Containing Amino Or Substituted Amino Group Patents (Class 430/73)
  • Patent number: 5486441
    Abstract: A 1,4-bis(4,4-diphenyl-1,3-butadienyl)benzene derivative represented by formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each independently represents a lower alkyl group which may be substituted, an aralkyl group which may be substituted, or an aryl group which may be substituted, and an electrophotographic photoreceptor using the compound are disclosed. The photoreceptor provides a high carrier drift mobility.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: January 23, 1996
    Assignee: Takasago International Corporation
    Inventors: Yoshimasa Matsushima, Toshimitsu Hagiwara
  • Patent number: 5484673
    Abstract: An electrophotographic photosensitive member of the present invention has a photosensitive lazer containing a compound represented by the formula (1): ##STR1## The electrophotographic photosensitive member has a high sensitivity and can maintain stable and excellent electrophotographic characteristics even when repeatedly used.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: January 16, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Toshihiro Kikuchi, Akio Maruyama, Noriko Ohtani, Shin Nagahara, Hisami Tanaka, Teigo Sakakibara, Takakazu Tanaka
  • Patent number: 5462826
    Abstract: Charge transporting materials having general formula (I): ##STR1## wherein R.sup.1 represents hydrogen; an unsubstituted or substituted alkyl group; an alkoxyl group having 1 to 4 carbon atoms; a thioalkoxyl group having 1 to 4 carbon atoms; an aryloxy group; an aralkyl group; a nitro group; an unsubstituted or substituted aryl group; a halogen; an amino group; an unsubstituted or substituted dialkylamino group; R.sup.2 represents hydrogen; an unsubstituted or substituted alkyl group; an alkoxyl group having 1 to 4 carbon atoms; or a halogen; R.sup.3 represents hydrogen; an alkyl group having 1 to 4 carbon atoms; an alkoxyl group having 1 to 4 carbon atoms; a halogen; a dialkylamino group; an amino group; a thioalkoxyl group having 1 to 4 carbon atoms; an aryloxy group; a methylenedioxy group; an aralkyl group; or an unsubstituted or substituted aryl group; R.sup.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: October 31, 1995
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Mitsuru Hashimoto, Tamotsu Aruga
  • Patent number: 5463128
    Abstract: A 1,4-bis(4,4-diphenyl-1,3-butadienyl)benzene derivative represented by formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each independently represents a lower alkyl group which may be substituted, an aralkyl group which may be substituted, or an aryl group which may be substituted, and an electrophotographic photoreceptor using the compound are disclosed. The photoreceptor provides a high carrier drift mobility.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: October 31, 1995
    Assignee: Takasago International Corporation
    Inventors: Yoshimasa Matsushima, Toshimitsu Hagiwara
  • Patent number: 5453343
    Abstract: Organic photoreceptors of the functionally separated laminated type containing a hydrazone compound in the charge transport layer thereof which provides low crystallinity and improved sensitivity, durability, and reproducibility. The hydrazone compound disclosed in the present invention is presented by the following general formula (I): ##STR1## wherein R.sub.1 represents a substituted or unsubstituted C.sub.1 -C.sub.4 alkyl group, R.sub.2 represents a hydrogen atom, or an alkyl or alkoxy group; n is an integer of either 1 or 2; R.sub.3 and R.sub.4 each independently represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group; or alternatively R.sub.3 and R.sub.4 form a substituted or unsubstituted aromatic heterocyclic ring residue cojointly with the nitrogen atom to which they are bonded.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: September 26, 1995
    Assignee: Industrial Technology Research Institute
    Inventors: Jia-Ming Liu, Shih-Ying Shen, Kuei-Fei Teng
  • Patent number: 5445909
    Abstract: An electrophotographic photoreceptor high in sensitivity and contrast potential after light irradiation is disclosed. The photoreceptor comprises an electroconductive substrate having thereon a photoconductive layer comprising a charge generating layer comprising a charge generating material, and a charge transporting layer comprising a charge transporting material, wherein the ionization potential IPg of the charge generating material is lower than the ionization potential IPt of the charge transporting material, the difference therebetween is 0.35 eV or less, and the difference between the ionization potential IPg1 of the charge generating layer and the ionization potential IPt1 of the charge transporting layer is within the range of -0.1 to +0.1 eV.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: August 29, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yutaka Akasaki, Katsuhiro Sato, Katsumi Nukada
