Plural Nitrogens In The Hetero Ring (e.g., Imidazolines, Etc.) Patents (Class 44/342)
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Patent number: 9212331Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.Type: GrantFiled: September 10, 2014Date of Patent: December 15, 2015Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDEInventors: Wolfgang Beilfuss, Ralf Gradtke, Jennifer Knopf, Ingo Krull
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Publication number: 20150113858Abstract: Certain UV filter compounds improve the combustion properties of diesel fuel compositions, and in particular modify the ignition delay and/or modify the burn period and/or modify the peak pressure and/or increase the cetane number of the liquid fuel composition. A liquid fuel composition is provided containing: (a) a diesel base fuel suitable for use in an internal combustion engine; and (b) in the range of 10 ppmw to 2 wt %, by weight of the liquid fuel composition, of one or more organic UV filter compounds selected from imidazoles, triazines, triazones and triazoles, and mixtures thereof.Type: ApplicationFiled: October 23, 2014Publication date: April 30, 2015Inventor: Mark Lawrence BREWER
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Publication number: 20150113857Abstract: A liquid fuel composition comprising: (a) a gasoline base fuel suitable for use in an internal combustion engine; (b) one or more organic UV filter compounds selected from imidazoles, triazines, triazone and triazoles, and mixtures thereof. The liquid fuel composition provides benefits in terms of improved acceleration and/or power output of an internal combustion engine fuelled by said fuel as well as an increase in flame speed.Type: ApplicationFiled: October 23, 2014Publication date: April 30, 2015Inventor: Mark Lawrence BREWER
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Publication number: 20140115953Abstract: Additives may be used to decrease the viscosity of heavy residual hydrocarbons. The additives are prepared using a formulation comprising: a first component selected from the group consisting of (alkoxylated)-(di or tri)-alkyl phenol-aldehyde (amine) resins; ?-Olefin-maleic anhydride co-polymers and grafted polymers including half ester/amide and full ester/amide derivatives; and combinations thereof; and a second component which is a synergist and selected from the group consisting of polyamines, amidoamines, imidazolines, and combinations thereof.Type: ApplicationFiled: October 30, 2013Publication date: May 1, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: Jeffery K. Bolton, Kimchi Phan, Paul J. Biggerstaff, Ross Poland
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Publication number: 20130247450Abstract: A gasoline deposit control additive composition for use in a fuel comprising from about 70 to about 95 volume percent of hydrocarbons in the gasoline boiling range and from about 5 to about 30 volume percent of at least one alcohol, comprising the imine or tertiary amine product of the reaction between (a) at least one aldehyde or ketone or mixture thereof having the formula R16CHO, R16CH2CHO, R17(C=0)R18 or R17CH2(C=0)R18, wherein R16, R17, and R18 are the same or different and are each independently a straight or branched chain hydrocarbyl or aryl group that contains from 1 to 18 carbon atoms, and (b) a primary or secondary amine functionality.Type: ApplicationFiled: May 16, 2013Publication date: September 26, 2013Applicant: BUTAMAX ADVANCED BIOFUELS LLCInventor: Leslie R. Wolf
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Publication number: 20130205654Abstract: The use of imidazolium salts (I) where R1 and R3 are each independently an organic radical having 1 to 3000 carbon atoms, R2, R4 and R5 are each independently hydrogen or an organic radical having 1 to 3000 carbon atoms, X is an anion and n is the number 1, 2 or 3 as additives for fuels, especially as detergent additives for diesel fuels, as wax antisettling additives for middle distillate fuels and as lubricity improvers, and for improving the use properties of mineral and synthetic nonaqueous industrial fluids.Type: ApplicationFiled: February 7, 2013Publication date: August 15, 2013Inventors: Maxim PERETOLCHIN, Ludwig VOELKEL, Harald BOEHNKE, Markus HANSCH, Boris GASPAR, Christian SEITZ
