Chalcogen In The Hetero Ring Patents (Class 44/334)
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Patent number: 12012564Abstract: The present disclosure provides fuel additives including Mannich-based quaternary ammonium salt additives, fuel compositions including such additives, and Methods of improving performance of fuel injector using such additives.Type: GrantFiled: August 25, 2021Date of Patent: June 18, 2024Assignee: Afton Chemical CorporationInventors: Scott D. Schwab, Geeta Vadehra, Michel Nuckols
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Patent number: 11447709Abstract: A method for improving the deposit control performance of a fuel comprises combining an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon with the fuel. The additive may also be used for controlling deposits in a system which comprises the fuel, such as in a spark-ignition internal combustion engine.Type: GrantFiled: August 13, 2018Date of Patent: September 20, 2022Assignee: BP OIL INTERNATIONAL LIMITEDInventor: Sorin Vasile Filip
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Patent number: 9039791Abstract: Use of a reaction product of saturated or unsaturated aliphatic mono- or polycarboxylic acids with aliphatic polyamines for improving or boosting the separation of water from fuel oils which comprise additives with detergent action. A Fuel additive concentrate comprising the said reaction product, certain additives with detergent action and optionally dehazers, cetane number improvers and solvents or diluents.Type: GrantFiled: May 21, 2013Date of Patent: May 26, 2015Assignee: BASF SEInventors: Maxim Peretolchin, Guenter Oetter, Harald Boehnke, Markus Hansch, Ludwig Voelkel
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Publication number: 20150101240Abstract: Base compounds including 1,3-oxazinan-6-one derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde, and their application as corrosion inhibitors with multifunctional properties serving as inhibitory/dispersant of asphaltene in production processes, transportation, refining and storage of crude oil and derivatives. The corrosion inhibitor with inhibitory/dispersant of asphaltenes properties comprises an active substance base of 1,3-oxaninan-6-ones and hydrocarbon solvents such as benzene, toluene, mixed xylenes, o-xylene, m-xylene and p-xylene, diesel, kerosene, jet fuel, alcohols, aliphatic branched and unbranched alcohols containing from 3 to 10 carbon atoms, such as isopropanol, butanol and pentanol, and mixtures of hydrocarbon solvents with aliphatic branched or unbranched liquid fuels. In addition, a process for obtaining 1,3-oxazinan-6-ones derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde is described.Type: ApplicationFiled: December 8, 2014Publication date: April 16, 2015Inventors: Raul Hernandez Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Hiram Isaac Beltran Conde, Eduardo Buenrostro Gonzalez
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Publication number: 20150034319Abstract: Triazine hydrogen sulfide (H2S) scavengers consume H2S and form dithiazines by-products which are corrosion inhibitors. Triazine H2S scavengers may be formulated with other corrosion inhibitors and used in H2S-containing fluids so that the dithiazine by-products may together with the at least one additional corrosion inhibitor form give synergistically better inhibiting of corrosion of iron and/or iron alloys in contact with the fluid to an extent greater than additive of the corrosion inhibition of the dithiazine and the corrosion inhibition of the at least one additional corrosion inhibitor, taken separately. The dithiazine may have the formula: where R is selected from the group consisting of a C1 to C10 saturated or unsaturated hydrocarbyl group or a C1 to C10 ?-hydroxy saturated or unsaturated hydrocarbyl group.Type: ApplicationFiled: July 2, 2014Publication date: February 5, 2015Applicant: BAKER HUGHES INCORPORATEDInventor: Grahame N. Taylor
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Publication number: 20140024568Abstract: A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: September 26, 2013Publication date: January 23, 2014Applicant: BASF SEInventors: Arno LANGE, Dietmar Posselt
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Publication number: 20130312318Abstract: Use of a reaction product of saturated or unsaturated aliphatic mono- or polycarboxylic acids with aliphatic polyamines for improving or boosting the separation of water from fuel oils which comprise additives with detergent action. A Fuel additive concentrate comprising the said reaction product, certain additives with detergent action and optionally dehazers, cetane number improvers and solvents or diluents.Type: ApplicationFiled: May 21, 2013Publication date: November 28, 2013Applicant: BASF SEInventors: Maxim PERETOLCHIN, Guenter OETTER, Harald BOEHNKE, Markus HANSCH, Ludwig VOELKEL
