (c) an electrically conductive substrate over which said charge transport compound and said charge generating compound are located.Type: GrantFiled: November 15, 2005Date of Patent: July 17, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Vytautas Getautis, Edmundas Montrimas, Maryte Daskeviciene, Valentas Gaidelis, Vygintas Jankauskas
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Patent number: 7235194Abstract: Disclosed are highly efficient multiphoton absorbing compounds and methods of their use. The compounds generally include a bridge of pi-conjugated bonds connecting electron donating groups or electron accepting groups. The bridge may be substituted with a variety of substituents as well. Solubility, lipophilicity, absorption maxima and other characteristics of the compounds may be tailored by changing the electron donating groups or electron accepting groups, the substituents attached to or the length of the pi-conjugated bridge. Numerous photophysical and photochemical methods are enabled by converting these compounds to electronically excited states upon simultaneous absorption of at least two photons of radiation. The compounds have large two-photon or higher-order absorptivities such that upon absorption, one or more Lewis acidic species, Lewis basic species, radical species or ionic species are formed.Type: GrantFiled: May 20, 2003Date of Patent: June 26, 2007Assignee: California Institute of TechnologyInventors: Brian Cumpston, Matthew Lipson, Seth R Marder, Joseph W Perry
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Patent number: 7229732Abstract: A composition comprised of a charge transport compound and a crosslinked polymer composition generated from the curing of a solution of a hydroxyl pendant polycarbonate, a hydroxylated charge transport compound, a curing agent and a solvent.Type: GrantFiled: August 4, 2004Date of Patent: June 12, 2007Assignee: Xerox CorporationInventors: Nan-Xing Hu, Timothy P. Bender, Ah-Mee Hor, H Bruce Goodbrand, Yvan Gagnon, George Liebermann
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Patent number: 7223507Abstract: A photoconductive imaging member comprised of a supporting substrate, and thereover a single layer comprised of a mixture of a photogenerator component, charge transport components, and a certain electron transport component, and a certain polymer binder.Type: GrantFiled: April 4, 2003Date of Patent: May 29, 2007Assignee: Xerox CorporationInventors: Andronique Ioannidis, Nancy L. Belknap, Cindy C. Chen, Lanhui Zhang, Timothy P. Bender, John F. Graham, Ah-Mee Hor, James M. Duff
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Patent number: 7220522Abstract: A photoreceptor including a photosensitive layer including a specific diamine compound, or a photoreceptor including an electroconductive substrate; a photosensitive layer located overlying the electroconductive substrate; and optionally a protective layer located overlying the photosensitive layer, wherein an outermost layer of the photoreceptor includes a filler, an organic compound having an acid value of from 10 to 700 mgKOH/g and a specific diamine compound. An image forming method, an image forming apparatus and a process cartridge using the photoreceptor are also provided. A method for manufacturing the photoreceptor including the steps of preparing a coating liquid including the filler, the organic compound, the specific diamine compound and an antioxidant; and coating the coating liquid is also provided.Type: GrantFiled: March 4, 2004Date of Patent: May 22, 2007Assignee: Ricoh Company LimitedInventors: Takaaki Ikegami, Tomoyuki Shimada, Yasuo Suzuki
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Patent number: 7217483Abstract: The present invention provides an electrophotographic photoreceptor which has high light resistance, has high durability in exposure to oxidizing gases such as ozone and NOx, is excellent in mechanical properties such as printing durability, wearing resistance, marring resistance, and slip properties in repetitions of use, and further has excellent electrical properties. Specifically, the present invention provides an electrophotographic photoreceptor having an electroconductive substrate and provided thereon at least a photosensitive layer having a charge generation material, a charge transport material, and a binder resin.Type: GrantFiled: June 13, 2005Date of Patent: May 15, 2007Assignee: Mitsubishi Chemical CorporationInventors: Mamoru Nozomi, Kazutaka Ida, Mitsuo Wada
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Patent number: 7205080Abstract: An arylamine compound represented by formula (1). Ar1 represents a phenyl group substitued by a substituted or unsubstituted monovalent polycyclic aromatic hydrocarbon group, and a substituted or unsubstituted monovalent heterocyclic group. Ar2 represents a substituted or unsubstituted arylene group. R1 represents a hydrogen atom, a halogen atom, an alkoxy group, or a substituted or unsubstituted alkyl group. R2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group. R3 and R4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, at least one of R3 and R4 represents a substituted or unsubstituted aryl group, and R3 and R4 may be bound to form a ring via a single bond or a divalent group. m represents an integral of from 0 to 4.Type: GrantFiled: July 21, 2004Date of Patent: April 17, 2007Assignee: Fuji Xerox Co., Ltd.Inventors: Masahiro Iwasaki, Katsumi Nukada, Mieko Seki
