Binder For Radiation-conductive Composition Patents (Class 430/96)
  • Patent number: 6183921
    Abstract: A crack resistant, curl-free electrophotographic imaging member includes a charge transport layer comprising an active charge transporting polymeric tetraaryl-substituted biphenyidiamine and a plasticizer.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: February 6, 2001
    Assignee: Xerox Corporation
    Inventors: Robert C. U. Yu, William W. Limburg, Merlin E. Scharfe, David H. Pan, Dale S. Renfer, Richard L. Schank, Surendar Jeyadev
  • Patent number: 6183923
    Abstract: A lithographic printing plate precursor is disclosed, comprising a water-resistant support having provided thereon an image-receiving layer, wherein the image-receiving layer comprises anatase-type titanium oxide grains and a binder resin comprising a complex composed of an organometallic polymer and an organic polymer containing at least one member selected from the group consisting of an amido bond, a urethane bond, a ureido bond and a hydroxy group, the surface of the image-receiving layer has a contact angle with water of at least 25 degrees and the contact angle with water thereof is reduced to 15 degrees or below when it is irradiated with ultraviolet light, and further, a method for preparing the lithographic printing plate precursor and a method for preparing a lithographic printing plate by using the lithographic printing plate precursor are disclosed.
    Type: Grant
    Filed: February 17, 1999
    Date of Patent: February 6, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Seishi Kasai
  • Patent number: 6180302
    Abstract: The present invention includes an electrophotographic photosensitive member having a surface layer containing a polyphenylene resin, and a process cartridge and an electrophotographic apparatus both having the electrophotographic photosensitive member.
    Type: Grant
    Filed: October 27, 1998
    Date of Patent: January 30, 2001
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takakazu Tanaka, Hideki Anayama, Tetsuro Fukui, Hidetoshi Hirano
  • Patent number: 6174636
    Abstract: Disclosed is an imaging member which comprises a conductive substrate, a photogenerating material, and a binder comprising a polymer of the formula wherein A is or a mixture of wherein R is a hydrogen atom, an alkyl group, an aryl group, or mixtures thereof, B is one of specified groups, such as or mixtures thereof, and n is an integer representing the number of repeating monomer units.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: January 16, 2001
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, John F. Yanus, Damodar M. Pai, Markus R. Silvestri, Ram S. Narang, William W. Limburg, Dale S. Renfer
  • Patent number: 6174637
    Abstract: A photo conducting imaging member has a charge generator layer including a binder containing at least a polycarbonate of formula (I):
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: January 16, 2001
    Assignee: Xerox Corporation
    Inventors: Kathleen M. Carmichael, Satish R. Parikh
  • Patent number: 6169869
    Abstract: An image forming apparatus includes an image bearing member, a developer carrying member for carrying thereon a developer to transport the developer to a developing zone, and a regulation member provided in touch with the surface of the developer carrying member to regulate coat weight of the developer carried thereon. The image bearing member includes a conductive substrate and a photosensitive layer formed thereon, and the photosensitive layer contains at least one polycarbonate resin (I) having a viscosity-average molecular weight not more than 1.5×104 and at least one polycarbonate resin (II) having a viscosity-average molecular weight more than 1.5×104, the polycarbonate resin (I) being contained in a proportion of from 30% by weight to 95% by weight based on the total weight of the polycarbonate resins (I) and (II). On the developer carrying member, the developer is in a coat weight not more than 1.5 mg/cm2 at the developing zone after its regulation by the regulation member.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: January 2, 2001
    Assignee: Canon Kabushiki Kaisha
    Inventors: Satoru Inami, Junichi Kato, Masahiro Yoshida, Yusuke Nakazono, Seiichi Shinohara
  • Patent number: 6165662
    Abstract: An electrophotographic photoreceptor having a photosensitive layer containing a binder resin on an electroconductive substrate, wherein at least a part of the binder resin in the photosensitive layer is a polycarbonate resin having a structure of the following formula (1) as main repeating units and a structure of the following formula (2) at one or each terminal and having a viscosity-average molecular weight of from 10,000 to 300,000: ##STR1## where, in the formula (1), each of Y.sup.1 to Y.sup.8 which are independent of one another, is a hydrogen atom, a C.sub.1-10 saturated aliphatic hydrocarbon group, a C.sub.3-10 unsaturated aliphatic hydrocarbon group, a halogen atom, a halogenated alkyl group, a C.sub.1-10 alkoxy group or a C.sub.6-20 aromatic hydrocarbon group which may be substituted, X.sup.1 is ##STR2## an aromatic ring, a single bond, a lactone or fluorene, each of R.sup.1 to R.sup.7 which are independent of one another, is a hydrogen atom, a C.sub.
