Abstract: Apparatus and method are provided for improving the sample aerosol yield in plasma-emission, sequential spectroscopic analysis. A reservoir is employed and an aerosol is produced therein from a limited amount of sample liquid with the assistance of an electro-mechanical oscillator system. Only that amount of aerosol which is supplied to an interconnected plasma by a carrier gas stream is used for a single analysis. Unused aerosol in the reservoir recondenses and mixed with residual sample liquid. Nearly 100% of a sample liquid may be used in this way.

Abstract: Method for determining monomer conversion in the liquid phase by analyzing vapor phase above a polymerization mixture comprising measuring temperature of the vapor phase, analyzing the vapor phase with a gas chromatograph provided with a flame ionization detector to determine relative amount of a certain monomer in the vapor phase, correlating initial amount of the monomer with an intermediate amount of the monomer adjusted by applying a temperature correction, and determining monomer conversion on the basis of an essentially linear relationship of conversion in the liquid phase with relative amount of the monomer in the vapor phase.

Abstract: A method for measuring the alcohol concentration of an acetic acid fermentation broth which comprises (a) forming a sample gas containing volatile components present in the acetic acid fermentation broth, the volatile componentscomprising alcohol and acetic acid; (b) passing the sample gas through an absorption column packed with a material which binds acetic acid whereby the acetic acid is absorbed on the material; (c) passing the sample gas which has passed through the absorption column to a gas sensor for measuring the alcohol content of the gas by outputting an electrical signal which correlates to the alcohol content of the sample gas; and (d) determining the alcohol content of the sample gas in response to the electrical output signal from the gas sensor.

Abstract: A petroleum alcohol test kit and a method of testing petroleum for alcohol content both as to volume and type. The volume of alcohol present is determined by mixing a petroleum sample with a first colorimetric solution whereby the volume of alcohol can be visually determined. The type of alcohol present is determined by mixing the components of a second colorimetric solution for impregnation of a visual indicator. A petroleum sample is mixed with an acidified potassium permanganate solution and the resultant vapors contact the visual indicator whereby the color the indicator turns is indicative of the type of alcohol present. The kit has the necessary containers, support and solutions to carry out the testing.

Abstract: A sample modulator cell for chromatographic analysis uses a diverting valve to send a carrier gas into a duct in a generally closed circular form periodically alternately through two separate ports. A sample inlet port opens between the carrier ports so that a sample-containing gas periodically alternately flows to an exit port through two channels A and B of different lengths in the duct. A phase-shift of 180.degree. is introduced between the channels so that all of the sample introduced into the modulator will be used for the analysis, thus increasing the peak response.

Abstract: A method and apparatus for determining the composition and the concentration of biocidal gas and other gases contained in a reaction chamber during processing of material contained in the chamber and exposed to the treating gas. A valved pre-evacuated gas-sampling vessel is positioned in the reaction chamber and, thereafter, opened by remote control to receive a gas sample representative of the gaseous atmosphere present in the chamber. The sampling vessel is then closed, removed from the treatment chamber, and connected to apparatus for analyzing the gas in the vessel. The qualitative and quantitative composition of the treating gas is thus determined.

Abstract: (CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy, wherein the resonance peaks of either .sup.1 H, .sup.13 C, .sup.15 N, or .sup.29 Si may be used as a reference.

Abstract: An improved apparatus is provided for detecting the presence of small concentrations of one gas, e.g. a poisonous or other noxious gas, in another gas, e.g. air. The gaseous mixture, e.g. contaminated air is caused to contact a colorimetric detector, e.g., an enzyme, supported on or in a support surface.

Abstract: A vapor detection tube is disclosed, the tube holding an adsorbent material for adsorbing vapors, the tube having at least one end with a constriction near the end and the diameter at the far end of the tube being of about the same diameter as the main portion of the tube. There is disclosed plastic sealing caps for sealing the ends of the tube for safe and contamination free handling and shipping, the tube being so constructed and arranged that it can be easily broken at the constriction in a clean and uniform manner to provide an open tube for sampling and the tube being easily sealed by sealing members after the sampling is finished and before analysis is made.

Abstract: A method and apparatus for introducing a sample of liquid to be analyzed for dissolved gas into an analyzer. The sample is transferred from a syringe to a bubble chamber through a valved conduit. Subsequently the volitile gas is swept out of the liquid and into an analyzer by a purge gas.

Abstract: A method for determining the concentration of carbonate salts in solutions containing other inorganic salts. The method includes converting the carbonate salts to carbon dioxide by acidifying the sample, sweeping the acidified solution with an inert gas to strip the carbon dioxide from the solution and contacting an ion-selective gas-sensing electrode with the gas stream. The electrode includes a buffered solution which changes in pH depending on the concentration of carbon dioxide in the gas stream thereby providing a measure of the carbonate salt concentration in the sample.

Abstract: A method and apparatus are disclosed for extracting amine compounds from air samples without loss due to formation of nitrosamine artifacts. The apparatus includes a cartridge having a separation zone between a first port and a second port. The separation zone contains an air pervious packing of a granular, solid phase amine complexing agent. The method includes a first step of driving an air sample through the separation zone of the cartridge from the first port to the second port, and a second step of driving an eluent through the separation zone from the second port to the first port, or backflushing the cartridge. To extract amine compounds, the eluent is a solvent for the amine complexing agent in the separation zone of the cartridge. The method may contain the further step of determining the amine compound concentration of at least a portion of the eluate which passes from the separation zone following the second step of the method.

Abstract: A method and apparatus for the preparation of a liquid sample for the quantitative determination of boron by flame photometry. The sample is combined in a vessel with sulfuric acid, and an excess of methanol is added thereto. The methanol reacts with any boron present in the sample to form trimethyl borate which is volatilized by the heat of reaction between the excess methanol and sulfuric acid. The volatilized trimethyl borate is withdrawn from the vessel by either a partial vacuum or a positive pressure and is rapidly transferred to a standard flame photometer. The method is free of interference from typical boron concomitants.