  • Patent number: 5436100
    Abstract: An electrophotographic photoconductor is composed of an electroconductive substrate and a photoconductive layer formed thereon including a m-phenylenediamine derivative of formula (I): ##STR1## wherein Ar represents a non-condensed polycyclic hydrocarbon group other than a phenyl group, or a condensed polycyclic hydrocarbon group having not more than 18 carbon atoms; and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each represent hydrogen a halogen atom a cyano group, a nitro group, an alkyl group, an alkoxyl group, an aryl group, an aryloxy group, an alkylmercapto group, a group represented by ##STR2## in which R.sup.6 and R.sup.7 each represent hydrogen, an alkyl group, or an aryl group, an alkylenedioxy group or an alkylenedithio group. Novel m-phenylenediamine derivatives for use in the electrophotoconductor and intermediates for producing the m-phenylenediamine derivatives, and methods of those derivatives are disclosed.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: July 25, 1995
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga, Hiroshi Adachi
  • Patent number: 5424157
    Abstract: An electrophotosensitive material containing, as a charge-generating agent, a compound represented by the following general formula (1), ##STR1## wherein Cp is an azo coupling component, Y is a divalent organic group containing at least one aromatic ring or heterocyclic ring, R1 and R8 are alkyl groups or halogen atoms, respectively, and R2 and R4 are alkyl groups, halogen atoms or hydrogen atoms, respectively. The charge-generating agent used here remains chemically stable and exhibits excellent recurring property and charge-forming efficiency.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: June 13, 1995
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Eiichi Miyamoto, Yasufumi Mizuta
  • Patent number: 5415962
    Abstract: An electrophotographic photosensitive member is constituted by disposing a photosensitive layer on an electroconductive support. The photosensitive layer is characterized by containing a specific fluorene compound or by containing another specific fluorene compound and a specific triphenylamine compound. The photosensitive layer is suitable for providing an electrophotographic apparatus showing excellent electrophotographic characteristics such as a high photosensitivity, a good potential stability in repetitive use, a decreased transfer memory, no crack in the photosensitive layer and no crystallization of a charge-transporting material.
    Type: Grant
    Filed: April 20, 1993
    Date of Patent: May 16, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Kanemaru, Toshihiro Kikuchi, Akihiro Senoo, Takakazu Tanaka
  • Patent number: 5403687
    Abstract: A method of modifying a pigment which comprises dissolving the pigment into sulfuric acid and then mixing water with the pigment-sulfuric acid solution. The modified pigment is excellent in achieving uniform dispersion and has a small particle size. An electrophotographic photoreceptor containing the modified pigment as the organic photoconductor has uniform sensitivity, sufficient charge acceptance and small dark decay.
    Type: Grant
    Filed: June 4, 1993
    Date of Patent: April 4, 1995
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Mizue Fujimori, Yorinobu Yamada
  • Patent number: 5395715
    Abstract: The present invention relates to an improvement of a photosensitive member having a photosensitive layer which contains a specific amino compound as a charge transporting material.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: March 7, 1995
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventors: Hideaki Ueda, Shigeaki Tokutake, Keiichi Inagaki, Yuki Shimada
  • Patent number: 5389480
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photosensitive layer formed thereon, wherein the photosensitive layer contains at least one member selected from the group consisting of compounds of the formula (I), (II), and (III) as defined in the specification.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Atsuo Saita
  • Patent number: 5389478
    Abstract: An electrophotographic photosensitive member has an electroconductive support, and a photosensitive layer formed thereon. The photosensitive layer contains a compound represented by the formula (1).