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Publication number: 20130133242Abstract: A group of tertiary amine azides are useful as hypergolic fuels for hypergolic bipropellant mixtures. The fuels provide higher density impulses than monomethyl hydrazine (MMH) but are less toxic and have lower vapor pressures that MMH. In addition, the fuels have shorter ignition delay times than dimethylaminoethylazide (DMAZ) and other potential reduced toxicity replacements for MMH.Type: ApplicationFiled: January 23, 2013Publication date: May 30, 2013Applicant: CFD RESEARCH CORPORATIONInventor: CFD Research Corporation
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Publication number: 20120180382Abstract: The present disclosure relates to a gasoline additive concentrate including a reaction product of (a) 1,8-naphthalic anhydride; and (b) a reaction product of a hydrocarbyl-substituted succinic anhydride with a polyamine. Fuel compositions containing the additive concentrate are also disclosed. Method of reducing greenhouse gas emissions is also disclosed.Type: ApplicationFiled: January 19, 2011Publication date: July 19, 2012Applicant: Afton Chemical CorporationInventors: Xinggao Fang, Jason Lagona, Michel Nuckols, May Duffield Thomas
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Publication number: 20120110899Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.Type: ApplicationFiled: June 21, 2010Publication date: May 10, 2012Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGInventors: Wolfgang Beilfuss, Ralf Grastke, Jennifer Knopf, Ingo Krull
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Publication number: 20120023811Abstract: Biodiesel compositions are provided, containing non-phenolic additives that improve the oxidative stability and lower the acid number. The invention further provides non-phenolic additive concentrate compositions and diesel fuel compositions containing the above biodiesel compositions.Type: ApplicationFiled: July 8, 2009Publication date: February 2, 2012Applicant: DORIVALE HOLDINGS LIMITEDInventors: Stamoulis Stournas, Georgios Karavalakis
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Patent number: 7942941Abstract: The present invention generally relates to oil compositions, primarily to fuel oil and petroleum compositions produced there from susceptible to wax formation at low temperatures, to polymeric amides for use with such fuel oil compositions, and to methods for their manufacture.Type: GrantFiled: April 5, 2005Date of Patent: May 17, 2011Assignee: Akzo Nobel N.V.Inventors: Rodney Lee Cravey, Stephen L. Mead
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Patent number: 7857871Abstract: This invention provides a composition and a method of using a composition containing an imidazoline, optionally containing a paraffin inhibitor, for improving the pour point of liquid hydrocarbons, such as crude oil and petroleum fuel, and/or inhibiting or reducing the formation of paraffin deposits in such liquids.Type: GrantFiled: September 6, 2005Date of Patent: December 28, 2010Assignee: Baker Hughes IncorporatedInventors: Richard L. Martin, Harold L. Becker, Dora Galvan
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Patent number: 7824454Abstract: A unique combination of a certain poly(oxyalkylene) amine and a thiadiazole compound when employed as a fuel additive in a hydrocarbon fuel such as gasoline or diesel fuel will preclude fuel gauge sending units from sustaining sulfur-related corrosion damage or restore fuel gauge sending units, particularly silver-based fuel gauge sending units, in vehicle fuel storage tanks to like-new operational condition. Moreover, a method suitable for use in precluding fuel gauge sending units from sustaining sulfur-related corrosion damage or restoring silver-based fuel gauge sending units in gasoline or diesel vehicle fuel storage tanks to like-new operational condition using the combination of a certain poly(oxyalkylene) amine and a thiadiazole compound as a fuel additive is also described.Type: GrantFiled: August 17, 2004Date of Patent: November 2, 2010Assignee: Chevron Oronite Company LLCInventor: Stephen M. Moore
