Heterocyclic Carbon Compound Containing A Hetero Ring Having Chalcogen Or Nitrogen As The Only Ring Hetero Atoms Patents (Class 44/329)
  • Patent number: 12102989
    Abstract: A nanocomposite catalyst includes a support, a multiplicity of nanoscale metal oxide clusters coupled to the support, and one or more metal atoms coupled to each of the nanoscale metal oxide clusters. Fabricating a nanocomposite catalyst includes forming nanoscale metal oxide clusters including a first metal on a support, and depositing one or more metal atoms including a second metal on the nanoscale metal oxide clusters. The nanocomposite catalyst is suitable for catalyzing reactions such as CO oxidation, water-gas-shift, reforming of CO2 and methanol, and oxidation of natural gas.
    Type: Grant
    Filed: August 14, 2023
    Date of Patent: October 1, 2024
    Assignee: Arizona Board of Regents on behalf of Arizona State University
    Inventors: Jingyue Liu, Xu Li
  • Patent number: 10494509
    Abstract: Described herein are associative polymers capable of controlling one or more physical and/or chemical properties of non-polar compositions and related compositions, methods and systems.
    Type: Grant
    Filed: August 31, 2018
    Date of Patent: December 3, 2019
    Assignee: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventors: Julia A. Kornfield, Ming-Hsin Wei, Simon Jones, Virendra Sarohia
  • Patent number: 10087310
    Abstract: Described herein are associative polymers capable of controlling one or more physical and/or chemical properties of non-polar compositions and related compositions, methods and systems.
    Type: Grant
    Filed: March 17, 2014
    Date of Patent: October 2, 2018
    Assignee: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventors: Julia A. Kornfield, Ming-Hsin Wei, Simon Jones, Virendra Sarohia
  • Publication number: 20140331547
    Abstract: Method of marking a hydrocarbon liquid includes: adding thereto, a tracer compound of Formula I: wherein, each A is independently selected from the group consisting of (i) a phenyl group, (ii) a phenyl group substituted with one or more halogen atoms, an aliphatic group or a halogenated aliphatic group, (iii) a partially or fully halogenated alkyl group or (iv) a linear branched or cyclic C1-C20 alkyl group, and each B is independently selected from the group consisting of a (i) phenyl, (ii) phenylmethyl group, (iii) a cyclohexyl group, (iv) a cyclohexylmethyl group, (v) a substituted phenyl or phenylmethyl group in which the benzene ring is substituted by at least one substituent selected from the group consisting of a fluorine atom, a partially or fully halogenated alkyl group and a linear, branched or cyclic C1-C20 alkyl group or (vi) a linear, branched or cyclic C1-C20 alkyl group.
    Type: Application
    Filed: January 4, 2013
    Publication date: November 13, 2014
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Vincent Brian Croud, Ian Stuart Edworthy, Duncan McCallien
  • Patent number: 8801811
    Abstract: A stabilized nano-Fe6-iron-crown ether complex is formed by preparing a solution of an iron salt and an oligomer crown compound in dialkylamine or diethylamine. Sodium tetrahydroboron (NaBH4) and dialkylamine or ethylendiamine are added at a temperature of 0-10° C. The mixture is heated to room temperature and boiled, thereby converting the formed iron (II)-borhydride complex (Fe(BH4)2) to a crown ether-iron-hydride complex [CWFe06].(2H)6. At higher temperature this last complex is converted to the Fe06-crown nanocomposite complex. The prepared nanoparticle Fe6° complex may be stabilized by inclusion into a cavity of a macrocyclic compound, and may be (1) added to diesel fuel to reduce NOx emissions upon combustion of that fuel; (2) added to lubricating oils as an anti-corrosion additive; and (3) used as an additive to secondary recovery processes within liquid hydrocarbon formations to increase the sweep efficiency and recovery factor of water-flooding operations.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: August 12, 2014
    Assignee: Asiacom Group Investments, Inc.