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: February 14, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Yoshida, Koji Goto, Fumio Sumino
  • Patent number: 5389481
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photosensitive layer formed thereon, wherein said photosensitive layer contains an arylamine compound of the following formula (I): ##STR1## wherein X is a hydrogen atom or a group of the formula (II): ##STR2## Y is a group of the formula (III) or (IV):--O--A.sup.1 --O-- (III)--A.sup.2 --O--A.sup.3 -- (IV)wherein, the substituents are defined hereafter.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: February 14, 1995
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Atsuo Saita, Shuichi Maeda, Kohzo Ishio, Hitoshi Ono, Tetsuo Murayama
  • Patent number: 5389479
    Abstract: The present invention provides a highly sensitive and highly durable electrophotographic photoconductor providing a conductive support and a photosensitive layer formed thereon, the photosensitive layer comprising a bis-enamine compound of the formula (I): ##STR1## wherein "A" is a C.sub.6-12 arylene group which may have a substituent, a bivalent heterocyclic reside which may have a substituent, a C.sub.2-4 lower alkylene group which may have a substituent; "B" is a lower dialkylamino group, a lower alkoxy group, a lower alkyl group, a hydrogen atom or a halogen atom; and k is an integer from 1 to 5 provided that when k is an integer of 2 or more, "B" may be identifcal or different, may together form a ring; and n is an integer from 2 to 4.
    Type: Grant
    Filed: August 24, 1993
    Date of Patent: February 14, 1995
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kiyofumi Morimoto, Akihiro Kondo, Satoshi Machino, Kazuhiro Emoto, Akiko Masuda
  • Patent number: 5358813
    Abstract: Crystals of chlorogallium phthalocyanine, having distinct diffraction peaks at (i) 7.4.degree., 16.6.degree., 25.5.degree. and 28.3.degree., (ii) 6.8.degree., 17.3.degree., 23.6.degree. and 26.9.degree., or (iii) 8.7.degree. to 9.2.degree., 17.6.degree., 24.0.degree., 27.4.degree. and 28.8.degree. of the Bragg angle (2.theta..+-.0.2) to a CuK.alpha. characteristic X-ray; a photoconductive material for electrophotographic photoreceptor comprising the chlorogallium phthalocyanine; and an electrophotographic photoreceptor comprising an electroconductive support having thereon a light-sensitive layer containing at least one or more of chlorogallium phthalocyanine crystals. The electrophotographic photoreceptor has excellent sensitivity and durability.
    Type: Grant
    Filed: January 12, 1993
    Date of Patent: October 25, 1994
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Masakazu Iijima, Katsumi Nukada, Katsumi Daimon, Akira Imai, Toru Ishii, Yasuo Sakaguchi, Kiyokazu Mashimo, Ichiro Takegawa
  • Patent number: 5356742
    Abstract: An electrophotographic photoconductor is composed of an electroconductive substrate and a photoconductive layer formed thereon, the photoconductive layer includes a dipyrenylamine derivative of formula (I): ##STR1## wherein R represents an alkyl group with 1 to 12 carbon atoms, which may have a substituent, or an aryl group which may have a substituent. Novel dipyrenylamine derivatives of formula (I), in which R is --ph--(R.sup.4)n, wherein, ph is a phenyl group, R.sup.4 is hydrogen, an unsubstituted or substituted alkyl group having 1 to 12 carbon atoms, an unsubstituted or substituted alkoxyl group having 1 to 12 carbon atoms, n is an integer of 1 to 5, and when n is 2 to 5, R.sup.4 may be the same or different, which are for use in the photoconductive layer of the electrophotographic photoconductor, are synthesized.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: October 18, 1994
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga, Hiroshi Adachi
  • Patent number: 5356746
    Abstract: An electrophotographic photosensitive member, comprising: an electroconductive support and a photosensitive layer disposed on the electroconductive support, wherein the photosensitive layer comprises a triazene compound represented by the following formula (1): ##STR1## wherein R denotes hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group.