    Type: Grant
    Filed: December 1, 1999
    Date of Patent: December 26, 2000
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Satoshi Kato, Itaru Ogawa
  • Patent number: 6146800
    Abstract: An electrophotographic photosensitive member is disclosed which is provided with a surface layer containing a polyarylate resin or polycarbonate resin. The polyarylate resin and polycarbonate resin have a structural unit having a cyclic siloxane structure in its backbone chain. Also a process cartridge and an electrophotographic apparatus using the photosensitive member are disclosed.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: November 14, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Yoshida, Hideki Anayama
  • Patent number: 6110628
    Abstract: An electrophotographic photosensitive member is comprised of a support and a photosensitive layer formed on the support. The electrophotographic photosensitive member has a surface layer which contains a resin having at least one of the structural units represented by the following formula: ##STR1## wherein the bond represented by a broken line may be present, and when present, m is 4 and when m is 6, n represents an integer of 0 or more, and R.sub.1 and R.sub.2 represent each independently hydrogen, halogen, hydroxy, a substituted or unsubstituted alkyl, a substituted or unsubstituted unsaturated aliphatic hydrocarbon, a substituted or unsubstituted aryl, a substituted or unsubstituted cycloalkyl, a substituted or unsubstituted cyclodienyl, a substituted or unsubstituted alkoxy, a substituted or unsubstituted carbonyl, or a substituted or unsubstituted heterocyclic group.
    Type: Grant
    Filed: July 31, 1998
    Date of Patent: August 29, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Michiyo Sekiya, Hideki Anayama, Akio Maruyama, Shoji Amamiya, Hiroki Uematsu, Hiroyuki Tanaka
  • Patent number: 6099998
    Abstract: An electrophotographic photoreceptor is disclosed. The topmost layer comprises a binder comprising a crosslinked resin having, as a recurring unit, (a) a portion comprising a constituent having a fluorine or silicon atom at the side chain, (b) a portion having an aromatic group in the main or side chain, and (c) a portion having a hydroxyl group or an amino group.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: August 8, 2000
    Assignee: Konica Corporation
    Inventors: Toyoko Shibata, Akira Kinoshita, Tomoo Sakimura
  • Patent number: 6099997
    Abstract: A photosensitive recording material containing a support and a charge generating layer (CGL) in contiguous relationship (contact) with a charge transporting layer (CTL), containing an n-charge transporting material (n-CTM), wherein the binder of the charge generating layer (CGL) is made insoluble in methylene chloride by crosslinking, and the binder is composed essentially of one or more polyepoxy compounds self-crosslinked under the influence of an amine catalyst and/or crosslinked by reaction with at least one primary and/or secondary poly NH-group amine.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: August 8, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: David Terrell, Stefaan De Meutter, Marcel Monbaliu
  • Patent number: 6093515
    Abstract: An electrophotographic photosensitive member, comprising a support and a photosensitive layer disposed on the support. The photosensitive member has a surface layer comprising a siloxane polymer which comprises at least two polysiloxane units each independently represented by a formula (1) (shown in the specification) and has a molecular structure such that adjacent two polysiloxane units of the formula (1) are connected with each other at their side chains by --O--Pc--CO--O-- where Pc denotes a polycarbonate chain. Such a molecular structure of the siloxane polymer is effective in improving lubricating properties of the surface of the photosensitive member while retaining a mechanical strength thereof.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: July 25, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Yoshida, Hideki Anayama
  • Patent number: 6042980
    Abstract: Charge generation layers for photoconductors comprise a binder and a charge generation compound, wherein the binder comprises a blend of polyvinylbutyral polymer and at least one resin which improves at least one electrical characteristic of a photoconductor in which the charge generation layer is included. Photoconductors comprise the charge generation layer in combination with a substrate and a charge transport layer.
    Type: Grant
    Filed: July 21, 1998
    Date of Patent: March 28, 2000
    Assignee: Lexmark Internatonal, Inc.
