Chalcogen In The Hetero Ring Patents (Class 44/334)
  • Patent number: 11447709
    Abstract: A method for improving the deposit control performance of a fuel comprises combining an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon with the fuel. The additive may also be used for controlling deposits in a system which comprises the fuel, such as in a spark-ignition internal combustion engine.
    Type: Grant
    Filed: August 13, 2018
    Date of Patent: September 20, 2022
    Assignee: BP OIL INTERNATIONAL LIMITED
    Inventor: Sorin Vasile Filip
  • Patent number: 9039791
    Abstract: Use of a reaction product of saturated or unsaturated aliphatic mono- or polycarboxylic acids with aliphatic polyamines for improving or boosting the separation of water from fuel oils which comprise additives with detergent action. A Fuel additive concentrate comprising the said reaction product, certain additives with detergent action and optionally dehazers, cetane number improvers and solvents or diluents.
    Type: Grant
    Filed: May 21, 2013
    Date of Patent: May 26, 2015
    Assignee: BASF SE
    Inventors: Maxim Peretolchin, Guenter Oetter, Harald Boehnke, Markus Hansch, Ludwig Voelkel
  • Publication number: 20150101240
    Abstract: Base compounds including 1,3-oxazinan-6-one derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde, and their application as corrosion inhibitors with multifunctional properties serving as inhibitory/dispersant of asphaltene in production processes, transportation, refining and storage of crude oil and derivatives. The corrosion inhibitor with inhibitory/dispersant of asphaltenes properties comprises an active substance base of 1,3-oxaninan-6-ones and hydrocarbon solvents such as benzene, toluene, mixed xylenes, o-xylene, m-xylene and p-xylene, diesel, kerosene, jet fuel, alcohols, aliphatic branched and unbranched alcohols containing from 3 to 10 carbon atoms, such as isopropanol, butanol and pentanol, and mixtures of hydrocarbon solvents with aliphatic branched or unbranched liquid fuels. In addition, a process for obtaining 1,3-oxazinan-6-ones derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde is described.
    Type: Application
    Filed: December 8, 2014
    Publication date: April 16, 2015
    Inventors: Raul Hernandez Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Hiram Isaac Beltran Conde, Eduardo Buenrostro Gonzalez
  • Publication number: 20150034319
    Abstract: Triazine hydrogen sulfide (H2S) scavengers consume H2S and form dithiazines by-products which are corrosion inhibitors. Triazine H2S scavengers may be formulated with other corrosion inhibitors and used in H2S-containing fluids so that the dithiazine by-products may together with the at least one additional corrosion inhibitor form give synergistically better inhibiting of corrosion of iron and/or iron alloys in contact with the fluid to an extent greater than additive of the corrosion inhibition of the dithiazine and the corrosion inhibition of the at least one additional corrosion inhibitor, taken separately. The dithiazine may have the formula: where R is selected from the group consisting of a C1 to C10 saturated or unsaturated hydrocarbyl group or a C1 to C10 ?-hydroxy saturated or unsaturated hydrocarbyl group.
    Type: Application
    Filed: July 2, 2014
    Publication date: February 5, 2015
    Applicant: BAKER HUGHES INCORPORATED
    Inventor: Grahame N. Taylor
  • Publication number: 20140024568
    Abstract: A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.
    Type: Application
    Filed: September 26, 2013
    Publication date: January 23, 2014
    Applicant: BASF SE
    Inventors: Arno LANGE, Dietmar Posselt
  • Publication number: 20130312318
    Abstract: Use of a reaction product of saturated or unsaturated aliphatic mono- or polycarboxylic acids with aliphatic polyamines for improving or boosting the separation of water from fuel oils which comprise additives with detergent action. A Fuel additive concentrate comprising the said reaction product, certain additives with detergent action and optionally dehazers, cetane number improvers and solvents or diluents.
    Type: Application
    Filed: May 21, 2013
    Publication date: November 28, 2013
    Applicant: BASF SE
    Inventors: Maxim PERETOLCHIN, Guenter OETTER, Harald BOEHNKE, Markus HANSCH, Ludwig VOELKEL
  • Publication number: 20130276362
    Abstract: The present invention relates to the use of additives with detergent action selected from: (i) compounds with moieties derived from succinic anhydride and having hydroxyl and/or amino and/or amido and/or imido groups; (ii) nitrogen compounds quaternized in an acid-free manner, obtainable by addition of a compound comprising an oxygen- or nitrogen-containing group reactive with an anhydride and additionally a quaternizable amino group onto a polycarboxylic anhydride compound and subsequent quaternization; (iii) polytetrahydrobenzoxazines and bistetrahydrobenzoxazines for further increasing the cetane number of fuel oils which comprise cetane number improvers; furthermore, it relates to a fuel additive concentrate consisting of additives (i) to (iii), cetane number improvers, organic diluents or solvents and possibly customary co-additives.
