Acyclic Chalcogen Or Acyclic Nitrogen Bonded Directly To Ring Carbon Of The Hetero Ring Patents (Class 44/338)
  • Patent number: 10005978
    Abstract: The composition of the present invention related to a quaternary ammonium salt detergent and the use of such quaternary ammonium salt detergents in a fuel composition to reduce diesel injector deposits and remove or clean up existing deposits on the diesel injectors.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: June 26, 2018
    Assignee: The Lubrizol Corporation
    Inventors: James H. Bush, Robert H. Barbour, David J. Moreton, Hannah Greenfield, Paul R. Stevenson, David C. Arters
  • Patent number: 9017429
    Abstract: Use in a gas oil fuel composition, which preferably comprises a Fischer-Tropsch derived fuel, of a compound according to formula (I): wherein: R1 to R4 are each independently hydrogen or a C1-10 alkyl group, where such alkyl groups may be the same as or different from one another; and X is a nitrogen- or oxygen-containing group, for the purpose of reducing the cetane number of said fuel composition; preparation of such a fuel composition; and operating a fuel consuming system.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: April 28, 2015
    Assignee: Shell Oil Company
    Inventors: Claire Griffiths, Richard Hugh Clark, Christopher William Clayton, Paul Anthony Stevenson, Robert Wilfred Matthews Wardle
  • Publication number: 20120005950
    Abstract: Use in a gas oil fuel composition, which preferably comprises a Fischer-Tropsch derived fuel, of a compound according to formula (I): wherein: R1 to R4 are each independently hydrogen or a C1-10 alkyl group, where such alkyl groups may be the same as or different from one another; and X is a nitrogen- or oxygen-containing group, for the purpose of reducing the cetane number of said fuel composition; preparation of such a fuel composition; and operating a fuel consuming system.
    Type: Application
    Filed: December 28, 2009
    Publication date: January 12, 2012
    Inventors: Claire Griffiths, Richard Hugh Clark, Christopher William Clayton, Paul Anthony Stevenson, Wilfred Matthews Wardle
  • Publication number: 20110155616
    Abstract: The present invention relates to an odorant comprising or consisting of (A) at least 75% by weight of acrylic acid methyl ester and/or acrylic acid ethyl ester, (B) 2-19.5% by weight of tetrahydrothiophene (THT), (C) 5-50 ppm of hydroquinone monomethyl ether, and also neither, one or both components selected from the group consisting of (D) 0.025-0.2% by weight of butylhydroxy toluene and/or butyl hydroxyanisole and (E) 5-500 ppm of one or more compounds of formula (I) wherein R is selected from the group consisting of H, —OH, —NH2, —O2CR1 and —NOCR1, wherein R1 represents an alkyl radical containing 1 to 4 carbon atoms, based on the total weight of the odorant.
    Type: Application
    Filed: September 21, 2007
    Publication date: June 30, 2011
    Applicant: SYMRISE GmbH & Co KG
    Inventors: Marcus Eh, Jörg Eilers, Ingo Wöhrle, Norbert Andreas Braun, Fritz Henke, Adrian Henke
  • Publication number: 20100011656
    Abstract: The invention relates to the use of rylene derivatives of the general formula (I) as markers for liquids, where the symbols and indices have the meanings given in the specification.
    Type: Application
    Filed: February 23, 2007
    Publication date: January 21, 2010
    Applicant: BASF SE
    Inventors: Thomas Gessner, Sophia Ebert, Ruediger Sens, Martin Koenemann, Wolfgang Ahlers, Christos Vamvakaris
  • Publication number: 20090151235
    Abstract: The present invention is directed to the use of alkyl (meth)acrylate polymers or copolymers of the formula (I) In-Poly-(E)y??(I) as cold flow improvers in biodiesel fuel (or bio-fuel) and biodiesel compositions incorporating said polymers or copolymers, obtained by nitroxyl mediated controlled free radical polymerization, wherein In is the initiator fragment starting the polymerization reaction; E is an end group bearing at least one stable free nitroxyl radical, which is bound via an oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; Poly is any polymer or copolymer formed from ethylenically unsaturated monomer(s); and y is a number 1 or greater than 1 indicating the average number of end groups E attached to Poly.