    Inventors: Laura Lee Kierstein, Kasturi Rangan Srinivasan
  • Patent number: 6040098
    Abstract: Charge generation layers comprising a binder and a charge generation compound, wherein the binder comprises a blend of methyl bisphenol A and an additional resin comprising an epoxy resin, a poly(phenylglycidyl ether)-co-dicyclopentadiene resin, a phenoxy resin or a polyhydroxystyrene resin. Dual layer photoconductors comprise the charge generation layer in combination with a substrate and a charge transport layer.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: March 21, 2000
    Assignee: Lexmark International, Inc.
    Inventors: David Glenn Black, Garry Dale Hinch, Dat Quoc Nguyen, Kasturi Rangan Srinivasan
  • Patent number: 6033816
    Abstract: A photoconductive drum of an aluminum substrate and a blend of polyvinylbutyral and one or a blend of phenoxy resin, epoxy novolac resin, and epoxy capped polymers which are derivatives of bisphenol and epichlorohydrin. The blend enhances the electrical properties.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: March 7, 2000
    Assignee: Lexmark International, Inc.
    Inventors: Weimei Luo, Kasturi Rangan Srinivasan, Julie Corrin House
  • Patent number: 6027844
    Abstract: Composites comprising polymeric binders and phthalocyanine pigments to form a single layer positive organic photoconductor are provided for use in electrophotography. The polymeric binders comprise an aliphatic polymer or copolymer having a saturated ring for each repeat unit either included in the polymer chain or pendant therefrom and about 4 to 35% of functional groups such as --OH, --SH, --N<, >NH, and --NH.sub.2 per repeat unit. The saturated ring portion, being essentially non-polar, or at least less polar than an unsaturated ring, maintains the specific morphology of the phthalo-cyanine pigments commonly employed in positive charge organic photoconductors (OPCs) and results in a stable dispersion required for the stable performance of the OPC. Keeping the functional groups listed above to less than about 35% ensures that the photoresponse is not reduced to an unacceptable level. Heating of the composite is used to control the concentration of the functional groups.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: February 22, 2000
    Assignee: Hewlett-Packard Company
    Inventors: Khe C. Nguyen, Sivapackia Ganapathiappan
  • Patent number: 6027846
    Abstract: An electrophotographic photoconductor includes an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a structural unit of formula (I), two structural units of formulae (I) and (II), or a repeat unit of formula (III): ##STR1## wherein Ar.sup.1 to Ar.sup.7, Y, X, and n are as specified in the specification.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: February 22, 2000
    Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.
    Inventors: Tomoyuki Shimada, Masaomi Sasaki, Masafumi Ohta, Akihiro Imai, Mitsutoshi Anzai, Tamotsu Aruga, Kazukiyo Nagai, Katsuhiro Morooka
  • Patent number: 6001523
    Abstract: The invention described in the specification provides an improved coating for an electrophotographic photoconductor printing system. In particular, a blend of polycarbonate-A and polycarbonate-Z binders according to the formula: ##STR1## wherein R.sup.1 is selected from the group consisting of CH.sub.2 an alkylidene group, a cycloalkyl group and a substituted cycloalkyl group, R.sup.2 and R.sup.3 are selected from the group consisting of hydrogen, halogen and an a CH.sub.3 group provides increased durability and wear properties to a charge transport layer coated onto a charge generation layer of a photoreceptor drum. The polycarbonate blend may be used with amine and hydrazone charge transport materials and the charge transport layer may include additional additives which further improve the wear properties of the photoconductor coatings in a laser printer.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: December 14, 1999
    Assignee: Lexmark International, Inc.