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Patent number: 7674365Abstract: A composition comprising: (i) a chelating aminocarboxylic acid-C8-C22 amine complex; (ii) a C15-C21 bis(2-hydroxyethyl)amide; and (iii) a C15-C44 imidazoline compound.Type: GrantFiled: October 6, 2005Date of Patent: March 9, 2010Assignee: Rohm and Haas CompanyInventors: Rajiv M. Banavali, Bharati Dinkar Chheda, Guido Mazza Manari
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Publication number: 20080182767Abstract: An imidazoline compound comprising the reaction product of (i) a dicarbonyl, (ii) a primary amine moiety of a polyamine, and (iii) a hydrocarbyl carbonyl is disclosed. Lubricant and fuel additive compositions comprising the imidazoline compound are also disclosed.Type: ApplicationFiled: January 29, 2007Publication date: July 31, 2008Inventor: John T. Loper
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Publication number: 20080168708Abstract: The present disclosure provides compositions and methods for reducing deposit formation in engines combusting a fuel containing ethanol and a corrosion inhibitor.Type: ApplicationFiled: January 11, 2007Publication date: July 17, 2008Inventors: Lawrence J. Cunningham, Richard J. Dumont
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Patent number: 7252690Abstract: This invention is a fuel composition having a sulphur content of ?50 ppm by weight and comprising ?50 ppm by weight of at least one fused polycyclic aromatic compound which has at least one hetero-atom selected from O and N either (a) as a heterocyclic group, or, (b) as an exocyclic group in which the hetero-atom is attached either directly or through one other carbon atom to a ring carbon atom wherein the fused polycyclic aromatic compound is substituted on at least one of its ring carbon atoms by a C1-C4 alkyl group. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuels, especially diesel fuels, when compared with the performance of the same fuel in the absence of such compounds.Type: GrantFiled: December 14, 2000Date of Patent: August 7, 2007Assignee: ExxonMobil Research and Engineering CompanyInventors: Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
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Patent number: 7175678Abstract: The present invention provides a polymeric a fuel composition comprising (i) a fuel; and (ii) a polymeric compound; wherein the polymeric compound comprises at least one monomer unit of Formula I wherein R1 is H or a C1-10 hydrocarbyl group; wherein L is an optional C1-30 hydrocarbyl linker group; and wherein heterocycle is an optionally substituted heterocyclic ring.Type: GrantFiled: September 26, 2003Date of Patent: February 13, 2007Assignee: Innospec LimitedInventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon, Derek Richard Green
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Patent number: 7112230Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): wherein R1 and R2 are independently C1-4 alkyl, R3 is a radical of the formula CmH2m wherein m is an integer of 2 to 6, R4 and R5 are each independently (i) hydrogen (ii) C1-4 alkyl, wherein R6 is selected from the group consisting of hydrogen and C1-4 alkyls and R7 is selected from the group consisting of hydrogen and C1-30 alkyl, (iv) wherein R8 is a saturated or unsaturated, linear, branched or cyclic, C7-23 hydrocarbyl group or (v) wherein R4 and R5 together with the nitrogen atom to which they are bonded, form a cyclic ring in which further hetero atoms.Type: GrantFiled: September 14, 2001Date of Patent: September 26, 2006Assignee: Afton Chemical Intangibles LLCInventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
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Publication number: 20030154648Abstract: This invention is a fuel composition having a sulphur content of ≦50 ppm by weight and comprising ≧50 ppm by weight of at least one fused polycyclic aromatic compound which has at least one hetero-atom selected from O and N either (a) as a heterocyclic group, or, (b) as an exocyclic group in which the hetero-atom is attached either directly or through one other carbon atom to a ring carbon atom wherein the fused polycyclic aromatic compound is substituted on at least one of its ring carbon atoms by a C1-C4 alkyl group. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuels, especially diesel fuels, when compared with the performance of the same fuel in the absence of such compounds.Type: ApplicationFiled: September 27, 2002Publication date: August 21, 2003Inventors: Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