    Inventors: Alimamed L. Shabanov, Elmira M. Ramazanova, Uliviyya A. Gasanova
  • Publication number: 20130192125
    Abstract: A stabilized nano-Fe6-iron-crown ether complex is formed by preparing a solution of an iron salt and an oligomer crown compound in dialkylamine or diethylamine. Sodium tetrahydroboron (NaBH4) and dialkylamine or ethylendiamine are added at a temperature of 0-10° C. The mixture is heated to room temperature and boiled, thereby converting the formed iron (II)—borhydride complex (Fe(BH4)2) to a crown ether—iron-hydride complex [CWFe06].(2H)6. At higher temperature this last complex is converted to the Fe06-crown nanocomposite complex. The prepared nanoparticle Fe6° complex may be stabilized by inclusion into a cavity of a macrocyclic compound, and may be (1) added to diesel fuel to reduce NOx emissions upon combustion of that fuel; (2) added to lubricating oils as an anti-corrosion additive; and (3) used as an additive to secondary recovery processes within liquid hydrocarbon formations to increase the sweep efficiency and recovery factor of water-flooding operations.
    Type: Application
    Filed: March 13, 2013
    Publication date: August 1, 2013
    Applicant: ASIACOM GROUP INVESTMENTS, INC.
    Inventor: Asiacom Group Investments, Inc.
  • Patent number: 8308827
    Abstract: A diesel fuel containing a soot dispersant additive which is a grafted and derivatized low molecular weight copolymer of ethylene and at least one C3-C10 alpha monoolefin is provided. Also provided is a method for improving the fuel economy of a diesel engine which comprises operating the diesel engine with a fuel composition comprising (a) a major amount of a diesel fuel and (b) a minor fuel economy improving effective amount of the soot dispersant additive.
    Type: Grant
    Filed: January 11, 2010
    Date of Patent: November 13, 2012
    Assignee: Texaco, Inc.
    Inventors: C. Yvonne Thiel, Thomas E. Hayden
  • Publication number: 20120251521
    Abstract: The present invention is a solution or colloid of fullerene, SWNTs, or graphene in cyclic terpenes, lactones, terpene-alcohol, fatty-acid alcohols, and lactones following ultrasonication and ultracentrifugation processing, for oil-energy, biological, electrical-thermal applications. The compositions are useful as fuel/oil/grease/gels (synthetic included), oil/fuel/additives/propellants, identification dyes, and heat-transfer fluids. Other functions are phase-change fluids for solar energy power plants, antifreeze, electronic dyes, electrolytic fluid/solvent, electrically-thermally conductive material for electrochemical, dielectric, filler/adhesive for semiconductor, eletro-optical, and liquid crystal substrates/coatings for touch sensitive transmissive or reflective displays. When combined with gelatin the formulations can function as dichroic-optical coatings for thin-films/waveguides/holograms.
    Type: Application
    Filed: April 2, 2011
    Publication date: October 4, 2012
    Inventors: Bertha Rostro, Mehdie Kohanloo
  • Patent number: 8197560
    Abstract: Disclosed is a fuel for fuel cells which contains at least one organic compound selected from the group consisting of methanol, ethanol, dimethyl ether and formic acid, and 1-200 ppm of a hydrocarbon compound in terms of a single component as determined by gas chromatography mass spectrometry. Also disclosed are a fuel cartridge for fuel cells and a fuel cell.
    Type: Grant
    Filed: June 14, 2006
    Date of Patent: June 12, 2012
    Assignees: Kabushiki Kaisha Toshiba, Toyo Seikan Kaisha, Ltd.
    Inventors: Yumiko Takizawa, Daisuke Imoda, Kyoko Yoshino
  • Patent number: 7976589
    Abstract: Nanoscopic core-shell material additives for high temperature jet aviation fuels are disclosed. The nanometer dimensions of these core-shell material additives materials provide extremely large surface areas to promote chemical reactivity while permitting suspension in liquid fuels and providing unlimited access to all components of an aircraft fuel system. Core-shell technology involves additive encapsulation in a protective, fuel-mimicking shell material.
    Type: Grant
    Filed: May 4, 2006
    Date of Patent: July 12, 2011
    Assignee: United States of America as represented by the Secretary of the Air Force
    Inventor: Christopher E. Bunker
  • Publication number: 20100287822
    Abstract: Polymeric mist control materials, methods of forming polymeric mist control materials, and methods of using such materials for mist control are provided. The polymeric mist control additives are formed of molecules comprised predominantly of monomers that confer high solubility in fuel and include associative groups that attract each other in donor-acceptor manner, and are incorporated such that multiple associative groups are in close proximity (“clusters”), such that the clusters are separated by very long non-associative sequences.
