Abstract: A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting.

Abstract: A matrix modifier of finely-divided metallic palladium dispersed to contact a metal constituent to improve analysis of the constituent during graphite furnace atomic absorption spectroscopy. The palladium interacts with a variety of metals in a sample to increase the vaporization temperatures of the metals. One way of contacting palladium with the metal analyte is to introduce it as a salt in solution with the sample into the graphite furnace along with a surfactant. A finely-divided metallic palladium having high surface area is produced in the furnace by introduction of hydrogen gas, which acts as a reducing agent, to reduce and maintain palladium in its metallic form at an early point in the temperature program, prior to evaporation of the surfactant.

Abstract: A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

Abstract: Ultratrace quantities of transuranic actinides are detected indirectly by their effect on the fluorescent emissions of a preselected fluorescent species. Transuranic actinides in a sample are coprecipitated with a host lattice material containing at least one preselected fluorescent species. The actinide either quenches or enhances the laser-induced fluorescence of the preselected fluorescent species. The degree of enhancement or quenching is quantitatively related to the concentration of actinide in the sample.

Abstract: Plant protoplasts are suspended in a solution of sodium alginate which is thereafter thickened by the addition of a soluble calcium or lanthanum salt to produce a matrix with large pores permeable to water and gas in which the protoplasts are held. The resulting material, in tape or spheroid form, when stored in a nutrient solution, will prolong the senescence of the protoplasts and increase their sensitivity to polluting materials. When such ribbons or particles are exposed to a polluting environment for a particular period of time, the effect of pollution can be detected by measuring the evolution of ethane or measuring the blocking of the enzyme ribulose-diphosphate-carboxylase, in the latter case using carbon dioxide marked with .sup.14 C. A control experiment in which an identical indicator treated in an equivalent environment without pollutants reveals, by comparison, the effect of the pollution.

Abstract: A process for the detection of carbon-containing ions, particularly uranyl tricarbonate, adsorbed on an ion-exchange resin, comprising introducing a sample of the ion-exchange resin to nuclear magnetic resonance (nmr) spectroscopy.

Abstract: A method and apparatus for visually monitoring the fluidized bed of a resin ion exchanger. The method includes establishing a sample fluidized bed displaced from, but in fluid communication with, the resin ion exchanger fluidized bed and supplying a quantity of exchanger process solution in a controlled manner to the sample fluidized bed such that the sample fluidized bed represents among other exchanger fluidized bed characteristics the exchanger fluidized bed height. The apparatus includes a monitor having a transparent sampling column in fluid communication with the exchanger fluidized bed and a regulator in fluid communication with the exchanger and the sample column for establishing a solution sample for supply to the sample fluidized bed. The regulator includes an orifice for controlling the flow rate of solution sample supplied to the sample fluidized bed.