    Type: Grant
    Filed: October 15, 1992
    Date of Patent: October 18, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Satomi Sugiyama, Yoshio Kashizaki, Koichi Suzuki, Shintetsu Go
  • Patent number: 5344734
    Abstract: An electrophotographic recording material which comprises an electrically conductive support having thereon a photoconductive layer containing at least one aromatic amino compound having positive charge transport capacity, wherein said aromatic amino compound is within the scope of general formula (A) defined in the description.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: September 6, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, David R. Terrell, Stefaan K. De Meutter
  • Patent number: 5342719
    Abstract: An electrophotographic imaging member including a charge generating layer, a charge transport layer with charge transport molecules and as sensitizing additive or dopant a hydroxy derivative of the transport molecule.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: August 30, 1994
    Assignee: Xerox Corporation
    Inventors: Damodar M. Pai, John F. Yanus, Paul J. DeFeo, Alan E. J. Toth, Walter Mychajlowskij, Zoran Popovic
  • Patent number: 5338634
    Abstract: The present invention provides a new diamino compound represented by the following general formula [I] or [X] excellent in charge transporting properties. ##STR1## The present invention provides a photosensitive member and an electroluminescence device both of which comprise the diamino compound of the general formula [I] or [X] as a charge transporting material.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: August 16, 1994
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 5338633
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive substrate and a photoconductive layer formed thereon, wherein said photoconductive layer contains a compound of the formula ( I ): ##STR1## wherein R.sup.1 to R.sup.18 are respectively and independently a hydrogen atom, a halogen atom, a saturated or unsaturated aliphatic hydrocarbon group, an aromatic hydrocarbon group, an alkoxy group, an aryloxy group, a dialkylamino group or a diarylamino group, wherein the aliphatic hydrocarbon group, the aromatic hydrocarbon group, the alkoxy group, the aryloxy group, the dialkylamino group and the diarylamino group may have substituents, X is a bivalent hydrocarbon group which may have substituents, each of A.sup.1 and A.sup.2 is a saturated or unsaturated aliphatic hydrocarbon group or an aromatic hydrocarbon group, or is bonded to R.sup.5 or R.sup.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: August 16, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Mamoru Nozomi, Sumiko Watabe, Ryoko Aso
  • Patent number: 5336576
    Abstract: An azo compound represented by the following general formula IA and an electrophotographic photosensitive member comprising a photosensitive layer containing the azo compound: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different from each other and indicate a hydrogen atom, an alkyl group, an alkenyl group, a hydroxyl group, an alkoxy group, a carboxy group, an alkoxy carbonyl group, an acyl group, an aryl group, a halogen group or a cyano group, respectively; R.sup.14 indicates a hydrogen atom, a halogen group, an alkyl group, an alkoxy group, an aryl group, an amine group, a cyano group, a nitro group or a sulfoxide group; and A indicates a coupler residue having an acceptor property.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: August 9, 1994
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Eiichi Miyamoto, Yasuyuki Hanatani, Hiroaki Iwasaki, Yasufumi Mizuta, Akihiko Kawahara
  • Patent number: 5330866
    Abstract: The present invention provides a new amino compound represented by the following general formula [I] excellent in charge transporting properties. ##STR1## The present invention provides a photosensitve member and an electroluminescence device both of which comprise the amino compound of the general formula [I] as a charge transporting material.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: July 19, 1994
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 5324605
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive support and a photosensitive layer formed thereon, wherein said photosensitive layer contains an arylamine compound of the formula (I): ##STR1## wherein each of Ar.sup.1, Ar.sup.2, Ar.sup.3 and Ar.sup.4 which may be the same or different, is an aryl group which may have substituents, or a heterocyclic group which may have substituents, each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 which may be the same or different, is a hydrogen atom, a hydroxyl group, a halogen atom, an alkyl group which may have substituents, an alkoxy group which may have substituents, or a phenyl group which may have substituents, and each of R.sup.7 and R.sup.8 which may be the same or different, is a hydrogen atom, a halogen atom, an alkyl group which may have substituents, or an alkoxy group which may have substituents.
    Type: Grant
    Filed: July 27, 1992
    Date of Patent: June 28, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Hitoshi Ono, Atsuo Saita
  • Patent number: 5314775
    Abstract: The present invention provides a new diamino compound represented by the following general formula [I]. ##STR1## The present invention provides also a photosensitive member and an electroluminescence device both of which comprise the diamino compound of the general formula [I] as a charge transporting material.