    Type: Application
    Filed: December 16, 2008
    Publication date: June 18, 2009
    Inventors: Eugene Scanlon, Kevin DeSantis, Clemens Auschra, Andreas Mock
  • Patent number: 7175678
    Abstract: The present invention provides a polymeric a fuel composition comprising (i) a fuel; and (ii) a polymeric compound; wherein the polymeric compound comprises at least one monomer unit of Formula I wherein R1 is H or a C1-10 hydrocarbyl group; wherein L is an optional C1-30 hydrocarbyl linker group; and wherein heterocycle is an optionally substituted heterocyclic ring.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: February 13, 2007
    Assignee: Innospec Limited
    Inventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon, Derek Richard Green
  • Patent number: 7112230
    Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): wherein R1 and R2 are independently C1-4 alkyl, R3 is a radical of the formula CmH2m wherein m is an integer of 2 to 6, R4 and R5 are each independently (i) hydrogen (ii) C1-4 alkyl, wherein R6 is selected from the group consisting of hydrogen and C1-4 alkyls and R7 is selected from the group consisting of hydrogen and C1-30 alkyl, (iv) wherein R8 is a saturated or unsaturated, linear, branched or cyclic, C7-23 hydrocarbyl group or (v) wherein R4 and R5 together with the nitrogen atom to which they are bonded, form a cyclic ring in which further hetero atoms.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: September 26, 2006
    Assignee: Afton Chemical Intangibles LLC
    Inventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
  • Patent number: 6676715
    Abstract: There is provided use of a thermal stabiliser for increasing the thermal stability of a cetane improver in a fuel composition comprising (i) a fuel, and (ii) the cetane improver wherein the thermal stabiliser is a compound of the formula H—R1 wherein H is a group comprising a heterocyclic group and R1 is a hydrocarbyl group having from 10 to 200 carbons.
    Type: Grant
    Filed: May 11, 2001
    Date of Patent: January 13, 2004
    Assignees: The Associated Octel Company Limited, Octel Starreon, LLC
    Inventors: Cyrus Pershing Henry, Barbara Elizabeth Goodrich
  • Publication number: 20030150153
    Abstract: The present invention provides a method for inhibiting deposit formation in a fuel at a temperature of from 100 to 335° C., the method comprising combining with the fuel a composition comprising: (i) high temperature antioxidant; and (ii) a deposit inhibiting compound.
    Type: Application
    Filed: November 1, 2002
    Publication date: August 14, 2003
    Inventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon
  • Patent number: 6293976
    Abstract: There are disclosed low sulphur content middle distillate fuel oils which have their lubricity properties greatly improved through the addition of a compound having at least one substituted aromatic ring system wherein the substituents are one or more aliphatic hydrocarbyl groups having 14 to 36 carbon atoms, one or more hydroxyl groups or a derivative thereof and one or more amide groups.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: September 25, 2001
    Assignee: Infineum USA L.P.
    Inventors: Rinaldo Caprotti, Christophe Le Deore
  • Patent number: 6261327
    Abstract: The present invention is directed to an additive concentrate for reducing octane requirement comprising a cyclic amide alkoxylate compound of the formula I: wherein x is from 3 to 11; y is from 1 to 50; R1 and R2 are each independently hydrogen, hydrocarbyl of 1 to 100 carbon atoms and substituted hydrocarbyl of 1 to 100 carbon atoms; R3 is hydrocarbyl of 1 to 100 carbon atoms or substituted hydrocarbyl of 1 to 100 carbon atoms; each R4 is independently hydrocarbyl of 2 to 100 carbon atoms or substituted hydrocarbyl of 2 to 100 carbon atoms; R5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms, substituted hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms; a detergent selected from polyalkenylamines, Mannich amines, polyalkenylsuccinimides, poly(oxyalkylene) carbamates and poly(alkenyl)-N-substituted carbamates and an optional solvent.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: July 17, 2001
    Assignee: Shell Oil Company
    Inventors: Joseph Graham, Robert Peter Aiello, Earl Jon Haury
  • Patent number: 5912189
    Abstract: The present invention is directed to a composition containing the reaction product of:(A) a cyclic compound containing a 5, 6, or 7-member ring, the ring containing at least one nitrogen and at least one carbonyl group, at least one carbonyl group being adjacent to at least one said nitrogen;(B) an aldehyde or ketone of 1 to about 15 carbon atoms, or a reactive equivalent thereof; and(C) an etheramine represented by the formulaR.sup.4 (O(CH.sub.2 CH(R)O).sub.n --R.sup.3 --NH.sub.2).sub.y(C-I)wherein in formula (C-I), each n independently is a number from 0 to about 50; each R independently is selected from the group consisting of hydrogen, hydrocarbyl groups of 1 to about 16 carbon atoms, and mixtures thereof; R.sup.3 is selected from the group consisting of hydrocarbylene groups of about 2 to about 18 carbon atoms and groups represented by the formula ##STR1## wherein R.sup.5 and each R.sup.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: June 15, 1999
    Assignee: The Lubrizol Corporation
    Inventors: Thomas J. Wolak, Richard M. Lange
  • Patent number: 5880072
    Abstract: Compositions for reducing wear and friction of rubbing surfaces including mixtures of a cyclic amide and a monoester formed by reacting a dicarboxylic acid and a polyol in substantially equimolar amounts where the dicarboxylic acid is a dimer of an unsaturated fatty acid. The invention also relates to methods of use of such compositions.
    Type: Grant
    Filed: January 14, 1998
    Date of Patent: March 9, 1999
    Assignee: Virginia Tech Intellectual Properties, Inc.