    Type: Application
    Filed: April 19, 2013
    Publication date: October 24, 2013
    Applicant: BASF SE
    Inventor: Harald BOEHNKE
  • Publication number: 20130130956
    Abstract: A synergistic mixture comprising from 1 to 99.9% by weight of compounds having structural elements (I) in which the free valencies on the oxygen atom and on the nitrogen atom may be combined to form a five-, six- or seven-membered ring and the benzene ring may also bear substituents at one or more of the free positions, and from 0.1 to 99% by weight of sulfur-containing organic compounds with antioxidant action. This synergistic mixture is suitable as a stabilizer for stabilizing inanimate organic material, especially mineral oil products and fuels, against the action of light, oxygen and heat.
    Type: Application
    Filed: January 14, 2013
    Publication date: May 23, 2013
    Inventors: Arno LANGE, Dietmar Posselt
  • Publication number: 20120311922
    Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions and, when the composition is biodiesel, also improve microbial resistance. The additives further enhance the antimicrobial efficacy of any added biocides contained in such compositions.
    Type: Application
    Filed: August 8, 2012
    Publication date: December 13, 2012
    Inventors: Sheila M. Tinetti, John L. Pohlman, Patrick E. Brutto, Charles E. Coburn, George D. Green, Raymond J. Swedo
  • Publication number: 20120255222
    Abstract: This invention relates to a fuel composition, comprising: (A) a normally liquid fuel; and (B) a cold flow improving amount of (i) a metathesized natural oil; (ii) a metathesized natural oil derivative; or (iii) a mixture of (i) and (ii). The invention also relates to metathesized derivatives formed by the reaction of a metathesized natural oil with a nucleophile, oxidizer, aromatic compound, enophilic acid reagent, or a mixture of two or more thereof.
    Type: Application
    Filed: April 7, 2011
    Publication date: October 11, 2012
    Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, S. Alexander Christensen
  • Publication number: 20120144731
    Abstract: The use of mixtures of (A) aliphatic saturated or unsaturated monocarboxylic acids having 12 to 24 carbon atoms or the dimerization or trimerization products thereof, which may be present in the form of free carboxylic acids and/or in the form of ammonium salts, amides, esters and/or nitriles, and (B) polycyclic hydrocarbon compounds which are obtainable from distillation residues of natural oils, which have been extracted from tree resins, for increasing the cetane number of fuel oils which comprise at least one additive with detergent action and at least one cetane number improver, the mixtures of components (A) and (B) being used in a concentration of 10 to 500 ppm by weight, based on the total amount of the fuel oil.
    Type: Application
    Filed: December 9, 2011
    Publication date: June 14, 2012
    Applicant: BASF SE
    Inventor: Harald Böhnke
  • Publication number: 20120110899
    Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.
    Type: Application
    Filed: June 21, 2010
    Publication date: May 10, 2012
    Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORG
    Inventors: Wolfgang Beilfuss, Ralf Grastke, Jennifer Knopf, Ingo Krull
  • Publication number: 20120000118
    Abstract: A fuel additive composition comprising (A) polyisobutyl-based nitrogen-containing dispersants with MN of the polyisobutyl group of from 650 to 1800 Dalton, (B) carrier oils substantially free of nitrogen and (C) polyisobutyl-based dispersant boosters with MN of the polyisobutyl group of from 200 to 650 Dalton, with the proviso that the difference between the MN of the polyisobutyl group of component (A) and the MN of the polyisobutyl group of component (C) is more than 100 Dalton. Said component (C) is especially useful as an intake valve clean-up booster in gasoline-operated port fuel injection internal combustion engines.
