Plural Nitrogens In The Hetero Ring (e.g., Imidazolines, Etc.) Patents (Class 44/342)
  • Patent number: 9212331
    Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.
    Type: Grant
    Filed: September 10, 2014
    Date of Patent: December 15, 2015
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Wolfgang Beilfuss, Ralf Gradtke, Jennifer Knopf, Ingo Krull
  • Publication number: 20150113857
    Abstract: A liquid fuel composition comprising: (a) a gasoline base fuel suitable for use in an internal combustion engine; (b) one or more organic UV filter compounds selected from imidazoles, triazines, triazone and triazoles, and mixtures thereof. The liquid fuel composition provides benefits in terms of improved acceleration and/or power output of an internal combustion engine fuelled by said fuel as well as an increase in flame speed.
    Type: Application
    Filed: October 23, 2014
    Publication date: April 30, 2015
    Inventor: Mark Lawrence BREWER
  • Publication number: 20150113858
    Abstract: Certain UV filter compounds improve the combustion properties of diesel fuel compositions, and in particular modify the ignition delay and/or modify the burn period and/or modify the peak pressure and/or increase the cetane number of the liquid fuel composition. A liquid fuel composition is provided containing: (a) a diesel base fuel suitable for use in an internal combustion engine; and (b) in the range of 10 ppmw to 2 wt %, by weight of the liquid fuel composition, of one or more organic UV filter compounds selected from imidazoles, triazines, triazones and triazoles, and mixtures thereof.
    Type: Application
    Filed: October 23, 2014
    Publication date: April 30, 2015
    Inventor: Mark Lawrence BREWER
  • Publication number: 20140115953
    Abstract: Additives may be used to decrease the viscosity of heavy residual hydrocarbons. The additives are prepared using a formulation comprising: a first component selected from the group consisting of (alkoxylated)-(di or tri)-alkyl phenol-aldehyde (amine) resins; ?-Olefin-maleic anhydride co-polymers and grafted polymers including half ester/amide and full ester/amide derivatives; and combinations thereof; and a second component which is a synergist and selected from the group consisting of polyamines, amidoamines, imidazolines, and combinations thereof.
    Type: Application
    Filed: October 30, 2013
    Publication date: May 1, 2014
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Jeffery K. Bolton, Kimchi Phan, Paul J. Biggerstaff, Ross Poland
  • Publication number: 20130247450
    Abstract: A gasoline deposit control additive composition for use in a fuel comprising from about 70 to about 95 volume percent of hydrocarbons in the gasoline boiling range and from about 5 to about 30 volume percent of at least one alcohol, comprising the imine or tertiary amine product of the reaction between (a) at least one aldehyde or ketone or mixture thereof having the formula R16CHO, R16CH2CHO, R17(C=0)R18 or R17CH2(C=0)R18, wherein R16, R17, and R18 are the same or different and are each independently a straight or branched chain hydrocarbyl or aryl group that contains from 1 to 18 carbon atoms, and (b) a primary or secondary amine functionality.
    Type: Application
    Filed: May 16, 2013
    Publication date: September 26, 2013
    Applicant: BUTAMAX ADVANCED BIOFUELS LLC
    Inventor: Leslie R. Wolf
  • Publication number: 20130205654
    Abstract: The use of imidazolium salts (I) where R1 and R3 are each independently an organic radical having 1 to 3000 carbon atoms, R2, R4 and R5 are each independently hydrogen or an organic radical having 1 to 3000 carbon atoms, X is an anion and n is the number 1, 2 or 3 as additives for fuels, especially as detergent additives for diesel fuels, as wax antisettling additives for middle distillate fuels and as lubricity improvers, and for improving the use properties of mineral and synthetic nonaqueous industrial fluids.
