Binder For Radiation-conductive Composition Patents (Class 430/96)
  • Patent number: 5759636
    Abstract: A method for forming electrographic imaging elements comprising a uniform dielectric layer is disclosed. The method comprises coating a conductive coating composition containing polymerizable precursors onto a base, curing the composition to form a conductive layer, and coating a dielectric layer on top of the conductive layer. The elements can be used to produce images have higher image density, reduced background, reduced grain, reduced mottle, reduced overtoning, and greater small-scale uniformity than comparable images formed on electrographic imaging elements produced by other methods. The elements are particularly useful for forming large size colored images, such as are required for posters, displays, other indoor advertising.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: June 2, 1998
    Assignee: Rexam Graphics, Inc.
    Inventors: Dene Harvey Taylor, Everett Wyman Bennett, Richard Scott Himmelwright, Douglas Allan Cahill, Weitong Shi
  • Patent number: 5750300
    Abstract: Embodiments of photoconductors and methods of making photoconductors for electophotography are described, each embodiment comprising a complex between metal oxide phthalocyanine compound(s) and hydroxy compound(s). A metal oxide phthalocyanine pigment exhibits extended photoresponse between 850 nm and 1000 nm when it is milled with a specific hydroxy binder, which preferably includes a modified poly-vinyl butyral binder containing a --CH.sub.2 CH.sub.2 OH unit, a cyclohexanol unit, or another hydroxy unit. Optionally, hydroxy solvents or other hydroxy additives may also be included. Preferably, the pigment is dehydrated or hydroxy-starved before milling with the binder and solvents. The metal oxide phthalocyanine pigments and the hydroxy groups form a complex which extends the photo-response of an OPC to wavelengths beyond about 850 nm, in order to achieve higher xerographic speed with higher resolution.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: May 12, 1998
    Assignee: Hewlett-Packard Company
    Inventor: Khe C. Nguyen
  • Patent number: 5747203
    Abstract: An electrophotographic photoreceptor comprising an electrically conductive support and at least a carrier generation layer and a carrier transport layer formed on the substrate, wherein said carrier generation layer contains a polyester resin having a repeating structural unit of the following formula (I): ##STR1## wherein each of R.sup.1 and R.sup.2 is an alkylene group which may have a substituent; each of R.sup.3 and R.sup.4 is a hydrogen atom, an alkyl group which may have a substituent or an aryl group which may have a substituent, or R.sup.3 and R.sup.4 may together form a ring; Ar is an arylene group which may have a substituent; each of Ar.sup.1 and Ar.sup.2 is a phenylene group which may have a substituent; and each of m and n is from 0 to 10, provided that m and n are not simultaneously 0.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: May 5, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Mamoru Nozomi, Osamu Murakami, Masahiro Fuse, Makoto Furuune
  • Patent number: 5744272
    Abstract: An electrophotographic recording material comprising:an electrically conductive base layer;a photoconductive layer which can be de-coated with alkaline solutions, the photoconductive layer comprising an organic photoconductor, a sensitizer and a binder comprising a mixture of:a) a copolymer comprising units composed of a first vinyl aromatic compound and units composed of maleic anhydride and/or a maleic partial ester, andb) a copolymer comprising units composed of a second vinyl aromatic compound and units of (meth)acrylic acid.
    Type: Grant
    Filed: March 25, 1996
    Date of Patent: April 28, 1998
    Assignee: AGFA-Gevaert AG
    Inventors: Andreas Elsaesser, Werner Frass, Fritz-Feo Grabley, Gabor Jerling
  • Patent number: 5736285
    Abstract: An electrophotographic photosensitive member including a photosensitive layer on a conductive substrate thereof. The photosensitive layer contains a charge transport polyester resin containing at least one of structures represented by the following general formulas (I-1) and (I-2) as a partial structure of repeated units; and at least one bisazo pigment represented by the following general formula (A) or condensational and polycyclic aromatic pigment: ##STR1## where R.sub.1 to R.sub.4 are each independently, a hydrogen atom or the like, X is a bivalent aryl group, k and I are 0 or 1 and T is a hydrocarbon radical,Cp-N.dbd.N-G-N.dbd.N-Cp' (A)wherein Cp and Cp' are each a coupler and G is a predetermined bivalent group.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: April 7, 1998
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Masahiro Iwasaki, Toru Ishii
  • Patent number: 5733695
    Abstract: A multiactive electrophotographic element comprising an electrically conductive support, a photoconductive pigment containing charge generation layer and a charge transport layer wherein the charge generation layer contains a polyester-ionomer binder having a weight average molecular weight of 2,500 to 75,000 and a glass transition temperature of 20.degree. to 150.degree. C.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: March 31, 1998
