Containing -x-n(=x) Or -x-n(=x)(=x) Bonded Directly To Carbon, Wherein The X's Are The Same Or Diverse Chalcogens (e.g., Thionitrite Esters, Etc.) Patents (Class 44/323)
  • Publication number: 20140182192
    Abstract: An additive composition for use in a diesel fuel formulation, comprising a cetane improver in an inclusion complex with a modified cyclodextrin of formula (I): wherein n is an integer from 6 to 20, and R1, R2 and R3 are each independently selected from hydrogen, optionally substituted alkyl, optionally substituted aryl and carbonyl, provided that R1, R2 and R3 are not all hydrogen. Also provided is a diesel fuel formulation comprising the additive composition, and the use of a modified cyclodextrin (I) as a vehicle for a cetane improver in an additive composition or diesel fuel formulation.
    Type: Application
    Filed: December 19, 2013
    Publication date: July 3, 2014
    Applicant: Shell Oil Company
    Inventors: Mark Lawrence BREWER, Roger Francis CRACKNELL, Tor Kit GOH
  • Patent number: 7615085
    Abstract: A reduction in the formation or presence of peroxides in middle distillate fuels is obtained through the combination of a hydrocarbon additive with the fuel. Specifically, the middle distillate fuel is blended with one or more oxygenates. The hydrocarbon additive includes a polar function group and a tertiary hydrogen beta to the functional group. Middle distillate fuels incorporating the additive, the additive itself, and methods using the additive all retard the formation of or reduce the presence of peroxides in the fuel. The reduction of peroxides improves the durability of fuels systems elastomers, enhances fuel stability and color durability, and reduces the formation of fuel sediment.
    Type: Grant
    Filed: November 4, 2003
    Date of Patent: November 10, 2009
    Assignee: Afton Chemical Corporation
    Inventors: Scott D. Schwab, Joshua J. Bennett, Allen A. Aradi
  • Publication number: 20080256846
    Abstract: A fuel composition for diesel engines comprising: (1) up to 80% volume of one or more intermediate fractions selected from the group consisting of a straight-run ‘kerosene fraction, a straight-run light oil fraction, a cracked light oil fraction, a cracked kerosene fraction and hydrodesulphurised products of these; and (2) at least 20% volume of gas-to-liquid product, wherein, in a test of oxidation stability in accordance with the EN14112 test, the time until a change of electrical conductivity occurs at a liquid temperature of 150° C. is at least four hours.
    Type: Application
    Filed: February 26, 2008
    Publication date: October 23, 2008
    Inventors: Tsutomu Yoshida, Nobuhiro Okabe, Hiroki Yoshida
  • Publication number: 20080209798
    Abstract: Fuels containing biodiesel, petroleum distillates, or blends of these may be treated by the addition of small amounts of one or more alkanolamines according to formula (I) Rn—N(CH2CHR1OH)3-n ; ??(I) wherein n is 1 or 2, R1 is H or CH3, and each R is independently selected from the group consisting of hydrogen and branched, linear, and cyclic C3-C24 alkyl groups, provided that at least one R is not hydrogen. Fuels treated in this manner may be less corrosive toward metals with which they are in contact.
    Type: Application
    Filed: June 26, 2006
    Publication date: September 4, 2008
    Inventors: Michael D. Gernon, Nicholas M. Martyak, Conor M. Dowling, Daniel Alford
  • Patent number: 7335238
    Abstract: The present invention relates to the manufacture of ferrous picrate and the preparation of fuel additives containing ferrous picrate. A process for producing ferrous picrate includes dissolving picric acid in a mixture of an aromatic hydrocarbon and an aliphatic alcohol in the presence of a trace amount of water and a metallic iron, thus forming a ferrous picrate solution. The ferrous picrate solution is blended with an organic solvent to form the fuel additive. Ferrous picrate produced by the product is also described.