    Type: Application
    Filed: April 19, 2010
    Publication date: November 18, 2010
    Applicant: California Institute of Technology
    Inventors: Ming-Hsin Wei, Julie A. Kornfield, R.L. Ameri David
  • Patent number: 7691158
    Abstract: Fuel additives, fuel formulations, and processes for their preparation and use are provided. The additives improve the combustion properties of hydrocarbon fuels. The enhanced combustion indicates reductions in certain emissions.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: April 6, 2010
    Assignee: Oryxe Energy International, Inc.
    Inventors: Frederick L. Jordan, Geoffrey E. Dolbear
  • Publication number: 20090307964
    Abstract: A cold-stabilized fuel oil composition comprising a major proportion by weight of a middle distillate fuel which boils in the range of 120-500° C. and minor proportions by weight of (A) at least one cold flow improver, (B) at least one detergent additive and (C) at least one cold solubilizer I which has at least one radical having at least 4 carbon atoms.
    Type: Application
    Filed: June 10, 2009
    Publication date: December 17, 2009
    Applicant: BASF SE
    Inventors: Frank-Olaf MAEHLING, Irene TROETSCH-SCHALLER, Heinrich LUBOJANSKI, Thomas PFEIFFER
  • Patent number: 7621971
    Abstract: A composition is disclosed that comprises the reaction product of an acidic organic compound, a boron compound, and a basic organic compound. The composition is useful as a detergent additive for lubricants and hydrocarbon fuels.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: November 24, 2009
    Assignee: Chemtura Corporation
    Inventor: Ronald J. Muir
  • Publication number: 20090107555
    Abstract: The present disclosure relates to methods and compositions for improving fuel atomization and combustion efficiency comprising fuel additives for use in combustion systems where fuel is injected into the combustion zone under very high pressure
    Type: Application
    Filed: October 31, 2007
    Publication date: April 30, 2009
    Inventor: Allen A. Aradi
  • Publication number: 20080086935
    Abstract: The present disclosure provides compositions and methods for improving corrosion inhibition in engines combusting a fuel containing ethanol. In particular, E85 fuels are provided containing additives able to reduce, eliminate and/or prevent corrosion of engine combustion surfaces and surfaces of engine components exposed to the fuel containing ethanol.
    Type: Application
    Filed: October 16, 2006
    Publication date: April 17, 2008
    Inventors: Lawrence J Cunningham, Richard J. DuMont, William J. Colucci, Alexander M. kulinowski, Joseph W. Roos, Ronald K. Fricke
  • Publication number: 20080028672
    Abstract: A diesel fuel composition made up of a major amount of a diesel fuel, a minor amount of at least one metallic species and a minor amount of a detergent additive is disclosed.
    Type: Application
    Filed: July 30, 2007
    Publication date: February 7, 2008
    Inventors: Rinaldo Caprotti, Angela Priscilla Breakspear, Tushar kanti Bera, Jacob Emert
  • Patent number: 7252690
    Abstract: This invention is a fuel composition having a sulphur content of ?50 ppm by weight and comprising ?50 ppm by weight of at least one fused polycyclic aromatic compound which has at least one hetero-atom selected from O and N either (a) as a heterocyclic group, or, (b) as an exocyclic group in which the hetero-atom is attached either directly or through one other carbon atom to a ring carbon atom wherein the fused polycyclic aromatic compound is substituted on at least one of its ring carbon atoms by a C1-C4 alkyl group. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuels, especially diesel fuels, when compared with the performance of the same fuel in the absence of such compounds.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: August 7, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
  • Patent number: 7112230
    Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): wherein R1 and R2 are independently C1-4 alkyl, R3 is a radical of the formula CmH2m wherein m is an integer of 2 to 6, R4 and R5 are each independently (i) hydrogen (ii) C1-4 alkyl, wherein R6 is selected from the group consisting of hydrogen and C1-4 alkyls and R7 is selected from the group consisting of hydrogen and C1-30 alkyl, (iv) wherein R8 is a saturated or unsaturated, linear, branched or cyclic, C7-23 hydrocarbyl group or (v) wherein R4 and R5 together with the nitrogen atom to which they are bonded, form a cyclic ring in which further hetero atoms.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: September 26, 2006
    Assignee: Afton Chemical Intangibles LLC
    Inventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
  • Patent number: 7041738
    Abstract: The present invention provides an additive for improving the cold flow properties of vegetable or animal fuel oil. The additive comprises A) a copolymer of ethylene and 8–21 mol % of at least one acrylic or vinyl ester having a C1–C18-alkyl radical and B) a comb polymer of at least one C8–C16-alkyl ester of an ethylenically unsaturated dicarboxylic acid and at least one C10–C20-olefin, wherein the sum Q Q = ? i ? w 1 ? i · n 1 ? i + ? j ? w 2 ? j · n 2 ? j ?of the molar averages of the carbon chain distributions in the alkyl side chains of the olefins (monomer 1) and the fatty alcohols (monomer 2) is from 23 to 27. In Q, w1 and w2 are the molar proportions of the individual chain lengths in the comb polymer from the different monomers 1 and 2, and n1 and n2 are the side chain carbon atom lengths, excluding comb polymer bonded carbon atoms of monomer 1, and the running variables i and j are the individual side chain lengths in the particular monomer groups.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: May 9, 2006