    Assignee: Eastman Kodak Company
    Inventors: Michel F. Molaire, Louis Joseph Sorriero
  • Patent number: 5731078
    Abstract: A coated donor roll comprises a core with a coating, the coating comprising a charge transporting polymer, an organic acid metal salt compound, and iodine.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: March 24, 1998
    Assignee: Xerox Corporation
    Inventors: Bing R. Hsieh, Joan R. Ewing, Damodar M. Pai, Kathyrn A. Wallace, Jerry H. Taylor, Francois Soos, Joseph R. Weber
  • Patent number: 5731118
    Abstract: A charge transporting random copolyester resin comprising a repeating unit comprising at least one partial structural unit represented by formula (I-1) or (I-2), and at least one partial structural unit represented by formula (II) as a dicarboxylic acid component: ##STR1## where the symbols in the above formulae are defined in the specification. A process for producing the same and an organic electronic device comprising the charge transporting random copolyester resin are also disclosed.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: March 24, 1998
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Masahiro Iwasaki
  • Patent number: 5725985
    Abstract: An electrophotographic imaging member including a substrate, a charge generating layer and a charge transport layer, the charge generating layer includes photoconductive particles selected from the group consisting of hydroxygallium phthalocyanine particles and titanyl phthalocyanine particles dispersed in a polymer matrix, the matrix comprising a uniform mixture of a film forming terpolymer reaction product of vinyl chloride, vinyl acetate and maleic acid and a film forming copolymer reaction product of vinyl chloride and vinyl acetate.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: March 10, 1998
    Assignee: Xerox Corporation
    Inventors: Richard H. Nealey, Martha J. Stegbauer
  • Patent number: 5723243
    Abstract: An electrophotographic photoconductor includes an electroconductive support, and a photoconductive layer formed thereon containing as an effective component an aromatic polycarbonate resin having a repeat unit of formula (I), or two repeat units of formula (II) and formula (III): ##STR1## wherein n, Ar.sup.1, Ar.sup.2, Ar.sup.3, R.sup.1, R.sup.2 and X are as specified in the specification, ##STR2## wherein k and j are also as specified in the specification.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: March 3, 1998
    Assignees: Ricoh Company, Ltd., Hodogaya Chemical Co., Ltd.
    Inventors: Masaomi Sasaki, Hiroshi Tamura, Tomoyuki Shimada, Tetsuro Suzuki, Chiaki Tanaka, Kouji Kishida, Akira Katayama, Kazukiyo Nagai, Chihaya Adachi, Nozomu Tamoto, Mitsutoshi Anzai, Akihiro Imai
  • Patent number: 5702856
    Abstract: In a method for making an image comprising the steps of forming an electrostatic image on a photosensitive body having a photosensitive layer and forming a visible image by means of a liquid development utilizing a developing liquid for electrostatic charge, the photosensitive layer comprises, as an electric charge transporting material, an electric charge transporting polymeric compound which contains as a partial moiety of repeating units the structures represented by the following general formulas 1-1 and/or 1-2, ##STR1## where R.sub.1 -R.sub.4 are each independently hydrogen, an alkyl radical that may have a substituent, or the like, X is a substituted or unsubstituted divalent aryl radical, k and l are each an integer of 0 or 1, and T is a divalent hydrocarbon radical of 1-10 carbon atoms that may be branched.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: December 30, 1997
    Assignee: Fuji Xerox Co, Ltd.
    Inventors: Kiyokazu Mashimo, Fumio Ojima, Toru Ishii, Katsumi Nukada
  • Patent number: 5693396
    Abstract: A near infrared light-absorbing dye comprising phthalocyanine compounds represented by the following formula (2): ##STR1## wherein in formula (2), M is two hydrogen atoms, a divalent metallic atom, a trivalent monosubstituted metallic atom, a tetravalent disubstituted metallic atom or an oxymetal atom, and L.sup.1, L.sup.2, L.sup.3 and L.sup.4 are each independently formula (a) or (b), ##STR2## in the formula (a) or (b), R.sup.1 and R.sup.3 are each a substituted or unsubstituted alkyl group, and R.sup.2 is a straight chain or branched halogenated alkyl or alkenyl group having 3 to 10 carbon atoms,X is a chlorine, bromine or iodine atom, and m is an integer of 1 to 12, provided that formula (2) represents a mixture of L.sup.1 =L.sup.2 =L.sup.3 =L.sup.4 =formula (a), L.sup.1 =L.sup.2 =L.sup.4 =formula (a) and L.sup.3 =formula (b), L.sup.1 =L.sup.4 =formula (a) and L.sup.2 =L.sup.3 =formula (b), L.sup.1 =L.sup.3 =formula (a) and L.sup.2 =L.sup.4 =formula (b), L.sup.1 =formula (a) and L.sup.2 =L.sup.3 =L.sup.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: December 2, 1997
    Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals, Inc.