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Publication number: 20130276362Abstract: The present invention relates to the use of additives with detergent action selected from: (i) compounds with moieties derived from succinic anhydride and having hydroxyl and/or amino and/or amido and/or imido groups; (ii) nitrogen compounds quaternized in an acid-free manner, obtainable by addition of a compound comprising an oxygen- or nitrogen-containing group reactive with an anhydride and additionally a quaternizable amino group onto a polycarboxylic anhydride compound and subsequent quaternization; (iii) polytetrahydrobenzoxazines and bistetrahydrobenzoxazines for further increasing the cetane number of fuel oils which comprise cetane number improvers; furthermore, it relates to a fuel additive concentrate consisting of additives (i) to (iii), cetane number improvers, organic diluents or solvents and possibly customary co-additives.Type: ApplicationFiled: April 19, 2013Publication date: October 24, 2013Applicant: BASF SEInventor: Harald BOEHNKE
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Publication number: 20130130956Abstract: A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: January 14, 2013Publication date: May 23, 2013Inventors: Arno LANGE, Dietmar Posselt
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Publication number: 20120311922Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions and, when the composition is biodiesel, also improve microbial resistance. The additives further enhance the antimicrobial efficacy of any added biocides contained in such compositions.Type: ApplicationFiled: August 8, 2012Publication date: December 13, 2012Inventors: Sheila M. Tinetti, John L. Pohlman, Patrick E. Brutto, Charles E. Coburn, George D. Green, Raymond J. Swedo
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Publication number: 20120255222Abstract: This invention relates to a fuel composition, comprising: (A) a normally liquid fuel; and (B) a cold flow improving amount of (i) a metathesized natural oil; (ii) a metathesized natural oil derivative; or (iii) a mixture of (i) and (ii). The invention also relates to metathesized derivatives formed by the reaction of a metathesized natural oil with a nucleophile, oxidizer, aromatic compound, enophilic acid reagent, or a mixture of two or more thereof.Type: ApplicationFiled: April 7, 2011Publication date: October 11, 2012Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, S. Alexander Christensen
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Publication number: 20120144731Abstract: The use of mixtures of (A) aliphatic saturated or unsaturated monocarboxylic acids having 12 to 24 carbon atoms or the dimerization or trimerization products thereof, which may be present in the form of free carboxylic acids and/or in the form of ammonium salts, amides, esters and/or nitriles, and (B) polycyclic hydrocarbon compounds which are obtainable from distillation residues of natural oils, which have been extracted from tree resins, for increasing the cetane number of fuel oils which comprise at least one additive with detergent action and at least one cetane number improver, the mixtures of components (A) and (B) being used in a concentration of 10 to 500 ppm by weight, based on the total amount of the fuel oil.Type: ApplicationFiled: December 9, 2011Publication date: June 14, 2012Applicant: BASF SEInventor: Harald Böhnke
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Publication number: 20120110899Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.Type: ApplicationFiled: June 21, 2010Publication date: May 10, 2012Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGInventors: Wolfgang Beilfuss, Ralf Grastke, Jennifer Knopf, Ingo Krull
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Publication number: 20120000118Abstract: A fuel additive composition comprising (A) polyisobutyl-based nitrogen-containing dispersants with MN of the polyisobutyl group of from 650 to 1800 Dalton, (B) carrier oils substantially free of nitrogen and (C) polyisobutyl-based dispersant boosters with MN of the polyisobutyl group of from 200 to 650 Dalton, with the proviso that the difference between the MN of the polyisobutyl group of component (A) and the MN of the polyisobutyl group of component (C) is more than 100 Dalton. Said component (C) is especially useful as an intake valve clean-up booster in gasoline-operated port fuel injection internal combustion engines.Type: ApplicationFiled: June 1, 2011Publication date: January 5, 2012Applicant: BASF SEInventors: Arno LANGE, Peter Schreyer, Robert Stuart Grace