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Bettina Siggelkow, Martina Hess, Ulrike Neuhaus
  • Patent number: 6676715
    Abstract: There is provided use of a thermal stabiliser for increasing the thermal stability of a cetane improver in a fuel composition comprising (i) a fuel, and (ii) the cetane improver wherein the thermal stabiliser is a compound of the formula H—R1 wherein H is a group comprising a heterocyclic group and R1 is a hydrocarbyl group having from 10 to 200 carbons.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: January 13, 2004
    Assignees: The Associated Octel Company Limited, Octel Starreon, LLC
    Inventors: Cyrus Pershing Henry, Barbara Elizabeth Goodrich
  • Patent number: 6656237
    Abstract: This invention provides a fuel composition having a sulphur content of not more than 50 ppm by weight and comprising at least 50 ppm based on the total weight of the fuel composition of at least one fused polycyclic aromatic compound which comprises at least one exocyclic group containing nitrogen wherein the nitrogen is attached directly to a ring carbon atom. Specific examples of such compounds include 1-amino naphthalene, 1,8-diaminonaphthalene, or 5-aminoindole, 2-(2-aminophenyl)indole and 8-aminoquinoline. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuel when compared with that of the same fuel in the absence of such compounds.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: December 2, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
  • Publication number: 20030154647
    Abstract: The invention provides photoluminescent markers consisting essentially of fluorene copolymers, which are colorless or nearly colorless to the naked eye and exhibit strong photoluminescence between about 380-800 nm upon exposure to ultra-violet radiation or laser light. The soluble fluorene copolymers described in this invention having a general formula as shown in Formula 1.
    Type: Application
    Filed: December 26, 2001
    Publication date: August 21, 2003
    Inventors: My T. Nguyen, Francois Raymond, Steven Xiao
  • Patent number: 6565616
    Abstract: The invention relates to blends of copolymers containing structural units of olefins, derivatives of dibasic carboxylic acids and, if required, polyolefins and, structural units of ethylene and vinyl esters of tertiary carboxylic acids, and their use as additives to fuel oils for improving their cold flow properties.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: May 20, 2003
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Thomas Volkmer, Werner Reimann
  • Publication number: 20030079399
    Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): 1
    Type: Application
    Filed: September 14, 2001
    Publication date: May 1, 2003
    Inventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
  • Patent number: 6540796
    Abstract: The invention relates to use of trioxepan compounds of formula I with R1-3 being independently selected from substituted or unsubstituted hydrocarbyl groups in the process to make fuels with improved ignition properties.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: April 1, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Johannes J. De Groot, John Meijer
  • Patent number: 6387512
    Abstract: A photochromic grey coloring 2H-naphtho[1,2-b]pyran of formula (1) wherein R1 is selected from mono-, di- or poly-substituted aryl groups, mono-, di- or poly-substituted naphthyl groups and mono-, di- or poly-substituted heteroaryl groups, wherein at least one substituent is a nitrogen containing group, including amino, C1-C20 and C6-C20 alkylamino, C1-C20 and C6-C20 dialkylamino, C2-C20 dialkenylamino, C2-C20 or C4-C20 di(polyalkenyl)amino, arylamino, diarylamino, C1-C20 alkylarylamino, tetra (C1-C10 linear or branched alkyl) guanidino and cyclic-amino groups and at least one of R7 and R9, which may be the same or different, is selected from C1-C20 N alkylamino C1-C20 N-alkylamido, C1-C20 N,N-dialkylamido, amido, nitro, amino, C1-C20 alkylamino, C1-C20 dialkylamino, C2-C20 dialkenylamino, C4-C20 di(polyalkenyl)amino, arylamino, diarylamino, C1-C20 alkylarylamino, or cyclicamino groups.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: May 14, 2002
    Assignee: James Robinson Limited
    Inventors: David Allan Clarke, Bernard Mark Heron, Christopher David Gabbutt, John David Hepworth, Steven Michael Partington, Stephen Nigel Corns
  • Publication number: 20020038524
    Abstract: The invention relates to use of trioxepan compounds of formula I 1
    Type: Application
    Filed: August 15, 2001
    Publication date: April 4, 2002
    Inventors: Johannes J. De Groot, John Meijer
  • Publication number: 20020014034
    Abstract: The invention concerns a fuel for diesel engines, with a sulphur content of less than 500 ppm containing in a major proportion at least one average distillate from a straight-run distilling cup of crude oil, with temperature ranges between 150 and 400° C. and in a minor proportion a lubricating additive containing monocarboxylic and polycyclic acids.