    Type: Application
    Filed: June 1, 2011
    Publication date: January 5, 2012
    Applicant: BASF SE
    Inventors: Arno LANGE, Peter Schreyer, Robert Stuart Grace
  • Publication number: 20110269650
    Abstract: Base compounds including 1,3-oxazinan-6-one derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde, and their application as corrosion inhibitors with multifunctional properties serving as inhibitory/dispersant of asphaltene in production processes, transportation, refining and storage of crude oil and derivatives. The corrosion inhibitor with inhibitory/dispersant of asphaltenes properties comprises an active substance base of 1,3-oxaninan-6-ones and hydrocarbon solvents such as benzene, toluene, mixed xylenes, o-xylene, m-xylene and p -xylene, diesel, kerosene, jet fuel, alcohols, aliphatic branched and unbranched alcohols containing from 3 to 10 carbon atoms, such as isopropanol, butanol and pentanol, and mixtures of hydrocarbon solvents with aliphatic branched or unbranched liquid fuels. In addition, a process for obtaining 1,3-oxazinan-6-ones derivatives of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl propionic acids and paraformaldehyde is described.
    Type: Application
    Filed: April 29, 2011
    Publication date: November 3, 2011
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Raúl Hernández Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Hiram Isaac Beltrán Conde, Eduardo Buenrostro González
  • Publication number: 20110113678
    Abstract: The use of polycyclic phenolic compounds which have up to 20 benzene rings per molecule and are obtainable by reacting a tetrahydrobenzoxazine I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals with one or more of the same or different phenols II where R7, R8, R9 and R10 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has from 13 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, have in each case from 1 to 20 carbon atoms as stabilizers for stabilizing inanimate organic material against the action of light, oxygen and heat.
    Type: Application
    Filed: January 28, 2011
    Publication date: May 19, 2011
    Applicant: BASF SE
    Inventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
  • Publication number: 20110041387
    Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: (I) wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions. The additives also enhance the antimicrobial efficacy of any added biocides contained in such compositions.
    Type: Application
    Filed: April 29, 2009
    Publication date: February 24, 2011
    Inventors: G. David Green, Sheila M. Tinetti, Patrick E. Brutto, John Pohlman
  • Publication number: 20100251602
    Abstract: Provided is a synergistic biocidal composition comprising a biocidal N-(2-nitroalkyl) morpholine compound of formula I: where R, x, and y are as defined herein, together with an aromatic alcohol. The composition is cold temperature stable and is therefore useful for the control of microorganisms in a variety of matrices, including liquid fuels.
    Type: Application
    Filed: March 25, 2010
    Publication date: October 7, 2010
    Inventor: John Pohlman
  • Publication number: 20100242341
    Abstract: Provided are additives of formula I for use in hydrocarbonaceous compositions, such as petroleum or liquid fuels: (I) wherein R1, R2, R3, R4, and R5 are as defined herein. The additives improve the corrosion resistance of the compositions and, when the composition is biodiesel, also improve microbial resistance. The additives further enhance the antimicrobial efficacy of any added biocides contained in such compositions.
    Type: Application
    Filed: December 4, 2008
    Publication date: September 30, 2010
    Inventors: Sheila M. Tinetti, John L. Pohlman, Patrick E. Brutto, Charles E. Coburn, George D. Green, Raymond J. Swedo
  • Publication number: 20100107476
    Abstract: A fuel, fuel additive concentrate, and method for removing and/or preventing the occurrence of deposits in a fuel injector of an injection engine are provided. The additive concentrate contains at least one hexahydro triazine.
    Type: Application
    Filed: October 31, 2008
    Publication date: May 6, 2010
    Applicant: AFTON CHEMICAL CORPORATION
    Inventor: Lelia Cosimbescu
  • Publication number: 20080196300
    Abstract: The use of tetrahydrobenzoxazines I where R1 is a hydrocarbyl radical and R2, R3, R4 and R5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R2 to R5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.