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Publication number: 20110269650Abstract: Base compounds including 1,3-oxazinan-6-one derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde, and their application as corrosion inhibitors with multifunctional properties serving as inhibitory/dispersant of asphaltene in production processes, transportation, refining and storage of crude oil and derivatives. The corrosion inhibitor with inhibitory/dispersant of asphaltenes properties comprises an active substance base of 1,3-oxaninan-6-ones and hydrocarbon solvents such as benzene, toluene, mixed xylenes, o-xylene, m-xylene and p -xylene, diesel, kerosene, jet fuel, alcohols, aliphatic branched and unbranched alcohols containing from 3 to 10 carbon atoms, such as isopropanol, butanol and pentanol, and mixtures of hydrocarbon solvents with aliphatic branched or unbranched liquid fuels. In addition, a process for obtaining 1,3-oxazinan-6-ones derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde is described.Type: ApplicationFiled: April 29, 2011Publication date: November 3, 2011Applicant: INSTITUTO MEXICANO DEL PETROLEOInventors: Raúl Hernández Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Hiram Isaac Beltrán Conde, Eduardo Buenrostro González
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Publication number: 20110113678Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.Type: ApplicationFiled: January 28, 2011Publication date: May 19, 2011Applicant: BASF SEInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Publication number: 20110041387Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: (I) wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions. The additives also enhance the antimicrobial efficacy of any added biocides contained in such compositions.Type: ApplicationFiled: April 29, 2009Publication date: February 24, 2011Inventors: G. David Green, Sheila M. Tinetti, Patrick E. Brutto, John Pohlman
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Publication number: 20100251602Abstract: Provided is a synergistic biocidal composition comprising a biocidal N-(2-nitroalkyl) morpholine compound of formula I: where R, x, and y are as defined herein, together with an aromatic alcohol. The composition is cold temperature stable and is therefore useful for the control of microorganisms in a variety of matrices, including liquid fuels.Type: ApplicationFiled: March 25, 2010Publication date: October 7, 2010Inventor: John Pohlman
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Publication number: 20100242341Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: (I) wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions and, when the composition is biodiesel, also improve microbial resistance. The additives further enhance the antimicrobial efficacy of any added biocides contained in such compositions.Type: ApplicationFiled: December 4, 2008Publication date: September 30, 2010Inventors: Sheila M. Tinetti, John L. Pohlman, Patrick E. Brutto, Charles E. Coburn, George D. Green, Raymond J. Swedo
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Publication number: 20100107476Abstract: A fuel, fuel additive concentrate, and method for removing and/or preventing the occurrence of deposits in a fuel injector of an injection engine are provided. The additive concentrate contains at least one hexahydro triazine.Type: ApplicationFiled: October 31, 2008Publication date: May 6, 2010Applicant: AFTON CHEMICAL CORPORATIONInventor: Lelia Cosimbescu
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Publication number: 20080196300Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.Type: ApplicationFiled: July 18, 2006Publication date: August 21, 2008Applicant: BASF AktiengesellschaftInventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
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Patent number: 7175678Abstract: The present invention provides a polymeric a fuel composition comprising (i) a fuel; and (ii) a polymeric compound; wherein the polymeric compound comprises at least one monomer unit of Formula I wherein R1 is H or a C1-10 hydrocarbyl group; wherein L is an optional C1-30 hydrocarbyl linker group; and wherein heterocycle is an optionally substituted heterocyclic ring.Type: GrantFiled: September 26, 2003Date of Patent: February 13, 2007Assignee: Innospec LimitedInventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon, Derek Richard Green