    Type: Application
    Filed: March 17, 1999
    Publication date: February 7, 2002
    Inventors: CHRISTIAN BERNASCONI, LAURENT GERMANAUD, JEAN-MICHEL LAUPIE, PAUL MALDONADO
  • Patent number: 6339163
    Abstract: Compositions that comprise at least one compound that corresponds to general formula (I): in which n is a number from 0 to 20; R1, R2, R3 and R4 each represent a hydrogen atom or a hydrocarbon radical, for example alkyl, with 1 to 30 carbon atoms, whereby at least one of R1, R2, R3, and R4 is a hydrocarbon radical; and m is a number from 1 to 30, can be prepared by a process that comprises the reaction of a hydroxymethylated derivative of tetrahydrofuran with ethylene oxide, then with one or more other epoxidized compounds. These compositions can be used as detergent additives for gasoline-type fuels.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: January 15, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Bruno Delfort, Stéphane Joly, Thierry Lacôme, Patrick Gateau, Fabrice Paille
  • Publication number: 20010034966
    Abstract: Method of reducing the pressure of a C3 to C12 hydrocarbon-based motor fuel mixture containing 0.1 to 20% by volume of ethanol for conventional spark ignition internal combustion engines, wherein, in addition to an ethanol component (b) and a C3 to C12 hydrocarbon component (a), an oxygen-containing additive (c) selected from at least one of the following types of compounds: alcohol other than ethanol, ketone, ether, ester, hydroxy ketone, ketone ester, and a heterocyclic-containing oxygen compound, is used in the fuel mixture in an amount of at least 0.05 by volume of the total fuel, is disclosed. A mixture of fuel grade ethanol (b) and oxygen-containing additive (c) usable in the method of the invention is also disclosed.
    Type: Application
    Filed: January 24, 2001
    Publication date: November 1, 2001
    Inventors: Angelica Golubkov, Igor Golubkov
  • Patent number: 6296677
    Abstract: The lubricity (anti-wear properties) of fuels, for example hydrocarbon fuels, oxygenated fuels or mixtures thereof, particularly diesel or aviation fuels having reduced sulphur and/or aromatic content for compliance with regulator requirements, is improved by addition of at least a product which can be obtained by reacting components a), b) and c), where component a) is a compound of the formula I or a mixture of compounds of the formula I, component b) is a compound of the formula II or a mixture of compounds of the formula II and component c) is a compound of the formula III or a mixture of compounds of the formula III, in which the general symbols are as defined in claim 1, the compound of the formula I being, for example, pentaerythritol, thiodiethylene glycol, 1,4-butanediol, 1,4-propanediol, diethylene glycol, triethylene glycol, diethanolamine or glycerol, the compound of the formula II being, for example, sunflower oil or coconut fat, and the compound of the formula III being, for ex
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: October 2, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Marc Ribeaud, Paul Dubs, Michael Rasberger, Samuel Evans
  • Patent number: 6261327
    Abstract: The present invention is directed to an additive concentrate for reducing octane requirement comprising a cyclic amide alkoxylate compound of the formula I: wherein x is from 3 to 11; y is from 1 to 50; R1 and R2 are each independently hydrogen, hydrocarbyl of 1 to 100 carbon atoms and substituted hydrocarbyl of 1 to 100 carbon atoms; R3 is hydrocarbyl of 1 to 100 carbon atoms or substituted hydrocarbyl of 1 to 100 carbon atoms; each R4 is independently hydrocarbyl of 2 to 100 carbon atoms or substituted hydrocarbyl of 2 to 100 carbon atoms; R5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms, substituted hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms; a detergent selected from polyalkenylamines, Mannich amines, polyalkenylsuccinimides, poly(oxyalkylene) carbamates and poly(alkenyl)-N-substituted carbamates and an optional solvent.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: July 17, 2001
    Assignee: Shell Oil Company
    Inventors: Joseph Graham, Robert Peter Aiello, Earl Jon Haury
  • Patent number: 5912213
    Abstract: Substituted carboxylic acylating agents formed by reacting an olefin with a carboxylic reactant are further reacted with .alpha.-.beta. unsaturated carboxylic compositions to form substituted carboxylic acylating agents. The substituted carboxylic acylating agents are further reacted with various compounds to form especially dispersants for use in oil compositions.