    Inventors: Tsutami Misawa, Kenichi Sugimoto, Taizo Nishimoto, Takeshi Tsuda, Keisuke Takuma
  • Patent number: 5688581
    Abstract: An electrographic image transfer element having a protective coating is disclosed. The protective coating is a single protective layer that contains a fluoropolymer and an acrylic polymer. Because the protective coating is resistant to surface pitting, dirt, stains, and general degradation, images formed from the element can be used effectively on billboards, banners, and other outdoor signs.
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: November 18, 1997
    Assignee: Rexam Graphics, Incorporated
    Inventors: Theresa M. Chagnon, Douglas Allan Cahill, Richard Scott Himmelwright, Dene Harvey Taylor
  • Patent number: 5688620
    Abstract: Disclosed is an electrophotographic photoreceptor which gives a very low residual potential and scarcely accumulates the residual potential even by repeated use and which varies very slightly in a charging property and sensitivity and has a very excellent stability. The electrophotographic photoreceptor has a conductive support and a photoconductive layer provided on the conductive support. The photoconductive layer contains a charge-generating material, a charge-transporting material, a binder resin and a fatty acid ester compound represented by the following Formula (1): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent hydrogen or a saturated or unsaturated aliphatic hydrocarbon group which may have substituents, and n and m each represent an integer of 1 to 10.
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: November 18, 1997
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yoshimasa Fujita, Kazushige Morita
  • Patent number: 5686216
    Abstract: An object of the present invention is to provide a photosensitive member having an excellent durability. A sensitizing solution is prepared by adding a polyester resin (resin A) synthesized using an isophthalic acid, neopentyl glycol, phthalic anhydride and adipic acid, other polyester resins, an X-form metal free phthalocyanine as a phthalocyanine type photoconductive compound and a curing agent to a solvent, and is dip-coated on a polyamide layer on an aluminum plate and then dried and cured to give a photosensitive member.
    Type: Grant
    Filed: November 14, 1995
    Date of Patent: November 11, 1997
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Kazuki Kubo, Takamitsu Fujimoto, Suguru Nagae, Toshio Kobayashi, Kazuko Wakita
  • Patent number: 5681678
    Abstract: An electrophotographic imaging member including a substrate, a charge generating layer and a charge transport layer, the charge generating layer comprising photoconductive hydroxygallium phthalocyanine particles dispersed in a polymer matrix, the matrix comprising a polymeric film forming reaction product of at least vinyl chloride, vinyl acetate and hydroxyalkyl acrylate.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: October 28, 1997
    Assignee: Xerox Corporation
    Inventors: Richard H. Nealey, Martha J. Stegbauer
  • Patent number: 5677096
    Abstract: An electrophotographic photoconductor, having an electrically conductive supporting substrate, an intermediate layer disposed thereon, a charge generation layer disposed on the intermediate layer, and a charge transport layer disposed on the charge generation layer, wherein the charge generation layer comprises particular titanyl phthalocyanine pigments dispersed in a particular binder resin, is provided which has improved photosensitivity and durability and is readily used for an analogue or digital photocopying machine, laser printer and laser facsimile apparatus.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: October 14, 1997
    Assignee: Ricoh Company, Ltd.
    Inventor: Yasuo Suzuki
  • Patent number: 5670283
    Abstract: An electrophotographic material for color proofing which comprises a substrate, a photoconductive layer and a transfer layer in this order, and is used for preparing a color proof in a process wherein at least one color toner image is electrophotographically formed on the transfer layer and then transferred together with said transfer layer to a sheet material to prepare the color proof, wherein said photoconductive layer comprises a polymer (P) and/or a polymer particle (L) which contain units having fluorine atom(s) and/or silicon atom(s) at least in the region near the surface facing said transfer layer and the surface of said photoconductive layer which contacts with the transfer layer has tack strength of not more than 150 gram.multidot.force, which is measured by Pressure Sensitive Tape and Sheet Test of JIS Z0237-1980.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: September 23, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Sadao Osawa
  • Patent number: 5665501
    Abstract: A photoconductive element having a photoconductive layer containing a polycarbonate binder based on di-(monohydroxyaryl) alkane, wherein the polycarbonate contains a branching agent selected from the group consisting of 1,2,4-benzene tricarboxylic acid, 1,3,5-benzene tricarboxylic acid, 1,2,4-benzene tricarboxylic acid chloride and 1,3,5-benzene tricarboxylic acid chloride.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: September 9, 1997
    Assignee: Oce-Nederland, B.V.