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Patent number: 7112230Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): wherein R1 and R2 are independently C1-4 alkyl, R3 is a radical of the formula CmH2m wherein m is an integer of 2 to 6, R4 and R5 are each independently (i) hydrogen (ii) C1-4 alkyl, wherein R6 is selected from the group consisting of hydrogen and C1-4 alkyls and R7 is selected from the group consisting of hydrogen and C1-30 alkyl, (iv) wherein R8 is a saturated or unsaturated, linear, branched or cyclic, C7-23 hydrocarbyl group or (v) wherein R4 and R5 together with the nitrogen atom to which they are bonded, form a cyclic ring in which further hetero atoms.Type: GrantFiled: September 14, 2001Date of Patent: September 26, 2006Assignee: Afton Chemical Intangibles LLCInventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
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Patent number: 6676715Abstract: There is provided use of a thermal stabiliser for increasing the thermal stability of a cetane improver in a fuel composition comprising (i) a fuel, and (ii) the cetane improver wherein the thermal stabiliser is a compound of the formula H—R1 wherein H is a group comprising a heterocyclic group and R1 is a hydrocarbyl group having from 10 to 200 carbons.Type: GrantFiled: May 11, 2001Date of Patent: January 13, 2004Assignees: The Associated Octel Company Limited, Octel Starreon, LLCInventors: Cyrus Pershing Henry, Barbara Elizabeth Goodrich
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Patent number: 6296677Abstract: The lubricity (anti-wear properties) of fuels, for example hydrocarbon fuels, oxygenated fuels or mixtures thereof, particularly diesel or aviation fuels having reduced sulphur and/or aromatic content for compliance with regulator requirements, is improved by addition of at least a product which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for exType: GrantFiled: February 2, 1998Date of Patent: October 2, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Marc Ribeaud, Paul Dubs, Michael Rasberger, Samuel Evans
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Patent number: 5919275Abstract: Fuel or lubricant additives based on reaction products of an ethylenically unsaturated poly-1-alkene derived from one or more 1-alkenes of 3 to 24 carbon atoms and from 0 to 50% by weight of ethene, processes for their preparation and fuel or lubricant compositions containing these additives are described.Type: GrantFiled: October 15, 1996Date of Patent: July 6, 1999Assignee: BASF AktiengesellschaftInventors: Knut Oppenlander, Jurgen Mohr, Hans-Joachim Muller, Dietmar Posselt, Wolfgang Gunther
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Patent number: 5837016Abstract: A fuel additive which comprises an amide compound of the formula ##STR1## wherein R.sup.1 is hydrogen or a C.sub.1 -C.sub.30 hydrocarbon group, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each are selected from the group consisting of hydrogen, a C.sub.1 -C.sub.10 hydrocarbon group and a group of formula (II), provided that at least one of R.sup.2, R.sup.3, R.sup.4 and R.sup.5 group of formula (II) R.sup.6 is a C.sub.2 -C.sub.6 alkylene group, R.sup.7 is a C.sub.1 -C.sub.6 alkylene group, a is an integer of 1-100, b is an integer of 0-100, the sum of a and b being equal to 1-200, c is an integer of 1-3, d is an integer of 0-2, the sum of c and d being equal to 3, and X is selected from the group consisting of hydrogen, a C.sub.1 -C.sub.30 hydrocarbon group, a group of formula (III), and a group of formula (IV), wherein formulas (II), (III) and (IV) are defined in the disclosure.Type: GrantFiled: April 10, 1997Date of Patent: November 17, 1998Assignee: Nippon Oil Co., Ltd.Inventors: Noboru Ishida, Takashi Nakano, Masaki Nagao, Takashi Kaneko
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Patent number: 5755833Abstract: A fuel additive comprising a urethane compound. A gasoline composition comprising gasoline blended with a urethane compound to suppress sludge or deposits in fuel intake systems or combustion chambers, such as an automobile engine.Type: GrantFiled: January 22, 1996Date of Patent: May 26, 1998Assignee: Nippon Oil Co., Ltd.Inventors: Noboru Ishida, Masaki Nagao, Takashi Kaneko
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Patent number: 5484462Abstract: A fuel composition comprising a mixture of hydrocarbons boiling in the range from about 320.degree. F. to 620.degree. F. and a sulfur content of about 0.05 wt. %, or below, containing from about 1 to about 20 PTB of aminoalkylmorpholine having the formula: ##STR1## where R is hydrogen of a C.sub.1 -C.sub.10 alkyl radical, and n is a number between 2 and about 10.Type: GrantFiled: September 21, 1994Date of Patent: January 16, 1996Assignee: Texaco Inc.Inventor: Sheldon Herbstman