    Type: Application
    Filed: July 18, 2006
    Publication date: August 21, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Arno Lange, Helmut Mach, Hans Peter Rath, Dietmar Posselt
  • Patent number: 7175678
    Abstract: The present invention provides a polymeric a fuel composition comprising (i) a fuel; and (ii) a polymeric compound; wherein the polymeric compound comprises at least one monomer unit of Formula I wherein R1 is H or a C1-10 hydrocarbyl group; wherein L is an optional C1-30 hydrocarbyl linker group; and wherein heterocycle is an optionally substituted heterocyclic ring.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: February 13, 2007
    Assignee: Innospec Limited
    Inventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon, Derek Richard Green
  • Patent number: 7112230
    Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): wherein R1 and R2 are independently C1-4 alkyl, R3 is a radical of the formula CmH2m wherein m is an integer of 2 to 6, R4 and R5 are each independently (i) hydrogen (ii) C1-4 alkyl, wherein R6 is selected from the group consisting of hydrogen and C1-4 alkyls and R7 is selected from the group consisting of hydrogen and C1-30 alkyl, (iv) wherein R8 is a saturated or unsaturated, linear, branched or cyclic, C7-23 hydrocarbyl group or (v) wherein R4 and R5 together with the nitrogen atom to which they are bonded, form a cyclic ring in which further hetero atoms.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: September 26, 2006
    Assignee: Afton Chemical Intangibles LLC
    Inventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
  • Patent number: 6676715
    Abstract: There is provided use of a thermal stabiliser for increasing the thermal stability of a cetane improver in a fuel composition comprising (i) a fuel, and (ii) the cetane improver wherein the thermal stabiliser is a compound of the formula H—R1 wherein H is a group comprising a heterocyclic group and R1 is a hydrocarbyl group having from 10 to 200 carbons.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: January 13, 2004
    Assignees: The Associated Octel Company Limited, Octel Starreon, LLC
    Inventors: Cyrus Pershing Henry, Barbara Elizabeth Goodrich
  • Patent number: 6296677
    Abstract: The lubricity (anti-wear properties) of fuels, for example hydrocarbon fuels, oxygenated fuels or mixtures thereof, particularly diesel or aviation fuels having reduced sulphur and/or aromatic content for compliance with regulator requirements, is improved by addition of at least a product which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for ex
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: October 2, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Marc Ribeaud, Paul Dubs, Michael Rasberger, Samuel Evans
  • Patent number: 5919275
    Abstract: Fuel or lubricant additives based on reaction products of an ethylenically unsaturated poly-1-alkene derived from one or more 1-alkenes of 3 to 24 carbon atoms and from 0 to 50% by weight of ethene, processes for their preparation and fuel or lubricant compositions containing these additives are described.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: July 6, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Knut Oppenlander, Jurgen Mohr, Hans-Joachim Muller, Dietmar Posselt, Wolfgang Gunther
  • Patent number: 5837016
    Abstract: A fuel additive which comprises an amide compound of the formula ##STR1## wherein R.sup.1 is hydrogen or a C.sub.1 -C.sub.30 hydrocarbon group, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each are selected from the group consisting of hydrogen, a C.sub.1 -C.sub.10 hydrocarbon group and a group of formula (II), provided that at least one of R.sup.2, R.sup.3, R.sup.4 and R.sup.5 group of formula (II) R.sup.6 is a C.sub.2 -C.sub.6 alkylene group, R.sup.7 is a C.sub.1 -C.sub.6 alkylene group, a is an integer of 1-100, b is an integer of 0-100, the sum of a and b being equal to 1-200, c is an integer of 1-3, d is an integer of 0-2, the sum of c and d being equal to 3, and X is selected from the group consisting of hydrogen, a C.sub.1 -C.sub.30 hydrocarbon group, a group of formula (III), and a group of formula (IV), wherein formulas (II), (III) and (IV) are defined in the disclosure.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: November 17, 1998
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Noboru Ishida, Takashi Nakano, Masaki Nagao, Takashi Kaneko
  • Patent number: 5755833
    Abstract: A fuel additive comprising a urethane compound. A gasoline composition comprising gasoline blended with a urethane compound to suppress sludge or deposits in fuel intake systems or combustion chambers, such as an automobile engine.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: May 26, 1998
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Noboru Ishida, Masaki Nagao, Takashi Kaneko
  • Patent number: 5484462
    Abstract: A fuel composition comprising a mixture of hydrocarbons boiling in the range from about 320.degree. F. to 620.degree. F. and a sulfur content of about 0.05 wt. %, or below, containing from about 1 to about 20 PTB of aminoalkylmorpholine having the formula: ##STR1## where R is hydrogen of a C.sub.1 -C.sub.10 alkyl radical, and n is a number between 2 and about 10.
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: January 16, 1996
    Assignee: Texaco Inc.