    Inventors: Paul Dwight Kemmesat, Jennifer Kaye Neely, Catherine Mailhe Randolph, Kasturi Rangan Srinivasan
  • Patent number: 5994011
    Abstract: An electrophotographic photosensitive member is disclosed which comprises a conductive support and a photosensitive layer provided on the conductive support. A surface layer of the electrophotographic photosensitive member contains a polycarbonate resin having a chain fluoroalkyl group having 4 or more carbon atoms. Also, an electrophotographic apparatus and a device unit are disclosed which comprise the electrophotographic photosensitive member.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: November 30, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventor: Noboru Kashimura
  • Patent number: 5972552
    Abstract: Embodiments of photoconductors and methods of making photoconductors for electrophotography are described, each embodiment comprising a complex between metal oxide phthalocyanine compound(s) and hydroxy compound(s) or amine compound(s). A metal oxide phthalocyanine pigment exhibits extended photoresponse between 850 nm and 1000 nm when it is milled with hydroxy binders or amine binders. The preferred hydroxy or amine binders include a modified poly-vinyl butyral binder unit containing a --CH.sub.2 CH.sub.2 OH unit, a cyclohexanol unit, a --CH.sub.2 CH.sub.2 NH.sub.2 unit, a --CH.sub.2 C.sub.6 H.sub.10 --NH.sub.2 unit, a --CH.sub.2 C.sub.6 H.sub.10 --CH.sub.2 NH.sub.2 unit, a --CH.sub.2 C.sub.6 H.sub.4 --NH.sub.2 unit, or other hydroxy or amine units. Optionally, hydroxy solvents or other hydroxy additives may also be included. Preferably, the pigment is dehydrated or hydroxy-starved before milling with the binder and solvents.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: October 26, 1999
    Assignee: Hewlett-Packard Company
    Inventors: Sivapackia Ganapathiappan, Khe C. Nguyen
  • Patent number: 5968694
    Abstract: The present invention provides photoconductive paints which have excellent dispersability and dispersion stability and which allow formation of coatings with high coating strength and excellent smoothness.The invention relates to photoconductive paint composed primarily of an inorganic photoconductive material and a binding resin formed on a conductive substrate, wherein the binding resin contains compound fine particles (A) and a resin (B) as defined below, in a solid weight ratio of compound fine particles (A)/resin (B) in the range of 0.5/9.5-4.0/6.0.The compound fine particles (A) have an organic polymer bound to surfaces of inorganic fine particles, and the resin (B) is a resin composition obtained by polymerizing an acrylic monomer mixture, the resin having an acid value of 2.0-12.0.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: October 19, 1999
    Assignees: Iwatsu Electro Co., Ltd., Nippon Shokubai
    Inventors: Hideki Sakai, Takafumi Hirano, Daijou Tomihisa, Shigefumi Kuramoto
  • Patent number: 5968696
    Abstract: A single-layer binder comprising a synthetic resin binder and a phthalocyanine pigment dispersed therein is modified so as to reduce the content of the phthalocyanine pigment while maintaining or further improving the sensitivity of the binder. A coating material comprising a synthetic resin binder comprising as a constituent component a polyester resin containing halogen atoms, e.g., chlorine or bromine, and a phthalocyanine pigment dispersed in the binder is applied to a conductive base to produce an electrophotographic binder.
    Type: Grant
    Filed: August 30, 1998
    Date of Patent: October 19, 1999
    Assignee: FIT Corporation
    Inventors: Ichiro Yoshida, Shozo Kaieda
  • Patent number: 5948579
    Abstract: An improved electrophotographic photosensitive material having a photosensitive layer on a conductive support.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: September 7, 1999
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Kiyokazu Mashimo, Toru Ishii, Katsumi Nukada, Masahiro Iwasaki, Taketoshi Higashi, Fumio Ojima
  • Patent number: 5942363
    Abstract: An electrophotographic photoconductor includes an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a repeat unit of formula (I), or two repeat units of formulae (II) and (III): wherein Ar.sup.1 to Ar.sup.5, X, n, k and j are as specified in the specification.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: August 24, 1999
    Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.
    Inventors: Chiaki Tanaka, Nozomu Tamoto, Masaomi Sasaki, Kazukiyo Nagai, Tomoyuki Shimada, Chihaya Adachi, Akira Katayama, Mitsutoshi Anzai, Katsuhiro Morooka
  • Patent number: 5905008
    Abstract: An electrophotographic photosensitive member has a photosensitive layer formed on a support. A surface layer (or the outermost layer) of the photosensitive layer contains a fluorine-modified organic silicone resin represented by the following average unit formula:{F(CF.sub.2).sub.a1 -Q.sub.1 -R.sub.1.m1 SiO.sub.(3-m1)/2 }.sub.X1 {F(CF.sub.2).sub.a2 -Q.sub.2 -R.sub.2.m2 SiO.sub.(3-m2)/2 }.sub.X2 . . . {F(CF.sub.2).sub.ap -Q.sub.p -R.sub.p.mp SiO.sub.(3-mp)/2 }.sub.Xp {R.sub.1 '.sub.n1 SiO.sub.(4-n1)/2)}.sub.y1 {R.sub.2 '.sub.n2 SiO.sub.4-n2)/2 }.sub.y2 . . . {R.sub.q '.sub.nq SiO.sub.(4-nq)/2 }.sub.yqwhere R.sub.1 -R.sub.p and R.sub.1 '-R.sub.q ' are each an alkyl or aryl group; Q.sub.1 -Q.sub.p are each an alkylene group; m1-mp are each an integer of 0 to 2; n1-nq are each an integer of 0 to 3; a1-aq are each an integer; x1-y1 are each a number larger than 0; and X2-Xp and Y2 are each respectively a number of 0 or more.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: May 18, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuo Yoshinaga, Shunichiro Nishida, Keiko Hiraoka, Yayoi Nagao, Hideki Kobayashi, Toru Masatomi