    Type: Application
    Filed: February 7, 2013
    Publication date: August 15, 2013
    Inventors: Maxim PERETOLCHIN, Ludwig VOELKEL, Harald BOEHNKE, Markus HANSCH, Boris GASPAR, Christian SEITZ
  • Publication number: 20130133242
    Abstract: A group of tertiary amine azides are useful as hypergolic fuels for hypergolic bipropellant mixtures. The fuels provide higher density impulses than monomethyl hydrazine (MMH) but are less toxic and have lower vapor pressures that MMH. In addition, the fuels have shorter ignition delay times than dimethylaminoethylazide (DMAZ) and other potential reduced toxicity replacements for MMH.
    Type: Application
    Filed: January 23, 2013
    Publication date: May 30, 2013
    Applicant: CFD RESEARCH CORPORATION
    Inventor: CFD Research Corporation
  • Publication number: 20120180382
    Abstract: The present disclosure relates to a gasoline additive concentrate including a reaction product of (a) 1,8-naphthalic anhydride; and (b) a reaction product of a hydrocarbyl-substituted succinic anhydride with a polyamine. Fuel compositions containing the additive concentrate are also disclosed. Method of reducing greenhouse gas emissions is also disclosed.
    Type: Application
    Filed: January 19, 2011
    Publication date: July 19, 2012
    Applicant: Afton Chemical Corporation
    Inventors: Xinggao Fang, Jason Lagona, Michel Nuckols, May Duffield Thomas
  • Publication number: 20120110899
    Abstract: An additive mixture for fuels including a) at least one N-formal, b) at least one antioxidant and c) at least one corrosion inhibitor. The additive mixture ensures that the additized fuels and lubricants have biocidal and corrosion-inhibiting additization, especially when they include proportions of renewable raw materials, such as biodiesel, and when they are in contact with copper-containing surfaces.
    Type: Application
    Filed: June 21, 2010
    Publication date: May 10, 2012
    Applicant: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORG
    Inventors: Wolfgang Beilfuss, Ralf Grastke, Jennifer Knopf, Ingo Krull
  • Publication number: 20120023811
    Abstract: Biodiesel compositions are provided, containing non-phenolic additives that improve the oxidative stability and lower the acid number. The invention further provides non-phenolic additive concentrate compositions and diesel fuel compositions containing the above biodiesel compositions.
    Type: Application
    Filed: July 8, 2009
    Publication date: February 2, 2012
    Applicant: DORIVALE HOLDINGS LIMITED
    Inventors: Stamoulis Stournas, Georgios Karavalakis
  • Patent number: 7942941
    Abstract: The present invention generally relates to oil compositions, primarily to fuel oil and petroleum compositions produced there from susceptible to wax formation at low temperatures, to polymeric amides for use with such fuel oil compositions, and to methods for their manufacture.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: May 17, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Rodney Lee Cravey, Stephen L. Mead
  • Patent number: 7857871
    Abstract: This invention provides a composition and a method of using a composition containing an imidazoline, optionally containing a paraffin inhibitor, for improving the pour point of liquid hydrocarbons, such as crude oil and petroleum fuel, and/or inhibiting or reducing the formation of paraffin deposits in such liquids.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: December 28, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Richard L. Martin, Harold L. Becker, Dora Galvan
  • Patent number: 7824454
    Abstract: A unique combination of a certain poly(oxyalkylene) amine and a thiadiazole compound when employed as a fuel additive in a hydrocarbon fuel such as gasoline or diesel fuel will preclude fuel gauge sending units from sustaining sulfur-related corrosion damage or restore fuel gauge sending units, particularly silver-based fuel gauge sending units, in vehicle fuel storage tanks to like-new operational condition. Moreover, a method suitable for use in precluding fuel gauge sending units from sustaining sulfur-related corrosion damage or restoring silver-based fuel gauge sending units in gasoline or diesel vehicle fuel storage tanks to like-new operational condition using the combination of a certain poly(oxyalkylene) amine and a thiadiazole compound as a fuel additive is also described.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: November 2, 2010
    Assignee: Chevron Oronite Company LLC
    Inventor: Stephen M. Moore
  • Patent number: 7674365
    Abstract: A composition comprising: (i) a chelating aminocarboxylic acid-C8-C22 amine complex; (ii) a C15-C21 bis(2-hydroxyethyl)amide; and (iii) a C15-C44 imidazoline compound.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: March 9, 2010
    Assignee: Rohm and Haas Company
    Inventors: Rajiv M. Banavali, Bharati Dinkar Chheda, Guido Mazza Manari
  • Publication number: 20080182767
    Abstract: An imidazoline compound comprising the reaction product of (i) a dicarbonyl, (ii) a primary amine moiety of a polyamine, and (iii) a hydrocarbyl carbonyl is disclosed. Lubricant and fuel additive compositions comprising the imidazoline compound are also disclosed.