    Inventor: Sheldon Herbstman
  • Patent number: 5383942
    Abstract: An amido alkanolamine composition obtained by reacting, at a temperature of 10.degree. C.-200.degree. C.:(a) a 4-alkyl-2-morpholinone represented by the formula: ##STR1## in which R represents a monovalent aliphatic radical having from 1 to 10 carbon atoms; and(b) a hydrocarbyl oxypolyoxyalkylene amine represented by the formula ##STR2## in which R' represents an alkyl, an alicyclic or an alkyl-alicyclic radical having from 12 to 30 carbon atoms or ##STR3## wherein R" represents a hydrocarbyl radical having from 4 to 30 carbon atoms, x has a value of from about 5 to 50, and R'" is an ethyl radical or a mixture of methyl and ethyl radicals.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: January 24, 1995
    Assignee: Texaco Inc.
    Inventors: Wei-Yang Su, Sheldon Herbstman, Joseph M. Russo, Robert L. Zimmerman, Michael Cuscurida
  • Patent number: 5312460
    Abstract: Disclosed is a fuel composition comprising a hydrocarbon boiling in the gasoline or diesel range and from about 30 to about 5,000 parts per million of an alkylphenyl poly(oxypropylene) aminocarbamate having at least one basic nitrogen and an average molecular weight of about 600 to 6,000 and wherein the alkyl group is substantially straight-chain of at least 15 carbon atoms. The instant invention is based on the discovery that use of the unique hydrocarbyl group, i.e., an alkylphenyl group wherein the alkyl group is derived from a substantially straight-chain alkyl group of at least 15 carbon atoms imparts to the alkylphenyl poly(oxypropylene) aminocarbamate not only lubricating oil compatibility but also an unexpected decrease in crankcase deposits.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: May 17, 1994
    Assignee: Chevron Research Company
    Inventor: Thomas F. Buckley, III
  • Patent number: 5312459
    Abstract: An additive for liquefied hydrocarbon fuel containsa) 30-60 volume percent of at least one nitrogen-containing solvent,b) 30-60 volume percent of at least one nitrogen-containing dispersing agent,c) 0.5-10 volume percent of a nitrogen-containing corrosion inhibiting agent andd) 0.5-10 volume percent of at least one oxidation inhibitor, wherein the sum of ingredients a, b, c and d is 100 volume percent. This additive protects against corrosion, aging, separation of materials on motor parts and purification of the exhaust gas in motors using liquefied hydrocarbon fuels.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: May 17, 1994
    Inventors: Friedrich A. Sprugel, Werner Angerer
  • Patent number: 5294233
    Abstract: An additive for improving the dispersibility of a particulate substance in an organic medium, a thermoplastic polymer, or a thermosetting resin, is at least one compound having a ##STR1## bond in the molecule, including, for example, compounds having an oxazolinium ion in the molecule. The preferred additive compounds are oligomeric or polymeric.
    Type: Grant
    Filed: July 31, 1991
    Date of Patent: March 15, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shizuo Kitahara, Hiroyuki Watanabe, Takuji Kishimoto, Tetuya Toyoshima, Takafumi Kawanaka, Kohkichi Noguchi
  • Patent number: 5286266
    Abstract: The present invention provides a novel class of compounds, useful as gasoline detergent additives, comprising asymmetrical ureas of either a hydrocarbyloxypolyether amine alone, or a hydrocarbyloxypolyether amine and a tertiary aminoalkyl primary amine. The present invention also provides a motor fuel composition containing the novel asymmetrical ureas and further provides a method of synthesizing the asymmetrical ureas of the present invention.
    Type: Grant
    Filed: July 9, 1992
    Date of Patent: February 15, 1994
    Assignee: Texaco Inc.
    Inventor: Sheldon Herbstman
  • Patent number: 5266080
    Abstract: The flame luminosity of a methanol fuel is appreciably enhanced by the addition thereto of at least one flame luminosity enhancing agent selected from the group consisting of azine dye, triarylmethane dye, fluorescein dye, imine dye and anthraquinone dye, said dye excluding any metal component whose combustion product(s) tend to cause excessive wear in an engine operated with the fuel composition or tend to significantly interfere with normal operation of such engine or any of its associated systems, the flame luminosity of the fuel composition during burning being appreciably enhanced relative to the flame luminosity of the same burning fuel composition but to which no flame luminosity enhancing agent has been added.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: November 30, 1993
    Assignee: The Standard Oil Company
    Inventors: Thomas E. Kiovsky, Wendy L. Clark
  • Patent number: 5203879
    Abstract: An amido alkanolamine composition obtained by reacting, at a temperature of 10.degree. C.-200.degree. C.:(a) a 4-alkyl-2-morpholinone represented by the formula: ##STR1## in which R represents a monovalent aliphatic radical having from 1 to 10 carbon atoms, and(b) a hydrocarbyl oxypolyoxyalkylene amine represented by the formula: ##STR2## in which R' represents an alkyl, an alicyclic, or a alkylalicyclic radical having from 8 to 30 carbon atoms, x has a value from 5 to 50, and R" represents a methyl radical or a mixture of hydrogen and methyl radicals is provided.