  • Patent number: 5882814
    Abstract: Disclosed is an imaging member which comprises a conductive substrate, a photogenerating layer, and a charge transport layer comprising a polymer of the formulae I, II, III, IV, V, VI, VII, VIII, IX, or X as further defined herein.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: March 16, 1999
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Leon A. Teuscher, Damodar M. Pai, John F. Yanus
  • Patent number: 5876891
    Abstract: An alternating copolymer comprising a repeating unit of the formula:--Z--(X--Y).sub.n-- (I)wherein n is at least 2, X is O, S, Se or Te, and Y and Z are independently an aromatic or substituted aromatic group, and at least one other repeating unit, which is useful as a photosensitive material used in a spatial light modulator.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: March 2, 1999
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Akio Takimoto, Hirofumi Wakemoto, Eiichiro Tanaka, Masanori Watanabe, Junko Asayama, Hisahito Ogawa, Shigehiro Sato, Fumiko Yokotani
  • Patent number: 5876892
    Abstract: An electrophotographic photoreceptor in which the surface of a photosensitive layer has a small friction coefficient without impairing the excellent electrophotographic characteristics and which has an enhanced oil resistance and does not cause light fatigue, the electrophotographic photoreceptor comprising an electroconductive support having formed thereon a photosensitive layer comprising at least a charge-generating agent, a charge-transfer agent and a binder resin, wherein the photosensitive layer contains a polycarbonate copolymer comprising a recurring unit represented by the general formula (I) as the binder resin: ##STR1## and a butadiene compound represented by the general formula (IV) as the charge-transfer agent: ##STR2##
    Type: Grant
    Filed: June 4, 1998
    Date of Patent: March 2, 1999
    Assignees: Shindengen Electric Manufacturing Co., LTD, Yamanashi Electronics Co., LTD.
    Inventors: Kenichi Fujimori, Yoshitaro Nakayama, Mitsuru Noro, Tetsuya Sakuma, Hajime Suzuki
  • Patent number: 5876890
    Abstract: A surface layer of a photosensitive layer contains a resin comprising a structural unit represented by the following general formula (1), and at least one compound of a triarylamine compound represented by the following general formula (2) and a styryl compound represented by the following general formula (3): ##STR1## wherein, X is --CR.sub.13 R.sub.14 --, substituted or unsubstituted cycloalkylidene, substituted or unsubstituted .alpha.,.omega.-alkylene, single bond, --O--, --S--, --SO-- or --SO.sub.2 --, wherein R.sub.13 and R.sub.14 are each hydrogen, trifluoromethyl, or substituted or unsubstituted alkyl or aryl, and R.sub.1 to R.sub.12 are each hydrogen, halogen, or substituted or unsubstituted alkyl or aryl; ##STR2## wherein Y is hydrogen, halogen, substituted or unsubstituted alkyl or alkoxy, or ##STR3## wherein R.sub.15 ' to R.sub.24 ' are each hydrogen, halogen, substituted or unsubstituted alkyl or alkoxy, R.sub.15 to R.sub.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: March 2, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventors: Wataru Kitamura, Hidetoshi Hirano, Kimihiro Yoshimura
  • Patent number: 5876889
    Abstract: An electrophotographic photoconductor has a conductive substrate and a photosensitive layer. The photosensitive layer is laminated on the conductive substrate and includes at least phthalocyanine compound as a photoconductive material. In the photosensitive layer, the content of o-phthalonitrile polymer except the phthalocyanine compound is in a range of 100 nmol to 200 mmol with respect to 1 mol of the phthalocyanine compound. Thus, the electrophotographic photoconductor has an excellent surface-charge retention.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: March 2, 1999
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yoichi Nakamura, Kazumi Egota, Koji Kawaguchi, Yoshimasa Hattori
  • Patent number: 5876888
    Abstract: A surface layer of a photosensitive layer contains at least one resin selected from the group consisting of (a) a polyarylate resin having a structural unit represented by the following general formula (1) and (b) a polycarbonate resin having a structural unit represented by the following general formula (2): ##STR1## wherein, X.sub.1 and X.sub.2 are each single bond, --O--, --S-- or substituted or unsubstituted alkylene and are the same or different, R.sub.1 to R.sub.8 and R.sub.11 to R.sub.14 are each hydrogen, halogen, or substituted or unsubstituted alkyl or aryl and are the same or different, and R.sub.9 and R.sub.10 are each hydrogen, halogen, or substituted or unsubstituted silyl, alkyl or aryl and are the same or different, and n is an integer of 2 or more; ##STR2## wherein X.sub.3 and X.sub.4 are each single bond, --O--, --S-- or substituted or unsubstituted alkylene and are the same or different, R.sub.15 to R.sub.