    Inventors: Petrus J. M. Derks, Hendrik J. A. Ogrinc
  • Patent number: 5654119
    Abstract: An organic electronic device comprises a layer containing a charge-transporting polyester comprising a repeating unit comprising at least one of partial structural units represented by the following formulae (I-a) and (I-b) as a partial structure of repeating unit: ##STR1## where the symbols in the above formulae are defined in the specification.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: August 5, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Toru Ishii, Fumio Ojima, Kiyokazu Mashimo, Tomozumi Uesaka, Tomoo Kobayashi, Katsumi Nukada, Akira Imai, Masahiro Iwasaki
  • Patent number: 5629117
    Abstract: There is disclosed an electrophotosensitive material using a binding resin of a bisphenol C type, bisphenol Z type, bisphenol Z type containing a substituent or bisphenol C-copolymer type polycarbonate in combination with a hole transferring material of a specific benzidine or phenylenediamine derivative. This photosensitive material is superior in mechanical strength and repeat characteristics and has a high glass transition temperature and a high sensitivity.
    Type: Grant
    Filed: October 12, 1995
    Date of Patent: May 13, 1997
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Masato Katsukawa, Masashi Tanaka, Ichiro Yamazato, Yuka Nakamura
  • Patent number: 5626996
    Abstract: An electrophotographic material for color proofing which comprises a substrate, a photoconductive layer and a transfer layer in this order, wherein said photoconductive layer comprises a polymer (P) which contains at least one polymer segment (X) containing not less than 50% by weight of units having fluorine atom(s) and/or silicon atom(s) and at least one polymer segment (Y) containing units having photosetting and/or thermosetting group(s); a polymer (Q) which contains units represented by the formula I--CH(a.sub.1)--C(a.sub.2)(COOR.sub.3)--wherein a.sub.1 and a.sub.2 each independently represent a hydrogen atom, and R.sub.3 represents a hydrocarbon group; and contains at least one polar group such as --PO.sub.3 H.sub.2, --SO.sub.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: May 6, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Sadao Osawa
  • Patent number: 5624777
    Abstract: An electrophotographic lithographic printing plate precursor having a photoconductive layer containing a resin which contains a functional group capable of forming --COOH group and a functional group capable of forming at least one group selected from --SO.sub.3 H group, --SO.sub.2 H group and --PO.sub.3 H group and which has a crosslinking structure.Owing to the specific polar group in the resin, a lithographic printing plate which is free from the occurrence of background stain and has excellent oil-desensitivity and high printing durability is provided.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: April 29, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Hiroshi Tashiro, Akio Oda, Kazuo Ishii
  • Patent number: 5616442
    Abstract: An electrophotographic photosensitive member is constituted by disposing a photosensitive layer on a support. The photosensitive layer is characterized by containing a specific triphenylamine compound having at least two phenyl groups each substituted with two alkyl groups including one alkyl group located in meta-position in conjunction with nitrogen atom or each substituted with three alkyl groups. The photosensitive member is suitable for providing an electrophotographic apparatus showing excellent electrophotographic characteristics such as a high photosensitivity, a good potential stability in repetitive use, a decreased transfer memory, no crack in the photosensitive layer and no crystallization of a charge-transporting material.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: April 1, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Kanemaru, Toshihiro Kikuchi, Akihiro Senoo, Kouichi Nakata
  • Patent number: 5604064
    Abstract: A charge-transporting polymer which is excellent in solubility and film-forming property and usable in producing various organic electron devices and whose ionization potential is controllable, and an organic electronic device, in particular electrophotographic photoreceptor, containing the same are disclosed; the charge-transporting polymer being represented by formula (I-1) or (I-2) ##STR1## wherein Y represents a divalent hydrocarbon group; Z represents a divalent hydrocarbon group; A represents a group represented by formula (II) ##STR2## (wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an alkoxy group, a substituted or unsubstituted aryl group, a substituted amino group, or a halogen atom, X represents a substituted or unsubstituted divalent aryl group, n represents an integer of 1 to 5, and k is 0 or 1); B represents a group represented by --O--(Y--O).sub.m --H or --O--(Y--O).sub.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: February 18, 1997
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Katsumi Nukada, Akira Imai, Masahiro Iwasaki, Ryosaku Igarashi
  • Patent number: 5604063