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Patent number: 5383942Abstract: An amido alkanolamine composition obtained by reacting, at a temperature of 10.degree. C.-200.degree. C.:(a) a 4-alkyl-2-morpholinone represented by the formula: ##STR1## in which R represents a monovalent aliphatic radical having from 1 to 10 carbon atoms; and(b) a hydrocarbyl oxypolyoxyalkylene amine represented by the formula ##STR2## in which R' represents an alkyl, an alicyclic or an alkyl-alicyclic radical having from 12 to 30 carbon atoms or ##STR3## wherein R" represents a hydrocarbyl radical having from 4 to 30 carbon atoms, x has a value of from about 5 to 50, and R'" is an ethyl radical or a mixture of methyl and ethyl radicals.Type: GrantFiled: June 22, 1993Date of Patent: January 24, 1995Assignee: Texaco Inc.Inventors: Wei-Yang Su, Sheldon Herbstman, Joseph M. Russo, Robert L. Zimmerman, Michael Cuscurida
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Patent number: 5312459Abstract: An additive for liquefied hydrocarbon fuel containsa) 30-60 volume percent of at least one nitrogen-containing solvent,b) 30-60 volume percent of at least one nitrogen-containing dispersing agent,c) 0.5-10 volume percent of a nitrogen-containing corrosion inhibiting agent andd) 0.5-10 volume percent of at least one oxidation inhibitor, wherein the sum of ingredients a, b, c and d is 100 volume percent. This additive protects against corrosion, aging, separation of materials on motor parts and purification of the exhaust gas in motors using liquefied hydrocarbon fuels.Type: GrantFiled: August 17, 1992Date of Patent: May 17, 1994Inventors: Friedrich A. Sprugel, Werner Angerer
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Patent number: 5312460Abstract: Disclosed is a fuel composition comprising a hydrocarbon boiling in the gasoline or diesel range and from about 30 to about 5,000 parts per million of an alkylphenyl poly(oxypropylene) aminocarbamate having at least one basic nitrogen and an average molecular weight of about 600 to 6,000 and wherein the alkyl group is substantially straight-chain of at least 15 carbon atoms. The instant invention is based on the discovery that use of the unique hydrocarbyl group, i.e., an alkylphenyl group wherein the alkyl group is derived from a substantially straight-chain alkyl group of at least 15 carbon atoms imparts to the alkylphenyl poly(oxypropylene) aminocarbamate not only lubricating oil compatibility but also an unexpected decrease in crankcase deposits.Type: GrantFiled: November 17, 1992Date of Patent: May 17, 1994Assignee: Chevron Research CompanyInventor: Thomas F. Buckley, III
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Patent number: 5294233Abstract: An additive for improving the dispersibility of a particulate substance in an organic medium, a thermoplastic polymer, or a thermosetting resin, is at least one compound having a ##STR1## bond in the molecule, including, for example, compounds having an oxazolinium ion in the molecule. The preferred additive compounds are oligomeric or polymeric.Type: GrantFiled: July 31, 1991Date of Patent: March 15, 1994Assignee: Nippon Zeon Co., Ltd.Inventors: Shizuo Kitahara, Hiroyuki Watanabe, Takuji Kishimoto, Tetuya Toyoshima, Takafumi Kawanaka, Kohkichi Noguchi
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Patent number: 5286266Abstract: The present invention provides a novel class of compounds, useful as gasoline detergent additives, comprising asymmetrical ureas of either a hydrocarbyloxypolyether amine alone, or a hydrocarbyloxypolyether amine and a tertiary aminoalkyl primary amine. The present invention also provides a motor fuel composition containing the novel asymmetrical ureas and further provides a method of synthesizing the asymmetrical ureas of the present invention.Type: GrantFiled: July 9, 1992Date of Patent: February 15, 1994Assignee: Texaco Inc.Inventor: Sheldon Herbstman
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Patent number: 5266080Abstract: The flame luminosity of a methanol fuel is appreciably enhanced by the addition thereto of at least one flame luminosity enhancing agent selected from the group consisting of azine dye, triarylmethane dye, fluorescein dye, imine dye and anthraquinone dye, said dye excluding any metal component whose combustion product(s) tend to cause excessive wear in an engine operated with the fuel composition or tend to significantly interfere with normal operation of such engine or any of its associated systems, the flame luminosity of the fuel composition during burning being appreciably enhanced relative to the flame luminosity of the same burning fuel composition but to which no flame luminosity enhancing agent has been added.Type: GrantFiled: October 11, 1989Date of Patent: November 30, 1993Assignee: The Standard Oil CompanyInventors: Thomas E. Kiovsky, Wendy L. Clark