    Type: Grant
    Filed: June 5, 1997
    Date of Patent: June 15, 1999
    Assignee: The Lubrizol Corporation
    Inventors: Mark R. Baker, Jeffry G. Dietz, Richard Yodice
  • Patent number: 5912189
    Abstract: The present invention is directed to a composition containing the reaction product of:(A) a cyclic compound containing a 5, 6, or 7-member ring, the ring containing at least one nitrogen and at least one carbonyl group, at least one carbonyl group being adjacent to at least one said nitrogen;(B) an aldehyde or ketone of 1 to about 15 carbon atoms, or a reactive equivalent thereof; and(C) an etheramine represented by the formulaR.sup.4 (O(CH.sub.2 CH(R)O).sub.n --R.sup.3 --NH.sub.2).sub.y(C-I)wherein in formula (C-I), each n independently is a number from 0 to about 50; each R independently is selected from the group consisting of hydrogen, hydrocarbyl groups of 1 to about 16 carbon atoms, and mixtures thereof; R.sup.3 is selected from the group consisting of hydrocarbylene groups of about 2 to about 18 carbon atoms and groups represented by the formula ##STR1## wherein R.sup.5 and each R.sup.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: June 15, 1999
    Assignee: The Lubrizol Corporation
    Inventors: Thomas J. Wolak, Richard M. Lange
  • Patent number: 5880072
    Abstract: Compositions for reducing wear and friction of rubbing surfaces including mixtures of a cyclic amide and a monoester formed by reacting a dicarboxylic acid and a polyol in substantially equimolar amounts where the dicarboxylic acid is a dimer of an unsaturated fatty acid. The invention also relates to methods of use of such compositions.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: March 9, 1999
    Assignee: Virginia Tech Intellectual Properties, Inc.
    Inventors: Michael J. Furey, Czeslaw Kajdas
  • Patent number: 5851964
    Abstract: Method of reducing wear between rubbing surfaces by contacting a surface of a solid material with a cyclic amide before and/or while it is being rubbed against another surface.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: December 22, 1998
    Assignee: Virginia Tech Intellectual Properties, Inc.