    Type: Application
    Filed: January 29, 2007
    Publication date: July 31, 2008
    Inventor: John T. Loper
  • Publication number: 20080168708
    Abstract: The present disclosure provides compositions and methods for reducing deposit formation in engines combusting a fuel containing ethanol and a corrosion inhibitor.
    Type: Application
    Filed: January 11, 2007
    Publication date: July 17, 2008
    Inventors: Lawrence J. Cunningham, Richard J. Dumont
  • Patent number: 7252690
    Abstract: This invention is a fuel composition having a sulphur content of ?50 ppm by weight and comprising ?50 ppm by weight of at least one fused polycyclic aromatic compound which has at least one hetero-atom selected from O and N either (a) as a heterocyclic group, or, (b) as an exocyclic group in which the hetero-atom is attached either directly or through one other carbon atom to a ring carbon atom wherein the fused polycyclic aromatic compound is substituted on at least one of its ring carbon atoms by a C1-C4 alkyl group. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuels, especially diesel fuels, when compared with the performance of the same fuel in the absence of such compounds.
    Type: Grant
    Filed: December 14, 2000
    Date of Patent: August 7, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
  • Patent number: 7175678
    Abstract: The present invention provides a polymeric a fuel composition comprising (i) a fuel; and (ii) a polymeric compound; wherein the polymeric compound comprises at least one monomer unit of Formula I wherein R1 is H or a C1-10 hydrocarbyl group; wherein L is an optional C1-30 hydrocarbyl linker group; and wherein heterocycle is an optionally substituted heterocyclic ring.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: February 13, 2007
    Assignee: Innospec Limited
    Inventors: Cyrus Pershing Henry, David Leonard Pinch, Andrea Sneddon, Derek Richard Green
  • Patent number: 7112230
    Abstract: Injector deposits in a direct injection gasoline engine are reduced by providing as fuel for the operation of said direct injection engine a fuel composition comprising a fuel-soluble compound having the formula (I): wherein R1 and R2 are independently C1-4 alkyl, R3 is a radical of the formula CmH2m wherein m is an integer of 2 to 6, R4 and R5 are each independently (i) hydrogen (ii) C1-4 alkyl, wherein R6 is selected from the group consisting of hydrogen and C1-4 alkyls and R7 is selected from the group consisting of hydrogen and C1-30 alkyl, (iv) wherein R8 is a saturated or unsaturated, linear, branched or cyclic, C7-23 hydrocarbyl group or (v) wherein R4 and R5 together with the nitrogen atom to which they are bonded, form a cyclic ring in which further hetero atoms.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: September 26, 2006
    Assignee: Afton Chemical Intangibles LLC
    Inventors: Dennis J. Malfer, Scott D. Schwab, Timothy J. Henly
  • Publication number: 20030154648
    Abstract: This invention is a fuel composition having a sulphur content of ≦50 ppm by weight and comprising ≧50 ppm by weight of at least one fused polycyclic aromatic compound which has at least one hetero-atom selected from O and N either (a) as a heterocyclic group, or, (b) as an exocyclic group in which the hetero-atom is attached either directly or through one other carbon atom to a ring carbon atom wherein the fused polycyclic aromatic compound is substituted on at least one of its ring carbon atoms by a C1-C4 alkyl group. These compounds are capable of improving the antiwear and lubricity properties of a low sulphur fuels, especially diesel fuels, when compared with the performance of the same fuel in the absence of such compounds.