    Abstract: An electrophotographic member which can give printed images of high quality and is markedly high in photoresponsiveness can be provided without using halogen solvents by using a composition for charge transport layer which contains a polycarbonate resin having a recurring structural unit represented by the following formula (I) and, if necessary, a specific styryl compound, a specific hydrazone compound and the like: ##STR1## wherein R.sub.1 and R.sub.2 =alkyl, etc.R.sub.3 through R.sub.18 =H, alkyl, etc.k/m=1/1-10/1.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: February 18, 1997
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Keiichi Endo, Seiji Miyaoka, Kouji Ohkoshi, Susumu Kaneko, Yasuo Katsuya, Akira Kageyama, Yoshii Morishita
  • Patent number: 5601958
    Abstract: A method for preparation of a printing plate by an electrophotographic process comprising forming a peelable transfer layer capable of being removed upon a chemical reaction treatment on a surface of an electrophotographic light-sensitive element, forming a toner image by an electrophotographic process on the transfer layer, heat-transferring the toner image together with the transfer layer onto a receiving material having a surface capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, and removing the transfer layer on the receiving material upon the chemical reaction treatment wherein the transfer layer is formed by an electrodeposition coating method using thermoplastic resin grains (AL) each containing a rein (A.sub.1) having a glass transition point of from 10.degree. C. to 140.degree. C. or a softening point of from 35.degree. C. to 180.degree. C. and a resin (A.sub.2) having a glass transition point of not more than 45.degree. C.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: February 11, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Makoto Momota, Hiroyuki Ohishi
  • Patent number: 5597672
    Abstract: A method for preparation of a printing plate by an electrophotographic process comprising providing a peelable first transfer layer (T.sub.1) containing a resin (A) capable of being removed upon a chemical reaction treatment on an electrophotographic light-sensitive element, forming a toner image on the first transfer layer by an electrophotographic process, either (a) providing a second transfer layer (T.sub.2) containing a resin (A) capable of being removed upon the chemical reaction treatment on the toner image and the first transfer layer in the non-image area and transferring the toner image together with the first transfer layer and the second transfer layer from the light-sensitive element to a receiving material having a surface capable of providing a hydrophilic surface suitable for lithographic printing at the time of printing, or (b) transferring the toner image together with the first transfer layer from the light-sensitive element onto the second transfer layer (T.sub.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: January 28, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Eiichi Kato
  • Patent number: 5597673
    Abstract: A toner comprising a binder resin, a colorant, and a charge controlling agent comprising (a) a specific iron-containing azo dye and (b) a copolymer of a styrene monomer and/or an acrylic monomer with a sulfonic acid group-containing acrylamide, wherein the amount of the azo dye present on the surface of the toner is 7.times.10.sup.-3 to 20.times.10.sup.-3 g per 1 g of said toner. The toner is suitably used in conjunction with carrier particles, each having a surface layer containing a silicone resin, electroconductive particles and a silane coupling agent.
    Type: Grant
    Filed: September 1, 1995
    Date of Patent: January 28, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Kazuhito Watanabe, Toshiki Nanya
  • Patent number: 5585214
    Abstract: An electrophotographic photosensitive member having a photosensitive layer formed on a supporting member and a protective layer formed on the photosensitive layer if necessary. At least one of the photosensitive layer and the protective layer is formed of a material containing a cured resin obtained by end-reactive curing of a polycarbonate having glycidyl end groups.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: December 17, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Noboru Kashimura, Shoji Amamiya, Masaaki Yamagami
  • Patent number: 5585212
    Abstract: A photoconductor for electrophotography comprising a photoconductive layer having a thickness of 27 micro-meter or more and including as a binder resin a first polycarbonate resin having a low molecular weight constituent which has a numerical average molecular weight being 10,000 or more and under 22,000, and a second polycarbonate resin having a high molecular weight constituent which has a numerical average molecular weight being 22,000 or more and under 38,000. The photoconductor has a high durability without toner filming, a wear resistance, a stable electrophotographic characteristics and an excellent cleaning characteristic.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: December 17, 1996
    Assignee: Minolta Co., Ltd.
    Inventor: Hideaki Ueda
  • Patent number: 5582942
    Abstract: A printing plate for electrophotographic type plate making having a photoconductive layer on an electrically conductive support. The photoconductive layer includes an organic photoconductive compound and a binding resin containing a copolymer including an acrylic acid ester or methacrylic acid ester having an aromatic ring and a vinyl polymerizable monomer having one to three acidic functional groups.