    Type: Grant
    Filed: August 10, 1992
    Date of Patent: May 24, 1994
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 5308726
    Abstract: An electrophotographic photosensitive element is here disclosed which comprises a conductive substrate and at least a photosensitive layer formed on the conductive substrate, the electrophotographic photosensitive element being characterized in that the photosensitive layer contains, as a charge transport material, a compound represented by the formula (1), (2) or (3) ##STR1##
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: May 3, 1994
    Assignee: NEC Corporation
    Inventors: Akira Hirano, Eriko Tsuruoka
  • Patent number: 5306587
    Abstract: A photosensitive recording material which comprises an electrically conductive support having thereon a layer containing a charge transporting compound (n-CTM-compound) capable of accepting and transporting electrons obtained by radiation-activated charge-generation in a charge generating compound (CGM-compound) present in said material, wherein said n-CTM-compound corresponds to a general formula (A), (B), or (C) as defined in the description.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: April 26, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: David R. Terrell, Frans C. De Schryver, Carina Geelen, Marcel J. Monbaliu, Stefaan K. De Meutter, Mark G. Van der Auweraer, Guy P. Verbeek
  • Patent number: 5300784
    Abstract: A selenium alloy electrophotographic imaging member having an optically transparent NESA coated substrate. An x-ray image is formed from the side of the photoreceptor opposite the transparent substrate and then is scanned from the back side through the transparent substrate with a fine beam of light, the position of which is precisely monitored. The ensuing discharge from the light beam is detected by a non-contacting x-ray transparent electrode located on the outer side of the photoreceptor, away from the substrate, which reads the discharge signal through capacitive coupling, pixel by pixel, according to the position of the light beam, to form a high resolution raster pattern digital readout of the image.
    Type: Grant
    Filed: June 1, 1992
    Date of Patent: April 5, 1994
    Assignee: Xerox Corporation
    Inventors: William D. Fender, Eddie M. Zanrosso, Algird G. Leiga, Lothar S. Jeromin, Phillip G. Perry
  • Patent number: 5290649
    Abstract: An electrophotographic photoreceptor is formed by a photosensitive layer containing a naphtylhydrazone compound of the formula: ##STR1## wherein X and Y are independently a hydrogen atom, lower alkyl group, lower alkoxy group, phenoxy group or arylalkoxy group; R.sup.1 is a naphtyl group; R.sup.2 is a hydrogen atom, lower alkyl group, allyl group, substituted or unsubstituted phenyl group, or aralkyl group; and l and m are 1 or 2. The photoreceptor thus formed is not only highly sensitive but resistant to ozone deterioration, which markedly improves the durability thereof.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: March 1, 1994
    Assignee: Mitsubishi Chemical Industries Ltd.
    Inventors: Tetsumi Suzuki, Hitoshi Ono, Osamu Ando
  • Patent number: 5286589
    Abstract: An electrophotographic photosensitive member has a photosensitive layer on an electroconductive support. The photosensitive layer comprises a compound having a structure represented by the general formula (1) or (2) as a charge-generating material: ##STR1## wherein A.sub.1 and A.sub.3 are respectively an alkyl radical, an aralkyl radical, an aromatic radical or a heterocyclic radical which may have a substituent; A.sub.2 is hydrogen atom, or an alkyl radical, an aralkyl radical, an aromatic radical, or a heterocyclic radical which may have a substituent; A.sub.1 and A.sub.2 may be the same with or different from each other; A.sub.1 and A.sub.2 may be linked together to form a ring; and n is an integer of 1, 2, or 3.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: February 15, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shintetsu Go, Kazushi Iuchi, Toshie Miyaji, Hajime Miyazaki, Hideyuki Takai, Masakazu Matsumoto
  • Patent number: 5284728
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive support and a photosensitive layer formed thereon, wherein said photosensitive layer contains at least one member selected from the group consisting of hydrazone compounds of the formulas (I), (II) and (III): ##STR1## wherein X is a hydrogen atom or a group of the formula (IV):--C(R.sup.8).dbd.N--Q.sup.2 (IV)Q.sup.1 is a group of the formula (V), (VI), (VII), (VIII) or (IX); Q.sup.2 is a group of the formula (VI), (VII), (VIII), (IX) or (X); each of Q.sup.3 and Q.sup.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: February 8, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Tetsuo Murayama, Hitoshi Ono, Atsuo Saita, Sumiko Watabe
  • Patent number: 5283144
    Abstract: A photoreceptor includes a charge generating layer having: 1) a photogenerating pigment purified by sublimation at a pressure not greater than 10.sup.-3 Torr and subsequent condensation of the photogenerating pigment at a temperature less than about 100.degree. C.; and 2) a film-forming binder.