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Patent number: 6083288Abstract: A strongly basic, hydrophobic amine which prevents the deposition of fuel-insoluble carboxylate deposits in fuel tanks and fuel transfer equipment is contained in a fuel additive package which minimizes the degradation of a hydrocarbon fuel during storage.Type: GrantFiled: July 7, 1998Date of Patent: July 4, 2000Assignee: BP Amoco CorporationInventor: Leslie R. Wolf
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Patent number: 5693107Abstract: The present invention is directed to the use of hydantoin-containing polyether alcohols as additives in a gasoline composition. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to hydantoin-containing compounds.Type: GrantFiled: August 6, 1996Date of Patent: December 2, 1997Assignee: Shell Oil CompanyInventors: Jiang-Jen Lin, Pen-Chung Wang, Sarah Louise Weaver
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Patent number: 5575823Abstract: Heavy diesel fuels, especially those containing sulphur and intended for marine or railroad use, are improved by incorporation therein of a combination of a cyclomatic manganese tricarbonyl and an ashless dispersant and optionally an antioxidant. Diesel fuels so modified show improved combustion characteristics and fuel economy.Type: GrantFiled: December 21, 1990Date of Patent: November 19, 1996Assignee: Ethyl Petroleum Additives LimitedInventors: Graeme M. Wallace, James P. Simmonds
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Patent number: 5560755Abstract: A composition comprising at least one compound of the general formula ##STR1## wherein each Ar is independently an aromatic group having from 4 to about 30 carbon atoms and from 0 to 3 optional substituents selected from the group consisting of amino, hydroxy- or alkyl-polyoxyalkyl, nitro, aminoalkyl, carboxy or combinations of two or more of said optional substituents, each R is independently a hydrocarbyl group, R.sup.1 is H or a hydrocarbyl group, R.sup.2 and R.sup.3 are each, independently, H or a hydrocarbyl group, R.sup.4 is a monovalent terminating group, each m is independently 0 or an integer ranging from 1 to about 10, x ranges from 0 to about 8, and each Z is independently OH, lower alkoxy, (OR.sup.5).sub.b OR.sup.6 or O.sup.-- wherein each R.sup.5 is independently a divalent hydrocarbyl group, R.sup.Type: GrantFiled: June 2, 1995Date of Patent: October 1, 1996Assignee: The Lubrizol CorporationInventors: Paul E. Adams, Richard M. Lange, Stephen H. Stoldt
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Patent number: 5538652Abstract: Combinations of dimercaptothiadiazole-mercaptan coupled derivatives with amines have been found to be effective load-carrying additives for lubricants and fuels.Type: GrantFiled: October 24, 1994Date of Patent: July 23, 1996Assignee: Mobil Oil CorporationInventors: Liehpao O. Farng, Arjun K. Goyal
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Patent number: 5516343Abstract: The instant invention relates to a hydrocarbon composition, such as motor fuel and lubricant compositions, containing a polyetheramide as a deposit control additive, to a concentrate containing such a polyetheramide as a deposit control additive, and to a method for improving the operation of an internal combustion engine.Type: GrantFiled: March 14, 1995Date of Patent: May 14, 1996Assignee: Huntsman CorporationInventor: Wei-Yang Su
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Patent number: 5489315Abstract: The present invention is directed to the use of hydantoin-containing polyether alcohols as additives in a gasoline composition. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to hydantoin-containing compounds.Type: GrantFiled: September 19, 1994Date of Patent: February 6, 1996Assignee: Shell Oil CompanyInventors: Jiang-Jen Lin, Pen-Chung Wang, Sarah L. Weaver