    Type: Application
    Filed: September 27, 2002
    Publication date: August 21, 2003
    Inventors: Robert Howie Barbour, David John Rickeard, Alan Mark Schilowitz
  • Patent number: 6083288
    Abstract: A strongly basic, hydrophobic amine which prevents the deposition of fuel-insoluble carboxylate deposits in fuel tanks and fuel transfer equipment is contained in a fuel additive package which minimizes the degradation of a hydrocarbon fuel during storage.
    Type: Grant
    Filed: July 7, 1998
    Date of Patent: July 4, 2000
    Assignee: BP Amoco Corporation
    Inventor: Leslie R. Wolf
  • Patent number: 5693107
    Abstract: The present invention is directed to the use of hydantoin-containing polyether alcohols as additives in a gasoline composition. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to hydantoin-containing compounds.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: December 2, 1997
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, Pen-Chung Wang, Sarah Louise Weaver
  • Patent number: 5575823
    Abstract: Heavy diesel fuels, especially those containing sulphur and intended for marine or railroad use, are improved by incorporation therein of a combination of a cyclomatic manganese tricarbonyl and an ashless dispersant and optionally an antioxidant. Diesel fuels so modified show improved combustion characteristics and fuel economy.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: November 19, 1996
    Assignee: Ethyl Petroleum Additives Limited
    Inventors: Graeme M. Wallace, James P. Simmonds
  • Patent number: 5560755
    Abstract: A composition comprising at least one compound of the general formula ##STR1## wherein each Ar is independently an aromatic group having from 4 to about 30 carbon atoms and from 0 to 3 optional substituents selected from the group consisting of amino, hydroxy- or alkyl-polyoxyalkyl, nitro, aminoalkyl, carboxy or combinations of two or more of said optional substituents, each R is independently a hydrocarbyl group, R.sup.1 is H or a hydrocarbyl group, R.sup.2 and R.sup.3 are each, independently, H or a hydrocarbyl group, R.sup.4 is a monovalent terminating group, each m is independently 0 or an integer ranging from 1 to about 10, x ranges from 0 to about 8, and each Z is independently OH, lower alkoxy, (OR.sup.5).sub.b OR.sup.6 or O.sup.-- wherein each R.sup.5 is independently a divalent hydrocarbyl group, R.sup.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 1, 1996
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, Richard M. Lange, Stephen H. Stoldt
  • Patent number: 5538652
    Abstract: Combinations of dimercaptothiadiazole-mercaptan coupled derivatives with amines have been found to be effective load-carrying additives for lubricants and fuels.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: July 23, 1996
    Assignee: Mobil Oil Corporation
    Inventors: Liehpao O. Farng, Arjun K. Goyal
  • Patent number: 5516343
    Abstract: The instant invention relates to a hydrocarbon composition, such as motor fuel and lubricant compositions, containing a polyetheramide as a deposit control additive, to a concentrate containing such a polyetheramide as a deposit control additive, and to a method for improving the operation of an internal combustion engine.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: May 14, 1996
    Assignee: Huntsman Corporation
    Inventor: Wei-Yang Su
  • Patent number: 5489315
    Abstract: The present invention is directed to the use of hydantoin-containing polyether alcohols as additives in a gasoline composition. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement increases and reducing octane requirement. The invention is further directed to hydantoin-containing compounds.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: February 6, 1996
    Assignee: Shell Oil Company
    Inventors: Jiang-Jen Lin, Pen-Chung Wang, Sarah L. Weaver
  • Patent number: 5482521
    Abstract: The invention relates to lubricant and fuel additives having antiwear and friction reducing properties. The invention also relates to compositions of oils with viscosities appropriate for lubricants, greases produced therefrom, and fuels and methods for making these compositions. Described in this invention are products of nitrogen heterocycles, such as benzotriazole and tolyltriazole, with amines, such as alkyl amines, aliphatic diamines, alicyclic amines, heterocyclic amines, propylene amines, and aliphatic etheramines, that are linked using carbonyl compounds (e.g., aldehyde, ketone or glyoxal). Additionally, products generated by the reaction of carboxylic acids or carboxylic acid generating compounds (e.g., salts or esters) with carbonyl (e.g., aldehyde, ketone or glyoxal) coupled nitrogen heterocycles and amines, including those described above, are also included in this invention. These products can be used in fuels and lubricants to produce improved antiwear and friction reducing properties.