    Type: Grant
    Filed: September 2, 1992
    Date of Patent: February 1, 1994
    Assignee: Xerox Corporation
    Inventors: Anthony T. Ward, George Liebermann, Ah-Mee Hor, Giuseppa Baranyi, Donald J. Teney
  • Patent number: 5281503
    Abstract: A photogenerating pigment has the formula: ##STR1## wherein A is the residual structure of an aromatic amine, p is an integer 1, 2, 3, 4, etc. depending on the amine structure, m is an integer 0, 1, 2, 3, or 4 and X may be selected from the group including but not limited to F, Cl, Br, NO.sub.2, CN, OH, NH.sub.2, OCH.sub.3, OCH.sub.2 CH.sub.3, CF.sub.3, alkyl and aromatic groups.
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: January 25, 1994
    Assignee: Xerox Corporation
    Inventors: Kock-Yee Law, Ihor W. Tarnawskyj
  • Patent number: 5274084
    Abstract: An azo compound represented by the following general formula IA and an electrophotographic photosensitive member comprising a photosensitive layer containing the azo compound: ##STR1## wherein R.sup.1 and R.sup.2 are the same or different from each other and indicate a hydrogen atom, an alkyl group, an alkenyl group, a hydroxyl group, an alkoxy group, a carboxy group, an alkoxy carbonyl group, an acyl group, an aryl group, a halogen group or a cyano group, respectively; R.sup.14 indicates a hydrogen atom, a halogen group, an alkyl group, an alkoxy group, an aryl group, an amino group, a cyano group, a nitro group or a sulfoxide group; and A indicates a coupler residue having an acceptor property.
    Type: Grant
    Filed: November 24, 1992
    Date of Patent: December 28, 1993
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Eiichi Miyamoto, Yasuyuki Hanatani, Hiroaki Iwasaki, Yasufumi Mizuta, Akihiko Kawahara
  • Patent number: 5272028
    Abstract: An electrophotographic photosensitive member has a photosensitive layer provided on an electroconductive support. The photosensitive layer contains an azo pigment represented by the general formula (I): ##STR1## wherein Ar.sub.1 and Ar.sub.2 are respectively a divalent aromatic hydrocarbon group or a divalent heterocyclic group which may be the same or different and may have a substituent, and A.sub.1 and A.sub.2 are respectively a coupler residue having a phenolic hydroxyl group which may be the same or different.
    Type: Grant
    Filed: September 7, 1990
    Date of Patent: December 21, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshio Kashizaki, Hajime Miyazaki, Toshie Miyaji
  • Patent number: 5272030
    Abstract: An enamine derivative containing a fluoroalkyl group, a fluoroaryl group or a fluoroaralkyl group is effective as a charge transport material in an electrophotographic member excellent in sensitivity, residual potential, durability and the like electrophotographic properties.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: December 21, 1993
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Yoshii Morishita, Shigeru Hayashida, Yasushi Sugimoto, Hiroko Ishikawa, Hiroshi Kobayashi, Takaaki Sonoda
  • Patent number: 5268246
    Abstract: An electrophotographic photoconductor is composed of an electroconductive support and a photoconductive layer formed thereon comprising a novel pyrene-ring-containing olefin compound having formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 each represent hydrogen or an alkyl group which may have a substituent; Y is an aliphatic hydrocarbon group which may have a substituent, a cyclic hydrocarbon group which may have a substituent, or an aromatic group which may have a substituent; n is an integer of 0 or 1, and m is an integer of 1 to 3, provided that when n is 0, m is 1, R.sup.1 is hydrogen, and Y is an aromatic group with a substituent ##STR2## R.sup.5 and R.sup.3 each represent hydrogen, and Y and R.sup.1 may be bonded to form a ring, a method of synthesizing the pyrene-ring-containing olefin compound and an intermediate therefor are disclosed.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: December 7, 1993
    Assignee: Ricoh Company, Ltd.