    Type: Grant
    Filed: July 2, 1997
    Date of Patent: March 2, 1999
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideki Anayama, Akira Yoshida
  • Patent number: 5874192
    Abstract: Disclosed is an imaging member which comprises a conductive substrate, a photogenerating material, a charge transport material, and a polymeric binder comprising (a) a first polymer comprising a polycarbonate, and (b) a second polymer of the formulae I, II, III, IV, V, VI, VII, VIII, IX, or X as further defined herein.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: February 23, 1999
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Leon A. Teuscher, Damodar M. Pai, John F. Yanus, Kathleen M. Carmichael, Edward F. Grabowski, Paul F. Zukoski
  • Patent number: 5871876
    Abstract: An electrophotographic photoconductor has an electroconductive support and a photoconductive layer formed thereon, which contains a charge transport material with a polycarbonate structure having a triarylamino group at least on the main chain or side chain thereof, and a charge generation material with a phthalocyanine skeleton.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: February 16, 1999
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Ikuno, Hiroshi Nagame, Tetsuro Suzuki, Hidetoshi Kami, Jun Aoto, Hiroshi Tamura, Narihito Kojima, Tatsuya Niimi
  • Patent number: 5871875
    Abstract: An electrophotographic imaging member is prepared by forming a dispersion of a charge transport material in a solvent system including at least two non-chlorinated solvents selected from tetrahydrofuran, dioxane and toluene, and applying the dispersion to an electrophotographic imaging member layer by solution coating.
    Type: Grant
    Filed: January 13, 1997
    Date of Patent: February 16, 1999
    Assignee: Xerox Corporation
    Inventors: John S. Chambers, Huoy-Jen Yuh
  • Patent number: 5858592
    Abstract: A thin (<5 .mu.m) charge injection barrier layer is provided on a top surface of an inverse dual layer photoconductor using hole transport or on at least one surface of a single layer photoconductor or on an electrically conductive substrate of a conventional dual layer photoconductor using either hole transport or electron transport. The charge injection barrier layer comprises at least one terpolymer given by the formula ?A.sub.x B.sub.y C.sub.z !.sub.n, where A is a charge injection prohibitor to prevent leakage of charge from the surface, B is a solubility control moiety to control solubility of the polymer and its glass transition temperature, and C is an electron charge moiety for neutralizing surface charge. Each of the moieties A, B, and C contain a vinyl group. The value of x is at least about 0.01, y is within the range of about 0.01 to 0.3, and z is within the range of about 0.01 to 0.4, with the sum of x+y+z=1.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: January 12, 1999
    Assignee: Hewlett-Packard Company
    Inventors: Khe C. Nguyen, Sivapackia Ganapathiappan
  • Patent number: 5856013
    Abstract: Electrical components comprising a ohmic contact-providing layer and a charge transport layer wherein the ohmic contact-providing layer comprises a fluorinated carbon filled fluoropolymer.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: January 5, 1999
    Inventors: Martin A. Abkowitz, Frederick E. Knier, Jr., Ihor W. Tarnawskyj, Milan Stolka, Joseph Mammino, Kock-Yee Law
  • Patent number: 5846681
    Abstract: An imaging member has a substrate of a polymer insoluble in solvent for the charge transport layer, a Tg of at least 90.degree. C. and a linear thermal contraction coefficient substantially identical to the linear thermal contraction coefficient of a charge transport layer.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: December 8, 1998
    Assignee: Xerox Corporation
    Inventors: Robert C. U. Yu, Richard L. Post
  • Patent number: 5840454
    Abstract: An aromatic polycarbonate containing a structural unit of the formula: ##STR1## wherein R.sup.1 is a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group, Ar.sup.1 is a substituted or unsubstituted aryl group and Ar.sup.2 and Ar.sup.3 are independently a substituted or unsubstituted arylene group. The aromatic polycarbonate is capable of transferring charges and is used for forming a photosensitive layer of an electrophotographic photosensitive medium.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: November 24, 1998
    Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.