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Patent number: 5482521Abstract: The invention relates to lubricant and fuel additives having antiwear and friction reducing properties. The invention also relates to compositions of oils with viscosities appropriate for lubricants, greases produced therefrom, and fuels and methods for making these compositions. Described in this invention are products of nitrogen heterocycles, such as benzotriazole and tolyltriazole, with amines, such as alkyl amines, aliphatic diamines, alicyclic amines, heterocyclic amines, propylene amines, and aliphatic etheramines, that are linked using carbonyl compounds (e.g., aldehyde, ketone or glyoxal). Additionally, products generated by the reaction of carboxylic acids or carboxylic acid generating compounds (e.g., salts or esters) with carbonyl (e.g., aldehyde, ketone or glyoxal) coupled nitrogen heterocycles and amines, including those described above, are also included in this invention. These products can be used in fuels and lubricants to produce improved antiwear and friction reducing properties.Type: GrantFiled: May 18, 1994Date of Patent: January 9, 1996Assignee: Mobil Oil CorporationInventors: Noyes L. Avery, Edward G. Barry, James T. Carey, Lisa S. Crocker, Flora W. Feng, John Hiebert, Andrew G. Horodysky, Lloyd A. Nelson
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Patent number: 5478367Abstract: The addition to diesel or jet fuel of macrocyclic polyamines, especially those derived from PIBSA, or hydrocarbyl polyamines reduces particle emission, especially in association with organic nitrate cetane improvers.Type: GrantFiled: December 9, 1992Date of Patent: December 26, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Michael D. Sexton, Anthony K. Smith, Antonio Gutierrez, Stanley J. Brois
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Patent number: 5472457Abstract: Compounds with general formula ##STR1## where R.sup.1 represents a hydrogen atom or a hydrocarbon group containing 1 to 40 carbon atoms. R.sup.2 represents a hydrogen atom or a hydrocarbon group containing 1 to 12 carbon atoms, A, B, and C, which may be identical or different, each represent a divalent hydrocarbon group containing 2 to 6 carbon atoms, n is a whole number from 5 to 50, m and p are each zero or a whole number from 1 to 25, and the sum n+m+p is a whole number from 5 to 50.These compounds are used in multifunctional additive compositions for fuels used in internal combustion engines, in particular spark ignition engines, in admixture with at least one compound selected from the group formed by detergent-dispersant compounds, and at least one compound selected from the group formed by mineral or synthetic lubricating oils and polyglycols which are soluble in said fuels.Type: GrantFiled: June 2, 1994Date of Patent: December 5, 1995Assignees: Institut Francais du Petrole, Elf Antar FranceInventors: Henri Delhomme, Jean Gaillard, Philippe Mulard, Daniele Eber
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Patent number: 5460633Abstract: An additive comprising an oil-soluble polymer of a C2 to C6 mono-olefin such as polyisobutylene, which polymer has a molecular weight of less than about 500, is used in a fuel oil to reduce, on combustion of the fuel oil, one or more of particulate emissions, hydrocarbon emissions, carbon monoxide emissions, and oxides of nitrogen emissions.Type: GrantFiled: February 28, 1994Date of Patent: October 24, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Anthony K. Smith, Michael D. Sexton, Richard J. Hart
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Patent number: 5294233Abstract: An additive for improving the dispersibility of a particulate substance in an organic medium, a thermoplastic polymer, or a thermosetting resin, is at least one compound having a ##STR1## bond in the molecule, including, for example, compounds having an oxazolinium ion in the molecule. The preferred additive compounds are oligomeric or polymeric.Type: GrantFiled: July 31, 1991Date of Patent: March 15, 1994Assignee: Nippon Zeon Co., Ltd.Inventors: Shizuo Kitahara, Hiroyuki Watanabe, Takuji Kishimoto, Tetuya Toyoshima, Takafumi Kawanaka, Kohkichi Noguchi
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Patent number: 5160349Abstract: A fuel composition contains an antiwear additive comprising the reaction product of heterocyclic compound having antiwear activity such as a triazole e.g. benzotriazole, tolyltriazole, and a copolymer with succinic anhydride moiety, such as an olefin/maleic anhydride copolymer.Type: GrantFiled: November 20, 1989Date of Patent: November 3, 1992Assignee: Mobil Oil CorporationInventors: Angeline B. Cardis, Carl E. Shanholtz