    Type: Grant
    Filed: July 27, 2004
    Date of Patent: February 26, 2008
    Assignee: RDI Construction
    Inventor: Alan F. Elliott
  • Patent number: 7157593
    Abstract: A fuel additive containing ferrous picrate produced by a process involving placing a non-powdered metallic iron, such as wire composed of an alloy of iron or steel wool, in any solution of picric acid in a solvent that is known in the art for reacting with iron to produce ferrous picrate. The wire can be suspended in the solution or placed upon the bottom of a reaction vessel that holds the solution. Preferably the wire is loosely coiled, at least when placed upon the bottom of a reaction vessel.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: January 2, 2007
    Assignee: RDI Construction
    Inventors: Alan F. Elliott, David M. Stewart
  • Patent number: 6969773
    Abstract: A fuel additive containing ferrous picrate produced by a process involving placing wire composed of an alloy of iron in any solution of picric acid in a solvent that is known in the art for reacting with iron to produce ferrous picrate. The wire can be suspended in the solution or placed upon the bottom of a reaction vessel that holds the solution. Preferably the wire is loosely coiled, at least when placed upon the bottom of a reaction vessel. Also preferably, after a concentrated fuel additive has been prepared, to the concentrate is added so much of a pre-mix solution produced by the steps of (a) dissolving picric acid in the same kind of solvent that was utilized to produce the solution into which the steel wool was placed and (b) removing water from the precursor to the pre-mix solution thus produced and so much of the same kind of alcohol that was utilized to produce the solution into which the steel wool was placed that the final product produced thereby contains approximately 1.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: November 29, 2005
    Assignee: RDI Construction
    Inventor: David M. Stewart
  • Patent number: 6833466
    Abstract: A fuel additive containing ferrous picrate produced by a process comprising placing an enclosed iron containing metallic source in a solution of picric acid in a solvent that reacts with iron to produce ferrous picrate. Enclosure of the iron containing metallic source is accomplished with an isolating material. Enclosure may be achieved by completely surrounding the iron containing metallic source with the isolating material or by installing a filter comprising the isolating material on the downstream or the upstream side of a vessel holding the iron containing metallic source and through which the picric acid and liquid containing the picric acid are circulated. If the iron containing metallic source has been completely surrounded, it is placed into the solution. The solution may be agitated. If a filter or filters are utilized, the solution is circulated through the vessel holding the iron containing metallic source.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: December 21, 2004
    Assignee: RDI Construction
    Inventors: Alan Frederick Elliott, David M. Stewart, George Riegel
  • Patent number: 6670495
    Abstract: A process for producing ferrous picrate and a fuel additive containing ferrous picrate involving placing wire composed of an alloy of iron in any solution of picric acid in a solvent that is known in the art for reacting with iron to produce ferrous picrate. The wire can be suspended in the solution or placed upon the bottom of a reaction vessel that holds the solution. Preferably the wire is loosely coiled, at least when placed upon the bottom of a reaction vessel. Also preferably, after a concentrated fuel additive has been prepared, to the concentrate is added so much of a pre-mix solution produced by the steps of (a) dissolving picric acid in the same kind of solvent that was utilized to produce the solution into which the steel wool was placed and (b) removing water from the precursor to the pre-mix solution thus produced and so much of the same kind of alcohol that was utilized to produce the solution into which the steel wool was placed that the final product produced thereby contains approximately 1.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: December 30, 2003
    Inventor: David M. Stewart
  • Patent number: 5720783
    Abstract: A process for preparing ferrous picrate is disclosed. The process includes the step of reacting under substantially non-oxidising conditions ferrous carbonate substantially free from ferric compounds with a substantially water-free solution of picric acid in a solvent medium to produce a solution of ferric picrate. The solvent medium is selected from aromatic hydrocarbon solvents, mixtures of aromatic hydrocarbon solvents, straight- or branched-chain aliphatic alcohols, mixtures of straight or branched-chain aliphatic alcohols, and mixtures of straight- or branched-chain aliphatic alcohols and aromatic hydrocarbon solvents. The reaction is preferably carried out under a continuously maintained inert atmosphere and at a temperature between 10.degree. C. and 120.degree. C.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: February 24, 1998
    Inventor: Alan Frederick Elliott
  • Patent number: 5489316
    Abstract: Process for marking industrial organic solvents miscible with water and petroleum products gaseous at atmospheric pressure and room temperature and liquid when compressed at low pressure, by the addition to the above solvents of a primary nitroderivative having the general formulaR-CH.sub.2 -NO.sub.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: February 6, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventor: Enrico Traverso
  • Patent number: 5466268
    Abstract: Polyalkyl and polyalkenyl aromatic amides having the formula: ##STR1## or a fuel-soluble salt thereof; wherein A is hydroxy, nitro, amino, N-alkylamino wherein the alkyl group contains 1 to 6 carbon atoms, or N,N-dialkylamino wherein each alkyl group independently contains 1 to 6 carbon atoms; R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 is hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.4 is hydrogen or an acyl group of the formula: ##STR2## wherein A.sub.1 is hydroxy, nitro, amino, N-alkylamino wherein the alkyl group contains 1 to 6 carbon atoms, or N,N-dialkylamino wherein each alkyl group independently contains 1 to 6 carbon atoms; R.sub.6 and R.sub.7 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: November 14, 1995
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5454842
    Abstract: The present invention is directed to materials which improve the cetane number of diesel fusel when added in an amount in the range of 0.01 to 2 wt % to such fuel. The materials are the nitration product of alcohols obtained by the reduction of tall oil fatty acids, tall oil fatty acid esters, vegetable oils and mixtures thereof.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: October 3, 1995
    Assignee: Exxon Research & Engineering Co.
    Inventors: Marc-Andre Poirier, David E. Steere, James A. Krogh
  • Patent number: 5162048
    Abstract: The present invention relates to an additive to hydrocarbon fuels which includes nitrate of ethanolamine as an additive to reduce the quantity of smoke and improve the efficiency of combustion. The invention also relates to a process for the preparation of this additive and of the fuels improved by the addition of the additive.
    Type: Grant
    Filed: August 20, 1990
    Date of Patent: November 10, 1992
    Assignee: Kirsten, Inc.
    Inventor: Samuel Diaz-Valdes