    Inventors: Michael J. Furey, Czeslaw Kajdas
  • Patent number: 5837867
    Abstract: The present invention is directed to the use of cyclic amide alkoxylate compounds as additives in fuel compositions having a major amount of a mixture of hydrocarbons in the gasoline boiling range and a minor amount of one or more cyclic amide alkoxylate compounds of the formula: ##STR1## wherein x is from 2 to 20 and y is from 1 to 50. R.sub.1 and R.sub.2 are independently hydrogen or hydrocarbyl of 1 to 100 carbon atoms. R.sub.3 is hydrocarbyl of 1 to 100 carbon atoms and R.sub.4 is independently hydrocarbyl of 2 to 100 carbon atoms. R.sub.5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms.The invention is also directed to the use of these cyclic amide alkoxylate compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to novel cyclic amide alkoxylate compounds.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: November 17, 1998
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, Charles Lee Edwards, Pen-Chung Wang, Garo Garbis Vaporciyan
  • Patent number: 5478367
    Abstract: The addition to diesel or jet fuel of macrocyclic polyamines, especially those derived from PIBSA, or hydrocarbyl polyamines reduces particle emission, especially in association with organic nitrate cetane improvers.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: December 26, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Michael D. Sexton, Anthony K. Smith, Antonio Gutierrez, Stanley J. Brois
  • Patent number: 5368615
    Abstract: Improved additives/detergents for lubricant and fuel compositions are obtained by condensing a hydroxyalkyl or hydroxyaryl compound with an amine compound. The condensates according to the present invention are produced by the acid catalyzed condensation of the amine reactant with the hydroxy reactant.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: November 29, 1994
    Assignee: The Lubrizol Corporation
    Inventor: Thomas F. Steckel
  • Patent number: 5366516
    Abstract: Various heterocyclic compounds have been discovered that impart improved fuel economy and friction modification to lubricant and fuel compositions. These heterocyclic compounds of the invention preferably contain nitrogen and may be further reacted with hydrocarbyl carboxylic acid acylating reactants or hydrocarbyl phenolic reactants to give higher molecular materials. These higher molecular weight materials have higher oil-solubility and impart dispersancy properties to lubricant and fuel compositions.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: November 22, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Joseph W. Pialet, Paul E. Adams
  • Patent number: 5352251
    Abstract: The present invention is directed to the use of cyclic amide alkoxylate compounds as additives in fuel compositions having a major amount of a mixture of hydrocarbons in the gasoline boiling range and a minor amount of one or more cyclic amide alkoxylate compounds of the formula: ##STR1## wherein x is from 2 to 20 and y is from 1 to 50. R.sub.1 and R.sub.2 are independently hydrogen, hydrocarbyl of 1 to 100 carbon atoms or substituted hydrocarbyl of 1 to 100 carbon atoms. R.sub.3 is hydrocarbyl of 1 to 100 carbon atoms or substituted hydrocarbyl of 1 to 100 carbon atoms and R.sub.4 is independently hydrocarbyl of 2 to 100 carbon atoms or substituted hydrocarbyl of 2 to 100 carbon atoms. R.sub.5 is hydrogen, hydrocarbyl of 1 to 100 carbon atoms, or substituted hydrocarbyl of 1 to 100 carbon atoms or acyl of 1 to 20 carbon atoms.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: October 4, 1994
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, James R. Macias, Earl J. Haury, Sarah L. Weaver, Charles L. Edwards, Pen-Chung Wang, Garo G. Vaporciyan
  • Patent number: 5312460
    Abstract: Disclosed is a fuel composition comprising a hydrocarbon boiling in the gasoline or diesel range and from about 30 to about 5,000 parts per million of an alkylphenyl poly(oxypropylene) aminocarbamate having at least one basic nitrogen and an average molecular weight of about 600 to 6,000 and wherein the alkyl group is substantially straight-chain of at least 15 carbon atoms. The instant invention is based on the discovery that use of the unique hydrocarbyl group, i.e., an alkylphenyl group wherein the alkyl group is derived from a substantially straight-chain alkyl group of at least 15 carbon atoms imparts to the alkylphenyl poly(oxypropylene) aminocarbamate not only lubricating oil compatibility but also an unexpected decrease in crankcase deposits.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: May 17, 1994
    Assignee: Chevron Research Company
    Inventor: Thomas F. Buckley, III
  • Patent number: 5254138
    Abstract: Conductive fuel detergent compositions which posses not only the desirable characteristics of minimizing unwanted deposits on internal engine surface such as intake systems or port fuel injectors and exhibiting anticorrosion characteristics but also have conductive properties comprise quaternary succinimides which are characterized by having an oligomeric alkyl moiety on the succinimide ring. The additive may be prepared by condensing a (polyalkyl)succinic anhydride with a polyamino hydroxyalkyl quaternary ammonium salt, where the latter is formed by the reaction of a .OMEGA.-haloepoxide with a tertiary amine followed by reaction of the resulting product with a polyamine.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: October 19, 1993
    Assignee: UOP
    Inventor: Paul R. Kurek