    Inventors: Tamotsu Aruga, Masaomi Sasaki, Tomoyuki Shimada, Hiroshi Adachi
  • Patent number: 5258251
    Abstract: The present invention provides a hydrazone compound represented by the following general formula (1). This compound has higher hole mobility as compared with an electric charge transferring material such as the conventional hydrazone compound or the like. Accordingly, when this compound is contained in a photosensitive layer as the electric charge transferring material, there may be obtained an electrophotosensitive material excellent in sensitivity, charging ability and repeat characteristics. ##STR1## (wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same as or different from one another, and each is a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group.
    Type: Grant
    Filed: March 23, 1992
    Date of Patent: November 2, 1993
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Yasuyuki Hanatani, Hiroaki Iwasaki
  • Patent number: 5250377
    Abstract: Aromatic diolefinic compounds including 1,4-divinylbenzene derivatives, which are useful not only as organic photoconductive materials for electrophotography, but also as intermediates for producing diethyl aromatic compounds which are also useful as organic photoconductive materials for electrophotography, the aromatic diethyl compounds, an electrophotographic photoconductor containing any of the above aromatic diethyl compounds in a photosensitive layer thereof, and a charge transporting medium containing any of the aromatic diethyl compound are disclosed.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: October 5, 1993
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Mitsuru Hashimoto
  • Patent number: 5246808
    Abstract: The present invention provides a hydrazone compound of the following general formula (I). This compound presents a higher hole mobility as compared with a conventional electric charge transferring material such as a conventional hydrazone compound or the like. Accordingly, when a photosensitive layer contains, as the electric charge transferring material, the hydrazone compound of the present invention, there can be obtained an electrophotosensitive material which is excellent in sensitivity and charging ability and has high repeating characteristics. ##STR1## (wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 may be same as or different from one another, and each is a hydrogen atom, an alkyl group, an alkoxy group, an aralkyl group or an aryl group, each of said alkyl, alkoxy, aralkyl and aryl groups may have a substituent group; A.sup.1, A.sup.2, A.sup.3, A.sup.4, A.sup.5 and A.sup.
    Type: Grant
    Filed: March 12, 1992
    Date of Patent: September 21, 1993
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Yasuyuki Hanatani, Hiroaki Iwasaki
  • Patent number: 5238765
    Abstract: An electrophotographic photosensitive member with stable potential characteristics even after repeated use, comprises an electroconductive support and a photosensitive layer formed on the electroconductive support, and that photosensitive layer contains a compound represented by the general formula (1) below: ##STR1##
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: August 24, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akihiro Senoo, Tetsuro Kanemaru, Masakazu Matsumoto
  • Patent number: 5230975
    Abstract: The alkoxy squaraines essentially as represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 independently represent alkyl or aryl groups; X is hydrogen, halogen, alkyl, hydroxy, or alkoxy; and n is a number of from 0 to about 2.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: July 27, 1993
    Assignee: Xerox Corporation
    Inventor: Kock-Yee Law
  • Patent number: 5230976
    Abstract: Electrophotographic imaging members are disclosed which incorporate a charge transport layer comprising an arylamine/siloxane polymer.
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: July 27, 1993
    Assignee: Xerox Corporation
    Inventors: Richard L. Schank, John Yanus
  • Patent number: 5229237
    Abstract: An electrophotographic photosensitive member is produced by coating an electroconductive substrate with a compound represented by formula (1) shown below and a compound represented by formula (2) shown below respectively by spray-coating through separate spraying means to form a photosensitive layer containing the compounds represented by the formulae (1) and (2) respectively on the electroconductive substrate: ##STR1## In the above formulae (1) an (2), Ar.sub.1 and Ar.sub.2 independently denote an aromatic hydrocarbon ring which may have a substituent, a heterocyclic aromatic ring which may have a substituent, or a ring assembly formed by bonding the aromatic rings directly or through an aromatic or non-aromatic bonding group; and R.sub.1 -R.sub.5 independently denote hydrogen atom, halogen atom, alkyl group, alkoxy group, nitro group or cyano group.