    Inventors: Kazukiyo Nagai, Masaomi Sasaki, Hiroshi Tamura, Tetsuro Suzuki, Tomoyuki Shimada, Chihaya Adachi, Chiaki Tanaka, Nozomu Tamoto, Kouji Kishida, Akira Katayama, Mitsutoshi Anzai, Akihiro Imai
  • Patent number: 5834147
    Abstract: A photosensitive member for electrophotography having excellent electrophotographic characteristics such as chargeability, photosensitivity and dark attenuation, excellent corona resistance and excellent durability, which comprises an electrically conductive support and a photosensitive layer containing a resin binder and particles of a photoconductive phthalocyanine compound dispersed in said binder, said photosensitive layer containing at least one member selected from the group consisting of an electron acceptive material, a coupling agent, an antioxidant and a hydroxyl group-containing polymer.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: November 10, 1998
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Suguru Nagae, Kazuko Wakita, Toshio Kobayashi, Yoshimi Sugimoto, Sei Tsunoda, Kikuo Hayama, Koe Enmanji
  • Patent number: 5830614
    Abstract: This invention relates to a charge transport dual layer for use in a multilayer photoreceptor comprising a support layer, a charge generating layer and a charge transport dual layer including a first transport layer containing a charge-transporting polymer, and a second transport layer containing a charge-transporting polymer having a lower weight percent of charge transporting segments than the charge-transporting polymer in the first transport layer. This structure has greater resistance to corona effects and provides for a longer service life. The charge-transporting polymers preferably comprise polymeric arylamine compounds.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: November 3, 1998
    Assignee: Xerox Corporation
    Inventors: Damodar M. Pai, William W. Limburg, John F. Yanus, Paul J. DeFeo
  • Patent number: 5814426
    Abstract: Disclosed is an imaging member which comprises a conductive substrate, a photogenerating material, and a binder which comprises a polymer of the formulae I, II, III, IV, V, VI, VII, VIII, IX, or X as further defined herein.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: September 29, 1998
    Assignee: Xerox Corporation
    Inventors: Timothy J. Fuller, Leon A. Teuscher, John F. Yanus, Damodar M. Pai, Kathleen M. Carmichael, Edward F. Grabowski, Paul F. Zukoski
  • Patent number: 5804343
    Abstract: An electrophotographic photoconductor including an electroconductive support and a photoconductive layer formed thereon, which has at least a charge generation layer containing a charge generating material and a polymeric charge transporting material, and a charge transport layer containing a polymeric charge transporting material.
    Type: Grant
    Filed: January 24, 1996
    Date of Patent: September 8, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Minoru Umeda, Tatsuya Niimi
  • Patent number: 5804346
    Abstract: An electrophotographic photoreceptor for digital photo-input, having a threshold value in its photo-induced decay curve and having a photosensitive layer of titanylphthalocyanine dispersed in a binder resin provided on an electroconductive substrate, wherein the binder resin is a polycarbonate resin and the photosensitive layer contains a compound having a carboxyl group.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: September 8, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toyoshi Ohashi, Masayoshi Yabe, Shinichi Suzuki
  • Patent number: 5800955
    Abstract: An electrophotographic photosensitive member is disclosed which comprises a conductive support and a photosensitive layer provided on the conductive support. A surface layer of the electrophotographic photosensitive member contains a polycarbonate resin having a chain fluoroalkyl group having 4 or more carbon atoms. Also, an electrophotographic apparatus and a device unit are disclosed which comprise the electrophotographic photosensitive member.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: September 1, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noboru Kashimura, Harumi Sakoh, Shoji Amamiya, Tatsuya Ikezue
  • Patent number: 5789126
    Abstract: Provided is an electrophotographic photoconductor comprising an electroconductive support and a photosensitive layer including a charge generation layer and a charge transport layer formed on the charge generation layer, the photosensitive layer being formed on the electroconductive support either directly or via an intermediate layer,wherein the charge transport layer contains a polyester resin having a structural unit (1) and a structural unit (2): ##STR1## wherein h:i is from 3:7 to 7:3, (h+i) is an integer from 10 to 1000, and a is an integer from 1 to 10, and the weight of the polyester resin is from 10 to 30 wt % to the total weight of resins contained in said charge transport layer. The residual potential of the photoconductor does not increase even upon repeated use under high temperature and high humidity. When a polycarbonate resin is contained as a binding resin in the charge transport layer, the surface of the photoconductor can be made tough and hardly scratched.