    Inventors: Michael J. Furey, Czeslaw Kajdas
  • Patent number: 5837867
    Abstract: The present invention is directed to the use of cyclic amide alkoxylate compounds as additives in fuel compositions having a major amount of a mixture of hydrocarbons in the gasoline boiling range and a minor amount of one or more cyclic amide alkoxylate compounds of the formula: ##STR1## wherein x is from 2 to 20 and y is from 1 to 50. R.sub.1 and R.sub.2 are independently hydrogen or hydrocarbyl of 1 to 100 carbon atoms. R.sub.3 is hydrocarbyl of 1 to 100 carbon atoms and R.sub.4 is independently hydrocarbyl of 2 to 100 carbon atoms. R.sub.5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms.The invention is also directed to the use of these cyclic amide alkoxylate compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to novel cyclic amide alkoxylate compounds.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: November 17, 1998
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, Charles Lee Edwards, Pen-Chung Wang, Garo Garbis Vaporciyan
  • Patent number: 5730762
    Abstract: A gas oil according to the present invention comprises a gas oil fraction, and has a sulfur content not higher than 0.05 wt %, and either or both of (1) a content of bicyclic and higher aromatic hydrocarbons in a range of from 3.5 wt % to 15 wt %, bicyclic and higher aromatic hydrocarbons having at least one side-chain C.sub.3-11 alkyl group amounting to at least 80 wt % of said first-mentioned bicyclic and higher aromatic hydrocarbons, and (2) a content of nitrogen-containing heterocyclic compounds in a range of from 80 ppm to 500 ppm, nitrogen-containing heterocyclic compounds having at least one side-chain alkyl group accounting for at least 90 wt % of said first-mentioned nitrogen-containing heterocyclic compounds. The gas oil according to the present invention, as a diesel fuel, can impart anti-wearing properties by simply adjusting its components without the need for incorporation of an additive such as an anti-wearing agent.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: March 24, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Kazuyuki Murakami, Shoukichi Yamamoto, Yutaka Hasegawa, Kazushi Tsurutani
  • Patent number: 5518510
    Abstract: This invention relates to low-sulfur diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective mount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The sulfur content of these diesel fuels is no more than about 0.1% by weight, preferably no more than about 0.05% by weight. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include .dbd.X, --XR, --NR.sub.2, --NO.sub.2, .dbd.NR, .dbd.NXR, .dbd.N--R*--XR, ##STR1## --CN, --N.dbd.NR and --N.dbd.CR.sub.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: May 21, 1996
    Assignee: The Lubrizol Corporation
    Inventors: Daniel T. Daly, Paul E. Adams, Nai Z. Huang, Scott T. Jolley, Frederick W. Koch, Christopher J. Kolp, Stephen H. Stoldt, Reed H. Walsh, Richard A. Denis, Dennis M. Dishong
  • Patent number: 5507843
    Abstract: The present invention is directed to the use of multiple cyclic nitrogen-containing alkoxylate compounds as additives in fuel compositions. The invention is also directed to the use of these multiple cyclic nitrogen-containing alkoxylate compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to a class of multiple cyclic nitrogen-containing alkoxylate compounds.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: April 16, 1996
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, Pen-Chung Wang, Sarah L. Weaver
  • Patent number: 5472457
    Abstract: Compounds with general formula ##STR1## where R.sup.1 represents a hydrogen atom or a hydrocarbon group containing 1 to 40 carbon atoms. R.sup.2 represents a hydrogen atom or a hydrocarbon group containing 1 to 12 carbon atoms, A, B, and C, which may be identical or different, each represent a divalent hydrocarbon group containing 2 to 6 carbon atoms, n is a whole number from 5 to 50, m and p are each zero or a whole number from 1 to 25, and the sum n+m+p is a whole number from 5 to 50.These compounds are used in multifunctional additive compositions for fuels used in internal combustion engines, in particular spark ignition engines, in admixture with at least one compound selected from the group formed by detergent-dispersant compounds, and at least one compound selected from the group formed by mineral or synthetic lubricating oils and polyglycols which are soluble in said fuels.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: December 5, 1995
    Assignees: Institut Francais du Petrole, Elf Antar France
    Inventors: Henri Delhomme, Jean Gaillard, Philippe Mulard, Daniele Eber
  • Patent number: 5460633
    Abstract: An additive comprising an oil-soluble polymer of a C2 to C6 mono-olefin such as polyisobutylene, which polymer has a molecular weight of less than about 500, is used in a fuel oil to reduce, on combustion of the fuel oil, one or more of particulate emissions, hydrocarbon emissions, carbon monoxide emissions, and oxides of nitrogen emissions.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 24, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Anthony K. Smith, Michael D. Sexton, Richard J. Hart