    Type: Grant
    Filed: April 10, 1989
    Date of Patent: December 10, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroaki Yokoya, Hiromichi Tachikawa
  • Patent number: 5580690
    Abstract: An electrophotographic light-sensitive material which has improved electrostatic characteristics and image forming performance and is excellent particularly in reproducibility of highly accurate image using a liquid developer and image forming performance upon a scanning exposure system using a laser beam of a low power.The electrophotographic light-sensitive material contains, as a binder resin, at least one resin selected from a low molecular weight resin (A.sub.1) formed from a macromonomer containing a polymer component of formula (I) and a monomer of the formula (I) and having a polar group bonded at one terminal of the main chain thereof, a low molecular weight resin (A.sub.2) formed from a macromonomer containing at random polar groups and a low molecular weight resin (A.sub.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: December 3, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Kazuo Ishii
  • Patent number: 5578406
    Abstract: An electrophotographic photoreceptor is disclosed which comprises an electroconductive substrate and a photosensitive layer formed thereon, said photosensitive layer containing as a binder resin a copolycarbonate resin comprising a structural unit represented by formula (I) ##STR1## and a structural unit represented by formula (II) ##STR2## wherein X and X' each is hydrogen, a halogen, or methyl; R, a substituent, is hydroxyl, carboxyl, acetyl, or a C.sub.1-4 alkyl; and j is 0 to 3 and further containing as a charge transport material a triarylamine compound represented by formula (III) ##STR3## wherein R.sub.1 is hydrogen or methyl; k is 1 or 2; and Ar.sub.1 and Ar.sub.2 each is an optionally substituted aryl.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: November 26, 1996
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Fumio Ojima, Tomoo Kobayashi, Toru Ishii, Kiyokazu Mashimo, Tomozumi Uesaka
  • Patent number: 5573879
    Abstract: An electrophotographic light-sensitive material which has improved electrostatic characteristics and image forming performance and is excellent particularly in reproducibility of highly accurate image using a liquid developer and image forming performance upon a scanning exposure system using a laser beam of a low power.The electrophotographic light-sensitive material contains, as a binder resin, at least one resin (A) which has a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and contains not less than 30% by weight of a polymer component of the formula (I) and from 0.5 to 15% by weight of a specified polar group-containing polymer component and at least one resin (B) which is a starlike polymer having a weight average molecular weight of from 3.times.10.sup.4 to 1.times.10.sup.6 and comprising an organic molecule having bonded thereto at least three polymer chains each containing a polymer component containing a specified polar group and a polymer component of the formula (I).
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: November 12, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Kazuo Ishii
  • Patent number: 5571648
    Abstract: An electrophotographic imaging member comprising a support substrate having a two electrically conductive ground plane layer comprising a layer comprising zirconium over a layer comprising titanium,a hole blocking layer, an adhesive layer comprising a copolyester film forming resin, an intermediate layer in contact with said adhesive layer, said intermediate layer comprising a film forming carbazole polymer, a charge generation layer comprising perylene or a phthalocyanine particles dispersed in a film forming polymer binder blend of polycarbonate and carbazole polymer, and a hole transport layer, said hole transport layer being substantially non-absorbing in the spectral region at which the charge generation layer generates and injects photogenerated holes but being capable of supporting the injection of photogenerated holes from said charge generation layer and transporting said holes through said charge transport layer.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: November 5, 1996
    Assignee: Xerox Corporation
    Inventors: Satchidanand Mishra, Robert C. U. Yu, Donald P. Sullivan, Kathleen M. Carmichael, Edward F. Grabowski, Anthony M. Horgan, William W. Limburg, Sharon E. Normandin, Richard L. Post, Donald C. VonHoene
  • Patent number: 5571647
    Abstract: An electrophotographic imaging member comprising a support substrate having a two layered electrically conductive outer surface, a hole blocking layer, an adhesive layer comprising a copolyester resin, a charge generation layer comprising photoconductive perylene or phthalocyanine particles dispersed in a film forming resin binder blend comprising polyvinyl butyral copolymer and a copolyester selected from the group consisting of a first copolyester, a second copolyester and mixtures thereof, and a charge transport layer.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: November 5, 1996
    Assignee: Xerox Corporation
    Inventors: Satchidanand Mishra, Robert C. U. Yu, Kathleen M. Carmichael, Edward F. Grabowski, Anthony M. Horgan, William W. Limburg, Sharon E. Normandin, Damodar M. Pai, Richard L. Post, Donald P. Sullivan, Donald C. VonHoene
  • Patent number: 5571649
    Abstract: An electrophotographic imaging member comprising a support substrate having a two layered electrically conductive ground plane layer comprising a layer comprising zirconium over a layer comprising titanium, a hole blocking layer, an adhesive layer comprising a polymer blend comprising a carbazole polymer and a film forming thermoplastic resin selected from the group consisting of copolyester, polyarylate and polyurethane in contiguous contact with the hole blocking layer, a charge generation layer comprising perylene or a phthalocyanine pigment particles dispersed in a polycarbonate film forming binder in contiguous contact with the adhesive layer, and a hole transport layer, the hole transport layer being substantially non-absorbing in the spectral region at which the charge generation layer generates and injects photogenerated holes but being capable of supporting the injection of photogenerated holes from the charge generation layer and transporting the holes through the charge transport layer.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: November 5, 1996
    Assignee: Xerox Corporation
    Inventors: Satchidanand Mishra, Robert C. U. Yu, Kathleen M. Carmichael, Edward F. Grabowski, Anthony M. Horgan, William W. Limburg, Sharon E. Normandin, Damodar M. Pai, Richard L. Post, Donald P. Sullivan, Donald C. VonHoene
  • Patent number: 5569566
    Abstract: A photoreceptor for electrophotography which comprises a conductive substrate and a photoconductive layer on the conductive substrate, a polycarbonate resin containing free chlorine of 2 ppm or below being contained in the photoconductive layer. No minute black spots generate and an excellent quality of picture is provided.