    Type: Grant
    Filed: June 27, 1997
    Date of Patent: August 4, 1998
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Hiroshi Sugimura
  • Patent number: 5786119
    Abstract: An electrophotographic element comprising a high mobility charge transport layer. The layer binder is a polyester according to formula I: ##STR1## wherein Ar represents phenylene, terephthoyl, isophthoyl, 5-t-butyl-1,3-phenylene and phenylene indane;D represents alkyl, linear or branched, or cycloalkyl, having from 4 to about 12 carbons;R.sup.1, R.sup.2, R.sup.7, and R.sup.8 represent H, alkyl having 1 to 4 carbon atoms, cyclohexyl, norbornyl, phenylindanyl, perfluoralkyl having 1 to 4 carbon atoms, .alpha., .alpha.-dihydrofluoroalkyl having 1 to 4 carbon atoms, and .alpha.,.alpha.,.omega.-hydrofluoroalkyl having 1 to 4 carbon atoms; andR.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.9, R.sup.10, R.sup.11, and R.sup.12 represent, H, halo and alkyl having from 1 to about 6 carbons;x is from 0 to 0.8; andy is from 0 to 1.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: July 28, 1998
    Assignee: Eastman Kodak Company
    Inventors: Louis Joseph Sorriero, Marie B. O'Regan, Paul Michael Borsenberger
  • Patent number: 5786118
    Abstract: A photoconductive recording material comprising a support and a charge generating layer (CGL) in contiguous relationship with a charge transporting layer (CTL) containing a p-charge transporting material (p-CTM), wherein the binder of said charge generating layer (CGL) has been made insoluble in methylene chloride by crosslinking, and said binder is composed essentially of at least one epoxy resin (1) as defined herein and/or at least one dialkanolamine-modified epoxy resin linked with at least one polyisocyanate.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: July 28, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: David Terrell, Stefaan De Meutter, Marcel Monbaliu
  • Patent number: 5780194
    Abstract: The present invention provides an electrophotosensitive material comprising a conductive substrate and a photosensitive layer provided on the conductive substrate, the photosensitive layer comprising a specific hole transferring material and/or electron transferring material and a binding resin of a polyester resin which is a substantially linear polymer obtained by using a specific dihydroxy compound represented by the general formula (1): ##STR1## wherein R.sup.1 is an alkylene group having 2 to 4 carbon atoms; and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different and indicate a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an aryl group or an aralkyl group or the like. This photosensitive material is improved in sensitivity, and is also superior in adhesion to conductive substrate as well as mechanical strength such as wear resistance, etc.
    Type: Grant
    Filed: April 9, 1996
    Date of Patent: July 14, 1998
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Masato Katsukawa, Akiyoshi Urano, Ayako Sugase, Mitsuo Ihara, Ichiro Yamazato, Yuka Nakamura
  • Patent number: 5780192
    Abstract: A multiactive photoconductive element exhibiting reduced black spots in discharged area development systems. The element includes (A) a conductive layer, (B) an aggregate charge generation layer in direct physcial contact with the conductive layer and (C) a charge transport layer. The charge generation layer contains (i) a binder an adhesive polymer. The charge transport layer contains a binder according to formula II: ##STR1## wherein the Ar, R.sup.1, R.sup.2, R.sup.7, R.sup.8, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.9, R.sup.10, R.sup.11, and R.sup.12 and x are defined in the specification.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: July 14, 1998
    Assignee: Eastman Kodak Company
    Inventors: Marie B. O'Regan, Anne F. Lairmore, Jeffrey R. Murray, Louis J. Sorriero, Albert V. Buettner, David S. Weiss
  • Patent number: 5763126
    Abstract: The present invention provides an electrophotographic photoreceptor having a uniform film, in which the electrical characteristics are not deteriorated over an extended period of time without causing abrasion, scratches and film defects on the surface of the photoreceptor by the contact with toner, a developer, paper and a cleaning blade and which can repeatedly be used. The electrophotographic photoreceptor has a conductive support and a photoconductive layer provided on the above conductive support, and the photoconductive layer contains a charge-generating material, a charge-transporting material and a binder resin having no or one glass transition point.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: June 9, 1998
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Masato Miyauchi, Kumiko Morita