  • Patent number: 5460634
    Abstract: An additive comprising an oil-soluble stable free radical, such as a nitroxide, or a precursor therefor, is used in a fuel oil to reduce, on combustion of the fuel oil, one or more of particulate emissions, hydrocarbon emissions, carbon monoxide emissions, and oxides of nitrogen emissions.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 24, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Carlo Fava, Wolfgang W. J. Gschwendtner, Anthony K. Smith, Michael D. Sexton, Richard J. Hart
  • Patent number: 5352251
    Abstract: The present invention is directed to the use of cyclic amide alkoxylate compounds as additives in fuel compositions having a major amount of a mixture of hydrocarbons in the gasoline boiling range and a minor amount of one or more cyclic amide alkoxylate compounds of the formula: ##STR1## wherein x is from 2 to 20 and y is from 1 to 50. R.sub.1 and R.sub.2 are independently hydrogen, hydrocarbyl of 1 to 100 carbon atoms or substituted hydrocarbyl of 1 to 100 carbon atoms. R.sub.3 is hydrocarbyl of 1 to 100 carbon atoms or substituted hydrocarbyl of 1 to 100 carbon atoms and R.sub.4 is independently hydrocarbyl of 2 to 100 carbon atoms or substituted hydrocarbyl of 2 to 100 carbon atoms. R.sub.5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms, or substituted hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: October 4, 1994
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, James R. Macias, Earl J. Haury, Sarah L. Weaver, Charles L. Edwards, Pen-Chung Wang, Garo G. Vaporciyan
  • Patent number: 5348561
    Abstract: Sediment and color formation in distillate fuels are reduced by the addition of a quaternary ammonium compound comprising a cation in which the ratio of carbon atoms to quaternary nitrogen atoms is not more than 10:1 and an anion which is derived from an acid which is a carboxylic acid, carboxylic acid anhydride, phenol, sulphurized phenol or sulphonic acid.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: September 20, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Michael D. Sexton, Rosalind H. Strange
  • Patent number: 5324334
    Abstract: There are disclosed macrocyclic and polycyclic polyamine lubricating oil additives formed by cyclodehydration of reaction products of hydrocarbon substituted succinic anhydrides or carboxylic acids with poly 3-amino propyl compounds or by acylation of macrocyclic polyamines and polycyclic polyamines with hydrocarbon substituted succinic anhydride or carboxylic acids. These compounds are useful as dispersants and dispersants-V.I. improvers in both gasoline and diesel engine lubricating oil compositions and are also useful fuel additives.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: June 28, 1994
    Assignee: Exxon Research & Engineering
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 5286265
    Abstract: The invention relates to an internal combustion fuel concentrate comprising: (a) from 1 to 95% of a chlorine-free carbamate prepared by reacting a carbamate of formula ##STR1## with a compound of the formula R OH (VI) in the presence of either a strone organic base or a tetra hydrocarbyl titanate so as to exchange the group R in formula (I) with a group R.sup.1 in formula (II), and (b) a fuel compatible solvent therefor. In the formula (I) R is a hydrocarbyl or substituted hydrocarbyl group and R.sup.1 is a hydrocarbyl or a hetero-substituted hydrocarbyl group different from R. In formula (I), X and Y are independently any of hydrogen, a hydrocarbyl group, or the group of the formula ##STR2## where Z is either a divalent hydrocarbyl, a substituted hydrocarbyl group or the group of formula(alkylene).sub.m (NH.sub.n (alkylene).sub.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: February 15, 1994
    Assignee: BP Chemicals Limited
    Inventors: Richard A'Court, William J. Fox, John E. Hamlin, Sean P. O'Connor
  • Patent number: 5266080
    Abstract: The flame luminosity of a methanol fuel is appreciably enhanced by the addition thereto of at least one flame luminosity enhancing agent selected from the group consisting of azine dye, triarylmethane dye, fluorescein dye, imine dye and anthraquinone dye, said dye excluding any metal component whose combustion product(s) tend to cause excessive wear in an engine operated with the fuel composition or tend to significantly interfere with normal operation of such engine or any of its associated systems, the flame luminosity of the fuel composition during burning being appreciably enhanced relative to the flame luminosity of the same burning fuel composition but to which no flame luminosity enhancing agent has been added.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: November 30, 1993
    Assignee: The Standard Oil Company
    Inventors: Thomas E. Kiovsky, Wendy L. Clark
  • Patent number: 5199960
    Abstract: Sulfur-coupled hydrocarbyl derived mercaptobenzothiazole adducts have been found to be effective multifunctional antiwear additives for fuels and lubricants.
    Type: Grant
    Filed: October 3, 1991
    Date of Patent: April 6, 1993
    Assignee: Mobil Oil Corporation
    Inventors: Liehpao O. Farng, Andrew G. Horodysky, James G. Murray