    Type: Grant
    Filed: April 14, 1995
    Date of Patent: October 29, 1996
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Satoshi Kanayama, Noriyoshi Ogawa, Jun Tajima
  • Patent number: 5561016
    Abstract: An electrophotographic photoconductor composed of an electroconductive support and a photoconductive layer formed thereon, which contains a charge generating material, a binder resin including a butyral resin containing a polyvinyl butyral resin component at a molar ratio of 68 mol % or more, a charge transporting material, and biphenyl or a biphenyl derivative.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: October 1, 1996
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasuo Suzuki, Satoshi Igari
  • Patent number: 5561017
    Abstract: A polyester polymer comprising repeating units (I), or repeating units (I) and (II), and having a reduced viscosity (.eta. sp/c) of 0.2 to 10.0 dl/g, measured at 20.degree. C. as a 0.5 g/dl solution dissolved in methylene chloride is prepared by allowing a dihydric phenol (III), or dihydric phenols (III) and (IV), to react with a carbonate precursor or a dibasic acid. An electrophotographic photoreceptor which comprises an electroconductive substrate and a photosensitive layer disposed on the electroconductive substrate and containing the polyester polymer as a charge transporting material or a binder resin. ##STR1## wherein, W is --O-- or single bond, X is a divalent group which is derived from a dihydric phenol containing a hydrazine structure, each of R.sup.25 and R.sup.26 is a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, each of m and n is an integer of 0 to 4, Y is single bond, --O--, --S--, --SO--, --SO.sub.2 --, --CR.sup.27 R.sup.28 --, a 1,1-cycloalkylene group or an .alpha.,.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: October 1, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Tomohiro Nagao, Shuji Sakamoto, Hironobu Morishita, Hideyuki Miyamoto
  • Patent number: 5558966
    Abstract: An electrophotographic light-sensitive material which has improved electrostatic characteristics and image forming performance and is excellent particularly in reproducibility of highly accurate image using a liquid developer and image forming performance upon a scanning exposure system using a laser beam of a low power.The electrophotographic light-sensitive material contains, as a binder resin, at least one resin selected from a low molecular weight resin (A.sub.1) formed from a macromonomer containing a polymer component of formula (I) and a monomer of the formula (I), a low molecular weight resin (A.sub.2) formed from a macromonomer containing at random polar groups and a low molecular weight resin (A.sub.3) formed from a macromonomer containing polar groups as a block, and a resin (B) which is a medium to high molecular weight AB block copolymer comprising an A block containing a specified polar group and a B block containing a polymer component of formula (I). ##STR1## wherein a.sup.1 and a.sup.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: September 24, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Kato, Kazuo Ishii
  • Patent number: 5554473
    Abstract: Organic photoconductive imaging receptors in which the charge transport layer contains, as a binder, a copolycarbonate of 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane and 2,2-bis-(4-hydroxylphenyl)propane exhibit excellent wear resistance.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: September 10, 1996
    Assignee: Mitsubishi Chemical America, Inc.
    Inventors: Rudolf E. Cais, Frederick W. Gerriets
  • Patent number: 5545499
    Abstract: A photoconductor for use in electrophotographic reproduction devices is disclosed. This photoconductor exhibits improved oil resistance when used with liquid toners and excellent cycling stability. The photoconductors of the present invention utilize a phthalocyanine dye, particularly an X-form metal-free phthalocyanine, dispersed in a medium molecular weight polyvinyl chloride binder in the charge generating layer, and a charge transport molecule, particularly a hydrazone such as DEH, in a polyestercarbonate binder in the charge transport layer.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: August 13, 1996
    Assignee: Lexmark International, Inc.