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Patent number: 7202002Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1 and R2 are, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; R3 and R4 are, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, or a heterocyclic group; X1 and X2 are, each independently, a linking group; Y1 and Y2, each independently, comprise an arylamino group; and Z is a bridging group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: April 30, 2004Date of Patent: April 10, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Ruta Budreckiene, Gintaras Buika, Valentas Gaidelis, Juozas V. Grazulevicius, Vygintas Jankauskas
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Patent number: 7196224Abstract: The invention provides 1,3,5-tris(arylamino)benzenes represented by the general formula (I) wherein A is naphthyl, anthryl, phenanthryl, biphenylyl or terphenylyl group, and R is alkyl having 1–6 carbon atoms or cycloalkyl group having five or six carbon atoms. The 1,3,5-tris(arylamino)benzenes have oxidation potentials in the range of about 0.5–0.6V, excellent reversibility in oxidation-reduction process and high glass transition temperatures and in addition, they are capable of forming stable and durable amorphous film useful as high performance organic semiconductors at normal temperatures or higher with no aid of binder resins, that is, by themselves.Type: GrantFiled: March 26, 2003Date of Patent: March 27, 2007Assignee: Bando Chemical Industries, Ltd.Inventors: Nobutaka Akashi, Hideki Norisada, Tomoko Hayashi, Yasuhiko Shirota
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Patent number: 7189482Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport compound having the formula where R1 and R2 are, independently, hydrogen, an alkyl group, an alkaryl group or an aryl group; X is an aromatic group; Y is an (N,N-disubstituted)arylamine; Z is (CH2)m group where m is an integer between 0 and 30 where one or more of the methylene groups is optionally replaced by O, S, C?O, O?C—O, O?C—NR3, sulfoxide, sulfate, phosphate, an aryl group, urethane, urea, NR4 group, CHR5 group, or CR6R7 group where R3, R4, R5, R6, and R7 are, independently, H, hydroxyl, thiol, an amine group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group, and E is a bond, O, S, C?O, NR8, CR9R10 group, a hetrocyclic group, or an aromatic group where R8, R9, and R10 are, independently, H, an alkyl group, an alkaryl group, or an aryl group; and (b) a chargType: GrantFiled: September 16, 2003Date of Patent: March 13, 2007Assignee: Samsung Electronics Co., LtdInventors: Zbigniew Tokarski, Nusrallah Jubran, Vytautas Getautis, Maryte Daskeviciene, Ingrida Paulauskaite, Robertas Maldzius, Jonas Sidaravicius
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Patent number: 7183028Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, and R4 are, independently, an alkyl group, an alkaryl group, an aryl group, or a part of a cyclic group; R5 is hydrogen, an alkyl group, an alkaryl group, an aryl group, or a heterocyclic group; X comprises an aromatic group, such as an aryl group or an aromatic heterocyclic group; Y is a linking group; and Z comprises an epoxy group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: December 30, 2003Date of Patent: February 27, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law, Vytautas Getautis, Maryte Daskeviciene, Edmundas Montrimas, Janina Gavutiene
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Patent number: 7179574Abstract: Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where R1, R2, R3, R4, R5, R6, R7, and R8, are, each independently, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group; R9 and R10 are, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heterocyclic group; Ar1 and Ar2 are, each independently, an aromatic group; Y is an arylamine group; and X1 and X2 are, each independently, a linking group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.Type: GrantFiled: March 31, 2004Date of Patent: February 20, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Nusrallah Jubran, Zbigniew Tokarski, Vytautas Getautis, Maryte Daskeviciene, Tadas Malinauskas, Jonas Sidaravicius, Vygintas Jankauskas
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Patent number: 7175956Abstract: The invention is to provide an organic photoconductive material capable of realizing electrophotographic photoreceptors of high reliability that have high charge potential, high sensitivity, good responsiveness to light and good durability, of which the characteristics do not lower even when they are driven at low temperatures or at high speed and even when they are exposed to light, and to provide an electrophotographic photoreceptor that comprises the material and an image-forming apparatus. An organic photoconductive material of the following general formula (1), for example, an enamine compound of the following structural formula (1-1) is produced.Type: GrantFiled: September 3, 2003Date of Patent: February 13, 2007Assignee: Sharp Kabushiki KaishaInventors: Takatsugu Obata, Akihiro Kondoh, Kazuya Ishida
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Patent number: 7166400Abstract: An organophotoreceptor comprises an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a charge transport material with the formula ?where X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by O, S, C?O, O?S?O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, hydroxyl group, thiol group, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; R1 and R2 are independently a hydrogen, a halogen, an alkyl group, an aryl group, an alkaryl group, an aromatic group or a heterocyclic group; Y is an aromatic group; and n is a distribution of integer values greater than 2; and (b) a charge generating compound.Type: GrantFiled: October 28, 2003Date of Patent: January 23, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Zbigniew Tokarski, Nusrallah Jubran, Kam W. Law