    Type: Grant
    Filed: April 10, 1991
    Date of Patent: July 20, 1993
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoichi Kawamorita, Hisao Maruyama, Kazushige Nakamura
  • Patent number: 5223364
    Abstract: The electrophotographic photoconductor of the present invention includes a conductive substrate and a photosensitive layer containing perylene pigment as a charge generating material formed on the conductive substrate. The X-ray diffraction peak of the perylene pigment exhibits its peak when the value of 2.theta. is 14.degree.(.+-.0.3.degree.), and the half-width of the peak when the value of 2.theta. is 14.degree. (.+-.0.3.degree.) is 0.5 or more. This electrophotographic photoconductor has excellent qualities of low residual potential and stabilized quality.
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: June 29, 1993
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Tatsuo Maeda, Eiichi Miyamoto, Nariaki Muto
  • Patent number: 5223362
    Abstract: A laminated organic photosensitive material which comprises an electroconductive support, a charge producing layer and a charge transporting layer formed thereon wherein the charge producing layer contains X-type nonmetal phthalocyanine as a charge producing substance and the charge transporting layer contains an arylaldehydehydrazone derivative of the general formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each an alkyl or an aryl group.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: June 29, 1993
    Assignee: Bando Chemical Industries, Ltd.
    Inventors: Tomokazu Kobata, Yosuke Matsui
  • Patent number: 5219692
    Abstract: An electrophotographic photoconductor comprising an electroconductive support, and a photoconductive layer formed thereon comprising at least one tertiary amine compound having a condensed polycyclic hydrocarbon group of formula (I): ##STR1## wherein A.sup.1 and A.sup.2 each independently represent an unsubstituted or substituted alkyl group or aryl group, and Ar represents an unsubstituted or substituted condensed polycyclic hydrocarbon group. Furthermore, novel tertiary amine compounds having a condensed polycyclic hydrocarbon group are disclosed.
    Type: Grant
    Filed: March 8, 1990
    Date of Patent: June 15, 1993
    Assignee: Ricoh Company, Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Tamotsu Aruga
  • Patent number: 5215842
    Abstract: A photosensitive element for electrophotography has an electrically conductive substrate and a layer structure thereon comprising a charge generating substance and a charge transport substance. An improved charge transport substance is a derivative of triphenylamine in which at least 80% of the electrons in the highest occupied molecular orbital are located on the triphenylamine skeleton. Examples of such compounds have the following formula: ##STR1## wherein X is a an optionally substituted heterocyclic radical containing at least one ring nitrogen, Q is a single bond or --C.dbd.C--, and Z.sub.1, Z.sub.2 and Z.sub.3 are H, lower alkyl or alkoxy, aryl, NO.sub.2, CF.sub.3, --N(R').sub.2, --S--C.sub.6 H.sub.5 or --S(R').sub.2.
    Type: Grant
    Filed: January 8, 1991
    Date of Patent: June 1, 1993
    Assignees: Hitachi, Ltd., Hitachi Chemical Co., Ltd.
    Inventors: Sukekazu Aratani, Shigeo Suzuki, Akira Hosoya, Katuo Sugawara, Toshiro Saito, Tsuneaki Kawanishi, Noriyuki Kinjo, Yasuo Katsuya, Akira Kageyama
  • Patent number: 5210301
    Abstract: Novel squarium compounds which have a flat photosensitivity in the wide range from visible ray region to the near infrared ray region as a charge generator and which can be prepared by reacting squaric acid and an aniline derivative, and electrophotographic photoreceptors containing the squarium compounds are disclosed.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: May 11, 1993
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Satoshi Saeki, Seki Kin, Kaoru Torikoshi, Hiroyuki Tanaka, Lyong S. Pu