    Inventors: Vernon M. Balthis, Ronald A. Merten, Robert J. Rumery, Robert L. Vollmer
  • Patent number: 5538827
    Abstract: Disclosed is a photosensitive material for printing comprising a photoconductive layer containing a phthalocyanine compound and a binder resin provided on a conductive substrate. The binder resin is composed of one or more sorts of resins. At least one sort of the resin is a homopolymer of a radical-polymerizable monomer (I) of the formula: ##STR1## wherein R.sup.1 is hydrogen or a methyl group, m is an integer of 2 to 5 and n is an integer of 0 to 10. An amount of the homopolymer is 0.01 to 50% by weight based on the total amount of the binder resin.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: July 23, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hisaichi Muramoto, Kazunori Kanda, Yutaka Kanoi
  • Patent number: 5536611
    Abstract: A phthalocyanine pigment dispersion using a dispersing polymer having pendant quaternary ammonium salt groups to form a highly dispersed and stable millbase is described. The pigment dispersion is compatible with poly(vinylbutyral) resins and stable in ketone solvents. The pigment dispersion is particularly useful as a charge-generating or charge-transport material in an organic photoconductor construction.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: July 16, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ravindra L. Arudi, John C. Haidos
  • Patent number: 5529869
    Abstract: An organic positive-charging photoconductor (+) OPC is disclosed. The (+) OPC has a conductive substrate; a hydroxy-containing binder component forming a layer greater than or equal to about 1 micron thick on said substrate; an X-type, metal-free phthalocyanine pigment component uniformly distributed throughout said binder component; and a reactive additive component selected from the list of cross-linkable resins, carboxlyic acid anhydrides, aldehydes, poly-ols, alkoxy silane coupling agents, reactive allyl polymers and dismaleimides, the reactive additive component also being uniformly distributed throughout, and being in cross-linked relation with, the hydroxy-containing binder component with an electron withdrawing functional group and an electron donating functional group in the same molecule. The (+) OPC, which may also contain a co-additive component, exhibits increased stability in a laser printing process.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: June 25, 1996
    Assignee: Hewlett-Packard Company
    Inventor: Khe C. Nguyen
  • Patent number: 5521041
    Abstract: A polycarbonate and a method of preparing the polycarbonate which comprises a repeating unit represented by the following general formula ##STR1## wherein each of R.sup.1 and R.sup.2 respectively is a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, each of a and b is an integer of 0 to 4, and X is a single bond, --O--, --CO--, --S--, --SO--, --SO.sub.2 --, --CR.sup.3 R.sup.4 --, a 1,1-cycloalkylidene group or an .alpha.,.omega.-alkylene group, and end groups represented by the following general formulas ##STR2## wherein, R.sup.5 is a perfluoroalkyl group or substituted perfluoroalkyl group of 1 to 30 carbon atoms, Y is --CH.sub.2 --, e is an integer of 0 to 6, Z is --O--, --CO--, --OCO--, --S--, --SO--, --SO.sub.2 -- or --NHCO--, f is 0 or 1, R.sup.6 is a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, and each of c and d is an integer satisfying c+d.ltoreq.
    Type: Grant
    Filed: October 13, 1993
    Date of Patent: May 28, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hideyuki Miyamoto, Shuji Sakamoto, Hironobu Morishita, Tomohiro Nagao
  • Patent number: 5521043
    Abstract: A photoconditive imaging member comprised of a supporting substrate, a photogenerating layer comprised of a photogenerating pigment, or photogenerating pigments dispersed in a polystyrene/poly(methacrylic acid) (A.sub.n -B.sub.m) block copolymer wherein A is the anchoring block, B is the steric stabilizing block, and n and m represent the number of segments; and a charge transport layer.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: May 28, 1996
    Assignee: Xerox Corporation
    Inventors: Nancy A. Listigovers, Charles G. Allen, Trevor I. Martin, Gordon K. Hamer, Cheng-Kuo Hsiao, Giuseppa Baranyi
  • Patent number: 5521044
    Abstract: An electrophotosensitive material of the present invention is formed by providing a photosensitive layer containing a bis-azo pigment expressed in formula (1): ##STR1## wherein A.sup.1, A.sup.2, R.sup.1 and n are as defined, as a charge generating material, and a diamine compound expressed in formula (2): ##STR2## wherein R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 p and q k, l, m and o are as defined, as a charge-trasferring material, on a conductive substrate. As a charge generating material, a perylene pigment, anthanthrone pigment, X-type metal-free phthalocyanine pigment, imidazoleperylene pigment or perylene bis-azo pigment are preferable used together with the bis-azo pigment. Thus, photosensitive material is excellent in sensitivity and durability.
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: May 28, 1996
    Assignee: Mita Industrial Co., Ltd.
    Inventors: Nariaki Muto, Keisuke Sumida, Hiroaki Iwasaki, Tsuneo Oki, Eiichi Miyamoto, Yasuyuki Hanatani, Hiroaki Sakai