    Type: Grant
    Filed: September 1, 1992
    Date of Patent: April 20, 1993
    Assignee: Texaco Inc.
    Inventors: Wei-Yang Su, Sheldon Herbstman, Joseph M. Russo, Robert L. Zimmerman, Michael Cuscurida
  • Patent number: 5157118
    Abstract: This invention describes phenothiazine derivatives which are N-substituted and which contain an additional sulfur molecule in the N substituent.
    Type: Grant
    Filed: November 8, 1990
    Date of Patent: October 20, 1992
    Assignee: The Lubrizol Corporation
    Inventor: Mary F. Salomon
  • Patent number: 5057123
    Abstract: A method of stabilizing a diesel fuel formulation by substantially minimizing the oxidation thereof is disclosed. In particular, at least one amine containing copolymer is incorporated into the diesel fuel formulation in an amount sufficient to improve the storage stability and, also, substantially minimize the oxidation thereof. The method of this invention is particularly well suited for substantially minimizing the high temperature oxidation of diesel fuels.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: October 15, 1991
    Assignee: Texaco Inc.
    Inventors: Sheldon Herbstman, Theodore E. Nalesnik
  • Patent number: 5047069
    Abstract: An antioxidant for liquid hydrocarbons such as fuels has the structure ##STR1## wherein X is N or S; R is H or a C.sub.1 to C.sub.5 alkyl moiety; R.sup.1 and R.sup.2 are each independently C.sub.5 to C.sub.18 alkyl or cycloalkyl moieties (which may optionally contain a hetero atom such as oxygen), only one of R.sup.1 and R.sup.2 being present if X is S, or may be combined to form a 5 or preferably 6 membered ring; each R.sup.6 is independently the residue of a C.sub.1 to C.sub.5 aldehyde; and R.sup.7 is the residue of a polyamine of the formula ##STR2## wherein R.sup.3 is a C.sub.8 to C.sub.50 alkyl moiety (which may optionally contain one or more ether linkages); R.sup.4 and R.sup.5 are each independently C.sub.2 to C.sub.6 alkylene moieties; a is 0 or 1; and m is at least 3.
    Type: Grant
    Filed: October 22, 1990
    Date of Patent: September 10, 1991
    Assignee: Petrolite Corporation
    Inventors: Jerry J. Weers, Thomas V. Bagwell
  • Patent number: 5035719
    Abstract: Middle distillate fuels may be treated to improve storage stability by addition of, as additive, an acrylate polymer containing moieties derived from an N-heterocyclic amine such as 4-vinyl pyridine or the enamine ester of morpholine and propionaldehyde.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: July 30, 1991
    Assignee: Texaco Inc.
    Inventors: Rodney L. Sung, Benjamin J. Kaufman
  • Patent number: 5034019
    Abstract: This invention describes phenothiazine derivatives which are N-substituted and which contain an additional sulfur molecule in the N substituent.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: July 23, 1991
    Assignee: The Lubrizol Corporation
    Inventor: Mary F. Salomon
  • Patent number: 4978366
    Abstract: A distillate fuel, particularly one which has a high acid number initially or which develops a high acid number as a result of fuel degradation, stabilized with a diaminomethane of the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be independently a saturated or unsaturated hydrocarbon group, e.g., alkyl, aryl, aralkyl, alkaryl, cycloalkyl, alkenyl, aralkenyl, alkenylaryl, cycloalkenyl and the like or heterocyclyl groups and in which R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 may be joined together to form a five or six member heterocyclyl ring and R.sub.5 may be hydrogen or lower alkyl is disclosed. A method of stabilizing a fuel oil wherein a stabilizing amount of the above-mentioned diaminomethane is incorporated into the fuel oil is also disclosed.
    Type: Grant
    Filed: January 14, 1988
    Date of Patent: December 18, 1990
    Assignee: Petrolite Corporation
    Inventor: Jerry J. Weers