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Patent number: 5203879Abstract: An amido alkanolamine composition obtained by reacting, at a temperature of 10.degree. C.-200.degree. C.:(a) a 4-alkyl-2-morpholinone represented by the formula: ##STR1## in which R represents a monovalent aliphatic radical having from 1 to 10 carbon atoms, and(b) a hydrocarbyl oxypolyoxyalkylene amine represented by the formula: ##STR2## in which R' represents an alkyl, an alicyclic, or a alkylalicyclic radical having from 8 to 30 carbon atoms, x has a value from 5 to 50, and R" represents a methyl radical or a mixture of hydrogen and methyl radicals is provided.Type: GrantFiled: September 1, 1992Date of Patent: April 20, 1993Assignee: Texaco Inc.Inventors: Wei-Yang Su, Sheldon Herbstman, Joseph M. Russo, Robert L. Zimmerman, Michael Cuscurida
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Patent number: 5157118Abstract: This invention describes phenothiazine derivatives which are N-substituted and which contain an additional sulfur molecule in the N substituent.Type: GrantFiled: November 8, 1990Date of Patent: October 20, 1992Assignee: The Lubrizol CorporationInventor: Mary F. Salomon
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Patent number: 5057123Abstract: A method of stabilizing a diesel fuel formulation by substantially minimizing the oxidation thereof is disclosed. In particular, at least one amine containing copolymer is incorporated into the diesel fuel formulation in an amount sufficient to improve the storage stability and, also, substantially minimize the oxidation thereof. The method of this invention is particularly well suited for substantially minimizing the high temperature oxidation of diesel fuels.Type: GrantFiled: May 25, 1990Date of Patent: October 15, 1991Assignee: Texaco Inc.Inventors: Sheldon Herbstman, Theodore E. Nalesnik
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Patent number: 5047069Abstract: An antioxidant for liquid hydrocarbons such as fuels has the structure ##STR1## wherein X is N or S; R is H or a C.sub.1 to C.sub.5 alkyl moiety; R.sup.1 and R.sup.2 are each independently C.sub.5 to C.sub.18 alkyl or cycloalkyl moieties (which may optionally contain a hetero atom such as oxygen), only one of R.sup.1 and R.sup.2 being present if X is S, or may be combined to form a 5 or preferably 6 membered ring; each R.sup.6 is independently the residue of a C.sub.1 to C.sub.5 aldehyde; and R.sup.7 is the residue of a polyamine of the formula ##STR2## wherein R.sup.3 is a C.sub.8 to C.sub.50 alkyl moiety (which may optionally contain one or more ether linkages); R.sup.4 and R.sup.5 are each independently C.sub.2 to C.sub.6 alkylene moieties; a is 0 or 1; and m is at least 3.Type: GrantFiled: October 22, 1990Date of Patent: September 10, 1991Assignee: Petrolite CorporationInventors: Jerry J. Weers, Thomas V. Bagwell
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Patent number: 5035719Abstract: Middle distillate fuels may be treated to improve storage stability by addition of, as additive, an acrylate polymer containing moieties derived from an N-heterocyclic amine such as 4-vinyl pyridine or the enamine ester of morpholine and propionaldehyde.Type: GrantFiled: December 27, 1988Date of Patent: July 30, 1991Assignee: Texaco Inc.Inventors: Rodney L. Sung, Benjamin J. Kaufman
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Patent number: 5034019Abstract: This invention describes phenothiazine derivatives which are N-substituted and which contain an additional sulfur molecule in the N substituent.Type: GrantFiled: August 16, 1990Date of Patent: July 23, 1991Assignee: The Lubrizol CorporationInventor: Mary F. Salomon
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Patent number: 4978366Abstract: A distillate fuel, particularly one which has a high acid number initially or which develops a high acid number as a result of fuel degradation, stabilized with a diaminomethane of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be independently a saturated or unsaturated hydrocarbon group, e.g., alkyl, aryl, aralkyl, alkaryl, cycloalkyl, alkenyl, aralkenyl, alkenylaryl, cycloalkenyl and the like or heterocyclyl groups and in which R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 may be joined together to form a five or six member heterocyclyl ring and R.sub.5 may be hydrogen or lower alkyl is disclosed. A method of stabilizing a fuel oil wherein a stabilizing amount of the above-mentioned diaminomethane is incorporated into the fuel oil is also disclosed.Type: GrantFiled: January 14, 1988Date of Patent: December 18, 1990Assignee: Petrolite CorporationInventor: Jerry J. Weers