    Type: Grant
    Filed: May 18, 1994
    Date of Patent: January 9, 1996
    Assignee: Mobil Oil Corporation
    Inventors: Noyes L. Avery, Edward G. Barry, James T. Carey, Lisa S. Crocker, Flora W. Feng, John Hiebert, Andrew G. Horodysky, Lloyd A. Nelson
  • Patent number: 5478367
    Abstract: The addition to diesel or jet fuel of macrocyclic polyamines, especially those derived from PIBSA, or hydrocarbyl polyamines reduces particle emission, especially in association with organic nitrate cetane improvers.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: December 26, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Michael D. Sexton, Anthony K. Smith, Antonio Gutierrez, Stanley J. Brois
  • Patent number: 5472457
    Abstract: Compounds with general formula ##STR1## where R.sup.1 represents a hydrogen atom or a hydrocarbon group containing 1 to 40 carbon atoms. R.sup.2 represents a hydrogen atom or a hydrocarbon group containing 1 to 12 carbon atoms, A, B, and C, which may be identical or different, each represent a divalent hydrocarbon group containing 2 to 6 carbon atoms, n is a whole number from 5 to 50, m and p are each zero or a whole number from 1 to 25, and the sum n+m+p is a whole number from 5 to 50.These compounds are used in multifunctional additive compositions for fuels used in internal combustion engines, in particular spark ignition engines, in admixture with at least one compound selected from the group formed by detergent-dispersant compounds, and at least one compound selected from the group formed by mineral or synthetic lubricating oils and polyglycols which are soluble in said fuels.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: December 5, 1995
    Assignees: Institut Francais du Petrole, Elf Antar France
    Inventors: Henri Delhomme, Jean Gaillard, Philippe Mulard, Daniele Eber
  • Patent number: 5460633
    Abstract: An additive comprising an oil-soluble polymer of a C2 to C6 mono-olefin such as polyisobutylene, which polymer has a molecular weight of less than about 500, is used in a fuel oil to reduce, on combustion of the fuel oil, one or more of particulate emissions, hydrocarbon emissions, carbon monoxide emissions, and oxides of nitrogen emissions.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 24, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Anthony K. Smith, Michael D. Sexton, Richard J. Hart
  • Patent number: 5294233
    Abstract: An additive for improving the dispersibility of a particulate substance in an organic medium, a thermoplastic polymer, or a thermosetting resin, is at least one compound having a ##STR1## bond in the molecule, including, for example, compounds having an oxazolinium ion in the molecule. The preferred additive compounds are oligomeric or polymeric.
    Type: Grant
    Filed: July 31, 1991
    Date of Patent: March 15, 1994
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Shizuo Kitahara, Hiroyuki Watanabe, Takuji Kishimoto, Tetuya Toyoshima, Takafumi Kawanaka, Kohkichi Noguchi
  • Patent number: 5160349
    Abstract: A fuel composition contains an antiwear additive comprising the reaction product of heterocyclic compound having antiwear activity such as a triazole e.g. benzotriazole, tolyltriazole, and a copolymer with succinic anhydride moiety, such as an olefin/maleic anhydride copolymer.
    Type: Grant
    Filed: November 20, 1989
    Date of Patent: November 3, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Angeline B. Cardis, Carl E. Shanholtz